© 2003 mark s. davis ap chemistry chapter 2. © 2006 mark s. davis 5

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© 2003 Mark S. Davis AP Chemistry Chapter 2

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Page 1: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2003 Mark S. Davis

AP Chemistry

Chapter 2

Page 2: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

5

Page 3: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

•http://dbhs.wvusd.k12.ca.us/webdocs/ChemTeamIndex.html

Page 4: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

• A man was out walking in the desert when a voice said to him, "Pick up some pebbles and put them in your pocket, and tomorrow you will be both happy and sad."

• The man obeyed. He stooped down and picked up a handful of pebbles and put them in his pocket. The next morning he reached into his pocket and found diamonds and rubies and emeralds. And he was both happy and sad. Happy he had taken some - sad that he hadn't taken more.

• And so it is with education

Page 5: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Atomic Theory of Matter

• Dalton’s Postulates1. Each element is composed of

extremely small particles called

2. All atoms of a given element are identical; the atoms of different elements are different and have different properties (including different masses.)

Page 6: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Dalton

3. Atoms of an element are not changed into different types of atoms by chemical reactions; atoms are neither created nor destroyed

4. Compounds are formed when atoms of more than one element combine; a given compound has the same relative number and kinds of atoms.

Page 7: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Define

• Atom:–

• Element:–

Page 8: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Define• Compounds:

– Substance composed

• Mixtures:– Combination of two or more

• Law of conservation of Mass:

Page 9: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Atomic Structure

• Protons:–

• Neutrons:–

• Electrons:– – Charge is 1.6 x 10-19C

Page 10: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Atomic Numbers

• Tell you:– Number of – Number of

Page 11: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Page 12: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Atomic Weights

• Atomic mass units (amu)

• 1 amu = 1.66054 x 10-24 g

• 1 g = 6.022137 x 1023 amu

• Mass on the table– 1 C = 12 amu

Page 13: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Average Mass

• Isotopes

• Ave mass = (mass x %) + (mass x %)

• C has two isotopes– C-12 at 98.93%– C-13 at 1.07 %– Determine the average atomic mass

Page 14: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

The Periodic Table

• Family/Group–

• Period–

• Isotopes

Page 15: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Types of elements

• Alkali Metals

• Alkaline Earth Metals

• Transition Metals

• Metalloids

• Non-metals

• Noble Gases

• Halogens

• Chalcogens

• Pnictides

• F-block

• Transuranium

Page 16: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Molecules and Ions

• Molecule:– Chemically combined elements

• Diatomic Molecule

Page 17: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Formulas

• Molecular–

• Empirical–

• Structural–

Page 18: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

IONS

• Cation:–

• Anion:–

• Polyatomic:–

Page 19: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Predicting Charges

• Based on the Periodic Table• Na• Br• O• Ca• Al• Si

Page 20: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Ionic Compounds

• Contain cations and anions–

• Use ELECTRONEGATIVITY to determine whether a compound is ionic–

Page 21: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Ionic Compounds

• Most ionic compounds can only be represented by empirical formulas–

• Writing formulas for ionic compounds– – –

Page 22: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Nomenclature

• System to ‘easily’ name chemical compounds.

• Organic, rules, rules, rules… – Ethane, ethanol, dimethyl ether

• Inorganic – much simpler

Page 23: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Ionic Naming

• Look at Periodic Table… Oxidation number

• Cations with one possible charge keep name– – – –

Page 24: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Ionic Naming

• Look at Periodic Table… Oxidation number

• Cations with more than one possible charge– – –

• Use the Stock System

Page 25: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Stock System

• Use a Roman Number, I, II, III, IV, V, VI to represent the oxidation number

• Cr+3

• Copper (I)

Page 26: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Anions

• Monatomic:–Ending is changed to

• Polyatomic: some have –ide ending–CN-

–OH-

Page 27: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Practice

• Write the formula for the following:–

Page 28: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Oxyanions

• Oddly enough… contain oxygen!–Ending is changed to:

• -ate • -ite

• Chlorine series

Page 29: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Practice

• Name the following–

Page 30: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Acids• Defined:

– Donate a proton

• Anion needs to be balance by hydrogen

• KNOW THE SIX STRONG ACIDS

Page 31: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Binary MOLECULAR Compounds

• Characterized by covalent bonds, not ionic

• Use prefixes mono-, di-, tri-, etc…

• More positive element named first

• Second element has –ide ending

Page 32: © 2003 Mark S. Davis AP Chemistry Chapter 2. © 2006 Mark S. Davis 5

© 2006 Mark S. Davis

Practice

• Name the following– – –