-cooh introduction to rilsanht h n-(ch grinding … · rilsan® ht - the first flexible ppa...

Rilsan® HT - The First Flexible PPA Confidential Arkema Property – Duplication prohibited

Introduction to Rilsan HT

1

ARKEMA


Castor seed

Castor plant

harvesting

grinding

Long chain PAPA11

monomer

Castor oil

Long chain PAPA12

Mid-chain PAPA612

Petroleum base

PA elastomerPEBA

Process flow of high performance PA

Rigid PA

High heat resistance PA

Aminoundecanoic acid

Sebacic acid

Decanediamine

H2N-(CH2)10-COOH

HOOC-(CH2)8-COOH

H2N-(CH2)10-NH2

Mid&long chain PA

PA610, 1010, 1012

PA elastomerPEBA

polymerization

45~100%Up to 95%

Amorphous PA

100% Up to 53%56% Up to 70%

Rilsan® XD


150°°°°C

110-120°°°°C

250°°°°C

110-120°°°°C

150°°°°C

220-200°°°°C

Metal

Metal & Rubber

Complex solutions (i.e. reinforced Rubber / FKM)

Cooling: PA11

HPPA MLT solutionPA12 Special Grade

Air IntakeTEEE, PA6, PA6-Alloy, Rubber

MetalMetal / / RubberRubber SolutionSolution Flexible Flexible ThermoplasticThermoplastic SolutionSolution

-

no solution

no solution

220-200°°°°C

A Breakthrough in Metal Replacement

Rilsan® HT creates opportunities to replace metal in tubing that were previously unthinkable !

Rilsan® HT New class of flexible PPA


What makes Rilsan® HT so different ?

�is the first flexible PPA to replace metal in tubing for high temperature applications

� surpasses other high-temperature thermoplastics with superior long-term resistance to thermo-oxidative and chemical aging at high temperatures

� is the only PPA being spin- weldable on aliphatic PA

� naturally fits into eco-design concepts

� can be easily manufactured on standard processing equipment

� offers cost-efficient manufacturing and system cost reduction

� features high design flexibility

� is a light- weight PPA resin

� offers exceptional dimensional stability

► Flexibility

► Processability: ► processing similar to aliphatic polyamides

► no need for special heating & cooling system

► excellent thermoforming and fitting insertion

►Long term heat resistance ► (thermooxidation) and chemical ► resistance at high temperature

► Integrity of mechanical properties ► at high temperature

► Spin-welding

► Low density

► Low moisture uptake

► Biobased

High Temperature Resistance…. PLUS : Rilsan® HT…..


Rilsan® HT: The optimum synergy of both

Rilsan® HT – The First Flexible PPA

LimitationsTemperature resistance

up to 150°C

LimitationsOnly available as injection grades due to intrinsic brittleness / stiffness of material

Poorer Long-Term Aging Resistance

Difficult overall processing

Rilsan® PA11 Classical PPA resins

Key Points:High melting point

High temperature resistance

Key Points:►Flexibility

►Excellent Long-Term Aging

► Resistance

►Ease of processing

►BioBased


Flexural modulus of Rilsan® HT compared to classic HT polymers –a breakthrough amongst HT materials

Rilsan® HT – Unprecedented Flexibility

Rilsan® HT: <<<< is the only PPA to combine the high-temperature resistance of conventional PPA grades with flexibility

Rilsan® HT

PA 11

9T6/6T

66/6T

6I/6T

46

1000

1500

2000

2500

3000

3500

150 170 190 210 230 250 270 290 310 330

Melting point (°°°°C)

Fle

xu

ral

mo

du

lus (

MP

a)

Classic PPA

New class of

flexible PPA

PA 6

(neat resins)

Rigid

Flexible

500

Rilsan® HT extrusion grades


Weight reduction by Rilsan® HTWeight savings, through

Metal replacement and substitution of rubber & other polymeric materials Low density

Rilsan® HT:

<<<< lowers total system weight by min. 50% (factor 2 to 3 vs Al, 6 to 8 vs steel)

<<<< is a light- weight PPA resin

<<<< helps to reduce emissions

and fuel consumption

8.67.8

7.1

2.21.7 1.7

1.4 1.3 1.2 1.2 1.1 1.1 1.0

0

2

4

6

8

10

Bra

ss

Ste

el

Zin

c

PT

FE

ET

FE

PV

DF

PP

S

PE

EK

PP

A 6

T

PA

46

PA

66

Rils

an®

HT

PA

11

MetalFluorinated Polymers

Other HT/HP

PolymersClassic

HT Materials

Densi

ty [

g/c

m3]

Ril

sa

n®

HT Rubber

1,15 – 1,3

1.211.18

1.14

1.08

1.02

0.85

0.95

1.05

1.15

1.25

Density of Rilsan® HT compared to metal, rubber and other polymeric materials

Rilsan® HT

is more

than 10%

lighter than

classic PPA

EnvironmentalEnvironmental

Metal assembly / 1000g � Rilsan® HT / 350gWeight gain: Rilsan® HT 3 times lighter

Blow-by @ VW

Alu tube w/ Brass QC (280g) resp. w/ Alu QC (110g) --> Rilsan® HT tubing / 50gWeight gain: Rilsan® HT 2 to 6 times lighter

EGR vacuum tubing @ PSA

Alu assembly / 270g � Rilsan® HT / 110gWeight gain: Rilsan® HT 2.5 times lighter

TOC @ Hyundai


System Cost reduction by Rilsan® HT

Rilsan® HT vs. metal based tubing assembly:

Rilsan® HT: <<<< generates up to 50% cost savings vs. metal tubing assemblies

0

10

20

30

40

50

60

70

80

90

100

Syst

em

cost

s[

Base

100 o

f M

eta

l Ass

em

bly

Syst

em

Cost

]

Assembly

Processing(Extrusion,Thermoforming)

Material

Component / system cost

Metal Tubing Assembly

Rilsan® HT Tubing Assembly

EconomicalEconomical


Rilsan® HT product line up

Extrusion grade

Rilsan® HT CESV P010TL

Rilsan® HT CESV Bk P010TL HP

Rilsan® HT CESV Bk P223TL


Rilsan® HT CZM30 Bk TLD

Rilsan® HT CSR13

Injection grade

feature (flexural modulus)

Standard (820MPa)

High pressure (1530MPa)

Flexible (520MPa)

Improved hydrolysis (820MPa)

feature (flexural modulus)

GF30% (7300MPa)

Conductive (7600MPa)

Rilsan® HT CMFO High flowability, non-filled (1800MPa)

Rilsan® HT CMNO TL Standard, non-filled (1370MPa)

Rilsan® HT CMNO Standard, non-filled (1800MPa)


… already been selected by many OEM

Rilsan® HT – …


Rilsan® HT – with best fit ….

Intercooler

EGR cooler EGR valve

Injector

Blow-by

Turbo

Air

Fuel

SCR

DPF

DOC

AdBlueTank

Exhaust Gas

DPF (Diesel Particulate Filter)

SCR (catalyst)

AdBlue®Tank

and InjectionDOC(Diesel OxydationCatalyst)

EGR

EGR Valve

Tubing

Mixer

SCR / AdBlue®

Air

Ma

na

ge

me

nt

Ag

gre

ssiv

e

Me

dia

Mn

gt.

Oil

Mn

gt.

Aq

ue

ou

s

Me

dia

Mn

gt.

EGR EGR (exhaust gas recirculation)

Air IntakeAir Intake

TOC TOC (Transmission Oil

Cooling)

BlowBlow--byby

AdBlueAdBlue®® / SCR / SCR (selective catalytic

reduction)

CoolingCooling

Fu

el

Mn

gt.

High High

TemperatureTemperature

Fuel LinesFuel Lines

… to Euro 6 & key powertrain technologies


� GradeGradeGradeGrade: Rilsan® HT CESV P010TL� Case studyCase studyCase studyCase study: Powertrain Powertrain Powertrain Powertrain ---- Aggressive Media ManagementAggressive Media ManagementAggressive Media ManagementAggressive Media Management

Blow By LineBlow By LineBlow By LineBlow By Line� Replaced:Replaced:Replaced:Replaced: Aluminium tubing / HPPA with heat shield� Status:Status:Status:Status: Approved and in series prod. since Q3 2010

at VW (PV 3936) / AUDI / SEAT / Porsche / Bentley; Daimler, Mahindra, Ferrari / Maserati / Alfa Romeo, Chrysler

� Models:Models:Models:Models: VW VW VW VW groupegroupegroupegroupe: : : : <<<<all diesel engines (having a diesel particle filter, due to new Euro 5/6 regulation), models/platforms starting with 2,0l & 1,6l engines, eg. Golf, Passat, Tiguan, A3, Skoda, …) <<<< all new 12 cyl. gasoline engines (e.g.A8, Phaeton, Bentley)Fiat Fiat Fiat Fiat groupegroupegroupegroupe: <<<< e.g. for new V6 engines of Ferrari & Chrysler for Maserati, Alfa Romeo, Chrysler

� Example: Example: Example: Example:

Rilsan® HT Tubing

AirBlow By GasExhaust Gas

Combustion Chamber

Piston

Connecting rod

Crankshaft

Oil pan

Blow-by tubing

Air IntakeExhaust gaz


Crankcase

2 temp. classes:►160°°°°C

►180°°°°C

Case: Aggressive M. / Blow By


IntercoolerIntercooler

FilterFilterClean air tube

Outside Intercooler Tube

OUTSIDE TURBO TUBE

Exhaust

gas pipeAIRAIR GAS

Turbo -Compressor

Outside Turbo TubeOutside Turbo Tube

4 cylinders engine4 cylinders engine

Rilsan® HT

180°°°°C < T < 200°°°°C

P~2-4bar, T ~ 180-200°C

P~2-4bar, T ~ 110°C

T ~125 to 150°°°°C

T ~125 to 150°°°°C

P~0.7-1 bar, T ~ 20-40°C

Orgalloy® LT

Orgalloy® LT

� GradesGradesGradesGrades: Rilsan® HT CESV P010TLRilsan® HT CESVO P223TL (“ultra-flexible”)

� Case studyCase studyCase studyCase study: Powertrain Powertrain Powertrain Powertrain –––– Air / Pressure ManagementAir / Pressure ManagementAir / Pressure ManagementAir / Pressure ManagementAir IntakeAir IntakeAir IntakeAir Intake

� Replaced:Replaced:Replaced:Replaced: Metal, Rubber� Status:Status:Status:Status: Under development� ExampleExampleExampleExample:

Rilsan® HT Tubing Case: Air Mngt. / Air Intake


� GradesGradesGradesGrades: Rilsan® HT CESV P010-HP TL (tubing)Rilsan® HT GF reinforced (QC)Connection by spin-welding

� Case studyCase studyCase studyCase study: Powertrain Powertrain Powertrain Powertrain ---- Oil Oil Oil Oil MngtMngtMngtMngt. / Transport. / Transport. / Transport. / TransportTOC TOC TOC TOC (Transmission Oil Cooling)

� Replaced:Replaced:Replaced:Replaced: Metal, Rubber Tubing� Status:Status:Status:Status: Approved at BMW, Greatwall

� Models:Models:Models:Models: will be in series for new platforms

� ExampleExampleExampleExample:

Metal, Rubber Tubing

replaced by:

Rilsan® HT CESV P010-HP TLRilsan® HT GF reinforced

(QC)

Gearbox

Transmission Fluid Cooler

Radiator

Transmission Oil Cooler Hose

Rilsan® HT CESV P010-HP TL

Specification:►3000h oil 150°°°°C / peak 175°°°°C►Burst resistance: hot oil at 220°°°°C

Rilsan® HT Tubing Case: Oil Mngt. / TOC


Case: Cooling

� GradesGradesGradesGrades: Rilsan® HT CESV P010 TL (medium temp.)Rilsan® HT CESV black P123 TL (high temp.)

� Case studyCase studyCase studyCase study: Powertrain Powertrain Powertrain Powertrain ---- Aqueous Media Aqueous Media Aqueous Media Aqueous Media MngtMngtMngtMngt....Cooling linesCooling linesCooling linesCooling lines

� Replaced:Replaced:Replaced:Replaced: Aluminium tubing / Rubber� Status:Status:Status:Status:

Current grade: Current grade: Current grade: Current grade: RilsanRilsanRilsanRilsan®®®® HT CESV P010 TLHT CESV P010 TLHT CESV P010 TLHT CESV P010 TL� BMWBMWBMWBMW

� Mini, series 3, 5, 7 / new Hybride� SOP end 2013

� DAIMLERDAIMLERDAIMLERDAIMLER� e.g. Mercedes Class “C”� SOP end 2013

� VOLVO Truck (US)VOLVO Truck (US)VOLVO Truck (US)VOLVO Truck (US)

New grade: CESV black P123 TL New grade: CESV black P123 TL New grade: CESV black P123 TL New grade: CESV black P123 TL � Under evaluations

(technical feedback from customer to pass VW specification)

125 - 130°°°°C (temp. class rating) (current grade CESV P010TL)

135 - 145°°°°C (temp. class rating) (new grade CESV P123L)

Rilsan® HT Tubing


� GradeGradeGradeGrade: Rilsan® HT CESVO P223 TL – “ultra-flexible” Rilsan® HT Grade� Case studyCase studyCase studyCase study: Industrial Applications Industrial Applications Industrial Applications Industrial Applications –––– Air / Vacuum ManagementAir / Vacuum ManagementAir / Vacuum ManagementAir / Vacuum Management

e.g. High Temperature Pneumatic TubingHigh Temperature Pneumatic TubingHigh Temperature Pneumatic TubingHigh Temperature Pneumatic Tubing� Replaced:Replaced:Replaced:Replaced: Metal, ETFE, PTFE� Status:Status:Status:Status: Under evaluation at customer / OEM� ExampleExampleExampleExample:

Temperature class:> 150°C

Key Benefits:

▶ Flexibility (520MPa) !

▶ “ultra-flexible”

Rilsan® HT Grade

Rilsan® HT Tubing Case: Industrial Tubing

-cooh introduction to rilsanht h n-(ch grinding … · rilsan® ht - the first flexible ppa...

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