,,., f•. b - usgsproduced about 400,000 tons of ore that averaged 0.4% cu, 2.72 opt ag, and q. 13...

1
DEPARTMENT OF THE INTERIOR U.S. GEOLOGICAL SURVEY 0 ,J . _l ) . ' ' Xsi:: ' z ·. < Ct:.. ,- " u < ' / ~ !" . '\, :/ , I ,, r -- . , ·- ' !· - + '" vx _ 5c :- >--< I \H- : "' s x,. \ \ · -:i ··- -- -- Base from U.S . Geological Survey, 1974 '' -- - ,, j , .,._. - Proterozoic rocks 6!"en1te and ;r1H1odlor1te Aleek1t.e and granophyre Sabbro and anorthoaite Intrue1ve rhyolit• M811C and f1l11r:: volcariic rocks Dick rhyol1t11 GJ Bl'1dla Formation (Nf1c volcanic rockel Fault, dashed whera inferred. X X ' ' ' '' ' ' ' ' I ' ,' I ' ' ' ' '' ____ .,,., X X X X X ' ' ' ' ' ' XX X X X ' ' ' ' ' ' ' ' ' ' ' ' ' ' X ' ' ' ' ' ' / / / , + + + f- -- ~- -- ' -- . . ,__! ___ ::_ __ J_ - -,_., ,, I \i . --~ ;j .. .. ;, I ' I "- --~ ......... ~. I ~ - ---• ---- -~ - -.L. ' -'-'0, --·--· -"""'--- "·, M + + + + I ' ' Y' ~' ~' - ,, ., E ., + + + + + + + - '\'Xs-C -- ' "- -- u ;• pbs,,xsc '" ~lcw ' ] ,:. · A ;< f•. B 0 0 ~•~• ..... •-~•~5 mi. 2 4 6 klll . l "'""'" '·' ' . EDITOR'S NOTE The metallogenic map of volcanogenic massive - sulfide occurrences in Arizona is one of several planned or published preliminary and interim products of a study of the distribution and setting of volcanogenic massive sulfides in the western United States. Volcanogenic massive-sulfide occurrences are inferred to be associated with the development of volcanic arcs or with rift systems in a mainly subaqueous environment . The massive - sulfide occurrences on this map were probably deposited in ancient island - arc environments. Most are considered to be proximal with respect to their emplacement near centers of volcanic activity. Some may have been deposited distal f rom volcanic centers. The distribution of favorable host rocks for massive-sulfide deposits is also shown on the map. The host rocks are not necessarily formal stratigraphic units, and they may contain several lithologic types . They are shown here in order to delineate areas that may contain undiscovered massive-sulfide deposits. Locality no. 2 3 4 Deposit name Antler --------- - Gppper World---- Copper King----- Old Dick/Bruce-- Location 34°52"57"N 113°58-06"W 34°54-35"N 113°55-1s"w 34°34-11"N 113°1Y45"W 34°32"47"N 113°1Y52"W MISCELLANEOUS FIELD STUDIES MAP MF-1853-B VOLCANOGENIC MASSIVE-SULFIDE MAP SERIES Table 1, --Proterozoic volcanogenic massive - sulfide occurrences in Arizona l- , approx i mate; ND, not determined; opt, ounces per ton] Age (b.y.} Host rock lithology 1,7-1.8 Quartzofeldspathic schist-- 1. 7- 1.8 -----------do.------------- Felsic volcaniclastic rocks intercalated with basalts, Na ture of exposure Dormant underground mine. --------do , -------- --- -- - --d O .---- -- -- ------- -do, --- -- --- Commodities Cu, Zn, Pb, Ag, Au Cu, Zn, Ag, Au---- Zn, Pb, Gu, Ag, Au Zn, Cu, Pb, Ag, Au Remarks Produced 78,000 tons of ore grading 37o Cu, 6.5% Zn, 0.75% Pb, l.l opt Ag, and 0,01 opt Au, Produced 61,000 tons of ore grading 3.55% Cu, l0.29% Zn, 0.66 opt Ag, and 0,0017 opt Au. Produced about 23,000 tons of Cu-Pb-Zn ore. L ,: SUMMARY OF PROTEROZOIC VOLCANOGENIC MASSIVE - SULFIDE OCCURRENCES IN ARIZONA At contact between thick basaltic unit and younger rhyolitic r acks, Collectively, the Old Dick/Bruce ore bodies yi elded 1,499,421 tons of ore grading ll .8% Zn and 3.5% Cu. The ore contained from 0.32 to 0.35 opt Ag, and from 0 ,0014 to 0.0026 opt Au. ' 10 '3 de sb ' ' . EXPLANATION '' Prescott-Jerome area insert Phanerozoic rocks ir I qd I ge I bg I Volcanogenic massive-sulfide occurrences comprise a distinct 1,7-1,8-b.y.-old metallogenic province in Arizona. All of the 41 occurrences shown on this map are stratabound accumulations of iron and base-metal sulfides containing v ariable amounts of gold and silver . Lode deposits and occurrences of questionable origin have been omitted. A review of information on ·these deposits shows that they are widely distributed throughout the Early Proterozoic metavol c ano - sedimentary succession, but they share many similar ities (Donnelly and Hahn, 1981). Regional geo l ogic setting The massive-sulfide occurrences are hosted in a thick succession of submarine volcanic and volcaniclastic rocks exposed intermittently from east - central Arizona to the northwestern part of the state. More than three-fourths of the deposits and prospects occur in 1,740-1,790-m . y.-old volcano - sedimentary strata of the Yavapai Series in western Arizona and the Prescott - Jerome area . This age range and other ages in this report are based on revised decay constants (Steiger and JAger, 1977) and are approximately 30 m. y. younger than pr eviously published ages. 5 Copper Queen---- 6 Rudkins-------- - 7 Ked Cloud------- 8 Pinafore ---- ---- 9 Boston Arizona-- 34°32-17"N 113°13-45"W 34°31-33"N 1 t.1°13-44"W 34°31-19"N 113°14-o5"W 34°29-27"N 113° 16-39"W 34°31-24"N 112°36-46"W Within rhyolitic tuffs and epiclastic rocks overlying an andesite unit. Rhyolitic pyroclastic rocks - Above a thin basaltic unit within rhyolitic pyroclastic rocks. -1,75 At contact between thick basal tic unit and younger rhyolitic rocks. 1.74-1.79 Volcanic wackes, and felsic valcaniclastics and tuffs. Exhausted and closed underground mine, Prospect with shallow shaft. Prospect with shaft and adit. Zn, Gu ------------ ND---------------- Zn, Cu, Au, Ag---- Prospect-- ---- ------- Zn, Cu, Ag, Au---- Dormant underground Zn, Cu------------ mine. Produced 140,350 tons of ore averaging 4.7% Cu and 14.4% Zn , The ore con- tained about 0.38 opt Ag arid 0.0016 opt Au . No reported production , Produced about 200 tons of ore with an average grade of 6.4% Cu, 2,7% Zn, 0,69 opt Ag, and 0,075 opt Au. Produced about 1,900 tons with an average grade of 3.2% Cu, 13% Zn, 1.04 opt Ag, and 0.014 opt Au. Minor production. Massive-sulfide prospects in the Tonto basin and the Ma~at~al 10 United Verde---- 34°45;02" to ~1.79 Quartz crystal tuffs, fine- Dormant underground Cu, Zn, Au, Ag---- World class d~pos it; produced total of Int.ruaive roc:ka Mountains (localities 38 , 39 40 and 41) occur in metavolcano- (U.V.) 34°45;30"N grained fels lc tuffs, and mine and open pit. 30,672,846 tons of ore averaging 1r.1ntrus1ve rock• un<11v1dad O 4 77% C O 046 65 t<1.11u1ru <11ar1u sedimentary strata that are about 30-80 m.y. younger than the 112 ort9" to associated felsic volcani - u, ' opt Au, and 1. opt a<1,Govern118nt canyon Ol"•no, :nortt• Yavapai Series (Silver, 1967 : Conway and others, 1981 ). Recent 112°or36"W elastic rocks, Ag; 10 million tons of Zn-rich ~;.Bredy Butte arenodlorlte fieldwork indica t es that this volcanic succession extends westward ma:ssive sulfide were left in ore "- -' --- ", , -j-------------------c 1 ==c 1 ------------+.J.---------~ ,n~t~o ~~ t~, ;, N~e;w~R ~i~ v~•~r~ M ;, o~u~n ~t ~aci~n~, ~s an ~.c;'t~•~ Cca~v~ ,°"; C~r~•~•~k~a ~r ; ,;a~ .!a~n ~ -.:: t~a~t ~~ t :". _______________________________________________________________________ .J,,ocy .------------------------- tg may unconformably " ov er lie the Yavapa i Series (Conway and Silver, ",;::,',aa_, ,.. ..,~ 11 Haynes--------- - 34°45-23" to ~1 .79 Crystal tuffs and fine- Dormant underground Cu, Zn, Au, Ag---- Blind ore body at a depth of " /oaa---' "'- --- }--------------~ ;rexea- Gulet1=oEor,111at-t on , ------- --' --+---------H184a--,-b9 =.------Ma-ssiv e-; sul-fide- occ urrences=at= loc a- l- it - ie&=- 3S-,- 36c,--and------aa;Ca.--a.c'--------- - 404°5-· zs• ,,,.C'---.;.;----- --' gr =a tne ct=fel"s1.l!LU · ff•-c . ----- - Tne , ~ ,= S-O O=f-t -.;=d-e. velopetl=f0 r -0~=Unit-ed---------- r-:-l 37 appear to be hosted by this younger volcanic sequence , but 112 o 0 r 48 ,, to Verde workings. stratigraphic relationships are uncertain (Conway, 1983). 112 oor 53"W , ----= "' \------ -\'='i --- -l-~ -l- ---------- ,, c,c,,..;i~ a, :=; V~ ,aia ,a ,a ,, ., •, ~--------+-------+--J.Alterna-t-1.-v.eJ.. y .. .-J.nder.son-and--CuiLber.t-( . l-9 4-~-3ugge s.t-tha t-t:h e-C a. vc~ --------------------c,------------------------------------------------------------------------------ ::, Creek - New River Mountains section is intermediate in age between 12 United Verde--- - 34°45-04" to 1. 79 Massive rhyolite, pyro - clastics, and associated tuf f aceous sedlments with minor amounts of andesite lavas. Dormant underground mine. Cu, Au, Ag --- ----- Blind ore body; produced J,878,825 tans of ore grading 10.23% Cu, 0.039 opt Au, and 1,71 opt Ag. ' ' ' ------- 1 0 r=-1 the Yavapai Series and the Tonto Baain-Hazatzal Mountains strata. Extension 34 45-1Q"N J Two or more periods of folding are· recognized in the Yavapai (U.V.X.} 112°06;38" to Spud Mountain Volcanics Series, whereas only one major deformational event is evident in 112°06-50''\,/ m the younger volcanic strata. Throughout the metallogenic province, metamorphic grad~ is primarily greenschist facies , with Dacite of Burnt Canyon contact Green Gulch Volcanica 0 Grapevine Gulch Formetion Deception Rhyolite Brindle Pup Andesite Buzzard Rhyolite GJ Geddes Beeelt 1yncl1ne 0 Shea Basalt u amphibolite faciea developed locally. In most cases, primary textures permit identification and interpretation of protoliths. Massive-sulfide deposits Since the la te 1800's, stratabound Cu-Zn-Pb sulfide deposits in Arizona ha ve produced nearly 44 million tons of ore . Ten occurrences contained more than 100,000 tons of ore each, and three deposits yielded more than 4,000 , 000 tons each. The bulk of the production, however, was from the United Verde mine (locality 10), which produced more than 30 million tons of Cu - Au ore over a span of 68 years . Mine maps and cross sections of Anderson and Creasey (1958) suggest that the United Ve r de orebody contained more than 80 million tons of pyritic massive and semi-massive sulfides and stockwork ore. 13 14 15 16 17 Verd~ Central--- Copper Chief -- -- Iron King----~- Victor-Swindler and Huron- Montezuma Lone Pine--- ---- 34°44;23"N 112°0 r l 6"W 34°42"00".N 112°05-25"w 34°29-38''N u2°15-45"w to 34°30-20"N u2°15-19"w 34°2r 1 2"N t12°15-38"W to 34°2a-25"N 112° 15- 32"W 34°2r57''N 112°14-57"1,i 1. 75 Massive rh y olite and pyro- clas t ics. Dormant underground mi.ne. Cu------ ---------- Basalt flows and tuffs-------- --------do.---------- Cu, Au, Ag-------- Andesitic tuffaceous and -- ------ do, -- --- ----- Gu, Pb, Zn, Au, Ag volcaniclastic rocks inter- calated with felsic tuff. Quartz crystal tuffs and tuffaceous metasediments, Rhyo l ite tuff, tuff breccia, and phyllitic metasediments. Prospects------------ Cu, Ag, Au ---- -- -- Small, dormant Cu, Pb, Zn, Au, Ag underground mine, Occurs 4,000 ft south of U.V. mine. The deposit has ore reserves of 12l,l24 t ons grad i ng 2.94% Cu. Also known as Equator-Iron King mine; produced about 400,000 tons of ore that averaged 0.4% Cu, 2.72 opt Ag, and Q. 13 opt Au. Mined to a vertical depth of 2,600 ft, tl1e lron King producl'.d more thnn 5,659,749 t ons of ore. More than 5 million tons contained an average grade of 2.50% Pb, 7 ,34% Zn, 0, 19% Cu, 0.123 opt Au, and 3.69 opt Ag. No recorded production. Generalized geologic map of the Prescott-Jerome area fault ant1cl1na The massive-sulfide deposits have many features in common, including mineral assemblages, hydrothermal alteration, and structural complexity. Regionally, they are tightly clustered, with 25 of the 41 occurrences confined to three districts . Within a district , deposits can occur in nearly all facies of the mafic to felsic volcanic piles and at numerous stratigraphic levels. Most of the occurrences are assoc iated with fals ie volcanic rocks, but seve r al, including the 1.5 - million-ton Old Dick/Bruce deposit (locality 4), were formed during t he waning stages of mafic volcanism and clearly preda te the overlying felsic eruptives. The massive-sulfide deposits belong to the Cu-Zn group of volcanogenic deposits . on ly one deposit, the Iron King mine (locality 15) , contained appreciable amounts of lead. Published data on precious metal values are sparse, but by-product gold and silver were certainly economically important in many of the deposits. Sulfide assemblages are simple and consist primarily of pyrite, pyrrhotite, sphalerite, chalcopyrite , and galena. The sulfide ores exhibit primary mineralogical banding . and relict sedimentary textures can be found locally. Incomplete records show that 2,763 tons of ore were shipped with average grade of 5,35% Gu, 0.20 opt Au, and 3.16 opt Ag, {modified after Anderson and others, 1971) ---- - < i k -I -.; ,· .... _ I "-- · ,L .. .... X p •. ' \ ·! ·-·---- -L -: ,, .--,, SCAL E l 1000000 '' '''. ';_ ' - .. ' rl ' , u--.xsc I. \ .= Fc= ce==~.-'i ' ..===== c-- ____ 2 0 5'============' 50 MI LES =, -------,=CCC,F-a=<O=C C"----- c2e5=======-'50 Kl L C-M ':: re: -IS '- i ' -:. -, -- -- --+----- ,_; f~. ,,. ' - - I ,• ,' "" ( ' .,/ C: C. ~ ,:J. 6"·' . l,··· .q . x~ . '·i. .. -- ". " ' ~' i.Xsc,, ,.~ "'1 ';-, dotted Where conceled ''j I'·'~ ·, ' -~ . QI, /~ -' -~ "'""' '' Xsc ,.., ,, ; ' .- ~Xsc '., . .. ·J 1 - "" ' " ' s.. .\< , / -- .!) ~" (' •, s ... .. - -·c .. , ____ " '" 1 :; . E N L -,-{ ' ,, ,. . ,,2-U! -\ n. : <- 'c ·f - ' ' " ' ' 11 ' ' I - \'"L'. ; ______ .. :-('-, --~ xsc:··_ ··- -- ~ >< i u. j ,, ', \ _, ' .. , ..,. __ ··-·· > - -''f'-- I Geology simplified from Wilson and others, 1969 and Anderson and others, 1971 Chert and cherty sericitic tuffs occur along strike with or in close s tratigraphic association with most of the sulfide bodies. Oxide-fa c ies iron formation and ferrug i nous chert are reported from 17 occurrences. All of the major deposits exhibit hydrothermally altered footwall zones that reflect varying degrees of chlorltization, sericitization, and silicification. Alteration pipes are characterized by a chloritic core and a sericitic outer zone . Chlori t ic "stringer oreff or stockwork ore was economically important in several deposits, including the United Verde and the Old Dick/Bruce. Large semi conform.able zones of silicification, epidotization, and albitization li e stratigraphically beneath the a lterat i on pipe at the Old Dick/Bruce deposit (Conway and others, 1985) but have yet to be documented elsewhere. The sulfide orebodies have high ratios of plunge length to strike length and were clearly deformed within the encasing volcanic strata. Many of the larger deposits are described as elliptical lense s or as rod-l i ke bodies that plunge steeply and are parallel to major or •inor f old axes . Ratios of plunge length to strike length are as much as 8:1 at the Blue Bell (locality 29), and stretching ratios of 3:1 are not uncommon elsewhere. Consequently , most deposits present small exploration targets at the surface. REFERHNCES CITED Anderson, C. A. , Blacet, P. M. , Silver, L. T. , and Stern, T. W., 1971, Revision of the Precambrian stratigr aphy in the Prescott-Jerome area, Yavapai County, Arizona: U.S. Geological Survey Bulletin 1324- C, p . Cl-Cl6. Anderson, C. A., and Creasey, S, C., 1958, Geology and ore deposits of the Jerome area, Yavapai County, Arizona: U.S . Geological Survey Professional Paper 308, 185 p. Anderson, P., and Guilbert , J . M., 1979, The Precambrian massive sulfides of Arizona -- a distinct metallogenic epoch and province : Nevada Bureau of Hines and Geology Report 33, p. 39-48. Conway, c. M., 1983, Volcanogenic mineralization at Copper Cemp Creek and the potential for massive sulfide deposits in the Proterozoic Alder format i on, Ari zona [abs.]: Geological Society of Amer ica Abstracts with Programs, v, 15, no, S, p. 298 . Conway, C. H. , Connelly , T. J. , and Robison, L. C., 1985, Volcanic and hydrothermal systems; Early Proterozoic massive sulfide deposits, Bagdad , Arizona [abs] : U.S. Geological Survey Circular 949 , p. 8-9. Conway. C. M ., and Silver, L. T., 1984a , Extent and implications of silic ic alkalic magmatism and quartz arenite sedimentation in the Proterozoic of central Arizona: Geological Society of America Abstracts with Programs, v. 16, Conway , C. M,, and Silver, L, T. , 1984b, From island arc to craton ; two major orogenic cycles in the Early Proterozoic of Arizona [abs.): Symposium on Southwestern geology and paleontology; Museum of Northern Arizona, Flagstaff , Arizona . Conway , C. M., Silver. L. T. , Vrucke, C. T., and Ludwig, K. R., 1981, Proterozoic Mazatzal quartzite of central Arizona: Geolog i cal Society of America Abstracts with Programs, v. 13, no. 2, p. SO . Donnelly, H. E., and Hahn, G. A. , 1981, A review of the Precambrian volcanogenic massive aulfide deposits in central Arizona and the relationship to their depositional environment: Arizona Geological Society Digest, v, 14, p . 11-21. Si lver , L, T .• 1967, Appare nt age r e lat iona in the older Preca mbrian stratigraphy of Arizona [abs.]. J.n Burwash, R. A. , and Horton , R. D. , eds., Geochronology of Precambrian stratified rocks: Edmonton , University of Alberta, p. 87 . Steiger, R. H., and JAger, E. , 1977, Subcommission on geochronology , conven t ion on the use of decay constants in geo- and cosmochronology: Earth and Planetary Science Letters, v. 36, p. 359-362. Vilson, E. D., Moore, R. T. , and Cooper, J, R., 1969, Geologic map of Arizona: U.S . Geological Survey Map, scale 1:500,000. DESCRIPTION OF MAP UNITS FOR MAIN MAP p Cenozoic to Paleozoic rocks, undivided Xs c Schist, undivided (Early Proterozoic)--Metavolcano- sedimentary terrane 1.71-1.79 b.y. old that includes Vishnu Schist in the Grand Canyon area, Yavapai Series in central Arizona, Pinal Schist in southeastern Arizona, and unnamed schistose units Xgn Gneiss, undivi ded (Early Pro t erozoic)--Principally orthogneiss wi th s ome ar eas of undiv ided schist and grani te Contact Fault--Dashed where approximately located EXPIANATION OF SAMPLE LOCALITY SYMBOLS ON MAIN MAP ANO INSET MAPS 39 SAMPLE LOCALITY- - Numbe rs ar e referred to in table 1 I Copper Gold Lead Silver ... Zinc C!) 4, 5 Cluster of sample locations 18 19 20 21 22 23 24 25 26 28 29 30 31 32 33 34 35 36 37 38 39 40 41 Boggs----------- Butternut------- Iron Queen------ Pentland-- ----- - Upshot---- --- --- Carbine - --- - ---- Hackberry------- Bell Ranch- - ---- Binghampton----- Copper Queen---- Stoddard-------- Blue Bell ----- -- De Soto -- ----- -- Unnamed prospect 2 mi SE of Clea tor, Unnamed prospect 4 mi NW of Black Canyon City. Unnamed prospect 2 mi NW of Black Canyon City. Kay---- - --- - ---- Orizaba--------- Gray-s Gulch--- - Bronco Creek---- Copper 'Camp Greek. Pittsburg-Tonto Ernie-s Tank- - -- Pranty-s Cabin-- 34°26;50"N 112°15-14"W 34°26-35"N 112°1roo"w 34 °26- 30"N ll2° 15-23"W 34°2s-2a"N 112°16-14"W 34°25-z2"N uz 0 l5-58"W 34°2s-04"N I L2°16-58"W J4°24-54"N 112°16-ZS"W 34°2s-01"N 1 12°1r11·•w to 34°2ro8"N 112°1r 14"W 34°2r19"N 112°tr36"W 34°2r22"N ll2°11-22"W 34°25-0S"N u2°10-5s"w 34°20-27".N l 12°14-29"W to 34°20-44"N ll2°14-23"W 34°1rll"N 112°1r21"w 34°15-35"N 112°u-36"W 34°or2o"N 112°10-4o"w 34°o4-12 11 N 112°1U;l2"W 34°0Y37"N L l 2°09-35"w 34°oo-J3"N 112°04- 50"W 33°S9-22"N 111°55-53"w 33°56-48"N 111° 5 J"44"W 33°5rs1"N 11 1 °34-oo"w 34°00-01"N 111°1r4I"w 34°0Y I 8"N 111°12-27"w 34°04-09".N lll 0 }0;05"W 1. 75 1.70(?) 1.70(?) 1. 70(?) -1. 70 -1. 70 Rhyolite crystal tuffs- - -- - --- ---- - ---do.------- - -- Cu, Zn, Au, Ag---- Fi ne - grained felsic tuffs and Prospect------------- Au, Ag, Cu, Zn---- tuf f aceous metasediments. Felsic tuffs and volcani- Prospect with in- Zn, Cu, Au, Ag---- clastic rocks, accessible under- ground workings. Fi ne-gralned f elsic tuffs and Prospect with in - Cu, Zn- ----------- tuffaceous metasediments. Ft ne-grained felsic tuf f s----- Fine-grained felsic tuff and tuffaceous metasediments. Fine-grained felsic tuff - -- --- Quartz-sericite and quartz- chlorite schists. Felsic tuffs and pyroclastic rocks. Exhal.l t e occurs at contact between rhyolite tuff and tuff breccia, and younger andesite tuffs. Silicified chlorite schist, chert, and schistose quartz porphyry. Fine- grained rhyolite tuffs and crystal tuffs. Coarse rhyolitic pyroclastics and tuffs. Fine-grained fels ic tuffs and quartz crystal tuffs. Quartz crystal t uf fs and felsic volcaniclastic rocks . Felsic tuffs---- ----- - ---- ---- Fine to coarse, felsic pyro - clas'"t ics, Calcareous mafic to inter- mediate tuffs intercalated with andesitic and rhyol i tic flow rocks. Felsic tuffs, wackes, and volcaniclastics intercalated with slates. accessible under- ground workings. Prospect------- · ----- Numerous prospect pits, Small, dormant und,,.rground mine. Prospect-------- ----- Do rmant underground mine. Pb, Zn, Cu, Au, Ag Cu---------------- Cu, Pb, Zn, Au, Ag Au------------ -- -- Cu, Au, Ag, Zn---- --------do.----- ----- Cu, Au, Ag, Zn- --- ---- - ---do,---------- Cu---------------- --------do,---------- Cu, Au, Ag - ------- ---- --- -do.--- --- ---- Cu, Au, Ag-------- Prospect---- - -- ------ Cu-- - ------ ------- --------du.- --------- Zn- - ---------- - --- - --- --- -do. --- --- - --- Dormant underground mine . Dormant underground mine and prospects. ND- --------------- Cu, Zn, Au, Ag---- Cu, Zn, Au, Ag---- Prospect pits-------- Cu, Zn------------ Fine-grained felsic tuffs and Prospect - ------------ Cu, Zn, Au, Pb, Ag felsic crystal tuffs. Felsic volcan ic breccia------- --------do , ------- -- - Cu--- ------------- Fine-grained felsic tuffs and --------do,- - ----- - -- Cu, Pb------------ crystal tuffs. Gray to purple phyllite interca l ated with felsic and mafic tu ft' s and vol- caniclastic rocks. Rhyo l itic lavas, explosive pyroclastics, and ash tuffs, - ------ -do,---------- Cu, Pb, Zn -- ------ --------do.------ ---- Cu, Zn------------ Is about 5,900 ft south of the Lone Pine deposit. Fram 1943 ta 1945, 98 tons of ore were shipped grading 1.07% Cu, 4.3% Zn, 0.45 opt Au, and 5.2 opt Ag. About 800 tons produced mainly from oxidized zone contained 6.4% Cu, 2,74 opt Ag, and 0 , 17 opt Au . Is about 2,000 ft S-SW of Boggs deposit. Siliceous ore reported tu contain 2-2.75% Cu, 0.025 opt Au, and 1.0 opt Ag. Occurs about 3,900 ft north of the Hackberry deposit. Is about l,500 ft E- SE of Pentland prospect . About 150 tons of ore produced. Occurs about 0.5 mi west of Hackberry depos i t. Between 1943 and 1945, 13,000 tons of ore were shipped grading 2.0% Cu, 3.5% Pb, 9. 0% Zn, 0,113 opt Au, and 5.18 opt Ag. Prospect occurs in distal part of stratigraphically asymmetrical rhyolite dome complex. About 175,000 tons of ore were pro- duced . Early-day production yielded average grade of 3.0% Gu, 0.0013 opt Au, and 0.22 opt Ag from 150,000 tons of ore. Production probably did not exceed 75,000 tons. Produced 14,000 tons of oxide ore grading 3.82% Cu. More than 1 million tons of ore were produced grading 3,0% Cu, 0,05 opt Au, and 1.5 opt Ag , from 1890 to 1930, approximately 180,000 tons of ore were produced grading 3, 75% Cu, 0.02 opt Au, and 1.0 opt Ag. No recorded production , Do. Do. Produced 2,271 tons of ore grading approximately 6,5% Cu, 0.062 opt Au, and 1.0 opt Ag. Approximately 40,000 tons of ore were shipped grading 4.0% Cu. No recorded production. 10,000 tons of pyritic ore grading 2,5% Cu and 0.16 opt Au .iere reportedly shipped for flux. No reported production. About 500 lbs of copper and 100 lbs of lead were produced. No reported production. Do. METALLOGENIC MAP OF VOLCANOGENIC MASSIVE-SULFIDE OCCURRENCES IN ARIZONA By MAR 2 6 2008 M.E. Donnelly' and C.M. Conway VOLCANOGENIC MASSIVE-SULFIDE MAP SERIES Edited by RL EARHART 1 Noranda Exploration, Inc. 1988 AUTON.VA 1 111 11111 1111,1 11111 1111~111 11111111 1m111 n111111 111111 i'1 1111 3 1818 00538970 3 Manuscript approved for publicatiori , J une 10, 1988 t.ny use of trade names 1n th is pull l1cauon 1s tor dsm1ptil'll purposes on~ and does not imply oodarssmem b'/ the U.S. Geological Survey I NTERIOR-GEOLOGICAL SURVEY, AESffiN, Vlfl>IN IA-1R8B For sa le by U. S. Geolog ical Survey Map D ist ~ buuon, Box 25286 , Federal Cemer, Den~sr, CO a022 5 mroo) -"YUi: I 8S-3 b c, /

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Page 1: ,,., f•. B - USGSproduced about 400,000 tons of ore that averaged 0.4% Cu, 2.72 opt Ag, and Q. 13 opt Au. Mined to a vertical depth of 2,600 ft, tl1e lron King producl'.d more thnn

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EDITOR'S NOTE

The metallogenic map of volcanogenic massive -sulfide occurrences in Arizona is one of several planned or published preliminary and interim products of a study of the distribution and setting of volcanogenic massive sulfides in the western United States. Volcanogenic massive-sulfide occurrences are inferred to be associated with the development of volcanic arcs or with rift systems in a mainly subaqueous environment . The massive - sulfide occurrences on this map were probably deposited in ancient island­arc environments. Most are considered to be proximal with respect to their emplacement near centers of volcanic activity. Some may have been deposited distal f rom volcanic centers.

The distribution of favorable host rocks for massive-sulfide deposits is also shown on the map. The host rocks are not necessarily formal stratigraphic units, and they may contain several lithologic types . They are shown here in order to delineate areas that may contain undiscovered massive-sulfide deposits.

Locality no.

2

3

4

Deposit name

Antler----------

Gppper World----

Copper King-----

Old Dick/Bruce--

Location

34°52"57"N 113°58-06"W

34°54-35"N 113°55-1s"w

34°34-11"N 113°1Y45"W

34°32"47"N 113°1Y52"W

MISCELLANEOUS FIELD STUDIES MAP MF-1853-B

VOLCANOGENIC MASSIVE-SULFIDE MAP SERIES

Table 1, --Proterozoic volcanogenic massive - sulfide occurrences in Arizona

l- , approxi mate; ND, not determined; opt, ounces per ton]

Age (b.y.} Host rock lithology

1,7-1.8 Quartzofeldspathic schist--

1. 7- 1.8 -----------do.-------------

Felsic volcaniclastic rocks intercalated with basalts,

Na t ur e of exposure

Dormant underground mine.

--------do ,--------

- - - --- --d O .--------

------- -do, --------

Commodities

Cu, Zn, Pb, Ag, Au

Cu, Zn, Ag, Au----

Zn, Pb, Gu, Ag, Au

Zn, Cu, Pb, Ag, Au

Remarks

Produced 78,000 tons of ore grading 37o Cu, 6.5% Zn, 0.75% Pb, l.l opt Ag, and 0,01 opt Au,

Pr oduced 61,000 tons of ore grading 3.55% Cu, l0.29% Zn, 0.66 opt Ag, and 0,0017 opt Au.

Produced about 23,000 tons of Cu-Pb-Zn ore.

L ~ ,: SUMMARY OF PROTEROZOIC VOLCANOGENIC

MASSIVE - SULFIDE OCCURRENCES IN ARIZONA

At contact between thick basaltic unit and younger rhyolitic racks,

Collectively, the Old Dick/Bruce ore bodies yi elded 1,499,421 tons of ore grading ll .8% Zn and 3.5% Cu. The ore contained from 0.32 to 0.35 opt Ag, and from 0 ,0014 to 0.0026 opt Au.

'

10

'3

de sb

'

' .

EXPLANATION

' '

Prescott-Jerome area insert

Phanerozoic rocks

ir I qd I ge I bg I

Volcanogenic massive-sulfide occurrences comprise a distinct 1,7-1,8-b.y.-old metallogenic province in Arizona. All of the 41 occurrences shown on this map are stratabound accumulations of iron and base-metal sulfides containing variable amounts of gold and silver . Lode deposits and occurrences of questionable origin have been omitted. A review of information on ·these deposits shows that they are widely distributed throughout the Early Proterozoic metavolcano - sedimentar y succession, but they share many similar ities (Donnelly and Hahn, 1981).

Regional geol ogic setting

The massive-sulfide occurrences are hosted in a thick succession of submarine volcanic and volcaniclastic rocks exposed intermittently from east -central Arizona to the northwestern part of the state. More than three-fourths of the deposits and prospects occur in 1,740-1,790-m.y.-old volcano- sedimentary strata of the Yavapai Series in western Arizona and the Prescott - Jerome area . This age range and other ages in this report are based on revised decay constants (Steiger and JAger, 1977) and are approximately 30 m. y. younger than previously published ages.

5 Copper Queen----

6 Rudkins---------

7 Ked Cloud-------

8 Pinafore----- - - -

9 Boston Arizona--

34°32-17"N 113°13-45"W

34°31-33"N 1 t.1°13-44"W

34°31-19"N 113°14-o5"W

34°29-27"N 113°16-39"W

34°31-24"N 112°36-46"W

Within rhyolitic tuffs and epiclastic rocks overlying an andesite unit.

Rhyolitic pyroclastic rocks -

Above a thin basaltic unit within rhyolitic pyroclastic rocks.

-1,75 At contact between thick basal tic unit and younger rhyolitic rocks.

1.74-1.79 Volcanic wackes, and felsic valcaniclastics and tuffs.

Exhausted and closed underground mine,

Prospect with shallow shaft.

Prospect with shaft and adit.

Zn, Gu------------

ND----------------

Zn, Cu, Au, Ag----

Prospect------------- Zn, Cu, Ag, Au----

Dormant underground Zn, Cu------------mine.

Produced 140,350 tons of ore averaging 4.7% Cu and 14.4% Zn , The ore con­tained about 0.38 opt Ag arid 0.0016 opt Au .

No reported production ,

Produced about 200 tons of ore with an average grade o f 6.4% Cu, 2,7% Zn, 0,69 opt Ag, and 0,075 opt Au.

Produced about 1,900 tons with an average grade of 3.2% Cu, 13% Zn, 1.04 opt Ag, and 0.014 opt Au.

Minor production.

Massive-sulfide prospects in the Tonto basin and the Ma~at~al 10 United Verde---- 34°45;02" to ~1.79 Quartz crystal tuffs, fine- Dormant underground Cu, Zn, Au, Ag---- World class d~pos it; produced total of Int.ruaive roc:ka Mountains (localities 38 , 39 • 40 • and 41) occur in metavolcano- (U.V.) 34°45;30"N grained fels l c tuffs, and mine and open pit. 30,672,846 tons of ore averaging

1r.1ntrus1ve rock• un<11v1dad O 4 77% C O 046 65 t<1.11u1ru <11ar1u sedimentary strata that are about 30-80 m.y. younger than the 112 ort9" to associated felsic volcani - • u, ' opt Au, and 1. opt a<1,Govern118nt canyon Ol"•no,:nortt• Yavapai Series (Silver, 1967 : Conway and others, 1981). Recent 112°or36"W elastic rocks, Ag; 10 million tons of Zn-rich ~;.Bredy Butte arenodlorlte fieldwork indicat es that this volcanic succession extends westward ma:ssive sulfide were left in ore

"-- '---",, -j-------------------c1==c1------------+.J.---------~,n~t~o~~t~,;,N~e;w~R~i~v~•~r~ M;,o~u~n~t~aci~n~,~san~.c;'t~•~Cca~v~,°";C~r~•~•~k~ a~r;,;a~. !a~n~ -.::t~a~t~~t:". _______________________________________________________________________ .J,,ocy.-------------------------tg may unconformably "over lie the Yavapa i Series (Conway and Silver, ",;::,',aa_,,....,~ 11 Haynes---------- 34°45-23" to ~1.79 Crystal tuffs and fine- Dormant underground Cu, Zn, Au, Ag---- Blind ore body at a depth of

" /oaa---'"'----}--------------~;rexea-Gulet1=oEor,111at-t on,---------'--+---------H184a--,-b9=.------Ma-ssiv e-;sul-fide- occurrences=at =loca-l-it-ie&=-3S-,- 36c,--and------aa;Ca.--a.c'---------- 404°5-·zs• ,,,.C'---.;.;-------'gr= a tnect=fel"s1.l!LU·ff•-c.------ Tne , ~ ,=S-OO=f-t-.;=d-e.velopetl=f0 r-0~=Unit-ed----------r-:-l 37 appear to be hosted by this younger volcanic sequence , but 112o0r 48,, to Verde workings. ~ stratigraphic relationships are uncertain (Conway, 1983). 112oor 53"W

,----="'\-------\'='i----l-~ -l-----------,,c,c,,..;i~a,:=;V~,aia,a,a, ,.,•,~--------+-------+--J.Alterna-t-1.-v.eJ..y .. .-J.nder.son-and--CuiLber.t-(.l-94-~-3ugges.t-that-t:he-Ca.vc~ --------------------c,------------------------------------------------------------------------------::, Creek-New River Mountains section is intermediate in age between 12 United Verde---- 34°45-04" to ~ 1. 79 Massive rhyolite, pyro­

clastics, and associated tuf f aceous sedlments with minor amounts of andesite lavas.

Dormant underground mine.

Cu, Au, Ag--- --- - - Blind ore body; produced J,878,825 tans of ore grading 10.23% Cu, 0.039 opt Au, and 1,71 opt Ag. '

'

'

-------

•1 0 r=-1 the Yavapai Series and the Tonto Baain-Hazatzal Mountains strata. Extension 34 45-1Q"N J ~ Two or more periods of folding are· recognized in the Yavapai (U.V.X.} 112°06;38" to

Spud Mountain Volcanics Series, whereas only one major deformational event is evident in 112°06-50''\,/ ~ m the younger volcanic strata. Throughout the metallogenic

~ province, metamorphic grad~ is primarily greenschist facies , with

Dacite of Burnt Canyon

contact

Green Gulch Volcanica

0 Grapevine Gulch Formetion

Deception Rhyolite

Brindle Pup Andesite

Buzzard Rhyolite

GJ Geddes Beeelt

1yncl1ne

0

Shea Basalt

u

amphibolite faciea developed locally. In most cases, primary textures permit identification and interpretation of protoliths.

Massive-sulfide deposits

Since the l ate 1800's, stratabound Cu-Zn-Pb sulfide deposits in Arizona have produced nearly 44 million tons of ore . Ten occurrences contained more than 100,000 tons of ore each, and three deposits yielded more than 4,000 , 000 tons each. The bulk of the production, however, was from the United Verde mine (locality 10), which produced more than 30 million tons of Cu-Au ore over a span of 68 years . Mine maps and cross sections of Anderson and Creasey (1958) suggest that the United Ver de orebody contained more than 80 million tons of pyritic massive and semi-massive sulfides and stockwork ore.

13

14

15

16

17

Verd~ Central---

Copper Chief- - --

Iron King----~-

Victor-Swindler and Huron­Montezuma

Lone Pine-------

34°44;23"N 112°0 r l 6"W

34°42"00".N 112°05-25"w

34°29-38''N u2°15-45"w to 34°30-20"N

u2°15-19"w

34°2r 12"N t12°15-38"W to

34°2a-25"N 112° 15- 32"W

34°2r57''N 112°14-57"1,i

~ 1. 75

Massive rhyolite and pyro­clas t ics.

Dormant underground mi.ne.

Cu----------------

Basalt flows and tuffs-------- --------do.---------- Cu, Au, Ag--------

Andesitic tuffaceous and - - ----- - do, - - -------- Gu, Pb, Zn, Au, Ag volcaniclastic rocks inter-calated with felsic tuff.

Quartz crystal tuffs and tuffaceous metasediments,

Rhyo l ite tuff, tuff breccia, and phyllitic metasediments.

Prospects------------ Cu, Ag, Au----- - --

Small, dormant Cu, Pb, Zn, Au, Ag underground mine,

Occurs 4,000 ft south of U.V. mine. The deposit has ore reserves of 12l,l24 t ons grad i ng 2.94% Cu.

Also known as Equator-Iron King mine; produced about 400,000 tons of ore that averaged 0.4% Cu, 2.72 opt Ag, and Q. 13 opt Au.

Mined to a vertical depth of 2,600 ft, tl1e lron King producl'.d more thnn 5,659,749 t ons of ore. More than 5 million tons contained an average grade of 2.50% Pb, 7 ,34% Zn, 0, 19% Cu, 0.123 opt Au, and 3.69 opt Ag.

No recorded production.

Generalized geologic map of the Prescott-Jerome area fault ant1cl1na

The massive-sulfide deposits have many features in common, including mineral assemblages, hydrothermal alteration, and structural complexity. Regionally, they are tightly clustered, with 25 of the 41 occurrences confined to three districts . Within a district , deposits can occur in nearly all facies of the mafic to felsic volcanic piles and at numerous stratigraphic levels. Most of the occurrences are assoc iated with fals i e volcanic rocks, but sever al, including the 1.5 -million-ton Old Dick/Bruce deposit (locality 4), were formed during t he waning stages of mafic volcanism and clearly preda te the overlying felsic eruptives.

The massive-sulfide deposits belong to the Cu-Zn group of volcanogenic deposits . onl y one deposit, the Iron King mine (locality 15) , contained appreciable amounts of lead. Published data on precious metal values are sparse, but by-product gold and silver were certainly economically important in many of the deposits. Sulfide assemblages are simple and consist primarily of pyrite, pyrrhotite, sphalerite, chalcopyrite , and galena. The sulfide ores exhibit primary mineralogical banding . and relict sedimentary textures can be found locally.

Incomplete records show that 2,763 tons of ore were shipped with average grade of 5,35% Gu, 0.20 opt Au, and 3.16 opt Ag,

{modified after Anderson and others, 1971)

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Chert and cherty sericitic tuffs occur along strike with or in close s tratigraphic association with most of the sulfide bodies. Oxide-fac ies iron formation and ferrug i nous chert are reported from 17 occurrences.

All of the major deposits exhibit hydrothermally altered footwall zones that reflect varying degrees of chlorltization, sericitization, and silicification. Alteration pipes are characterized by a chloritic core and a sericitic outer zone . Chlori t ic "stringer oreff or stockwork ore was economically important in several deposits, including the United Verde and the Old Dick/Bruce. Large semi conform.able zones of silicification, epidotization, and albitization lie stratigraphically beneath the a lterat i on pipe at the Old Dick/Bruce deposit (Conway and others, 1985) but have yet to be documented elsewhere.

The sulfide orebodies have high ratios of plunge length to strike length and were clearly deformed within the encasing volcanic strata. Many of the larger deposits are described as elliptical lenses or as rod-l i ke bodies that plunge steeply and are parallel to major or •inor f old axes . Ratios of plunge length to strike length are as much as 8:1 at the Blue Bell (locality 29), and stretching ratios of 3 : 1 are not uncommon elsewhere. Consequently , most deposits present small exploration targets at the surface.

REFERHNCES CITED

Anderson, C. A. , Blacet, P. M. , Silver, L. T. , and Stern, T. W., 1971, Revision of the Precambrian stratigr aphy in the Prescott-Jerome area, Yavapai County, Arizona: U.S. Geological Survey Bulletin 1324- C, p . Cl-Cl6.

Anderson, C. A., and Creasey, S, C., 1958, Geology and ore deposits of the Jerome area, Yavapai County, Arizona: U.S . Geological Survey Professional Paper 308, 185 p.

Anderson, P., and Guilbert , J . M., 1979, The Precambrian massive sulfides of Arizona --a distinct metallogenic epoch and province : Nevada Bureau of Hine s and Geology Report 33, p. 39-48.

Conway, c. M., 1983, Volcanogenic mineralization at Copper Cemp Creek and the potential for massive sulfide deposits in the Proterozoic Alder format i on, Ari zona [abs.]: Geological Society of Amer ica Abstracts with Programs, v, 15, no, S, p. 298 .

Conway, C. H. , Connelly , T. J. , and Robison, L. C., 1985, Volcanic and hydrothermal systems; Early Proterozoic massive sulfide deposits, Bagdad , Arizona [abs] : U.S . Geological Survey Circular 949 , p. 8-9.

Conway. C. M., and Silver, L. T., 1984a , Extent and implications of silic i c alkalic magmatism and quartz arenite sedimentation in the Proterozoic of central Arizona: Geological Society of America Abstracts with Programs, v. 16,

Conway , C. M,, and Silver, L, T. , 1984b, From island arc to craton ; two major orogenic cycles in the Early Proterozoic of Arizona [abs.): Symposium on Southwestern geology and paleontology; Museum of Northern Arizona, Flagstaff , Arizona .

Conway , C. M., Silver. L. T. , Vrucke, C. T., and Ludwig, K. R., 1981, Proterozoic Mazatzal quartzite of central Arizona: Geologi cal Society of America Abstracts with Programs, v. 13, no. 2, p. SO .

Donnelly, H. E., and Hahn, G. A. , 1981, A review of the Precambrian volcanogenic massive aulfide deposits in central Arizona and the relationship to their depositional environment: Arizona Geological Society Digest, v, 14, p . 11-21.

Si lver , L, T .• 1967, Apparent age r e lat iona in the older Precambrian stratigraphy of Arizona [abs.]. J.n Burwash, R. A. , and Horton , R. D. , eds., Geochronology of Precambrian stratified rocks: Edmonton , University of Alberta, p. 87 .

Steiger, R. H., and JAger, E. , 1977, Subcommission on geochronology , convent ion on the use of decay constants in geo- and cosmochronology: Earth and Planetary Science Letters, v. 36, p. 359-362.

Vilson, E. D., Moore, R. T. , and Cooper, J, R., 1969, Geologic map of Arizona: U.S . Geological Survey Map, scale 1:500,000.

DESCRIPTION OF MAP UNITS FOR MAIN MAP

p Cenozoic to Paleozoic rocks, undivided

Xsc Schist, undivided (Early Proterozoic)--Metavolcano­sedimentary terrane 1.71-1.79 b.y. old that includes Vishnu Schist in the Grand Canyon area, Yavapai Series in central Arizona, Pinal Schist in southeastern Arizona, and unnamed schistose units

Xgn Gneiss, undivi ded (Early Prot erozoic)--Principally orthogneiss wi th s ome a r eas of undiv ided schist and granit e

Contact

Fault--Dashed where approximately located

EXPIANATION OF SAMPLE LOCALITY SYMBOLS ON MAIN MAP ANO INSET MAPS

• 39 SAMPLE LOCALITY- -Numbers ar e referred to in table 1

• I

Copper

Gold

Lead

Silver

... Zinc

C!) 4, 5 Cluster of sample locations

18

19

20

21

22

23

24

25

26

28

29

30

31

32

33

34

35

36

37

38

39

40

41

Boggs-----------

Butternut-------

Iron Queen------

Pentland--------

Upshot----- - - ---

Carbine- ---- ----

Hackberry-------

Bell Ranch- - ----

Binghampton-----

Copper Queen----

Stoddard--------

Blue Bell- - - - - --

De Soto- - -------

Unnamed prospect 2 mi SE of Clea tor,

Unnamed prospect 4 mi NW of Black Canyon City.

Unnamed prospect 2 mi NW of Black Canyon City.

Kay----- ---- --- -

Orizaba---------

Gray-s Gulch----

Bronco Creek----

Copper 'Camp Greek.

Pittsburg-Tonto

Ernie-s Tank-- --

Pranty-s Cabin- -

34°26;50"N 112°15-14"W

34°26-35"N 112°1roo"w

34 °26- 30"N ll2° 15-23"W

34°2s-2a"N 112°16-14"W

34°25-z2"N uz0 l5-58"W

34°2s-04"N I L2°16-58"W

J4°24-54"N 112°16-ZS"W

34°2s-01"N 112°1r11·•w to 34°2ro8"N

112°1r 14"W

34°2r19"N 112°tr36"W

34°2r22"N ll2°11-22"W

34°25-0S"N u2°10-5s"w

34°20-27".N l 12°14-29"W to

34°20-44"N ll2°14-23"W

34°1rll"N 112°1r21"w

34°15-35"N 112°u-36"W

34°or2o"N 112°10-4o"w

34°o4-1211 N 112°1U;l2"W

34°0Y37"N L l 2°09-35"w

34°oo-J3"N 112°04- 50"W

33°S9-22"N 111°55-53"w

33°56-48"N 111°5 J"44"W

33°5rs1"N 11 1°34-oo"w

34°00-01"N 111°1r4I"w

34°0Y I 8"N 111°12-27"w

34°04-09".N lll 0 }0;05"W

~ 1. 75

1.70(?)

1.70(?)

1. 70(?)

-1. 70

-1. 70

Rhyolite crystal tuffs-- --- --- ----- ---do.-------- -- Cu, Zn, Au, Ag----

Fi ne - grained felsic tuffs and Prospect------------- Au, Ag, Cu, Zn---­tuf f aceous metasediments.

Felsic tuffs and volcani- Prospect with in- Zn, Cu, Au, Ag----clastic rocks, accessible under­

ground workings.

Fi ne-gralned felsic tuffs and Prospect with in- Cu, Zn------------tuffaceous metasediments.

Ft ne-grained felsic tuf f s-----

Fine-grained felsic tuff and tuffaceous metasediments.

Fine-grained felsic tuff- --- - -

Quartz-sericite and quartz­chlorite schists.

Felsic tuffs and pyroclastic rocks.

Exhal.l t e occurs at contact between rhyolite tuff and tuff breccia, and younger andesite tuffs.

Silicified chlorite schist, chert, and schistose quartz porphyry.

Fine- grained rhyolite tuffs and crystal tuffs.

Coarse rhyolitic pyroclastics and tuffs.

Fine-grained fels i c tuffs and quartz crystal tuffs.

Quartz crystal t uf f s and felsic volcaniclastic rocks .

Felsic tuffs---------- ---- --- -

Fine to coarse, felsic pyro­clas'"t ics,

Calcareous mafic to inter­mediate tuffs intercalated with andesitic and rhyol i tic flow rocks.

Felsic tuffs, wackes, and volcaniclastics intercalated with slates.

accessible under­ground workings.

Prospect-------·-----

Numerous prospect pits,

Small, dormant und,,.rground mine.

Prospect--------- - - - -

Do r mant underground mine.

Pb, Zn, Cu, Au, Ag

Cu----------------

Cu, Pb, Zn, Au, Ag

Au----------------

Cu, Au, Ag, Zn----

--------do.--- - - ----- Cu, Au, Ag, Zn----

----- ---do,---------- Cu----------------

--------do,---------- Cu, Au, Ag- -------

------- -do.---------- Cu, Au, Ag--------

Prospect----- -------- Cu-- - -------------

--------du.---------- Zn-- ----------- ---

- --- ----do. ------- ---

Dormant underground mine .

Dormant underground mine and prospects.

ND----------------

Cu, Zn, Au, Ag----

Cu, Zn, Au, Ag----

Prospect pits-------- Cu, Zn------------

Fine-grained felsic tuffs and Prospect- ------------ Cu, Zn, Au, Pb, Ag felsic crystal tuffs.

Felsic volcani c breccia------- --------do ,---------- Cu----------------

Fine-grained felsic tuffs and --------do,-- ------ -- Cu, Pb-----------­crystal tuffs.

Gray to purple phyllite intercal ated with felsic and mafic tu ft' s and vol­caniclastic rocks.

Rhyol itic lavas, explosive pyroclastics, and ash tuffs,

- ------ -do,---------- Cu, Pb, Zn- - ------

--------do.----- - ---- Cu, Zn------------

Is about 5,900 ft south of the Lone Pine deposit. Fram 1943 ta 1945, 98 tons of ore were shipped grading 1.07% Cu, 4.3% Zn, 0.45 opt Au, and 5.2 opt Ag.

About 800 tons produced mainly from oxidized zone contained 6.4% Cu, 2,74 opt Ag, and 0 , 17 opt Au .

Is about 2,000 ft S-SW of Boggs deposit. Siliceous o r e reported tu contain 2-2.75% Cu, 0.025 opt Au, and 1.0 opt Ag.

Occurs about 3,900 f t north of the Hackberry deposit.

Is about l,500 ft E- SE of Pentland prospect . About 150 tons of ore produced.

Occurs about 0.5 mi west of Hackberry depos i t.

Between 1943 and 1945, 13,000 tons of ore were shipped grading 2.0% Cu, 3.5% Pb, 9 . 0% Zn, 0,113 opt Au, and 5.18 opt Ag.

Prospect occurs in distal part of stratigraphically asymmetrical rhyolite dome complex.

About 175,000 tons of ore were pro­duced . Early-day production yielded average grade of 3.0% Gu, 0.0013 opt Au, and 0.22 opt Ag from 150,000 tons of ore.

Production probably did not exceed 75,000 tons.

Produced 14,000 tons of oxide ore grading 3.82% Cu.

More than 1 million tons of ore were produced grading 3,0% Cu, 0,05 opt Au, and 1. 5 opt Ag ,

from 1890 to 1930, approximately 180,000 tons of ore were produced grading 3 , 75% Cu, 0.02 opt Au, and 1.0 opt Ag.

No recorded production ,

Do.

Do.

Produced 2,271 tons of ore grading approximately 6,5% Cu, 0.062 opt Au, and 1.0 opt Ag.

Approximately 40,000 tons of ore were shipped grading 4.0% Cu.

No recorded production.

10,000 tons of pyritic ore grading 2,5% Cu and 0.16 opt Au .iere reportedly shipped for flux.

No reported production.

About 500 lbs of copper and 100 lbs of lead were produced.

No reported production.

Do.

METALLOGENIC MAP OF VOLCANOGENIC MASSIVE-SULFIDE OCCURRENCES IN ARIZONA By

MAR 2 6 2008

M.E. Donnelly' and C.M. Conway

VOLCANOGENIC MASSIVE-SULFIDE MAP SERIES Edited by RL EARHART

1Noranda Exploration, Inc.

1988

AUTON.VA

1

111111111111,1111111111~111111111111m111n111111111111i'11111 3 1818 00538970 3

Manuscript approved for publicatiori , J une 10, 1988

t.ny use of trade names 1n th is pulll1cauon 1s tor dsm1ptil'll purposes on~ and does not imply oodarssmem b'/ the U.S. Geological Survey

INTERIOR-GEOLOGICAL SURVEY, AESffiN, Vlfl>IN IA-1R8B

For sa le by U. S. Geolog ical Survey Map Dist~buuon, Box 25286, Federal Cemer, Den~sr, CO a0225 mroo)

-"YUi: I 8S-3b c, /