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NBS Publl - cations NArL INST. OF STAND & TECH NBS SPECIAL PUBLICATION 478 U.S. DEPARTMENT OF COMMERCE / National Bureau of Standards NITROGEN OXYCHLORIDES: A Bibliography on Data for Physical and Chemical Properties of CUNO, CLNO2, and CdNOs

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NBSPubll -

cationsNArL INST. OF STAND & TECH

NBS SPECIAL PUBLICATION 478

U.S. DEPARTMENT OF COMMERCE / National Bureau of Standards

NITROGEN OXYCHLORIDES:

A Bibliography on Data for

Physical and Chemical Properties

of CUNO, CLNO2, and CdNOs

NATIONAL BUREAU OF STANDARDS

The National Bureau of Standards^ was established by an act of Congress March 3, 1901. The Bureau's overall goal is to'

strengthen and advance the Nation's science and technology and facilitate their effective application for public benefit. To this

end, the Bureau conducts research and provides: (1) a basis for the Nation's physical measurement system, (2) scientific andtechnological services for industry and government, (3) a technical basis for equity in trade, and (4) technical services to pro-

mote public safety. The Bureau consists of the Institute for Basic Standards, the Institute for Materials Research, the Institute!

for Applied Technology, the Institute for Computer Sciences and Technology, the Office for Information Programs, and the

Office of Experimental Technology Incentives Program.

THE INSTITUTE FOR BASIC STANDARDS provides the central basis within the United States of a complete and consist-

ent system of physical measurement; coordinates that system with measurement systems of other nations; and furnishes essen-'

tial services leading to accurate and uniform physical measurements throughout the Nation's scientific community, industry,!

and commerce. The Institute consists of the Office of Measurement Services, and the following center and divisions:

Applied Mathematics — Electricity — Mechanics — Heat — Optical Physics — Center for Radiation Research — Lab-

oratory Astrophysics^ — Cryogenics'' — Electromagnetics^ — Time and Frequency".

THE INSTITUTE FOR MATERIALS RESEARCH conducts materials research leading to improved methods of measure-

ment, standards, and data on the properties of well-characterized materials needed by industry, commerce, educational insti-

tutions, and Government; provides advisory and research services to other Government agencies; and develops, produces, and

distributes standard reference materials. The Institute consists of the Office of Standard Reference Materials, the Office of Air

and Water Measurement, and the following divisions:

Analytical Chemistry — Polymers — Metallurgy — Inorganic Materials — Reactor Radiation — Physical Chemlstry.l

THE INSTITUTE FOR APPLIED TECHNOLOGY provides technical services developing and promoting the use of avJ^able technology; cooperates with public and private organizations in developing technological standards, codes, and test meth-|

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designed to aid Government agencies in improving cost effectiveness in the conduct of their programs through the selection,

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utive branch for the development of Federal standards for automatic data processing equipment, techniques, and computer!

languages. The Institute consist of the following divisions:

Computer Services — Systems and Software — Computer Systems Engineering — Information Technology.

THE OFFICE OF EXPERIMENTAL TECHNOLOGY INCENTIVES PROGRAM seeks to affect public policy and processi

to facilitate technological change in the private sector by examining and experimenting with Government policies and prac-

tices in order to identify and remove Government-related barriers and to correct inherent market imperfections that impede

the innovation process.

THE OFFICE FOR INFORMATION PROGRAMS promotes optimum dissemination and accessibility of scientific informa-

tion generated within NBS; promotes the development of the National Standard Reference Data System and a system of in- i

formation analysis centers dealing with the broader aspects of the National Measurement System; provides appropriate services

to ensure that the NBS staff has optimum accessibility to the scientific information of the world. The Office consists of thejl

following organizational units:

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Office of International Standards — Office of International Relations.

' Headquarters and Laboratories at Gaithersburg, Maryland, unless otherwise noted; mailing address Washington, D.C. 20234.

' Located at Boulder, Colorado 80302.

AUG 2 4 1977

NITROGEN OXYCHLORIDES:I DO

A Bibliography on Data for Physical and

Chemical Properties of CUNO, CtN02, and CtNOa /f rr

t

Francis Westley

Institute for Materials Research

National Bureau of Standards

Washington, D.C. 20234

Sponsored by:

Office of Standard Reference DataNational Bureau of StandardsWashington, D.C. 20234

Office of Air and Water MeasurementNational Bureau of StandardsWashington, D.C. 20234

Department of TransportationFederal Aviation AdministrationWashington, D.C. 20591

National Aeronautics and Space AdministrationWashington, D.C. 20546

U.S. DEPARTMENT OF COMMERCE, Juanita M. Kreps, Secretary

Dr. Sidney Harman, Under Secretary

Jordan J. Baruch, Assistant Secretary for Science and Technology

3 NATIONAL BUREAU OF STANDARDS, Ernest Ambler, Acting DirectorI'

Issued August 1977

Library of Congress Cataloging in Publication Data

Westley, Francis.

Nitrogen oxychlorides.

(NBS special publication ; 478)

Supt. of Docs, no.: €13.10:478.

1. Nitrogen oxychlorides—Bibliography.

I. United States. National Bureau of Standards. Office of Standard

Reference Data. II. Title. III. Series: United States. National Bureau

of Standards. Special publication ; 478.

QC100.U57 no. 478 [Z5524.N55] [QD181.C5] 77-2757

602Ms [546'.732'2]

National Bureau of Standards Special Publication 478

Nat. Bur. Stand. (U.S.), Spec. Publ. 478, 54 pages (Aug. 1977)

CODEN: XNBSAV

U.S. GOVERNMENT PRINTING OFFICEWASHINGTON: 1977

For sale by the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402

Price $2 Stock No. 003-003-01824-4

TABLE 6F C6NTENTS

I nt r o duction. 1

Guideline;.': for the User. 2

List of Abbreviations. .......................... ^

Nitrosyl Chlorine - ClNe 6

Chemistry and Chemical Kinetics ................... 6

Molecular Properties. ........................ HPhysical Properties ......................... 12

Spectral Properties ......................... 13

Ther tnodynam ic Properties. ...................... 15

Nitryl Chloride - C1N6, 16

Chemistry and Chemical Kinetics ................... 16

Molecular Properties. ........................ 18

Physical Properties ......................... 19

Spectral Properties ......................... 19

Thermodynamic Properties. ...................... 20

Chlorine Nitrate - ClNe^ 21

Chemistry and Chemical Kinetics ................... 21

Molecular Properties. ......... 22

Physical Properties .......... 22

Spectral Properties ......................... 22

Thermodynamic Properties. ...................... 23

References ................................ 24

List of Abbreviations. .......................... ^1

iii

NITS6GEN eXYCHLOfilDES

[a Bibliography on Data for Physical and ChemicalProperties of ClNO, CINA-. and CINC,]

FRANCIS WESTLEY

A data oriented list of references is provided for publishedpapers and reports containing measured or calculated data for thephysical and chemical properties of nitrosyl chloride, nitrylchloride, and chlorine nitrate with particular emphasis onthe chemistry and chemical kinetics of these compounds. Morethan 387 papers are listed. The period covered extends from1874 through 1977,

Kej^ords: Bibliography; chemical kinetics; chemistry; chlorinenitrate; molecular properties; nitrosyl chloride; nitryl chloride;physical properties; spectral properties; thermodynamic properties.

INTRelDUCTIQN

This bibliography lists papers and reports containing data for the chemical^molecular; physical; spectralj and thermodynamic properties of nitrosyl chloride,ClNfl ; nitryl chloride, ClNCg; and chlorine nitrate, ClNfl^, with particular emphasison the chemical kinetics of these compounds. Amon§<: these, nitryl chloride has beenrecently found to exist in two isomeric forms by Molina who in 1977 identifiedby UV spectrometry the existence of nitryl chloride, ClNOg, and--at lower temperatui--of its isomer, C16-N0, The later one was named by Molina: "chlorine nitrite"(by analogy with chlorine nitrate, whose structural formula is: CIQ-NS^and which as also been referred to as: nitryl oxychloride ),

The articles have been selected from the files of the Chemical KineticsInformation Center and the Chemical Abstracts ( 1874-1977),

The references are arranged in chronological rather than alphabeticalorder, as described in detail in the "guidelines for the user", following thei nt roduc t ion ,

The particular properties for which data are published are indicated byflags. The abbreviations for data flagging are based on the Fourth InterimlUPAC List ( C0DATA Bulletin 1£, 20 (1976)), The list of lUPAC flags iscompleted by a short number of abbreviations for descriptive terms (e.g. :

calculation, decomposition, etc. ), These descriptive abbreviations applymostly to Chemical Kinetics,

CIN0, CIN62, and CINQ.^ are potentially important in oollution and atmosphericchemistry. In particular, the chlorine nitrate formation in atmosphere seemsto produce a decrease in the projected ozone reduction. For that reason,the physical and chemical properties of ClN'ij have been the object of a numberof recent studies.

It is believed that this bibliography provides extensive coverage ofthe available data for the physical and chemical properties of CINI, ClN'ig* andCIN©^. The more than 387 references indexed here span all physical and chemicalproperties of CIN0, CIN02, and ClNQ^* No claim is made that this bibliographyis all-inclusive, 6ur past experience in the preparation of bibliographieshas taught us that it is virtually impossible to identify and obtain every paperor to flag correctly every paper that has been retrieved. The author willwelcome suggestions for additions and corrections or errors and thanks thecontributors in advance.

This bibliography is not the result of the effort of a single person,but of the whole staff of Chemical Kinetics Information Center, My thanks toall of them.

In particular, I wish to thank Dr. David Garvin, Section Chief and Dr. RobertHampson, Jr., Director of the Center, for their more than helpful suggestions andconstant guidance; Dr. William H, Evans for his thorough editing and proofreadingof the manuscript; Mr, James Koch, Supervisor, for tracking down and obtainingpapers and reports, otherwise very difficult to obtain; Mrs. Geraldlne Zumwaltand Miss Sheri Schroyer, for typing a difficult manuscript with particular care.

GUIDELINES FAR THE USE R

Arrangement of the Report

This b ibt iography is in four parts:

Part I. Nitrosyl Chloride - CINQ

Part II. Nitryl Chloride - ClNe2

Part III. Chlorine Nitrate - ClNa^

Part IV. The combined bibliographies for Parts I to III arranged chronologicallyby years and - within each year - alphabetically by authors. The completereference for each article mentioned is given here; occasionallyexplanatory notes are appended. These establish the "bibliographic chain"for closely related papers by the same authors.

Each of the Parts I to III is subdivided into five parts:

Chemistry and Chemical KineticsMolecular PropertiesPhysical PropertiesSpectral PropertiesThermodynamic Properties

Each entry in parts I to III consists of an identification of the paper orreport and a set of abbreviations that specify the types of data reported therein.These two features are explained below.

R eference Code s

Each paper or report Included in Parts I to III is indicated by areference code formed by a string of characters showing:

1 . ) Year ( last two digits )

2, ) Author or first two authors, using the first threeletters of each last name (patronymic ). When two names are present they areseparated by a slash.

3. ) If necessary a digit is added to distinguish amongpapers that would have the same codes according to rules (1 ) and (2),

Examples

:

40 ASM41 ATW/R0L53 ASH/CHAl53 ASH/CHA2

The total length of the string, including the digit, may be no longerthan 11 characters. A code without digit has, implicitly, the digit 1

associated with it.The code is essentially that used by Auer and Kienitz, " Landolt -Bornstei

n

Zahlenwerte and Funktlonen", Sechste Auflage II Band, 4. Tell "KalorischeZus t ands erossen" , pp. 569-687, (1961 ), for their tables of thermochemical data.

P roperties Codes

Following the year and author code, at five spaces distance, are the abbreviationsfor data flagging. These flags are taken from the Fourth Interim lUPAC List* andtheir use is an expe r Imen t- - te st i ng the usefulness and completeness of the techniqueon a body of related data--and an attempt to achieve a substantial compression ofinformation.

Although the lUPAC List Includes 113 flags, this bibliography usesonly 33 of them as listed below. The 80 flags not included indicateproperties which have not yet been investigated for ClNfl, CIN^^, and .

ClNf*^. Theflags for spectra are indicated by three capital initials, all other onlyby two initials.

Under the subheading "molecular properties" the year and author codes arefollowed by flags indicating only molecular properties. The same rule appliesfor the remaining four subheadings. The lUPAC List of Flags is supplementedby 11 codes for descriptive terms fe.g.: Clc - calculation; For from:formation from; Rev - Review; e tc . j . These descriptive codes Includethree letters the first being a capital. Only two descriptive codes have 7

2

cbaract ers. These are:

For from: Formation fromRxn with: Reaction with (other compounds)

The code "Rip" means Related Paper and indicates that a paper does notreport rate data, or Quantum yields, or mechanisms, but may describe thessmthesis of compound.

The flags for data appear first in alphabetical order, followed bythe descriptive terms.

Examples

:

CIN0

Chemistry and Chemical Kinetics

61 ASH/BUR KR, Dec, Mec , Rxn with: CI, N6 , N6,

which indicates that the paper by Ashmore and Burnett ( 1961 ) reportsreaction rate data on the CINQ decomposition, a mechanism of the reaction andsome information on the reaction of CIN6 with Chlorine atoms, N0 and .

ClNe

Spectral Properties

74 BAL/ARM UVS, VIS

which indicates that the paper by Ballash and Armstrong ( 1^74 ) reportsstudies on the ClNf* ultraviolet and visible spectra.

To find the complete references for the above examples (61 ASM/BUR and74 BAL/ARM ) the reader should look in Part IV under the subheadings 196 1 and1974, where the papers by Ashmore and Burnett ( 1961 ) and Ballash andArmstrong (1974) are listed alphabetically within the same year.

For easy location, each reference listed in Part IV is preceded bythe year and author code.

The Properties Codes (including the lUPAC list for Data Flagging Abbreviationsand- -separately- -the list for Descriptive Terms) follow below. For the convenienceof the reader, these two lists are repeated in the last page of this bibliography,after the References,

»The complete lUPAC list is published in: CADATA {Committee on the Data forScience and Technology) Bulletin No . 19 . "Flagging and Tagging Data,P, 20 ff. (June 1976. Paris, France )

3

LIST «F ABBKEVIATieNS

Abbreviations for Datra Flaig^gingFourth Interim lUPAC List

AB Absorption Cross Section

BE Bond Energy, Atomization Energy, Dissociation Energy

B6 Bond Angle, Bond Length

BT Boiling Temperature (Boiling Point)

CD Critical State Data (Critical Density, Critical Temperature,Critical Pressure)

DC Dielectric Constant

DM Dielectric Properties (Electric Dipole Moment, MolecularPolarization Quadrupole Coupling Constant)

DN Density Data (Density, Specific Density)

EN Entropy

EQ Equilibrium Data (Equilibrium Constant)

ET Enthalpy (Heat of Vaporization, Heat of Sublimation,Heat of Reaction)

HO Heat Capacity

IP Ionization Potential, Electron Affinity

IRS Infrared Spectrum

MG Magnetic Data, (Magnetic Dipole (and Higher) Moments,Magnetic Susceptibility)

ML Molecular Energy Level, Rotational and VibrationalConstants, Force Constant, Moment of Inertia

MSS Mass Spectrum

MT Melting Temperature (Melting Point)

MWS Microwave Spectrum

KMS Nuclear Magnetic Resonance Spectrum

QY Quantum Yield (and Quantum Efficiency)

RAS Raman Spectrum

RD Radii (Atomic, Ionic, Molecular, Molecular Volume,Molecular Diameter, Molecular Cross Section)

RR Reaction Rate Data (Sate Constant, Relaxation Time,Half- life )

ST Surface Tension

TO Thermal Conductivity

TE Thermodynamic Energy Data ( Gibbs Free Energy,Helmholtz Energy, Thermodynamic energy functions)

UVS Ultraviolet Spectrum

VIS Visible Spectrum

VP Vapor Pressure (Sublimation Pressure)

VS Viscosity Data

XPS X-ray Photoe lec tron Spectrum

XRS X-ray Spectrum

4

Descriptive Terms

Clc Calculation

Dec Decomposition

For from: Formation from another compound

Mec Mechanism

Phi Photolysis

Raot Radiation

Rev Review

Rip Related Paper

Rxn with: Reaction with other compounds

Syn Synthesis (preparative methods)

Thp Theoretical Paper

5

PART I

NITR0SYL CHL6RIDECtN6

Chemistry and Chemical Kinetics

TIL Ftp, Rxn with: Au and Pt, Syn

9 1 SUD Rip, Rxn wi th : me tal

s

1 2 BRI/PYI Rip, Syn

1 4 TRA RR, For from: N6 and Clg

1 5 TRA/HIN Dec , For from: N0 and CI2, Rlp

1 6 BR I For f rom : HNCg and HCl, Mec, Rip, Rxn with:

1 6 TRA/HIN Dec , For from: NC and Clj, Rlp

1 6 TO A/W A C Dec , For Ju t \J lU 1^ \y OilU ^ 1- ip

23 CUT/TAR Rip, Rxn with: Cua and TljQ, Syn

23 KIS RR, Dec , For from: N6 and Clj, Mec, Phi

24 K IS RR, For from: CIN02 and N0, Mec

24 TRA/GER Rip, Syn

24 TRA/SCH KR, For from: N6 and Clg. Mec

25 BeW/SHA QY, Phi

26 LYN/SHO Rip, Rxn with: Inorg. and 6rg. Chem.

2 "7 GAL/MEN Rip, Rxn with: MCln (M - metal, n - 1 to 5 ),

27 T AY/DEN RR, Dec

2 8 N9Y For f rom : NCl^, Rlp, Rxn with: NCl^

2 9 SCF/ SPRl Rip, Rxn with : 9-J

25 SCH/ SPR3 Rip, Rxn wi th : 6^

30 KIS QY, Dec , Mec, Phi, Rxn with: CI

30 NeY For f rom : NCI3 and Nl, Mec

31 WHY/LUN Rip, Rxn with: NaGH, Syn

74 TRA/FRE Dec , Rip

35 WAD/Tf»L RR, Dec

37 KRA/SAR RR, F or from: Nfl and Clg

38 SCH KR, Dec, For from: N0 and CX^t ^^"^

38 WEL/TAY RR, Dec , For from: N0 and Clg

35 CaL/LIL Rip, Syn

39 ceei/KRA Rip, Dec

35 NAT QY, RR, Mec, Phi

6

4 0 ASM

40 NAT

4 1 ATW/R6L

47 SCH

4 8 MCG

4 8 PAE/WHY

4 8 saL

49 ADD/THei

49 DR«/GAL

4 9 PAR/WHYl

5 0 0OG/WIL

51 BEC/FES

5 2 BUR/MCK

52 BUR/DAI2

5 2 CHA/ASH

52 FRE/JflH

53 ASH/CHAl

5 3 ASH/CHA2

5 3 ASH/CHA3

53 J6H/LEI

54 PRE

54 LEI

55 EPS/NIK

55 MAR/K0H

55 RAY

56 PIT/P0W

5 7 ASH/LEV

5 7 RAY/0GG

57 SCH/FIN

5 8 ART/STR

5 8 C0L/GIN

58 GIN/G0D

5 8 MAR

5 8 MAR/KflH

59 DUH/BAU

Rip, Rxn with: MCl^ (M - metal, n " 1 to 5 )

ER, Cle, Dec, Thp

QY, Phi

Rip, Rxn with: 0^

Dec, Rev, Rxn with: HgO, 0, S and 0rg, Conp. , Syn

Rip, Rxn with: M and MCl^ (M " metal, n - 1 to 5 )

Dec, Rev, Rxn with: Inorg. and 0rg. Comp., Syn

Rip, Rxn with: ¥1^6^, CCl^, metals

RR, for from: HNO^, Rxn with: 03

Rip, Rxn with: M, MCI 3 and M( N©^ )^ (M - metal, n - 1 to 4)

Dec, For from: CIN02, Etp, Rxn with: 0^ and 6^

QY, RR, Dec, Phi, Rev, Rxn with: Inorg. and 0rg. Comp., Syn

Rip, Rxn with: FeCl^

RR, Rxn with: CI, C0CI

RR, Dec

RR, For from: CIN02 and N0

RR, Dec, For from: Cl^. Mec , Rxn with: Cl , M

RR, Dec, Mec, Rxn with: Cl

RR, Clc, For from: Clg

RR, Mec, Rxn with: 0^ and

For from: CX^ and N0, Mec, Thp

RR, Mec, Rxn with: 0^ and NO^

RR For from: HN0,

RR, Rxn with: C102

RR, Mec, Rxn with: N0,

BR, Clc, Dec, For from: ClNflg N0 and Clg,Rxn with: Cl, Thp

Dec, Rip

RR, Mec, Rxn with: N02

Rip, Rxn with: CIN©^

For from: N0, Phi, Rxn with: CgHg, Cl

For from: CIN02 and H^© or HCl, Hip

RR, For from: CIN02, H20, HNOg , Rxn with: Mesitylene)

For from: CX^0 and N0, Rxn with: ^2^5

RR, Mec, Rxn with: C102, 0CI, N02, N©^

RR, Dec, For from: Clg, Phi, Rxn with: Cl

7

59 MAR/SPE SR. Dec, For from: Clg. Mec, Rxn with: CI

59 NFU QY, Phi

59 TAL/THe RH, For from: HCl and Nflg. Mec

60 FIN/LEE OY, For 1 rem : CI and Ne, Phi, Rxn with: AlCl-

60 GE0 Rip, Rev, Rxn with: Tnorg. Salts, Syn

60 MAR/W6H RR, Dec, Mec, Phi, Rxn with: CI

60 MCK/FIN Qy, For from: N0 and Clg, Phi

61 ASH/BUR RR, Dec, Mec, Rxn with: CI, NQg

61 BAS/NGR Phi

61 CAS/P0L PR, Rxn with: H

61 DEK RR, Dec, Mec, Rxn with: CI

61 MAR/wem QY, RR, Dec, For from: N0 and Clg. Mec, Rev,Rxn with: Cl

61 MAR/W0H2 QY, RR, Dec, For from: N0 and Clg, Phi

61 RIC RR, Mec, Hxn with: NgCg

61 WAR Rip, Rxn with: Hg

62 ASH/BUR RR, Dec, Mec

62 BAS Mec, Phi, Rxn with: Cl, N0

6 2 BAS/NflH Mec, Phi

62 CHA/KHA Rxn with: H

62 DEK/PAL RR, Dec, Mec, Rxn with: Cl

62 MAR/CHU QY, Phi

63 MER Rip, For from: N0 and Clg, Phi

63 WEI Rip, Rxn with:

63 W0L/ECK Rip, Rxn with;

64 ASH/HER BR, Dec

64 WAY QY, Phi

65 ASH/WES RR, Dec, Mec, Rxn with: Cl, H

65 VAN/HEU Rlp, Rxn with: SQ^

65 ZEV RR, Rxn with: 65 and Nfl^

66 CLY/STE RR, Rxn with: H

66 DEU Dec, Rip

66 MAR RR, Mec, Rxn with: Clg. SCI, Nflg* ^63, Ngfg

66 NIE/WAG Rad, Rip

66 PAP QY, Mec, Phi, Rxn with: Alkanes

66 P6L Dec, Phi, Rxn with: Cl

66 ST0/GR0 Rip, For from: ,CIN02 and SOg

66 WEL Dec, Phi

67 CAL/PIT QY, Mec, Phi, Rev

8

67 DEJ/LEG For from: NasQgCl, Rip

67 KUH Rip, Rxn with: HF and Lewis acid fluorides

67 MIT/SIM Rip, Phi, Thp

67 VAN Rip, Rxn with: S6^

68 AMI/KEF RR, Mec, Rxn with: flg

68 GRI/C9S RR, Rxn with: Cs and 8b

68 LEN/flKA QY, Dec, Phi

69 BI6 Mec, Rxn with: CI, N

6? HAT/HUS RR, Rxn with: I

69 TIM/DAR QY, RR, Dec, For from: Cl and N0, Mec, Phi, Rxn with: CI

7 0 ANL Rxn with: H

70 FeR/SAI RR, Clc, Dec, Thp

7 0 Oee/GRA Dec, k

71 DUN/FREl RR, Mec, Kxn with: N

71 DUN/FHE2 RR, Rxn with: «

7 1 DUN/SUT RR, Rxn with: H

7 1 YAG/AMI Rip, Rxn with: C and «2

72 BEL/PER Rip, Rxn with: fllefins

7 2 BUS/WIL RR, Phi

72 CQL/PER Rip, Rxn with: 0

72 CLY/CRUl RR, Rxn with: Br, Cl

7 2 CLY/CRU2 RE, Rxn with: Br, Cl

72 DEA/HUS RR, Rxn with: I

72 DIJ/SCH Dec, For from: NOg and HCl, Rip, Rxn with: Nflg

7 2 DUB/DEV Rip, Syn

72 ENG/GAR Dec, Rip

"'2 F9R/LIN QY, RR, Dec, Fpr from: N0 and Cl, Mec, Phi, Rxn with: Cl

72 MAL RR, Dec, Rxn with: Cl

72 MAR/R6B RR, Mec, Rxn with: CI2C, 6Cl, Nflg

7 2 MEN/MEN RS , Rxn with:

72 SER/L9B Rip, Rxn with: Be or BeClg and N^Q^

73 BKA/WHY RR, Rxn

73 FCK/EDE Rxn with: Ba , Ca, Mg, Sr

73 GAV Phi, Rip, Hxn with: cyclohexane

73 JAN/FNG SR, Dec, For from: HCl, HNfl^, Kev,

Rxn with: Cl and Tnorg. Comp« , Syn

7 3 MAL/PAL FR, Dec

73 MeV/KYA Rip, Rxn with: Cyclic ethers

73 PRA/KAR QY, RR, Mec, Phi, Rxn with: I and R* ( R* • alkyl

)

7 3 SAV/LAC RR, Dec

73 SYR/GIL R\p, Rxn wi th : e-

7 3 VI A/AM

A

Rip, Rxn Kith: Tieclg

73 WU Dec, For from: CI and N0. Mec, Phi, Rxn w

74 BAL/BflL Mec , Phi

74 DEJ/HEU Btp, Rxn wi-th: se^

74 ECK/EDE Rxn with: Ba, Ca, Mg, Sr

74 KAR/PRAl QY. Phi, Rxn, k, Mec

7 4 K AR/PR A2 QY, RR, Mec, Phi, Rxn with: I and C^Hyl

74 KNA/MAR For rfrom: ClNCg, Mec, Rxn with: NOg and

"'4 NAZ/P6L RR, Rxn with: H

74 P6 I/KEF Rxn with:

74 TSE/DR 61 Rxn with: HNO^

7 4 SCH/UR6 For from: NaCl and NOg, Rip

74 TSE/DR62 Rxn with* HNfiA 11 WXVIl* XI 1^ \J^

74 W IL RR, For from: N6 and CXN^g* Rxn with; N2

74 W IL/ DdD RR, For, irom J No anci CLNGg

•75 BEC/FIC For from: VCt^, Rl-p, Rxn with: V( €6 )^

75 BRA/TIC Hip, Rxn with : enamines

75 DEG/KAC QY, RR, Mec , Phi, Rxn wi th : poI yet hylene

75 D6R/SCH RR, Dec

7 5 DU B/ AMA Rip, Kxn with: TlCL^t KCOg aLKyU

75 GAL/0ST Dec, For from: N6 and Clg, Rlp , Rxn with:

75 HAB/SCH Rxn with: H and D

75 KIR/SPR KXp, Rxn with: (CF2NCl)3

75 L AZ/GAV QY, Phi, Rxn with: Cycloalkanes^5 LEZ/MAL Rip, Rxn with: carbonyl complexes

75 MAL/KAT Rip, Rxn with: AsBr^, PBr^, Ph^l, Ph^As

75 MARl Rip, Rxn with: Pinene

^5 MARS Rip, Rxn with: CgHgMgBr

75 MEH/PAN Rip. Rxn with: Polyciclic Hydroc.

75 ReC/DEM Mec . Rxn with : Cyclohexene

75 ReG/VIT Mec. Rxn with: Cyclic ketones

75 SCH/CHR SR. Rxn with : e-

75 BinA «-P. Rxn with • RN ( R ~ alkvl

)

75 WAT/MARl Mec, Rxn with: CgHgMgBr

75 WAT/MAH2 Mec . Rxn with: CgH^MgBr

75 WIL RR, Mec, Rxn with: amines

75 YAR/NflF Rip, Rxn with: CF^Se^H

10

76 AMI/KEF

76 AUS/RAK

76 HIP/TRfl

76 ISA/GAS

76 KYU/CLA

76 MIR/P0V

7 6 SCH

76 SER/LEE

76 V0S

7 7 MeL/M9L

For from: Clg and Ng©^, Rlp

Rip, Rxn with: CgHj-^NE

RR, For from: CI and Ne, Rxn with: CI

QY, RB. Phi

Mec , Rxn with: 6ximes

Rip, Kxn with: Polycyclic Hydro.

Rip, Rxn with: Hydroxy polymers

RR, Rxn with: Epoxides

Rip, Rxn with: K2(M03CLg)

AB, UVS (for CieN0, Chlorine Nitrite Isomer)

ClNe

Molecular Properties

37 KET/PAL E0, RD

38 KET BE. Be, ML

39 BEE/YQSl Be, ML

43 KET B0. EC, DM

50 BER Be. ML

50 BUR/BER Be, ML

51 BEC/FES B6. RD, Rev

51 PUL/WAL ML

51 R0G/PIE MG, ML

52 BUR/MCK DC

52 EBE/ BUR ML

54 SIE ML, Clc

55 KAW/ SIM Be, ML

56 PIT/P9W EQ. ML

57 TAN Be

58 SUT Be, Clc

60 ERR BE

60 GE6 Be. DM, Rev

60 LAN/FLE ML

61 LIN Be

61 LUM DM

61 MAR/weH2 Be, DC, DM. IP. MG, ML, RD . Rev

6 1 MIL/PAN Be, DM, ML

6 1 S0G/WIL Be

62 BEN RD

6 2 KHA Be, ML

62 MIR/FAV WL

63 DUR/LeR Be, DM, ML, RD

6 4 RAY DM

65 GUA/FAY ML

65 VEN/MARl B0, ML, Clc

65 VEN/MAR2 B0, ML

66 GER/H9H MT

6 6 LIP/NAG DM

66 MIR/MAZ ML

66 M0R BE

66 NAG Be, DM, ML, RD

6 6 TAN/TAN B0, DM

67 NEL/LID DM

6 8 jeN/RYA ML

6 8 LEN/eKA BE

7 0 F0R/SAI RD

7 1 RAJ/Peu DM

7 1 RAM/NAM ML, Clc

7 1 STU/PRe Be, ML

7 2 CflT/WIL B0

72 NAT/RAM BO, ML, Clc

72 SHI ML

73 JAN/ENG DC, ML, Rev

RAG BE, Be, EC, DM, IP, MG, Rev

75 BER/Bec DM, IP

75 CHA/COR Be, ML

7 5 FHe/LEE IP

75 SPI/SPE ML, Clc

7 6 ABB/DYK IP

76 GIL/SCH IP, Clc

76 STe Be, IP, Clc

ciNe

Physical Properties

12 BRI/PYL BT, CD, DN, ST. VP, VS

2 4 TRA/GER VP

27 GAL/MEN BT, MT, VP

34 TRA/FRE TC, VS

39 ceL/LIL BT. CD, DN, MT, VP

40 ASM BT, MT

48 MCG BT, CD, DN, MT, Rev

48 SeL BT, CD, DN, MT, VP, Rev

12

49 ADD/THe2 MT

4 9 PAR/WHY 1 MT

4 9 PAR/WHY2 VP

51 BEC/FES BT, T)N, MT, ST, Rev

5 1 EPS/MIK BT, VP

5 2 BUR/ DA II MT, VP

5 2 BUR/MCK VP

60 GE0 BT, DN, MT, Rev

6 1 DEV/HIS B0, ML, C\c

6 1 MAR/W0H2 BT, CD, DN, Ml, ST, VP, VS, Rev

6 2 BEN CD, DN

6 2 SVE TC, VS

6 3 W6L/ECK VP

6 8 KDZ/EG0 CD

6 9 PAN/RIP BT, CD

7 2 C0T/WIL BT, MT

7 2 DUB/DEV MT

73 JAN/ENG MT, VP, Rev

73 RAG BT, CD, DN, MT, Rev

74 KHe/R0Z VP

7 5 KH0/R9Z VP

7 6 AMI/KEF VP

CINQ

Spectral Properties

30 KIS UVS, VIS

32 LEE/RAM VIS

34 BAI/CAS IRS

39 G00/KAT UVS, VIS

39 NAT VIS

41 PR! "SIM UVS

5 0 BER MWS

5 0 BUR/BER IRS

5 0 PIE/R6G1 MWS

50 PIE/R0G2 MWS

5 0 W IS/ELM IRS

5 1 BEC/FES IRS, UVS, VIS

51 PUL/WAL IRS

51 R0G/PIE MWS

52 EBE/BUR IRS

52 W0L/J0N IRS

13

53 WAL

5 4 HAS/J AN

5 5 K AW/ SIM

5 6 BAY/WAT

56 GEN/FIN

56 MAR/GAR

5 6 PIE/FLF

5 7 BEL/WIL

5 7 TAN

5 8 C9L/GIN

59 RAY/0GG

6 0 BR I

6 0 LAN/FLE

6 1 CAS/PQL

61 MIL/ PAN

6 2 MIR/FAV

6 3 DUR/L0R

6 3 G0L

63 HIS/MIL

6 3 LEN/6KA

6 5 GUA/FAV

66 MIR/MAZ

6 6 TAN/ TAN

6 8 J0N/RYA

6 8 LEN/6KA

7 0 AND/MAS

7 1 DUN/SUT

72 F9R/LIN

7 2 MAC/DEV

7 3 JAN/ENG

7 4 BAL/ARM

74 DUB/CAB

74 H0E/WAD

7 5 BER/SeC

75 CAZ/CER

7 5 FR6/LEE

7 5 ST6

7 6 ABB/DYK

7 6 GIL/SCH

76 ILL/TAK

76 SAV/BES

77 M0L

UVS, VIS,

IRS

IRS

UVS

UVS, VIS

UVS

IRS

IRS

UVS

IRS, UVS

IRS

UVS

IRS

IRS

MWS

MWS

IRS

IRS

IRS

UVS

MWS

MWS

UVS

IRS

UVS

NMS

MSS

MSS

IRS, RAS

IRS, Rev

UVS, VIS

XRS

AE, RAS

XPS

IRS, MWS

XPS

XRS

XPS

XPS

AB, UVS

MSS

AB, UVS

CIN0

Thermoctynamic Properties

1 2 BR I/PYL ET

1 5 TRA/HIN EQ

16 BR I ET

1 6 TRA/HIN EQ

1 6 TRA/WAC EQ

24 TRA/SCH EQ

27 GAL/MEN VP

31 DIX EN. EQ. ET

31 WHI/LUN ET. TE

32 LEE/RAM EN. EQ. ET, TE,

36 B I C/R 9 S ET

38 JAH EN. EQ, ET. TE,

39 BEE/Y0S1 EN. EQ, ET, HC,

39 BEE/YQS2 EQ

40 ASM ET

41 PRI/SIM ET

41 SCH/MAS EQ, TE

45 DR0/GAL IE

49 PAR/WHY2 ET

50 BUR/BER EN. HC, TE

5 1 BEC/FE S EN. EQ, ET, HC,

5 1DTT T /nr A T EN

57 K AY/ Ov?G EQ

5 8 U A T3 /^ |0|UMAK/ K-OH ET

c co >y EN. C> 1

6 0 GEO ET, Rev

6 1 MAA/ W Oa^ EN, EQ, ET, HC ,

61 WAR EN. ET, TE

62 GdR EN, ET. HC, TE

62 SVE HC

65 CAL/GLA ET

65 VEN/MAR2 EN, HC, TE

66 NAG EN, HC, TE

68 GLU EN, ET, HC, TE

68 KUZ/EG0 ET

68 LEN/eKA ET

68 WAG/EVA EN. ET, HC, TE

69 PAN/R I

P

ET

70 G00/GRA ET

15

71 STU/PRS

7 1 YAG/AM

I

7 2 DUB/DEV

7 3 JAN/ENG

73 RAG

7 3 VI A/AM

A

7 4 GUR/KAR

7 5 CHA/CUR

76 AMI/KEF

EN, ET, HC, TE

TE

ET

EN, BC, Rev

ET, TE, Rev

EQ

ET

EN, ET, HC, TE

EQ

PART II

NITRYL CHLSRIDE

Chemistry and Chemical Kinetics

24 KIS

2 9 SCH/SPRl

29 SCH/SPR2

29 SCH/SPR3

31 SCH/SPR

4 7 SCH

48 PET

5 0 6GG/W I

L

52 BAT/SIS

52 FRE/jan

52 SEE/N6G

53 J0H/LEI

54 C0R

54 ceR/J0H

54 LEI

5 5 MAK/K0H

55 RAY

55 SCH

5 6 HER/JflH

5 6 V0L/J0H

57 CAS

BR, For from: CI and Neg, Mec, Rxn with: N0

Rip, Syn

RR, Dec

RR, Dec, For from: CIN0 and 0^, Mec

RR, Dec

Dec, For from: CIN0 and with: NH^,Na0H, AgNOg, AgNOg, Syn

Rip, Rxn with: Na0H, NH^, Syn

For from: Clg, N20^, ^^^^^t CIN0, 0^

Rip, Rxn with: NH^, metals, Inorg. oxides and salts

RR, Rxn with: N0

Dec, Rip, Rxn with: Hgl, - , Syn

R8, For from: CIN0 and NO^

RR, Dec

RR, Dec, Mec, Rxn with: Cl

RR, For from: CIN0 and 0^

RR, For from: ClO^ and CIN0

For from: Clg. CIN0, NOg, Mec

Rip, Rxn with: Cl20g. ^2^2' Na0H, NH^, N^-, Syn

RR, Clc, Rxn with: N0, Thp

RR, Dec, Mec, Kxn with: Cl , H, N0

RR, Dec16

57 RAY/aCG RR, For from: CINQ and NQg

57 SCH/FIN RVp. Rxn with: ClNa^

58 CeL/GIN Rip, Dee. Rxn with: CgH^a CgHg . HCl, HgSQ^, Syn

58 GIN/G0D RR. Rxn with: Alkylbenzenes, Hgfl, HNQg

58 MAR RR, For from: ClgS, Ndg, Ng^s

58 MAE/K6H RR, Dec. For from: ClGg. N«2» NQ^. CIN6. Mec

59 MAR/ME

I

RR, For from: CX^G, NgQg

59 NIK RR, Dec. Clc

59 TAL/THe For from: HCl and ti^el^, Mec, Rxn with: N0

60 MAR/ME

I

RR, For from: Cl^^t NQg, NgCt^, CIN0, Rxn with CINQ^

6 1 ASn/ oUK RR , Dec, Mec, Kxn with: NO and C INO

6 1 DflH/W IL RR, Dec, Phi, Rxn with: CI

6 1 FEU Rip, Syn

62 ASH/BUR RR, Dec, Mec

62 HIR/HAR RR, Dec, Rxn with:

62 W IE/MAR RR, Clc, Dec, Thp

63 SIN RR, Clc, Dec, Rxn with: Cl, Thp

63 WEI Rip, Rxn with: HgO and SQ^

65 VAN/HEU Rip, For from: Inorg, Nitro Comp . , Rxn with:

66 DRE Dec

66 MAR FR, For from: ClQg. ^2®' ^'^2* ^^3» ^2^5* CIN6, Mec

66 MIL Rip, Syn

66 TAR/RAB Clc, Dec, Thp

67 BEG Rip, Rxn with: Olefins

67 DEJ/LEG For from: N0S0,CI and N-jQa. Rip

67 KUH Rip. Rxn with: HF and Lewis acid fluorides

67 VAN For from: Inorg Nitro comp.. Rip

68 TAR/RAB ClC, Dec, Thp

69 PAU/STN Rip, Rxn with: HgSgfly, HjSe^, SbClg, BCI3

70 BEN/fl'

N

RR, Dec, For from: NQg Cl, Mec, Rev. Rxn with:

70 CAI RR, Dec

71 HIR Rip, Rxn with: L1N(CH3)2. Syn

72 DUT RR, Dec

72 DUT/BUN RR, Dec

72 MAR/R6B RR, For from: CI2CI. CIN0

72 PAU/AR0 Rip, Rxn with: se^

73 JAN/ENG Dec, Rev, Rxn with: Inorg, subst., Syn

73 TRe Dec. Thp

17

73 TSA RB, Dec, Sev, Rxn with: Cl

74 KNA/MAR KR, For from: NBg, ClNfl^, CIN0,ClgC. Mec, Rxn with: Ne

74 V0R/ENG Dec, Kip, Rxn with: SFg

74 WIL RR, For from: Ng 65 and CIN0, Rxn with: N0

74 WIL/D0D RR, Mec, Rxn with: N0

76 AMI/KEF For from: and N^O^, Rlp

76 BIR/JES RR, FhV

77 M0L/MQL RR, For from: ClSNS, CIN0, and CIN^^, Mec, Phi (for C19N6,Chlorine Nitrite Isomer)

CIN0-

Molecular Properties

37 LUC

5 0 0GG/WIL

5 4 RTA/WIL

55 MIL/SIN

5 6 CLA/WIL

5 6 HER/jaH

57 GEI/RXT

58 HAR

58 MIL/SIN

5 8 SUT

59 CLA/WIL

6 0 GE0

6 1 DEV/HIS

6 1 LIN

61 LUM

6 1 KKI

6 1 PUH/RAS

6 1 VEN/THI

6 2 BEN

6 2 KHA

6 2 VEN/RAJ

6 3 eKA/MflR

64 RAY

6 5 M6R/TAN

6 5 PUR/RAG

6 5 SU T.

6 6 EAG/WE

A

RD

BE

ML

ML

DM, ML

WL

B0

ML, Clc

B0, ML

B0, Clc

Be, DM, ML

B0, Rev

B0, ML, Clc

Be

DM

ML, Clc

B0, ML, Clc

ML, Clc

ML

Be

ML, Clc

DM, ML

DM

B0, ML

E0, Clc

B0

DM

6 6 M«R

6 7 BER/MIL

6 7 MUL/NAG

6 7 NEL/LID

6 7 NEMl

6 7 NEM2

6 8 MUL/KRE

6 8 NEM

69 PRE

69 RAe

71 STU/PR©

7 2 C0T/WIL

72 SHI

7 3 JAN/ENG

7 5 FR9/LEE

BE, Clc

ML

B6, Clc

DM

ML, Clc

ML, Clc

ML, Clc

ML, Clc

ML, Clc

DM, ML

Be, ML

B0

ML

DM, Rev

IP

CIN0-

Physical Properties

29 SCH/SPRl

37 LUC

4 8 PET

57 GEI/RAT

5 8 CeL/GIN

61 HEU

62 BEN

66 DRE

68 KUZ/EG6

6 9 PAN/HIP

69 PAU/SIN

7 2 cex/wiL

7 3 JAN/ENG

BT, DN, MT, VP

VS

BT, DN, MT

EN, EQ, HC, TE

BT, MT

BT, MT, DN

CD, DN

TC

CD

BT, CD

FP

BT, MT

VP, Rev

CIN6-.

Spectral Properties

5 0 eCG/WIL

54 RYA/WIL

55 MIL/SIN

5 6 CLA/WIL

56 MAR/GAR

IRS

IRS, RAS

MWS

MWS

UVS

19

5 8 C0L/GIN

58 MIL/SIN

5 9 CLA/WIL

59 RAY/0GG

6 3 6KA/M0R

6 5 MeR/TAN

6 6 EAG/WE

A

66 MIL

6 7 BER/MIL

69 PAU/SIN

7 0 MAS/BRe

71 BAR/VAS

71 HIR

73 JAN/ENG

7 4 CHR/SCH

75 FRe/LFE

75 FIL/LdR

76 BIR/JES

76 ILL/TAK

77 M0L

77 MeL/iceL

IRS, DVS

MWS

MWS

IRS

MWS

MWS

MWS

IRS

IRS

IKS. RAS

NMS

IRS

IRS

IRS, Rev

IRS, RAS

XPS

MWS

AB, UVS

AB, DVS

AB, UVS (for both isomers: Nltryl Chloride, andCl0Ne, Chlorine Nlirri-te

AB, UVS (for Cl6Ne, Chlorine Nitrite Isomer)

ClNe,

Thermodynaalc Properties

29 SCH/SPRl

55 RAY

5 7 gei/r31t

57 RAY/ffGG

5 8 MAR/K0H

5 9 RAY/aCG

60 GE0

61 KRI

61 LAR/MAR

6 1 PIL

61 PUR/RAe

66 MIL

6 7 BER/MIL

6 8 GLU

6 8 KUZ/EG9

6 8 WAG/EVA

6 9 PAN/RIP

ET

EN,

EN.

EQ

ET

EN,

ET,

EN,

EN,

EN,

EN,

EN,

EN,

EN.

ET

EN,

ET

EQ, ET

EQ, HC, TE

ET

Rev

HC, TE, Clc

HC, TE

HC

HC, TE

ET, HC, TE

ET, HC, TE

ET, HC, TE

ET, MC, TE

20

7 0 BEN/e'N

71 STU/PR0

7 3 JAN/ENG

7 4 GUH/KAP

EN, ET, HC

EN, ET, HC, TE

EN, ET, HC, Rev

ET

PART III

CHL6RINE NITRATE

Chemistry and Chemical Kinetics

3 5 USH/CHI

36 USH/CHI

3 7 USH/CHI

55 MAH/JAC

5 6 MAR/GAR

57 SCH/BHR

57 SCH/FIN

58 MAR

58 SKI/CAD

59 MAR/ME

I

6 0 MAR/ME

I

61 CAP

6 1 CAF/SIC

61 FINl

61 FIN2

6 1 SCH/BRi

66 MAR

66 MIL

67 SCHl

67 SCH2

6 8 MUL/DEH

7 0 BEN/6'

N

7 4 KNA/MAR

74 SCH/CHR

75 cee/pRi

7 6 RQW/SPEl

Rip, Rxn with: fllefins

Rip, Syn

Blp, Syn

RR, For from: Cl0, Clflg* Nflg* Mec

RR, For from: CIG^, NCg, Mec

Rip, Rxn with: ICI3, SuCl^, TiCl^

For from: ClOg, Clgf, ClSAsG^, N62 . ^2^5' R^P.Rxn with: HCl, NSj . CIN6, CIN62. Syn

RR, For from: ClCflg* ClgC. NSg* ^265, Mec

Rip

RR, For from: ClgG, NGg. ^265

RR, For from: Cl20, ecl , N02

RR, Dec

RR, Dec

Rip, Rxn with: eiefins

Rip, Rxn with: dlefins

For from: C102» Na2 , ^265,Rxn with: Inorg. Solvent, Syn

RR, For from: Cl02» ClgS, Nflg. NgGg, CIN6, Mec

Hip, Syn

Rip, Syn

Rip, Syn

Blp, Rxn with: SbF3Cl2

RR, Dec, lixn with: NCg* ^l» ^^2' ^^^^ Rev, Rxn with: 6Cl

RR, Dec, Mec, Rxn with: CI and NGg

Rip, Rxn with: 6^

KR, Rxn with: HCl

For from: CIO and N0p, Phi, Rip, Rxn with: 0

21

7 6 RflW/SPE2 For

76 BIR/JES SR.

7 6 R0W/SPE1 For

76 R6W/SPF2 For

77 KUR/MAN SR,

7 7 M9L/SPE KB,

7 7 RAV/DAV RR,

77 SMI/Cae QY,

from: Cie and N6

Phi

from: C16 and N0

from: CIS and N0

Rxn with: CI

Rxn with: 0, Syn

Rxn with: 0, 0H

Phi

, Phi, Rxn with:

, Phi, Rip, Rxn wi

, Phi, Rxn with:

3 7 PAU/BR0

6 0 brVsch6 3 ARV/CAFl

63 ARV/CAF2

6 7 MIL/BER

7 6 SUE/J0H

B0, Rip

ML

ML

ML

BE, B0, ML

ML

CIN0.

Molecular Properties

5 5 MAR/J AC

5 8 MAK

6 0 GEO

61 SCH/BRX

67 SCHl

6 7 SCH2

BT, MT

BT, MT, VP

BT, MT, Rev

BT, MT

BT, VP

BT, MT

CIN0,

Physical Properties

CIN0-

Spectral Properties

5 6 MAR/GAR UVS

6 0 BRU/SCH IRS

6 3 ARV/CAFl IRS

63 ARV/CAF2 IRS

66 MIL IRS

67 MIL/BER IRS22

74 CHR/SCH IRS, RAS

74 SHA/YEL RAS

75 AMO/FLE RAS

76 BIR/JES AB, UVS

76 RdW/SPEl UVS

76 SUE/J0H MWS

77 BIR/JES RR, Phi

77 GRA/TOA AB, IRS

77 SMI/CHS QY, PHL

77 KOR/MAN RR, Rxn with: 0, 0H

77 RAV/DAV RR, Rxn with: 0, 0H

77 MSL AB, UVS

CIN03

Thermodynamic Ppopertiesi

6 0 GE0 ET, Rev

6 1 SCH/BRX ET

67 MTL/BEK EN, ET, HC, TE

67 SCHl ET

68 GLU EN, ET, HC, TE7 0 BEN/0'N EN, ET, HC

74 KNA/MAR ET

23

PAST I

V

Keferences

1 874

74 TIL TlXden, W. A., "en Aqua Segia and the Nltrosyl Chlorides," J. Chem.(London) 27, 630 (1874)

Soc.

1 891

9 1 SUD Sudborough, J. J., Action of Nitrosyt Chloride on Metals,'Soc. (London) 59, 655 (1891)

J. Chem.

1 912

12 BRI/PYL Briner, M. E., and Pylkoff, M. Z., "Contributions a la Connaissance desmodes de Formation et des Proprieties du Chlorure de Nitrosyle,"J. Chim. Phys. 10, 640 (1912)

19 14

14 TRA Trautz, M. , "Der Temper aturkoeffiz ient der Nitrosylchloridbildung ausStickoxyd und Chlor," Z. Anorg. Chem. 88, 285 ( 1914)

1915

15 TRA/HIN Trautz, M. , and Hinck, C. F., "Das Zer fal Isglei chgewicht 2N9 Clg —2N6CI des Nitrosylchlorids. Eine Bestatigung des Gesetzes von derAdditivitat der inneren Atomwarmen," Z. Anorg. Allg. Chem. 9 3 .

177 ( 191 5 )

i£i6

16 BRI Briner, M, E., "Sur le Mecanisme des Reactions dans I'eau Regale,"C. R. Hebd. Seances Acad. Sci. ( Par is ) 162 , 387 ( 1916 )

16 TRA/HIN Trautz, M., and Hinck, C. F. , "Das Zerfallsglelchgewicht 2N^ CI g "

2N6CI des Nitrosylchlorids. II. Ersetzung der chemischen Konstantendurch In tegra t ionskonstan ten , berechnet aus der Molekulgrosse,Z. Anorg. Allg. Chem. 97, 127 (1916)

16 TRA/WAC Trautz, M. , and Wachenheim, L. , "Das Zer fallsgle ichgewi cht von Nitrosyl-chlorid," Z. Anorg. Allg. Chem. 97, 241 (1916)

1 923

2 3 CUT/TAR

23 KIS

Cuttica, v., Tarchi, A., and Alinari, P., "L'azione di VflClg, e di NQClSoora gli Sssidi Metallici," Gazz . Chim. Ital. 53, 189 ( 1923)

Kiss, A., "Ueber Den Lichtzerfall des Nitrosylchlorids," Rec. Trav,Chim. Pays-Bas 6g, ^65 (1923)

24

24 KIS Kiss, A,, "Studien Ober Ka-talyse bei Homogenen G asr eakt ionen II,Katalyse der Nl trosylchlor idebildung Durch Ni t rogend ioxyd ,

"

Rec . Trav, Chlm. Pays-Bas 43, 68 (1924)

24 TRA/GER Trautz, M. , and Gerwig, W., "Der Dampfdruck des flussigen Ni trosylchlorids, "

Z. Anorg. Allg. Chem. 1 34 . 409 (1924)

24 TRA/SCH Trautz, M. , and Schlueter, H., "Dreirs+osse als Folge von Zwe 1 er s tosse

n

in physlkaii sche r vind in chemlscher Be-trachtungsweise, " Z. Anorg.Allg. Chem. i.36, 1 ( 1924)

1 925

2 5 B6W/SHA Bowen, E. J,, and Sharp, J. P., "The Pho-tochemical Decomposition ofNi-trosyl Chloride," J. Chem. Soc. (London) 127 . 1026 ( 1925)

1926

26 LYN/SHe Lynn, E. V,, and Shoemaker, H. A., "Ni trosyl Chloride," J. Am. Pharm.Assoc. 15, 217 (1926)

19 27

27 GAL/MEN Gall, H., Mengdehl, H., "Ober die Anlagerung von Ni trosylc hlor id anMetallsalze, " Ber. Dtsch. Chem. Ges. 60, 86 (1927)

27 TAY/DEN Taylor, H. A,, and Denslow, R. B., "The Thermal Decomposition ot NitrosylChloride, J. Phys. Chem. 3±, 374 (1927)

1928

2 8 N0Y Noyes, W. A., The Interaction Between Nitrogen Trichloride and Nitricdxide. Reactions of Compounds with ffdd Electrons," J. Am Chem. Soc,50, 2902 (1928)

1929

29 SCH/SPRl Schumacher, H. J., and Sprenger, G,, "Die Darstellung und E i genschaftendes Nitrylchlorids, " Z. Anorg. Allg. Chem. 1 82 . 139 (1929)

29 SCH/SPR2 Schumacher, H. J., and Sprenger, G., "Die Ge schwi ndigke i t desnonomolekularen Zerfalls einfacher Gase," Naturwissenschaften17 . 997 ( 1929 )

29 SCH/SPR3 Schumacher, H. J., and Sprenger, G., "Ni trylchlor id: Bildung undthermischer Zerfall. Ein experimenteller Beitrag zur Theorie dernonomolekularen Reaktionen," Z, Elektrochem. 35, 653 (1929)

1 93 0

30 KIS

3 0 N0Y

Klstiakowsky, G, B. , "Photochemical Decomposition of Nitrosyl Chloride,"J. Am. Chem. Soc. 52, 102 (1930)

Noyes, W. A., "The Interaction Between Nitrogen Trichloride and Nitric6xide at -150°. II. Further Evidence for the Formation of NitrogenDichloride and 0f Mono-6xygen -D i ni t rogen -D Ichlor ide, " J. Am. Chem.Soc. 5g, 429 8 (1930)

25

1931

31 DIX Dixon, J. K. . "The Equilibrium between Chlorine, Nitric 6xitte and NitrosylChloride, Z. Phys. Chem. A Bodenstein -F estband . 679 ( 1931 )

31 SCH/SPR Schumacher, H. J,, and Sprenger, G., "Der thermische Zerfall des Nitryl-chlorides. Ei ne homogene Gasreaktion erster 6rdnung," Z, Phys,Chem. B 12, 115 ( 1931 )

31 WHT/LUN Whittaker, C. W., Lundstrom, F. 6., and Merz, A. R. , "Preparation o*Potassluni Nitrate from Solid Potassium Chloride and NitrogenPeroxide," Ind. Eng. Chem. 23, 1410 (1931)

1932

32 LEE/RAM Leermakers, J. A,, and Ramsperger, H. C, "The Gas Phase EquilibriumBetween Methyl Nitrite, Hydrogen Chloride, Methyl Alcohol, andNitrosyl Chloride. The Absorption Spectrum of Nitrosyl Chloride,"J. Am. Chem. Soc. 54, 1837 (1932)

1934

34 BAI/CAS Bailey, C. B. , and Cassie, A. B. D., "investigations in theInfra-red Region of the Spectrum. Part X, The AsymmetricalMolecule Nitrosyl Chloride, NOCL," Proc. Roy. Soc. (London) A165 . 336 ( 1934 )

34 TRA/FRE Trautz, M., and Freytag, A., "Die Reibung, Warmeleitung und Diffusionin Gasmi schungen XXVIII, Die innere Reibung von Clg, N6 und N0CI,Gasreibung wahrend der Reaktion 2N9 Clg " 2N6CI," Ann. Physik 20 .

135 ( 1934 )

1935

35 WAD/TOL Waddington, G. , and Tolman, R. C, "The Thermal Decomposition of NitrosylChloride," J. Am. Chem. Soc. 57 . 689 (1935)

35 USH/CHI Ushakov, M. I., Chistov, V. 6., and Shlosberg, M. A,, "The Salt Propertiesof Halides, Products of the Reaction of the Compounds of UnivalentPositive Halides with Unsaturated Hydrocarbons," Zh , dbshch. Khim.5, 1391 ( 1935 ); Chem. Abstr, 30:2190-9 ( 1936)

1236

36 BIC/RflS Bichowsky, F. R., and Rossini, F. D., "The Thermochemistry of theChemical Substances," Reinhold Publishing Corporation, 35 (1936)

36 USH/CHT Ushakov, M. I., and Chistov, V. 0., "Chlorine Nitrate," Bull.Soc, Chim. France 3, 2142 (1936)

19 37

37 KET/PAL Ketelaar, J. A. A., and Palmer, K. J., "The Electron DiffractionInvestigation of Nitrosyl Chloride and Nitrosyl Bromide,J. Am. Chem, Soc, 59, 2629 (1937)

37 KRA/SAR Krauss, W, , and Saraclni, M, , "Der Mechanismus der Reaktion von Stickoxydmit Sauerstoff, Chlor und Brom, III," Z, Phys, Chem. A 178, 245 (1937)

37 LUC Luchinskii, G. P., "Mechanical Characteristics of Anhydrous Halogen

Compounds," Zh. flbshch. Khlm. 7, 2110 (1937)

26

37 PAU/BR6 Pauling, L. , and Bpockway, L. 6., "The Adjacent Charge Rule and theStructure o± Methyl Azide, Methyl Nitrate, and Fluorine Nitrate,"J. Am. Chem. Soc . 59, 13 (1937)

37 USH/CHI Ushakov, M. I., and Chistov, V. 0., "Chlorine Nitrate, "Zh. 6bshch. Khim.7, 253 (1937); Chem. Abstr . 31 : 340 5 -6 (1937)

1 938

3 8 BFE/C9R

3 8 J AH

38 KET

38 SCH

38 WEL/TAY

Beeson, C, M. , and Coryell, C, D., "The Diamagnetism of Gaseous NitrosylChloride," J. Chem. Phys. 6, 656 (1938)

Jahn, F. P., "The Free Energy and Entropy of Nitrosyl Chloride," J. Chem.Phys. 6, 335 (1938)

Ketelaar, J. AAtti Congr.

A., "La Structure Moleculaire du Chlorure de Nitrosyle,"Int. Chim. 16, 301 (1938)

Schumacher, H. J., Chemische Gasreakt ionen, ( T. Steinkopff Publisher,Dresden and Leipzig, 1938), pp. 127, 281, and 321 ( P hot o -Li thoprin tedin 1943 by E. Brother, Inc., Ann Arbor, Michigan)

Welinsky, I., and Taylor, H, A., "The Energy and Entropy of Activationof the Reaction Between Nitric 0xlde and Chlorine," J. Chem. Phys. 6,466 ( 1938 )

1939

39 BEE/Y9S1

3 9 BEE/Y0S2

39 C0L/LIL

39 G60/KAT

3 9 NAT

Beeson, C. M., and Yost, D. M. , "The Equilibrium Dissociation andThermodynamic Constants of Nitrosyl Chloride. Comparison withSpectroscopic Data," J. Chem. Phys. 7, 44 (1939)

Beeson, C. M., and Yost, D. M. , "The Thermodynamic Constants of BromineChloride. The Equilibrium Reaction Between Nitric Qxide, Bromine,Chlorine, Nitrosyl Bromide and Chloride, and Bromine Chloride,"J. Am. Chem. Soc 61, 1432 (1939)

Coleman, G. H., Lillis, GChloride. S0<, HN0

A., and Goheen, G. E.

,

2 ""-3 -* HeS02^N0, H0S020N0 HClNi trosyl-> N0CI H„S0^

Inorg. Synth. 1, 55 (1939)

Goodeve, C, F,, and Eatz, S., "The Absorption Spectrum of NitrosylChloride," P roc . Roy. Soc. (London) A 172 . 432 (1939)

Natanson, G, L. , "0n the Mechanism of Photochemical Decomposition ofNitrosyl Chloride," Acta Physicochim. URSS H, 521 ( 1939)

1 940

40 ASM Asmussen, S. W. , "Ober Ni trosylchl orid und seine Verbindungen mitanorgani sche n Chloriden Magnetochemlsche Untersuchungen. 3.,"Z. Anorg. Allg. Chem. 243, 127 (1940)

40 NAT Natanson, G. L. , "The Lifetime of Activated Triatomic Molecules andthe Mechanism of P redi ssociation of Nitrosyl Chloride," ActaPhysicochim. URSS 13, 317 ( 1940)

1941

41 ATW/R0L Atwood, K., and Rollefson, G. K., "The Efficiency of the PrimaryPhotochemical Process in Solution," J. Chem. Phys. 9, 506 (1941)

41 PRI/SIM Price, W. C., and Simpson, D. M. , "The Absorption Spectra of NitrogenDioxide, Ozone and Nitrosyl Chloride in the Vacuum Ultra -Vi ol e t,

"

Trans. Faraday Soc. 37, 106 (1941)

27

41 SCH/MAS Schmld, H, , and Maschka^ A., P hot ome-t ri sche Bestlmmung der freienBlT-dungsentha Ipie wasserlgen Ni trosylchlorlds, " Z, Phys. Chem.B 49, 171 ( 1941 )

1 943

43 KET Ketelaar, J. A. A., "The Dipole Moment and the Constitution of Nitrosyl

Chloride and Nitrosyl Bromide," Rec. Trav. Chim. Pays-Bas 62, 2 89 ( 1943)

1 947

47 SCH Schmeisser, M. , "tSber das Ni trylchlorid Ne2Cl," Z, Anorg. Altg. Chem.255 . 33 ( 1947

)

1948

48 PAB/WHY Partington, J. R. , and Whynes. A. L. , The Action ot Nitrosyl Chlorideon Some Metals and Their Compounds," J. Chem. Soc. (London)1952 (1948)

48 PET Petri, H., "Ober das N itryIchlorid, " Z. Anorg. Allg. Chem. 257 .

1 80 ( 1 948 )

48 MCG

4 8 set

McGonigle, T. J., "Properties presented and Reactions of Nitrosyl Chloride,'presented at Amer. Chem. Soc. Meeting ( 1948), The Solvay ProcessDivision, Allied Chemical A Dye Corporation, Product DevelopmentDepartment, 40 Rector Street, New York 6, N. Y., see also SolvayProcess Division

Solvay Process Division, "Nitrosyl Chloride," presented at Amer. Chem.Soc. Meeting (1948), Solvay Process Division, Allied Chemical A DyeCorporation, Product Development Department, 40 Reactor Street, NewYork 6, N. Y., see also McGonigle

1949

49 ADD/THOl Addison, C. C. , and Thompson, R. , The Liquid Dlnitrogen TetroxideSolvent System. Part T. General Introduction," J. Chem. Soc. (London),S211 (1949)

49 ADD/TH62 Addison, C. C. , and Thompson, R. , "The Liquid Dlnitrogen TetroxideSolvent System. Part II. Liquid and Solid Solutions of NitrosylChloride in Dlnitrogen Tetroxide," J. Chem. Soc. (London), S2 1 8 ( 1949 )

49 DBe/GAL Drozin, N, N., and Galinker, I. S. , "0xldatlon of Nitrosyl Chloride,"Zh. Prikl. Khim. £2, 475 (1949)

49 PAR/WHYl Partington, J. R. , and Whynes, A. L. , "Reactions of Nitrosyl Chloride.Part II," J. Chem. Soc. (London) 3135 ( 1949)

49 PAR/WHY2 Partington. J. R., and Whynes, A. L. , "The Vapor Pressure of NitrosylChloride," J. Phys. Colloid Chem. 53, 500 (1949)

1250

50 BER Bernstein, H. J., "The Structure of Nitrosyl Chloride from the MicrowaveAbsorption Spectrum," J. Chem. Phys. 18, 1514 (1950)

50 BUR/BER Burns, W. G., and Bernstein, H. J., "The Vibrational Spectra andStructure of Inorganic Molecules. III. The Infra-Red Specjfraof Nitrosyl Chloride and Nitrosyl Bromide from 2.0 to 25>i,

J. Chem. Phys. 18, 1669 (1950)

28

I

1

5 0 eOG/WTL

50 PIE/Kaci

50 PIE/R9G2

5 0 W IS/ELM

51 BEC/FES

51 E PS/MI

K

51 PUL/WAL

5 1 R0G/PIE

52 BAT/SIS

52 BUR/MCK

52 BOR/DAIl

52 BUR/DAI2

52 C HA/ASH

52 EBE/BUR

52 FRE/J0H

5 2 SEE/N0G

52 W6L/J0N

53 ASH/CHAl

53 ASH/CHA2

0gg, R. A., and Wilson, W. K. , "The Stability o* Gaseous Ni tryl Chloride,"J. Chem. Phys. 18, 900 (1950)

Pietenpol, W. J., Rogers, J, D. , and Williams, D,, "Microwave Spectra ofAsymmetric Top Molecules," Phys. Rev. 78, 480 (1950)

Pietenpol, W, J., Rogers. J. D,, and Williams, D. , "Microwave Spectrumof Nitrosyl Chloride,* Phys. Rev. Z_7, 741 ( 1950)

Wise, J. H. , and Elmer, J. T., "The Infra-Red Spectrum of NitrosylChloride," J. Chem. Phys. 18, 1411 (1950)

1951

Beckham, L. J., Fessler, W. A., and Ki se , M. A., "Nitrosyl Chloride,"Chem. Rev. 48, 319 (1951)

Epshtein, D. A., and Mikhaleva, S. V., "The System Clg-Necl," Dokl. Akad.Nauk SSSR 78, 71 (1951); Chem. Abstr. 54:1786-h (1954)

Pulford, A. G. , and Walsh, A. "The Infra-Red Spectrum and ThermodynamicConstants of Nitrosyl Chloride," Trans. Faraday Soc. 47, 347 (1951)

Rogers, J. D. , Pietenpol, W. J., and Williams, D,. "The MicrowaveAbsorption Spectrum of Nitrosyl Chloride N0CI, Phys. Rev. 83,431 , ( 1951 )

1952

Bat ey, H, H.. and Sisler, H, H., "Some Inorganic Reactions of NitrylChloride," J. Am. Chem. Soc. 74, 3408 (1952)

Burg, A. B. , and McEenzie, D. E., "Further Studies of Nitrosyl Chlorideas an Ionizing Solvent," J. Am. Chem. Soc. 74, 3143 (1952)

Burns, W. G. , and Dainton, F. S, , "The Vapour Pressure Curves of Solidand Liquid Nitrosyl Chloride, Trans. Faraday Soc. 48, 21 (1952)

Burns, W. G. , and Dainton, F. S., "The Rate Constants of the Reaction ofNitrosyl Chloride with Chloride Atoms and C0CI Radicals," Trans.Faraday Soc. 48, 52 (1952)

Chanmugam, J., and Ashmore, P. G., "The Hydrogen-6xygen ReactionSensitized by Nitrosyl Chloride," Nature 170 . 1067 (1952)

Eberhardt, W. H., and Burke, T. G. , "An Absorption Band of N0CI at 30»i,"J. Chem. Phys. 20, 529 (1952)

Freiling, E. C. , Johnston, H. S., and 0gg, R. A., Jr., "The Kinetics ofthe Fast Gas-Phase Reaction Between Nitryl Chloride and Nitric 0xide,"J. Chem. Phys. 20, 327 (1952)

Seel, F. , and Nogradi, J., "Zur Konstitution und Reakti onsweise desNitrylchlorids, " Z. Anorg. Allg. Chem. 269 . 188 (1952)

Woltz, P. J. H., Jones, E. A., and Nielsen, A. H. . "The Infrared Spectrumof Nitrosyl Fluoride. Part I. Prism Spectrum, J. Chem. Phys. 20, 378( 1952 )

1953

Ashmore, P. G. , and Chanmugam, J., "Reactions in the System Hydrogen,Chlorine, Nitric ©xide and Nitrosyl Chloride Part 1. The ReactionBetween Hydrogen and Chlorine in the Presence of Nitric 0xide andNitrosyl Chloride," Trans. Faraday Soc. 49, 254 { 1953)

Ashmore, P. G. , and Chanmugam, J., "Reactions in the System Hydrogen,Chlorine, Nitric Gxide, and Nitrosyl Chloride Part 2. The ThermalDecomposition of Nitrosyl Chloride," Trans. Faraday Soc. 49, 265 (1953)

29

5 3 ASH/CHA3

5 3 JflH/LEI

53 WAL

54 ceR

54 C9R/jaH

54 FRE

54 HAS/JAN

54 I.EI

54 RYA/WIL

54 SIE

55 EPS/NIK

55 KAW/SIM

55 MAB/JAC

55 MAR/KflH

55 MIL/SIN

5 5 RAY

55 SCH

Ashmore, P. G., and Chanmugam, J,, "Seac-tions in the System Hydrogen,Chlorine, Nitric exide, and Nltrosyl Chloride Part 3. The VelocityConstant of the Reaction N0 • Clg -> NGCl CI," Trans. Faraday Soc,49 . 270 ( 1953 )

Johnston, H. S. , and Leighton, F., Jr., "The Mechanism of the Reactionbetween 0zone and Nltrosyl Chloride," J. Am. Chem. Soc. 75, 3612 (1953)

Walsh, A. D., "The Electronic Qrbitals, Shapes, and Spectra of PolyatomicMolecules. Part II. Non-hydride AB2 and BAC Molecules," J. Chem. Soc,(London) 2266 (1953)

1954

Cordes, H. F., Jr. "The Thermal Decomposition of Nitryl Chloride at LowPressure, Diss. Abstr. 14, 155 8 (1954)

Cordes, H. F, , Jr., and Johnston, H. S. , "Thermal Decomposition of NitrylChloride. I. Second-Order Unimolecular Rate Study," J. Am.Chem. Soc. 76, 4264 (1954)

Fre Jacques, C, "Sur la Clnetique Anormale des Reactions du Bioxyded' Azote," J. Chim. Phys. Phys.-Chim. Biol. 5i, 78 (1954)

Haszeldine, R. N., and Jander, J., "Studies in Spectroscopy. Part VI.Ultra-Violet and Infra-Red Spectra of Nitrosamines. Nitrites, andRelated Compounds," J. Chem. Soc. (London), 691 (1954)

Leighton, F., Jr., "The Mechanism of the Reaction Between NltrosylChloride and ©zone," Diss. Abstr. 14 . 935 (1954)

Ryason, R. , and Wilson, M. K. , "Vibrational Spectrum and Structure of NitrylChloride," J. Chem. Phys. 22, 2000 (1954)

Siebert, H., "Kr aftkonstante und Strukturchemie. IV. Struktur derNichtmetall-Gxyde und -6xyhalogenide ,

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Epshtein, D. , A., and Nlkonova, I. N., "Formation of Solid Products fromReactions of Watersoluble Salts with Gaseous Substances in the Presenceof Water Vapor," Issledovanl ya po Priklad. Khlm. , Akad. Nauk SSSRetdel Khim. Nauk., 50 (1955); Chem. Abstr. 50:4607f (1956)

Kawal, K, and Simizu, K. , "Potential Constants for Some Nltrosyl Halldes,"Kagaku To Kogyo 29, 9 (1955)

Martin, H., and Jacobsen, Th. , "Ober die Blldung von NO^Cl bei Reaktionenzwischen Chlordioxyd und 6xyden des Stickstof f s, " Angew. Chem. 67,524 ( 1955 )

Martin, H. , and Kohnlein, E. , "Die Gas reaktion, " Angew.Chem. 67, 524 (1955)

Mi lien, D. J., and Sinnott, K, M., "The Microwave Spectrum and Structure ofNitryl Chloride," Chem. A Industry, 538 ( 1955)

Ray, J. D. , "Thermodynamics and Kinetics of the Nitrogen Dioxide Catalyzed6xidation of Nltrosyl Chloride to Nitryl Chloride, Diss. Abstr. 15 .

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Schmeisser, M. , "Die Chemie der anorganlschen Acylnitrate (ein Problem desNltry Ichlorlds ) und Acyperchlorate (ein Problem des Dichlorhexoxyds ),Angew. Chem. 67, 493 (1955)

30

1956

56 BAY/WAT Baytiss, N. S., and Watts, D. W. , The Spectra and Equilibria ofNitrosonium Ion, Ni tro-Ac idium Ion, and Nitrous Acid in Solutionsof Sulphuric, Hydrochloric, and Phosphoric Acids," Aust, J. Chem,9, 319 ( 1 956 )

56 CLA/WIL Clayton, L., Williams, Q. , and Weatherly, T. L., "Ouadrupole CouplingConstants of Nitryl Chloride," Am. Phys. Soc. Bull. J., 341 ( 1956)

56 GEN/FIN Genkina, E.V., Finkel'sbtein, A. I., and Artem'ev, A. A., "MolecularComplexes of Nitrosyl Chloride," Dokl. Akad. Nauk SS SR J.09, 528 (1956 )

56 HEP/J0H Herschbach, D. R. , Johnston, R. S., Pitzer, K. S., and Powell, R. E. , ^"Theoretical Pre- Expone nti al Factors for Twelve Bimolecular Reactions,J. Chem. Phys. 25, 736 (1956)

56 MAK/GAR Martin, H., and Gareis, R. , "Die Kinetik der Reaktion von Clegmit in der Lo esungsphas e, " Z. Elektrochem. 60, 959 (1956)

56 PIE/FLF Pierson, R. H., Fletcher, A. N., and St. Clair Gantz, E., "Catalog ofInfrared Spectra for Qualitative Analysis of Gases," Anal. Chem. 28 .

1218 ( 1956 )

56 V0L/JflH Volpe, M., and Johnston, H. S. , "Energy Transfer Processes in the UnimolecularDecomposition of Nitryl Chloride," J. Am. Chem. Soc. 78, 3903 (1956)

1 957

57 ASH/LEV Ashmore, P. G. , and Levitt, B. P., The Thermal Reaction Between Hydrogenand Nitrogen Dioxide. Part 3. Further Experimental Work on the Kinetics:Reaction Mechanism," Trans. Faraday Soc. 53, 945 (1957)

57 BEL/WIL Bellamy, L. J., and Williams, R. L., "infrared Spectra and Polar Effects.Part VI. Internal and External Spectral Relationships,"J. Chem. Soc. (London), 863 ( 1957)

57 CAS Casaletto, G. J., "Kinetics of the Thermal Decomposition of NitrylChloride at High Pressures," Diss. Abstr. ^7, 43 (1957)

57 GEI/H^T Geiseler, G. , and R&tzsch, M. , "Thermodynami sc he Eigenschaf ten desNitrylchlorids, " Z. Phys. Chem. 20^ . 138 (1957)

57 RAY/0GG Ray, J, D. , and flgg, R., A., Jr., "Kinetics of the Nitrogen Catalyzedflxidation of Nitric Oxide," J. Chem. Phys. 26, 984 (1957)

57 SCH/BR!1 Schmeisser, M., and BrSndle, K. , "CIN6^ als Ausgangsmateri al fur Acylnitrate.6ber Acylnitrate und Acylperchloriate (TV. ), " Angew. Chem. .69, 781 ( 1957)

57 SCH/FIN Schmeisser, M. , Fink. W., and Brandle, K., "Darstellung und Reaktionendes ' Chlorni trats uber Acylnitrate und Acylper chlor at e (III),"Angew. Chem. 69, 780 (1957)

57 TAN Tanaka, J., "Effects of Substituents on the Electronic Spectra of 6rganicCompounds. III. Electronic Structure and Electronic Spectra of NitrosoGroup and its Related Substances," Nippon Kagaku Zassi 78, 1647 (1957)

1 958

58 ART/STR Artem'ev, A. A., St rel ' tsova , A. A., Genkina, E. V., and Vul'fson, K. S. ,"Photochemical Reactions with Nitrosyl Chloride, Khim. Nauka i Prom.3, 629 ( 1958 )

58 C6L/GIN Collis, M. J., Gintz, F. P., Goddard, D. R., Hebdon, E. A., andMinkoff, G. J., "Nitryl Chloride. Part II. Its Preparation andthe Properties of its Solutions in Some Organic Solvents,"J. Chem. Soc. (London) 438 (1958)

58 GIN/G0D Gintz, F. P., Goddard, D. H. , and Collis, M. J., "Nitryl Chloride. Part II,The Reaction with Alkylbenzene s, " J. Chem. Soc. (London)445 ( 1958 )

31

5 8 HAR Hariharan. T. A., The Force Constants of Kitryl Chloride and NitrylFluoride," Proc. Indian Acad. Sci . A 48, 49 (1958)

58 MAR Martin, H. , " Bi Idungsreak tionen des Ni troxychlorids, " Angew. Chem.70 . 97 ( 1958 )

58 MAR/Ki=)H Martin, H. , and. Kohnlein, E., "Die Reaktion des Chlordioxyds mitNitrosylchlor id in der Gasphase, " Z. Physik, Chem. [ NF J 18,S-'S ( 1958 )

5 8 MIL/SIN Millen. D. J., and Sinnott, K. M. , "The Microwave Spectrum, Structure,and Dipole Moment of N i tryl Chi oride, " J. Chem. Soc. (London)350 ( 1958 )

58 SKI/CAD Sklens, W. E. , and Cady, G. H., "Thermal Decomposition of Fluorine Nitrate,'J. Am. Chem. Soc, 80, 5640 (1958)

58 SUT Sutton, L. E., (Scientific Editor), "Tables of Interatomic Distances andConfiguration in Molecules and Ions," Chem. Soc. Spec. Publ.No. ±i_ S6, S7 and M43 ( 1958)

1959

59 ASH/SPE Ashmore, P. G., and Spencer, M, S., "Concurrent Molecular and Chlorine AtomMechanisms in the Reversible Dissociation of Nitrosyl Chloride,"Trans. Faraday Soc. 55, 1868 (1959)

59 CLA/WIL Clayton, L. , Williams, Q. , and Weatherly, T. L., "Nitryl ChlorideMolecular Constants from Microwave Spectrum Analysis,"J. Chem. Phys. 30, 1328 (1959); Erratum, ibid 31, 554 (1959)

59 DUH/BAU Duhaut, P., and Baumgartner, P., "Etude d'un Equilibre Pho tost at ionnai re,

"

Bull, Soc, Chim. France, 154 0 ( 1959)

59 MAR/MET Martin, H., and Meise, W, , "Die Kinetik der Reaktionen des D ichlormonoxydsmit NOg vind mit 5 der Loe sungsphase, " Z. Elektrochem.63. 1 62 ( 1959 )

59 NEU Neuwirth, 6. S. , "The Photolysis of Nitrosyl Chloride and the Storageof Solar Energy," J. Phys. Chem. 63, 17 (1959)

59 NIK Nikitin, E. E. , "Calculation of the Rate Constant for the Thermal,Bimolecular Decomposition of Molecules," Zh, Fiz, Khim, 33, (1959)

59 KAY/9GG Ray, J. D. , and ©gg, R. A., Jr., "Thermodynamic Properties of NitrylChloride," J. Chem. Phys. 31, 168 (1959)

59 TAL/THS Talbot, P. J., and Thomas. J, H., "The Reaction Between Hydrogen Chlorideand Nitrogen Peroxide, Trans. Faraday Soc, 55, 1884 (1959)

1 960

60 BR.^/SCH BrSndle, K, , Schmeisser, M, , and Luttke , W., "l n frarot -Spektrum undStruktur des Ne^Cl," Chem. Ber. 93, 2300 (1960)

60 BRI Brim, W. W., "Low Frequency Vibration Rotation Bands of ND^, N6CI, andCH3CCH, " Diss. Abstr. 21, 769 (1960)

60 ERR Errede, L, A., "Simple Equations for Calculating Bond DissociationEnergies, J. Phys. Chem. 64, 1031 (1960)

60 FI>7/LEE Findl, E. , Lee, W, B. , Margerum, J. D., and McKee, W. E. , " SolarRegenerative Fuel Cell System on the Way. Regeneration and Fuel CellPhases Work Separately in Lab Tests. Next Step is to Combine Them,S. A. E. Journ., 84-87 (1960)

60 GE9 George, J. W., "Halides and Qxyhalides of the Elements of Group Vb andVib," Prog. Inorg. Chem. 2, 33 (1960)

60 LAN/FLE Landau, L. , and Fletcher, W. H., "The Infrared Spectrum and PotentialFunction of Nitrosyl Chloride," J. Mol. Spectroscopy 4, 276 (1960)

32

60 MAK/MEI Martin. H. , Melse, V.. and Engelmann. E. . " Ober die Kinetik der Reaktiondes Dichlormonoxyds mi t Stickstof fdioxyd in der Gasphase und im ±lussigenKondensat," Z. Physik. Chem. [ NF ] 24, 285 ( 1960)

60 MAR/W0H Marcus, S. J., and Wohlers, H. C, "Photolysis of Nitrosyl Chloride in theSolar Furnace," J. Sol, Energy Sci. Eng. ±, 1 (1960)

60 MCK/FIN McKee, W. E. , Findl, E., Margerium, J. D., and Lee, W. B. , "SolarRegenerative Fuel Cells," Power Sources Symp. Proc, ( 1960),Fort Monomouth, N.J.

i£6L

61 ASH/BUR

6 1 BAS/NGR

61 CAF

61 CAF/SIC

6 1 CAS/P6L

61 DEK

61 DEV/HIS

61 D6H/WIL

61 FINl

61 FIN2

61 HEU

61 KRI

61 LAR/MAR

61 LIN

6 1 LUM

6 1 MAR/weHl

61 MAR/we)H2

61 MIL/PAN

6 1 PUR/RA6

Ashmore, P. G., and Burnett, M. G,, "Thermal Decomposition of NitrosylChloride Catalyzed by Nitrogen Dioxide," Trans. Faraday Soc. 57,1315 ( 1961 )

Basco, N, and Norrish, R. G. W. , " Vi br at ionally Excited Nitric 0xideProduced In the Flash Photolysis of Nitrosyl Chloride," Nature189 . 455 ( 1961

)

Cafferata, L. F. B., "Kinetic Study of the Thermal Decomposition of theGaseous Nitryl flxychloride ( Ne^Cl )

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Univ. Nad. La Plata 3,2., 103 ( 1961 ); Chem. Abstr. 58:5068f ( 1963)

des thermischen Zerfalls von Ni troxychlor id ( NCI^Cl ),'

Z. Physik. Chem. [ NF ] a£, 188 ( 1961 )

'Die Kinetik

Cashion, J. K. , and Polanyl, J. C, Infrared Chemi lumi nescence in theSystem H N9CI," J. Chem. Phys . 3^, 600 (1961)

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63 ARV/CAFl

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7 2 CflT/WIL

7 2 DEA/HUS

72 DIJ/SCH

7 2 DUB/DEV

7 2 DUT

7 2 D0T/BUN

7 2 ENG/GAR

7 2 F0R/LIN

7 2 MAC/DEV

7 2 MAL

7 2 MAR/RflTI

7 2 MEN/MEN

7 2 NAT/H AM

72 PAU/AR0

'2 RAM/NAM

72 SER/L0B

72 SHI

Co-tton, F. A,, and Wilkinson, G,, "Advanced Inorganic Chemistry,"Inte rsc ience Publishers, (N, Y. , 1972), p. 365

Deakin, J, J., and Husain, D. , "Electronically Excited Iodine Atoms,I( 5p '*l/2*' Kinetic Study of Some Chemical Reactions by AtomicAbsorption Spectroscopy Using Time-Resolved Attenuation ofResonance Radiation at A " 206.23 nm {l[ 5p*6s( '

*"

5, 2„05p^( ^P"j^2 »" ^' Photochem. 1, 353 ( 1972/73 )

van Dijk, C. P..to Chlorine,

and Schreiner, W. C,, Process for Conversion of HCLChem. Econ. Eng. Rev, 4, 42 ( 1972)

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" C. R, Hebd. Seances.Acad. Sci. (Paris) ^4 C , 1289 ( 1972)

Dutton, M. L., "High Pressure Gas Kinetics. I: The Thermal Decompositionof Nitryl Chloride. TI: The Thermal Decomposition of NitrogenPentoxide," Diss. Abstr. Int. B 32, 6324 (1972)

Dutton, H. L., Bunker, D. L. , and Harris, H. H., "Two Familiar GasReactions at Suprahigh Pressure," J. Phys. Chem. 76, 26 14 (1972)

English, J. R., Ill, Gardner, H. C,, and Merritt, J. A., "Pulsed StimulatedEmission from N, C, CI, and F Atoms," IEEE J. Quantum Electron. QE-

8

843 (1972); see also U.S. Army Missile Command Tec. ReportRR-TR-72-5, Feb. 1972, NTIS 741 334 (1972)

Fornstedt, L., and Lindquist, S. E., "Flash Photolytic Decomposition ofNitrosyl Chloride Studied by Time -o f -Fl ight Mass Spectrometry,"Dyn. Mass Spectrom 3, 193 (1972)

MacCordlck, J., Devin, C, Perrot, R., and Rohmer, R,, "Etude des Composersdu Type M^^Cl^, 2 N©Cl (M » Zr, Hf, Th ) par Spect rosscopi e Infrarougeet Ranan," C. R. Acad. Sci. (Paris) C 274, 278 (1972)

Maloney, K. L., "A Shock Tube Study of the Thermal Decomposition of AllylIodide, Nitrosyl Bromide and Nitrosyl Chloride," Diss. Abstr. Int. B33 , 311 ( 1972)

Martin, H. , Robisch, J., Knauth, H.-D., and Prusseit, K.-G., "Kinetik^und Mechanismus der Reaktlon des Di chlormonoxids mit Nitrosylchlorid,

"

Z. Physik. Chem. [NF] 77, 227 (1972)

Men ard" Bourcin, F., Menard, J., and Henry, L., "Distribution de I'EnergieVibra tl onnelle Entre les Molecules de gaz Chlorhydrique au coura d' unefieaction Chimique. Reaction du Chlorure de Nitrosyle et de I'Hydrogene,

"

C. H. Acad. Sci. (Paris) 274 . 1134 (1972)

Natarajan, A., and Ramasamy, R. , "Generalized Mean-Square Amplitudes ofVibration & Coriolis Coupling Constants of Some Triatomic Systems,"Indian J. Pure Appl. Phys. 10, 12 (1972)

Paul, R, C, Arora, C. L, , and Malhotra, K. C., "Nature of the Complexes ofof Sulphur Trloxide ^ith Acetyl A Monochloroacetyl Chlorides, NitrosylA Nitryl Chlorides, Phosphoryl Chloride & Selenyl Chloride," IndianJ. Chen. iO, 92 (1972)

Ramaswamy, K., and Namasivayam, R. , "Molecular Constants of Some NitrogenHalogen Compounds by Green's Function Analysis. II, Acta Phys. Pol.A 41, 129 ( 1972

)

Serezhklna, L. B., Lobaqheva, M. P., Serezhkin, V. N. , Tamm, N. S. , andNovoselova, A. V., "interaction of Metallic Beryllium with LiquidMixtures of Nitrosyl Chloride and Dinitrogen Tetroxide," Suss. J.Inorg. Chem. 12,, 1678 (1972); tr . of Zh. Neorg. Khlm. 17, 3191 (1972)

Shlmanouchl, T. , "Tables of Molecular Vibrational Frequenices Part 5,"

J. Phys. Chem. Kef. Data 1, 189 (1970)

40

1973

^2 BRA/WHY Bradley, J. N., Whytock, D. A., and Zaleskl. T. A., "Electron Spin

7 3 ECK/EDE

7 3 G\V

73 JAN/ENG

73 MAL/PAL

7 3 MSV/KYA

73 RAG

7 3 SAV/LAC

7 3 SHI

7 3 SYR/GIL

7 3 TR0

73 TSA

73 VIA/AMA

73 WU

Resonance Study of the Reaction of 6( P) Atoms with Chlorine andNltrosyl Chloride," J. Chem. Soc., Faraday Trans. 69, 1251 (1973)

Eckstrom, D, J., and Edelstein, S. A., Benson, S. Wjj , Black, G. , andLurla, M,, Study of New Chemical Laser System, Stanford ResearchInstitute Tech. Report RK-CR-73-6 (SRI MP 73-15), Dec. 1973,NTIS AD 773 031 (1973)

Gavrilkin, G. N., "Radiation Sources for Preparation of lactams byPhotcnitrosation, " S ve totekhnika 8, 4 (1973); Chem. Abstr.83 :9142u ( 1975 )

Jander, J., and Engelhardt, U. , "Nitrogen Compounds of Chlorine, Bromine,and Iodine," Dev. Inorg. Nitrogen Chem. 2, 70 (1973)

Maloney, K. K., and Palmer, H. B., "Low-P ressure Thermal Decompositionof 0NBr and eNCl in Shock Waves," Int. J. Chem. Kinet. 5,1025 ( 1973 )

Movsumzade, M. M., Kyazimov, A. S. , and Sidekova, G. A.,"Ni t rosy Ichl o ri na ti on of 0xiranes," Sopryazhenno

e

Galofzen irovan ie 0lef inov Ikh Protzvodnykh Kis t orosoderz hashch imiSoedin, 129 (1973); Chem. Abstr. 84:43722 (1976)

73 PRA/KAR Pravilov, A, M. , Karpov, L. G. , Smirnova, L. G., and Vilesov, F. I.,

"The Reaction K P1/2' NfKJl I. Measurement of Quantum

Yields for the Formation of K Photolysis of CH^Iand CF^I and Ratios of Rate Constants for its Reactions,"High Energy Chen. 7, 294 (1973); tr. Khim. Vys. Energ. 7,335 ( 19^3)

Kagsdale, R. 0., "Reactions of Nitrogen (II ) 0xide, " Dev. Inorg. NitrogenChem. 2, 1 ( 1973

)

Savall, A., Lacoste, G., and Routie, R., "Mise en Evidence deI'Existence d'un Maximum d'Activite de la Decharge Electrlqueau cours de al Dissociation primaire du Chlorure de Nitrosyle dans un Champdans un Champ Electrique Alternatif," C. R, Acad. Sci. (Paris)C 277 . 603 ( 1973

)

Shimanouchi, T. , "Tables of Molecular Vibrational Frequencies,"J. Phys. Chem. Ref. Data 2, 225 (1973)

Syrvatka, B. G. and Gil'burd, M. M., "Mass- spec trome tri c Study ofTrif luoronitrosomethane," Russ. J. Phys. Chem. 47, 1215 (1973);tr. of Zh. Fiz. Khim. 47, 2146 (1973)

Troe, J., "Collisional Energy Transfer in Thermal Unimolecular Reactions,"Ber. Bunsenges. Phys. Chem. 77, 665 (1973)

Tsang, W., "Comparisons between Experimental and Calculated RateConstants for Dissociation and Combination Reactions InvolvingSmall Polyatomic Molecules," Int. J. Chem. Kinet. 5, 947 (1973)

Viard, B., Amaudrut, J., Devin, C, "Action du Chlorure de Nitrosylesur l'0xydichlorure de Titane," C. R. Acad. Sci. (Paris) C276, 1279 ( 1973 )

Wu, T.-l., "Kinetics of the Photochemical Reaction of Nitrosyl Chlorideto Ethylene and 1 -butene in the Gas Phase," Diss. Abstr. Int. B 33 .

3568 ( 1973

)

7 4 BAL/ARM

74 BAL/B0L

74 CHR/SCH

1974

Ballash, N. M. , and Armstrong, D. A,, "0n the Ultraviolet and VisibleAbsorption Spectrum of CIN0," Spectrochim. Acta 30 A, 941 (1974)

Balzani, V., Bolletta, F., Moggi, L., and Gleria, M, " Trasformazi oneFotochimica Delia Energia Solare Mediante Sistemi non Biologici,Parte Seconda; Esame critico dei sistemi proposti,Chim. Ind. (Milan) 56, 115 (1974)

Christe, K. 0., Schack, C. J., and Wilson, R. D., "Halogen Nitrates,"Inorg. Chem. 13, 2811 (1974)

41

^4 DEJ/HEU De Jaeger, R. D. , and Heubel, J,, "Etude Conduc time trique de la Seactionde NGCL sur Sfl^ Dans SGg Llqulde a -20°C," J. R, Neth. Chem. Soc, 93 .

74 DUB/CAB

74 ECK/EDE

7 4 GUR/KAR

74 H6E/WAD

74 KAR/PRAl

74 KAR/PRA2

74 KH0/Rez

7 4 KNA/MAR

74 NAZ/POL

74 P0I/KEF

74 SCH/CH8

74SCH/UR9

7 4 SHA/YEL

^4 TSE/DR61

74 TSE/DR02

74 V6R/FIL

74 WIL

63 ( 1 974 )

Dubois, C, , Cabala, H,, and Devin, C. , "Mise au Point d'une Cellule PourL'etude de la Di*±raction des Kayons X, a Basse Temperature ( -180°C)et Sous la Presslon Atmosphe r ique ,

" C» R. Acad. Sci. (Paris) C278, 781 ( 1974)

Eckstrom, D. J., Edelstein, S. A., and Benson, S. W. , " ChemiluminescencePhoton Yields for Several Alkaline Earth Metal -Halogen/6xygenReactions," J. Chem. Phys. ^0, 2930 (1974)

Gurvich, L. V., Karachevtsev, G. V., Kondratieu, V. N. , Lebedev, Y. A.,Medvedev, V. A., Potapov, V. K. , and Khodeev, Y. C., "EnergiiHazryva Chimicbeskich Svyazei. Potentsialy lonizatsii iSrodstvo k Elektronu," Akad . Nauk SSSR, Moscow, 113 (1974)

Hoell, J. M., and Wade, W. S. , "Relative Cross Section and Depolarizationof N0CI," Appl. Phys. Lett. £5, 202 (1974)

Karpov, L, G., Pravilov, A. M, , and Vilesov, F. I., "The ReactionsI(^Pj^2> * N0CI II. Capture of CF ^ Radicals and

Deactivation of 1(2^1/2 ^^-^ Nitric 0xide in the Photolysis

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Khim. Vys. Energ. 8, 483 (1974)

Karpov, L. G. , Provilov, A. M, , and Vilesov, F. and T,, Primary-Processes in the Photolysis 1 -I odop ropane and 2-1 odooropane

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High Energy Chem. 8, 420 (1974); tr . of Khim. Vys. Energ.8, 489 ( 1974 )

Khodeeva, S. M. , and Rozovskii, M. B., "Liquid Phase in theCarbon Te trachloride-Cyclododecanone 6xime Hydroc hloride

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Hydrogen Chlo ride- Nitrosyl Chloride System," Tr. N.-i.i proekt. in-ta azot. prom-sti 23, 13 (19''4); ChemAbstr. 83:12ie68-w (1975)

Knauth, H.-D., Martin, H., and Stockmann, W. , "Bestimmung derBi Idungsentha Ipie von Ni troxychlorid ( Chlorni t rat , Nfl^Cl) alsBeitrag zur Deutung der Kinetik des Thermischen Nfl^Cl -Ze rfall

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Nazar, M. A., Polanyi, J. C. , and Skrlac, W. J.,among Reaction Products. H N0CI, H ICl,473 ( 1 974 )

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Schack, C. J., and Christe, K. 6., "Reactions of 0zone with CovalentHypohalites, " Inorg. Chem. 1_3, 2378 ( 1974)

Schroeder, W. H., and Orone, P., "Formation of Nitrosyl Chloride fromSalt Particles in Air," Environ. Sci. Technol. 8, 756 (1974)

Shamir, J., Yellin, D., and Claassen, H. H., "Laser Raman Spectra euidStructure of Halogen Nitrates ( F0N02 and Cl<5N62)," Israel J. Chem. 1

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Tseitlin, A. N. , and Drozhina, D. N. , "Oxidation of Nitrosyl Chlorideby Nitric Acid," Vestn. Khar'k. Politekh. Inst. No . 91 . 9 (1974);Chem. Abstr. 83:16379e (1975); see also Sheitlin

Tseitlin, A. N. , Drozhina, D. N. , Ravkina, S. B., and Lavrik, L. D.,"6xidation of Nitrosyl Chloride, Vestn. Khar kov. Politekhn Inst.No. 98 . 48 (1974); Chem. Abstr. 83:125538b (1975); see also Sheitlin

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Wilkins, R. A., Jr., "The Kinetics of Nitrosyl Chloride Qxidation byDenitrogen Pentoxide in the Presence and Absence of Nitric Acid,Diss. Abstr. Int. B 35, 174 (1974)

42

74 WIL/DOD

7 5 AM^/FLE

7 5 BEC/FIC

75 BER/aec

75 BER/PEN

75 BRA/TIC

7 5 CAZ/CER

7 5 CHA/CUR

7 5 Cfle/PRI

7 5 DEG/KAC

75 D0R/SCH

75 DUB/AMA

75 FIL/FflR

7 5 FR0/LEE

75 GAL/0ST

7 5 HAB/SCH

7 5 KHe/R0Z

75 KIR/SPR

Wilkins, R. A., Jr., DodgCj M. C, and Hisatsune, I. C. , "Kinetics ofNitric flxide Catalyzed Decomposition of Nitr^i Chloride and itsRelated Nitrogen Isotope Exchange Reactions, J. Phys. Chem.78 . 2073 (1974)

1975

Amos, D. W. , and Flewett, G, W. , "Raman Spectrum of Chlorine Nitrate,"Spectrochim. Acta A 31, 213 (1975)

Beck, W., Fick., H. G. , Lottes, K. , and Schmidtner, K. H., "Darstellungund Seaktionen von Dichlorotrini trosyl vanadin, " Z, Anorg. Allg. Chem.416 . 97 ( 1975 )

Bergmann, H. , and Bock, H,, "Photoe lec tron Spectra and MolecularProperties. XLVI, Nitroso Compounds - Electron-rich Molecules,"Z. Naturforsch. B 30, 629 (1975)

Bernard, J. M, , and Penner, S. S., "Anomalous Transparency in NitrosylChloride," J. Quant. Spectrosc. Radiat. Transfer 15» ^57 (1975)

Bravo, P., and Ticozzl, C, "The Reaction of Enamines with NitrosylChloride and Ke to-Stabili zed Sulphonium Ylids: A New Synthesis ofIsoxazoles," Gazz. Chim. Ital. 1 05 . 91 ( 1975)

Cazzoli, G. , Cervellati, R,, and Mirri, A. M,, "Rotational Spectrumof 0NCL in the (0,0,1) and (0,1,0) Vibrational States and 'b'Type Spectrum in the Ground State. Comparison of Force Fieldflbtained by Different Combinations of Experimental Data,"J. Mol. Spectroscopy 56, 422 (1975)

Chase, M. W., Curnutt, J. L. , Prophet, H,, McDonald, R, A., andSjrverud, A. N., "JANAF Thermochemic al Tables, 1975 Supplement,"J. Phys. Chem. Ref. Data 4, 65 (1975)

Coombe, R. D., Pritt, A. T., Jr., and Pilipovich, D., "CollisionalRelaxation of HCl(v-l) by Selected Polyatomic Molecules," Chem. Phys.Lett. 35, 349 ( 1975 )

Degtyareva. A. A., Kachan, A. A., Luk'yanchuk , L, F., and Shrubovlch,V. A., Photochemical Interaction of Nitrosyl Chloride with Polyethylene,"Vysokomol. Soedin., H, 532 ( 1975); Chem. Abstr. 83:18016f (1975)

Dorko, E. A., Scheller, U . G., and Mueller, G. W. , "Shock TubeDecomposition of Dilute Mixtures of Nitrosyl Chloride in Argon,"J. Phys. Chem. 79, 1625 (1975)

Dubois, C. , Amaudrut, J., and Devin, C., "Use of Powder Diagramsin Studying the Products Formed by the Action of NitrosylChloride on Some Titanium Trichloride Monoalkanoates,

"

Bull. Soc. Chim. France, 1597 ( 1975)

Filgueira, R. R., Forti, P., and Corbelll, G,, "Microwave Spectrum andMolecular Force Field of Tetratomlc C^v Molecules: NQgCl,"J. Mol. Spectroscopy 57, 97 (1975)

Frost, D, C. , Lee, S, T., McDowell, C. A., and Westwood, N. P. C. ," Photoe lectron Spectroscopic Studies of Some Nitrosyl and NitrylHalides and Nitric Acid," J. Electron Spectres. Relat. Phenom. 7,331 ( 1 975 )

Gale, R. J., and flsteryoung, R. A., "Dissociative Chlorination ofNitrogen 0xides and 6xy Anions in Molten Sodium Chloride -AluminumChloride Solvents," Inorg. Chem. 14, 1232 (1975)

Haberland, H., and Schmidt, K. , "Reactive Scattering of Hydrogen andDeuterium Atoms. III. Angular Distributions for ClNa, SClg. S^CX^,seclg and CIF3," Chem. Phys. 10, 33 (1975)

Khodeeva, S. M. , and Sozovskii , M. B., "The Liquid-Gas Equilibria inthe Hydrogen Chlo ride -Carbon Tetrachloride and Nitrosyl Chloride-Carbon Tetrachloride Systems," Russ . J. Phys. Chem. 49, 824 ( 1975);tr. Zh. Fiz. Khim. 49, 1396 (1975)

Kirchmeier, R. L., Sprenger, G. B., and Shreeve, J. M. , "( CFgNCl )2, A

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43

7 5 LAZ/GAV

75 LEG/MAL

7 5 MAL/KAT

75 MARl

75 MARS

75 MEB/PAN

7 5 R0G/DEM

7 5 R0G/VIT

75 SCH/CHR

75 SPT/SPE

75 ST9

7 5 V0L/SCH

75 WAT/MARl

75 WAT/MAR2

75 WIL

75 YAR/N6F

Lazareva, M. P., Gavrilkina, G. N., Sarychev, G, S, , Gromoglasov, Y. A,,Levashova, L. A,, and Karchlkhina, V. V,, "Quantum Efticlency of -thePhotoni t rosat ion of Cyclododecane ,

" Russ. J. Phys. Chem. 4-9,529 (1975); tr. of Zh. F Iz . Khim. 49. 904 (1975)

Legzdins, P., and Malito, J. T., "©rganometallic Nitrosyl Chemistry,I, Reactions of Nitrosyl Chloride with Some Anionic and NeutralCarbonyl Complexes," Inorg. Chem . J_4, 1875 ( 1975)

Redox Reactions in Acetic Anhydride,Malhotra, K. C, and Katoch, D. S.,Aust. J. Chem. 28, 991 (1975)

Markowicz, S. W. , "Determination of Structure of 'By' -P roduc t in theReaction of o-Pinene with Nitrosyl Chloride, Rocz. Chem. 4921 1 7 ( 1975 )

Marsh, P, 'The Reaction Between Nitrosyl Chlorine and P henylmagnes iumBromide, Diss. Abstr. Int. B 35, 3838 (1975)

Mehta, G., and Pandey, P. N,, "Stereochemistry and Mechanism ofEl ectrophili c Additions to Tr icyc lo[ 4 . 2 . 2

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Rogic, M. M., Demmin, T. H,, Fuhrmann, R., and Koff , F. W, , " Homo speci f i

c

and Heterospeci f ic Dimerization of Nitroso Compounds. The ControversySurrounding the Nature of the 2 -Chloroni t roso cyclohexane Diraer flbtainedby Addition of Nitrosyl Chloride to Cyclohexane," J. Am, Chem. Soc, 97,3241 (1975)

Rogic, M, M,, Vitrone, J., and Swerdloff, M, D. , "Nitrosation in 6rganicChemistry, Ni tro solysi s, a Novel Carbon -Car boji Bond Cleavage Effectedthrough Nitrosation. Nitrosolysis of Ketones, J. Am. Chem. Soc. 97,3848 ( 1975 )

Schultes, E., Christodoulides, A. A., and Schindler, R. N., "Studies by theElectron Cyclotron Resonance (ECR) Technique, VIII. Interactions oflow-energy electrons with the chlori ne -containing molecules CCl^, CHCl^,CHgClg, CjjHg^^jCK n-1 to 4), CgHjCl , COClg, N9CI, CNCl and Clg,"Chem. Phys. 8, 354 (1975)

Spirko, v., and Speirs, G, K, , "The Application of the Monte Carlo Method toAnharmonic Force Constant Calculations The Anharmonic PotentialFunctions of ONF, CNCl, 9NBr," J, Mol , Spectroscopy 55, 151 (1975)

Stogard, A,, "Molecular 6rbital Interpretation of X-ray Emission Spectra ofCICN and 6NCI," Chem, Phys, Lett, 36, 357 (1975)

Volgnandt, P., and Schmidt, A,, "The Reaction of Alkyl Azldeswith Nitrosyl Chloride and Antimony( V) Chloride," Z, Naturforsch, B 3 0 .

295 ( 1975 )

Waters, W, L., and Marsh, P, G, , "Reaction of Nitrosyl Chloride withPhenylmagnesium Bromide," J, 6rg. Chem. ±0, 3344 (1975)

Waters, W, L, , and Marsh, P, G,, "Synthesis of Symmetrical Diarylamines, " i

J, 0rg, Chem, 40, 3349 (1975)|

Williams, D, L, H,, "Kinetics and Mechanism of the Fischer-Hepp Rearrangemen'Jand Deni trosa ti on. Part VI. The Relative Reactivity of a Number ofNitrogen-containing Species towards Nitrosation, and Further Evidence '

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I

Yarbro, S. K,, Noftle, R, E., and Fox, W, B. , "The Reaction of Nitryl|

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i

76 A3B/DYK Abbas, M, I,, Dyke, J. M., and Morris, A., "Photo el ectron Spectrum ofNitrosyl Chloride, J, Chem Soc. Faraday Trans, II 22, 814 (1976)

76 AMI/KEF Amirova, S, A,, Kefer, R, G, , Shuster, Ya, A,, and Pfefer, £, fi,,

"Liquid - Vapor Equilibrium in the Binary Systems Chlorine -

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76 AUS/BAK Austigard, B, , and Bakke, J. M, , "A New flne Step Synthesis of Diazooctanefroir flctylamine," Acta Chem. Scand. B 30, 274 ( 1976)

44

76 BIR/JES Birks, J. B. , Jesson, J. P., Glasgow, L. C, and Young, R. A,"Solar Photodissociatlon Rates of C l6Ne2 . CIN62 and C10^,1 2 th Informal Conference on Pho +ocheioistry, Ga i t hersburg ,

MD. ( 1976 )

76 GIL/SCH

76 HIP/TR0

76 ILL/TAK

76 ISA/GAS

76 KYU/CLA

76 MIR/P6V

76 R6W/SPE1

76 R0W/SPE2

76 SAV/BES

7 6 SCH

7 6 SER/LEE

76 sxe

76 SUE/J0H

76 ves

Gllberg, E. , Schatzl. W. , and Schrenk, H. W, , "fln the Electronic Structureof CNCl and N9CI, Chem Phys. 13, 115 (1976)

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Kyung, J. H. and Clapp, L. B. , "Pathway Control of Products in the Reaction6f Nitrosyl Chloride on 6ximes, " J. Grg. Chem. 41, 2024 (1976)

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Savall, A., and Bes, R. , "Study of the Mass Spectrum of Nitrosyl Chloride,'Analusis, 4, 8 (1976); Chem. Abstr. 85:12797h (1976)

Schweiger, R. G. , "Nitrite Esters of Polyhydroxy Polymers," J. 0rg.Chem. 41, 90 (1976)

Sergeev, G. A., Leenson, L. A., Movsumzade, M. M. , Shabanov, A. L. , andSidakova, G. A., "Kinetics and Mechanism of Reaction of a-Sxideswith Nitrosyl Chloride," Zh. erg. Khim. 12, 506 (1976); Chem.Abstr. 85:45728q (1976)

St^gard, A., "AB Initio Calculations on ClCN and GNCl," Chem. Phys,Lett. 40, 429 (1976)

Suenram, R. S. , Johnson, D. R., Glasgow, L. C, and Meakin, P. Z.,"Laboratory Microwave Spectrum of CI6N62," Geoohys. Res. Lett,3, ( 1976 ); Erratum, ibid 3, 758 ( 1976)

Voss, K, E. , "The Reaction of Potassium ^c tachlo rodimolybdat e( 1 1 ) withNitrosyl Chloride in Ethyl Acetate," Diss. Abst. Int. 36, 3378 (1976)

45

1222

77 GRA/TUA Graham, S. A., Tuazon, E. C, Winer, A. M. , Pitto^ J. N., Jr.,Molina, L. T., Beatnan, L, , and Molina, M. J., High ResolutionInfrared Abs orptl vl tl e s for Gaseous Chlorine Nitrate, Geophys.Res. Lett. 4, 3 (1977)

KUR/MAN Kurylo, M. J., and Manning, R. G. , "Flash Photolysis ResonanceFluorescence Investigation of the Reaction of CI ( P) Atomswith ClGNeg," typescript, Phys. Chem. Div., Natl. Bureau ofStandards, Washington, D. C. 20234 (1<?77)

77 M9I- Molina, J. J«, "Absorption Cross Section and Quantum Yields, " typescriptDept. Chem., University of California, Irvine (1977)

77 M0L/M9L Molina, L. T., and Molina, M. J., "Ultraviolet Absorption Spectrumof Chloride Nitrite, CWNe," Geophys. Res. Lett. 4, 83 ( 1977)

77 M9L/SPF Molina, L. T., Spencer, J. E., and Molina, M. J., "Rate Constantfor the Reactions 9( "^P ) Atoms with C16N92," Chem. Phys. Lett.45 . 158 ( 197 7 )

77 RAV/DAV Ravishankara, A. B., Davis, D. D., Smith, G., Tesi, G., andSpencer, J., "A Study of the Chemical Degradation ofClON^g in the Stratosphere," Geophys. Res. Lett. 4, 7 (1977)

'7 SMI/CHe Smith, W. S., Chou, C. C, and Rowland, F. S. , "Photolysis ofChlorine Nitrate at 302. 5nm," 173rd Am. Chem. Soc. NaturalMeeting, New erleans Phys. -14 (197^)

46

LIST 6F ABBBEVIATIflNS

Abbr ev ia-t ions for Data FlaggingFourth Interim lUPAC List

AB Absorption Cross Section

BE Bond Energy, Atomization Energy, Dissociation Energy

B0 Bond Angle, Bond Length

BT Boiling Temperature (Boiling Point)

CD Critical State Data (Critical Density, Critical Temperature,Critical Pressure)

DC Dielectric Constant

DM Dielectric Properties (Electric Dipole Moment, MolecularPolarization Quadrupole Coupling Constant)

DN Density Data (Density, Specific Density)

EN Entropy

EO Equilibrium Data (Equilibrium Constant)

ET Enthalpy (Heat of Vaporization, Heat of Sublimation,Heat of Keaction)

HC Beat Capacity

IP Ionization Potential, Electron Affinity

IRS Infrared Spectrum

MG Magnetic Data, (Magnetic Dipole (and Higher) Moments,Magnetic Susceptibility)

ML Molecular Energy Level, Rotational and VibrationalConstants, Force Constant, Moment of Inertia

MSS Mass Spectrum

MT Melting Temperature (Melting Point)

MWS Microwave Spectrum

NMS Nuclear Magnetic Resonance Spectrum

QY Quantum Yield (and Quantum Efficiency)

RAS Raman Spectrum

RD Sadll (Atomic, Ionic, Molecular, Molecular Volume,Molecular Diameter, Molecular Cross Section)

RR Reaction Rate Data (Rate Constant, Relaxation Time,Half- life )

ST Surface Tension

TC Thermal Conductivity

TE Thermodynamic Energy Data (Gibbs Free Energy,Helmholtz Energy, Thermodynamic energy functions)

UVS Ultraviolet Spectrum

VIS Visible Spectrum

VP Vapor Pressure (Sublimation Pressure)

VS Viscosity Data

XPS X-ray Photoe I ectron Spectrum

XRS X-ray Spectrum

47

Descriptive Terms

CXc Calculation

Dec Decomposition

For from: Formation from another compound

Mec Mechanism

Pbl Photolysis

Rad Radiation

Rev Review

Rip Related Paper

Rxn with: Reaction with other compounds

Syn Synthesis (preparative methods)

Thp Theoretical Paper

4S

NOTE ADDED IN PROOF

Part III

Chlorine Nitrate

Chemistry and Chemical Kinetics

77 BIR/SHO RR, For from

77 LEU/LIN RR, For from

77 ZAH/CHA RR, For from

do and NO2, Rxn with: HC-t, NO, NO2, 0,

do and NO2

do and NO , Rxn with: OH

Part IV

References

1977

77 BIR/SHO Birks, J. W. , Shoemaker, B., Leek, T. J., Borders, R. A., andHart, L. J., "Studies of Reactions of Importance in the Stratosphere,II. Reactions Involving Chlorine Nitrate and Chlorine Dioxide,"J. Chem. Phys. (1977) (in press)

77 LEU/LIN Leu, M. T., Lin, C. L., and DeMoore, W. B., "Rate Constant for Formation

of Chlorine Nitrate and by the Reaction dO + NO^ + M," J. Phys.

Chem. 81, 190 (1977)

77 ZAH/CHA Zahniser, M. A., Chang, J. S., and Kaufman, F. , "Chlorine Nitrate:Kinetics of Formation by dO + T>iO^ + M and of Reaction with OH,"

J. Chem. Phys. (1977) (submitted)

<t U. S. GOVERNMENT PRINTING OFFICE: 1 977--2'*0-81t8/277

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4. TITLE AND SUBTITLE 5. Publication Date

NITROGEN OXYCHLORIDES: August 1977A Bibliography on Data for Physical and Chemical

Properties of ClNO, ClNO^, and ClNO^6. Performing Organization Code

7. AUTHOR(S)Francis Westley

8. Performing Organ. Report No.

9. PERFORMING ORGANIZATION NAME AND ADDRESS

NATIONAL BUREAU OF STANDARDSDEPARTMENT OF COMMERCEWASHINGTON, D.C. 20234

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I SP 1874 - 1977

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Library of Congress Catalog Card Number: 77-2757

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bibliography or literature survey, mention it ftere.)

A data oriented list of references is provided for published papers and reportscontaining measured or calculated data for the physical and chemical propertiesof nitrosyl chloride, nitryl chloride, and chlorine nitrate with particularemphasis on the chemistry and chemical kinetics of these compounds. More than

387 papers are listed. The period covered extends from 1874 through 1977.

17. KEY WORDS (six to twelve entries; alphabetical order; capitalize only the first letter of the first key word unless a proper

name; separated by semicolons

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Bibliography; chemical kinetics; chemistry; chlorine nitrate; molecular properties;nitrosyl chloride; nitryl chloride; physical properties; spectral properties;thermodynamic properties

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