0.00 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16 [a] (m)ekwan/pdfs/29 - applications...0.00 0.02 0.04...

0.00 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16 0.0 5.0x10 -7 1.0x10 -6 1.5x10 -6 2.0x10 -6 2.5x10 -6 rate (M s -1 ) [A] (M) experiment 1 experiment 2

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0.00 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16

0.0

5.0x10-7

1.0x10-6

1.5x10-6

2.0x10-6

2.5x10-6

rate

s-1)

[A] (M)

experiment 1

experiment 2

Page 2: 0.00 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16 [A] (M)ekwan/pdfs/29 - Applications...0.00 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16 0.0 5.0x10-7 1.0x10-6 1.5x10-6 2.0x10-6 2.5x10-6 s-1)

Page 3: 0.00 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16 [A] (M)ekwan/pdfs/29 - Applications...0.00 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16 0.0 5.0x10-7 1.0x10-6 1.5x10-6 2.0x10-6 2.5x10-6 s-1)

Page 4: 0.00 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16 [A] (M)ekwan/pdfs/29 - Applications...0.00 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16 0.0 5.0x10-7 1.0x10-6 1.5x10-6 2.0x10-6 2.5x10-6 s-1)

Page 5: 0.00 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16 [A] (M)ekwan/pdfs/29 - Applications...0.00 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16 0.0 5.0x10-7 1.0x10-6 1.5x10-6 2.0x10-6 2.5x10-6 s-1)

Page 6: 0.00 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16 [A] (M)ekwan/pdfs/29 - Applications...0.00 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16 0.0 5.0x10-7 1.0x10-6 1.5x10-6 2.0x10-6 2.5x10-6 s-1)

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Page 8: 0.00 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16 [A] (M)ekwan/pdfs/29 - Applications...0.00 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16 0.0 5.0x10-7 1.0x10-6 1.5x10-6 2.0x10-6 2.5x10-6 s-1)

Page 9: 0.00 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16 [A] (M)ekwan/pdfs/29 - Applications...0.00 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16 0.0 5.0x10-7 1.0x10-6 1.5x10-6 2.0x10-6 2.5x10-6 s-1)

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increasing kdeact

0.00 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16

0.0

5.0x10-7

1.0x10-6

1.5x10-6

2.0x10-6

2.5x10-6

rate

s-1)

[A] (M)

experiment 1

experiment 2

0.00 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16

0.0

5.0x10-7

1.0x10-6

1.5x10-6

2.0x10-6

2.5x10-6

rate

s-1)

[A] (M)

experiment 1

experiment 2

0 200000 400000 600000 800000 1000000

0.0000

0.0002

0.0004

0.0006

0.0008

0.0010

nce

ntr

atio

n (

time (s)

free catalyst

catalyst bound to A

dead catalyst

0.00 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16

-2.0x10-7

0.0

2.0x10-7

4.0x10-7

6.0x10-7

8.0x10-7

1.0x10-6

1.2x10-6

1.4x10-6

1.6x10-6

te (

M s

-1)

[A] (M)

experiment 1

experiment 2

0.00 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16

-2.0x10-7

0.0

2.0x10-7

4.0x10-7

6.0x10-7

8.0x10-7

1.0x10-6

1.2x10-6

1.4x10-6

1.6x10-6

1.8x10-6

2.0x10-6

2.2x10-6

2.4x10-6

rate

s-1)

[A] (M)

experiment 1

experiment 2

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