1 chemistry: atoms first julia burdge & jason overby copyright (c) the mcgraw-hill companies,...
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Chemistry: Atoms FirstJulia Burdge & Jason Overby
Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
Chapter 1Chemistry:
The Science of Change
Kent L. McCorkle
Cosumnes River College
Sacramento, CA
Homework: 5, 9, 15, 17, 23,25, 27, 31,37, 29, 43, 45, 47, 49, 51, 53, 55, 57, 59, 61, 63, 65, 67, 69,71, 73, 75, 77 and 79
Chemistry: The Science of ChangeChemistry: The Science of Change1
1.1 The Study of Chemistry Chemistry You May Already Know The Scientific Method1.2 Classification of Matter States of Matter Mixtures1.3 The Properties of Matter Physical Properties Chemical Properties Extensive and Intensive Properties 1.4 Scientific Measurement SI Base Units Mass Temperature Derived Units: Volume and Density
1.5 Uncertainty in Measurement Significant Figures Calculations with Measured Numbers Accuracy and Precision
1.6 Using Units and Solving Problems Conversion Factors
Dimensional Analysis Tracking Units
The Study of ChemistryThe Study of Chemistry
Chemistry is the study of matter and the changes that matter undergoes.
Matter is anything that has mass and occupies space.
1.1
The Study of ChemistryThe Study of Chemistry
Scientists follow a set of guidelines known as the scientific method:
• gather data via observations and experiments
• identify patterns or trends in the collected data
• summarize their findings with a law
• formulate a hypothesis
• with time a hypothesis may evolve into a theory
Classification of MatterClassification of Matter
Chemists classify matter as either a substance or a mixture of substances.
A substance is a form of matter that has definite composition and distinct properties.Examples: salt (sodium chloride), iron, water, mercury, carbon dioxide, and oxygen
Substances differ from one another in composition and may be identified by appearance, smell, taste, and other properties.
1.2
A mixture is a physical combination of two or more substances.
A homogeneous mixture is uniform throughout. Also called a solution. Examples: seawater, apple juice
A heterogeneous mixture is not uniform throughout. Examples: trail mix, chicken noodle soup
Classification of MatterClassification of Matter
All substances can, in principle, exist as a solid, liquid or gas.
We can convert a substance from one state to another without changing the identity of the substance.
Classification of MatterClassification of Matter
Solid particles are held closely together in an ordered fashion.
Liquid particles are close together but are not held rigidly in position.
Gas particles have significant separation from each other and move freely.
Solids do not conform to the shape of their container.
Liquids do conform to the shape of their container.
Gases assume both the shape and volume of their container.
Classification of MatterClassification of Matter
A mixture can be separated by physical means into its components without changing the identities of the components.
The Properties of MatterThe Properties of Matter
There are two general types of properties of matter:
1) Quantitative properties are measured and expressed with a number.
2) Qualitative properties do not require measurement and are usually based on observation.
1.3
The Properties of MatterThe Properties of Matter
A physical property is one that can be observed and measured without changing the identity of the substance.Examples: color, melting point, boiling point
A physical change is one in which the state of matter changes, but the identity of the matter does not change.Examples: changes of state (melting, freezing, condensation)
The Properties of MatterThe Properties of Matter
A chemical property is one a substance exhibits as it interacts with another substance.Examples: flammability, corrosiveness
A chemical change is one that results in a change of composition; the original substances no longer exist.
Examples: digestion, combustion, oxidation
The Properties of MatterThe Properties of Matter
An extensive property depends on the amount of matter.Examples: mass, volume
An intensive property does not depend on the amount of matter.Examples: temperature, density
Scientific MeasurementScientific Measurement1.4
Properties that can be measured are called quantitative properties.
A measured quantity must always include a unit.
The English system has units such as the foot, gallon, pound, etc.
The metric system includes units such as the meter, liter, kilogram, etc.
SI Base UnitsSI Base Units
The revised metric system is called the International System of Units (abbreviated SI Units) and was designed for universal use by scientists.
There are seven SI base units
Units in Measurements
Taylor 2010
Factor Prefix Symbol
1 x 106 Mega M
1 x 103 Kilo k
the base units grams (g) meters (m) Moles (mol) volume (L)
1 x 10-2 centi c
1 x 10-3 milli m
1 x 10-6 micro
1 x 10-9 nano n
1 x 10-12 pico p
MassMass
Mass is a measure of the amount of matter in an object or sample.
Because gravity varies from location to location, the weight of an object varies depending on where it is measured. But mass doesn’t change.
The SI base unit of mass is the kilogram (kg), but in chemistry the smaller gram (g) is often used.
1 kg = 1000 g = 1×103 g
Atomic mass unit (amu) is used to express the masses of atoms and other similar sized objects.
1 amu = 1.6605378×10-24 g
TemperatureTemperature
There are two temperature scales used in chemistry:
The Celsius scale (°C) Freezing point (pure water): 0°C Boiling point (pure water): 100°C
The Kelvin scale (K) The “absolute” scale Lowest possible temperature: 0 K (absolute zero)
K = °C + 273.15
Normal human body temperature can range over the course of a day from about 36°C in the early morning to about 37°C in the afternoon. Express these two temperatures and the range that they span using the Kelvin scale.
Worked Example 1.1Worked Example 1.1
Strategy Use K = °C + 273.15 to convert temperatures from Celsius to Kelvin.
Solution 36°C + 273 = 309 K37°C + 273 = 310 K
What range do they span?310 K - 309 K = 1 K
Depending on the precision required, the conversion from °C to K is often simply done by adding 273, rather than 273.15.
Think About It Remember that converting a temperature from °C to K is different from converting a range or difference in temperature from °C to K.
The Fahrenheit scale is common in the United States. Freezing point (pure water): 32°C Boiling point (pure water): 212°C
There are 180 degrees between freezing and boiling in Fahrenheit (212°F-32°F) but only 100 degrees in Celsius (100°C-0°C).
The size of a degree on the Fahrenheit scale is only of a degree on the Celsius scale.
TemperatureTemperature
Temp in °F = ( ×temp in °C ) + 32°F
5
9
5
9
A body temperature above 39°C constitutes a high fever. Convert this temperature to the Fahrenheit scale.
Worked Example 1.2Worked Example 1.2
Solution Temp in °F = ( × 39°C ) + 32°F
Temp in °F = 102°F
Think About It Knowing that normal body temperature on the Fahrenheit scale is approximately 98.6°F, 102°F seems like a reasonable answer.
Temp in °F = ( × temp in °C ) + 32°F5
9
5
9
Strategy We are given a temperature and asked to convert it to degrees Fahrenheit. We will use the equation below:
Taking Measurements
Taylor 2010
While Erlenmeyer flasks and beakers have volume markings, those Markings are only approximations and should NEVER be used for taking measurement readings
Taking Measurements
Taylor 2010
Graduated cylinders are moderately accurate and are primarily what we use in the laboratory for measuring volumes of liquids
Taking Measurements
Taylor 2010
Burettes, Pipettes and volumetric flasks are the most accurate way to make solutions and to measure volumes. However, they tend to be more difficult to use than graduated cylinders.
Taking Measurements
Taylor 2010
You want to read the volume of solution at the meniscus and you may need to get down to eye level with the graduated cylinder to read the meniscus properly.
Uncertainty in MeasurementUncertainty in Measurement
An inexact number must be reported so as to indicate its uncertainty.
Significant figures are the meaningful digits in a reported number.
The last digit in a measured number is referred to as the uncertain digit.
When using the top ruler to measure the memory card, we could estimate 2.5 cm. We are certain about the 2, but we are not certain about the 5.
The uncertainty is generally considered to be + 1 in the last digit.
2.5 + 0.1 cm
Uncertainty in MeasurementUncertainty in Measurement
When using the bottom ruler to measure the memory card, we might record 2.45 cm.
Again, we estimate one more digit than we are certain of.
2.45 + 0.01 cm
Taking Measurements
Taylor 2010
Which piece of glassware would you use to get the most accurate measured value?
Beaker
or
Graduated cylinder
Taking Measurements
Taylor 2010
Let’s consider the significant figure value we would obtain?
What is our certain measured value?
What is our estimated value ?
10
13
Taking Measurements
Taylor 2010
Let’s consider the significant figure value we would obtain?
What is our certain measured value?
What is our estimated value ?
13.5
13.51
Taking Measurements
Taylor 2010
Which piece of glassware would you use to get the most accurate measured value?
Beaker
or
Graduated cylinder
Significant Figures
Taylor 2010
• Why?– To show the certainty in a measured value– To indicate the margin of error when
measuring
• How?– Report all known values– Estimate one value past what’s given
Significant Figures Rules
Taylor 2010
•Any digit that is not zero is significant
1.234 kg 4 significant figures
•Zeros between nonzero digits are significant
606 m 3 significant figures
•Zeros to the left of the first nonzero digit are not significant
0.08 L 1 significant figure
•If a number is greater than 1, then all zeros to the right of the decimal point are significant
2.0 mg 2 significant figures
•If a number is less than 1, then only the zeros that are at the end and in the middle of the number are significant
0.00420 g 3 significant figures
Significant Figures Rules
Taylor 2010
•Any number that has zeros after the digits and no decimal point according to Tro may have an infinite number of significant figures
•However, there is considerable number of scientists who believe that zeros that come after the digits when a decimal point is not present are considered to be NOT significant
•For example the number 54, 000 would have infinite or 2 significant figures where as 54, 000. would have 5
Significant Figures
Taylor 2010
How many significant figures are in each of the following measurements?
24 mL 2 significant figures
3001 g 4 significant figures
0.0320 m3 3 significant figures
6.4 x 104 molecules 2 significant figures
560 kg 2 significant figures
Significant Figures
Taylor 2010
How many significant figures are there in 1.3070 g?
A. 6
B. 5
C. 4
D. 3
E. 2
Ans: B
Determine the number of significant figures in the following measurements: (a) 443 cm, (b) 15.03 g, (c) 0.0356 kg, (d) 3.000×10-7 L, (e) 50 mL, (f) 0.9550 m.
Worked Example 1.4Worked Example 1.4
Solution (a) 443 cm (b) 15.03 g
(c) 0.0356 kg (d) 3.000 x 10-7 L
(e) 50 mL (f) 0.9550 m
Strategy Zeros are significant between nonzero digits or after a nonzero digit with a decimal. Zeros may or may not be significant if they appear to the right of a nonzero digit without a decimal.
3 S.F. 4 S.F.
3 S.F. 4 S.F.
1 or 2, ambiguous 4 S.F.Think About It Be sure that you have identified zeros correctly as either significant or not significant. They are significant in (b) and (d); they are not significant in (c); it is not possible to tell in (e); and the number in (f) contains one zero that is significant, and one that is not.
Significant Figures
Taylor 2010
Addition and Subtraction of Significant Figures
The answer cannot have more digits to the right of the decimalpoint than any of the original numbers.
89.3321.1+
90.432 round off to 90.4
one significant figure after decimal point
3.70-2.91330.7867
two significant figures after decimal point
round off to 0.79
Significant Figures
Taylor 2010
Multiplication and Division of Significant Figures
The number of significant figures in the result is set by the original number that has the smallest number of significant figures.
4.51 x 3.6666 = 16.536366 = 16.5
3 sig figs round to3 sig figs
6.8 ÷ 112.04 = 0.0606926
2 sig figs round to2 sig figs
= 0.061
Significant Figures
Taylor 2010
What are Exact Numbers?
Numbers from definitions or numbers of objects are consideredto have an infinite number of significant figures.
The average of three measured lengths; 6.64, 6.68 and 6.70?
6.64 + 6.68 + 6.703
= 6.67333 = 6.673
Because 3 is an exact number
= 7
Significant Figures
Taylor 2010
After carrying out the following operations, how many significant figures are appropriate to show in the result?
(13.7 + 0.027) 8.221A. 1
B. 2
C. 3
D. 4
E. 5
Ans: C
In addition and subtraction, the answer cannot have more digits to the right of the decimal point than any of the original numbers.
102.50 + 0.231 102.731
143.29 - 20.1 123.19
← round to two digits after the decimal point, 102.73
← round to one digit after the decimal point, 123.2
← two digits after the decimal point← three digits after the decimal point
← two digits after the decimal point← one digit after the decimal point
Calculations with Measured NumbersCalculations with Measured Numbers
Perform the following arithmetic operations and report the result to the proper number of significant figures: (a) 317.5 mL + 0.675 mL, (b) 47.80 L – 2.075 L, (c) 13.5 g ÷ 45.18 L, (d) 6.25 cm x 1.175 cm, (e) 5.46x102 g + 4.991x103 g
Worked Example 1.5Worked Example 1.5
Solution (a) 317.5 mL + 0.675 mL 318.175 mL
(b) 47.80 L - 2.075 L 45.725 L
Strategy Apply the rules for significant figures in calculations, and round each answer to the appropriate number of digits.
← round to 318.2 mL
← round to 45.73 L
Perform the following arithmetic operations and report the result to the proper number of significant figures: (a) 317.5 mL + 0.675 mL, (b) 47.80 L – 2.075 L, (c) 13.5 g ÷ 45.18 L, (d) 6.25 cm x 1.175 cm, (e) 5.46x102 g + 4.991x103 g
Worked Example 1.5 (cont.)Worked Example 1.5 (cont.)
Solution (e) 5.46 x 102 g + 49.91 x 102 g 55.37 x 102 g
Strategy Apply the rules for significant figures in calculations, and round each answer to the appropriate number of digits.
= 5.537 x 103 g
Think About It Changing the answer to correct scientific notation doesn’t change the number of significant figures, but in this case it changes the number of places past the decimal place.
Perform the following arithmetic operations and report the result to the proper number of significant figures: (a) 317.5 mL + 0.675 mL, (b) 47.80 L – 2.075 L, (c) 13.5 g ÷ 45.18 L, (d) 6.25 cm x 1.175 cm, (e) 5.46x102 g + 4.991x103 g
Worked Example 1.5 (cont.)Worked Example 1.5 (cont.)
Solution(c) 13.5 g 45.18 L
(d) 6.25 cm×1.175 cm
Strategy Apply the rules for significant figures in calculations, and round each answer to the appropriate number of digits.
← round to 0.299 g/L= 0.298804781 g/L
3 S.F.
4 S.F.
← round to 7.34 cm2= 7.34375 cm2
3 S.F. 4 S.F.
An empty container with a volume of 9.850 x 102 cm3 is weighed and found to have a mass of 124.6 g. The container is filled with a gas and reweighed. The mass of the container and the gas is 126.5 g. Determine the density of the gas to the appropriate number of significant figures.
Worked Example 1.6Worked Example 1.6
Solution 126.5 g – 124.6 g
mass of gas = 1.9 g
density =
Strategy This problem requires two steps: subtraction to determine the mass of the gas, and division to determine its density. Apply the corresponding rule regarding significant figures to each step.
← one place past the decimal point (two sig figs)
1.9 g9.850 x 102 cm3 ← round to 0.0019 g/cm3= 0.00193 g/cm3
Think About It In this case, although each of the three numbers we started with has four significant figures, the solution only has two significant figures.
In multiplication and division, the number of significant figures in the final product or quotient is determined by the original number that has the smallest number of significant figures.
1.4×8.011 = 11.2154
11.57/305.88 = 0.0378252
2 S.F.
← fewest significant figures is 2, so round to 114 S.F.
← fewest significant figures is 4, so round to 0.037834 S.F. 5 S.F.
Calculations with Measured NumbersCalculations with Measured Numbers
Exact numbers can be considered to have an infinite number of significant figures and do not limit the number of significant figures in a result.
Example: Three pennies each have a mass of 2.5 g. What is the total mass?
3×2.5 = 7.5 g
Calculations with Measured NumbersCalculations with Measured Numbers
Exact(counting number)
Inexact(measurement)
Scientific Notation
Taylor 2010
Converting Numbers to Scientific Notation
The number of atoms in 12 g of carbon:
602,200,000,000,000,000,000,000
6.022 x 1023
The mass of a single carbon atom in grams:
0.0000000000000000000000199
1.99 x 10-23
N x 10n
N is a number between 1 and 10
n is a positive or negative integer
In calculations with multiple steps, round at the end of the calculation to reduce any rounding errors.Do not round after each step.
Compare the following:
Calculations with Measured NumbersCalculations with Measured Numbers
1) 3.66×8.45 = 30.92) 30.9×2.11 = 65.2
1) 3.66×8.45 = 30.932) 30.93×2.11 = 65.3
Rounding after each step Rounding at end
In general, keep at least one extra digit until the end of a multistep calculation.
Scientific Notation
Taylor 2010
• Why?– To express large or small numbers in a
simpler format– All numbers provided in scientific notation are
significant
• How?568.762
n > 0
568.762 = 5.68762 x 102
move decimal left
0.00000772
n < 0
0.00000772 = 7.72 x 10-6
move decimal right
Scientific Notation
Taylor 2010
Addition and Subtraction Of numbers in Scientific notation
1. Write each quantity with the same exponent n
2. Combine N1 and N2
3. The exponent, n, remains the same
4.31 x 104 + 3.9 x 103 =
4.31 x 104 + 0.39 x 104 =
4.70 x 104
Scientific Notation
Taylor 2010
Multiplication and Division In Scientific Notation
Multiplication Rules
1. Multiply N1 and N2
2. Add exponents n1 and n2
3. Check to make sure N3
is between 1-10
(4.0 x 10-5) x (7.0 x 103) =
(4.0 x 7.0) x (10-5+3) =
28 x 10-2 =
2.8 x 10-1
Division Rules
1. Divide N1 and N2
2. Subtract exponents n1 and n2
3. Check to make sure N3 is between 1-10
8.5 x 104 ÷ 5.0 x 109 =
(8.5 ÷ 5.0) x 104-9 =
1.7 x 10-5
Scientific Notation
Taylor 2010
Put the following values into Scientific Notation
24 mL 2.4 x 101 mL
3001 g 3.001 x 103 g
0.0320 m33.20 x 10-2 m3
640,000,000 molecules 6.4 x 108 molecules
0.000000000091 kg 9.1 x 10-12 kg
Scientific Notation
Taylor 2010
Do the following Mathematical Calculations using Scientific Notation
2.4 x 104 + 3.72 x 103 = 2.8 x 104
4.4 x 10-5 ÷ 5.92 x 102 = 7.4 x 10-8
7.19 x 1015 X 8.345 x 10-5 =
5.6 x 10-4 - 3.0 x 10-3 =
6.00 x 1011
5.9 x 10-4
Units in Measurements
Taylor 2010
Hints for converting between units•Always write fractions on 2 lines•Always use scientific notation for your factor•Always go through the “base”•Always pair the base with the factor
Remember these rules regarding working with numbers in Scientific Notation•When you multiply values with exponents, ADD the exponents•When you divide values with exponents, SUBTRACT the exponent of the denominator from the numerator•When you raise an exponent to a power, multiply the exponent by the power
Scientific Notation and your Calculator
Taylor 2010
Scientific Notation and your Calculator
Taylor 2010
The scientific notation key
Derived Units: Volume and DensityDerived Units: Volume and Density
There are many units (such as volume) that require units not included in the base SI units.
The derived SI unit for volume is the meter cubed (m3).
A more practical unit for volume is the liter (L).
1 dm3 = 1 L
1 cm3 = 1 mL
d = densitym = massV = volume
SI-derived unit: kilogram per cubic meter (kg/m3)
Other common units: g/cm3 (solids)g/mL (liquids)g/L (gases)
Derived Units: Volume and DensityDerived Units: Volume and Density
The density of a substance is the ratio of mass to volume.
md =
V
Ice cubes float in a glass of water because solid water is less dense than liquid water. (a) Calculate the density of ice given that, at 0°C, a cube that is 2.0 cm on each side has a mass of 7.36 g, and (b) determine the volume occupied by 23 g of ice at 0°C.
Solution (a) A cube has three equal sides so the volume is (2.0 cm)3, or 8.0 cm3
d =
(b) Rearranging d = m/V to solve for volume gives V = m/d
V =
Think About It For a sample with a density less than 1 g/cm3, the number of cubic centimeters should be greater than the number of grams. In this case, 25 cm3 > 23 g.
7.36 g8.0 cm3
23 g0.92 g/cm3
= 0.92 g/cm3
= 25 cm3
Worked Example 1.3Worked Example 1.3
Strategy (a) Determine density by dividing mass by volume, and (b) use the calculated density to determine the volume occupied by the given mass.
Units in Measurements
Taylor 2010
Conversions to try:
1) 3.72 mm2 to Km2 6) 5.34 g/ L to pg/pL2) 3.72 pmol to Mmol 7) 5.34 KL to nL3) 3.72 mol/ L to mmol/ mL 8) 5.34 ng to Mg4) 3.72 KL to mL 9) 5.34 pm to cm5) 3.72 ng/ mol to g/ mmol 10) 5.34 g/cm3 to Kg/m3
Answers: 1)3.72 x 10-12 Km2 2) 3.72 x 10-18 Mmol 3) 3.72 mmol/ mL4) 3.72 x 106 mL 5) 3.72 x 10-12 g/mmol 6) 5.34 pg/pL7) 5.34 x 1012 nL 8) 5.34 x 10-15 Mg 9) 5.34 x 10-10 cm10) 5.34 x 103 Kg/m3
Problem Solving
Taylor 2010
Dimensional Analysis
• What is it?– a problem-solving method that uses the fact that any
number or expression can be multiplied by one without changing its value
– also called Factor-Label Method or the Unit Factor Method
• Why use it?– To describe the same or equivalent "amounts" of what
we are interested in. For example, we know that1 inch = 2.54 centimeters
Problem Solving
Taylor 2010
1. Determine which unit conversion factor(s) are needed
2. Carry units through calculation
3. If all units cancel except for the desired unit(s), then the problem was solved correctly
1 L = 1000 mL
How many mL are in 1.63 L?
1L
1000 mL1.63 L x = 1630 mL
1L1000 mL
1.63 L x = 0.001630L2
mL
Problem solving
Taylor 2010
A rock climber estimates that the rock face is 155 ft high. The rope he brought is 65 m long. Is the rope long enough to reach the top? (1 ft = 0.3048m)
65 m 1 foot 210 feet 0.3048m
X =
To answer we need the unit conversion of1 foot = 0.3048 meters
Problem Solving
Taylor 2010
The speed limit is 55 miles/hr. What is the speed limit in standard SI units?
55 miles 1.6093 Km 1000 m 8.9x104 m 1 hr 1 mile 1 Km 1 hr
X X =
To answer we need the unit conversion of1 mi = 1.6093 Km1Km = 1000 m
density = mass
volumed =
m
V
A piece of platinum metal with a density of 21.5 g/cm3 has a volume of 4.49 mL. What is its mass?
d =m
V
m = d x V = 21.5 g/cm3 x 4.49 cm3 = 96.5 g
Density
Typicall the units are g/ mL or g/ cm3
Taylor 2010
A piece of metal with a mass of 114 g was placed into a graduated cylinder that contained 25.00 mL of water, raising the water level to 42.50 mL. What is the density of the metal?
A. 0.154 g/mLB. 0.592 g/mLC. 2.68 g/mLD. 6.51 g/mLE. 7.25 g/mL
Ans: D
Taylor 2010
Density
Density
Taylor 2010
using density as a conversion factor what is the mass of a piece of metal with a volume of 15.8 grams if the density of the metal is 2.7 g/mL?
1 The units of volume are either mL, cm3, or L. Given that the density is given in g/mL, the volume of the piece of metal is most likely 15.8 mL (and not 15.8 g).
Assuming that is the case, you are trying to convert from mL to grams, so the labels of the conversion factor must be grams on top and mL on the bottom so that the mL labels will cancel. The density tells us the numbers that go into the conversion factor: 2.7 grams of Al has a volume of 1 mL.
So 15.8 mL x ( 2.7 g / 1 mL ) = _________ grams
Using Units and Solving ProblemsUsing Units and Solving Problems
A conversion factor is a fraction in which the same quantity is expressed one way in the numerator and another way in the denominator.
For example, 1 in = 2.54 cm, may be written:
1.6
1 in2.54 cm
2.54 cm1 in
or
Dimensional Analysis – Tracking UnitsDimensional Analysis – Tracking Units
The use of conversion factors in problem solving is called dimensional analysis or the factor-label method.
Example: Convert 12.00 inches to meters.
12.00 in ×
Which conversion factor will cancel inches and give us centimeters?
1 in2.54 cm
2.54 cm1 in
or
= 30.48 cm
The result contains 4 sig figs because the conversion, a definition, is exact.
The Food and Drug Administration (FDA) recommends that dietary sodium intake be no more than 2400 mg per day.
Worked Example 1.7Worked Example 1.7
Solution2400 mg ×
Strategy The necessary conversion factors are derived from the equalities1 g = 1000 mg and 1 lb = 453.6 g.
1 lb453.6 g
453.6 g1 lb
or1 g
1000 mgor
1000 mg1 g
1 g1000 mg
1 lb453.6 g
× = 0.005291 lb
Think About It Make sure that the magnitude of the result is reasonable and that the units have canceled properly. If we had mistakenly multiplied by 1000 and 453.6 instead of dividing by them, the result(2400 mg×1000 mg/g×453.6 g/lb = 1.089×109 mg2/lb) would be unreasonably large and the units would not have canceled properly.
An average adult has 5.2 L of blood. What is the volume of blood in cubic meters?
Worked Example 1.8Worked Example 1.8
Solution5.2 L ×
Strategy 1 L = 1000 cm3 and 1 cm = 1x10-2 m. When a unit is raised to a power, the corresponding conversion factor must also be raised to that power in order for the units to cancel appropriately.
1000 cm3
1 L1 x 10-2 m
1 cm× = 5.2 x 10-3 m3
3
Think About It Based on the preceding conversion factors, 1 L = 1×10-3 m3. Therefore, 5 L of blood would be equal to 5×10-3 m3, which is close to the calculated answer.
Accuracy and PrecisionAccuracy and Precision
Accuracy tells us how close a measurement is to the true value.
Precision tells us how close a series of replicate measurements are to one another.
Good accuracy and good precision
Poor accuracy but good precision
Poor accuracy and poor precision
Accuracy and PrecisionAccuracy and Precision
Three students were asked to find the mass of an aspirin tablet. The true mass of the tablet is 0.370 g.
Student A: Results are precise but not accurate
Student B: Results are neither precise nor accurate
Student C: Results are both precise and accurate
Chapter Summary: Key PointsChapter Summary: Key Points1
The Scientific MethodStates of MatterSubstancesMixturesPhysical PropertiesChemical PropertiesExtensive and Intensive PropertiesSI Base UnitsMassTemperatureVolume and DensitySignificant Figures