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1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter 1 Chemistry: The Science of Change Kent L. McCorkle Cosumnes River College Sacramento, CA Homework: 5, 9, 15, 17, 23,25, 27, 37, 29, 43, 45, 47, 49, 51, 55, 57, 59, 61, 63, 65, 67, 71, 73, 75, 77 and 79

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Page 1: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

1

Chemistry: Atoms FirstJulia Burdge & Jason Overby

Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

Chapter 1Chemistry:

The Science of Change

Kent L. McCorkle

Cosumnes River College

Sacramento, CA

Homework: 5, 9, 15, 17, 23,25, 27, 31,37, 29, 43, 45, 47, 49, 51, 53, 55, 57, 59, 61, 63, 65, 67, 69,71, 73, 75, 77 and 79

Page 2: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Chemistry: The Science of ChangeChemistry: The Science of Change1

1.1 The Study of Chemistry Chemistry You May Already Know The Scientific Method1.2 Classification of Matter States of Matter Mixtures1.3 The Properties of Matter Physical Properties Chemical Properties Extensive and Intensive Properties 1.4 Scientific Measurement SI Base Units Mass Temperature Derived Units: Volume and Density

1.5 Uncertainty in Measurement Significant Figures Calculations with Measured Numbers Accuracy and Precision

1.6 Using Units and Solving Problems Conversion Factors

Dimensional Analysis Tracking Units

Page 3: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

The Study of ChemistryThe Study of Chemistry

Chemistry is the study of matter and the changes that matter undergoes.

Matter is anything that has mass and occupies space.

1.1

Page 4: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

The Study of ChemistryThe Study of Chemistry

Scientists follow a set of guidelines known as the scientific method:

• gather data via observations and experiments

• identify patterns or trends in the collected data

• summarize their findings with a law

• formulate a hypothesis

• with time a hypothesis may evolve into a theory

Page 5: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Classification of MatterClassification of Matter

Chemists classify matter as either a substance or a mixture of substances.

A substance is a form of matter that has definite composition and distinct properties.Examples: salt (sodium chloride), iron, water, mercury, carbon dioxide, and oxygen

Substances differ from one another in composition and may be identified by appearance, smell, taste, and other properties.

1.2

A mixture is a physical combination of two or more substances.

A homogeneous mixture is uniform throughout. Also called a solution. Examples: seawater, apple juice

A heterogeneous mixture is not uniform throughout. Examples: trail mix, chicken noodle soup

Page 6: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Classification of MatterClassification of Matter

All substances can, in principle, exist as a solid, liquid or gas.

We can convert a substance from one state to another without changing the identity of the substance.

Page 7: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Classification of MatterClassification of Matter

Solid particles are held closely together in an ordered fashion.

Liquid particles are close together but are not held rigidly in position.

Gas particles have significant separation from each other and move freely.

Solids do not conform to the shape of their container.

Liquids do conform to the shape of their container.

Gases assume both the shape and volume of their container.

Page 8: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Classification of MatterClassification of Matter

A mixture can be separated by physical means into its components without changing the identities of the components.

Page 9: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

The Properties of MatterThe Properties of Matter

There are two general types of properties of matter:

1) Quantitative properties are measured and expressed with a number.

2) Qualitative properties do not require measurement and are usually based on observation.

1.3

Page 10: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

The Properties of MatterThe Properties of Matter

A physical property is one that can be observed and measured without changing the identity of the substance.Examples: color, melting point, boiling point

A physical change is one in which the state of matter changes, but the identity of the matter does not change.Examples: changes of state (melting, freezing, condensation)

Page 11: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

The Properties of MatterThe Properties of Matter

A chemical property is one a substance exhibits as it interacts with another substance.Examples: flammability, corrosiveness

A chemical change is one that results in a change of composition; the original substances no longer exist.

Examples: digestion, combustion, oxidation

Page 12: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

The Properties of MatterThe Properties of Matter

An extensive property depends on the amount of matter.Examples: mass, volume

An intensive property does not depend on the amount of matter.Examples: temperature, density

Page 13: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Scientific MeasurementScientific Measurement1.4

Properties that can be measured are called quantitative properties.

A measured quantity must always include a unit.

The English system has units such as the foot, gallon, pound, etc.

The metric system includes units such as the meter, liter, kilogram, etc.

Page 14: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

SI Base UnitsSI Base Units

The revised metric system is called the International System of Units (abbreviated SI Units) and was designed for universal use by scientists.

There are seven SI base units

Page 15: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Units in Measurements

Taylor 2010

Factor Prefix Symbol

1 x 106 Mega M

1 x 103 Kilo k

the base units grams (g) meters (m) Moles (mol) volume (L)

1 x 10-2 centi c

1 x 10-3 milli m

1 x 10-6 micro

1 x 10-9 nano n

1 x 10-12 pico p

Page 16: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

MassMass

Mass is a measure of the amount of matter in an object or sample.

Because gravity varies from location to location, the weight of an object varies depending on where it is measured. But mass doesn’t change.

The SI base unit of mass is the kilogram (kg), but in chemistry the smaller gram (g) is often used.

1 kg = 1000 g = 1×103 g

Atomic mass unit (amu) is used to express the masses of atoms and other similar sized objects.

1 amu = 1.6605378×10-24 g

Page 17: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

TemperatureTemperature

There are two temperature scales used in chemistry:

The Celsius scale (°C) Freezing point (pure water): 0°C Boiling point (pure water): 100°C

The Kelvin scale (K) The “absolute” scale Lowest possible temperature: 0 K (absolute zero)

K = °C + 273.15

Page 18: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Normal human body temperature can range over the course of a day from about 36°C in the early morning to about 37°C in the afternoon. Express these two temperatures and the range that they span using the Kelvin scale.

Worked Example 1.1Worked Example 1.1

Strategy Use K = °C + 273.15 to convert temperatures from Celsius to Kelvin.

Solution 36°C + 273 = 309 K37°C + 273 = 310 K

What range do they span?310 K - 309 K = 1 K

Depending on the precision required, the conversion from °C to K is often simply done by adding 273, rather than 273.15.

Think About It Remember that converting a temperature from °C to K is different from converting a range or difference in temperature from °C to K.

Page 19: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

The Fahrenheit scale is common in the United States. Freezing point (pure water): 32°C Boiling point (pure water): 212°C

There are 180 degrees between freezing and boiling in Fahrenheit (212°F-32°F) but only 100 degrees in Celsius (100°C-0°C).

The size of a degree on the Fahrenheit scale is only of a degree on the Celsius scale.

TemperatureTemperature

Temp in °F = ( ×temp in °C ) + 32°F

5

9

5

9

Page 20: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

A body temperature above 39°C constitutes a high fever. Convert this temperature to the Fahrenheit scale.

Worked Example 1.2Worked Example 1.2

Solution Temp in °F = ( × 39°C ) + 32°F

Temp in °F = 102°F

Think About It Knowing that normal body temperature on the Fahrenheit scale is approximately 98.6°F, 102°F seems like a reasonable answer.

Temp in °F = ( × temp in °C ) + 32°F5

9

5

9

Strategy We are given a temperature and asked to convert it to degrees Fahrenheit. We will use the equation below:

Page 21: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Taking Measurements

Taylor 2010

While Erlenmeyer flasks and beakers have volume markings, those Markings are only approximations and should NEVER be used for taking measurement readings

Page 22: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Taking Measurements

Taylor 2010

Graduated cylinders are moderately accurate and are primarily what we use in the laboratory for measuring volumes of liquids

Page 23: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Taking Measurements

Taylor 2010

Burettes, Pipettes and volumetric flasks are the most accurate way to make solutions and to measure volumes. However, they tend to be more difficult to use than graduated cylinders.

Page 24: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Taking Measurements

Taylor 2010

You want to read the volume of solution at the meniscus and you may need to get down to eye level with the graduated cylinder to read the meniscus properly.

Page 25: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Uncertainty in MeasurementUncertainty in Measurement

An inexact number must be reported so as to indicate its uncertainty.

Significant figures are the meaningful digits in a reported number.

The last digit in a measured number is referred to as the uncertain digit.

When using the top ruler to measure the memory card, we could estimate 2.5 cm. We are certain about the 2, but we are not certain about the 5.

The uncertainty is generally considered to be + 1 in the last digit.

2.5 + 0.1 cm

Page 26: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Uncertainty in MeasurementUncertainty in Measurement

When using the bottom ruler to measure the memory card, we might record 2.45 cm.

Again, we estimate one more digit than we are certain of.

2.45 + 0.01 cm

Page 27: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Taking Measurements

Taylor 2010

Which piece of glassware would you use to get the most accurate measured value?

Beaker

or

Graduated cylinder

Page 28: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Taking Measurements

Taylor 2010

Let’s consider the significant figure value we would obtain?

What is our certain measured value?

What is our estimated value ?

10

13

Page 29: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Taking Measurements

Taylor 2010

Let’s consider the significant figure value we would obtain?

What is our certain measured value?

What is our estimated value ?

13.5

13.51

Page 30: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Taking Measurements

Taylor 2010

Which piece of glassware would you use to get the most accurate measured value?

Beaker

or

Graduated cylinder

Page 31: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Significant Figures

Taylor 2010

• Why?– To show the certainty in a measured value– To indicate the margin of error when

measuring

• How?– Report all known values– Estimate one value past what’s given

Page 32: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Significant Figures Rules

Taylor 2010

•Any digit that is not zero is significant

1.234 kg 4 significant figures

•Zeros between nonzero digits are significant

606 m 3 significant figures

•Zeros to the left of the first nonzero digit are not significant

0.08 L 1 significant figure

•If a number is greater than 1, then all zeros to the right of the decimal point are significant

2.0 mg 2 significant figures

•If a number is less than 1, then only the zeros that are at the end and in the middle of the number are significant

0.00420 g 3 significant figures

Page 33: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Significant Figures Rules

Taylor 2010

•Any number that has zeros after the digits and no decimal point according to Tro may have an infinite number of significant figures

•However, there is considerable number of scientists who believe that zeros that come after the digits when a decimal point is not present are considered to be NOT significant

•For example the number 54, 000 would have infinite or 2 significant figures where as 54, 000. would have 5

Page 34: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Significant Figures

Taylor 2010

How many significant figures are in each of the following measurements?

24 mL 2 significant figures

3001 g 4 significant figures

0.0320 m3 3 significant figures

6.4 x 104 molecules 2 significant figures

560 kg 2 significant figures

Page 35: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Significant Figures

Taylor 2010

How many significant figures are there in 1.3070 g?

A. 6

B. 5

C. 4

D. 3

E. 2

Ans: B

Page 36: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Determine the number of significant figures in the following measurements: (a) 443 cm, (b) 15.03 g, (c) 0.0356 kg, (d) 3.000×10-7 L, (e) 50 mL, (f) 0.9550 m.

Worked Example 1.4Worked Example 1.4

Solution (a) 443 cm (b) 15.03 g

(c) 0.0356 kg (d) 3.000 x 10-7 L

(e) 50 mL (f) 0.9550 m

Strategy Zeros are significant between nonzero digits or after a nonzero digit with a decimal. Zeros may or may not be significant if they appear to the right of a nonzero digit without a decimal.

3 S.F. 4 S.F.

3 S.F. 4 S.F.

1 or 2, ambiguous 4 S.F.Think About It Be sure that you have identified zeros correctly as either significant or not significant. They are significant in (b) and (d); they are not significant in (c); it is not possible to tell in (e); and the number in (f) contains one zero that is significant, and one that is not.

Page 37: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Significant Figures

Taylor 2010

Addition and Subtraction of Significant Figures

The answer cannot have more digits to the right of the decimalpoint than any of the original numbers.

89.3321.1+

90.432 round off to 90.4

one significant figure after decimal point

3.70-2.91330.7867

two significant figures after decimal point

round off to 0.79

Page 38: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Significant Figures

Taylor 2010

Multiplication and Division of Significant Figures

The number of significant figures in the result is set by the original number that has the smallest number of significant figures.

4.51 x 3.6666 = 16.536366 = 16.5

3 sig figs round to3 sig figs

6.8 ÷ 112.04 = 0.0606926

2 sig figs round to2 sig figs

= 0.061

Page 39: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Significant Figures

Taylor 2010

What are Exact Numbers?

Numbers from definitions or numbers of objects are consideredto have an infinite number of significant figures.

The average of three measured lengths; 6.64, 6.68 and 6.70?

6.64 + 6.68 + 6.703

= 6.67333 = 6.673

Because 3 is an exact number

= 7

Page 40: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Significant Figures

Taylor 2010

After carrying out the following operations, how many significant figures are appropriate to show in the result?

(13.7 + 0.027) 8.221A. 1

B. 2

C. 3

D. 4

E. 5

Ans: C

Page 41: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

In addition and subtraction, the answer cannot have more digits to the right of the decimal point than any of the original numbers.

102.50 + 0.231 102.731

143.29 - 20.1 123.19

← round to two digits after the decimal point, 102.73

← round to one digit after the decimal point, 123.2

← two digits after the decimal point← three digits after the decimal point

← two digits after the decimal point← one digit after the decimal point

Calculations with Measured NumbersCalculations with Measured Numbers

Page 42: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Perform the following arithmetic operations and report the result to the proper number of significant figures: (a) 317.5 mL + 0.675 mL, (b) 47.80 L – 2.075 L, (c) 13.5 g ÷ 45.18 L, (d) 6.25 cm x 1.175 cm, (e) 5.46x102 g + 4.991x103 g

Worked Example 1.5Worked Example 1.5

Solution (a) 317.5 mL + 0.675 mL 318.175 mL

(b) 47.80 L - 2.075 L 45.725 L

Strategy Apply the rules for significant figures in calculations, and round each answer to the appropriate number of digits.

← round to 318.2 mL

← round to 45.73 L

Page 43: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Perform the following arithmetic operations and report the result to the proper number of significant figures: (a) 317.5 mL + 0.675 mL, (b) 47.80 L – 2.075 L, (c) 13.5 g ÷ 45.18 L, (d) 6.25 cm x 1.175 cm, (e) 5.46x102 g + 4.991x103 g

Worked Example 1.5 (cont.)Worked Example 1.5 (cont.)

Solution (e) 5.46 x 102 g + 49.91 x 102 g 55.37 x 102 g

Strategy Apply the rules for significant figures in calculations, and round each answer to the appropriate number of digits.

= 5.537 x 103 g

Think About It Changing the answer to correct scientific notation doesn’t change the number of significant figures, but in this case it changes the number of places past the decimal place.

Page 44: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Perform the following arithmetic operations and report the result to the proper number of significant figures: (a) 317.5 mL + 0.675 mL, (b) 47.80 L – 2.075 L, (c) 13.5 g ÷ 45.18 L, (d) 6.25 cm x 1.175 cm, (e) 5.46x102 g + 4.991x103 g

Worked Example 1.5 (cont.)Worked Example 1.5 (cont.)

Solution(c) 13.5 g 45.18 L

(d) 6.25 cm×1.175 cm

Strategy Apply the rules for significant figures in calculations, and round each answer to the appropriate number of digits.

← round to 0.299 g/L= 0.298804781 g/L

3 S.F.

4 S.F.

← round to 7.34 cm2= 7.34375 cm2

3 S.F. 4 S.F.

Page 45: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

An empty container with a volume of 9.850 x 102 cm3 is weighed and found to have a mass of 124.6 g. The container is filled with a gas and reweighed. The mass of the container and the gas is 126.5 g. Determine the density of the gas to the appropriate number of significant figures.

Worked Example 1.6Worked Example 1.6

Solution 126.5 g – 124.6 g

mass of gas = 1.9 g

density =

Strategy This problem requires two steps: subtraction to determine the mass of the gas, and division to determine its density. Apply the corresponding rule regarding significant figures to each step.

← one place past the decimal point (two sig figs)

1.9 g9.850 x 102 cm3 ← round to 0.0019 g/cm3= 0.00193 g/cm3

Think About It In this case, although each of the three numbers we started with has four significant figures, the solution only has two significant figures.

Page 46: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

In multiplication and division, the number of significant figures in the final product or quotient is determined by the original number that has the smallest number of significant figures.

1.4×8.011 = 11.2154

11.57/305.88 = 0.0378252

2 S.F.

← fewest significant figures is 2, so round to 114 S.F.

← fewest significant figures is 4, so round to 0.037834 S.F. 5 S.F.

Calculations with Measured NumbersCalculations with Measured Numbers

Page 47: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Exact numbers can be considered to have an infinite number of significant figures and do not limit the number of significant figures in a result.

Example: Three pennies each have a mass of 2.5 g. What is the total mass?

3×2.5 = 7.5 g

Calculations with Measured NumbersCalculations with Measured Numbers

Exact(counting number)

Inexact(measurement)

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Scientific Notation

Taylor 2010

Converting Numbers to Scientific Notation

The number of atoms in 12 g of carbon:

602,200,000,000,000,000,000,000

6.022 x 1023

The mass of a single carbon atom in grams:

0.0000000000000000000000199

1.99 x 10-23

N x 10n

N is a number between 1 and 10

n is a positive or negative integer

Page 49: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

In calculations with multiple steps, round at the end of the calculation to reduce any rounding errors.Do not round after each step.

Compare the following:

Calculations with Measured NumbersCalculations with Measured Numbers

1) 3.66×8.45 = 30.92) 30.9×2.11 = 65.2

1) 3.66×8.45 = 30.932) 30.93×2.11 = 65.3

Rounding after each step Rounding at end

In general, keep at least one extra digit until the end of a multistep calculation.

Page 50: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Scientific Notation

Taylor 2010

• Why?– To express large or small numbers in a

simpler format– All numbers provided in scientific notation are

significant

• How?568.762

n > 0

568.762 = 5.68762 x 102

move decimal left

0.00000772

n < 0

0.00000772 = 7.72 x 10-6

move decimal right

Page 51: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Scientific Notation

Taylor 2010

Addition and Subtraction Of numbers in Scientific notation

1. Write each quantity with the same exponent n

2. Combine N1 and N2

3. The exponent, n, remains the same

4.31 x 104 + 3.9 x 103 =

4.31 x 104 + 0.39 x 104 =

4.70 x 104

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Scientific Notation

Taylor 2010

Multiplication and Division In Scientific Notation

Multiplication Rules

1. Multiply N1 and N2

2. Add exponents n1 and n2

3. Check to make sure N3

is between 1-10

(4.0 x 10-5) x (7.0 x 103) =

(4.0 x 7.0) x (10-5+3) =

28 x 10-2 =

2.8 x 10-1

Division Rules

1. Divide N1 and N2

2. Subtract exponents n1 and n2

3. Check to make sure N3 is between 1-10

8.5 x 104 ÷ 5.0 x 109 =

(8.5 ÷ 5.0) x 104-9 =

1.7 x 10-5

Page 53: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Scientific Notation

Taylor 2010

Put the following values into Scientific Notation

24 mL 2.4 x 101 mL

3001 g 3.001 x 103 g

0.0320 m33.20 x 10-2 m3

640,000,000 molecules 6.4 x 108 molecules

0.000000000091 kg 9.1 x 10-12 kg

Page 54: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Scientific Notation

Taylor 2010

Do the following Mathematical Calculations using Scientific Notation

2.4 x 104 + 3.72 x 103 = 2.8 x 104

4.4 x 10-5 ÷ 5.92 x 102 = 7.4 x 10-8

7.19 x 1015 X 8.345 x 10-5 =

5.6 x 10-4 - 3.0 x 10-3 =

6.00 x 1011

5.9 x 10-4

Page 55: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Units in Measurements

Taylor 2010

Hints for converting between units•Always write fractions on 2 lines•Always use scientific notation for your factor•Always go through the “base”•Always pair the base with the factor

Remember these rules regarding working with numbers in Scientific Notation•When you multiply values with exponents, ADD the exponents•When you divide values with exponents, SUBTRACT the exponent of the denominator from the numerator•When you raise an exponent to a power, multiply the exponent by the power

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Scientific Notation and your Calculator

Taylor 2010

Page 57: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Scientific Notation and your Calculator

Taylor 2010

The scientific notation key

Page 58: 1 Chemistry: Atoms First Julia Burdge & Jason Overby Copyright (c) The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter

Derived Units: Volume and DensityDerived Units: Volume and Density

There are many units (such as volume) that require units not included in the base SI units.

The derived SI unit for volume is the meter cubed (m3).

A more practical unit for volume is the liter (L).

1 dm3 = 1 L

1 cm3 = 1 mL

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d = densitym = massV = volume

SI-derived unit: kilogram per cubic meter (kg/m3)

Other common units: g/cm3 (solids)g/mL (liquids)g/L (gases)

Derived Units: Volume and DensityDerived Units: Volume and Density

The density of a substance is the ratio of mass to volume.

md =

V

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Ice cubes float in a glass of water because solid water is less dense than liquid water. (a) Calculate the density of ice given that, at 0°C, a cube that is 2.0 cm on each side has a mass of 7.36 g, and (b) determine the volume occupied by 23 g of ice at 0°C.

Solution (a) A cube has three equal sides so the volume is (2.0 cm)3, or 8.0 cm3

d =

(b) Rearranging d = m/V to solve for volume gives V = m/d

V =

Think About It For a sample with a density less than 1 g/cm3, the number of cubic centimeters should be greater than the number of grams. In this case, 25 cm3 > 23 g.

7.36 g8.0 cm3

23 g0.92 g/cm3

= 0.92 g/cm3

= 25 cm3

Worked Example 1.3Worked Example 1.3

Strategy (a) Determine density by dividing mass by volume, and (b) use the calculated density to determine the volume occupied by the given mass.

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Units in Measurements

Taylor 2010

Conversions to try:

1) 3.72 mm2 to Km2 6) 5.34 g/ L to pg/pL2) 3.72 pmol to Mmol 7) 5.34 KL to nL3) 3.72 mol/ L to mmol/ mL 8) 5.34 ng to Mg4) 3.72 KL to mL 9) 5.34 pm to cm5) 3.72 ng/ mol to g/ mmol 10) 5.34 g/cm3 to Kg/m3

  Answers: 1)3.72 x 10-12 Km2 2) 3.72 x 10-18 Mmol 3) 3.72 mmol/ mL4) 3.72 x 106 mL 5) 3.72 x 10-12 g/mmol 6) 5.34 pg/pL7) 5.34 x 1012 nL 8) 5.34 x 10-15 Mg 9) 5.34 x 10-10 cm10) 5.34 x 103 Kg/m3

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Problem Solving

Taylor 2010

Dimensional Analysis

• What is it?– a problem-solving method that uses the fact that any

number or expression can be multiplied by one without changing its value

– also called Factor-Label Method or the Unit Factor Method

• Why use it?– To describe the same or equivalent "amounts" of what

we are interested in. For example, we know that1 inch = 2.54 centimeters

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Problem Solving

Taylor 2010

1. Determine which unit conversion factor(s) are needed

2. Carry units through calculation

3. If all units cancel except for the desired unit(s), then the problem was solved correctly

1 L = 1000 mL

How many mL are in 1.63 L?

1L

1000 mL1.63 L x = 1630 mL

1L1000 mL

1.63 L x = 0.001630L2

mL

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Problem solving

Taylor 2010

A rock climber estimates that the rock face is 155 ft high. The rope he brought is 65 m long. Is the rope long enough to reach the top? (1 ft = 0.3048m)

65 m 1 foot 210 feet 0.3048m

X =

To answer we need the unit conversion of1 foot = 0.3048 meters

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Problem Solving

Taylor 2010

The speed limit is 55 miles/hr. What is the speed limit in standard SI units?

55 miles 1.6093 Km 1000 m 8.9x104 m 1 hr 1 mile 1 Km 1 hr

X X =

To answer we need the unit conversion of1 mi = 1.6093 Km1Km = 1000 m

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density = mass

volumed =

m

V

A piece of platinum metal with a density of 21.5 g/cm3 has a volume of 4.49 mL. What is its mass?

d =m

V

m = d x V = 21.5 g/cm3 x 4.49 cm3 = 96.5 g

Density

Typicall the units are g/ mL or g/ cm3

Taylor 2010

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A piece of metal with a mass of 114 g was placed into a graduated cylinder that contained 25.00 mL of water, raising the water level to 42.50 mL. What is the density of the metal?

A. 0.154 g/mLB. 0.592 g/mLC. 2.68 g/mLD. 6.51 g/mLE. 7.25 g/mL

Ans: D

Taylor 2010

Density

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Density

Taylor 2010

using density as a conversion factor what is the mass of a piece of metal with a volume of 15.8 grams if the density of the metal is 2.7 g/mL?

1 The units of volume are either mL, cm3, or L.  Given that the density is given in g/mL, the volume of the piece of metal is most likely 15.8 mL (and not 15.8 g).

Assuming that is the case, you are trying to convert from mL to grams, so the labels of the conversion factor must be grams on top and mL on the bottom so that the mL labels will cancel.  The density tells us the numbers that go into the conversion factor:  2.7 grams of Al has a volume of 1 mL.

So                      15.8 mL  x   (  2.7 g / 1 mL  )  =   _________  grams

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Using Units and Solving ProblemsUsing Units and Solving Problems

A conversion factor is a fraction in which the same quantity is expressed one way in the numerator and another way in the denominator.

For example, 1 in = 2.54 cm, may be written:

1.6

1 in2.54 cm

2.54 cm1 in

or

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Dimensional Analysis – Tracking UnitsDimensional Analysis – Tracking Units

The use of conversion factors in problem solving is called dimensional analysis or the factor-label method.

Example: Convert 12.00 inches to meters.

12.00 in ×

Which conversion factor will cancel inches and give us centimeters?

1 in2.54 cm

2.54 cm1 in

or

= 30.48 cm

The result contains 4 sig figs because the conversion, a definition, is exact.

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The Food and Drug Administration (FDA) recommends that dietary sodium intake be no more than 2400 mg per day.

Worked Example 1.7Worked Example 1.7

Solution2400 mg ×

Strategy The necessary conversion factors are derived from the equalities1 g = 1000 mg and 1 lb = 453.6 g.

1 lb453.6 g

453.6 g1 lb

or1 g

1000 mgor

1000 mg1 g

1 g1000 mg

1 lb453.6 g

× = 0.005291 lb

Think About It Make sure that the magnitude of the result is reasonable and that the units have canceled properly. If we had mistakenly multiplied by 1000 and 453.6 instead of dividing by them, the result(2400 mg×1000 mg/g×453.6 g/lb = 1.089×109 mg2/lb) would be unreasonably large and the units would not have canceled properly.

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An average adult has 5.2 L of blood. What is the volume of blood in cubic meters?

Worked Example 1.8Worked Example 1.8

Solution5.2 L ×

Strategy 1 L = 1000 cm3 and 1 cm = 1x10-2 m. When a unit is raised to a power, the corresponding conversion factor must also be raised to that power in order for the units to cancel appropriately.

1000 cm3

1 L1 x 10-2 m

1 cm× = 5.2 x 10-3 m3

3

Think About It Based on the preceding conversion factors, 1 L = 1×10-3 m3. Therefore, 5 L of blood would be equal to 5×10-3 m3, which is close to the calculated answer.

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Accuracy and PrecisionAccuracy and Precision

Accuracy tells us how close a measurement is to the true value.

Precision tells us how close a series of replicate measurements are to one another.

Good accuracy and good precision

Poor accuracy but good precision

Poor accuracy and poor precision

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Accuracy and PrecisionAccuracy and Precision

Three students were asked to find the mass of an aspirin tablet. The true mass of the tablet is 0.370 g.

Student A: Results are precise but not accurate

Student B: Results are neither precise nor accurate

Student C: Results are both precise and accurate

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Chapter Summary: Key PointsChapter Summary: Key Points1

The Scientific MethodStates of MatterSubstancesMixturesPhysical PropertiesChemical PropertiesExtensive and Intensive PropertiesSI Base UnitsMassTemperatureVolume and DensitySignificant Figures