1 general chemistries and manufacturing capabilities tom karol, ph.d. research director r. t....
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General Chemistries and Manufacturing Capabilities
Tom Karol, Ph.D.Research Director
R. T. VANDERBILTR. T. VANDERBILTCompanyCompany
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MANUFACTURING
CHEMICAL PLANTS
Murray KentuckyBethel Connecticut
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Carbon Disulfide & Secondary Amines
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CARBON DISULFIDE CHEMISTRY
CS2
N
R
R
S
S O
O
O
O
R'
R'
SS
N
S
R
R
N
S
R
R
S
N N
S
O
O
O
O
S
R
R H
S
N N
S SRS SR
MSN
S
R
R n
S
N N
S SH H
S
N N
S SH S
N N
S S H
N
NS H
N
NS Zn2
CH3
CH3
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Dithiocarbamic acid reactions
CS2
N
R
R
S
S O
O
O
O
R'
R' SSN
S
R
R
N
S
R
RMS
N
S
R
R n
NR
RH
N
R
R
S
S
H
NaOHN
R
R
S
S
Na+
Metaloxide
CH2Cl2
Metal
salt
N
R
R
S
S
SN
S
R
R
SxSN
R
R
S
SN
S
R
R
N
S
R
R
N
R
R
S
S
oxidation
maleate
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2-Mercaptotoluimidazole
CS2
N
NS H
N
NS Zn2
CH3
CH3
N
N
H
H
H
HCH3
+
Zn+
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CS2 to 1,3,4-Thiadiazole
CS2
S
N N
S
O
O
O
O
S
R
R H
S
N N
S SS S R
R
S
N N
S SH H
S
N N
S SH S
N N
S S H
N
H
H
NH
H
NaOH S
N N
S SH
H+
S
N N
-S SNa
+Na
+Na
+
oxidation
maleate
oxidative
S
N N
S HS
N N
S SH
coupling
NaOH
R- -HS
coupling
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Cooperative Research RTV will enter into cooperative research agreements
Confidential information may be exchanged to promote inter-company cooperation
Mutually beneficial results