SL-1-160-crude-H

Sample: SL-1-160-crude-HFile: data/hg2/slevin/vnmrsys/data/SL-1-160-crude-H.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Ambient temperatureOperator: slevinFile: SL-1-160-crude-HINOVA-500 "erice.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.998 sec Width 4796.2 Hz 8 repetitionsOBSERVE H1, 299.8165647 MHzDATA PROCESSING Line broadening 1.0 HzFT size 32768Total time 0 min, 26 sec

2.00

2.05

9.46

5.59

ppm12345678910

Br

OTBS

8

bromide

Sample: RRN-2-propargylBrFile: data/indy/slevin/vnmrsys/data/RRN-2-propargylBr/CARBON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #1, Operator: slevinFile: CARBON01INOVA-500 "erice.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.042 sec Width 31446.5 Hz 1000 repetitionsOBSERVE C13, 125.6635141 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 0.5 HzFT size 65536Total time 35 min, 38 sec

ppm20406080100120140160180200

Br

OTBS

8

RRN-2-233-6

Sample Name: RRN-2-233-6-1H Data Collected on: indy.caltech.edu-inova500 Archive directory: /home/nanir/vnmrsys/data Sample directory: RRN-2-233-6-1H FidFile: PROTON01

Pulse Sequence: PROTON (s2pul)Solvent: cdcl3Data collected on: Nov 11 2009

Temp. 25.0 C / 298.1 KSample #5, Operator: nanir

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 64 repetitionsOBSERVE H1, 499.7550811 MHzDATA PROCESSINGFT size 32768Total time 3 min 16 sec

2.00

6.03

2.04

2.07

0.78

9.03

5.05

ppm12345678910

Plotname: --Not assigned--

OTBS

MeO2C

MeO2C

S1

RRN-2-234-6

Sample Name: RRN-2-234-6 Data Collected on: indy.caltech.edu-inova500 Archive directory:

Sample directory:

FidFile: Carbon_02

Pulse Sequence: Carbon (s2pul)Solvent: cdcl3Data collected on: Oct 9 2009

Sample #45, Operator: nanir

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.300 sec Width 30165.9 Hz 512 repetitionsOBSERVE C13, 125.6635228 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 0.5 HzFT size 131072Total time 19 min

ppm20406080100120140160180200

OTBS

MeO2C

MeO2C

S1

RRN-2-234-6

Sample Name: RRN-2-234-6 Data Collected on: indy.caltech.edu-inova500 Archive directory:

Sample directory:

FidFile: Proton_02

Pulse Sequence: Proton (s2pul)Solvent: cdcl3Data collected on: Oct 9 2009

Sample #45, Operator: nanir

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 16 repetitionsOBSERVE H1, 499.7550816 MHzDATA PROCESSING Resol. enhancement -0.0 HzFT size 65536Total time 0 min 55 sec

2.00

5.96

2.07

2.10

0.88

0.86

ppm12345678910

OH

MeO2C

MeO2C

9

RRN-2-234-6

Sample Name: RRN-2-234-6 Data Collected on: indy.caltech.edu-inova500 Archive directory:

Sample directory:

FidFile: Carbon_02

Pulse Sequence: Carbon (s2pul)Solvent: cdcl3Data collected on: Oct 9 2009

Sample #45, Operator: nanir

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.300 sec Width 30165.9 Hz 512 repetitionsOBSERVE C13, 125.6635228 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 0.5 HzFT size 131072Total time 19 min

ppm20406080100120140160180200

OH

MeO2C

MeO2C

9

RRN-2-238-2

Sample Name: RRN-2-238-2 Data Collected on: indy.caltech.edu-inova500 Archive directory:

Sample directory:

FidFile: Proton_01

Pulse Sequence: Proton (s2pul)Solvent: cdcl3Data collected on: Oct 11 2009

Sample #45, Operator: nanir

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 16 repetitionsOBSERVE H1, 499.7550819 MHzDATA PROCESSING Resol. enhancement -0.0 HzFT size 65536Total time 0 min 55 sec

4.01

6.00

2.13

2.12

0.75

0.81

ppm12345678910

O

MeO2C

MeO2C

S2

RRN-2-238-2

Sample Name: RRN-2-238-2 Data Collected on: indy.caltech.edu-inova500 Archive directory:

Sample directory:

FidFile: Carbon_02

Pulse Sequence: Carbon (s2pul)Solvent: cdcl3Data collected on: Oct 11 2009

Sample #45, Operator: nanir

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.300 sec Width 30165.9 Hz 1000 repetitionsOBSERVE C13, 125.6635164 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 0.5 HzFT size 131072Total time 38 min

ppm20406080100120140160180200

O

MeO2C

MeO2C

S2

RRN-2-239-4

Sample Name: RRN-2-239-4 Data Collected on: indy.caltech.edu-inova500 Archive directory: /home/nanir/vnmrsys/data Sample directory: RRN-2-239-405 FidFile: PROTON01

Pulse Sequence: PROTON (s2pul)Solvent: cdcl3Data collected on: Oct 12 2009

Temp. 25.0 C / 298.1 KSample #45, Operator: nanir

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 16 repetitionsOBSERVE H1, 499.7550816 MHzDATA PROCESSINGFT size 32768Total time 0 min 49 sec 0.91

0.91

2.00

2.01

5.81

2.04

2.00

ppm12345678910

Plotname: --Not assigned--

O

MeO2C

MeO2C

10

arene

Sample: RRN-2-239-4File: indy/nanir/vnmrsys/data/RRN-2-239-405/CARBON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #45, Operator: nanirFile: CARBON01INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.042 sec Width 31446.5 Hz 512 repetitionsOBSERVE C13, 125.6635166 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 0.5 HzFT size 65536Total time 17 min, 30 sec

ppm20406080100120140160180200

O

MeO2C

MeO2C

10

RRN-2-241-2

Sample Name: RRN-2-241-2 Data Collected on: indy.caltech.edu-inova500 Archive directory: /home/nanir/vnmrsys/data Sample directory: RRN-2-241-201 FidFile: PROTON01

Pulse Sequence: PROTON (s2pul)Solvent: cdcl3Data collected on: Oct 14 2009

Temp. 25.0 C / 298.1 KSample #43, Operator: nanir

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 16 repetitionsOBSERVE H1, 499.7550811 MHzDATA PROCESSINGFT size 32768Total time 0 min 49 sec 0.93

0.92

2.00

2.02

2.97

0.97

2.12

1.05

1.06

ppm12345678910

Plotname: --Not assigned--

O

S3

MeO2C

RRN-2-241-2

Sample Name: RRN-2-241-2 Data Collected on: indy.caltech.edu-inova500 Archive directory: /home/nanir/vnmrsys/data Sample directory: RRN-2-241-201 FidFile: CARBON01

Pulse Sequence: CARBON (s2pul)Solvent: cdcl3Data collected on: Oct 14 2009

Temp. 25.0 C / 298.1 KSample #43, Operator: nanir

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.042 sec Width 31446.5 Hz 512 repetitionsOBSERVE C13, 125.6635166 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 0.5 HzFT size 65536Total time 17 min

ppm20406080100120140160180200

Plotname: --Not assigned--

O

S3

MeO2C

carboxylic acid

Sample: RRN-2-286-1HFile: indy/nanir/vnmrsys/data/RRN-2-286-1H/PROTON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #1, Operator: nanirFile: PROTON01INOVA-500 "urbino.caltech.edu"

Relax. delay 2.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 64 repetitionsOBSERVE H1, 499.7550816 MHzDATA PROCESSINGFT size 32768Total time 4 min, 20 sec

0.71

0.92

0.97

2.00

2.10

1.04

2.02

2.19

ppm1234567891011

O

11

HO2C

carboxylic acid

Sample: RRN-2-286-13CFile: indy/nanir/vnmrsys/data/RRN-2-286-13C/CARBON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #2, Operator: nanirFile: CARBON01INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.042 sec Width 31446.5 Hz 1000 repetitionsOBSERVE C13, 125.6635204 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 0.5 HzFT size 65536Total time 34 min, 11 sec

ppm20406080100120140160180200

O

11

HO2C

RRN-2-287-3

Sample Name: RRN-2-287-3 Data Collected on: indy.caltech.edu-inova500 Archive directory: /home/nanir/vnmrsys/data Sample directory: RRN-2-287-3 FidFile: PROTON01

Pulse Sequence: PROTON (s2pul)Solvent: cdcl3Data collected on: Nov 12 2009

Temp. 25.0 C / 298.1 KSample #1, Operator: nanir

Relax. delay 2.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 64 repetitionsOBSERVE H1, 499.7550811 MHzDATA PROCESSINGFT size 32768Total time 4 min 20 sec 0.93

0.92

0.79

2.00

2.02

0.88

3.09

1.09

ppm12345678910

Plotname: --Not assigned--

O

O

N2 S4

RRN-2-287-3

Sample Name: RRN-2-287-3 Data Collected on: indy.caltech.edu-inova500 Archive directory: /home/nanir/vnmrsys/data Sample directory: RRN-2-287-3 FidFile: CARBON01

Pulse Sequence: CARBON (s2pul)Solvent: cdcl3Data collected on: Nov 12 2009

Temp. 25.0 C / 298.1 KSample #1, Operator: nanir

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.042 sec Width 31446.5 Hz 2000 repetitionsOBSERVE C13, 125.6635166 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 0.5 HzFT size 65536Total time 1 hr, 8 min

ppm20406080100120140160180200

Plotname: --Not assigned--

O

O

N2 S4

SL-3-007-500-H

Sample: SL-3-007-500-HFile: indy/slevin/vnmrsys/data/SL-3-007-500-H/PROTON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #48, Operator: slevinFile: PROTON01INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 8 repetitionsOBSERVE H1, 499.7550814 MHzDATA PROCESSINGFT size 32768Total time 0 min, 24 sec

0.88

0.89

1.86

1.94

1.00

0.98

0.99

0.96

2.83

ppm12345678910

O

HO2C

12

SL-3-007-125-C13

Sample: SL-3-007-125-C13File: indy/slevin/vnmrsys/data/SL-3-007-125-C13/CARBON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #48, Operator: slevinFile: CARBON01INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.042 sec Width 31446.5 Hz 5000 repetitionsOBSERVE C13, 125.6635136 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 0.5 HzFT size 65536Total time 2 hr, 50 min, 56 sec

ppm20406080100120140160180200

O

HO2C

12

RRN-2-288-2

Sample Name: RRN-2-288-2 Data Collected on: indy.caltech.edu-inova500 Archive directory: /home/nanir/vnmrsys/data Sample directory: RRN-2-288-2 FidFile: PROTON01

Pulse Sequence: PROTON (s2pul)Solvent: cdcl3Data collected on: Nov 13 2009

Temp. 25.0 C / 298.1 KSample #1, Operator: nanir

Relax. delay 2.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 32 repetitionsOBSERVE H1, 499.7550816 MHzDATA PROCESSINGFT size 32768Total time 2 min 10 sec 1.01

0.96

2.12

2.11

3.00

1.09

1.09

1.04

1.10

3.25

ppm12345678910

Plotname: --Not assigned--

O

MeO2C

13

RRN-2-288-2

Sample Name: RRN-2-288-2 Data Collected on: indy.caltech.edu-inova500 Archive directory: /home/nanir/vnmrsys/data Sample directory: RRN-2-288-2 FidFile: CARBON01

Pulse Sequence: CARBON (s2pul)Solvent: cdcl3Data collected on: Nov 13 2009

Temp. 25.0 C / 298.1 KSample #2, Operator: nanir

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.042 sec Width 31446.5 Hz 1300 repetitionsOBSERVE C13, 125.6635224 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 0.5 HzFT size 65536Total time 44 min

ppm20406080100120140160180200

Plotname: --Not assigned--

O

MeO2C

13

RRN-2-274-3

Sample Name: RRN-2-274-3 Data Collected on: indy.caltech.edu-inova500 Archive directory: /home/nanir/vnmrsys/data Sample directory: RRN-2-274-3 FidFile: PROTON01

Pulse Sequence: PROTON (s2pul)Solvent: cdcl3Data collected on: Nov 2 2009

Temp. 25.0 C / 298.1 KSample #45, Operator: nanir

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 16 repetitionsOBSERVE H1, 499.7550811 MHzDATA PROCESSINGFT size 32768Total time 0 min 49 sec 0.91

0.87

0.69

2.00

2.00

1.01

1.95

1.12

2.78

ppm12345678910

Plotname: --Not assigned--

O

ON2

H 14

RRN-2-274-3

Sample Name: RRN-2-274-3 Data Collected on: indy.caltech.edu-inova500 Archive directory: /home/nanir/vnmrsys/data Sample directory: RRN-2-274-3 FidFile: CARBON01

Pulse Sequence: CARBON (s2pul)Solvent: cdcl3Data collected on: Nov 2 2009

Temp. 25.0 C / 298.1 KSample #45, Operator: nanir

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.042 sec Width 31446.5 Hz 1500 repetitionsOBSERVE C13, 125.6635136 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 0.5 HzFT size 65536Total time 51 min

ppm20406080100120140160180200

Plotname: --Not assigned--

O

ON2

H 14

SL-3-021-500-column-H

Sample: SL-3-021-500-column-HFile: indy/slevin/vnmrsys/data/SL-3-021-500-column-H/PROTON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #46, Operator: slevinFile: PROTON01INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 32 repetitionsOBSERVE H1, 499.7550815 MHzDATA PROCESSING Line broadening 0.5 HzFT size 32768Total time 1 min, 38 sec

0.91

0.84

1.94

2.02

1.00

2.07

2.61

1.04

2.53

ppm12345678910

O

ON2

H3C15

SL-3-021-125-column-13C

Sample: SL-3-021-125-column-13CFile: indy/slevin/vnmrsys/data/SL-3-021-125-column-13C/CARBON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #47, Operator: slevinFile: CARBON01INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.042 sec Width 31446.5 Hz 1650 repetitionsOBSERVE C13, 125.6635240 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 2.0 HzFT size 65536Total time 56 min, 24 sec

ppm20406080100120140160180200

O

ON2

H3C15

SL-1-217-500-column-H

Sample: SL-1-217-500-column-HFile: indy/slevin/vnmrsys/data/SL-1-217-500-column-H/PROTON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #47, Operator: slevinFile: PROTON01INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 16 repetitionsOBSERVE H1, 499.7550812 MHzDATA PROCESSINGFT size 32768Total time 0 min, 49 sec

0.89

0.86

1.88

1.99

2.79

1.10

2.14

1.63

1.00

1.00

ppm12345678910

O

ON2

MeO2C16

SL-1-217-125-C13

Sample: SL-1-217-125-C13File: indy/slevin/vnmrsys/data/SL-1-217-125-C13/CARBON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #46, Operator: slevinFile: CARBON01INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.042 sec Width 31446.5 Hz 1000 repetitionsOBSERVE C13, 125.6635136 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 2.0 HzFT size 65536Total time 34 min, 11 sec

ppm20406080100120140160180200

O

ON2

MeO2C16

SL-3-171-column-500-H

Sample: SL-3-171-column-500-HFile: indy/slevin/vnmrsys/data/SL-3-171-column-500-H/PROTON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #46, Operator: slevinFile: PROTON01INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 32 repetitionsOBSERVE H1, 499.7550816 MHzDATA PROCESSINGFT size 32768Total time 1 min, 38 sec

0.89

1.00

1.99

2.33

2.95

1.81

1.00

1.08

1.08

1.98

1.10

1.10

ppm123456789101112

O

O

MeO2C

S5

O

HO

MeO2C

SL-3-171-column1-500-H

Sample: SL-3-171-column1-500-HFile: indy/slevin/vnmrsys/data/SL-3-171-column1-500-H/CARBON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #47, Operator: slevinFile: CARBON01INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.042 sec Width 31446.5 Hz 1500 repetitionsOBSERVE C13, 125.6635192 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 0.5 HzFT size 65536Total time 51 min, 17 sec

ppm20406080100120140160180200

O

O

MeO2C

S5

O

HO

MeO2C

RRN-2-289-2

Sample Name: RRN-2-289-2 Data Collected on: indy.caltech.edu-inova500 Archive directory: /home/nanir/vnmrsys/data Sample directory: RRN-2-289-2 FidFile: PROTON01

Pulse Sequence: PROTON (s2pul)Solvent: cdcl3Data collected on: Nov 15 2009

Temp. 25.0 C / 298.1 KSample #5, Operator: nanir

Relax. delay 2.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 32 repetitionsOBSERVE H1, 499.7550811 MHzDATA PROCESSINGFT size 32768Total time 2 min 10 sec 1.00

0.98

2.10

2.16

2.00

1.07

1.08

1.06

2.19

1.09

1.09

ppm12345678910

Plotname: --Not assigned--

O

O

NCS6

nitrile

Sample: RRN-2-289-2-13CFile: indy/nanir/vnmrsys/data/RRN-2-289-2-13C/CARBON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #6, Operator: nanirFile: CARBON01INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.042 sec Width 31446.5 Hz 1000 repetitionsOBSERVE C13, 125.6635136 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 0.5 HzFT size 65536Total time 34 min, 11 sec

ppm20406080100120140160180200

O

O

NCS6

SL-3-127-crude-500-H

Sample: SL-3-127-column-500-HFile: indy/slevin/vnmrsys/data/SL-3-127-column-500-H/PROTON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #46, Operator: slevinFile: PROTON01INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 16 repetitionsOBSERVE H1, 499.7550812 MHzDATA PROCESSINGFT size 32768Total time 0 min, 49 sec

0.88

0.87

1.95

1.95

1.01

1.94

1.98

1.01

1.00

ppm12345678910

O

O

NC17

N2

SL-3-127-crude-500-H

Sample: SL-3-127-column-500-HFile: indy/slevin/vnmrsys/data/SL-3-127-column-500-H/CARBON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #46, Operator: slevinFile: CARBON01INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.042 sec Width 31446.5 Hz 1250 repetitionsOBSERVE C13, 125.6635200 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 0.5 HzFT size 65536Total time 42 min, 44 sec

ppm20406080100120140160180200

O

O

NC17

N2

SL-1-209-column2-500-H

Sample: SL-1-209-column2-500-HSample ID: s_20090409_17File: home/slevin/vnmrsys/data/Autosave/2009Apr09/Proton_02.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #48, Operator: slevinFile: Proton_02INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 64 repetitionsOBSERVE H1, 499.7550750 MHzDATA PROCESSING Resol. enhancement -0.0 HzFT size 65536Total time 3 min, 21 sec

0.88

0.88

1.01

3.05

1.00

2.11

2.13

1.08

1.02

0.78

ppm12345678910

O

H

O H

18

SL-1-209-125-13C

Sample: SL-1-209-prepTLC-F2-500-HSample ID: s_20090409_26File: home/slevin/vnmrsys/data/Autosave/2009Apr10/Carbon_01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #41, Operator: slevinFile: Carbon_01INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.300 sec Width 30165.9 Hz 7000 repetitionsOBSERVE C13, 125.6635136 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 1.0 HzFT size 131072Total time 4 hr, 29 min, 22 sec

ppm20406080100120140160180200

O

H

O H

18

SL-3-191-purified-500-H

Sample: SL-3-191-purified-500-HFile: indy/slevin/vnmrsys/data/SL-3-191-purified-500-H/PROTON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #49, Operator: slevinFile: PROTON01INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 128 repetitionsOBSERVE H1, 499.7550816 MHzDATA PROCESSING Line broadening 0.3 HzFT size 32768Total time 6 min, 31 sec

0.92

0.91

4.12

1.96

1.10

2.27

2.15

3.00

ppm12345678910

O

OCH3

H

19

SL-3-191-1-125-13C

Sample: SL-3-191-1-125-13CFile: data/indy/slevin/vnmrsys/data/SL-3-191-1-125-13C/CARBON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #46, Operator: slevinFile: CARBON01INOVA-500 "erice.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.000 sec Width 31446.5 Hz 14100 repetitionsOBSERVE C13, 125.6635136 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 0.5 HzFT size 65536Total time 8 hr, 11 min, 48 sec

ppm20406080100120140160180200

O

OCH3

H

19

*

* - “grease” 29.7 ppm

SL-3-103-F3-column-500-H

Sample: SL-3-103-F3-storage-500-HFile: indy/slevin/vnmrsys/data/SL-3-103-F3-storage-500-H/PROTON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #46, Operator: slevinFile: PROTON01INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 16 repetitionsOBSERVE H1, 499.7550811 MHzDATA PROCESSINGFT size 32768Total time 0 min, 49 sec

0.82

0.82

1.87

1.86

1.00

1.91

2.80

1.03

ppm12345678910

O

OCN

21

SL-3-103-pHPLC-500-H

Sample: SL-3-103-pHPLC-500-HFile: indy/slevin/vnmrsys/data/SL-3-103-pHPLC-500-H01/CARBON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #47, Operator: slevinFile: CARBON01INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.042 sec Width 31446.5 Hz 13900 repetitionsOBSERVE C13, 125.6635158 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 1.0 HzFT size 65536Total time 7 hr, 55 min, 10 sec

ppm20406080100120140160180200

O

OCN

21

monoester alcohol

Sample: RRN-1-262-6File: indy/nanir/vnmrsys/data/RRN-1-262-6/PROTON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #45, Operator: nanirFile: PROTON01INOVA-500 "erice.caltech.edu"

Relax. delay 5.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 64 repetitionsOBSERVE H1, 499.7550816 MHzDATA PROCESSINGFT size 32768Total time 7 min, 37 sec

2.00

3.10

1.12

1.91

2.22

0.95

0.99

ppm12345678910

MeO2C

OH

S7

monoester alcohol

Sample: RRN-1-262-2File: indy/nanir/vnmrsys/data/RRN-1-262-2/CARBON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #40, Operator: nanirFile: CARBON01INOVA-500 "erice.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.042 sec Width 31446.5 Hz 512 repetitionsOBSERVE C13, 125.6635324 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 0.5 HzFT size 65536Total time 18 min, 14 sec

ppm20406080100120140160180200

MeO2C

OH

S7

RRN-2-266-3

Sample Name: RRN-2-266-3 Data Collected on: indy.caltech.edu-inova500 Archive directory: /home/nanir/vnmrsys/data Sample directory: RRN-2-266-3 FidFile: PROTON01

Pulse Sequence: PROTON (s2pul)Solvent: cdcl3Data collected on: Nov 24 2009

Temp. 25.0 C / 298.1 KSample #45, Operator: nanir

Relax. delay 2.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 32 repetitionsOBSERVE H1, 499.7550811 MHzDATA PROCESSING Line broadening 0.3 HzFT size 32768Total time 2 min 10 sec

2.00

3.01

1.01

4.03

0.79

0.85

14.69

ppm12345678910

Plotname: --Not assigned--

MeO2C

O Si(i-Pr)2

23

RRN-2-266-3

Sample Name: RRN-2-266-3 Data Collected on: indy.caltech.edu-inova500 Archive directory: /home/nanir/vnmrsys/data Sample directory: RRN-2-266-3 FidFile: CARBON01

Pulse Sequence: CARBON (s2pul)Solvent: cdcl3Data collected on: Nov 25 2009

Temp. 25.0 C / 298.1 KSample #45, Operator: nanir

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.042 sec Width 31446.5 Hz 4000 repetitionsOBSERVE C13, 125.6635136 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 0.5 HzFT size 65536Total time 2 hr, 16 min

ppm20406080100120140160180200220

Plotname: --Not assigned--

MeO2C

O Si(i-Pr)2

23

RRN-2-269-2

Sample Name: RRN-2-269-2 Data Collected on: indy.caltech.edu-inova500 Archive directory: /home/nanir/vnmrsys/data Sample directory: RRN-2-269-201 FidFile: PROTON01

Pulse Sequence: PROTON (s2pul)Solvent: cdcl3Data collected on: Oct 28 2009

Temp. 25.0 C / 298.1 KSample #45, Operator: nanir

Relax. delay 2.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 32 repetitionsOBSERVE H1, 499.7550811 MHzDATA PROCESSINGFT size 32768Total time 2 min 10 sec 0.99

0.99

2.08

3.00

1.02

2.11

2.12

1.98

12.17

ppm12345678910

Plotname: --Not assigned--

Si(i-Pr)2

O

MeO2C

24

RRN-2-269-2

Sample Name: RRN-2-269-2 Data Collected on: indy.caltech.edu-inova500 Archive directory: /home/nanir/vnmrsys/data Sample directory: RRN-2-269-201 FidFile: CARBON01

Pulse Sequence: CARBON (s2pul)Solvent: cdcl3Data collected on: Oct 28 2009

Temp. 25.0 C / 298.1 KSample #45, Operator: nanir

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.042 sec Width 31446.5 Hz 1500 repetitionsOBSERVE C13, 125.6635136 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 0.5 HzFT size 65536Total time 51 min

ppm20406080100120140160180200

Plotname: --Not assigned--

Si(i-Pr)2

O

MeO2C

24

RRN-2-272-6

Sample: RRN-2-272-6File: home/slevin/vnmrsys/data/RRN-2-272-6.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KOperator: slevinFile: RRN-2-272-6INOVA-500 "urbino.caltech.edu"

Relax. delay 2.000 sec Pulse 45.0 degrees Acq. time 2.049 sec Width 9594.6 Hz 16 repetitionsOBSERVE H1, 599.6613025 MHzDATA PROCESSING Resol. enhancement -0.0 HzFT size 65536Total time 1 min, 13 sec

0.95

0.98

2.00

0.92

2.05

2.02

1.95

11.91

ppm12345678910

Si(i-Pr)2

O

HO2C

S8

RRN-2-272-3

Sample Name: RRN-2-272-3 Data Collected on: indy.caltech.edu-inova500 Archive directory: /home/nanir/vnmrsys/data Sample directory: RRN-2-272-3 FidFile: CARBON01

Pulse Sequence: CARBON (s2pul)Solvent: cdcl3Data collected on: Nov 23 2009

Temp. 25.0 C / 298.1 KSample #1, Operator: nanir

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.042 sec Width 31446.5 Hz 1000 repetitionsOBSERVE C13, 125.6635166 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 0.5 HzFT size 65536Total time 34 min

ppm20406080100120140160180200

Plotname: --Not assigned--

Si(i-Pr)2

O

HO2C

S8

silyl diazo ketone

Sample: RRN-2-275-3File: indy/nanir/vnmrsys/data/RRN-2-275-3/PROTON02.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #1, Operator: nanirFile: PROTON02INOVA-500 "urbino.caltech.edu"

Relax. delay 2.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 32 repetitionsOBSERVE H1, 499.7550812 MHzDATA PROCESSINGFT size 32768Total time 2 min, 10 sec

0.96

0.98

0.80

2.00

0.85

0.98

1.09

0.94

1.07

1.96

11.86

ppm12345678910

Si(i-Pr)2

O

S9

O

N2

H

silyl diazo ketone

Sample: RRN-2-275-2File: indy/nanir/vnmrsys/data/RRN-2-275-2/CARBON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #1, Operator: nanirFile: CARBON01INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.042 sec Width 31446.5 Hz 1500 repetitionsOBSERVE C13, 125.6635136 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 2.0 HzFT size 65536Total time 51 min, 17 sec

ppm20406080100120140160180200

Si(i-Pr)2

O

S9

O

N2

H

SL-3-123-column-500-H

Sample: SL-3-123-column-500-HFile: indy/slevin/vnmrsys/data/SL-3-123-column-500-H01/PROTON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #46, Operator: slevinFile: PROTON01INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 32 repetitionsOBSERVE H1, 499.7550750 MHzDATA PROCESSINGFT size 32768Total time 1 min, 38 sec

0.92

0.93

1.97

2.78

1.00

0.67

1.27

0.99

2.04

0.91

1.95

11.68

ppm12345678910

Si(iPr)2

O

OOMe

25

SL-3-123-column-500-H

Sample: SL-3-123-column-500-HFile: indy/slevin/vnmrsys/data/SL-3-123-column-500-H01/CARBON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #46, Operator: slevinFile: CARBON01INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.042 sec Width 31446.5 Hz 1500 repetitionsOBSERVE C13, 125.6635171 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 0.5 HzFT size 65536Total time 51 min, 17 sec

ppm20406080100120140160180200

Si(iPr)2

O

OOMe

25

SL-3-125-column-500-H

Sample: SL-3-125-column-500-HFile: indy/slevin/vnmrsys/data/SL-3-125-column-500-H01/PROTON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #46, Operator: slevinFile: PROTON01INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 16 repetitionsOBSERVE H1, 499.7550812 MHzDATA PROCESSINGFT size 32768Total time 0 min, 49 sec

0.94

0.95

1.99

1.85

1.02

1.01

0.98

2.00

1.01

1.00

1.90

11.59

ppm12345678910

Si(i-Pr)2

O

O

S10NC

SL-3-125-column-500-H

Sample: SL-3-125-column-500-HFile: indy/slevin/vnmrsys/data/SL-3-125-column-500-H01/CARBON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #46, Operator: slevinFile: CARBON01INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.042 sec Width 31446.5 Hz 1250 repetitionsOBSERVE C13, 125.6635196 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 0.5 HzFT size 65536Total time 42 min, 44 sec

ppm20406080100120140160180200

Si(i-Pr)2

O

O

S10NC

SL-3-129-column-500-H

Sample: SL-3-129-column-500-HFile: indy/slevin/vnmrsys/data/SL-3-129-column-500-H/PROTON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #46, Operator: slevinFile: PROTON01INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 32 repetitionsOBSERVE H1, 499.7550812 MHzDATA PROCESSINGFT size 32768Total time 1 min, 38 sec

0.94

0.96

1.99

1.00

1.97

2.00

1.01

1.01

1.88

11.63

ppm12345678910

Si(iPr)2

O

O

26NCN2

SL-3-129-column-500-H

Sample: SL-3-129-column-500-HFile: indy/slevin/vnmrsys/data/SL-3-129-column-500-H/CARBON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #46, Operator: slevinFile: CARBON01INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.042 sec Width 31446.5 Hz 1500 repetitionsOBSERVE C13, 125.6635136 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 2.0 HzFT size 65536Total time 51 min, 17 sec

ppm20406080100120140160180200

Si(iPr)2

O

O

26NCN2

SL-3-177-column-500-H

Sample: SL-3-177-column-500-HFile: indy/slevin/vnmrsys/data/SL-3-177-column-500-H/PROTON02.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #46, Operator: slevinFile: PROTON02INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 128 repetitionsOBSERVE H1, 499.7550815 MHzDATA PROCESSING Line broadening 0.5 HzFT size 32768Total time 6 min, 31 sec

0.89

0.87

0.98

0.97

1.00

1.95

3.00

1.06

1.99

11.79

ppm12345678910

Si(i-Pr)2

O

CN

H

O27

SL-3-177-column-125-13C

Sample: SL-3-177-column-125-HFile: indy/slevin/vnmrsys/data/SL-3-177-column-125-H/CARBON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #46, Operator: slevinFile: CARBON01INOVA-500 "urbino.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.042 sec Width 31446.5 Hz 13750 repetitionsOBSERVE C13, 125.6635149 MHzDECOUPLE H1, 499.7575738 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 2.0 HzFT size 65536Total time 7 hr, 50 min, 3 sec

ppm20406080100120140160180200

Si(i-Pr)2

O

CN

H

O27

SL-3-253-F3-500-H

Sample: SL-3-253-F3-600-HFile: indy/slevin/vnmrsys/data/SL-3-253-F3-600-H/PROTON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #47, Operator: slevinFile: PROTON01INOVA-500 "erice.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 2.048 sec Width 8000.0 Hz 128 repetitionsOBSERVE H1, 499.7420463 MHzDATA PROCESSINGFT size 32768Total time 6 min, 43 sec

1.91

2.21

2.09

1.00

1.09

1.06

2.13

2.23

1.13

ppm12345678910

S11O

O

SL-3-253-F3-125-13C

Sample: SL-3-253-F3-125-13CFile: indy/slevin/vnmrsys/data/SL-3-253-F3-125-13C/CARBON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #48, Operator: slevinFile: CARBON01INOVA-500 "erice.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.042 sec Width 31446.5 Hz 5000 repetitionsOBSERVE C13, 125.6602375 MHzDECOUPLE H1, 499.7445450 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 2.0 HzFT size 65536Total time 2 hr, 58 min, 8 sec

ppm20406080100120140160180200

S11O

O

Std proton

Sample: SL-3-224-crude-600-HFile: data/fid/slevin/SL-3-253-F4-128-600-H.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KOperator: slevinFile: SL-3-253-F4-128-600-HINOVA-500 "erice.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 2.049 sec Width 9594.6 Hz 128 repetitionsOBSERVE H1, 599.6604896 MHzDATA PROCESSING Resol. enhancement -0.0 HzFT size 65536Total time 6 min, 56 sec

0.97

1.00

0.95

2.38

1.14

1.00

2.16

1.11

1.12

1.11

1.10

1.11

ppm12345678910

S12OO

SL-3-253-F4-125-13C-2

Sample: SL-3-253-F4-125-13C-2File: indy/slevin/vnmrsys/data/SL-3-253-F4-125-13C-2/CARBON01.fid

Pulse Sequence: s2pul

Solvent: cdcl3 Temp. 25.0 C / 298.1 KSample #49, Operator: slevinFile: CARBON01INOVA-500 "erice.caltech.edu"

Relax. delay 1.000 sec Pulse 45.0 degrees Acq. time 1.042 sec Width 31446.5 Hz 13800 repetitionsOBSERVE C13, 125.6602375 MHzDECOUPLE H1, 499.7445450 MHz Power 39 dB continuously on WALTZ-16 modulatedDATA PROCESSING Line broadening 1.0 HzFT size 65536Total time 8 hr, 11 min, 31 sec

ppm20406080100120140160180200

S12OO