100204_mb 2_ceridust and licoene .pdf

10.02.2010

Public

BU Additives

TM Waxes

Clariant Waxes forPigment & Additive MasterbatchesMasterbatch II Ceridust® & Licocene® for color preparation

02.2010BU Additives, TM Waxes (Copyright Clariant. All rights reserved.)

Public: Masterbatch Presentation Part II

Table of Contents

Base information on Clariant waxes (focus on Ceridust® & Licocene®)

Information on selected monoazo-pigments in PP and LLDPE

Information on selected diazo-pigments in PP

Information on selected polycyclic pigments in PP and LLDPE

Information on Cu-phtalocyanine in PC, PET and PA (concrete example)

Back-up

Summary

Base Information on Clariant Waxes

focused on Ceridust® & Licocene®


Public: Masterbatch Presentation Part II > Base Information on Clariant Waxes focused on Ceridust® & Licocene®

Wax-Types Used in MasterbatchValue Stories -Extract-

� excellent price-performance ratio due to

superior dispersion ability,

� oustanding technical performance in high

demanding fiber applications

Licocene PP 6102 FG,


Ceridust 6050 M

Dispersing aid

for PP MB

� better dispersion ability by lower content of

dispersing aid

� the same filter value is achieved,

� 5 - 10 % higher tensile strength,

� better compatibility


Ceridust 6050 M

MB

manufacturer in

China

� optimized production process and formula with

economies of >15 %,

� increased pigment load from 25 % to 50 %


Licocene PP 6102 FG

PP fiber

producer in

Latam

Key benefitProductCustomer



Wax-Types Used in MasterbatchValue Stories

� highly efficient dispersion agent for film and PP

fiber MBLicocene PP 6102 FG

Dispersing aid

for PP MB in

China

� superior filter value and color strength at the

sameCeridust 6050 M

MB producer in

Europe

Key benefitProductCustomer

source and full version available:

Teamroom Licocene grades for plastic application



The Clariant Wax RangeAbstract

non-polar polar

Licolub H 12

Ceridust 3715

Liocwax PED 521

Licowax PED 191

oxidized

Polyethylene

Waxes

Licocene PE MA 4351

Licocene PE MA 4221

Licocene PP MA 7452 TP


Licocene PP 7502 TP

Licocene PP 6502 TP

Licocene PP 2602

Licocene PP 1602

Licocene PP 1502

Licocene PP 1302

Licocene PP 6102

TP Ceridust 6050 M

Licocene PE 5301

Ceridust 130

Ceridust 3620

Licocene PE 4201

Liocwax PE 190

Licowax PE 520

Licowax PE 130

Ceridust 3910

Licowax C

Licomont ET 132

Ceridust 5551

Licomont ET 141

Licomont NaV 101

Licomont CaV 102

Licowax E

Licowax OP

Licolub WM 31

Licolub WE 40

Licolub WE 4

modified

Polypropylene/

Polyethylene WaxesPolyethylene

Waxes

Polypropylene

Waxes

Polyolefin Waxes Amide Waxes Montan Waxes

Licolub H 4

Hydrocarbon

Wax

Licolub CE 2 TP

highly modified

Polymer Wax



Clariant Wax used for Color PreparationsRecommended

non-polar polar

Licolub H 12

Ceridust 3715

Liocwax PED 521

Licowax PED 191

oxidized

Polyethylene

Waxes


Licocene PE MA 4221


Licocene PP 1502

Licocene PP 1602

Licocene PP 2602

Licocene PP 6102

Licocene PP 7502 TP

TP Ceridust 6050 M

Ceridust 130

Ceridust 3620

Licocene PE 4201

Liocwax PE 190

Licowax PE 520

Licowax PE 130

Ceridust 3910

Licowax C

Ceridust 5551

Licowax E

Licowax OP

Licolub WM 31

Licolub WE 40

Licolub WE 4

modified

Polypropylene/

Polyethylene WaxesPolyethylene

Waxes

Polypropylene

Waxes

Polyolefin WaxesAmide Waxes Montan Waxes

Licolub CE 2 TP

highly modified

Polymer Wax

Legal status of waxes from Clariant

with respect to Food Legislation (FDA)

is listed in DA 8250 E_11/06



The Licocene® Range Abstract

non-polar polar

Licocene PP 7502 TP

Licocene PP 6502 TP

Licocene PP 2602*

Licocene PP 1502*

Licocene PP 1302

Licocene PP 1602 *

Licocene PP 6102*

Polyethylene

Waxes

Polypropylene

Waxes

Polyolefin Waxes

Licocene®

as processing/dispersing aid

Licocene PE 4201*

Licocene PE 5301*

modified

Polyethylene

Waxes



Licocene PE MA 4221*

Licocene PE MA 4351

modified

Polypropylene

Waxes

*Licocene used in masterbatch



The Ceridust® Range Abstract

non-polar polar

Ceridust® 3715

oxidized

PE-wax

Ceridust® 3620

Ceridust® 130

PE-wax

PP-wax

Polyolefin

Waxes

Ceridust® 6050 M

Ceridust®

as

dispersing improver

Ceridust® 3910 Ceridust® 5551

Amide

WaxesMontan

Waxes

Compound-

Waxes

Ceridust® 9615 A

Legal status of waxes from Clariant

with respect to Food Legislation (FDA)

is listed in DA 8250 E_11/06



Influence of Particle Size and Amount of Wax30 % Cu-Phthalocyanine in LLDPE

0

2

4

6

8

10

12

14

16

18

without wax 10% Licowax

PE 520

15% Licowax

PE 520

20% Licowax

PE 520

15% PE 520 +

Ceridust 3620

(2:1)

20% PE 520 +

Ceridust 3620

(2:1)

filter pressure value [bar/g]

VN 86931 - 86941

filter value: DIN-EN 13900-5

filter: 40 µm, 725 meshpremix: cold mixing

decrease of filter pressure value (FPV) due to

finer particle size and higher amount of wax

� 30 % Pigment Blue 15:1 + 50 % LLDPE (MFR 25) + 13,3 % Licowax® PE 520 + 6,7 % Ceridust® 3620

In Medias Res -from Practice for Practice

Monoazo-Pigments in PP and LLDPE


Public: Masterbatch Presentation Part II > In Medias Res - from Practice for Practice Monoazo-Pigments in PP and LLDPE

Licocene® PP for Monoazo-Pigments40 % Naphtol AS in PP

0

1

2

3

4

5

6

7

30 % PP-Wax A (800 mPas) 30 % Licocene PP 6102 FG

Filter pressure value (FPV) in [bar/g]

95

100

105

110

115

120

125

rel. Color yield [%]

FPV

rel. Color yield

� 40 % Pigment Red 170 + 30 % PP HG 245 (Borealis) + 30 % Licocene PP 6102

premix: cold mixingfilter value: DIN-EN 13900-5

filter: 14 µm, 724 mesh

color yield: DIN 55986



Licocene® & Ceridust® for Monoazo-Pigments40 % Laked-Azo-Pigment in PP

0

2

4

6

8

10

20 % PP-Wax B

(1700 mPas)

30 % PP-Wax B +

Ceridust 6071 (2:1)

30 % Licocene PP 6102 +

C 6050 M (2:1)


80

85

90

95

100

105

110

115

120


FPV

rel. Color yield

� 40 % Pigment Red 48:2 + 30 % PP HG 245 (Borealis) + 20 % Licocene PP 6102 +

10 % Ceridust 6050 M

premix: hot mixing filter value: DIN-EN 13900-5

filter: 25 µm




Ceridust® for Monoazo-Pigments40 % Laked-Azo-Pigment in PP

0

2

4

6

8

10

12

14

without wax 20% Licowax

PE 520

30% Licowax

PE 520

20% PE 520 +

Ceridust 3620

(2:1)

30% PE 520 +

Ceridust 3620

(2:1)


90

95

100

105

110

115

120

125

130

135

140


FPV

rel. Color yield

� 40 % Pigment Red 57:1 + 30 % LLDPE (MFR 25) + 20 % Licowax PE 520 + 10 % Ceridust 3620



premix: cold mixing color yield: DIN 55986

VN 86196- 86203


Diazo-Pigments in PP


Public: Masterbatch Presentation Part II > In Medias Res - from Practice for Practice Diazo-Pigments in PP


0

5

10

15

20

20 % PP-Wax B 30 % Licocene PP 6102


95

100

105

110

115

120

125

130


FPV

rel. Color yield

� 40 % Pigment Yellow 155 + 30 % PP HG 245 (Borealis) + 30 % Licocene PP 6102 FG


filter: 40 µm




Licocene® & Ceridust® for Diazo-Pigments40 % Diazo-Condensation in PP

VN 94186 – 94201 // 94295 – 298

� 40 % Pigment Yellow 155 + 40 % PP HG 245 (Borealis) + 13 % Licocene PP 6102 + 7 % Ceridust 6050 M



premix: hot mixing film note: Clariant norm

0

2

4

6

8

10

20 % PP-Wax B 20 % Licocene

PP 6102 FG

13 % PP 6102 FG +

7 % Ceridust 6050 M

13 % PP 1302 +

7 % Ceridust 6050 M


1

2

3

4

5

6

Film

note

FPV

Film note

(excellent)

(bad)




0

5

10

15

20

30 % PP-Wax B 30 % PP-Wax A 30 % Licocene PP 6102


95

100

105

110

115

120

125

130


FPV

rel. Color yield

� 40 % Pigment Red 214 + 30 % PP HG 245 (Borealis) + 30 % Licocene PP 6102

premix: cold mixing filter value: DIN-EN 13900-5

filter: 25 µm



Polycylic Pigments:Quinacridone in PPCu-Phtalocyanine in PP and LLDPEDioaxine in PP


Public: Masterbatch Presentation Part II > In Medias Res - from Practice for Practice Polycylic Pigments: Quinacridone in PP Cu-Phtalocyanine in PP and LLDPE

Dioaxine in PP

Licocene® & Ceridust® for Polycyclic Pigments 30 % Quinacridone in PP

0

5

10

15

20

no wax 30% PP-Wax B +

Ceridust 6050M, (2:1)

30% Licocene PP 6102 +

Ceridust 6050M (2:1)


100

110

120

130

140


FPV

rel. Color yield

� 30 % Pigment Violett 19 + 40 % PP HG 245 (Borealis) + 20 % Licocene PP 6102 +

10 % Ceridust 6050 M

> 21 bar/g


filter: 25 µm




Dioaxine in PP

Licocene® & Ceridust® for Polycyclic Pigments 40 % Cu-Phtalocyanine in PP

0

2

4

6

8

10

12

15% PP-Wax A 10% Licocene PP 6102 +

Ceridust 6050M, (2:1)

15% Licocene PP 6102 +

Ceridust 6050 M, (2:1)


90

100

110


FPV

rel. Color yield

� 40 % Pigment Green 7 + 45 % PP HG 245 (Borealis) + 10 % Licocene PP 6102 + 5 % Ceridust 6050 M

premix: hot mixing filter value: DIN-EN 13900-5

filter: 25 µm




Dioaxine in PP

Licocene® PP for Polycyclic Pigments 40 % Cu-Phtalocyanine in LLDPE

0

0,2

0,4

0,6

0,8

1

1,2

30% Licowax PE

520

15% PP 1302 FG

+ PP 6102 FG (2:1)

15% PP 1502 FG 30% PP 1502 FG

+ PP 6102 FG (2:1)


0

50

100

150

200

250

300

Film

surface irregularities (specs) in

[number]

FPV

Film specs

� 40 % Pigment Green 7 + 30 % LLDPE (Borealis) + 20 % Licocene PP 1502 + 10 % Licocene PP 6102

premix: Haake-Kneader (roller type rotor); 120 °C; 40 rpm; 7 min.

application weight: 5 kg



film note : Clariant norm



Dioaxine in PP

Licocene® & Ceridust® for Polycyclic Pigments 40 % Cu-Phtalocyanine in LLDPE

0

0,2

0,4

0,6

0,8

1

1,2

1,4

1,6

1,8

2

30 % Licowax

PE 520

30 % PE 520 +

C 3620 (2:1)

30 % Licowax

PE 520

30 % PE 520 +

C 3620 (2:1)


500

600

700

800

900

1000

1100

1200

1300

1400

1500

Film

surface irregularities (specs) in

[number]

FPV

Film specs

� 40 % Pigment Green 7 + 30 % LLDPE (MFR 25) + 20 % Licowax PE 520 P + 10 % Ceridust 3620

15 kg/h 18 kg/h



film note : Clariant normpremix: cold mixing



Dioaxine in PP


0

2

4

6

8

10

12

14

16

Withou Wax 20 % Licowax PE 520 30 % Licowax PE 520 +

Ceridust 3610 (2:1)


94

96

98

100

102

104

106

108

110

112

114


FPV

rel. Color yield

� 40 % Heligonblue K-6907 + 40 % Escorene LL 6101 + 10 % Licowax PE 520 + 10 % Ceridust 3610


filter: 14 µm




Dioaxine in PP

Licocene® & Ceridust® for Polycyclic Pigments 40 % Cu-phtalocyanine in LLDPE

0

2

4

6

8

10

12

14

16


Ceridust 3610 (2:1)


90

95

100

105

110

115

120


FPV

rel. Color yield


premix: hot mixingfilter value: DIN-EN 13900-5

filter: 14 µm




Dioaxine in PP


0

2

4

6

8

10

12

14

16


Ceridust 3610 (2:1)


1

2

3

4

5

6

film

note

FPV

Film note

(excellent)

(bad)


premix: hot mixingfilter value: DIN-EN 13900-5

filter: 14 µm

film note : Clariant norm



Dioaxine in PP

Licocene® & Ceridust® for Polycyclic Pigments 40 % Dioazine in PP

0

1

2

3

4

5

6

7

8

9

10

20 % PP 6102 13 % PP 6102 +

7 % C 6050 M

13 %

PP 1302 +

7 % C 6050 M

13 %

PP 1302 +

7 % C 6050 M

20 % PP 6102 +

10 % C 6050 M


95

100

105

110

115

120


FPV

rel. Color yield

� 40 % Pigment PV Fast Violet RL (violett 23) + 30 % PP powder (MFI 25 g/10 min) +

20 % (13) Licocene PP 6102 FG + 10 % (7) Ceridust 6050 M

hot mix cold mix





Cu-Phtalocyanine in PC, PET and PA


Public: Masterbatch Presentation Part II > In Medias Res - from Practice for Practice Cu-Phtalocyanine in PC, PET and PA

Licowax® & Ceridust® used in PC-Masterbatch17 % Cu-Phtalocyanine in PC

0

5

10

15

20

25

30

without 3 %

Licowax E

3 % Ceridust

5551

2 % Licowax E

+ 1 % Ceridust

5551

3 %

Licowax C

Correlated haze

80

90

100

110

120

130

140

rel. Color yield in

[%]

Corr. Haze

rel. color yield

� 17 % Pigment Green 7 + 80 % PC powder + 2 % Licowax E + 1 % Ceridust 5551

color yield: DIN 55986premix: cold mixing

lowest

correlated haze

with Ceridust 5551

highest color yield with mixture

of Licowax E & Cerdiust 5551



Licowax® & Ceridust® used in PC-Masterbatch17 % Cu-Phtalocyanine in PC

Magnification:

4000x

No wax 3 % Licowax E 2 % Licowax E

1 % Ceridust 5551

(colour yield = 100 %) (colour yield =117 %) (colour yield = 131 %)

- TEM photographs of polycarbonate samples -

� Ultrafine sections of granules, thickness 60-80 [nm]; cutter type Ultracut E

(sample preparation by German manufacturer) sample preparation



Licolub® & Ceridust® used in PET-Masterbatch30 % Cu-Phtalocyanine in PET

0

5

10

15

20

25

30

1 % Licolub

WE 4

3 % Licolub

WE 4

5 % Licolub

WE 4

2 % Licolub

WE 4 + 1 %

Ceridust 5551


80

90

100

110

120

130

140

rel. Color yield in

[%]

FPV

rel. color yield

� 30 % Pigment Green 7 + 69-65 % PET milled + 2 % Licolub WE 4 + 1 % Ceridust 5551

lowest FPV

with 5% Licolub WE 4

highest color yield with mixture

of Licolub WE 4 & Cerdiust 5551

premix: cold mixing color yield: DIN 55986filter value: DIN-EN 13900-5




Licolub® & Ceridust® used in PA-Masterbatch30 % Cu-Phtalocyanine in PA

0

1

2

3

4

5

6

7

8

without

wax

3 %

Licolub

WE 4

3 %

Licolub

CE 2

3 %

Licocene

PE MA

4221

3 %

Licowax E

3 %

Ceridust

9615

3 %

Ceridust

8020

3 %

Ceridust

5551


94

99

104

109

114

rel. Color yield in

[%]

FPV

rel. color yield

� 30 % Pigment Blue 15.3 + 67 % (PA) Aquamid AQ 500 milled + 3 % Ceridust 5551

premix: cold mixing color yield: DIN 55986filter value: DIN-EN 13900-5


Summary


Public: Masterbatch Presentation Part II > Summary

Summary

Ceridust® and Licocene® –

products, which meet your demands and bring your ideas in form

� Increased demands like

– Economical processing and cost compensation

– Stable production process and constant quality

– Fully compatible products for selected plastics

– Reduction of the agglomerates

– Reduction in screen filter blockage

– Reduction of specks, spots and surface irregularities

– Reduction in number of extrusions

always a

step ahead

with:

Ceridust®

Licocene®


Public: Masterbatch Presentation Part II > Summary

Summary

� High quality masterbatches are achievable by the use of

– Well defined waxes:

– Licowax®, Licolub®, Licomont®

– Micronized waxes (particle: < 0,025 mm) :

– Ceridust®

– Metallocene waxes:

– Licocene®

Finis

Thank you

Questions?

Hermann Diem, Feb. 2009

Back-up


Public: Masterbatch Presentation Part II > Back-up

The Licocene® PP-Range Technical Data



The Licocene® PE-Range Technical Data



The Licocene® Modified Range Technical Data



2 .00 0

4 .00 0

6 .00 0

8 .00 0

10 .00 0

12 .00 0

14 .00 0

16 .00 0

18 .00 0

20 .00 0

22 .00 0

24 .00 0

26 .00 0

28 .00 0

30 .00 0

32 .00 0

34 .00 0

36 .00 0

40 .00 0

m P a ·s

8 0 9 0 1 00 110 12 0 1 30 140 1 50 16 0 17 0 18 0°C

visc. [mPas]

Temp. [°C]

PP 1502PP 3502

PP 2602

� Licocene® PP 1502 and 2602

The Licocene® PP Range Viscosity vs. Temperature



The Ceridust® Range Physical Data

~7~125~0,970PE-waxCeridust® 3615

< 20 (d100)~145~0,9< 1PP-waxTP Ceridust® 6050 M

~8~96~1,113 - 18partly saponified ester of

montanic acidsCeridust® 5551

~6~142~1,05 - 8amide waxCeridust® 3910

~8~125~0,972 - 5polar modified PE-waxCeridust® 3715



d50 [µm][°C][g/cm³][mg/KOH/g]

paticle sizedrop pointdensityacid valuedescriptionproduct

100204_mb 2_ceridust and licoene .pdf

Documents