2 countries 10,000 added value to biogas · pentair biogas 3 co2fermentation and purification...
TRANSCRIPT
14-5-2019
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PENTAIR 1
PRODUCT LINE MANAGEMENT
PRESENTER: NIELS DEN HEIJER
DATE: MAY 8, 2019
BIOGAS UPGRADING
BIOMETHANE & LIQUID CO2
ADDED VALUE TO BIOGAS
PENTAIR
130 locations
United in our belief that the future
of water depends on us
In 34 countries
10,000employees
PENTAIR Biogas 3
CO2 fermentation and purification technologiesfor efficient and safeendproducts.
An extensive product portfolio within qualityand control components.
Innovative solutions – alsofor craft brewers.
Beverage: BreweriesSoft drink bottlersCraft brewersDistilleries
CO2 capture and recoverytechnologies for obtaininga safe endproduct evenfrom a low purity source.
The plants are delivering an end-product that exceedsthe highest demands form ISBT and EIGA.
Industrial Gases: PetrochemicalLarge industrial groupsIndependent gascompanies
Recovery and upgradingplants for ‘zero-methane’ slip solutions.
The upgrading plants areavailable with two differenttechnologies, dependingon need and plant size.
The recovery plants offer a second value stream.
Energy:Biogas plantsFarmers Industrial GasesLandfill
Safe CO2 technology for remineralising the desaltedseawater, in order to supply regions with scarcewater resources.
The plants are efficient and available and an importantingredient in deliveringdrinking water to the people.
Desalination:ContractorsDesalination plantconsortiums
Relocation of an existingCO2 plant, extending the capicity or developing a special technology for scientific purposes.
Process Services:UniversitiesAny existing projectsor company
After Market Service Serious Service is covering all segment,
offering an extensive service programmeglobally.
PENTAIR
STORIES TO SHAREHaffmans story short
Union Engineering’s story short
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FoundedIn Fredericia, Denmark
First CO2
plant installed; Coca Cola, Iran
Acquired byBritish Oxygen Company BOC )
1933
1948
1972
Foundedin Venlo, Holland
1984
Acquired by Norsk Hydro Danmark
1994
Sales and productionin China established
1995
Sales and productionin Brazilestablished
2013
Acquisitionof Wittemann, USA
ECO2Brew launched
Acquired by Pentair
CO2mpactBrewlaunched
2017
1967
First CO2
Gehaltemeter, Type GMT
1977
Started to produce CO2
recoverysystems
First Biogas upgradingplantsinstalled
2010
Digital CO2/O2
GehaltemeterType c-DGM
20062009
Acquired by Norit togetherwith Südmo
Haffmans, Südmo, NoritProcess Technology and X-Flow acquired by Pentair
2011
Combinedforces allow us to offer greattechnologies, components, units andSeriousServiceglobally!
PENTAIR Biogas5
SEGMENT: ENERGY
LEADING PARTNER IN BIOGAS UPGRADING
PENTAIR
LEADING PARTNER IN CO2 & BIOGAS UPGRADING
20.000+
MEASUREMENT DEVICES
40+
MEMBRANEPLANTS
300+
AMINE PLANTS
1400+
CO2 PLANTS
HAFFMANS & UNION: COMBINING 60 YEARS OF PROCESS TECHNOLOGY6
CO2/O2 in BreweriesBioSENSE
5000 Nm3/h Biogas55000 Nm3/h Industrial
3 Stage & 2 Stage with CO2
> 3000 Nm3/hNo Methane Slip
Market Leader inBreweries & CSD
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PENTAIR
BIOMETHANE APPLICATIONS
- USE the CH4 as fuel
- Bio-CNG (LNG) for:
- Trucks
- Buses
- Cars
- USE the CH4 for pipeline injection
- Bio-methane for:
- Transportation
- Electricity
- Heat
PENTAIR Beverage SystemsPENTAIR Process TechnologyPENTAIR
CO2 APPLICATIONS
FROM FEEDSTOCK TO GREEN CO2
THE FUTURE: DRY ICE – POWER-TO-GAS – POWER-TO-LIQUID
PENTAIR
SUSTAINABLE GAS SOLUTIONS – ENERGY/BIOGAS
STANDARDMembrane Solution
Without
CO2-Liquefaction<0,5% METHANE LOSS
ADVANCEDMembrane Solution
Without
CO2-Liquefaction0% METHANE LOSS
ADVANCED plusMembrane Solution
Including
CO2-Liquefaction0% METHANE LOSS
PR
OD
UC
TS
BIO-METHANE→GRID INJECTION
BIO-METHANE → CNG
FOODGRADE CO2
LNGFUTURE SOLUTION
BIO-METHANE→GRID INJECTION
BIO-METHANE → CNG
LNG FUTURE SOLUTION
BIO-METHANE→GRID INJECTION
BIO-METHANE→ CNG
LNG FUTURE SOLUTION
PR
OD
UC
TS
PR
OD
UC
TS
CURRENT PENTAIR PORTFOLIO
ELECTRICITY
LOCAL HEAT
PRODUCT
ANAEROBIC DIGESTION
PRE-TREATMENT (COOLING, HEATING, H2S REMOVAL)
WASTE STREAMS ENERGY CROPS LANDFILL
CHPBIOGAS UPGRADING –PRODUCT PORTFOLIO
WASTE WATER MANURE
AMINE Solution
OptionalCO2-Liquefaction
<0,1% METHANE LOSS
BIO-METHANE→GRID INJECTION
BIO-METHANE→ CNG
LNG SOLUTION
PR
OD
UC
TS
CO2 BOLT SOLUTION0% METHANE LOSS
EXISTING UPGRADER(PENTAIR OR NON PENTAIR)
FOODGRADE CO2
PR
OD
UC
TS
0% METHANE LOSS & CO2 ADDITIONAL REVENUEPENTAIR
BIOGAS UPGRADING - MEMBRANE GAS SEPARATION
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PENTAIR
Low Pressure Stage
ScrubberChillerHeater
Activ Carbon(H2S/VOC)
Low PressureConditioning
High Pressure Stage
Compression High PressureConditioning
Membrane Stage 1 & 2
1st Stage 2nd Stage
Biogas AD
TemperatureConditioning
Revenue Stream
QualityControl
Flare
Membrane Stage 3
3rd Stage
BioMethane
Flare / Digester
Methane Recovery
BIOGAS UPGRADING - STANDARD
BIOGAS PART
Membrane SeparationFan Blower
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Vent
PENTAIR
Low Pressure Stage
ScrubberChillerHeater
Activ Carbon(H2S/VOC)
Low PressureConditioning
High Pressure Stage
Compression High PressureConditioning
Membrane Stage 1 & 2
1st Stage 2nd Stage
Biogas AD
TemperatureConditioning
Revenue Stream
QualityControl
Flare
High Pressure Stage
Compression High PressureConditioning
Purification & Liquefaction Stage
RegenerativeActiv Carbon& Drier
CO2 Liquefier Stripper -Reboiler
BioMethane
BIOGAS PART
Membrane Separation
CO2 PART
Cryogenic Separation
Flare / DigesterMethane Recovery Green CO2 to free air /
Local gas consumption
Fan Blower
BIOGAS UPGRADING - ADVANCED
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9 10
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PENTAIR
Low Pressure Stage
ScrubberChillerHeater
Activ Carbon(H2S/VOC)
Low PressureConditioning
High Pressure Stage
Compression High PressureConditioning
Membrane Stage 1 & 2
1st Stage 2nd Stage
Biogas AD
TemperatureConditioning
Revenue Stream
QualityControl
Flare
High Pressure Stage
Compression High PressureConditioning
Purification & Liquefaction Stage
RegenerativeActiv. Carbon& Dryer
CO2 Liquefier Stripper -Reboiler+ Pump
BioMethane
Revenue Stream
Liquid CO2
Storage tankFoodgrade
Liquid CO2
BIOGAS PART
Membrane Separation
CO2 PART
Cryogenic Separation
Flare / DigesterMethane Recovery
Fan Blower
BIOGAS UPGRADING ADVANCED plus
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Green CO2 to free air /
Local gas consumption
INTEGRATED PROCESS – NO CH4 SLIP – FOOD-GRADE CO2 – LESS ENERGYPENTAIR
ADDITIONAL REVENUE WITH CO2 -BOLT-ONBiogas AD
Flare
High Pressure Stage
Compression High PressureConditioning
Purification & Liquefaction Stage
RegenerativeActiv Carbonand Drier
CO2 LiquefierSystem
Reboiler +Stripper + Pump
Revenue Stream
Liquid CO2
Storage tank
EXISTING BIOGAS
UPGRADING PLANT
CO2-Bolt-On
Methane Recovery ~2% of Biogas flow
• CO2 purity acc EIGA Specs
Foodgrade
Liquid CO2
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Green CO2 to free air /
Local gas consumption
PENTAIR
Low Pressure StageScrubberChillerHeater
Activ Carbon(H2S/VOC)
Low PressureConditioning
First StageAbsorbor
Second StageH2S Polishing Compressor
Biogas AD
Dryer
Revenue StreamQualityControl
Flare
BioMethane
Flare / Digester
Fan Blower
BIOGAS UPGRADING – Amine Solution
BASED ON OVER 60 YEARS OF EXPERT KNOWLEDGE15
Water Scrubber
StripperReboiler
Amine Treatment
Heat for Digester
High Pressure Stage
Compression High PressureConditioning
Purification & Liquefaction Stage
RegenerativeActiv Carbon& Drier
CO2 Liquefier Stripper -Reboiler
Optional CO2 PART
Cryogenic Separation
PENTAIR
REFERENCES BIOGAS UPGRADING AND BOLT-ON CO2
Our installed plants can fuel 133,000 homes or 275,000 cars
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South Africa & Philippines
1 Advance Plus2 CO2 recovery plants
North America3x3220Nm3/hSupported by
US offices
UK & Ireland10x Standard Solution 2x Advanced Solution
6x Advanced Plus Solution1x Bolt-on Solution
Support byIreland office
Scandinavia-1x Standard Solution
-1x Amine SolutionSupport by
DK office
Central Europe4x Standard Solution5x Advanced Solution
5x Advanced Plus SolutionSupport by
NL office
PENTAIR
BIOGAS UPGRADING in Nederland
In 2018 was de productie van Bio-methaan +/- 1,170 GWh (source EBA)
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NL AD – Bio-Methane2018 :
268 bio gas installaties met WKKGeïnstalleerd vermogen 119 MW
Totaal geleverd vermogen 17,0840,720 GWh
34 installaties met bio-methaan productieTotaal geleverd vermogen van 1,170 GWh
6 AD installaties leveren CO2
PENTAIR
NL 2011: 450 Nm3/h BIOGAS TO GRID & GREEN CO2
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6 YEARS OF LIQUID CO2 RECOVERY
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PENTAIR
BIOGAS UPGRADING – COMPACT ENCLOSED SKID
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KALUNDBORG BIOENERGI
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BIGADAN BUILDS BIGGEST BIOGAS PLANT IN DK
5000 Nm3/h heat recovery to AD
PENTAIR
Westdorpe (Aben) 2018
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Start productie Q1 2019
3600 Nm3/h Biogas Jaarlijkse product Bio-methaan : +/- 19 -20 miljoen Nm3 Jaarlijkse productie CO2: +/- 21,000 Ton
PENTAIR
CO2 from Biogas
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Niels den HeijerProduct Line Manager – BiogasHaffmans [email protected]+31 77 3232 396
PENTAIR PENTAIR Process TechnologyPENTAIR
CO2 FROM BIOGAS – QUALITY & EXPERIENCE
FURTHER REFERENCES IN SOUTH AFRICA, USA and PHILIPINES
FOOD SAFETY RISK ASSESSMENT
WITH INDUSTRIAL GAS COMPANY
• Food safety risk assessment completed
• Inline / complete batch analysis before supply
(30 vs. 9 components for industrial CO2)
• 1200+ EIGA samples since 2015
• CO2 complies with food-grade requirements
• Test result: < 2 bacteria / dm3
NL EXPERIENCE
• First plant in operation since 2011
• Mainly bio-waste, vegetable & food waste
• Higher level of impurities -> process control
• CO2 goes via industrial gas companies and
OCAP pipeline mainly to greenhouses
• Demand driven by greenhouses
UK EXPERIENCE
• Energy crops / unprocessed vegetable matter
• High quality -> low risk
• CO2 goes via industrial gas companies to
food & beverage and industrial applications
• Shortage in conventional sources -> imports
• Regional demand & distant industrial sources
PENTAIR 24
SECURITY AND FUTURE PROOFING
CO2 - QUALITY
Food Grade-EIGA DOC 70/08 UK Industrial Grade
-Stricter Values required-Detailed analysis is required-FSRA Mandatory by law
Current Feed stock: Unprocessed vegetable matter + Energy Crops
• FSRA Air Liquide & Pentair has been completed
• Since July 2015 > 400 samples have been analysed
according to the EIGA standard
• Key Indicaters to be installed to avoid non-conforming
product
Air Liquide + Pentair-Haffmans
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PENTAIR TECHNICAL & ECONOMIC FEASIBILITY OF SUSTAINABLE CO2 FROM BIOGAS
CURRENT NL Bio CO2 to greenhouses (OCAP)
OCAP
• 300.000 ton CO2 jaarlijks via OCAP
• Vraag glastuinbouw +/- 2 miljoen ton
• OCAP ontvangst station in Rotterdam
• +/- 4 AD installaties leveren nu aan OCAP
• Ruimte voor meer!
PENTAIR TECHNICAL & ECONOMIC FEASIBILITY OF SUSTAINABLE CO2 FROM BIOGAS
Nr. Plant Location Process
1. Air Liquide Ince Fertiliser
2. Air Liquide Wissington Bio-ethanol
3. Azelis Billingham Fertiliser
4.NorthBritish
EdinburghDistillery
Fermentation
5. Yara TeessideBio-ethanol
(Mothballed) + Import terminal
6 Yara Purfleet Import Terminal
CURRENT UK CO2 PRODUCTION SITES
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3
4
5
Air Liquide3rd PartyYara
North British
Yara (Teesside)
Azelis
AL - Ince
AL - Wissington
CO2 Import terminal
CO2 Import terminal
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Yara (Purfleet)
1
Centralized supply model
• Demand: 500.000 t/a
• Capacity: 450.000 t/a
• Few main production sites
• Import: 100.000 t/r (Shipment every week)
• 9 AD-Plants: 65.000 t/a
PENTAIR
METHANE SLIP, GHG AND RHI IMPACT
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0
5
10
15
20
25
30
35
Maize (1% CH4 loss) Maize (0% CH4 loss)
GH
G E
mis
sio
ns
(gC
O2
e/M
J o
f b
iom
eth
ane
inje
cte
d)
Scenario
Biogas upgrading - other
Biogas upgrading - methane slip
Biogas Production
Silage - production & transport
Harvesting - diesel
Cultivation - diesel
Pesticides
Soil N2O emissions
Fertiliser Production
Seed
1 %
0 %27.5 – possible future GHG limit?
34.8 – current GHG limit
PENTAIR
Questions?
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Niels den HeijerProduct Line Manager – BiogasHaffmans [email protected]+31 77 3232396
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