(216871532) msds

OIL & NATURAL GAS CORPORATION LIMITED

HAZIRA PLANT, SURAT

MATERIAL SAFETY DATA SHEET (MSDS)

MATERIAL SAFETY DATA SHEET

SL NOS.CONTENTSPAGE NOS.

AA)PRODUCTS

1AVIATION TURBINE FUEL1-2

2HIGH SPEED DIESEL3-4

3KEROSENE5-6

4LIQUIFIED PETROLEUM GAS7-8

5NAPHTHA9-10

6PROPANE11-12

7SWEET GAS13-14

BB)BY PRODUCTS

8HYDROGEN SULPHIDE15-16

9SULPHUR17-18

10SULPHUR DIOXIDE19-20

CC)PROCESS CHEMICALS

11CHLORINE21-22

12ETHYL MERCATAN23-24

13HYDRO CHLORIC ACID25-26

14HYDRAZINE27-28

15METHANOL29-30

16METHYL DIETHANOL AMINE31-32

17POTASSIUM HYDROXIDE33-34

18SODIUM HYDROXIDE35-36

19SULPHURIC ACID37-38

20TRI ETHYELNE GLYCOL39-40

21UREA41-42

DD)FIRE FIGHTING CHEMICALS

22AQUEOUS FILM FORMING FOAM43-44

23DRY CHEMICAL POWDER45-46

(AQUEOUS FILM FORMING FOAM)

1. CHEMICAL IDENTITYRegulated Identification

Chemical NameN/A, this is a mixtureShipping nameFire fighting chemicals

SynonymsCodes/Label

Trade NameHazardous Waste

Chemical ClassificationMIXTUREHazchem Code

FormulaN/AHazardousclassification

Hazardous IngredientsC.A.S.No.C.A.S. No.

112-34-5U.N. No.

Hazardous IngredientsC.A.S.No.

2.PHYSICAL/CHEMICAL DATAPhysical stateLiquid

Boiling Pt/Range100CVapour Pressure@35CNot determined

Melting/Freezing Pt.Ph--

Vapour Density (Air =1)1AppearanceClear Amber coloured liquid

Specific Gravity (Water =1)1.01OdourMild sweet odour

Solubility, In water at 30CSoluble (100%)Others(Molecular wt)--

3.FIRE /EXPLOSION HAZARD DATAFlammabilityNO

Auto ignition TemperatureCN.A.TDG Flammability

Explosion sensitivity to impactLEL

Explosion sensitivity to staticElectricityUEL

Hazardous combustion productsFlash Point CN.A.

Hazardous PolymerizationWill not occurFlash Point C

OxidiserCombustible Liquid

Organic PeroxideFlammable Material

Corrosive MaterialPyrophoric Material

OthersExplosive MaterialNo

4. REACTIVITY DATAChemical stability - Stable

Incompatibility with other materialReactive metals, any material reactive with water & give electrical connection

Reactivity

Hazardous Reaction Prods.None

5. HEALTH HAZARD DATARoutes of Entry : Eye contact, Skin contact, Inhalation & Ingestion

Effects of Exposure/ SymptomsInhalation : Inhalation is not anticipated to be a problem. Ingestion : Low oral riskwhen used as intended, may cause Nausea, do not induce vomiting when ingested. Skin & Eye contact : May cause mild transient irritation. Emergency treatment : Inhalation : Remove victim to fresh air area, Seek medical attention, if discomfort continues. Ingestion : If Patient is conscious, give large amount of water & do not induce vomiting, seek medical help. Skin : Wash with soap & water if irritation persist. Seek medical attention. Eye contact : Flush with large amount of gentle flowing water, if irritation persists, seek medical attention.

LD50 (oral Rat)NFPA Hazard Signals

Permissible exposure limitHealth 0

TLV (ACGIH)Flammability 0

STELReactivity 0

Odour ThresholdSpecial -

IDLH


MATERIAL SAFETY DATA SHEET (AQUEOUS FILM FORMING FOAM )6. PREVENTIVE MEASURES :

Personnel ProtectiveEquipmentUse protective rubber hand gloves & chemical goggles for eye protection.

Handling &StoragePrecautionsRecommended storage environment is within +40 to 0C. Store product inoriginal shipping container or tank design for product storage.

7. EMERGENCY/ FIRST AID MEASURES :

FIRE

Fire Extinguishing MediaThis is an extinguishing agent

Special ProcedureUnusual HazardsRinse floor thoroughly with water as material is slippery. Prevent material from reaching sewers or water ways to avoid nuisance foaming.--None

Exposure

First Aid measures/ Emergency Treatment

Inhalation : Remove victim to fresh air area. Seek medical attention if discomfort continues. Ingestion : IfPatient is conscious, give large amount of water & do not induce vomiting. Seek medical help. Eyes : Flush with large amount of gentle flowing water, if irritation persist, seek medical attention. Skin : Wash with soap & water. If irritation persists, seek medical attention.

Antidotes/Dosages : --

SPILLS

Steps to be TakenShut off leaks if without risk

Waste Disposal MethodThe product can be successfully treated in biological waste water system with proper dilution. Local legal regulations to be complied to for discharge into common Drainage / Sewage system.

8. ADDITIONAL INFORMATION/REFERENCESThe above information is provided in good faith & is said to be accurate to the best of our knowledge and belief as of the effective data. However, the company is not responsible as it is the responsibility of the buyer to ensure that is complies with the above regulation. Place risk as required by other health & safety legislation.

9. MANUFACTURERS/SUPPLIERS DATA

M/s. K.V. FIRE Chemicals (I) Pvt. Ltd., Kamala Nivas, 2nd floor, Plot 32, Lane-D, Sector -8 Vashi, Navi Mumbai 400 703. 022- 27826733

Name of Firm

Contact Person in case of Emergency

10. DISCLAIMERInformation contained in this MSDS is believed to be reliable but no representation, guarantee of warranties of any kind are made as to its accuracy, suitability for a particular application of results to be obtained for them. It is up to the user to ensure that the information containing in the material safety data sheet is relevant to the product manufactured/handled or used by him as the case may be. Helps makes no warranties expressed or implied in respect of the adequacy of this document for any particular purpose.

11. Abbrevations

C.A.S. No. Chemical Abstracts Service

U.N. No. United Nations Number Identification of Materials during transportation

LD50 (Oral-Rat) Lethal Dose=50,(LD-50, Specify Laboratory Animal species & Routs for Tests)

STEL Short-Term Exposure Limit-Max. Concentration

TDG Flammability Transport of Dangerous Goods Flammability, Classification by United Nations

ACGIH American Conference of Governmental Industrial Hygienists

TLV Threshold Limit value

LEL Lower Explosive Limit Lowest Concentration

UEL Upper Explosive Limit- Highest Concentration

TWA Time Weighted Average Exposure Limit

PPM Parts per Million

IDLH Immediately Dangerous to Life or Health, Indicates Maximum concentration

Mg/m3 Milligrams(mg) of a material per cubic metre (m3) of air.

(AVIATION TURBINE FUEL)1. CHEMICAL IDENTITYRegulated Identification

Chemical NameAviation Turbine FuelShipping name

SynonymsJet A-1Codes/LabelCombustible Liquid

Trade NameATFHazardous WasteCO, CO2 as combustion product

Chemical ClassificationCombustible HydrocarbonLiquidHazchem Code

FormulaHydrocarbon MixtureHazardousclassification

Hazardous IngredientsC.A.S.No.C.A.S. No.8008-20-6

U.N. No.



Boiling Pt/Range150 to 260CVapour Pressure@35C1 PSi

Melting/Freezing Pt.-50CpH--

Vapour Density (Air =1)AppearanceClear & Bright

Specific Gravity (Water =1)0.7940OdourKerosene Like

Solubility, In water at 30CInsolubleOthers(Molecular wt)--

3.FIRE /EXPLOSION HAZARD DATAFlammabilityYES

Auto ignition TemperatureC210C (410F)TDG Flammability

Explosion sensitivity to impactLEL0.7%

Explosion sensitivity to staticElectricityUEL5%

Hazardous combustion productsFlash Point C45C(min)


OxidiserCombustible LiquidYES

Organic PeroxideFlammable MaterialYES

Corrosive MaterialPyrophoric MaterialYES

OthersExplosive MaterialYES

4. REACTIVITY DATAChemical stability - Stable under normal conditions of storage & Handling

Incompatibility with other materialStrong oxidizing Agents

ReactivityNil

Hazardous Reaction Prods.Oxides of Carbon (on burning)

5. HEALTH HAZARD DATA1) Routes of Entry : Combustible liquid & Vapour

Effects of Exposure/ SymptomsHarmful or fatal if swallowed. May cause lung damage if swallowed. May cause respiratory tract. Inhalation : If inhaled, causes Skin irritation. Toxic to aquatic organisums. Eye : Not expected to cause prolonged or significant eye irritation. Skin : Contact with the skin causes irritation. Symptoms may include Pain, itching, discolouration, swelling & blistering, contact with the skin is not expected to cause an allergic Skin response : Not expected to be harmful to internal organs if absorbed through the skin. Ingestion : Because of its low viscosity, this material can directly enter into lungs, if swallowed or if subsequently vomited.




STELReactivity 0


IDLH


MATERIAL SAFETY DATA SHEET (AVIATION TURBINE FUEL )6. PREVENTIVE MEASURES :

Personnel ProtectiveEquipmentLiquid vapourises & forms vapor (fumes) which can catch fire & burn with explosive force. Vapour spreads easily and can be set on fire by source such as pilot light, welding equipment & electric motors & switches. Fire hazard is greater as liquid temprises above 35C

Handling &StoragePrecautionsDo not get in eyes or skin or on clothing. Do not breath the vapor or fumes. Do not breadth mist. Do not taste or swallow. Wash thoroughly after handling . Water Do not use as portable heater or appliance fuel. Toxic fumes may accumulate & cause death. Avoid contaminating soil or releasing this materialinto sewage & drainage systems and bodies of water. Do not use or store nearheat, sparks & open flames. Use and store only in well ventilated area. Keep container closed when not in use.

7. EMERGENCY/ FIRST AID MEASURES : Inhalation

FIREUse water fog, dry chemical or CO2 to extinguish flames.

Fire Extinguishing MediaFire extinguishing media : Dry chemical, alcohol foam or carbon dioxide, water spray may be used to keep fire exposed materials cool. Water or foam may cause frothing.

Special ProcedureUnusual HazardsSpecial Information : In the event of a fire, wear full protective clothing & self contained breathing apparatus.

Exposure

First Aid measures/ Emergency TreatmentEye : ;No specific first aid measures are required. As a precautions, remove contactlenses, if worn, & flush eyes with water, Skin : Wash skin into water immediately & remove contaminated clothing & Shoes Get medical attention if any symptoms develop. To remove the material from Skin , use soap & water. Ingestion : Get immediate medical attention. Do not induce vomiting. Never give anything by mouth to an unconscious person.

Eyes :


SPILLS

Steps to be Taken

Waste Disposal Method

8. ADDITIONAL INFORMATION/REFERENCESPrecautionary measures : Do not get in eyes, or skin, or an clothing. Do not breathe vapour or fumes. Do not breathe mist. Do not taste or swallow. Wash thoroughly after handling.

9. MANUFACTURERS/SUPPLIERS DATAONGC, Hazira Plant, Surat, Tel. Nos.(0261-2875500, Fax (091) (0261 2875577)Contact Person in case of EmergencyName of Firm : ONGC, Hazira Plant, Surat, Gujarat-394 518.Contact person : Shri K Raman, GM- Head Operation, ONGC, Surat


11. Abbrevations














(CHLORINE)1. CHEMICAL IDENTITYRegulated Identification

Chemical NameCHLORINEShipping nameCHLORINE

SynonymsNoneCodes/LabelNon Flammable Gas, Poison, Class-2

Hazardous Waste

ID. NO 17

Chemical ClassificationInorganic Gas or LiquidHazchem Code2 x E

FormulaCl2Hazardous Classification


1. Chorine7782-50-5U.N. No.1017

2.Hazardous IngredientsC.A.S.No.

3

4

2.PHYSICAL/CHEMICAL DATAPhysical stateLIQUIFIED Compr. Ga

Boiling Pt/Range-34CVapour Pressure4800 mm Hg at 20C

Melting/Freezing Pt.-101.0CpHNot Pertinent

Vapour Density (Air =1)2.49AppearanceGreenish Yellow

Specific Gravity (Water =1)1.47 at 0COdourIrriting, Bleach likeChoking Odour

Solubility, In water at 30CSlighly SolubleOthersSoluble in Alkalies

3.FIRE /EXPLOSION HAZARD DATAFlammabilityNo

Auto ignition TemperatureCNot PertinentTDG Flammability2

Explosion sensitivity to impactStableLELNot Pertinent %

Explosion sensitivity to staticElectricityStableUELNot Pertinent %

Hazardous combustion productsToxic products are generated when combustible burn in ClFlash Point CNot Pertinent %

Hazardous PolymerizationWill not occurFlash Point CNot Pertinent (CC)

OxidiserYesCombustible LiquidNO

Organic PeroxideNOFlammable MaterialNO

Corrosive MaterialYesPyrophoric MaterialNO

OthersYesExplosive MaterialNO

4. REACTIVITY DATAChemical stability Stable

Incompatibility with other materialCombustible substance, finely divided metals

ReactivityViolent reaction with Alcohols, explosive reaction with metals, potentially dangerous reaction with Hydrocarbons, Lewis Acids, Sulfides, Trialkyl Boranes.

Hazardous ReactionProductsToxic products are generated when combustible burn in Cl

5. HEALTH HAZARD DATARoutes of entry : Inhalation, Ingestion Skin & Eyes

Effects ofExposure/SymptomsSkin & Eyes : Irritation, sneezing, copious salivation, general exsitement, rentlessness. Inhalation : High concentration causes respiratory distress & violent coughing, often with retching. Death may result from suffocation.

LD50 (oral Rat)Not Listed mg/kgNFPA Hazard SignalsMF=16

Permissible exposure limit1 ppm 3 mg/m3Health 3HC = -BTU/lbx103

TLV (ACGIH)1 ppm 3 mg/m3Flammability 0Molecular Weight70.91

STEL3 ppm 9 mg/m3Reactivity 0

Odour Threshold3.5 ppm 10.16 mg/m3Special -1 ppm = 2.90 mg/m3

IDLH10 ppm


(CHLORINE)

6. PREVENTIVE MEASURES

Personnel ProtectiveEquipmentAvoid contact with liquid or vapours. Provide PVC gloves, gumboots, rubber overcoat, head mask, self-contained breathing apparatus.

Handling &StoragePrecautionsStore in dry, cool, relatively isolated, well ventilated place. Store in cylinders, pressure vessels or pipeline

7. EMERGENCY/ FIRST AID MEASURES

FIRE

Fire Extenguishing MediaNot flammable

Special ProcedureUnusual HazardsKeep the containers cool spraying water if exposed to heat or flame. Poisonous gas may be produced in fire

Exposure

First Aid Measures/Emergency Treatment

Inhalation : Remove the victim to fresh air area, apply artifical respiration or oxygen if neededIngestion : Get Medical care urgentlySkin : Wash eye or skin with plenty of water under quick opening safety shower and eye wash fountainEyes : Flush with plenty of water for 15 min.

Antidotes/Dosages Not available

SPILLS

Steps to be TakenShut off leaks without risk. Contain the leaking liquid on earth/sand. Prevent the liquid from entering the sewer. Vapour create toxic atmosphere. Knock down vapour withwater spray

Waste Disposal MethodNeutralise small liquid spillages with soda ash & drain with abundant water. Cover pool with protein foam, so that the release of vapour to atmosphere is low and undercontol.

8. ADDITIONAL INFORMATION/REFERENCESIn case of large gas escapes, the presence of cloud can be marked with ammonia with which it will turn into a mist. Run away from the gas clouds in a direction perpendicular to the wind direction. Avoid liquid chlorine from leaking and body contact. Persons with pulmonary diseases should avoid the exposure. A concentration of 3.5 ppm produces a detectable odour. 15 ppm causes immediate irritation of the throat conc. Of 50 ppm are dangerous for even short exposures. 1000ppm is fatal. Can react to cause fire/explosion on contact with Turpentine, illuminating gas Polypropylene, Rubber, Sulfamic Acid, Acetaldehyde, Alcohols, Bring the leaking portion of the cylinder to the upper most position so that only the gas escapes and not the liquid.


Name of Firm



11. AbbrevationsC.A.S. No. Chemical Abstracts ServiceU.N. No. United Nations Number Identification of Materials during transportationLD50 (Oral-Rat) Lethal Dose=50,(LD-50, Specify Laboratory Animal species & Routs for Tests)STEL Short-Term Exposure Limit-Max. ConcentrationTDG Flammability Transport of Dangerous Goods Flammability, Classification by United NationsACGIH American Conference of Governmental Industrial HygienistsTLV Threshold Limit valueLEL Lower Explosive Limit Lowest ConcentrationUEL Upper Explosive Limit- Highest ConcentrationTWA Time Weighted Average Exposure LimitPPM Parts per MillionDLH Immediately Dangerous to Life or Health, Indicates Maximum concentration. Mg/m3Milligrams(mg) of a material per cubic metre (m3) of airI(DRY CHEMICAL POWDER)1. CHEMICAL IDENTITYRegulated Identification

Chemical NameMono AmmoniumPhosphateShipping nameFire fightingChemical

SynonymsCodes/Label

Trade NameDCP (MAP)Hazardous Waste

Chemical ClassificationMixtureHazchem Code

FormulaN/AHazardousclassification


1. Dry Chemical powder1310-73-2U.N. No.


2.PHYSICAL/CHEMICAL DATAPhysical statePowder

Boiling Pt/RangeN/AVapour Pressure@35CN/A

Melting/Freezing Pt.N/ApHPowder

Vapour Density (Air =1)N/AAppearanceFine blue Powder

Specific Gravity (Water =1)--OdourOdourless

Solubility, In water at 30CSolubleOthers--

3.FIRE /EXPLOSION HAZARD DATAFlammabilityNo

Auto ignition TemperatureCN/ATDG Flammability



Hazardous combustion productsAmmonia, Phosphorus oxidesFlash Point CN A

Hazardous PolymerizationMay occurFlash Point C


Organic PeroxideFlammable MaterialNO


OthersExplosive MaterialNO

4. REACTIVITY DATAChemical stability -

Incompatibility with other materialNone

Reactivity

Hazardous Reaction Prods.

5. HEALTH HAZARD DATA2) Routes of Entry :Eye contact, Skin contact, Inhalation

Effects of Exposure/ SymptomsHealth Hazard (Acute & Chronic) Breathing dust may irritate the nose & Throat & causecoughing and chest discomfort. Dusts may irritate the eyes. Prolonged contact can produce slight skin irritation. Medical condition generally aggravated by explosure : Respiratory disease including Asthma & Emphysema.


Permissible exposure limitHealth

TLV (ACGIH)Flammability

STELReactivity


IDLH

(DRY CHEMICAL POWDER)


Personnel Protective Equipment

Handling &Storage Precautions


FIRE

Fire Extinguishing MediaThis is an extinguishing agent

Special ProcedureUnusual HazardsNone

Exposure

First Aid Measures/Emergency Treatment Eye contact Flush thoroughly with water for atleast 15 mins. Get medical assistance.

Inhalation : Remove from further exposure if unconsciousness occurs. Seek immediate medicalassistance and call a physician if breathing has stopped. Use mouth to mouth resuscitation.Skin : Wash contact areas with soap & water.Ingestion : Not expected to be a problem, how ever, if more than half litre ingested, immediately give 1 to 2 glasses of water & call a physician. Do not induce vomiting or give anything by mouth to an unconscious person


SPILLS

Steps to be TakenWear protective equipment including rubber boots, rubber gloves, rubber apron and a full face piece or a hand mask air purifying cartridge respirator with particular filters wear chemical goggles if a half mask is worn. For smallspills ,sweep up & dispose off in Dot approved waste container.

Waste Disposal MethodDispose off contaminated product & materials used in cleaning up spills or leaks in a manner approved for this material. Consult appropriate state and local regulatory agencies to ascertain proper disposal procedures.

8. ADDITIONAL INFORMATION/REFERENCES


Name of Firm



11. Abbrevations














(EHTYL MERCAPTAN)1. CHEMICAL IDENTITYRegulated Identification

Chemical NameEHTYL MERCAPTANShipping nameEHTYLMERCAPTAN

SynonymsETHANETHIOL, MERCAPTOETHANECodes/LabelFlammable liquid, Class-3

Trade NameThioethy AlcoholEthyl SulphydrateHazardous WasteID NO. 17

Chemical ClassificationMercaptanHazchem Code2 X E

FormulaC2H6SHazardousclassification


Ethyl Mrcaptan75-08-1U.N. No.1228



Boiling Pt/Range-34.4CVapour Pressure@35CNot Available

Melting/Freezing Pt.-147CpHNot Available

Vapour Density (Air =1)2.49AppearanceColourless to Yellow

Specific Gravity (Water =1)0.826. e 20C solidOdourStrong Penetrating like Garlic odour

Solubility, In water at 30CSolubleOthersSoluble in Alkalies


Auto ignition TemperatureC298.9CTDG Flammability3

Explosion sensitivity to impactStableLEL2.8%

Explosion sensitivity to staticElectricityExplodesUEL18.2%

Hazardous combustion productsEmits toxic fumes ofSOXFlash Point C< - 17.7 (OC)

Hazardous PolymerizationWill not occurFlash Point CNot available (CC)

OxidiserNOCombustible LiquidYES

Organic PeroxideNOFlammable MaterialYES

Corrosive MaterialNOPyrophoric MaterialNO

Others---Explosive MaterialNO


Incompatibility with other materialAcids, water, steam & oxidizers

ReactivityVoilent reaction with Ca(ocL)2. Reacts vigorously with oxidizers. Contact withAcid fumes emit highly toxic fumes of SOX

Hazardous Reaction Prods.Not available

5. HEALTH HAZARD DATARoutes of entry : Inhalation, Ingestion, Skin & Eyes

Effects ofExposure/SymptomsInhalation : Causes muscular weakness convulsions, respiratory paralysis. High Concentration may cause pulmonary irritation. Ingestion : Causes nausea & irritation of mouth and stomach. Eye & Skin : Causes irritation. Emergency Treatment : Inhalation : Remove the victim to Fresh air area, Provide Respiration or oxygen if indicated. Ingestion : Induce vomiting & follow with gastric lavage. Seek medical aid immediately.

LD50 (oral Rat)1960 mg/kgNFPA Hazard Signals


TLV (ACGIH)0.5 ppm, 1.0 mg/m3Flammability 4

STELReactivity 0

Odour Threshold0.001ppm,0.0026 mg/mg3Special -

MATERIAL SAFETY DATA SHEET (EHTYL MERCAPTAN)


Protective EquipmentAvoid contact with liquid or vapour

Provide Rubber hand gloves, Protective over clothing side covered safety goggles/ Face shield.

Handling &StoragePrecautionsKeep in dry, cool, well ventilated area away from heat,flame or oxidizers. Keep the containers tightly closed.


FIRE

Fire Extinguishing MediaDry chemical powder, Foam, CO2

Special ProcedureUnusual HazardsKeep the containers cool by spraying water if exposed to Heat or flamePoisonous gases are produced in fire

Exposure


Inhalation : Remove the victim to fresh air area, provide artificial respiration or oxygen if needed. Ingestion :Induce vomiting & follow with gastric lavage. Eyes : Flush with water for 15 mins. Skin : wash the affected area with plenty of water & soap. Seek medical aid immediately.


SPILLS

Steps to be TakenShut off leaks if without risks. Contain the spillage on earth or sand.

Waste Disposal MethodDissolve in a combustible solvent as Alcohol. Benzene etc. Burns in furnace with an after burner & scrubber to neutralise Sulphur Dioxide.

8. ADDITIONAL INFORMATION/REFERENCESLC 50 = 4420 ppm/4H (inh-rat). A very dangerous fire hazard when exposed to heat or flame. A moderate explosion hazard, when exposed to spark of flame will reacat with water steam to produce toxic & flammable vapours.


Name of Firm



11. Abbrevations














(HYDROGEN SULPHIDE)1. CHEMICAL IDENTITYRegulated Identification

Chemical NameHYDROGENSULPHIDEShipping nameHydrant SulphideLiquified

SynonymsSPLUTTERED HYDROGENCodes/LabelFlammable gas, Class-2

Trade Name--Hazardous WasteID. NO. 6

Chemical ClassificationInorganic GasHazchem Code2 WE

FormulaH2SHazardousclassification


1. Hydrogen Sulphide7783-06-4U.N. No.1053


2.PHYSICAL/CHEMICAL DATAPhysical stateGas

Boiling Pt/Range--Vapour Pressure@35C15200 @ mm Hg at25.5C

Melting/Freezing Pt.82.8CpHNot Pertient

Vapour Density (Air =1)1.189AppearanceColourless

Specific Gravity (Water =1)0.916 at - 60C LiquidOdourOdour of rotten eggs

Solubility, In water at 30CSolubleOthersSoluble in Gyecrol, Crude Oil


Auto ignition TemperatureC260CTDG Flammability2

Explosion sensitivity to impactStableLEL4%

Explosion sensitivity to staticElectricityNot availableUEL46%

Hazardous combustion productsEmits toxic fumes ofSOXFlash Point C--

Hazardous PolymerizationDoes not occurFlash Point C--




Others--Explosive MaterialNO


Incompatibility with other materialoxidizers Metals

ReactivityVigorous reaction with metal powders, incandescent reaction with chromium Tri-oxide. Reacts violently with NI3NF3 P-Bromo-Benzene-Diazonium chloride Acetaldehyde etc. Mixture of Hydrogen Sulphide & Air may explode violently.

Hazardous Reaction Prods.Reacts with 4-bromobenzene diazonium chloride to form an explosive product.

5. HEALTH HAZARD DATARoutes of Entry :Inhalation, Skin and Eyes

Effects of Exposure/ SymptomsInhalation : if high concentrations are inhaled, hyperpnoea & respiratory symptoms Paralysis may occur very High concentration may produce pulmonary edema. Skin & Eyes : Causes severe irritation .Emergency Treatment : Inhalation : Remove the victim to fresh air area. Provide respiration or oxygen if needed. Eyes : Irrigate with plenty of water for 15 mins. Skin : Remove the contaminated clothing and wash the affected area with plenty of water & soap. Seek medical aid immediately.

LD50 (oral Rat)Not availableNFPA Hazard Signals

Permissible exposure limit10ppm Not 14 mg/m3Health 3

TLV (ACGIH)0.5 ppm 14 mg/m3Flammability 4

STEL2,15 ppm, 21 mg/m3Reactivity 0

Odour Threshold0.0047 ppmSpecial -

IDLH


MATERIAL SAFETY DATA SHEET (HYDROGEN SULPHIDE)6. PREVENTIVE MEASURES

Personnel Protective EquipmentAvoid contact with gas. Provide rubber framed side covered, goggles respirator, rubber hand gloves, over-clothing & shoes

Handling &Storage PrecautionsKeep in a cool, dry, well ventilated area. Away from oxidizingAgents


FIRE

Fire Extinguishing MediaAlcohol Foam, CO2, DCP

Special ProcedureUnusual HazardsKeep the container cool by spraying water if exposed to heat or flame. Flash back along vapour trail may occur.

Exposure


Inhalation : Remove victim to fresh area, Provide artificial respiration or oxygen, if needed.Eyes : Irrigate with plenty of water for 15 mins.Skin : Remove the contaminated clothing and wash the affected area with plenty of water & Soap. Seek medical aid immediately.

Antidotes/Dosages : Not available.

SPILLS

Steps to be TakenShut off leaks if without risk

Waste Disposal MethodIf in the liquid form, allow to vapourise. In case of gas leakage, pass through Recl3 solution with a trap in line for prevention of back siphoning,. Place cylinder in or near hood and leave bleed off.

8. ADDITIONAL INFORMATION/REFERENCESLC50- 444 ppm/4H (inh-rat) Extremely hazardous, poisonous & flammable gas. An asphyxiate. Low concentratory 20-150 ppm causes irritation of eyes. Slightly higher concentration may cause irritation of upper respiratory tract. Exposures of 800-1000 ppm may be fatal in 30 mins. Higher concentrations are instantly fatal. H2S poisoning occur even more rapidly thanthat of HCN. Potentially explosive reaction into copper + Oxygen. Explosive reaction when heated with Perchlory Fluoride(above 100C ). Explodes when in contact oF2, Hcl3, Br2, F5, CLF3, CL2o & silver fulminate.


Name of Firm



11. Abbrevations














MATERIAL SAFETY DATA SHEET (HYDROCHLORIC ACID)1. CHEMICAL IDENTITYRegulated Identification

Chemical NameHydrochloric AcidShipping name

SynonymsMuratic AcidCodes/Label

Trade NameMuratic AcidHazardous Waste

Chemical ClassificationInorganic AcidHazchem Code2 R

FormulaHcLHazardousclassification


1. Hydrochloric Acid764-01-0U.N. No.1789


2.PHYSICAL/CHEMICAL DATAPhysical stateFuming liquid/gas

Boiling Pt/Range-84.8CVapour Pressure @35C4 atm at 17.8C

Melting/Freezing Pt.-114.3CpHAcidic


Specific Gravity (Water =1)--OdourStrong Pungent

Solubility, In water at 30CSolubleOthers--

3.FIRE /EXPLOSION HAZARD DATAFlammabilityNO

Auto ignition TemperatureCNot applicableTDG Flammability3

Explosion sensitivity to impactNot applicableLELNot applicable

Explosion sensitivity to staticElectricityNot applicableUEL18.2%

Hazardous combustion productsNot applicableFlash Point CNot applicable (OC)

Hazardous PolymerizationWill not PolymeriseFlash Point CNot applicable (OC)

OxidiserNOCombustible LiquidNO

Organic PeroxideNOFlammable MaterialNO

Corrosive MaterialYESPyrophoric MaterialNO



Incompatibility with other materialAcids, Water, Steam & oxidizers. Reacts explosively with Potassium permangate, Sodium, Tetraselenium Tetraitride is also explosive

ReactivityReacts rapidly with bases

Hazardous Reaction Prods.Nil

5. HEALTH HAZARD DATA3) Routes of Entry :Inhalation, Skin and Eyes

Effects of Exposure/ SymptomsInhalation : The major effects of actute exposure to HCL are usually to upper respiratory tract Exposure to the gas causes cough, burning of the throat & laryx. Explosure to higher concentration may cause laryngeal spasm & ocdema of the lungs & vocal cords. Prolonged or repeated exposure may cause dental decolouration &erosion. Gastritis & chronic bronchitis have been also reported in exposed workers. giddiness, mental confusion & nausea. Skin Contact : Causes skin burns & may produce Keloid & rectile Scarring . Facial burns may result in serious & disfiguring scars. Frequent contact with dilute acid may cause dermatitis & photosensitization may result from industrial contyract. Eye Contact : HCL is a strong eye irritant and contact with the acid may cause burns, reduced vision & total blindness. Ingestion :Ingestion of Hcl causes severe burns & corrosion of mouth esophagus & stomach. Symptom include dysphasia, Pain, Nausea, vomiting, Diarrhea & thirst. Emergency Treatment :Eye Wash eye with flowing water for 10 mins. LUNG : Remove casualty from the area of exposure. If unconscious, do not give any thing to drink, give artificial ventilation, chest compression or place in the recovery position if unconscious, give oxygen if available. Mouth : Do not make the casualty vomit. Treat unconscious casualty as for lunges. Skin : Remove contaminated clothing immediately. Drench the affected area with running water for atleast 10 minutes, transfer the patient to hospital as soon as possible.


Permissible exposure limitHealth

TLV (ACGIH)5 ppm, 7 mg/m3Flammability

STEL3 ppmReactivity


IDLH


Personnel Protective EquipmentApproved respirator safety goggles, neoprene, Viton or butyl rubber glove and acid resistant outer clothing, mechanical exhaust.

Handling &Storage PrecautionsIt should be handled wearing approved & appropriate personal protective equipment as indicated above. It should be kept in a cool, well ventilated place away from oxidizing materials and protectedagainst physical damage.


FIRE

Fire Extinguishing MediaHydrochloric Acid is not combustible so an extinguisher appropriate to the surrounding fire condition should be used.

Special ProcedureUnusual Hazards--

Exposure

First Aid Measures/Emergency Treatment As described in Health Hazard Data


SPILLS

Steps to be TakenCover spill with sodium bicarbonate or a 50-50 mixture of soda Ash-Calcium Hydroxide& slowly & carefully mix to a slurry. If highly concentrated acid is spilled, the 1st priority is to contain by dyking & dilute with water spray to reduce fuming before neutralization.Waste Disposal Method :Ventilate the area & wear personal protective equipment.Add slowly to a large amount of soda ash & slaked time by stirring. Discharge the solution with large amount of water into a sink lined with protective matting & filled with plenty of running water. Allow 2-3 minutes between each stage as heat is generated by neutralisation.


8. ADDITIONAL INFORMATION/REFERENCES



Name of Firm



11. Abbrevations














(HIGH SPEED DIESEL)

1. CHEMICAL IDENTITYRegulated Identification

Chemical NameHigh speed Diesel(HSD)Shipping nameDiesel Oil

SynonymsGas OilCodes/LabelClass-B, FlammableLiquid

DieselHazardous WasteID NO. 5

Chemical ClassificationFuelHazchem Code3 Z

FormulaA complex mixture ofHydrocarbonsHazardousClassification


1. Methyl AlcoholU.N. No.1202


3

4

2.PHYSICAL/CHEMICAL DATAPhysical stateLiquid @ 15C & 1atm

Boiling Pt/Range110C to 400CVapour Pressure@35C< 0.1 psi @ 38C

Melting/Freezing Pt.0.18CpHNot Pertinent

Vapour Density (Air =1)3.0 5.0AppearanceOily Brown to Yellow

Specific Gravity (Water =1)0.82 gm/1@!15COdourCharcteristic Odour

Solubility, In water at 30CInsoluble in waterFloats on water.OthersSulphur Content 1% (max)




Explosion sensitivity to staticElectricityStableUEL6%

Hazardous combustion productsAcrid smoke/CO/CO2/NOxFlash Point C55C TO 100C

Hazardous PolymerizationDoes not occurFlash Point CNA (OC)




OthersNOExplosive MaterialYES


Incompatibility with other materialSaturated aliphatic hydrocarbons, which are contained in GAS OIL may be incompatible with strong oxidizing agents such as nitric acid. Charring may occur followed by ignition of unreacted hydrocarbon and other nearby combustibles.

ReactivityMostly unreactive. Not affected by aqueous solutions of acids, alkalis, most oxidizing agents, and most reducing agents.

Hazardous ReactionProductsWhen heated sufficiently or when ignited in the presence of air, oxygen or strong oxidizing agents burns exothermically.


Effects ofExposure/SymptomsInhalation : Dizziness, headache, Ingestion : Nausea & vomiting. Irritation of mouth & gastro intestinal tract may follow. Skin & Eye Contact : Irritation will remove natural fat from skin. Prolonged contact should be avoided. Otherwise skin chapping, cracking orpossible contact dermatitis may result.

LD50 (oral Rat)5 to 15 g/kgNFPA Hazard SignalsMF=16

Permissible exposure limitNot ListedHealth 1HC = 18.7 BTU/lbx103

TLV (ACGIH)5 mg/m3Flammability 2Molecular Weight226.43

STELNot ListedReactivity 0

Odour ThresholdNot ListedSpecial -Conversion


PersonnelAvoid contact with liquid or vapours

Protective EquipmentUse Gum boot, Hand gloves while handling the product

Handling &StoragePrecautionsStore in dry, cool, well ventilated area away from heat and flame. Keep away from oxidizing agents.


FIRE

Fire Extenguishing MediaDry Chemical Powder, CO2 & Foam

Special ProcedureUnusual HazardsKeep the containers cool spraying water if exposed to fireFlashback may occur along vapour trail

Exposure


Inhalation : Maintain respiration; administer oxygen if neededIngestion : Give victim water or milk; do not induce vomiting; guard against aspiration into lungs.Skin : Remove the contaminated clothing and wash the affected area with plenty of water and soapEyes : Wash with copious quantity of water


SPILLS

Steps to be TakenShut off leaks if no risks involved. Cantain/absorb spillage in earth/sand bund. Prevent liquid from entering into sewers.

Waste Disposal MethodSeal all waste in vapour tight plastic bags for eventual disposal

8. ADDITIONAL INFORMATION/REFERENCESEmergency treatment : If inhaled, remove the victim to fresh air, if not breathing, give artificial respiration. if unconscious but breathing, place in unconscious (recovery) position. Give external cardiac massage if necessary. If ingested to not induce vomiting. Remove contaiminated clothing, wash all effected skin thoroughly with soap and water irrigate affected eye with copious amount of water. Administration of medical paraffin may reduce absorption through digestive table. Gastrict lavage should be done only after endotracheal Intubation in view of respiration which may cause serious chemical pneumonitis for which antibiotic and corticosteroid therapy may be indicated.



Name of Firm



11. Abbrevations














(HYDRAZINE)1. CHEMICAL IDENTITYRegulated Identification

Chemical NameHYDRAZINEShipping nameHydrazine Anhydrous

SynonymsHydrazine AnhydrousDiamineCodes/LabelFlammable, corrosive liquid, Class-3

Trade Name--Hazardous WasteId. No.17

Chemical ClassificationInorganic compoundHazchem Code2 PE

FormulaH4N2Hazardousclassification


1. Hydrazine302-01-2U.N. No.2029



Boiling Pt/Range113.5CVapour Pressure@35CN/A. 14.9 mm Hg at25C

Melting/Freezing Pt.1.4CpHAlkaline

Vapour Density (Air =1)1.1AppearanceColourless, fuming liquid

Specific Gravity (Water =1)1.008 at 20COdourAmmonical odour

Solubility, In water at 30CSolubleOthersMiscible with methyl, Ethyl, Propyl & ISO- butyl Alcohols



Explosion sensitivity to impactExplodesLEL4.7%

Explosion sensitivity to staticElectricityExplodesUEL100%

Hazardous combustion productsEmits highly toxic fumes of NOX & NH3Flash Point C37.7(OC)

Hazardous PolymerizationDoes not occurFlash Point CN.A. (CC)



Corrosive MaterialYESPyrophoric MaterialNO

Others--Explosive MaterialYES

4. REACTIVITY DATAChemical stability - Stable at room temp. decomposed if heated

Incompatibility with other materialOxidizers, Hydrogen peroxide, Nitric Acid, Metal oxides/Acids & Porous materials

ReactivityViolent reaction with Benzene seleminimc Acid or anhy. CO2 + steel, copper oxide, Lead oxide, potassium Peroxodisulphate, Ruthen (iii) Chloride

Hazardous Reaction Prods.Forms sensitive explosive mixture with 2 Chloro 5- Methyl Nitrobenzene, Metal Salts (e.g. Cadium perchlorate, copper chlorate, Magnesium Nitrate (Heat sensitive) Hg(I) & (II) chlorites & Nitrates.

5. HEALTH HAZARD DATA4) Routes of Entry :Inhalation, Ingestion, Skin, and Eyes

Effects of Exposure/ SymptomsVapours may cause itching, swelling & blistering of eyelids, skin, nose & throat. The symptoms may be delayed for several hours. Temporary blindness may occur. Liquid Causes a caustic like burn, if not washed off at once. Ingestion or absorption through skin caused nausea, dizziness, headache., severe exposure may cause death. Emergency treatment : For any type of exposure, seek medical aid immediately. Inhalation : Remove the victim to fresh air area. Observe for development of delayed symptoms. Keep the victim quiet. Ingestion : Induce vomiting. Give egg white or other emollient. Skin & Eyes : Wash with large amounts of water for atleast 15 mins.

LD50 (oral Rat)60 mg/KgNFPA Hazard Signals

Permissible exposure limit0.1 ppm (Skin)Health 3

TLV (ACGIH)0.1 ppm (Skin)Flammability 3

STELNot listedReactivity 2

Odour Threshold3-4 ppmSpecial -


Personnel Protective EquipmentAvoid contact with liquid or vapour. Provide self contained breahing apparatus, Ammonia like gas mask, rubber or plastic hand gloves over clothing. Side covered safety glasses, shoes & safety showernearby.

Handling &Storage PrecautionsStrict precautions are to be observed for storage. Should be stored in sealed glass containers, in a cool and dark place, away from heat, flame & other materials.


FIRE

Fire Extinguishing MediaWater, Alcohol Resistance foam, CO2, Dry chemical powder.

Special ProcedureUnusual HazardsKeep the container cool by spraying water if exposed to heat fire or flame. Explodes if confined & flash back may occur.

Exposure

First Aid Measures/Emergency Treatment For any type of exposure, seek medical aid immediately.

Inhalation : Remove the victim to fresh air area. Observe the development of delayed symptoms. Keep thevictim quiet. Ingestion : Induce vomiting, give white egg or other emollient.Skin & Eyes : Wash with large amount of water for atleast 15 mins.


SPILLS

Steps to be TakenShut off leaks if without risk. Contain the spillage on sand or earth.

Waste Disposal MethodDilute with water to produce atleast 40% solution. Neutralise with dilute sulphuric Acid. Drain into sewer with abundant water.

8. ADDITIONAL INFORMATION/REFERENCESLC 50-570 ppm/4H (Inh-root). The compound is corrosive & suspected from human carcinogen (SHC). Severe explosion hazard when exposed to heat or flame or by chemical reaction. Explodes on contact with Barium / calcium compounds (at130C). Potentially explosive reaction with alkali metals. Forms explosive mixture with methanol & nitro methane, air, Lithium, perchlorate sodium perchlore & sodium. Ignites on contact with cotton waste & heavy metals, dinitrogen oxide, Rhenium & Alumins. Nitric Acid, H2O2 Ignites spontaneously in air. Full instructions to be obtained from the manufacturer. It is very sensitive & must not be used without full & complete instructions fromthe manufacturers for handling, storage and disposal, on contact with metal catalysts, it decomposes to NH3, H2& N2 which may ignite or explode. violent reaction with i-chloro 2,4 Dinitrobenzene, oxidants & Thiocynate.

MATERIAL SAFETY DATA SHEET(HYDRAZINE)


Name of Firm



11. Abbrevations














MATERIAL SAFETY DATA SHEET (KEROSENE)1. CHEMICAL IDENTITYRegulated Identification

Chemical NameKEROSENEShipping name

Synonyms (common)Petroleum Solvent, Light NaphthaCodes/Label


Chemical ClassificationIlluminated oil, Miscellaneous Hydrocarbon mixturesHazchem Code

FormulaC2H2+2Hazardousclassification


U.N. No.3.3/ 1223



Boiling Pt/Range392-500C F=200-260C (at 1 atm)Vapour Pressure@35C

Melting/Freezing Pt.-50F=-45.6CpH

Vapour Density (Air =1)Appearance

Specific Gravity (Water =1)0.80 at 15C liquidOdourCharacteristic

Solubility, In water at 30COthers

3.FIRE /EXPLOSION HAZARD DATAFlammability

Auto ignition TemperatureC444FTDG Flammability



Hazardous combustion productsNot pertinentFlash Point C

Hazardous PolymerizationFlash Point C




OthersExplosive Material

4. REACTIVITY DATAChemical stability

Incompatibility with other materialReactivity with water No reaction, Stability during transport StablePolymerization Not pertinent

ReactivityReactivity group = 33

Hazardous Reaction Prods.Reactivity with common materials No reaction Neutralising agents for Acids& Caustic Not pertinent

5. HEALTH HAZARD DATA5) Routes of entry : 1)PPE Protective gloves, goggles or face shield, 2) Threshold limit valve 200 ppm, 3)Toxicity by Ingestion grade 1 LD = 5 to15 g/kg, 4)Short term inhalation limits 2500 mg/m3 for 60 mins.,5)Symptoms following exposure Vapour causes slight irritation of eyes & nose. Liquid irritates stomach. If taken into lungs, causes distress & rapidly developing pulmonary edema.

Effects of Exposure/ Symptoms




STELReactivity 0

Odour Threshold1 ppmSpecial -

IDLHData not available


Personnel

Protective EquipmentExposure - Call for medical aid, Harmful it swallowed. Liquid Irritating to skin & Eyes. Remove contaminated clothing & shoes. Flush affected areas with plenty of water. If in eyes hold eyelidsopen & flush with plenty of water. If swallowed & victim isconscious, have victim drunk water or milk. Do not induce vomiting.

Handling &Storage Precautions


FIRE

Fire Extinguishing MediaCombustible Extinguish with dry chemicals, Foam or carbon dioxide. Water may be ineffective on fire. Cool exposed containers with water.

Special ProcedureUnusual Hazards

Exposure


Exposure - Call for medical aid, Harmful it swallowed. Liquid Irritating to skin & Eyes. Remove contaminated clothing & shoes. Flush affected areas with plenty of water. If in eyes hold eyelids open& flush with plenty of water. If swallowed & victim is conscious, have victim drunk water or milk. Donot induce vomiting.

Antidotes/Dosages

SPILLS

Steps to be Taken


8. ADDITIONAL INFORMATION/REFERENCESNFPA Hazard Classification : Category ClassificationHealth & Hazard (Blue) 0Flammability (Red) 2Reactivity (Yellow) 0

MATERIAL SAFETY DATA SHEET(KEROSENE)


Name of Firm



11. Abbrevations














MATERIAL SAFETY DATA SHEET (LIQUEFIED PETROLEUM GAS)1. CHEMICAL IDENTITYRegulated Identification

Chemical NameLIQUEFIED PETROLEUM GASShipping namePETROLEUM GAS LIQUEFIED

SynonymsLPG, Propane, Butane, Bottled gas, Propylene, PurofaxCodes/LabelFlammable gas , Class-2

Trade NameLPGHazardous WasteID NO. 5

Chemical ClassificationHydrocarbon MixtureHazchem Code2 WE

FormulaC3H8,C4H10(MIXTURE)Hazardous classification


1.68476-85-7U.N. No.1075


1. Hydrogen sulfide74-98-6

2 Butane106-97-8

3. Propylene115-07-1

2.PHYSICAL/CHEMICAL DATAPhysical stateGas, 15C & 1atm

Boiling Pt/Range> - 40CVapour Pressure @35CN/A mm Hg.

Melting/Freezing Pt.Not pertinentpHNot Pertinent


Specific Gravity (Water =1)0.51 0.58 at -50COdourMercaptan added as an odouriser

Solubility, In water at 30CSlightOthersSoluble in organic solvent, Alcohol


Auto ignition TemperatureC460.1 Propane,405ButaneTDG Flammability3

Explosion sensitivity to impactNot establishedLEL1.9%

Explosion sensitivity to staticElectricityMay explodeUEL9.5%

Hazardous combustion Prod.Emits CO, CO2Flash Point C(OC)

Hazardous PolymerizationDoes not occurFlash Point C104.4(CC)






Incompatibility with other materialStrong, Oxidisers

ReactivityNo reaction with common material but may react with oxidizing material

Hazardous Reaction ProductsNot available

5. HEALTH HAZARD DATARoutes of entry Inhalation, Skin

Effects ofExposure/SymptomsConservation in air greater than 10% causes dizziness in few minutes and conc gives the same symptoms in 10 Mtrs. High concentration causes asphyxiation. Liquid on skin causes frostibote. Emergency treatment : If inhalation, remove the victim to fresh air area. Provide artificial resuscitation. Skin : Remove the wetted clothes & wash theaffected area with plenty of water. Eyes : Flush with plenty of water for 15 mins. Seek medical aid immediately.

LD50 (oral Rat)Not ListedNFPA Hazard Signals

Permissible exposure limitNot ppm Not ListedHealth 1

TLV (ACGIH)1000 ppm, 1800mg/m3Flammability 4

STELNot listedReactivity 0

Odour Threshold5000 to 20000ppm mg/m3Special -

MATERIAL SAFETY DATA SHEET (LIQUEFIED PETROLEUM GAS)6. PREVENTIVE MEASURES

Personnel ProtectiveEquipmentAvoid contact of gas. Provide hand gloves,

Safety goggles, gas mask, protective over clothing & shoes.

Handling &StoragePrecautionsKeep in a tightly closed cylinders in a cool well ventilated area, Away from heat, flame & sparks.


FIRE

Fire Extenguishing MediaCO2,Dry Chemical Powder, Water spray

Special ProcedureUnusual HazardsKeep the containers cool by spraying water if exposed to fire or heat. If not cooled sufficient, containers will explode in fire.

Exposure


If inhaled, remove the victim to fresh air area and artificial respiration may be provided if required.If skin is affected with Liquid, remove the clothing & wash the affected area with plenty of water. Seek medical aid


SPILLS

Steps to be TakenShut off leaks if without risk. Warn everybody that air mixture is explosive.

Waste Disposal MethodAllow gas to burn under control

8. ADDITIONAL INFORMATION/REFERENCESAvoid contact with oxidizers. Olefinic impurities may lead to narcotic effect or it may act as a simple Asiphyxiant. A very dangerous hazard when exposed to heat or flame. If fire is big, keep surrounding area cool by spraying water.


Name of Firm



11. Abbrevations














(METHANOL)1. CHEMICAL IDENTITYRegulated Identification

Chemical NameMETHYL ALCOHOLShipping nameMethanol

SynonymsMethanol, Wood Alcohol Wood spirit, colonial SpiritCodes/LabelFlammable Liquid, Class-3

Trade NameHazardous WasteID NO. 17

Chemical ClassificationAlcoholHazchem Code2PE

FormulaCH3OHHazardousClassification


1. Methyl Alcohol67-56-1U.N. No.1230


3

4


Chemical Name64.5CVapour Pressure@35C@35CC100mm Hgat 21.2C

Boiling Pt/Range-97.8CpHNeutral

Melting/Freezing Pt.1.1AppearanceColourless, Watery

Vapour Density (Air =1)0.79OdourAlcoholic Odour

Specific Gravity (Water =1)20C(liqu.)OthersMiscible with Ethanol, Ether, Benzene, Ketones& other Organic Solvents

Solubility, In water at 30C

3.FIRE /EXPLOSION HAZARD DATAFlammability YES

Auto ignition TemperatureC463.8TDG Flammability3


Explosion sensitivity to staticElectricityVapours are explosiveUEL36.5%

Hazardous combustion productsEmits acrid smoke &imitating fumesFlash Point C16.1 (OC)

Hazardous PolymerizationWill not occurFlash Point C12.2 (OC)




OthersExplosive MaterialNO


Incompatibility with other materialstrong Oxidisers, Berylium Dihydride, Metals (K Mg), Carbon Tetrachloride + Metal (Al. Mg. Zn.), Dichloromethane, Oxidants

ReactivityViolent reaction with Alkyl Aluminium salts, Acetyl Bromide, Chloroform + NaOH, CrO3,Nitric Acid, HCIO4, P2O3

Hazardous ReactionProducts


Effects ofExposure/SymptomsSkin & Eyes : Exposure to vapours causes eye irritation, headache, fatigue, drowsiness, High concentration can produce central nervous sytem depression and optic nerve damage. 50000 ppm will probably cause death in 1-2 hrs. Can absorb through skin ingestion : Sweeling may cause death or eye damage.

LD50 (oral Rat)5628 mg/kgNFPA Hazard SignalsMF=16

Permissible exposure limit200 ppm(skin)Health 2HC = 8.6 BTU/lbx10-3

TLV (ACGIH)200 ppm(skin)Flammability 3Molecular Weight

STEL250 ppm(skin)Reactivity 032.1

Odour Threshold100 ppmSpecial 0Conversion1 ppm = 1.31 mg/m3

IDLH6000 ppm


(METHANOL)



Protective EquipmentProvide air-supplied respirator, (Do not use organic cannister Mask), Wear boots, Safety goggles, protective appron and rubber gloves. Provide eye wash and basin nearby.

Handling &StoragePrecautionsStore away from heat, ignition source, sparks, Keep away from heat and flame.


FIRE

Fire Extenguishing MediaCO2 Dry chemicals powder, Alcohol Foam, Water Mist/Fog.

Special ProcedureUnusual HazardsKeep the containers cool by spraying water if exposed to heat or flame. Containers may explode in fire.

Exposure


Inhalation : Remove the victim to fresh air area. Seek Medical Aid ImmediatelySkin : Remove the soak clothes and wash the affected area with plenty of water and soapEyes : Immediately wash with plenty of water for 15 minutes

Antidotes/Dosages Baking soda in glass of water

SPILLS

Steps to be TakenShut off leaks if without risks. Drench with water

Waste Disposal MethodSeal all waste in vapour tight plastic bags for eventual disposal

8. ADDITIONAL INFORMATION/REFERENCESA human poison by ingestion. Poison also by skin contact. The main toxic effect is extended to the nervous system, particularly optic nerves and Ratina, which may lead to permanent blindness. Once absorbed, it is slowly eliminated, Coma by severe exposure may lost for 2-4 days. Person with eye, liver, kidney & lung problem should avoid contact. Periodic medical check up is recommended. Dangerous fire hazard when exposed to heat, flame and oxidizers.


Name of Firm



11. Abbrevations














(N-METHYL DIETHANOLAMINE (MDEA)1. CHEMICAL IDENTITYRegulated Identification

Chemical NameN Methyl DiethanolAmine (MDEA)Shipping nameFire fightingChemical

SynonymsN-di (2-Hydraxyethyl) N- METHYLAMINECodes/Label


Chemical ClassificationHazchem Code

FormulaCH3-3(CH2-CH2-OH)2Hazardousclassification


1. N Methyl DiethanolAmine105-59-9U.N. No.


2.PHYSICAL/CHEMICAL DATAPhysical state

Boiling Pt/Range247C (477F)Vapour [email protected] 20C

Melting/Freezing Pt.-21C (-5.8F)pH

Vapour Density (Air =1)4.1AppearanceColourless to light yellow

Specific Gravity (Water =1)1.04189 at 20COdourSlight amine like odour119.16

Solubility, In water at 30CInfinitely solubleOthers(Molecular wt)

3.FIRE /EXPLOSION HAZARD DATAFlammability

Auto ignition TemperatureCN/ATDG Flammability



Hazardous combustion productsFlash Point C136C(CC)





OthersExplosive Material

4. REACTIVITY DATAChemical stability - Stable under ordinary conditions of use and storage.Darkens on exposure to air or light . Burning may produce CO, CO2, nitrogen oxides.

Incompatibility with other material

Reactivity

Hazardous Reaction Prods.

5. HEALTH HAZARD DATA6) Routes of Entry :

Effects of Exposure/ SymptomsInhalation : No adverse effects expected since MDEA has a low vapor pressure. Ingestion : May cause burns in the mouth, pharynx & esophagus, abdominal pain, Nausea, vomiting & diarrhea. Skin contact : May cause irritation, redness & pain especially on prolonged or repeated contact. Eye contact : Corrosive, contact causes severe irritation, burns, redness & pain. May cause irritation, redness, Pain & cornealdamage.




STELReactivity 1


IDLH

(N-METHYL DIETHANOLAMINE (MDEA )


Personnel Protective Equipment

Handling &Storage PrecautionsKeep in a tightly closed container, Store in a cool, dry ventilated area. Protect against physical damage isolate from any source of Heat or ignition. Avoid contact with copper & copper alloys. Material is suitably handled in stainless steel equipment. Do not use aluminum for storage of aqueous solution, outside or detached storage is preferred. Isolate from Acidic materials. Do not store above43C (110 F)

7. EMERGENCY/ FIRST AID MEASURES : Inhalation : Not expected to require first aid measures. Ingestion : If swallowed, Do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person.Get medical attention immediately.

FIRE

Fire Extinguishing MediaFire extinguishing media : Dry chemical, alcohol foam or carbon dioxide, water spray may be used to keep fire exposed materials cool. Water or foam may cause frothing.

Special ProcedureUnusual HazardsSpecial Information : In the event of a fire, wear full protective clothing & self contained breathing apparatus.

Exposure


Eyes : Use chemical safety goggles and / or a full face shield where splashing is possible. Maintain eyewash fountains & quick drench facilities in work area.


SPILLS

Steps to be Taken

Waste Disposal MethodWhatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility.

8. ADDITIONAL INFORMATION/REFERENCESLabel Hazard warning : Harmful if swallowed. Causes skin irritation and severe eye irritation. Avoid contact with eyes, skin& clothing. Wash thoroughly after handling. Avoid breathing vapour. Keep container closed. Use with adequate ventilation. Label first aid : If swallowed, do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Remove contaminated clothing & shoes. Wash clothing before reuse. If inhaled, remove to fresh air. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 mins. If not breathing, give artificial respiration. In all cases, get medical attention.


Contact Person in case of EmergencyName of Firm : Advance Petrochemicals Ltd, 167, PIRANA ROAD, PIPLAJ, Ahmedabad -382 405Phone (091)-7925715196, 25711218, Fax 091-79-25710027


11. Abbrevations














MATERIAL SAFETY DATA SHEET (NAPHTHA)1. CHEMICAL IDENTITYRegulated Identification

Chemical NameNAPHTHAShipping nameGasoline

Synonyms

Chemical ClassificationPetroleum NaphthaCoal TarSolventCodes/Label33/Class 3, Flammable Liquid

Trade NameHazardous Waste5

Chemical ClassificationHazchem Code3 Y E

FormulaA complex mixture ofHydrocarbonHazardousClassification


1. Naphtha8030-30-6U.N. No.1255


3

4

2.PHYSICAL/CHEMICAL DATAPhysical stateLiquid @ 15C & 1atm

Chemical NameVapour PressureNot available

Boiling Pt/Range35C to 205CpHNeutral

Melting/Freezing Pt.Not availableAppearanceDarkstraw coloured to colourless

Vapour Density (Air =1)2.5 to 4.8OdourPetrol like Odour

Specific Gravity (Water =1)0.69 to 0.78 gm/1 @20COthersSoluble in BenzeneToluene Xylene

Solubility, In water at 30CInsoluble in water, Floats on water


Auto ignition TemperatureC229- 293CTDG Flammability3


Explosion sensitivity to staticElectricityMay ExplodeUEL5.90%

Hazardous combustion productsAcrid smoke & irritating fumesFlash Point C-20 - 50C (OC)

Hazardous PolymerizationWill not occurFlash Point CNA (OC)




OthersNOExplosive MaterialNO


Incompatibility with other materialIncompatible with strong oxidizers

ReactivityDoes not react with common materials but may react with oxidizing agents

Hazardous ReactionProductsData Not available


Effects ofExposure/SymptomsInhalation : Can causes consciousness which may go to coma, Strentorious breathing& bluish tint to the skin. ingestion : In mild form, intoxication resembles drunkeness. Sometimes headache, lack of appetite, dizziness, sleeplessness, Indigestion & nausea. Chemical pneumonitis results if aspirated during ingestion of while vomiting. Can causesyestemic effects after repeated exposure. Skin : Causes Irritation, Prolonged contact will dry & defat skin with dermatitis. Eye : Imitation

LD50 (oral Rat)Not listed mg/kgNFPA Hazard SignalsMF=16

Permissible exposure limit300 ppm 900 mg/m3Health 1HC =18.0 BTU/lbx103

TLV (ACGIH)300 ppm 900 mg/m3Flammability 3Molecular Weight

STEL500 ppm 1500mg/m3Reactivity 0

Odour Threshold0.25 ppm 1300 mg/m3Special 0

(NAPHTHA)



Protective EquipmentHand gloves, Gas Mask. PVC Suit

Handling &StoragePrecautionsKeep in cool, well ventilated area away from heat flame or Oxidisers. Keep the containers tightly closed as the vapour fumes when exposed to air.


FIRE

Fire Extenguishing MediaDry Chemical powder, CO2, Foam

Special ProcedureUnusual HazardsKeep the containers cool, spraying water if exposed to fire

ExposureFlashback may occur along vapour trail


Inhalation : Remove the victim to fresh air area. Apply artificial respiration or Oxygen if neededIngestion : Seek medical aid immediately, Skin : Remove the contaminated clothing and wash the affected areas with plenty of water & soapEyes : Flush with plenty of water for 15 mins. Seek medical aid immediately without delay

Antidotes/Dosages Baking soda in glass of water

SPILLS

Steps to be TakenCollect leaking product into closed container. Use water spray to dilute the vapours. Prevent run-off from entering into sewer. Shut off leaks if no risk involved . Cantain/absorb spillage in earth/sand. Eliminate allsource of ignition. Ventilate the area.

Waste Disposal MethodCollect all the waste in vapour tight plastic bags for eventual disposal.

8. ADDITIONAL INFORMATION/REFERENCESEmergency treatment : Remove victim to fresh air. Give artificial respiration, if required, Remove contaminated clothing quickly. Do not induce vomiting if ingested. Keep patient warm and quit. Olive oil or any other vegetable oil should be given orally to retard absorption of naphtha.



Name of Firm


10. DISCLAIMERInformation contained in this MSDS is believed to be reliable but no representation, guarantee of warranties of any kind are made as to its accuracy, suitability for a particular application of results to be obtained for them. It is up to the user to ensure that the information containing in the material safety data sheet is relevant to the product manufactured/handled or used by him as the case may be. Helps makes no warranties expressed o

(216871532) msds

Documents

material reactive

skin eye contact

soap water

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medical attention

hazardous polymerizationwill

gentle flowing water

eye protection