240 230 220 210 200 190 180 170 160 150 140 130 120 110 ...240 230 220 210 200 190 180 170 160 150...
TRANSCRIPT
-4-3-2-1012345678910111213141516f1 (ppm)
-5000
0
5000
10000
15000
20000
25000
30000
35000
40000
45000
50000
55000
5.93
9.47
6.16
1.95
2.12
1.03
1.00
2.03
2.09
2.13
2.13
2.32
2.35
6.99
7.04
7.26
7.35
7.35
7.36
9.03
9.04
-20-100102030405060708090100110120130140150160170180190200210220230240f1 (ppm)
0
5
10
15
20
25
30
35
40
45
50
55
9.0
17.2
21.1
21.1
77.0
121.3
128.1
129.7
129.9
130.5
133.0
133.9
134.4
136.9
141.1
141.5
11.92
6.07
6.00
4.06
0.99
2.05
2.07
2.35
7.05
7.05
7.26
9.06
-10
010
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
f1(ppm)
8.71
17.41
21.30
77.16
128.37
128.71
130.10
134.60
141.59
NN
OT
f
6b
NN
OT
f
6b
-4-3-2-1012345678910111213141516f1 (ppm)
-5000
0
5000
10000
15000
20000
25000
30000
35000
40000
45000
50000
55000
60000
6.17
10.45
12.24
6.06
4.15
4.09
1.00
0.80
0.81
2.07
2.36
7.05
7.26
9.19
-20-100102030405060708090100110120130140150160170180190200210220230240f1 (ppm)
-20
-10
0
10
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
13.40
13.61
17.36
17.38
21.15
21.85
22.20
22.88
23.11
27.87
30.34
31.15
77.00
128.54
129.97
132.09
132.14
134.36
136.82
141.34
12.48
6.31
6.19
4.17
1.00
2.14
2.35
2.76
7.00
7.04
7.26
9.04
17.37
21.08
23.24
27.82
77.00
129.34
129.79
133.91
139.70
139.99
141.21
-4-3-2-1012345678910111213141516f1 (ppm)
-5000
0
5000
10000
15000
20000
25000
30000
35000
40000
45000
50000
55000
60000
65000
70000
75000
12.23
10.31
4.04
1.00
2.07
2.35
7.04
7.26
9.15
-20-100102030405060708090100110120130140150160170180190200210220230240f1 (ppm)
-10
0
10
20
30
40
50
60
70
80
90
100
110
120
130
140
17.3
19.9
21.1
21.5
76.6
77.0
77.4
128.4
129.9
130.9
134.3
135.9
141.3
-1.0
-0.5
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
6.0
6.5
7.0
7.5
8.0
8.5
9.0
9.5
10.0
10.5
11.0
f1(ppm)
4.12
2.08
12.08
6.01
3.99
4.00
0.98
1.72
1.74
1.89
1.90
2.05
2.34
2.43
2.45
2.47
7.04
7.26
8.98
1.6
1.8
2.0
2.2
2.4
2.6
f1(ppm)
4.12
2.08
12.08
6.01
3.99
1.72
1.74
1.89
2.05
2.34
2.43
2.45
2.47
17.44
21.27
23.90
30.17
77.16
128.60
129.99
133.86
141.51
NN
OT
f
6f
NN
OT
f
6f
-1.0
-0.5
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
6.0
6.5
7.0
7.5
8.0
8.5
9.0
9.5
10.0
10.5
11.0
f1(ppm)
12.01
2.993.04
2.00
2.01
1.00
5.02
4.28
2.31
0.99
2.11
2.13
2.36
2.66
3.15
3.17
3.20
6.44
6.47
7.01
7.03
7.06
7.23
7.25
7.26
7.30
9.31
6.5
7.0
7.5
f1(ppm)
1.00
5.02
4.28
2.31
6.44
6.47
7.01
7.03
7.06
7.23
7.25
7.26
2.0
2.5
3.0
f1(ppm)
12.01
2.99
3.04
2.00
2.01
2.11
2.13
2.36
2.41
2.66
2.69
2.72
3.15
3.17
3.20
-10
010
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
f1(ppm)
17.42
17.61
18.70
21.27
21.40
28.75
77.16
120.58
123.88
128.04
129.86
131.60
141.70
141.90
120
122
124
126
128
130
132
134
136
138
140
142
f1(ppm)
120.58
123.88
128.04
128.12
128.87
129.41
129.86
130.09131.60
134.35
134.53
134.63
137.42
141.70
141.90
NN
OT
f
6g
NN
OT
f
6g
-1.0
-0.5
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
6.0
6.5
7.0
7.5
8.0
8.5
9.0
9.5
10.0
10.5
11.0
f1(ppm)
23.99
3.96
8.00
4.00
2.02
0.98
1.19
1.21
1.24
1.26
1.95
2.25
2.28
2.30
2.32
2.33
2.34
7.26
7.33
7.35
7.54
7.56
7.59
9.39
7.0
7.2
7.4
7.6
7.8
f1(ppm) 4.00
2.02
7.26
7.33
7.35
7.54
7.56
7.59
1.0
1.5
2.0
2.5
f1(ppm)
23.99
3.96
8.00
1.19
1.21
1.24
1.26
1.95
2.25
2.28
2.30
2.32
2.33
-10
010
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
f1(ppm)
20.25
21.54
23.35
24.80
29.27
77.16
124.93
127.72
131.84
137.08
145.17
NN
OT
f
6h
NN
OT
f
6h
-1.0
-0.5
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
6.0
6.5
7.0
7.5
8.0
8.5
9.0
9.5
10.0
10.5
11.0
f1(ppm)
4.95
4.71
3.08
6.25
3.39
9.07
2.17
2.17
1.00
4.17
1.25
1.87
2.10
2.28
2.36
2.97
3.01
3.03
4.07
4.09
6.69
6.69
6.96
7.26
-10
010
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
f1(ppm)
9.92
18.26
19.80
28.72
33.28
33.99
50.91
51.50
77.16
81.65
82.23
120.36
128.14
128.24
129.63
129.71
130.60
133.85
134.48
134.94
136.32
138.48
180.60
120
122
124
126
128
130
132
134
136
138
140
f1(ppm)
120.36
128.14
128.24
129.63
129.71
130.60
133.85
134.48
136.32
137.29
137.89
138.48
138.69
17
18
19
20
21
22
f1(ppm)
18.26
18.37
19.76
19.80
21.24
21.31
NN
IrC
l
7a
NN
IrC
l
7a
-4-3-2-1012345678910111213141516f1 (ppm)
0
5000
10000
15000
20000
25000
30000
35000
40000
14.31
4.15
5.89
4.30
6.05
6.02
1.89
1.90
1.91
2.00
0.75
0.76
0.77
0.78
0.80
0.80
1.17
1.62
2.06
2.90
2.90
4.03
4.04
6.95
6.99
7.26
-20-100102030405060708090100110120130140150160170180190200210220230240f1 (ppm)
-20
-10
0
10
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
13.6
13.8
18.4
21.1
28.2
28.8
28.9
31.2
51.0
51.0
81.0
81.0
128.0
129.5
130.7
130.7
134.2
134.9
137.6
138.1
178.4
-4-3-2-1012345678910111213141516f1 (ppm)
-2000
0
2000
4000
6000
8000
10000
12000
14000
16000
18000
20000
22000
24000
26000
28000
30000
32000
34000
-20-100102030405060708090100110120130140150160170180190200210220230240f1 (ppm)
-10
0
10
20
30
40
50
60
70
80
90
100
110
120
18.2
19.7
21.1
23.8
28.0
28.9
33.5
51.1
77.0
82.0
127.9
129.4
134.2
134.8
137.1
138.2
138.2
186.0
4.80
4.194.37
10.25
12.41
1.89
1.88
4.00
1.24
1.25
1.26
1.63
2.04
2.08
2.303.03
3.03
3.04
4.06
4.07
4.08
6.96
6.99
7.26
-20
-10
010
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
f1(ppm)
-10
0 10
20
30
40
50
60
70
80
90
100
110
120
18.1
19.6
20.7
21.1
22.3
28.9
33.5
50.8
77.0
81.4
128.0
129.1
129.5
133.9
134.6
137.5
138.2
178.7
-0.50.00.51.01.52.02.53.03.54.04.55.05.56.06.57.07.58.08.59.09.510.010.511.0f1 (ppm)
-100102030405060708090100110120130140150160170180190200f1 (ppm)
18.35
19.86
21.28
24.78
27.34
29.02
30.78
33.64
50.79
77.16
80.92
128.00
129.63
132.07
134.32
135.26
138.06
138.43
177.47
N N
IrCl
7f
N N
IrCl
7f
-0.5
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
6.0
6.5
7.0
7.5
8.0
8.5
9.0
9.5
10.0
10.5
11.0
f1(ppm)
1.25
1.27
1.29
1.64
2.06
2.35
2.432.94
2.96
2.98
3.03
3.10
4.10
4.11
4.13
4.15
6.27
6.29
6.90
6.91
6.93
6.99
7.03
7.04
7.06
7.15
7.17
7.26
-10
010
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
f1(ppm)
18.33
18.56
19.76
19.84
20.03
21.31
21.43
28.81
29.22
29.78
33.92
51.24
51.58
77.16
82.14
82.55
119.75
126.68
127.37
128.21
128.45
128.59
129.82
130.00
131.80
133.57
133.79
134.76
135.15
135.36
137.73
137.87
138.85
138.96
7g
NN
IrC
l
7g
NN
IrC
l
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
6.0
6.5
7.0
7.5
8.0
f1(ppm)
12.94
2.51
3.92
16.682.14
2.12
4.01
2.35
4.18
2.04
3.94
2.00
1.06
1.08
1.26
1.33
1.63
1.702.10
2.11
2.11
2.12
2.14
3.13
3.13
3.14
3.28
4.55
4.56
4.56
6.99
7.00
7.09
7.21
7.23
7.28
7.29
7.31
010
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
f1(ppm)
22.66
23.05
25.47
25.96
29.13
29.51
34.48
50.61
82.97
124.88
130.24
135.26
137.86
148.17
185.14
NN
IrC
l
7h
NN
IrC
l
7h
-1.0
-0.5
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
6.0
6.5
7.0
7.5
8.0
8.5
9.0
9.5
10.0
10.5
11.0
f1(ppm)
3.00
6.19
6.19
6.31
0.96
2.05
2.00
1.95
1.95
2.16
2.22
2.35
2.37
6.84
6.84
6.99
7.02
7.26
-10
010
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
f1(ppm)
9.83
18.51
18.62
21.33
21.39
77.16
120.66
129.34
129.54
131.50
132.79
135.12
135.26
135.53
139.58
168.75
175.30
180.33
120
125
130
135
140
f1(ppm)
120.66
129.34
129.54
131.50
135.12
135.26
139.34
139.58
68
10
12
14
16
18
20
22
24
f1(ppm)
9.83
18.51
18.62
21.33
21.39
NN
Me
sM
es
IrC
OC
l
CO
8a
NN
Me
sM
es
IrC
OC
l
CO
8a
-4-3-2-1012345678910111213141516f1 (ppm)
-2000
0
2000
4000
6000
8000
10000
12000
14000
16000
18000
20000
22000
24000
26000
28000
30000
32000
34000
36000
38000
6.00
10.63
11.40
4.07
5.89
3.51
0.775
0.797
0.819
1.176
2.155
2.189
2.274
2.357
6.988
7.260
-20-100102030405060708090100110120130140150160170180190200210220230240f1 (ppm)
-10
0
10
20
30
40
50
60
70
80
90
100
110
120
130
13.6
13.8
18.7
18.7
21.2
22.1
22.2
23.4
23.6
28.1
30.6
31.2
129.3
131.4
131.5
133.2
135.4
139.0
168.6
173.3
180.3
-20-100102030405060708090100110120130140150160170180190200210220230240f1 (ppm)
-10
0
10
20
30
40
50
60
70
80
90
100
110
120
13018.5
21.2
23.6
28.2
76.6
77.0
77.4
129.2
133.7
135.0
138.9
139.1
168.6
180.2
180.4
-4-3-2-1012345678910111213141516f1 (ppm)
-5000
0
5000
10000
15000
20000
25000
30000
35000
40000
45000
50000
55000
4.08
16.48
6.94
4.00
1.80
2.16
2.35
6.99
7.26
-20-100102030405060708090100110120130140150160170180190200210220230240f1 (ppm)
-20
-10
0
10
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
18018.4
20.6
21.2
22.1
76.6
77.0
77.4
129.2
129.8
132.8
135.3
139.1
168.8
172.9
180.4
-4-3-2-1012345678910111213141516f1 (ppm)
0
5000
10000
15000
20000
25000
30000
35000
40000
5.44
2.52
13.47
4.62
6.88
4.00
1.66
2.14
2.18
2.27
2.29
2.31
2.35
6.99
7.26
7.36
-20-100102030405060708090100110120130140150160170180190200210220230240f1 (ppm)
-10
0
10
20
30
40
50
60
70
80
90
100
110
120
18.4
21.2
24.6
27.0
30.6
128.3
129.2
132.7
133.1
135.7
139.1
168.8
171.5
180.3
-4-3
-2-1
01
23
45
67
89
10
11
12
13
14
15
16
f1(ppm)
-2000
0 2000
4000
6000
8000
10000
12000
14000
16000
18000
20000
22000
24000
26000
28000
30000
12.52
6.81
2.42
2.18
0.99
1.11
4.00
1.45
1.13
2.178
2.214
2.371
2.422
2.491
2.517
2.544
3.008
3.035
3.061
6.306
6.332
6.934
6.959
6.985
7.024
7.055
7.085
7.089
7.110
7.113
7.135
7.138
7.200
7.223
7.260
-20
-10
010
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
f1(ppm)
-10
0 10
20
30
40
50
60
70
80
90
100
110
120
18.5
18.6
19.4
21.2
21.4
29.5
76.6
77.0
77.4
119.9
126.4
127.4
128.6
128.7
129.3
129.6
135.4
168.6
175.4
180.1
-1.0-0.50.00.51.01.52.02.53.03.54.04.55.05.56.06.57.07.58.08.59.09.510.010.511.0f1 (ppm)
12.09
12.01
4.02
3.96
4.00
3.98
2.03
1.13
1.15
1.37
1.75
2.24
2.82
2.84
2.86
2.89
2.91
2.93
2.95
7.26
7.31
7.34
7.47
7.49
7.52
0102030405060708090100110120130140150160170180190200f1 (ppm)
21.85
22.21
24.70
25.37
28.60
77.16
124.72
130.42
131.72
132.90
146.44
169.25
176.11
179.89
8h
N NDIPP DIPP
Ir COCl
CO
8h
N NDIPP DIPP
Ir COCl
CO