38.advantages and disadvantages of various plasticizers in different applications-mr. juergen...
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plasticisersTRANSCRIPT
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Advantages and Disadvantagesof various Plasticizers in different Applications
Jürgen Trimbach
Hansen & Rosenthal
IRE 2011Chennai, India
26.01.2010
H&R, 2011, TRJ
Agenda
� H&R – a short Introduction
� Plasticizers – some Basics
� Plasticizers in different Applications> PC Tyres> Truck Tyres> Transmission Belts> Profiles
� Conclusion
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H&R, 2011, TRJ
Introduction of H&R – the Highlights
1919 - Foundation of H&R in Hamburg, Germany
1956 - Tudapetrol, the H&R production site
1985 - First production of TDAE under the control of H&R
1994 - Merge of the Salzbergen refinery (BASF)
1996 - First production of MES under the control of H&R
2004 - Merge of the Hamburg refinery (BP)
Investment in a large plasticizer production
2005 - Start of the new TDAE production
Enlargement of the international production
(Thailand, China, Australia, South Africa, …)
2009 - First H&R production in North America
H&R, 2011, TRJ
Introduction of Hansen & Rosenthal – the Assets
Tank farm forProcess oils
Sales office
Blend plant
Production and
Tank farm forProcess oils
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H&R, 2011, TRJ
Introduction of H&R – the Highlights
Today, H&R is producing more than 350.000 mt
label free plasticizers for rubber applications
… plus Anti Ozone Waxes.
From the top 10 of the tyre industry 10 are on H&R´s
customer list.
From the top 10 of the technical rubber good producers
10 are on H&R´s customer list.
H&R, 2011, TRJ
Introduction of H&R – the Product Portfolio
0
10
20
30
40
50
60
70
80
90
0 10 20 30 40 50
Aromatic content [wt. %]
Vis
co
sit
y@
10
0 °
C [
mm
²/s
]
MES
TDAE
DAE
PAR
NAP
Plus Anti Ozone Waxes
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H&R, 2011, TRJ
Basics
PAR
RAE
100 200 1.000500 2.000 10.0005.000
0
10
20
30
40
50
Molecular weight [g/mol]
100 200 1.000500 2.000 10.0005.000
0
10
20
30
40
50
Aro
ma
tic
co
nte
nt[%
]
DAE
NAP
TDAE
MES
H&R, 2011, TRJ
Basics
BR
NR/IR
SBR
IIR
EPDM
CR
NBR
PAR NAP AR HAR Synth.
0,80 0,85 0,90 0,95 1,00
Viskosität-Dichte-Konstante (VDK)
PVC
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H&R, 2011, TRJ
Basics
BR
NR/IR
SBR
IIR
EPDM
CR
NBR
paraffinic naphthenic aromatic highly syntheticaromatic
0,80 0,85 0,90 0,95 1,00
constant of density and viscosity (VGC)
PVC
DAE
TDAE
MES
NAP
RAE
H&R, 2011, TRJ
Plasticizers in different Applications
RUBBER FILLER
OIL CHEMICALS
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H&R, 2011, TRJ
Performance of PC Tyres (Silica filled, SSBR/NdBR/NR)
H&R, 2011, TRJ
Performance of PC Tyres
60
70
80
90
100
110
Productivity
Rolling Resistance
Abrasion Loss
(after 30.000 miles)
Braking
wet and dry
Driving Comfort
(after 30.000 miles)
DAE
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H&R, 2011, TRJ
Performance of PC Tyres
Commission Regulation (EC) 1907/2006(formerly EU Directive 2005/69/EC)
„The ban of Polycyclic Aromatic Hydrocarbons“
starting 01.01.2010
Similar regulations in Japan and other countries
This regulation affects more and more the productionof technical rubber goods because more and moreauto manufacturers require also „cancer free TRG“.
H&R, 2011, TRJ
Performance of PC Tyres
EU Tyre Labelling Regulation 1222/2009
starting 01.11.2012
Similar regulations in North America, Japan and other countries
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H&R, 2011, TRJJanuar 11 15© 2010 • Hansen & Rosenthal KG
Performance of PC Tyres
60
70
80
90
100
110
Productivity
Rolling Resistance
Abrasion Loss
(after 30.000 miles)
Braking
wet and dry
Driving Comfort
(after 30.000 miles)
DAE
NAP
TDAE
RAE
H&R, 2011, TRJ
Performance of Truck Tyres (CB, NR/NdBR/ESBR)
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H&R, 2011, TRJ
80
85
90
95
100
105
Productivity
Rolling Resistance
Abrasion Loss
(after 40.000 miles)
Braking
wet and dry
Retreadability
DAE
NAP/MES
TDAE
RAE
Performance of Truck Tyres
H&R, 2011, TRJ
Transmission Belts (CR based, CB)
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H&R, 2011, TRJ
Performance of Transmission Belts
60
70
80
90
100
110
Productivity
Tear Resistance
Tear Propagation rateLife Time
Heat Dissipation
DAE
NAP
TDAE
RAE
H&R, 2011, TRJ
Profiles (EPDM based, Sulfur System)
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H&R, 2011, TRJ
Profiles
60
70
80
90
100
110
Productivity
Compression Set
Fatigue to FailureAbrasion Loss
Aging Properties
PAR
NAP (low CA)
RAE
MES
TDAE
H&R, 2011, TRJ
Conclusion
BR
NR/IR
SBR
IIR
EPDM
CR
NBR
paraffinic naphthenic aromatic highly syntheticaromatic
0,80 0,85 0,90 0,95 1,00
constant of density and viscosity (VGC)
PVC
DAE
TDAE
MES
NAP
RAE
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H&R, 2011, TRJ
Plasticizers, Compatibility with Rubbers
EPDM IIR (X)IIR BR NR SBR CR NBR
DAE
TDAE
MES
RAE
NAP
Veg. Oils
Synth. WM
PAR
- - - + + + + 0
- - + + + + + 0/-
- - - + + 0 - -
- - - 0 0 0 0 -
+ + 0 + + 0 - -
0 0 0 0 0 - - -
- - 0 - - 0 0/+ +
+ + 0 + + - - -
H&R, 2011, TRJ
Last but not least
Do you have any further questions?Thank you for your attention