4. exposure scenario 4: use at industrial site ... · 4.2.1. control of environmental exposure:...

4. Exposure scenario 4: Use at industrial site - electroplating Sn-source:electroplating and galvanic; PC 14; Pc 15; PC 19; PC 21; SU 0:

EXPOSURE SCENARIO ADDENDUM

Short description of all exposure scenarios

Table . Overview of all exposure scenarios and contributing scenarios

Identifiers Market

Sector

Titles of exposure scenarios and the related contributing

scenarios

ES1 - M1 Manufacture - Manufacture of tin sulphate in the EU

- Manufacture of tin dichloride in the EU (ERC 1)

- Laboratory use, reasearch and development, quality

control (PROC 15)

- Synthesis in closed process (scc) (PROC 1)

- synthesisprocess in continous closed system (PROC 2)

- synthesis process in batch closed system (PROC 3)

- synthesis in opens systems (PROC 4)

- General Transfer operations including filling and/or

repacking, decicated (PROC 8b)

ES2 - F1 Formulation - Formulation of mixtures (liquid and solid)

- Formulation of solutions (ERC 2)

- Mixing process under strictly controled conditions (PROC

1)

EC Number: 231-302-2CAS Number: 7488-55-3Date of Generation/Revision: 13/05/2014 / Revision 8

ANODAL COLOR T LIQ.

Identifiers Market

Sector


scenarios

- mixing process in continous closed system (PROC 2)

- mixing process in batch closed system (PROC 3)

- Mixing in opens systems (PROC 4)

- GGeneral Transfer operations including filling and/or



control (PROC 15)

- Mixing operations in batch processes with multistage

contact (PROC 5)


repacking, non-decicated (PROC 8a)

- Transfer operations, special filling system (PROC 9)

- Production of preparations* or articles by tabletting,

compression, extrusion, pelletisation (PROC 14)

ES3 - F2 PC 14;

PC 15;

PC 19;

PC 21

Formulation - Formulation of solutions

- Formulation of solutions (ERC 2)


1)




- GGeneral Transfer operations including filling and/or



control (PROC 15)


Safety Data Sheet

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Safety Data Sheet

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Identifiers Market

Sector


scenarios

contact (PROC 5)



ES4 - IW1 PC 14;

PC 15;

PC 19;

PC 21

Use at industrial site - electroplating Sn-source

- Electroplating Sn-Source (ERC 6a)


1)




- electroplating operation (PROC 13)


control (PROC 15)


contact (PROC 5)






ES5 - IW2 PC 14;

PC 15;

PC 19;

PC 21


- Electroplating Sn-Source (ERC 5)


1)


Safety Data Sheet

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Identifiers Market

Sector


scenarios





control (PROC 15)


contact (PROC 5)



- Transfer operations, special filling systems (PROC 9)



ES6 - IW3 PC 14;

PC 15;

PC 19;

PC 21


- Electroplating Sn-Source (ERC 4)


1)






control (PROC 15)

ES7 - SL-PW1 PC 14;

PC 15;

PC 19;

PC 21

Service life (professional worker) - Service life (professional

worker)

- Service life (professional worker) (ERC 11a)

Safety Data Sheet

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Identifiers Market

Sector


scenarios

ES8 - SL-C1 PC 14;

PC 15;

PC 19;

PC 21

Service life (consumers) - Service life (consumers)

- Service life (consumers) (ERC 11a)

ES9 - IW4 PC 1; PC

19; PC

21; PC

32; PC 0

Use at industrial site - reduction agent

- reduction agent (ERC 6a)


1)





repacking, dedicated (PROC 8b)


control (PROC 15)


contact (PROC 5)






- Manual cutting, cold rolling or assembly/disassembly of

material/article (PROC 21)

ES10 - IW5 PC 1; PC

19; PC

21; PC

32; PC 0

Use at industrial site - general catalyst use (incl. reactive

catalyst

- general catalyst use (incl. reactive catalyst (ERC 5)

Safety Data Sheet

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Identifiers Market

Sector


scenarios


1)







control (PROC 15)


contact (PROC 5)








ES11 - IW6 PC 1; PC

19; PC

21; PC

32; PC 0

Use at industrial site - Sn Source in chemical industry /

intermediate use

- Sn Source in chemical industry / intermediate use (ERC

6d)


1)




Safety Data Sheet

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Identifiers Market

Sector


scenarios




control (PROC 15)


contact (PROC 5)








ES12 - SL-PW2 PC 1; PC

19; PC

21; PC

32; PC 0


worker)


ES13 - SL-C2 PC 1; PC

19; PC

21; PC

32; PC 0



ES14 - F3 PC 9b;

PC 19;

PC 21;

PC 0

Formulation - Formulation of solutions

- Formulation of cement mixtures (reduction of Cr VI into

Cr III in later contact with humidity and or water (substance

reacts in the mixture) (ERC 2)


1)


Safety Data Sheet

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Identifiers Market

Sector


scenarios






control (PROC 15)


contact (PROC 5)



ES15 - SL-PW3 PC 9b;

PC 19;

PC 21;

PC 0


worker)


- Stone, plaster, cement, glass and ceramic articles (PROC

21)

ES16 - SL-C3 PC 9b;

PC 19;

PC 21;

PC 0



- Stone, plaster, cement, glass and ceramic articles (AC 4)

STANNOUS SULPHATE 225 GR/L SCENARIO ESPOSITIVO 4 bozza 06 08 2014

Safety Data Sheet

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4. Exposure scenario 4: Use at industrial site - electroplating Sn-source:electroplating and galvanic; PC 14; Pc 15; PC 19; PC 21; SU 0:

4.1. Title section

4.2. Condition of use affetcting exposure

4.3. Exposure estimation and reference to ist source

4.4. Guidance to DU to evaluate whether he works inside the boundaries set by theES

4.1. Title section

Metal surface treatment products, including galvanic and electroplating products (PC 14)

Non-metal-surface treatment products (CPC 15);

Intermediate (PC 19);

Laboratory Chemicals (PC 21);

Other (electroplating and galvanic) (SU 0)

Environment contributing scenario(s):

CS 1 Electroplating Sn-Source ERC 6a

Worker contributing scenario(s):

CS 2Mixing process under strictly controled conditions PROC 1

CS 3mixing process in continous closed system PROC 2

CS 4mixing process in batch closed system PROC 3

CS 5Mixing in opens systems PROC 4

Safety Data Sheet

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CS 6 electroplating operation PROC 13

CS 7 Laboratory use, reasearch and development, quality control PROC 15

CS 8 Mixing operations in batch processes with multistage contact PROC 5

CS 9 General Transfer operations including filling and/or repacking,

non-decicated

PROC 8a

CS 10 Transfer operations, special filling system PROC 9

CS 11 General Transfer operations including filling and/or repacking, decicated PROC 8b

4.2. Condition of use affetcting exposure

4.2.1. Control of environmental exposure: Electroplating Sn-Source (ERC 6a)

Amount used, frequency and duration of use (or from service life)

• Daily use at site: <= 14.5 tonnes/day

• Annual use at a site: <= 290 tonnes/year

• Percentage of tonnage used at regional scale: = 100 %

Conditions and measures related to sewage treatment plant

• Municipal STP: Yes [Effectiveness Water: 43.95%]

• Discharge rate of STP: >= 2E3 m3/d

• Application of the STP sludge on agricultural soil: Yes

Conditions and measures related to treatment of waste (including article waste)

• Particular considerations on the waste treatment operations: No (low risk) (ERC based assessment

demonstrating control of risk with default conditions. Low risk assumed for waste life stage. Waste

disposal according to national/local legislation is sufficient.)

Safety Data Sheet

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Other conditions affecting environmental exposure

• Receiving surface water flow rate: >= 1.8E4 m3/d

4.2.2 Control of worker exposure: Mixing process under strictly controled conditions (PROC 1)

Product (article) characteristics

• Dustiness of material: Low

• Concentration of substance in mixture: Substance as such

Amount used (or contained in articles), frequency and duration of use/exposure

• Duration of activity: < 8 hours

Technical and organisational conditions and measures

• General ventilation: Basic general ventilation (1-3 air changes per hour)

• Containment: Closed system (minimal contact during routine operations)

• Occupational Health and Safety Management System: Advanced

Conditions and measures related to personal protection, hygiene and health evaluation

• Dermal Protection: No [Effectiveness Dermal: 0%]

• Respiratory Protection: No [Effectiveness Inhal: 0%] ))))))))))))))))))))))))))))))))))))))))))))))))))

Other conditions affecting workers exposure

• Place of use: Indoor

• Process temperature (for solid): Ambient

4.2.3. Control of worker exposure: mixing process in continous closed system (PROC 2)


Safety Data Sheet

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• Concentration of substance in mixture: Substance as suc





• Containment: Closed continuous process with occasional controlled exposure

• Local exhaust ventilation: yes [Effectiveness Inhal: 90%]

• Local exhaust ventilation (for dermal): yes [Effectiveness Dermal: 90%]



• Dermal Protection: Yes (chemically resistant gloves conforming to EN374 with basic employee

training) [Effectiveness Dermal: 90%]




4.2.4. Control of worker exposure: mixing process in batch closed system (PROC 3)






Safety Data Sheet

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• Containment: Closed batch process with occasional controlled exposure








4.2.4. Control of worker exposure: Mixing in opens systems (PROC 4)








• Containment: Semi-closed process with occasional controlled exposure




Safety Data Sheet

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4.2.6. Control of worker exposure: electroplating operation (PROC 13)








(((((((((((((((((((((((((((((• Containment: No TRA Worker

v3)))))))))))))))))))))))))))))

)))))))








Safety Data Sheet

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4.2.7. Control of worker exposure: Laboratory use, reasearch and development, quality control(PROC 15)















4.2.8. Worker contributing scenario 7: Mixing operations in batch processes with multistagecontact (PROC 5)



Safety Data Sheet

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4.2.9. Control of worker exposure: General Transfer operations including filling and/orrepacking, non-decicated (PROC 8a)







Safety Data Sheet

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4.2.10. Control of worker exposure: Transfer operations, special filling system (PROC 9)












Safety Data Sheet

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4.2.11. Control of worker exposure: General Transfer operations including filling and/orrepacking, decicated (PROC 8b)














• Respiratory Protection: No [Effectiveness Inhal: 0%]



Safety Data Sheet

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4.3. Exposure estimation and reference to ist source

4.3.1. Environmental release and exposure: Electroplating Sn-Source (ERC 6a)

Release

route

Release rate Release estimation

method

Water 0.014 Kg/day Release factor

Air 0.145 Kg/day Release factor

Soil o.145 Kg/day Release factor

Protection target Exposure estimate (based on EUSES

2.1.2)

Risk characterisation

Freshwater Local PEC: 4.064E-4 mg/L RCR = 0.136

Sediment (freshwater) Local PEC: 0.004 mg/kg dw RCR < 0.01

Marine water Local PEC: 4.064E-5 mg/L RCR < 0.01

Sediment (marine water) Local PEC: 3.727E-4 mg/kg dw RCR < 0.01

Sewage treatment plant Local PEC: 0.004 mg/L RCR < 0.01

Agricultural soil Local PEC: 0.003 mg/kg dw RCR = 0.037

Man via Environment -

Inhalation

Qualitative risk

characterisation (see below)

Man via Environment - Oral Exposure via food consumption:

4.49E-4 mg/kg bw/day

RCR = 0.073

Safety Data Sheet

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Protection target Exposure estimate (based on EUSES

2.1.2)

Risk characterisation

Man via environment -

combined routes

RCR = 0.073

4.3.2 Worker exposure: Mixing process under strictly controled conditions (PROC 1)

Route of exposure and type

of effects

Exposure estimate Risk characterisation

Inhalation, systemic,

long-term

0.01 mg/m³ (TRA Worker v3) RCR < 0.01

Inhalation, systemic, acute 0.04 mg/m³ (TRA Worker v3) RCR < 0.01

Inhalation, local, long-term 0.01 mg/m³ (TRA Worker v3) RCR < 0.01

Inhalation, local, acute 0.04 mg/m³ (TRA Worker v3) RCR < 0.01

Dermal, systemic, long-term 0.034 mg/kg bw/day (TRA Worker v3) RCR = 0.309

Dermal, local, long-term 0.01 mg/cm² (TRA Worker v3) RCR < 0.01

Combined routes, systemic,

long-term

RCR = 0.31


acute

RCR < 0.01

4.3.3. Worker exposure: mixing process in continous closed system (PROC 2)


of effects



long-term


Safety Data Sheet

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of effects








long-term

RCR = 0.125


acute

RCR < 0.01

4.3.4. Worker exposure: mixing process in batch closed system (PROC 3)


of effects

Exposure estimante Risk characterisation


long-term

0.1 mg/m³ (TRA Worker v3) RCR = 0.012

Inhalation, systemic, acute 0.4 mg/m³ (TRA Worker v3) RCR = 0.05

Inhalation, local, long-term 0.1 mg/m³ (TRA Worker v3) RCR = 0.012

Inhalation, local, acute 0.4 mg/m³ (TRA Worker v3) RCR = 0.05




long-term

RCR = 0.64

Safety Data Sheet

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of effects

Exposure estimante Risk characterisation


acute

RCR = 0.05

4.3.5. Worker exposure: Mixing in opens systems (PROC 4)


of effects



long-term








long-term

RCR = 0.63


acute

RCR = 0.025

4.3.6. Worker exposure: electroplating operation (PROC 13)


of effects



long-term


Safety Data Sheet

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of effects








long-term

RCR = 0.749


acute

RCR < 0.01

4.3.7. Worker exposure: Laboratory use, reasearch and development, quality control (PROC 15)


of effects



long-term

0.1 mg/m³ (TRA Worker v3) RCR = 0.012


Inhalation, local, long-term 0.1 mg/m³ (TRA Worker v3) RCR = 0.012





long-term

RCR = 0.322

Safety Data Sheet

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of effects



acute

RCR = 0.05

4.3.8. Worker exposure: Mixing operations in batch processes with multistage contact (PROC 5)


of effects



long-term








long-term

RCR = 0.752


acute

RCR = 0.025

4.3.9. Worker exposure: General Transfer operations including filling and/or repacking,non-decicated (PROC 8a)


of effects


Inhalation, systemic, 0.03 mg/m³ (TRA Worker v3) RCR < 0.01

Safety Data Sheet

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of effects


long-term







long-term

RCR = 0.752


acute

RCR = 0.025

4.3.10. Worker exposure: Transfer operations, special filling system (PROC 9)


of effects



long-term







Safety Data Sheet

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of effects



long-term

RCR = 0.625


acute

RCR < 0.01

4.3.11. Worker exposure: General Transfer operations including filling and/or repacking,decicated (PROC 8b)


of effects



long-term








long-term

RCR = 0.624


acute

RCR < 0.01

Safety Data Sheet

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4.4. Guidance to DU to evaluate whether he works inside the boundaries set by theES

The downstream user (DU) works inside the boundaries set by the ES if either the proposed risk

management measures as described above are met or the DU can demonstrate on his own that his

operational conditions and implemented risk management measures are adequate. This has to be

done by showing that they limit the inhalation and dermal exposure to a level below the respective

DNEL (given that the processes and activities in question are covered by the PROCs listed above) as

given below. If measured data are not available, the DU may make use of an appropriate scaling tool

such as ECETOC to estimate the associated exposure

4. exposure scenario 4: use at industrial site ... · 4.2.1. control of environmental exposure:...

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