5.1 – natural radioactivity 5.2 – nuclear reactions 5.3...

26
Chapter 5 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 – Radiation Measurement 5.4 – Half-Life of a Radioisotope 5.5 – Medical Applications using Radioactivity 5.6 – Nuclear Fission and Fusion Goal: Describe alpha, beta, positron, and gamma radiation. Most naturally occurring isotopes of elements up to atomic number 19 have stable nuclei (plural of nucleus). In stable nuclei, the nuclear forces balance the repulsions between the positive protons. Elements above atomic number 19 generally have one or more isotopes with unstable nuclei. The nuclear forces cannot offset the repulsions from the greater number of protons. The nuclei become unstable and spontaneously emits small particles of energy (radiation) to become more stable. Unstable nuclei are called radioisotopes and are said to be radioactive.

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Page 1: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

Ch

apte

r 5

5.1

–N

atur

al R

adio

acti

vity

5.2

–N

ucle

ar R

eac

tio

ns

5.3

–R

adia

tio

n M

eas

ure

me

nt

5.4

–H

alf-

Life

of a

Rad

iois

oto

pe

5.5

–M

ed

ical

Ap

pli

cati

on

s us

ing

Rad

ioac

tivi

ty

5.6

–N

ucle

ar F

issi

on

an

d F

usio

n

Go

al: D

esc

rib

e a

lph

a, b

eta

, po

sitr

on

, an

d g

amm

a ra

dia

tio

n.

Mo

st n

atur

ally

occ

urri

ng

iso

top

es

of e

lem

en

ts u

p to

ato

mic

num

be

r 19

hav

e s

tab

le

nucl

ei (

plu

ral o

f nuc

leus

).

In s

tab

le n

ucle

i, th

e n

ucle

ar fo

rce

s b

alan

ce th

e r

ep

ulsi

on

s b

etw

ee

n th

e p

osi

tive

pro

ton

s.

Ele

me

nts

ab

ove

ato

mic

num

be

r 19

ge

ne

rally

hav

e o

ne

or

mo

re is

oto

pe

s w

ith

un

stab

le n

ucle

i.T

he

nuc

lear

forc

es

can

no

t off

set t

he

re

pul

sio

ns

fro

m th

e g

reat

er

num

be

r o

f pro

ton

s.

Th

e n

ucle

i be

com

e u

nst

able

an

d s

po

nta

ne

ous

ly e

mit

s sm

all p

arti

cle

s o

f en

erg

y (r

adia

tion

)to

be

com

e m

ore

sta

ble

.

Un

stab

le n

ucle

i are

cal

led

rad

iois

otop

esan

d a

re s

aid

to b

e r

adio

acti

ve.

Page 2: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

Rad

iati

on

can

be

em

itte

d fr

om

a r

adio

iso

top

e in

the

form

of:

Alp

ha

(α)p

arti

cle

sB

eta

(β)

par

ticl

es

Posi

tro

ns

(β+)

Pur

e e

ne

rgy

(exa

mp

le:

gam

ma

(γ) r

ays)

A r

adio

isot

ope

Is a

n is

oto

pe

of a

n e

lem

en

t th

at e

mit

s ra

dia

tio

n.

Can

be

on

e o

r m

ore

iso

top

es

of a

n e

lem

en

t.In

clud

es

the

mas

s nu

mb

er

in it

s n

ame.

Th

e a

tom

ic n

umb

er

of i

od

ine

-131

has

a m

ass

num

be

r o

f 131

an

d a

n

ato

mic

num

be

r o

f 53.

By

em

itti

ng

rad

iati

on

, an

un

stab

le n

ucle

us fo

rms

a m

ore

sta

ble

, low

er

en

erg

y nu

cle

us.

Alp

ha

par

ticl

esar

e id

en

tica

l to

a h

eli

um n

ucle

us (

2 p

roto

ns,

2 n

eut

ron

s).

Mas

s nu

mb

er

= 4

(2

pro

ton

s +

2 n

eut

ron

s)

Ato

mic

num

be

r =

2

(2 p

roto

ns)

Ch

arg

e =

+2

or

Page 3: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

By

em

itti

ng

rad

iati

on

, an

un

stab

le n

ucle

us fo

rms

a m

ore

sta

ble

, low

er

en

erg

y nu

cle

us.

Bet

a p

arti

cles

are

hig

h e

ne

rgy

ele

ctro

ns

Mas

s nu

mb

er

= 0

Ato

mic

num

be

r =

0

Ch

arg

e =

-1

(or

1-)

A b

eta

par

ticl

e is

form

ed

wh

en

a n

eut

ron

in a

nun

stab

le n

ucle

us c

han

ge

s in

to a

pro

ton

.

By

em

itti

ng

rad

iati

on

, an

un

stab

le n

ucle

us fo

rms

a m

ore

sta

ble

, low

er

en

erg

y nu

cle

us.

Pos

itro

ns

are

hig

h e

ne

rgy

ele

ctro

ns

wit

h a

pos

itiv

e ch

arge

Mas

s nu

mb

er

= 0

Ato

mic

num

be

r =

0

Ch

arg

e =

+1

(or

1+)

A p

osi

tro

n is

pro

duc

ed

by

an u

nst

able

nuc

leus

wh

en

a

pro

ton

is tr

ansf

orm

ed

into

a n

eut

ron

an

d a

po

sitr

on

.

By

em

itti

ng

rad

iati

on

, an

un

stab

le n

ucle

us fo

rms

a m

ore

sta

ble

, low

er

en

erg

y nu

cle

us.

Pur

e e

ne

rgy

call

ed

gam

ma

ray

Mas

s nu

mb

er

= 0

Ato

mic

num

be

r =

0

Ch

arg

e =

0

Re

leas

ed

wh

en

an

un

stab

le n

ucle

us u

nd

erg

oe

s a

rear

ran

ge

men

t of i

ts p

arti

cle

s to

giv

e

a m

ore

sta

ble

, low

er

en

erg

y nu

cle

us.

Gam

ma

rays

are

oft

en

em

itte

d a

lon

g w

ith

oth

er

typ

es

of r

adia

tio

n a

t th

e s

ame

tim

e.

Page 4: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

Ide

nti

fy th

e ty

pe

of r

adia

tio

n fr

om

the

foll

owin

g d

esc

rip

tio

ns:

A. C

on

tain

s 2

pro

ton

s an

d 2

ne

utro

ns

B. H

as a

mas

s nu

mb

er

of 0

an

d a

1-

char

ge

Ion

izin

g r

adia

tio

n s

trik

es

mo

lecu

les

in

its

pat

h a

nd

K

no

cks

away

the

ele

ctro

ns

in

mo

lecu

les,

form

ing

un

stab

le io

ns

such

as

H2O

+.

Cau

ses

und

esi

rab

le c

he

mic

al

reac

tio

ns.

Dam

age

s th

e c

ell

s w

hic

h m

ay lo

se

the

ir a

bil

ity

to p

rod

uce

ne

cess

ary

mat

eri

als.

Can

cer.

Dif

fere

nt t

ype

s o

f ra

dia

tio

n p

en

etr

ate

the

b

od

y to

dif

fere

nt d

ep

ths.

Mo

st s

usce

pti

ble

ce

lls

are

tho

se th

at u

nd

erg

o r

apid

ce

ll

div

isio

n (

reg

en

era

tio

n):

ado

lesc

en

t ce

lls

bo

ne

mar

row

skin

rep

rod

ucti

ve o

rgan

s

inte

stin

al li

nin

gFi

gh

t fir

e w

ith

fire

!

Man

y p

rofe

ssio

ns

exp

eri

en

ce w

ork

wit

h r

adio

acti

ve

iso

top

es:

Nuc

lear

me

dic

ine

tech

no

log

ists

, ch

em

ists

, do

cto

rs, a

nd

nur

ses

MR

I (m

agn

eti

c re

son

ance

imag

ing

), X

-ray

s, C

T s

can

s (c

om

put

ed

to

mo

gra

phy

), P

ET

(p

osi

tro

n e

mis

sio

n to

mo

gra

phy

),ca

nce

r tr

eat

me

nt,

etc

.

Pro

pe

r sh

ield

ing

is n

ee

de

d to

pro

tect

yo

urse

lf fr

om

ra

dia

tio

n.

Page 5: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

Rad

iati

on

pro

tect

ion

re

qui

rem

en

ts d

ep

en

d o

n th

e ty

pe

of

rad

iati

on

:A

lpha

par

ticle

s ar

e s

low

an

d la

rge

an

d o

nly

trav

el a

few

ce

nti

me

ters

b

efo

re c

oll

idin

g w

ith

air

mo

lecu

les,

acq

uire

ele

ctro

ns,

an

d b

eco

me

st

able

he

lium

ato

ms.

Pap

er

and

clo

thin

g b

lock

s al

ph

a p

arti

cle

s.

Beta

par

ticle

s ar

e v

ery

sm

all a

nd

mov

e m

uch

fast

er

and

fart

he

r th

an

alp

ha

par

ticl

es.

Th

ey c

an tr

ave

l sev

era

l me

ters

. Th

ey c

an p

ass

thro

ugh

p

ape

r an

d p

en

etr

ate

4-5

mm

into

the

bo

dy.

T

hre

at: s

kin

can

cer

He

avy

clo

thin

g (

lab

co

ats

and

glo

ves)

pro

tect

ag

ain

st b

eta

par

ticl

es.

Gam

ma

rays

trav

el g

reat

dis

tan

ces

thro

ugh

the

air

an

d p

ass

thro

ugh

m

any

mat

eri

als

(in

clud

ing

bo

dy

tiss

ues)

Incr

ed

ibly

dan

ge

rous

.O

nly

ve

ry d

en

se s

hie

ldin

g (

lead

or

con

cre

te)

wil

l sto

p g

amm

a ra

ys.

Dif

fere

nt t

ype

s o

f ra

dia

tio

n p

en

etr

ate

the

b

od

y to

dif

fere

nt d

ep

ths.

For

tho

se w

ork

ing

in a

n e

nvir

on

me

nt w

he

re r

adio

acti

ve m

ate

rial

s ar

e p

rese

nt,

lim

it

your

exp

osu

re b

yM

inim

izin

g th

e a

mo

unt o

f tim

e s

pe

nt n

ear

a r

adio

acti

ve s

our

ce.

Incr

eas

ing

the

dis

tan

ce fr

om

the

so

urce

.

Ind

icat

e w

hat

typ

e o

f rad

iati

on

(al

ph

a, b

eta

, an

d/o

r g

amm

a) th

at is

p

rote

cte

d fo

r e

ach

typ

e o

f sh

ield

ing

.

A.

He

avy

clo

thin

g

B.

Pap

er

C.

Lead

D.

Th

ick

co

ncr

ete

5.1

–N

atur

al R

adio

acti

vity

5.2

–N

ucle

ar R

eac

tio

ns

5.3

–R

adia

tio

n M

eas

ure

me

nt

5.4

–H

alf-

Life

of a

Rad

iois

oto

pe

5.5

–M

ed

ical

Ap

pli

cati

on

s us

ing

Rad

ioac

tivi

ty

5.6

–N

ucle

ar F

issi

on

an

d F

usio

n

Page 6: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

Go

al: W

rite

a b

alan

ced

nuc

lear

eq

uati

on

sh

owin

g m

ass

num

be

rs fo

r ra

dio

acti

ve d

eca

y.

In a

pro

cess

cal

led

rad

ioac

tive

dec

ay, a

nuc

leus

sp

on

tan

eo

usly

bre

aks

dow

n b

y e

mit

tin

g

rad

iati

on

. T

his

can

be

sh

own

wit

h a

nuc

lear

eq

uatio

n:

Rad

ioac

tive

nuc

leus

n

ew n

ucle

us +

rad

iati

on

(α,

β, β

+, o

r γ)

Cf→Cm+

HeT

he

mas

s nu

mb

er

and

ato

mic

num

be

r m

ay c

han

ge.

Th

e s

um o

f th

e m

ass

num

be

rs a

nd

the

ato

mic

num

be

rs m

ust b

e e

qua

l fo

r th

e r

eac

tan

ts (

left

si

de

) an

d th

e p

rod

ucts

(ri

gh

t sid

e).

Alp

ha

dec

ayo

ccur

s w

he

n a

ra

dio

acti

ve n

ucle

us e

mit

s an

al

ph

a p

arti

cle,

form

ing

a n

ew

nucl

eus

wit

h:

Th

e m

ass

nu

mb

er d

ecre

ased

by

4T

he

atom

ic n

um

ber

dec

reas

ed

by 2

Page 7: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

Co

mp

lete

the

foll

owin

g n

ucle

ar e

qua

tio

n fo

r th

e d

eca

y o

f am

eri

cium

-241

:

In th

e n

ucle

ar e

qua

tio

n fo

r b

eta

dec

ay, a

bet

a p

arti

cle,

(an

ele

ctro

n),

is

em

itte

d fr

om

the

nuc

leus

w

he

n a

ne

utro

n in

the

nu

cle

us b

reak

s d

own

, fo

rmin

g a

pro

ton

an

d a

be

ta

par

ticl

e a

nd

incr

eas

ing

the

at

om

ic n

umb

er

by

1.

Wri

te a

n e

qua

tio

n fo

r th

e d

eca

y o

f 42K

, a b

eta

em

itte

r.W

rite

the

nuc

lear

eq

uati

on

for

the

be

ta d

eca

y o

f 60C

o.

Page 8: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

In p

osit

ron

em

issi

on,

A p

roto

n is

co

nve

rte

d to

a n

eut

ron

an

d a

po

sitr

on

Th

e m

ass

num

be

r o

f th

e n

ew n

ucle

us is

the

sam

e, b

ut th

e a

tom

ic

num

be

r d

ecr

eas

es

by

1.

Wri

te th

e n

ucle

ar e

qua

tio

n fo

r th

e p

osi

tro

n e

mis

sio

n o

f 44K

In g

amm

a ra

dia

tion

En

erg

y is

em

itte

d fr

om

an

un

stab

le n

ucle

us, i

nd

icat

ed

by

mfo

llow

ing

the

mas

s nu

mb

er.

Th

e m

ass

num

be

r an

d th

e a

tom

ic n

umb

er

of t

he

new

nuc

leus

are

th

e s

ame.

Wh

en

the

nuc

lei o

f alp

ha,

b

eta

, po

sitr

on

, an

d g

amm

a e

mit

ters

em

it r

adia

tio

n,

new

an

d m

ore

sta

ble

nuc

lei

are

pro

duc

ed

.

Page 9: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

Rad

ioac

tive

isot

opes

are

pro

duc

ed

Wh

en

a s

tab

le n

ucle

us is

co

nve

rte

d to

a r

adio

acti

ve n

ucle

us b

y b

om

bar

din

g it

wit

h a

sm

all p

arti

cle.

Th

is is

cal

led

tran

smu

tati

on.

Wri

te th

e b

alan

ced

nuc

leus

eq

uati

on

for

the

bo

mb

ard

me

nt o

f nic

kel-

58 b

y a

pro

ton

H, whic

h p

rod

uce

s a

rad

ioac

tive

iso

top

e a

nd

an

alp

ha

par

ticl

e.

Wh

at r

adio

acti

ve is

oto

pe

is p

rod

uce

d w

he

n a

ne

utro

n b

om

bar

ds

98T

c,

rele

asin

g a

alp

ha

par

ticl

e?

5.1

–N

atur

al R

adio

acti

vity

5.2

–N

ucle

ar R

eac

tio

ns

5.3

–R

adia

tio

n M

eas

ure

me

nt

5.4

–H

alf-

Life

of a

Rad

iois

oto

pe

5.5

–M

ed

ical

Ap

pli

cati

on

s us

ing

Rad

ioac

tivi

ty

5.6

–N

ucle

ar F

issi

on

an

d F

usio

n

Page 10: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

Go

al: D

esc

rib

e th

e d

ete

ctio

n a

nd

me

asur

em

en

t of r

adia

tio

n.

A G

eige

r co

un

ter

is a

co

mm

on

inst

rum

en

t th

atD

ete

cts

be

ta a

nd

gam

ma

rad

iati

on

Use

s io

ns

pro

duc

ed

by

rad

iati

on

to c

reat

e a

n e

lect

ric

curr

en

t.

Ar

+ r

adia

tio

n

Ar+

+ e

-

Th

e a

ctiv

ity

of a

rad

iois

oto

pe

is d

efi

ne

d a

s th

e n

umb

er

of

dis

inte

gra

tio

ns

pe

r se

con

d.

Th

e C

uri

e (C

i): t

he

num

be

r o

f dis

inte

gra

tio

ns

that

occ

ur in

1 s

for

1 g

of r

adiu

m.

Nam

ed

aft

er

Mar

ie a

nd

Pie

rre

Cur

ie, w

ho

dis

cove

red

rad

ium

an

d p

olo

niu

m.

Th

e S

I un

it fo

r ac

tivi

ty is

the

bec

qu

erel

(Bq

): 1

dis

inte

gra

tio

n p

er

seco

nd

.

An

oth

er

way

to m

eas

ure

rad

iati

on

is b

y th

e a

mo

unt a

bso

rbe

d b

y a

mat

eri

al (

such

as

bo

dy

tiss

ue).

T

he

rad

(rad

iati

on a

bso

rbed

dos

e) is

a u

nit

that

me

asur

es

the

am

oun

t of

rad

iati

on

ab

sorb

ed

by

a g

ram

of m

ate

rial

.T

he

SI u

nit

for

rad

iati

on

ab

sorp

tio

n is

the

gra

y (G

y) –

the

joul

es

of e

ne

rgy

abso

rbe

d b

y 1k

g o

f bo

dy

tiss

ue. (

1 G

y=

100

rad

)

Co

nve

rt 2

.2 C

urie

to B

ecq

uere

l. (1

Ci =

3.7

x 1

010 B

q)

Page 11: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

Co

nve

rt 3

20 G

yto

rad

. (1

Gy

= 1

00 r

ad)

An

oth

er

way

to m

eas

ure

rad

iati

on

is b

y th

e b

iolo

gic

al e

ffe

cts

of

dif

fere

nt k

ind

s o

f rad

iati

on

. Th

is is

cal

led

the

rem

(rad

iati

on

equ

ival

ent i

n h

um

ans)

.A

lpha

par

ticle

s ca

n’t

en

ter

the

bo

dy

thro

ugh

the

sk

in, b

ut if

it fi

nd

s an

oth

er

way

(m

out

h, e

yes,

inju

ry, e

tc)

it c

an c

ause

ext

en

sive

dam

age

w

ith

in a

sh

ort

dis

tan

ce in

tiss

ue.

Hig

h e

ne

rgy

rad

iati

on

(b

eta,

hig

h-en

erg

y p

roto

ns, h

igh-

ener

gy

neut

rons

) ca

n tr

ave

l far

the

r an

d b

y d

oin

g s

o c

ause

mo

re d

amag

e

than

alp

ha.

G

amm

a ra

ys a

re d

amag

ing

be

caus

e th

ey tr

ave

l a lo

ng

way

thro

ugh

th

e b

od

y ti

ssue

.

To d

ete

rmin

e th

e e

qu

ival

ent d

ose

or

rem

do

se, t

he

ab

sorb

ed

do

se

(rad

) is

mul

tip

lie

d b

y a

fact

or

that

ad

just

for

bio

log

ical

dam

age

cau

se

by

a p

arti

cula

r fo

rm o

f rad

iati

on

.

Bio

log

ical

dam

age

(rem

) = A

bso

rbed

dos

e (r

ad) x

Fac

tor

Be

ta a

nd

gam

ma

rad

iati

on

, th

e fa

cto

r is

1

Hig

h-e

ne

rgy

pro

ton

s an

d n

eut

ron

s, th

e fa

cto

r is

10

Alp

ha

par

ticl

es,

the

fact

or

is 2

0

A p

atie

nt r

ece

ive

s 34

00m

rad

s o

f I-1

31, w

hic

h e

mit

s b

eta

p

arti

cle

s. If

that

fact

or

that

ad

just

s fo

r b

iolo

gic

al d

amag

e is

1

for

be

ta p

arti

cle

s, h

ow m

any

rem

s d

id th

e p

atie

nt r

ece

ive

?

Page 12: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

Oft

en

the

me

asur

em

en

t fo

r an

eq

uiva

len

t do

se w

ill b

e in

mil

lire

ms

(mre

m).

1 re

m =

100

0 m

rem

Th

e S

I un

it is

the

Sie

vert

(Sv)

. 1

Sv=

100

re

m

Foo

db

orn

e il

lne

sse

s ca

use

d b

y p

ath

og

en

ic b

acte

ria

such

as

Salm

onel

la, L

iste

ria,

and

E. C

olih

ave

be

com

e m

ajo

r h

eal

th c

on

cern

s in

the

Un

ite

d S

tate

s.

Th

e U

.S. F

oo

d a

nd

Dru

g A

dm

inis

trat

ion

(FD

A)

has

ap

pro

ved

the

do

se

of 0

.3 k

Gy

to 1

kG

yo

f rad

iati

on

pro

duc

ed

by

cob

alt-

60 o

r ce

sium

-137

fo

r tr

eat

me

nt o

f fo

od

s.

Wh

en

foo

d p

asse

s th

roug

h a

se

rie

s o

f rac

ks,

gam

ma

rays

pas

s th

roug

h th

e fo

od

an

d k

ill t

he

bac

teri

a w

ith

out

har

min

g th

e fo

od

.

Cur

ren

tly

tom

ato

es,

blu

ebe

rrie

s,

stra

wb

err

ies,

an

d m

ush

roo

ms

are

b

ein

g ir

rad

iate

d to

all

ow th

em

to b

e

har

vest

ed

wh

en

they

are

co

mp

lete

ly

rip

e to

ext

en

d th

eir

sh

elf

life

.

Th

e F

DA

re

qui

res

the

sym

bo

l (a)

to

app

ear

on

irra

dia

ted

foo

ds.

Aft

er

two

w

ee

ks,

the

irra

dia

ted

str

awb

err

ies

on

th

e r

igh

t sh

ow n

o d

amag

e. W

hil

e

tho

se n

ot i

rrad

iate

d g

row

mo

ld.

No

te th

at th

e fo

od

nev

er

com

es

into

co

nta

ct w

ith

the

rad

ioac

tive

iso

top

es

itse

lf. O

nly

the

gam

ma

rays

. So

the

fo

od

do

esn

’t b

eco

me

rad

ioac

tive

.

Peo

ple

wh

o w

ork

in r

adia

tio

n la

bo

rato

rie

s w

ear

d

osi

me

ters

att

ach

ed

to th

eir

clo

thin

g.

Do

sim

ete

rs d

ete

ct th

e a

mo

unt o

f rad

iati

on

ex

po

sure

fro

m th

e fo

llow

ing

:X

-ray

sG

amm

a ra

ysB

eta

par

ticl

es

It is

an

ad

de

d le

vel o

f se

curi

ty to

mak

e a

bso

lute

su

re th

at th

ey a

re s

afe.

Page 13: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

Ave

rag

e a

nnu

al r

adia

tio

n r

ece

ive

d b

y a

pe

rso

n in

the

Un

ite

d S

tate

s:

Th

e a

vera

ge

pe

rso

n in

the

Un

ite

d S

tate

s is

exp

ose

d to

360

mre

m o

f rad

iati

on

an

nual

ly. E

xpo

sure

to r

adia

tio

n o

ccur

s ev

ery

day

fro

m n

atur

ally

occ

urri

ng

ra

dio

iso

top

es

in

Bui

ldin

gs

wh

ere

we

live

an

d w

ork

Foo

d a

nd

wat

er

Th

e a

ir w

e b

reat

he

Post

assi

um-4

0 in

all

po

tass

ium

-co

nta

inin

g fo

od

s (b

anan

as!)

Co

smic

rad

iati

on

fro

m th

e s

un

Th

e la

rge

r th

e d

ose

of r

adia

tio

n r

ece

ive

d

at o

ne

tim

e, th

e g

reat

er

the

eff

ect

on

the

b

od

y.

Exp

osu

re to

rad

iati

on

of 5

00 r

em

is

exp

ect

ed

to c

ause

de

ath

in 5

0% o

f th

e

pe

op

le r

ece

ivin

g th

e d

ose

. (ca

lle

d th

e

leth

al d

ose

for

one-

half

the

pop

ulat

ion,

or

LD50

.)

Mat

ch e

ach

pro

pe

rty

(1-3

) w

ith

its

unit

of m

eas

ure

me

nt (

A-D

).

1. a

ctiv

ity

A. m

rad

2. a

bso

rbe

d d

ose

B. m

rem

3. b

iolo

gic

al d

ose

C. b

ecq

uere

l

D. S

v

Page 14: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

5.1

–N

atur

al R

adio

acti

vity

5.2

–N

ucle

ar R

eac

tio

ns

5.3

–R

adia

tio

n M

eas

ure

me

nt

5.4

–H

alf-

Life

of a

Rad

iois

oto

pe

5.5

–M

ed

ical

Ap

pli

cati

on

s us

ing

Rad

ioac

tivi

ty

5.6

–N

ucle

ar F

issi

on

an

d F

usio

nG

oal

: Giv

en

the

hal

f-li

fe o

f a r

adio

iso

top

e, c

alcu

late

the

am

oun

t o

f rad

iois

oto

pe

re

mai

nin

g a

fte

r o

ne

or

mo

re h

alf-

live

s.

Th

e h

alf l

ife

is th

e a

mo

unt o

f tim

e it

take

s h

alf o

f a r

adio

activ

e

sam

ple

to d

eca

y.

For

exam

ple

, I,has a

hal

f-li

fe o

f 8.0

day

s. A

s

Idecays

, it

pro

duc

es

the

no

n-r

adio

activ

e is

oto

pe

, Xeand

a b

eta

par

ticl

e.

IXe+

e

IXe+

eSu

pp

ose

we

hav

e a

sam

ple

that

init

ially

co

nta

ins

20. m

g o

f I.

In 8

.0 d

ays,

on

e-h

alf (

10 m

g)

of a

ll th

e

Inuclei i

n th

e s

amp

le w

ill h

ave

de

caye

d,

wh

ich

leav

es

10 m

g o

f I-1

31 le

ft.

You

now

hav

e 1

0mg

an

d a

fte

r an

oth

er

hal

f lif

e o

f 8 d

ays,

5 m

g w

ill h

ave

de

caye

d

and

yo

u w

ill h

ave

5 m

g le

ft…

etc

Page 15: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

A d

ecay

cu

rve

is a

d

iag

ram

of t

he

de

cay

of a

ra

dio

acti

ve is

oto

pe.

Th

e d

eca

y cu

rve

for

I-13

1 sh

ows

that

on

e-h

alf t

he

sa

mp

le d

eca

ys e

very

8

day

s.

Th

e r

adio

iso

top

e s

tro

nti

um-9

0 h

as a

hal

f-li

fe o

f 38.

1 ye

ars.

If a

sam

ple

co

nta

ins

36 m

g o

f Sr-

90, h

ow m

any

mil

lig

ram

s w

ill r

em

ain

aft

er

152.

4 ye

ars.

Ge

olo

gis

t, ar

chae

olo

gis

ts, a

nd

his

tori

ans

use

kn

owle

dg

e o

f ra

dio

acti

ve is

oto

pe

s to

est

imat

e th

e a

ge

of a

nci

en

t ob

ject

s.

Th

e a

ge

of a

n o

bje

ct d

eri

ved

fro

m p

lan

ts o

r an

imal

s (s

uch

as

wo

od

, fib

er,

bo

ne,

wo

ol c

loth

ing

, etc

.) is

de

term

ine

d b

y m

eas

urin

g th

e a

mo

unt o

f car

bo

n-1

4 in

the

sam

ple

.C

arb

on

-14

is a

nat

ural

ly o

ccur

rin

g is

oto

pe

wh

ich

is

pro

duc

ed

in n

atur

e in

the

up

pe

r at

mo

sph

ere

.Li

vin

g p

lan

ts c

on

tinu

ous

ly a

bso

rb c

arb

on

-14

thro

ugh

re

spir

atio

n. O

nce

the

pla

nt d

ies,

it b

eg

ins

to lo

se th

e

carb

on

-14

as it

de

cays

. (ca

rbo

n-1

4s h

alf-

life

is 5

730

year

s.)

In c

arb

on

-dat

ing

, sci

en

tist

s us

e th

e le

vel o

f car

bo

n-1

4 in

an

ob

ject

to e

stim

ate

how

lon

g it

had

be

en

de

cayi

ng

an

d

gue

ss w

he

n it

die

d.

(Liv

ing

thin

gs

reac

h a

n a

mo

unt o

f car

bo

n-1

4 th

at s

tays

fa

irly

co

nst

ant d

urin

g li

fe.)

Car

bo

n d

atin

g w

as u

sed

to

de

term

ine

that

the

De

ad S

ea

Scro

lls

are

ab

out

200

0 ye

ars

old

.

Page 16: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

A r

adio

log

ical

dat

ing

me

tho

d u

sed

be

ge

olo

gis

ts u

ses

the

sam

e

tech

niq

ue a

s ca

rbo

n d

atin

g, b

ut w

ith

ura

niu

m-2

38.

Ura

niu

m-2

38 h

as a

hal

f lif

e o

f 4.5

bil

lio

n y

ear

s an

d it

de

cays

to le

ad-

206.

By

me

asur

ing

the

U-2

38 a

nd

Pb

-206

am

oun

ts in

a r

ock

, th

e a

ge

can

b

e e

stim

ate

d. O

ver

tim

e th

e a

mo

unt o

f U-2

38 d

ecr

eas

es

and

Pb

-206

in

cre

ase

s.

Th

is m

eth

od

was

use

d to

dat

e m

oo

n r

ock

s re

turn

ed

by

the

Ap

ollo

mis

sio

ns.

Th

ey w

ere

foun

d to

be

ab

out

4 b

illi

on

ye

ars

old

, ap

pro

xim

ate

ly th

e s

ame

ag

e o

f th

e E

arth

.

Car

bo

n-1

4 w

as u

sed

to d

ete

rmin

e th

e a

ge

of t

he

De

ad

Sea

Scro

lls.

If th

e D

ead

Se

a Sc

roll

s w

ere

de

term

ine

d to

b

e 2

000

year

s o

ld a

nd

the

hal

f-li

fe o

f car

bo

n-1

4 is

573

0 ye

ars,

wh

at fr

acti

on

of t

his

hal

f-li

fe h

as p

asse

d?

Th

e h

alf-

life

of I

-123

is 1

3 h

our

s. H

ow m

uch

of a

64

mg

sam

ple

of I

-123

is le

ft a

fte

r 26

ho

urs?

5.1

–N

atur

al R

adio

acti

vity

5.2

–N

ucle

ar R

eac

tio

ns

5.3

–R

adia

tio

n M

eas

ure

me

nt

5.4

–H

alf-

Life

of a

Rad

iois

oto

pe

5.5

–M

ed

ical

Ap

pli

cati

on

s us

ing

Rad

ioac

tivi

ty

5.6

–N

ucle

ar F

issi

on

an

d F

usio

n

Page 17: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

Go

al: D

esc

rib

e th

e u

se o

f rad

iois

oto

pe

s in

me

dic

ine.

Rad

iois

oto

pe

s w

ith

sh

ort

hal

f-liv

es

are

use

d in

nuc

lear

m

ed

icin

e b

eca

use

:T

he

ce

lls

in th

e b

od

y d

o n

ot d

iffe

ren

tiat

e b

etw

ee

n n

on

-rad

ioac

tive

at

om

s an

d r

adio

activ

e a

tom

s (t

hey

tre

at th

e r

adio

iso

top

es

as th

ey

wo

uld

the

re

gul

ar is

oto

pe

)O

nce

inco

rpo

rate

d in

to c

ell

s, th

e r

adio

activ

e a

tom

s ar

e d

ete

cte

d

be

caus

e th

ey e

mit

rad

iati

on

, giv

ing

an

imag

e o

f an

org

an.

Aft

er

a ra

dio

iso

top

e is

ing

est

ed

by

the

pat

ien

t, th

e b

od

y w

ill d

ire

ct th

e is

oto

pe

just

as

if it

was

the

typ

ical

no

n-

rad

ioac

tive

form

.

A s

can

ne

r is

the

n p

asse

d o

ver

the

bo

dy

abov

e th

e r

eg

ion

w

he

re th

e o

rgan

co

nta

inin

g th

e r

adio

iso

top

e is

loca

ted

.

Th

e s

can

ne

r d

ete

cts

the

gam

ma

rad

iati

on

giv

en

off

an

d

cre

ate

s an

imag

e b

ase

d o

n h

ow m

uch

rad

iati

on

is d

ete

cte

d

acro

ss th

e o

rgan

. A

n a

rea

of l

owe

r o

r h

igh

er

rad

iati

on

can

ind

icat

e c

on

dit

ion

s su

ch a

s a

dis

eas

e o

f th

e o

rgan

, a tu

mo

r, a

blo

od

clo

t, o

r e

de

ma.

Page 18: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

To d

ete

rmin

e th

yro

id fu

nct

ion

, do

cto

rs u

se r

adio

activ

e io

din

e up

take

.

Take

n o

rally

, rad

ioac

tive

I-1

31 m

ixe

s w

ith

the

iod

ine

al

read

y in

the

thyr

oid

.

24 h

our

s la

ter,

the

am

oun

t of i

od

ine

take

n u

p b

y th

e

thyr

oid

is d

ete

rmin

ed

wit

h a

sca

nn

er.

A p

ers

on

wit

h h

ype

rthy

roid

ism

wil

l hav

e a

hig

he

r th

an

no

rmal

leve

l of r

adio

activ

e io

din

e. A

pe

rso

n w

ith

hy

po

thyr

oid

ism

wil

l hav

e a

low

er

than

no

rmal

leve

l.

On

e tr

eat

me

nt f

or

hyp

ert

hyro

idis

m is

to g

ive

a

“th

era

pe

utic

do

se”

of I

-131

(a

hig

he

r d

ose

than

for

the

sc

an).

Th

e r

adio

acti

ve io

din

e w

ill d

est

roy

som

e o

f th

e

cell

s in

the

thyr

oid

, low

eri

ng

the

am

oun

t of t

hyro

id

ho

rmo

ne

pro

duc

ed

.

Posi

tro

n e

mit

ters

wit

h s

ho

rt h

alf-

live

s:C

an b

e u

sed

to s

tud

y b

rain

fun

ctio

n, m

eta

bo

lism

, an

d b

loo

d fl

ow.

Mig

ht b

e c

arb

on

-11,

oxy

ge

n-1

5, n

itro

ge

n-1

3 o

r fl

uori

ne

-18.

Co

mb

ine

wit

h e

lect

ron

s af

ter

em

issi

on

to p

rod

uce

gam

ma

rays

, w

hic

h a

re th

en

de

tect

ed

by

com

put

ers

, cre

atin

g a

3-D

imag

e o

f th

e o

rgan

.

Th

ese

PE

T s

can

s o

f th

e b

rain

sh

ow a

no

rmal

bra

in o

n th

e le

ft

and

a b

rain

aff

ect

ed

by

Alz

he

ime

r’s

dis

eas

e o

n th

e r

igh

t.

An

imag

ing

me

tho

d u

sed

to s

can

org

ans

such

as

the

bra

in, l

ung

s, a

nd

he

art.

A c

om

put

er

mo

nit

ors

the

ab

sorp

tio

n o

f 30,

000

X-r

ay b

eam

s d

ire

cte

d a

t th

e o

rgan

in s

ucce

ssiv

e

laye

rs.

Dif

fere

nce

s in

ab

sorp

tio

n b

ase

d o

n ti

ssue

d

en

siti

es

and

flui

ds

pro

vid

e a

n im

age

of t

he

o

rgan

.

Th

e p

atie

nt d

oe

s n

ot i

ng

est

rad

ioac

tive

mat

eri

al.

Rat

he

r, ra

dio

activ

e m

ate

rial

was

use

d to

cre

ate

th

e X

-ray

s.

An

oth

er

nam

e fo

r th

is is

Co

mp

ute

rize

d A

xial

To

mo

gra

phy

(C

AT

sca

n)

CT

sca

n o

f a b

rain

sh

ows

a tu

mo

r (y

ell

ow).

Page 19: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

An

MR

I is

a p

owe

rful

imag

ing

tech

niq

ue th

at is

the

le

ast i

nvas

ive

imag

ing

me

tho

d a

vail

able

.

MR

I is

bas

ed

on

the

ab

sorp

tio

n o

f en

erg

y w

he

n

pro

ton

s in

hyd

rog

en

ato

ms

are

exc

ite

d th

en

re

laxe

d b

y ra

dio

wav

es.

Wh

en

pla

ced

wit

hin

a m

agn

eti

c fi

eld

, th

e p

roto

ns

pre

vio

usly

ran

do

m o

rie

nta

tio

ns,

ali

gn

wit

h th

e fi

eld

.W

hil

e in

the

mag

ne

tic

fie

ld, r

adio

wav

es

are

pul

sed

at

dif

fere

nt f

req

uen

cie

s (w

ave

len

gth

s).

Pro

ton

s in

dif

fere

nt c

he

mic

al e

nvir

on

me

nts

re

son

ate

at

dif

fere

nt f

req

uen

cie

s (j

ump

to a

hig

he

r e

ne

rgy

stat

e)

and

the

n r

ela

x b

ack

to it

s o

rig

inal

wh

en

the

rad

io

wav

es

are

turn

ed

off

.E

ne

rgy

is r

ele

ase

d, c

orr

esp

on

din

g to

par

ticu

lar

colo

rs.

MR

Is a

re tu

ne

d to

hyd

rog

en

nuc

lei

be

caus

e th

ere

is s

uch

a la

rge

ab

und

ance

of h

ydro

ge

n in

the

bo

dy

(mo

stly

in w

ate

r).

MR

Is a

re p

arti

cula

rly

use

ful f

or

soft

b

od

y ti

ssue

wh

ich

co

nta

ins

larg

e

amo

unts

of w

ate

r.

Out

sid

e o

f th

e m

ed

ical

fie

ld, t

his

te

chn

ique

is c

alle

d N

ucle

ar M

agn

eti

c R

eso

nan

ce (

NM

R)

and

is u

sed

ex

ten

sive

ly in

ch

em

istr

y la

bs.

MR

I of h

ear

t an

d lu

ng

s.

Wh

ich

of t

he

foll

owin

g r

adio

iso

top

es

are

mo

st li

kely

to b

e

use

d in

nuc

lear

me

dic

ine

?

A. 40

Kh

alf-

life

1.3

x 1

09ye

ars

B. 42

K

hal

f-li

fe 1

2 h

our

s

C. 13

1 Ih

alf-

life

8 d

ays

Th

e p

roce

ss o

f bra

chyt

her

apy,

or

see

d im

pla

nta

tio

n, i

s an

in

tern

al fo

rm o

f rad

iati

on

the

rap

y fo

r ca

nce

r.

Th

e b

en

efi

t of b

rach

yth

era

py

ove

r tr

adit

ion

al e

xte

rnal

ca

nce

r tr

eat

me

nts

is th

at th

e r

adia

tio

n is

lim

ite

d to

a v

ery

sp

eci

fic

are

a (t

he

dir

ect

loca

tio

n o

f th

e tu

mo

r), w

he

re a

s tr

adit

ion

al tr

eat

me

nts

oft

en

eff

ect

an

en

tire

org

an.

Bra

chyt

he

rap

y is

als

o q

uick

er

than

trad

itio

nal

me

tho

ds.

B

eca

use

the

targ

et a

rea

is o

nly

the

can

cer,

larg

er

do

ses

can

b

e a

dm

inis

tere

d a

t a ti

me,

less

en

ing

how

man

y tr

eat

me

nts

ar

e r

eq

uire

d.

Page 20: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

Per

man

ent b

rach

yth

erap

y is

a tr

eat

me

nt

op

tio

n fo

r p

rost

ate

can

cer.

Invo

lve

s im

pla

nti

ng

40+

tita

niu

m c

apsu

les

call

ed

se

ed

s in

the

can

cero

us a

rea.

Insi

de

the

tita

niu

m c

apsu

les

are

rad

ioac

tive

is

oto

pe

sI-

125,

Pd

-103

, or

Cs-

131

Th

e is

oto

pe

s d

eca

y b

y g

amm

a e

mis

sio

n w

hic

h

kil

ls th

e c

ance

r ce

lls’

ab

ilit

y to

re

pro

duc

e.If

the

rig

ht d

osa

ge

is u

sed

, th

e is

oto

pe

s w

ill e

mit

al

l its

rad

iati

on

into

the

can

cer

the

n s

top

be

fore

d

amag

ing

a la

rge

am

oun

t of b

od

y ti

ssue

.

Th

e “

see

ds”

are

inse

rte

d o

nce

an

d le

ft in

sid

e th

e b

od

y. (

On

ce

all t

he

rad

ioac

tive

de

cay

has

o

ccur

red

, th

e s

ee

ds

are

h

arm

less

.)

Tem

por

ary

bra

chyt

her

apy

is a

lso

a tr

eat

me

nt f

or

pro

stat

e

can

cer.

Lon

g n

ee

dle

s ar

e im

pla

nte

d in

to th

e tu

mo

r co

nta

inin

g Ir

-19

2.C

an b

e u

sed

to d

eliv

er

a h

igh

er

do

se o

f rad

iati

on

ove

r a

sho

rte

r ti

me

co

mp

are

d to

pe

rme

nan

tan

d m

ay b

e r

ep

eat

ed

in

a fe

w d

ays.

Th

e n

ee

dle

s ar

e r

em

ove

d a

fte

r 5-

10 m

inut

es.

Bra

chyt

he

rap

y is

als

o u

sed

foll

owin

g b

reas

t can

cer

lum

pe

cto

my

(tum

or

rem

oval

).

An

Ir-1

92 is

oto

pe

is in

sert

ed

into

a c

ath

ete

r im

pla

nte

d in

th

e s

pac

e le

ft b

y th

e r

em

oval

of t

he

tum

or.

Th

e is

oto

pe

is r

em

ove

d a

fte

r 5-

10 m

inut

es.

Th

e g

oal

is to

kil

l any

re

mai

nin

g c

ance

r ce

lls.

Th

e tr

eat

me

nt i

s re

pe

ate

d tw

ice

a d

ay fo

r 5

day

s. T

he

n th

e

cath

ete

r is

re

mov

ed

an

d n

o r

adio

acti

ve m

ate

rial

re

mai

ns

in

the

bo

dy.

5.1

–N

atur

al R

adio

acti

vity

5.2

–N

ucle

ar R

eac

tio

ns

5.3

–R

adia

tio

n M

eas

ure

me

nt

5.4

–H

alf-

Life

of a

Rad

iois

oto

pe

5.5

–M

ed

ical

Ap

pli

cati

on

s us

ing

Rad

ioac

tivi

ty

5.6

–N

ucle

ar F

issi

on

an

d F

usio

n

Page 21: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

Go

al: D

esc

rib

e th

e p

roce

sse

s o

f nuc

lear

fiss

ion

an

d fu

sio

n.

Dur

ing

the

193

0s, s

cie

nti

sts

bo

mb

ard

ed

ura

niu

m-2

35 w

ith

n

eut

ron

s an

d d

isco

vere

d th

at th

e U

-23

5 nu

cle

us s

pli

ts in

to tw

o s

mal

ler

nucl

ei a

nd

pro

duc

es

a g

reat

amo

unt

of e

ne

rgy.

Nu

clea

r fi

ssio

n: s

pli

ttin

g a

n

ato

m in

to 2

+ p

arts

Ato

mic

en

erg

y: th

e e

ne

rgy

ge

ne

rate

d b

y fi

ssio

n.

n+U→

U→Kr+

Ba+ 3n+ en

erg

y

Od

dly

en

oug

h, i

f yo

u w

ere

ab

le to

we

igh

sta

rtin

g

mat

eri

als

(ne

utro

n a

nd

U-2

35)

and

the

n th

e p

rod

ucts

(K

r-91

, Ba-

142,

an

d 3

ne

utro

ns)

yo

u’d

fin

d th

ey d

idn

’t w

eig

h th

e s

ame.

Th

at is

be

caus

e s

om

e o

f th

e ‘m

ass’

was

co

nve

rte

d to

an

e

no

rmo

us a

mo

unt o

f en

erg

y.

E =

mc2

Ein

ste

in’s

fam

ous

eq

uati

on

. En

erg

y re

leas

ed

(E

), m

ass

lost

(m

), s

pe

ed

of l

igh

t (c)

= 3

x 1

08 m

/s.

Eve

n th

oug

h th

e m

ass

lost

is v

ery

ve

rysm

all,

wh

en

yo

u m

ulti

ply

that

by

the

sp

ee

d o

f lig

ht s

qua

red

, it b

eco

me

s a

hug

e a

mo

unt o

f en

erg

y.

Fiss

ion

be

gin

s w

he

n a

hig

h-e

ne

rgy

ne

utro

n c

oll

ide

s w

ith

a h

eav

y ra

dio

acti

ve

ato

m (

U-2

35 fo

r ex

amp

le).

T

he

ne

utro

n b

eco

me

s p

art o

f th

e a

tom

, h

owev

er

the

new

nuc

leus

is u

nst

able

an

d

spli

ts in

to s

mal

ler

nucl

ei.

Th

is a

lso

re

leas

es

seve

ral n

eut

ron

s th

at c

an

the

n c

oll

ide

wit

h o

the

r ra

dio

acti

ve a

tom

s an

d r

ep

eat

the

pro

cess

, cau

sin

g a

ch

ain

re

acti

on.

An

en

orm

ous

am

oun

t of e

ne

rgy

is r

ele

ase

d

as w

ell

.

Page 22: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

To s

usta

in a

ch

ain

re

acti

on

, w

ith

out

ad

din

g a

ny

add

itio

nal

U-2

35 o

r n

eut

ron

s, th

e o

rig

inal

am

oun

t of U

-235

mus

t eq

ual

a cr

itica

l mas

s.

So m

uch

he

at a

nd

en

erg

y b

uild

up

that

an

ato

mic

ex

plo

sio

n c

an o

ccur

.

Hir

osh

ima,

Jap

anA

ugus

t 6, 1

945

Nag

asak

i, Ja

pan

Aug

ust 9

, 194

5

Dur

ing

WW

II, a

fte

r G

erm

any’

s d

efe

at, J

apan

re

fuse

d to

su

rre

nd

er.

It w

as c

lear

that

Ja

pan

wo

uld

no

t win

in th

e

lon

g r

un, w

hic

h a

pp

ear

ed

to

mak

e Ja

pan

eve

n m

ore

d

ead

ly. J

apan

ese

forc

es

infl

icte

d th

e s

ame

am

oun

t of

All

ied

forc

e c

asua

ltie

s in

3

mo

nth

s, a

s th

e fu

ll w

ar in

the

p

revi

ous

1.5

ye

ars.

Hir

osh

ima,

Jap

anA

ugus

t 6, 1

945

Nag

asak

i, Ja

pan

Aug

ust 9

, 194

5

Pre

sid

en

t Tru

man

’s w

ar c

oun

sel b

roug

ht h

im 2

o

pti

on

s.

1. T

o c

on

tinu

e c

urre

nt t

acti

cs o

f co

nve

nti

on

al

bo

mb

ing

foll

owe

d w

ith

a m

assi

ve in

vasi

on

. Tru

man

w

as a

dvi

sed

that

suc

h a

n in

vasi

on

wo

uld

re

sult

in

U.S

. cas

ualt

ies

of u

p to

mil

lio

n.

2. U

se th

e a

tom

ic b

om

b in

ho

pe

of b

rin

gin

g th

e w

ar

to a

qui

ck e

nd

.

Th

is w

as a

he

artb

reak

ing

an

d d

iffi

cult

de

cisi

on

to

mak

e. P

resi

de

nt T

rum

an c

ho

se to

use

an

ato

mic

b

om

b r

eg

ard

less

of t

he

mo

ral r

ese

rvat

ion

s m

any

in

his

war

co

unci

l vo

ice

d a

s w

ell

as

scie

nti

sts

wh

o

dev

elo

pe

d it

.

Th

e fi

rst a

tom

ic b

om

b, n

ame

d L

ittle

Boy

use

d

Ura

niu

m-2

35. I

t we

igh

ed

900

0 p

oun

ds.

It d

eto

nat

ed

200

0 fe

et a

bov

e H

iro

shim

a an

d

leve

led

5 s

qua

re m

ile

s o

f th

e c

ity.

Th

e b

last

was

the

eq

uiva

len

t of 1

2-15

,000

to

ns

of T

NT.

Page 23: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

To A

me

rica

’s d

ism

ay, J

apan

ese

e

mp

ero

r, H

iro

hit

o, r

efu

sed

to

surr

en

de

r. H

e d

idn

’t b

eli

eve

th

e U

.S. c

oul

d p

oss

ibly

hav

e a

se

con

d b

om

b.

Pre

sid

en

t Tru

man

mad

e th

e

de

cisi

on

that

a s

eco

nd

bo

mb

w

as n

ece

ssar

y.

Th

e s

eco

nd

bo

mb

, nam

ed

Fat

Man

was

big

ge

r th

an th

e

firs

t.

It c

on

tain

ed

plu

ton

ium

(th

ere

was

no

t en

oug

h u

ran

ium

le

ft to

mak

e a

2n

db

om

b w

ith

).

Th

e b

om

b w

as d

rop

pe

d o

n N

agas

aki a

fte

r th

ick

clo

uds

pre

ven

ted

the

firs

t tar

ge

t, K

ok

ura,

fro

m b

ein

g a

n o

pti

on

.

Alt

ho

ugh

the

bo

mb

was

big

ge

r th

an th

e fi

rst,

Nag

asak

i w

as n

est

led

in n

arro

w v

alle

ys b

etw

ee

n m

oun

tain

s th

at

red

uce

d th

e b

last

rad

ius

to 2

.6 s

qua

re m

ile

s.

6 d

ays

late

r, o

n A

ugus

t 15,

194

5,

Em

pe

ror

Hir

oh

ito

an

no

unce

d Ja

pan

’s

surr

en

de

r in

a r

adio

bro

adca

st.

En

din

g W

WII

.

In o

rde

r to

re

ach

the

cri

tical

mas

s th

at e

nab

led

the

b

om

bs

to e

xplo

de,

the

ura

niu

m/p

luto

niu

m

mo

lecu

les

had

to b

e in

cred

ibly

clo

se to

ge

the

r.

In o

rde

r to

ach

ieve

this

, dyn

amit

e e

nci

rcle

d th

e

uran

ium

/plu

ton

ium

an

d w

as d

eto

nat

ed

.

Th

is c

ann

ot b

e a

chie

ved

in th

e s

ett

ing

of a

nuc

lear

re

acto

r.

Page 24: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

In a

nuc

lear

pow

erp

lan

t, a

he

avy

ele

me

nt u

nd

erg

oe

s fi

ssio

n a

nd

the

en

erg

y g

en

era

ted

fro

m th

e r

eac

tio

n is

co

nve

rte

d to

ele

ctri

city

.U

ran

ium

-235

an

d p

luto

niu

m-2

39 a

re c

om

mo

n

Th

e a

mo

unt o

f en

erg

y h

arn

ess

ed

fro

m 1

gra

m o

f U-2

35 is

th

e e

qui

vale

nt o

f bur

nin

g 6

000

po

und

s o

f co

al.

Wit

hin

the

re

acto

r, th

ere

is a

sm

all b

ox (

14”

tall

, 20”

wid

e)

wh

ere

the

fiss

ion

take

s p

lace

.

Con

trol

rod

sca

n b

e in

sert

ed

into

the

box

or

rem

ove

d a

s n

ee

de

d.

U-2

35 (

or

wh

atev

er)

is a

dd

ed

in T

INY

am

oun

ts to

the

ch

amb

er

alo

ng

wit

h h

igh

-e

ne

rgy

ne

utro

ns.

Th

e e

ne

rgy

due

to fi

ssio

n is

in

the

form

of h

eat

.

n+U→

U→Kr+

Ba+ 3n+ en

erg

y

A s

yste

m

tran

sfe

rs th

e h

eat

o

ut o

f th

e r

eac

tor

into

a w

ate

r ta

nk

w

he

re it

he

ats

the

w

ate

r.

Th

e s

team

co

min

g o

ff th

e

wat

er

is fe

d

thro

ugh

a tu

rbin

e

wh

ich

ge

ne

rate

s e

lect

rici

ty a

nd

it

turn

s.

Nuc

lear

re

acto

rs r

eq

uire

sm

all

amo

unts

of f

uel t

o b

e a

dd

ed

ho

urly

b

y re

acto

r o

pe

rato

rs.

A r

eac

tor

nev

er

has

en

oug

h fu

el i

n it

to

re

ach

cri

tical

mas

san

d b

eco

me

ex

plo

sive

. In

fact

the

fue

l in

re

acto

rs

are

dif

fere

nt t

he

n th

ose

in b

om

bs,

an

d th

e te

chn

olo

gy

to a

chie

ve

“bo

mb

gra

de

mat

eri

al”

is h

igh

ly

clas

sifi

ed

. Ve

ry fe

w c

oun

trie

s in

the

w

orl

d h

ave

fig

ure

d it

out

.R

eac

tors

are

als

o b

uilt

wit

h g

ian

t co

ncr

ete

do

me

s w

ith

a th

ick

ne

ss

that

blo

cks

rad

iati

on

, sh

oul

d th

e

wo

rst e

ver

hap

pe

n.

Page 25: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

Th

e “

wo

rst t

hat

co

uld

hap

pe

n”

is c

alle

d a

“r

eac

tor

me

ltd

own

.”

Gia

nt c

oo

lin

g ta

nk

s su

rro

und

the

re

acto

r an

d

mo

de

rate

it’s

tem

pe

ratu

re.

Pip

es

run

fro

m th

e c

oo

lin

g ta

nks,

thro

ugh

th

e r

eac

tor

box

, an

d b

ack

into

the

tan

ks.

If th

e r

eac

tor

is a

t a p

owe

r p

lan

t, th

e p

ipe

s w

ill

run

thro

ugh

wat

er

tan

ks

be

fore

re

turn

ing

to th

e

coo

lin

g ta

nk

s.T

he

se p

ipe

s ab

sorb

he

at fr

om

the

re

acto

r, co

oli

ng

the

re

acto

r.90

,000

gal

lon

s o

f liq

uid

so

diu

m p

asse

s th

roug

h

the

re

acto

r b

ox P

ER

MIN

UT

E. A

s th

e s

od

ium

e

nte

rs th

e b

ox, i

t is

700°

F an

d a

s it

leav

es

it is

820

°

F.

A r

eac

tor

me

ltd

own

occ

urs

wh

en

the

co

oli

ng

sys

tem

s fa

il.

Th

is h

app

en

ed

to 3

nuc

lear

pow

er

pla

nts

in M

arch

201

1 w

he

n a

9.0

m

agn

itud

e e

arth

qua

ke s

truc

k o

ff s

ho

re o

f Jap

an.

Th

e e

arth

qua

ke c

ut o

ff th

eir

pow

er

sup

ply

.T

he

15-

me

ter

tsun

ami f

loo

de

d th

e d

iese

l bac

k u

p g

en

era

tors

loca

ted

in th

e

bas

em

en

ts o

f th

e p

lan

ts.

Wit

ho

ut c

oo

lin

g s

yste

ms,

all

thre

e c

ore

s (r

eac

tor

box

es)

me

lte

d w

ith

in 3

d

ays.

Th

e d

ang

er

was

the

re

acto

r b

oxe

s b

ein

g c

rack

ed

fro

m th

e e

arth

qua

ke a

nd

ra

dio

activ

e m

ate

rial

leak

ing

out

an

d in

to g

roun

d w

ate

r.

Nuc

lear

pow

er

pla

nt f

uel i

s n

ot e

xplo

sive

.

Nuc

lear

pow

er

pla

nt f

uel i

s n

ot e

xplo

sive

.

Nuc

lear

pow

er

pla

nt f

uel i

s n

ot e

xplo

sive

.

Th

e th

reat

fro

m th

e fu

el i

s le

akin

g a

nd

en

teri

ng

the

gro

und

.

Th

ere

we

re 2

-3 e

xplo

sio

ns

at th

e F

ukus

him

a re

acto

rs o

ver

the

we

ek

aft

er

the

e

arth

qua

ke. T

hey

we

re d

ue to

op

era

tors

de

spe

rate

ly tr

yin

g to

co

ol t

he

re

acto

r d

own

. Due

to th

e in

san

e h

eat

(50

72°F

), p

ress

ure

was

bui

ldin

g in

all

the

pip

e w

ork

an

d to

avo

id a

wo

rse

dis

aste

r, th

ey le

t th

e p

ipe

s ve

nt.

Th

is r

ele

ase

d h

ydro

ge

n g

as

wh

ich

is fl

amm

able

wh

ich

pro

cee

de

d to

ign

ite.

100,

000

pe

op

le w

ere

eva

cuat

ed

fro

m th

eir

ho

me

s as

a p

reca

utio

n.

Th

ere

hav

e b

ee

n n

o d

eat

hs

or

case

s o

f rad

iati

on

sic

kn

ess

fro

m th

e

acci

de

nt.

Th

e F

ukus

him

a A

ccid

en

t was

a w

ake

up

cal

l to

the

nuc

lear

ind

ustr

y w

orl

d w

ide.

(an

d a

ho

rrif

yin

g e

mb

arra

ssm

en

t to

sci

en

tist

s.)

Th

e r

eac

tors

had

be

en

bui

lt to

wit

hsta

nd

tsun

amis

of 5

.7 m

ete

rs o

r le

ss b

ase

d o

ff a

tsun

ami i

n C

hil

e in

196

0. (

Jap

an w

as 1

5m)

Th

e

reac

tors

we

re a

lso

de

cad

es

out

of d

ate.

Page 26: 5.1 – Natural Radioactivity 5.2 – Nuclear Reactions 5.3 ...ion.chem.usu.edu/~scheiner/LundellChemistry/lectureslides/ch05... · Chapter 5 5.1 – Natural Radioactivity 5.2 –

Foll

owin

g F

ukus

him

a, n

ucle

ar p

owe

r p

lan

ts a

ll o

ver

the

wo

rld

we

re s

hut

dow

n to

co

nd

uct m

ain

ten

ance

.

Nuc

lear

pow

er

pla

nts

are

bui

lt to

wit

hst

and

eve

ry p

oss

ible

dis

aste

r. B

ut m

ain

ten

ance

is

exp

en

sive

an

d c

an s

lip

be

twe

en

the

cra

cks.

Th

e U

.S. g

ove

rnm

en

t has

ve

ry s

tric

t re

gul

atio

ns

abo

ut m

ain

ten

ance

of b

oth

g

ove

rnm

en

t an

d in

dus

try

own

ed

pla

nts

. Tw

ice

a y

ear

, eve

ry r

eac

tor

is s

hut

dow

n a

nd

is

tho

roug

hly

insp

ect

ed

an

d m

ain

ten

ance

do

ne.

(T

his

ge

ne

rally

take

s 4-

8 w

ee

ks

pe

r re

acto

r.)

Man

y re

acto

rs a

re a

lso

bui

lt in

a w

ay th

at e

ven

if th

e p

owe

r fa

ils,

the

co

oli

ng

sys

tem

s co

nti

nue

to fu

nct

ion

we

ll e

no

ugh

to p

reve

nt m

elt

dow

ns.

In fu

sion

, tw

o s

mal

l nuc

lei c

om

bin

e to

form

a la

rge

r nu

cle

us.

Mas

s is

lost

, an

d a

tre

me

nd

ous

am

oun

t of e

ne

rgy

is r

ele

ase

d (

eve

n

mo

re th

an fr

om

fiss

ion

.)

A fu

sio

n r

eac

tio

n r

eq

uire

s 10

0 m

illi

on

°C

to o

verc

om

e th

e r

ep

ulsi

on

of

the

two

nuc

lei a

nd

cau

se th

em

to u

nd

erg

o fu

sio

n.

Fusi

on

re

acti

on

s o

ccur

co

nti

nuo

usly

on

the

Sun

an

d o

the

r st

ars,

p

rovi

din

g u

s w

ith

he

at a

nd

lig

ht.

If w

e c

oul

d a

chie

ve fu

sio

n r

eac

tors

, it w

oul

d b

e e

sse

nti

ally

cle

an e

ne

rgy.

H

owev

er

the

tem

pe

ratu

re to

ach

ieve

is d

aun

tin

g.

Re

sear

ch g

roup

s ar

oun

d th

e w

orl

d a

re a

tte

mp

tin

g to

dev

elo

p th

e te

chn

olo

gy

ne

ed

ed

wit

hin

our

life

tim

e.

5.1

–N

atur

al R

adio

acti

vity

5.2

–N

ucle

ar R

eac

tio

ns

5.3

–R

adia

tio

n M

eas

ure

me

nt

5.4

–H

alf-

Life

of a

Rad

iois

oto

pe

5.5

–M

ed

ical

Ap

pli

cati

on

s us

ing

Rad

ioac

tivi

ty

5.6

–N

ucle

ar F

issi

on

an

d F

usio

n