6 elimination reactions and...
TRANSCRIPT
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Elimination Reactions and Distillation
S343
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Lab Goals
• We want to compare product distributions in elimination reactions
• Does mechanism matter?
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Experimental Flowchart
• Conduct the reactions with a partner• How do we further purify and characterize a liquid sample?– Melting point?– Recrystallize?– TLC?
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Distillation
• Purification• Characterization
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Practical Considerations
• Clamps• Thermometer placement
• Heating• Water in/out• Sealed containers
What’s wrong here?
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Theory:Vapor Pressure and Boiling Point
35o 126o
25 C
507torr
20torr
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Boiling Mixtures
• Ideal liquid• Little interaction between molecules
• Partial pressures add up to total pressure
This is for Pentane/Hexane;Redraw for pentane/octane
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Separation of Pentane and Octane• Starting with 75% octane/ 25% pentane– L1: 75/25 mixture boils at 77oC
– V1: at same temperature, composition is 15%/85%
– L2: liquid condenses on glass as 15/85 mixture
– V2: second vaporization is again enriched: 99% pure pentane
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Separation of Pentane/Hexane35o 126o
25 C
507torr
148torr
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Fractional Distillation
• Separation of pentane and hexane• Theoretical plates
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Simple vs Fractional Distillation
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Azeotropes
• Constant boiling mixtures
• Non‐ideal solution (H‐bonding)
• Problem• Useful: co‐distillation
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Writing an Introduction
• Purposes– Gives background
• State of the field• Importance of work
– Explain where you are going with your writing• Why is your contribution valuable?• What do you plan to contribute?
• My expectations for you– Show that you understand your purpose– Given articles, pull out relevant background
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Pointers
• Before you write your introduction, ask yourself why you are doing what you are doing!
• Clearly present your thesis• To write an effective introduction, write a compelling case with reference to others
• Do others agree with you? • What have others done? Why?