6_weathering.ppt

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    Weathering profile of volcanic tuff in a road cut after five years of exposure to

    weathering processes.

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    Weathering profile of volcanic tuff in a road cut after fifteen years of exposure to

    weathering processes. Note that rills have developed over time where surface runoffhas flowed down the face of the road cut.

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    Weathering profile of volcanic tuff in a road cut after twenty-five years of exposure

    to weathering processes. Note that sharp edges are now rounded and the profileis stained red.

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    Exposed bedrock is subject to both physical and chemical weathering processes.

    Natural joints within the bedrock facilitate weathering by allowing water to penetrateat depth and exposing a greater surface area of the rock to weathering processes.

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    Note how the natural joint pattern facilitates weathering by providing an environment

    conducive to vegetation growth by trapping soil and collecting water.

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    Jointed bedrock of El Capitan Yosemite

    Park, California forms from expansion

    during uplift and unloading of overburden

    rock.

    Note how jointed grainitc bedrock in

    this New Hampshire quarry permits

    ground water to reach great depths.

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    Joints can form during cooling and

    contraction of lava flows such as

    columnar basalts shown in theimage on the left.

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    Physical or mechanical weathering

    includes weathering processes that

    cause rock or sediment to break down

    into smaller pieces without changing

    the chemistry (mineralogy) of the rock.

    The image on the left demonstrates

    how freezing water can exert high

    stresses as it expands, causing theglass jar to break.

    Water trapped in micro-cracks within

    rock can expand during freezing

    cycles and exert tremendous stressesto the crack wall and cause rock to

    break apart.

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    Freeze-thaw cycles in this alpine environment are responsible for the break-up of this

    granitic bedrock by frost wedging. Freeze-thaw cycles are also important in subpolarenvironments where temperature fluctuate around the freezing isotherm (0 C).

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    Spalling due to range or forest fires can cause the physical break-up of rock through

    rapid expansion and contraction of hydrous mineral during heating (>900C) and cooling

    of the rock as the fire passes over a given location.

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    Root penetration, such as that

    exhibited by this small lodgepole

    pine, can exert great pressures

    within joint cracks as the tree grows

    and the roots begin to expand.

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    Chemical weathering of an

    Egyptian obelisk after arriving in

    Central Park, New York.

    An Egyptian obelisk survives

    over 3000 year in the aridity of

    the Sahara Desert.

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    Chemical weathering processes cause changes in the mineralogy of rock. A

    marble tombstone engraved in 1970 is subjected to chemical weathering.

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    Over time the calcium carbonate (CaCO3) will dissolve by solution weathering to

    form calcium (Ca+2)and bicarbonate (HCO3-1) ions causing the 1820 engraving to

    disappear.

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    A granitic tombstone engraved in 1820 is still well-preserved because its

    constituent minerals are more resistant to chemical weathering processes.

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    H d l i ti i l

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    Hydrolysis reactions involve

    hydrogen ions (H+1) derived from

    carbonic or other acids within the

    environment. Hydrolysis reactions

    can convert primary feldspars in

    rock to clay minerals, such askaolinite.

    Eocene oxisol, Ione, CA

    Iron oxide laterite (red) overlies

    kaolinite clay (white). Formed onalluvium derived from eroded Sierra

    Nevada volcanics in a tropical

    climate 38 m.y. ago.

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    Modern soil formed in laterite of

    Eocene Ione Formation

    A Horizon

    B Horizon

    (goethite yellow precipitate

    and hematite red

    precipitate)

    4FeO + 2H2O + O2 2FeOOH

    Goethite

    Dehydration to form Hematite

    2FeOOH Fe2O3+ H2O

    Oxidation Reactions

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    Rills form from solution weathering of limestone. Compare the depth of rilling

    on the subsequent two slides.

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    What factors may account for increasing depth of rilling on the limestone boulders.

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    If environmental factors are held constant what factor will explain greater weathering?

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    Terminal zone of melting glacier.

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    Recessional moraine loop within Chiatovich Valley, CA. How

    could you infer the relative age of glacial moraines from

    weathering properties of surface boulders?

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    Solution weathering of limestone results in hummocky topography (see inset slide).

    Sinkholes form as acidic groundwater dissolves the underlying carbonate rock.

    Roofs of caves can collapse when underlying support is removed by solutionweathering.

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    The karst towers in southern China are the result of long-term solution weathering

    the limestone bedrock by surface and groundwater. The top of the towers provide a

    minimum estimate of downcutting and lowering of the surrounding landscape.

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    The formation of stalactites and

    stalagmites in limestone caves

    demonstrates that dissolution of

    calcium carbonate (calcite) is a

    reversible process.

    Environmental factors such as

    changes in water temperature,

    acidity, changes in pressure can all

    influence the solubility of calciumcarbonate in solution.

    The image was taken from

    Carlsbad Caverns, New Mexico.

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    Minerals weather at different rates. The plagioclase crystals stand in relief

    because they are more resistant to chemical weathering processes than the mafic

    minerals that are oxidized.

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    Monuments and hoodoos form because of differential weathering. A resistant

    cap rock, such as quartzite, protects the underlying weaker rock, in this case,sandtone and shale from weathering and erosion.

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    Classic examples of differential weathering are prevalent throughout the southwestern

    United States. These monuments and mesas are capped with resistant quartzite. The

    weaker sandstone and shale are being eroded by fluvial and mass wasting processes.

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    Frost-wedging and solution weathering of limestone (Claron Formation) have

    worked in tandem to create the spectacular amphitheaters of Bryce National Park,

    Utah.

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    Water and wind worked in concert to form the arches within oxidized Entrada

    sandstone in southern Utah.

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    Spheroidal weathering patterns develop in bedrock that is exposed to weathering

    processes for extended time periods.

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    Strong spheroidal weathering pattern is exhibited in granitic bedtock in the

    Sierra Nevada, California. Core stones are gradually exposed at the

    surface as mafic minerals are oxidized and the more resistant quartz

    grains accumulate as grus near the base of the boulder.

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    Soils can form in residual bedrock.

    Soils can be described as a weathering veneer covering the terrestrial surfaces of

    the earth. Soils are composed of weathered minerals and decomposed organic

    matter. Soil profiles can form in residual bedrock or unconsolidated sediment.

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    Soil forming processes include: 1. accumulation (illuviation), 2. transformation, 3.

    Removal (eluviation), and 4. translocation.

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    (Partially weathered parent material)

    B Horizon

    A Horizon

    C Horizon

    Soil forming in granitic bedrock.

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    A

    Bwk

    Bk

    Formation of caliche soils

    in arid climates. Calcium

    carbonate accumulates in

    the B (Bk) horizon in arid

    climates.

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    Eocene oxisol, Ione, CAModern soil formed in laterite of

    Eocene Ione Formation

    A Horizon

    B Horizon

    (goethite and hematite)

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    Soil Forming Factors (Clorpt)

    1. Climate

    2. Organisms

    3. Relief

    4. Parent material

    5. Time

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    Note that climate plays a major role in the depth of the B horizon (zone of

    accumulation) or illuvial zone.

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    Vegetation can play an important role in soil nutrient replacement and pH.

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    Unweathered parent material (glacial till)

    Soil development versus position on a moraine slope. Compare solum depth at crest

    versus the flank of the moraine

    solum

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    Bedding structure can influence the rate of soil development. Think about how

    water penetration would differ between horizontal and vertical oriented strata.

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    Soil development on a 13,000 year old moraine, Snoqualmie Pass, WA.

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    Soil development on 75,000 and 150,000 year old moraines. As soils age