7 transfer of electrons at a distance
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REDOXTransfer of electron at a distanceWhat is means by transfer of electron at a distance?
Look at this diagram :
G
Reducing agent
Oxidizing agent
e e
+─ Positive terminal
Negative terminal
ElectrolyteU-Tube
The reducing agent undergoes oxidation (loss of electron) The oxidizing agent undergoes reduction (gain of electron)
Galvanometer
When oxidizing agent and reducing agent solutions is separated by an electrolyte in a U-Tube, redox reactions occur by transfer of electron using connecting wire. This electron transfer is call “transfer of electron at a distance”.
Solution that can react as oxidizing agent is the substances that undergoes reduction process
SolutionHalf equation (gain of electron) and changes colour of solution
Acidified potassium manganate(VII), KMnO4
MnO4- + 8H+ + 5e →
Mn2+ + 4H2O(purple to colourless)
Acidified potassium dichromate(VI) , K2Cr2O7
Cr2O72- + 14H+ + 6e →
2Cr3+ + 7H2O (orange to green)
Chlorine, Cl2Cl2 + 2e → 2Cl-
(pale yellow to colourless)
Bromine, Br2 Br2 + 2e → 2Br-
(reddish brown to colourless)
Iodine, I2I2 + 2e → 2I-
(brown to colourless)
Give extra attention to half equation for acidified potassium manganate(VII) solution and acidified potassium dicrhomate(VI)solution.
(fisrt time we see this half equation, must memorize)
Solution that can react as reducing agent is undergoes oxidation process
Solution nameHalf equation
(loss of electron) and changes colour of solution
Iron(II) sulphate, FeSO4
Fe2+ → Fe3+ + 1e(green to brown)
Stanum(II) chloride, SnCl2
Sn2+ → Sn4+ + 2e(both of the ions is colourless)
Potassium chloride, KCl
2Cl- → Cl2 + 2e (colourless to pale yellow)
Potassium bromide, KBr
2Br- → Br2 + 2e (colourless to reddish
brown)
Potassium iodide, KI
2I- → I2 + 2e (colourless to brown)
Remember : i. Electron transfer from reducing agent to
oxidizing agent through connecting wire. ii. Carbon/graphite electrode that is immersed in
reducing agent act as negative terminal.iii. Carbon/graphite electrode that is immersed in
oxidising agent act as positive terminal.iv. The deflection of galvanometer needle shows
the electron flowing/moving.
Few reaction that you must know…Example 1:
Can you predict what will happen?
Tips : determine the solution that react as oxidizing agent an reducing agent first.
Oxidizing agent : acidified potassium manganate(VII) solution.
Reducing agent : iron(II) sulphate solution
If you can identify, the rest will be much easier.
G
iron(II) sulphate solution, FeSO4 0.1 mol dm-3
Acidified potassium manganate(VII) solution, KMnO4 0.1 mol dm-3
e e+─Negative
terminal
Sulphuric acid, H2SO4 0.1 mol dm-3 U-Tube
Galvanometer
Positive terminal
[Look at the list of oxidant and reductant that you have prepared above]
Oxidation process ( reducing agent ) Half equation : Fe2+ → Fe3+ + 1e
- 1 iron(II)ion /Fe2+ loss 1 electron to produce 1 iron(III)ion/Fe3+
- Fe2+ is oxidize to Fe3+
- iron(II)ion react as reducing agent- oxidation number of iron is increase from +2
to +3- the colour of the solution is turn from (light)
green to brown-
What will happen to the electrons that has been released?
- The electron will be released through negative terminal (carbon that is immersed in iron(II)sulphate solution), and flow through connecting wire to positive terminal (carbon that is immersed in acidified potassium manganate (VII)
solution), so, the galvanometer needle will deflect.
- Manganate(VII) ion, MnO4- will gain
electron and undergoes the reduction process.
Reduction process (oxidizing agent)
Half equation: MnO4- + 8H+ + 5e → Mn2+ +4H2O
- 1 Manganate (VII) ion, MnO4- gain 5 electron
produce 1 mangan(II) ion, Mn2+ - Manganate(VII) ion is reduced to mangan(II)
ion- Mangnate (VII) ion act as oxidizing agent- oxidation number for mangan is decreasing
from +7 to +2 - the colour of solution is changes from purple
to colourless Can you write the total ionic equation for this reaction?
MnO4- + 8H+ + 5e → Mn2+ + 4H2O
5Fe2+ → 5Fe3+ + 5e
MnO4- + 8H+ + 5Fe2+ → Mn2+ + 4H2O + 5Fe3+
How this process is made? Maybe this question will be ask in PAPER2 this year (structure/essay)Example 2:
Can you predict what will happen?
G
Bromine water
Potassium iodide solution, KI 0.1 mol dm-3
Sulphuric acid, H2SO4 0.1 mol dm-3
U-tube
Galvanometer
Tips : recognize the solution that react as oxidizing agent and reducing agent first.
Oxidising agent : bromine water
Reducing agent : potassium iodide solution
Negative terminal: The carbon that immersed in potassium iodide solution
Positive terminal: The carbon that immersed in bromine solution/water
After you have recognize it, the others will be easier. Look at the table that you have prepare above,
Oxidation process / (Reducing agent)Half equation : 2I- → I2 + 2e
- 2 iodide ions loss 2 electron to produce 1 molecule of iodine
- Iodide ion is oxidize to iodine- Iodide ion react as reducing agent- Oxidation number for iodine increase from -1 to
0. thus oxidation occur- Colourless solution change to brownish yellow
What will occur to this releasing electron?- This electron will be released through negative
terminal - graphite electrode that is immersed in potassium
iodide solution, and flow through connecting wire to positive terminal
- graphite electrode that is immersed in bromine solution),
- Thus, galvanometer needle will deflect.- bromine will gain electron and reduction process
will occur.
Reduction processHalf equation for reduction : Br2 + 2e → 2Br-
- 1 molecule bromine gains 2 electron to produce 2 bromide ion
- Bromine is reduce to bromide ion.- Bromine react as oxidizing agent- Oxidation number for bromine decreasing from 0
to -1- Brownish-yellow solution change to colourless
Can you write the total ionic equation for this reaction?
Br2 + 2I- 2Br- + I2
example 3: (cont 5.1 & 5.2 :28.7.2008)
Tips : recognize the solution that react as oxidizing agent and reducing agent first.
Oxidizing agent : acidified potassium dicrhomate(VI)
Terminal positive: Carbon electrod that is immersed into acidified potassium dichromate(VI)
G
stanum(II) chloride solution, SnCl2 0.1 mol dm-3
Acidified potassium dichromate solution, K2Cr2O7
Sulphuric acid, H2SO4 0.1 mol dm-3
U-Tube
Galvanometer
Reducing agent : stanum(II) chloride solution
Terminal negative: carbon immersed into stanum(II) chloride solution
Oxidation process (reducing agent) Cont: 5.1Half equation : Sn2+ → Sn4+ + 2e [observation: no changes in colour of solution]
Cl- Cl2 + 2e[observation: The colour changes from colourless to pale yellow]
(depend on the question)
- 1 stanum(II) ion loss 2 electrons to produce 1 stanum(IV) ion
- Stanum(II) ion is oxidize to stanum(IV) ion- Stanum(II) ion react as reducing agent- Oxidation number for stanum is increasing from
+2 to +4
What will occur to this releasing electron?
- This electron will be released through negative terminal
- graphite electrode that is immersed in stanum(II) chloride solution) is negative terminal, and flow through connecting wire to positive terminal
- electrode that is immersed in acidified potassium dichromate(VI) solution is positive terminal,
- Galvanometer needle will deflect.- Dicrhomate(VI)ion will gain electron and
reducing process will occur
Reduction process / (oxidising agent)half equation for reduction:
Cr2O72- + 14H+ + 6e → 2Cr3+ + 7H2O
- 1 dichromate(VI) ion gain 6 electron to produce 2 chromium(III)ion- dichromate(VI) ion is reduced to 2 chromium(III) ion- dichromate(VI) ion react as oxidizing agent.- Oxidation number for chromium decreasing from
+6 to +3- Orange solution turn to green
Can you write the total ionic equation for this reaction?
Can you answer the following question;i. State the electrode that react as positive terminal
Carbon electrode that immersed in acidified K2Cr2O7 solution
ii. State the electrode that react as negative terminalCarbon electrode that immersed in SnCl2 solution
iii. Mark the direction of the flow of current at the wire
iv. Name the substance that undergoes oxidation processstanum(II) Ion
v. Name the substance that undergoes reduction processdichromate(VI) Ion
vi. Name the oxidizing agentAcidified potassium dicrhomate(VI) solution /dikromat(VI)ion
vii. Name the reduction agentstanum(II)chloride solution / stanum(II)ion
viii.State the observation at the end of this reactionColour of solution for acidified potassium dicrhomate(VI)solution change from purple to green
ix. Write the half equation for the both electrodeSn2+ ----> Sn4+ + 2eCr2O7
2- + 14H+ + 6e ---> 2Cr2+ + 7H2O x. Write the total ionic equation for this reaction
3Sn2+ + Cr2O72- + 14H+ ---> 3Sn4+ + 2Cr2+ +
7H2O