7th annual micro & fast gas chromatography symposium · 2018-11-07 · 7th annual micro &...
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7th Annual micro & Fast Gas Chromatography Symposium
7 Year Progress Report
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Ultrafast GC: The Journey to Credibility
Ultrafast gas chromatography has come a long way since the first of these Gulf Coast Conference symposia seven years ago. From invention to patents to applications including an ASTM method, to the roll out to wineries, refineries, petrochemicals, chemicals and upstream to the wellhead, Ultrafast GC has become mainstream. In labs, online and even transportable platforms, the Ultrafast GC platform expansions including 16 meter column modules for up to 32 meters total length and the newest inventions enabling 3 different column types using a single switching valve broadens applications even more. This year the symposium will take a step back to make an assessment of the breadth and depth of applications and the developments making them possible.
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Session Outline
• Introduction – 7 Year Progress Report – John Crandall, Falcon
• Chromperfect: Peak Integration? Of course but Automation, Software and Data Integration Too! – George Schreiner, Chromperfect
• Optimizing Gas Chromatography – Brian Rohrback, Infometrix
• Ultrafast Simulated Distillation in the Refinery Laboratory: The Skeptics become the Believers – Shauna Teclemariam, US Oil Refining Company
• Long column technology, gasoline, pesticides – Derrick Saul, Falcon
• 3 columns, two module applications – Nate Caton
• Low concentrations using GS-T – Matt Holliday, Derrick Saul, Falcon (presenter)
• Discussion - Group
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2010-2018A quantum leap in technique for 60 year old traditional, air bath oven GC technology.
The Journey to Credibility
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Falcon Joins Teledyne Advanced Monitoring Solutions
October 12, 2018
Turning the Page to a New Chapter
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Transitioning from Lewisburg, WV to Englewood, CO
From Country Roads to Rocky MountainsOpacity
CEMS
Industrial Labs
Transportable
Industrial Process
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Wide Range of Applications – Wide range of Locations
• Industrial Process – Tucked in the Pipes• Extractive sampling very near the sample point
• Trace level measurements
• Condensation issues
• Reactivity issues
• Industrial Laboratory• Quick response to process changes
• Endpoint detection
• Process Validation
• Transportable• Fraud detection
• Regulatory compliance
• Short term composition survey campaigns
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Onsite Composition SurveyNovember 28, 2017
• Initial sample line insulation was inadequate• The water vapor was
clearly condensing and could be seen periodically “burping” from the stainless steel connections into the clear Teflon tubing
• Chromatography was consistent with the condensate problem
• Corrective action was taken as shown next
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Onsite InstallationNovember 28, 2017
• Heat tracing was added up to the sample valve• There were still cold
spots causing condensation
• The water “burp” frequency and impact was reduced
• We expect a properly implemented permanent sample system will remove this issue
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Low Level Components of Interest
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Tucked in the Pipes, 30’ UpVapor phase sample with 15% water measuring ppm levels of very polar acids, aldehydes & anhydrides
Modular CALIDUS in Process Enclosure Module
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Batch Reactor Endpoint & Leak Detection… One Door Away
Food Grade Fatty Acid Boiling Range Distribution
Leak Detection: Heat Transfer Media by Heated Headspace Gas Chromatography
Batch Reactor 30’ this way
Quick, Easy Process Validation, Common Sense Automation
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Fatty Acid Boiling Range
• Notes• The high boilers were
easily integrated along with the other components of interest
• Baseline assignments are done automatically
• Color flooded peaks correlate to legacy values
Region of high boilers
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Fits in the RigPipeline Interface Detection
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Interference Free N2 @ 35 Seconds
Cycle time
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The Result: 170 Second Resolution for Determining Flare Start & Stop Timing
Before Online N2 Analysis After Online N2 Analysis
Far less wasted Product 1 & 2 & Nitrogen
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The CALIDUS/PALARUS Solution
HardwareFalcon Analytical:-Dual CALIDUS 101 Micro GC’s
PALARUS (CTC Analytics)-Dual Tower PAL HTX-xt
SoftwareJustice Laboratory Software:-ChromPerfect Seven
Axel-Semerau:-Chronos
Infometrix, Inc:-Line-Up
ChromwareRestek:-MTX micro-packed
Winery Ethanol/Fusel Oil Concentrations
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• Ethanol & Fusel Oils in Distilled SpiritsJose Cuervo, Grey Goose, Johnnie Walker Black, & Crown Royal
Various Distilled SpiritsEthanol & fusel oils
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Serious BusinessEthanol & Fusel Oil
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Session Outline
• Chromperfect: Peak Integration? Of course but Automation, Software and Data Integration Too! – George Schreiner, Chromperfect
• Optimizing Gas Chromatography – Brian Rohrback, Infometrix
• Ultrafast Simulated Distillation in the Refinery Laboratory: The Skeptics become the Believers – Shauna Teclemariam, US Oil Refining Company
• Long column technology, gasoline, pesticides – Derrick Saul, Falcon
• 3 columns, two module applications –Nate Caton
• Low concentrations using GS-T – Matt Holliday, Derrick Saul, Falcon (presenter)
• Discussion - Group