a review of archaean and paleoproterozoic evolution in ouzzal 2003
TRANSCRIPT
Journal of African Earth Sciences 37 (2003) 207–227
www.elsevier.com/locate/jafrearsci
A review of Archaean and Paleoproterozoic evolution of theIn Ouzzal granulitic terrane (Western Hoggar, Algeria)
Khadidja Ouzegane a, Jean-Robert Kienast b,*, Abderrahmane Bendaoud a,Amar Drareni a
a Laboratoire de G�eeodynamique, G�eeologie de l’Ing�eenieur et de Plan�eetologie, Facult�ee des Sciences de la Terre, de G�eeographie et de l’Am�eenagement duTerritoire, U.S.T.H.B., B.P. 32 El Alia, Dar el Beida, Algiers 16111, Algeria
b Laboratoire de G�eeosciences Marines, C.N.R.S.––IPGP, UMR 7097, Universit�ee Paris 7, 4 place Jussieu, Tour 26, 3�eeme �eetage,Paris Cedex 05 75252, France
Received 20 September 2002; accepted 30 May 2003
Abstract
The In Ouzzal terrane (Western Hoggar) is an example of Archaean crust remobilized during a very-high-temperature meta-
morphism related to the Paleoproterozoic orogeny (2 Ga). Pan-African events (�0.6 Ga) are localized and generally of low intensity.
The In Ouzzal terrane is composed of two Archaean units, a lower crustal unit made up essentially of enderbites and charnockites,
and a supracrustal unit of quartzites, banded iron formations, marbles, Al–Mg and Al–Fe granulites commonly associated with
mafic (metanorites and garnet pyroxenites) and ultramafic (pyroxenites, lherzolites and harzburgites) lenses. Cordierite-bearing
monzogranitic gneisses and anorthosites occur also in this unit. The continental crust represented by the granulitic unit of In Ouzzal
was formed during various orogenic reworking events spread between 3200 and 2000 Ma. The formation of a continental crust made
up of tonalites and trondhjemites took place between P3200 and 2700 Ma. Towards 2650 Ma, extension-related alkali-granites
were emplaced. The deposition of the metasedimentary protoliths between 2700 and 2650 Ma, was coeval with rifting. The me-
tasedimentary rocks such as quartzites and Al–Mg pelites anomalously rich in Cr and Ni, are interpreted as a mixture between an
immature component resulting from the erosion and hydrothermal alteration of mafic to ultramafic materials, and a granitic mature
component. The youngest Archaean igneous event at 2500 Ma includes calc-alkaline granites resulting from partial melting of a
predominantly tonalitic continental crust. These granites were subsequently converted into charnockitic orthogneisses. This indi-
cates crustal thickening or heating, and probably late Archaean high-grade metamorphism coeval with the development of domes
and basins. The Paleoproterozoic deformation consists essentially of a re-activation of the pre-existing Archaean structures. The
structural features observed at the base of the crust argue in favour of deformation under granulite-facies. These features are
compatible with homogeneous horizontal shortening of overall NW–SE trend that accentuated the vertical stretching and flattening
of old structures in the form of basins and domes. This shortening was accommodated by horizontal displacements along trans-
pressive shear corridors. Reactional textures and the development of parageneses during the Paleoproterozoic suggest a clockwise P–
T path characterized by prograde evolution at high pressures (800–1050 �C at 10–11 kbar), leading to the appearance of exceptional
parageneses with corundum–quartz, sapphirine–quartz and sapphirine–spinel–quartz. This was followed by an isothermal
decompression (9–5 kbar). Despite the high temperatures attained, the dehydrated continental crust did not undergo any significant
partial melting. The P–T path followed by the granulites is compatible with a continental collision, followed by delamination of the
lithosphere and uprise of the asthenosphere. During exhumation of this chain, the shear zones controlled the emplacement of
carbonatites associated with fenites.
� 2003 Elsevier B.V. All rights reserved.
Keywords: Archaean; Paleoproterozoic; Hoggar massif; Tuareg shield; In Ouzzal; Very-high-temperature granulites
* Corresponding author. Tel.: +33-1-44-87-51-90; fax: +33-1-44-27-
39-11.
E-mail address: [email protected] (J.-R. Kienast).
0899-5362/$ - see front matter � 2003 Elsevier B.V. All rights reserved.
doi:10.1016/j.jafrearsci.2003.05.002
1. Introduction
During the Archaean, various cycles of geodynamic
evolution took place in several cratons whereby an
episode of island-arc accretion was followed by the
formation of tonalites, trondjhemites and granodiorites
Fig. 1. (A) Schematic map of the Tuareg shield showing the setting of
the In Ouzzal terrane within the Trans-Saharan Pan-African belt
(Black et al., 1994). (B) Geological sketch-map of the In Ouzzal ter-
rane and adjacent areas (Caby, 1996). AH: Ahnet Palaeoprotero-
zoic quartzites; AM: Amesmessa gold deposit; BE: In Bezeg granulite
unit; IA: In Assaka non-metamorphic Paleoproterozoic quartz-
ites; IAL: In Alarene layered complex; IGU: Iforas Granulite Unit; IH:
208 K. Ouzegane et al. / Journal of African Earth Sciences 37 (2003) 207–227
(TTG). This led to a period of reworking of the crustaccompanied by dome-and-basin tectonics, the
emplacement of calc-alkaline granites and the develop-
ment of high-grade metamorphism followed by a long
period of quiescence lasting up to 500 million years
(Choukroune et al., 1997; Condie, 1997). One of the
aims of this review is to highlight the timing as well as
the mechanisms of creation, deformation and differen-
tiation of a segment of crust from the Archaean to thePaleoproterozoic. Despite a Paleoproterozoic tectono-
metamorphic event (2000 Ma), these granulites preserve
the general characteristics of the precursors to the Ar-
chaean granite/greenstone belt-like terrains. The topics
of geological research on this kind of terrain, are to
characterize the nature of the protoliths, the relation-
ships between the meta-igneous and metasedimentary
units, the emplacement age of the protoliths and that ofmetamorphic events. Finally, the structural and meta-
morphic characterization of granulites is required to
establish the pressure–temperature paths followed by
these rocks during their evolution.
The Hoggar is composed of well preserved and lar-
gely reworked Archean (3200–2500 Ma) and Paleopro-
terozoic terranes (2000 Ma) and juvenile Pan-African
terranes (750–550 Ma). The main tectonic feature of thisarea is the system of lithospheric north–south shear
zones with large movements related to terranes collage
and continental collision (Black et al., 1994; Fig. 1A).
The In Ouzzal terrane forms an elongated N–S trending
block, more than 400 km long and 80 km wide in the
north around the In Hihaou massif, thinning out until it
disappears in the south near the Malian border, where it
is then offset towards the Iforas granulitic unit (Fig. 1B).The main relief rising several hundreds of metres above
the In Ouzzal granulitic reg (¼ desert pediment with
small pebbles) is made up of ignimbrite massifs dated at
530 Ma (Picciotto et al., 1965), and the Pan-African
granites of In Hihaou and In Eher in the West, Nahalet
and Tihimatine in the centre and Ihouhaouene in the
East (Fig. 2). The boundaries of the In Ouzzal granulitic
terrane with the branches of the Pan-African belt arerepresented by vertical wrench faults. The East-In
Ouzzal mylonitic margin has been studied in detail in
the areas of Tirek (Attoum, 1983) and Amesmessa
(Djemai, 1996), where it consists of a major vertical fault
with a dextral strike-slip component. The West-Ouzza-
lian wrench fault, on the other hand, has a sinistral
displacement (Caby, 1970), the last movements along
the fault coincided with the emplacement of the TinZebane alkaline–peralkaline dyke swarm (�592 Ma;
bFig. 1 (continued)
Ihouhahouene alkali-granite; IZ: In Zize volcanic complex, TAS:
Tassendjanet; TIS: Tissangenine; TI: Tirek gold deposit; TZ: Tin
Zebbane dyke complex.
Fig. 2. Geological sketch-map (simplified from Caby, 1970) showing
the location of areas mentioned in the text (black square) and position
of cross-section (Fig. 3).
K. Ouzegane et al. / Journal of African Earth Sciences 37 (2003) 207–227 209
Hadj-Kaddour et al., 1998). Moussine-Pouchkine et al.
(1988) pointed out that the extreme northern part of In
Ouzzal is overthrust onto the volcanogenic series of
Adrar Ahnet. In fact, arc-type formations and glauco-
phane-bearing metamorphic rocks indicate the existenceof a Pan-African subduction zone in this area (Caby and
Moni�ee, 2003, this issue; Mokri, personal communica-
tion). The recognition of the tectonic contacts and the
metamorphic contrast between the In Ouzzal granulitic
unit and the Pan-African belt (amphibolite and greens-
chist facies, respectively), along with the Archaean age
of the granulite protoliths, suggest that In Ouzzal is an
exotic Pan-African terrane made of Archean and Pa-leoproterozoic rocks (Kienast and Ouzegane, 1987;
Black et al., 1994; Caby, 1996).
Lelubre (1952) conducted the first petrological studyof In Ouzzal; he stressed the original nature of the
series exhibiting ‘‘In Ouzzal facies’’. He compared them
with the charnockites of India and proposed that
these granulites were much older than the terrains that
surround them. In the area around In Hihaou and
Tekhamalt, a granulitic complex was described briefly by
Giraud (1961) and Le Fur (1966). This complex is com-
posed of charnockites, nodular marbles, garnet–graphitegneisses, quartzites with magnetite and quartzites with
garnet–orthopyroxene–sillimanite (Giraud, 1961). Litho-
logically the In Ouzzal formations are very diversified
(Kienast et al., 1996) and are composed mainly of two
units: (i) a lower crustal unit made up essentially of
enderbitic orthogneisses, and (ii) a supracrustal unit
composed of quartzites, banded iron formations, mar-
bles, Al–Mg granulites and Al–Fe granulites commonlyassociated with meta-igneous material such as mafic
(metanorites and garnet pyroxenites) and ultramafic
(lherzolites, harzburgites and pyroxenites) lenses, as well
as anorthosites and cordierite-bearing monzogranitic
gneisses. Regarding the supracrustal unit, the most ori-
ginal feature is the abundance and the variety of Al–Mg
granulites. These rocks contain parageneses which indi-
cate a very-high-temperature metamorphism at about1000 �C for a pressure of 10–11 kbar. The marbles with
wollastonite–scapolite–calcite–quartz, anorthite–grossu-
larite (Benyahia, 1996; Boureghda, 2000; Ouzegane
et al., 2002) and the spinel–quartz quartzites with or
without corundum (Ait Djafer, 1996; Guiraud et al.,
1996; Badani-Djebloun, 1998) also confirm the extreme
temperature conditions of this metamorphism.
2. Principal lithological types
2.1. Enderbitic and charnockitic orthogneisses
The charnockitic and enderbitic unit is very exten-
sively exposed, covering most of the area between Oued
Tin Tchik Tchik and Tekhamalt (Fig. 2, Ouzegane,
1987; Ouzegane and Kienast, 1996) and form the major
part of the outcrops in the areas of Tirek and Ames-messa (Fig. 1B). These rocks are also found in the areas
of Roccan, Ihouhaouene and Tikechitine (Fig. 2) asso-
ciated with marbles and alumino-magnesian granulites.
The foliation trajectories delineate dome structures
occupied by the charnockites or enderbites, whereas the
metasedimentary formations occur in basins (Fig. 3;
Haddoum et al., 1994). Foliation is generally sub-verti-
cal and parallel to the lithological layering, reflecting theeffects of tectonic transposition. The stretching linea-
tions show highly variable but generally steep plunges
(70–90�). Based on the structural, geochemical and
geochronological (U/Pb on zircon) studies, three major
Fig. 3. Schematic NNW-SSE cross-section summarizing the style of deformation and structural relationships between Archean charnockitic gneisses
and supracrustal series of the In Ouzzal terrane.
210 K. Ouzegane et al. / Journal of African Earth Sciences 37 (2003) 207–227
groups of orthogneisses have been distinguished (Had-
doum et al., 1994; Peucat et al., 1996):
• the first group corresponds to orthogneisses of the
trondhjemite, tonalite and granodiorite type (TTG)
that are dated at between 3200 and 2700 Ma;• the second group corresponds to alkali-granitic or-
thogneisses dated at 2650 Ma;
• the third group corresponds to a calc-alkaline suite
made up of granodiorites and monzogranites em-
placed close to 2500 Ma.
The first group comprises folied enderbitic ortho-
gneisses exposed in the areas of Tin Tchik Tchik, Roc-can and Tickechitine. The structure of these rocks is
generally banded with a foliation defined by dark layers
containing pyroxenes. Orthogneisses of trondhjemitic to
tonalitic composition exhibit varied mineral associa-
tions. The trondhjemitic gneisses are composed of
hypersthene, quartz, oligoclase and accessory minerals
such as magnetite, ilmenite, apatite and zircon. In cer-
tain cases, perthites and biotite also occur aroundhypersthene. In addition to hypersthene, tonalitic or-
thogneisses are composed of clinopyroxene, plagioclase
(An35–40), perthite, quartz, rare biotite, magnetite,
ilmenite, apatite and zircon.
The second group includes charnockitic ortho-
gneisses generally forming small ranges that rise more
than 60 m above the reg, including Tekhamalt Tan
Affela and Tekhamalt Tan Ataram (Fig. 2). Theserocks occur also in the reg of Roccan and Oued
Ihouhaou�eene (Fig. 2). The distinctive feature of these
rocks is the presence of the association perthite-quartz-
ferro-augite, to which can be added oligoclase and
green hornblende. The accessory minerals are apatite,
zircon, magnetite, ilmenite, pyrochlore and chevkinite
(Acef et al., 2001).
The third group consists of calc-alkali orthogneisses
forming a granodioritic to monzogranitic suite intruded
into the preceding groups, but which are also associated
with the supracrustal formations. The mineralogical
composition of granodioritic orthogneisses includes
plagioclase (An30), quartz, perthites and hypersthene,with rare biotite and, sometimes, green hornblende
(Lassel, 1990). Monzogranitic orthogneisses contain
more biotite than the granodioritic orthogneisses, while
hornblende is not observed (Peucat et al., 1996).
Orthogneisses of the first group define a trondjhemitic
differentiation trend, with K2O/Na2O ratios <0.5 (Bar-
ker, 1979). The spiderdiagram plots normalized to the
primitive mantle show patterns for most of the elementsthat agree with Archaean TTG suites, e.g. negative
anomalies in Ta, Nb, P and Ti, but a positive anomaly in
Pb (Fig. 4). The low contents of Ta (<0.5 ppm), Nb (9–12
ppm), Y (<20 ppm) and Yb (<1.6 ppm) are comparable
with values from igneous rocks of present-day island
arcs. As with the Archaean granitoids, the In Ouzzal
gneisses with TTG composition show low contents of Yb
and a strong fractionation of the REE, suggesting thatthe source could have been garnet amphibolites. Their
contents of Y (7–18 ppm) and Sr/Y ratios (18–62) may be
explained by variable quantities of garnet in the residue
and varied pressure conditions of formation (Peucat
et al., 1996). The U–Pb zircon dating suggest at least two
emplacement episodes at 3.2 and 2.7 Ga and a probable
reworking of an older crust in the case of the TTG dated
at 2.7 Ga, with some of these rocks having TDM modelages of 3.3 Ga (Peucat et al., 1996). Most of these or-
thogneisses yield TDM model ages around 3.2 Ga, in good
agreement with the U–Pb zircon ages, thus supporting
the relative immobility of Sm and Nd, and all the rare
earth elements (REE). The calculated eNd at 3.2 Ga
ranges from +0.4 to +5.3, with a concentration of values
around +4 (Peucat et al., 1996) that corresponds to the
0.1
1
10
100
1000
Cs Rb Ba Th U K Ta Nb La Ce Pb Sr Nd P Hf Zr Sm Ti Tb Y Yb
TTG
CA2
CA1
Alk3
Sam
ple/
Prim
itive
Man
tle
Fig. 4. Spider diagram of Archaean granitic orthogneisses. Data after Peucat et al. (1996). Primitive mantle normalization values of McDonough
et al. (1992).
K. Ouzegane et al. / Journal of African Earth Sciences 37 (2003) 207–227 211
depleted mantle at 3.2 Ga. Conversely, the ISr values at
3.2 Ga are much too high since they vary from 0.7021 to
0.7065. This illustrates that these rocks have undergone a
Rb loss.
The second orthogneiss type shows alkali-type com-
positions ranging from granodiorite–monzogranite togranite (SiO2 ¼ 69–75 wt.%). With the exception of the
most felsic members, which display a slightly peralumi-
nous trend, the remaining samples are metaluminous.
They are rich in K2O (>6 wt.%), low in Na2O (<2.9
wt.%), and have very low XMg ratios (0.07–0.11). Their
composition suggests a rift-type magmatism (Peucat
et al., 1996). The enrichment in incompatible elements
such as Ta, Nb, Y, and especially Ba (>1000 ppm), Hfand Zr (500–600 ppm), as well as their high Ga/Al ratios
(Peucat et al., 1996) also shows an affinity with intra-
plate granites and particularly the type-A2 granites of
Eby (1992). Apart from the most mobile elements and
Hf and Zr, the trace element contents of the alkali-
orthogneisses (Fig. 4) are very close to those of the
Archaean ALK3-type granites of Sylvester (1994). For
example, the REE are enriched and show relativelyweak fractionation ((La/Yb)N ¼ 6–10), in particular the
HREE ((Gd/Yb)N <1.7). On the other hand, Hf and Zr
contents are typical of present-day alkali-granites. Sev-
eral authors (Anderson, 1983; Creaser et al., 1991)
attribute the origin of this type of granite to partial
melting of tonalites. However, the binary diagrams trace
elements rule out any genetic link with the sampled
TTGs. The Rb/Sr pair makes it possible to calculate anisochron at 2.61 ± 0.07 Ga with an initial ISr ratio of
0.709 ± 0.002 (MSWD¼ 10). This is consistent with the
result obtained by the U–Pb method on zircons, which
yields an age of 2.65 Ga (Peucat et al., 1996). The eNd
values corresponding to 2.65 Ga are low and relatively
homogeneous, being located around )6.5, whereas TDM
model ages vary between 3.7 and 3.3 Ga. Thus, the
isotopic compositions of Sr and Nd suggest the
reworking of an older source. However, these alkali
granites also exhibit low dO18 values (5.95–7.7&; Peucat
et al., 1996), suggesting a re-equilibration at high tem-
perature with their surrounding metasedimentary rocks,which have a low dO18. This implies that the alkali-
granites have a juvenile origin (or at least are derived by
remelting of a juvenile material, for example of met-
adiorites). For the type-A granites, the juvenile source
could correspond mainly to the lower part of the con-
tinental lithosphere enriched in HFSE and the upper
part of the asthenosphere, as suggested by Li�eegeois et al.
(1998). The isotopic compositions would thus resultfrom a previously enriched lithosphere or a crustal
contamination process (Li�eegeois et al., 1998; Bonin et al.,
1998).
Orthogneisses belonging to the third group have
compositions typical of calc-alkaline suites (Peucat et al.,
1996). They are divided into two units. The first unit
consists of granodioritic to monzogranitic gneisses of
very slightly peraluminous composition (A/CNK¼1.01–1.08) having XMg (0.22–0.36) typical of Archaean
calc-alkali granites as defined by Sylvester (1994). Ele-
mental abundances normalized to the primitive mantle
show patterns similar to those observed in orogenic
magmatic suites, with negative anomalies in Ba, Ta, Nb,
Sr, P and Ti (Fig. 4). However, just like the Archaean
TTGs, these rocks yield highly fractionated REE ((La/
Yb)N �50) with a concave-upward pattern for theHREE. In addition to the low contents of TiO2 and V,
this suggests a residue containing garnet (Sylvester,
1994). Except for the most mobile elements (Cs, U,
Rb and Cu), the trace element composition of these
ancient granites is comparable to the Archaean CA2-
type calc-alkaline granites of Sylvester (1994). This
212 K. Ouzegane et al. / Journal of African Earth Sciences 37 (2003) 207–227
author attributes their origin to the fusion of a tonaliticArchaean lower crust. Such an origin implies a thick-
ening of the crust or heat event and the prior existence of
TTG. The second unit shows a calc-alkaline trend and is
made up of orthogneisses with monzogranitic compo-
sition. Their major element composition is typical of
post-orogenic highly fractionated calc-alkaline granites
(Peucat et al., 1996). Their trace element contents re-
semble those of the Archaean calc-alkaline granites oftype CA1. According to Sylvester (1994), such granites
would be derived from the melting of tonalites inter-
stratified with metasedimentary rocks, at shallower
depths than for the CA2, without leaving garnet in the
residue. The U/Pb zircon data indicate an emplacement
age of 2.5 Ga for both types of calc-alkali-granites, with
a minimum protolith age of 2.94 Ga (Peucat et al.,
1996). The Sm/Nd isotopic data for the first unit, withCA2-type composition, provide model ages of around
3.1 Ga. The second unit has more scattered TDM, be-
tween 3.05 and 3.5 Ga. Peucat et al. (1996) attribute
these values to the presence of an older tonalitic pro-
tolith.
2.2. Supracrustal mafic and ultramafic meta-igneous
granulites
The mafic granulites (metanorites and garnet pyroxe-
nites) are mostly located around In Hihaou, but they
also occur in the areas of Tekhamalt, Ihouhaou�eene andAmesmessa (Figs. 1 and 2). They occur in boudinaged
lenses parallel to the foliation in Al–Mg granulites, ban-
ded iron formations, marbles, peridotites, enderbitic and
charnockitic orthogneisses. Two types of metamorphosed
mafic rocks––with or without garnet––are distinguished
in the field. The metanorites are composed of salitic clin-
opyroxene (Ca48Mg40Fe12), orthopyroxene (XMg ¼ 0:65),
plagioclase (An48 to An70), pargasite, magnetite andsometimes biotite. The garnet pyroxenites are composed
of two quite distinct parageneses. The primary assemblage
is characterized by the presence of garnet, clinopyroxene,
pargasite, plagioclase (labradorite), magnetite, rutile and
quartz. This assemblage is involved in reactions leading to
the development of orthopyroxene–plagioclase symplec-
tites following decompression (Kienast and Ouzegane,
1987; Djemai, 1996).The peridotites appear especially in lenticular masses
several hundreds of metres thick in the northern part of
In Ouzzal (In Hihaou and Tekhamalt), frequently
associated with pyroxenites, anorthosites and with me-
tasedimentary formations with which they are folded.
These banded rocks generally show a very advanced
degree of serpentinization. These peridotites can be
classified into two groups (Bendaoud et al., 2001): (1)lherzolites containing olivine (Fo88), diopside, orthopy-
roxene (XMg ¼ 0:87), spinel (24–42% Cr2O3) and (2)
harzburgites containing olivine, orthopyroxene and
magnetite. The pyroxenites are characterized in the fieldby a light green colour, and are composed essentially of
orthopyroxene (XMg ¼ 0:75–85) and pargasite (XMg ¼0:82–0:90) showing equilibrium textures with triple
points. The chromium-rich (6–33% weight oxide) brown
spinel forms interstitial fine crystals or inclusions in
pargasite or enstatite. Plagioclase (An80–99) is ubiquitous,
appearing in patches, whereas phlogopite (XMg ¼0:87–0:92) and diopsidic clinopyroxene (Ca49Mg45Fe6)are rarer.
All the mafic and ultramafic rocks clearly show a
mobility in certain elements such as Rb, U and Th, as
indicated by Rb/Sr (0.01–3.44), La/Th (<6) and Th/U
(<8) ratios that are abnormal for igneous rocks (Peucat
et al., 1996). The same probably applies to Na and K.
The samples with the highest MgO contents (>20%) are
cumulates, as shown by their contents of Ca, K, P and Tiand certain trace elements such as Sm and Yb that are
depleted relative to the primitive mantle. These rocks
display chondritic values for Al2O3/TiO2, CaO/Al2O3
and (Gd/Yb)N , with average ratios of 22.3, 0.85 and 1.05,
respectively (Bendaoud et al., 2002). The metanorites
have MgO between 7.5 and 13.5 wt.%, and are highly
magnesian tholeiites. Their REE contents and abun-
dance patterns are comparable with those of Archaeantholeiites (Fig. 5). Some metanorites, like those of Roc-
can and Tin Tchik Tchik, plot in the fields of calc-alka-
line rocks. Even if some of these rocks are clearly
depleted in the most mobile elements (Cs, Rb, Th and U),
they yield REE patterns and spiderdiagram similar to
those of present-day highly magnesian andesites (Fig. 5).
Not all of these rocks could be dated. They yield ISr ratios
that remain high even at 3.2 Ga (0.7046–0.7072) and TDM
model ages which vary from 3136 to 4193 Ma (Peucat et
al., 1996). These values indicate that the element pairs
Rb/Sr and Sm/Nd were strongly disturbed by meta-
morphic alteration and/or events subsequent to their
emplacement. This is often the case for the mafic and
ultramafic rocks from Archaean greenstone belts and
particularly those having undergone high-grade meta-
morphism (Gruau et al., 1992; Arndt, 1998).
2.3. Supracrustal metasedimentary formations
2.3.1. Al–Mg granulites
Alumino-magnesian granulites are exceptionally well
developed near Adrar In Hihaou and in the Tekhamalt
area, but also occur more rarely in the areas of
Ihouhaouene and Amesmessa (Figs. 1 and 2). These
granulites are generally interstratified with rocks of
sedimentary origin such as banded iron formations and
marbles. They are also in direct contact with meta-
igneous rocks such as enderbites, charnockites, metan-orites or peridotites. A first distinction can be made
between two types of alumino-magnesian granulite
displaying a clear contrast in the field (Kienast and
Fig. 5. Chondrite-normalized REE patterns for Archaean mafic and ultramafic granulites. Normalizing values are those of Boynton (1984). Data
after Peucat et al. (1996).
K. Ouzegane et al. / Journal of African Earth Sciences 37 (2003) 207–227 213
Ouzegane, 1987). One type of granulite is rich in quartz,
while the other is quartz-free. However, the majority of
these granulites are rich in quartz and form layers with a
brown patina of variable thickness (from one to several
metres). They are dense massive rocks with a sometimeswell-marked foliation. Garnet and orthopyroxene por-
phyroblasts show a ductile behaviour expressed by an
elongation of the grains materialising the sub-vertical
stretching lineations as well as the torsion of orthopy-
roxene cleavage planes. This provides evidence of high-
temperature deformation by diffusion-creep at the grain
boundaries. Within these quartzitic layers, occur quartz-
free lenses of varied sizes (a few cubic centimetres toseveral cubic metres), easily recognizable in the field
because of their blue colour due to the abundance of
sapphirine. All these rocks are remarkable in exhibiting
the association orthopyroxene–sillimanite along with an
extremely diverse mineralogy made up of cordierite,
biotite, spinel, corundum, plagioclase, potassic feldspar,
ilmenite and rutile. Like sapphirine, garnet can be an
abundant mineral in certain layers. Based on the pres-ence of certain index minerals and their silica content,
alumino-magnesian granulites can be classified into five
groups (Bernard-Griffiths et al., 1996; Ouzegane and
Kienast, 1996; Fig. 6): spinel-bearing Al–Mg granulites
(SiO2: 37–40%), corundum-bearing Al–Mg granulites
(SiO2: 40–45%), quartz-free Al–Mg granulites (SiO2: 43–
45%), quartz-bearing Al–Mg granulites (SiO2: 46–63%)
and quartzitic Al–Mg granulites (SiO2: 65–85%).
2.3.2. Al–Fe granulites and quartzites
Al–Fe granulites containing garnet and sillimanite are
well represented in the area of Ihouhaouene (Fig. 2) near
the carbonatite occurrences (Ait Djafer and Ouzegane,
1998). They crop out in an extremely variable way in
stratified massive bands that form hills rising 10 m
above the reg between carbonatite centres 1 and 2
(Ouzegane, 1987), sometimes in discontinuous disruptedbands forming lenses from 10 to 20 cm in size. Quartzo-
feldspathic veinlets are distributed in the fold hinges,
giving these rocks a migmatitic appearance (Ait Djafer,
1996; Ait Djafer and Ouzegane, 1998). In thin section,
these veinlets are composed of quartz in plates with
sutured outlines associated with plagioclase (An33) and
potassic feldspar. Primary garnet (XMg ¼ 0:2–0:4) is
systematically surrounded by cordierite, whereas thespinel occurs as vermiculated grains (XMg ¼ 0:15–0:39),
that grow out from sillimanite to form symplectites with
cordierite (XMg ¼ 0:64 to 0.87). The synchronous
development of cordierite and spinel is explained by the
breakdown of garnet in contact with sillimanite during
decompression. Some large primary spinel crystals are
isolated from quartz by a corona of cordierite (Ait
Djafer and Ouzegane, 1998).Gedrite–garnet–sillimanite granulites appear in cm-
scale lenses associated with Al–Mg granulites containing
sapphirine–orthopyroxene–sillimanite, and with garnet
pyroxenites in the area of Amesmessa (Djemai, 1996;
Ouzegane et al., 1996). The gedrite–sillimanite associa-
tion is rare, existing only in few documented localities
worldwide (Robinson and Jaffe, 1969; Spear, 1982;
Goscombe, 1992; Spear, 1993). The primary paragenesisis made up of garnet (pyrope: 22–50%, almandine: 45–
75%), gedrite (XMg ¼ 0:64–0:70), sillimanite, quartz,
plagioclase (An25–42), rutile, ilmenite and biotite
(XMg ¼ 77–78). The minerals belonging to the primary
Fig. 6. Classification of Al–Mg and Al–Fe granulites according to The Mg/Mg+Fe (in mole proportions) versus SiO2 (wt.%) plot showing fields for
quartz-free granulites (SiO2 < 45%) and quartz-bearing granulites (SiO2 > 45%). This diagram also distinguishes garnet-free Al–Mg granulite (Mg/
Mg+Fe >0.80) from garnet-bearing Al–Mg and Al–Fe granulites (Mg/Mg+Fe> 0.80); orthopyroxene-free granulites (XMg < 0:50Þ are also shown
as a separate field from orthopyroxene-bearing granulites. Data reported in Bernard-Griffiths et al. (1996), Badani-Djebloun (1998) and Ouzegane
et al. (2003).
214 K. Ouzegane et al. / Journal of African Earth Sciences 37 (2003) 207–227
paragenesis are not observed in direct contact with each
other. Instead, they are always separated by coronas or
symplectites related to the secondary paragenesis made
up of cordierite-orthopyroxene (with or without spinel)
formed following decompression. The newly formed
orthopyroxene displays an enstatite composition near
47–51 mol% when it develops from the reaction: garnet +quartz) orthopyroxene+ cordierite, but is more mag-
nesian (enstatite 62–68%) when gedrite participates in
the reaction in the presence of quartz. The cordierite–
orthopyroxene–spinel symplectites develop at the con-
tacts between gedrite and garnet in the microdomains
without quartz. Garnet is surrounded by a corona of
cordierite and sillimanite is surrounded by cordierite-
spinel symplectites in the microdomains lacking quartzand gedrite, suggesting a decompression reaction: gar-
net + sillimanite) cordierite + spinel. Cordierite alone,
forming a corona, separates garnet from sillimanite and
quartz in the absence of gedrite (Ouzegane et al., 1996).
Al–Fe quartzites containing hercynite–quartz are less
rare than the preceding rock-types; they form discontin-
uous layers generally related to the shear zones at Alouki,
Ihouhaouene and Tin Tchik Tchik, where they are asso-ciated with rocks of sedimentary origin (Fig. 2). The
development of garnet and sillimanite in coronas or
symplectites is explained by a reaction of the type:
hercynite+magnetite+ quartz) almandine+ sillimanite
or hercynite+ quartz) almandine+ sillimanite (Badani-
Djebloun et al., 2000). We also sometimes observe
thin garnet coronas around the sillimanite and magne-
tite. The following reaction accounts for these tex-tures: quartz+ sillimanite +magnetite) almandine+O2
(Helal, 1987).
Al–Mg and Al–Fe granulites are composed essen-
tially of the components SiO2–Al2O3–FeO–MgO,
accounting for a sum higher than 90% of the total oxi-
des. Fig. 6 shows a plot of Mg/Mg + Fe mole ratio
versus SiO2 for a set of whole-rock samples. This dia-
gram allows to distinguish granulites containing primary
garnet (XMg ¼ 0:30–0:80) from those which do notcontain any (XMg ¼ 0:82–0:96), as well as granulites with
quartz (SiO2 > 45%) from quartz-free varieties (SiO2 <
45%). Al–Fe granulites exhibit XMg ratios ranging be-
tween 0.3 and 0.48, and this chemical characteris-
tic prevents the development of the orthopyroxene +
sillimanite or sapphirine-bearing association. This is in
contrast with Al–Mg granulites (XMg > 0.50), which are
characterized by the omnipresence of these associations.The major and trace geochemistry of Al–Mg granulites
from In Ouzzal, especially the very high contents of Cr
(400–2500 ppm), Ni (100–1100 ppm), Co (50–80 ppm),
cannot be explained by a process of partial melting. The
preservation of their oxygen isotope composition (Ber-
nard-Griffiths et al., 1996) suggests rather that their
particular refractory chemistry is of pre-metamorphic
origin. Thus, the lowest dO18 values––varying from +5to +6&––are recorded in Al–Mg granulites from the
area of Tekhamalt. Although these values do not cor-
respond to the dO18 of ordinary pelites, they are com-
parable with those of chlorites, a mineral produced by
the hydrothermal alteration of mafic to ultramafic
materials in the marine environment (Rahmani, 1992;
Bernard-Griffiths et al., 1996). These metasedimentary
rocks have dO18 values between 5 and 9.5&, corre-sponding to a mixture, in variable proportions, between
a mature detrital component (composed essentially of
K. Ouzegane et al. / Journal of African Earth Sciences 37 (2003) 207–227 215
quartz) derived from the erosion of a granitic protolithand an extremely immature component, resulting from
hydrothermal alteration of mafic to ultramafic proto-
liths. This latter component is of chloritic type, rich in
Al, Mg, Cr, Co and Ni, with possible additions of
chromium-rich spinel and small proportions of illite
and/or muscovite to account for the K contents of these
granulites (0.3–2%, Bernard-Griffiths et al., 1996). The
very high contents of chromium (3960 ppm) and nickel(up to 1100 ppm) in the Al–Mg granulites of In Ouzzal
is a typical feature of early Archaean immature sedi-
ments (Bernard-Griffiths et al., 1996). Al–Fe granulites
also exhibit Cr, Ni and Co contents that are comparable
with Archaean and end-Archaean shales, since they
result––like the Al–Mg granulites––from the mixing of
chloritic and detrital quartz components (Badani-Djeb-
loun, 1998). The Al–Mg quartzites and Al–Fe quartzitesshow SiO2 contents varying from 62 to 85 wt.% and
chromium contents of up to 100–200 ppm, and are
characterized by the presence of detrital chromite in the
sedimentary protoliths. These rocks resemble the fuch-
site-bearing quartzites of the Archean cratons (Eriksson
et al., 1997).
Detrital zircons from the Al–Fe quartzites of Ihou-
haou�eene show growth structures with ancient cores andcoronas formed during the granulite-facies event at 2
Ga. Inherited zircon cores indicate ages that are scat-
tered between 3100 and 2700 My (Lancelot et al., 1976;
Helal, 1987; Peucat et al., 1996). These geochronological
data indicate that the deposition of the supracrustal
series probably took place after 2 700 Ma (Peucat et al.,
1996). Inherited zircons present in the Al–Mg granulites
show a spectrum of ages ranging between 2700 and 3200Ma, which corresponds to the emplacement of the var-
ious generations of TTG (Peucat et al., 1996). This im-
plies that part of silica present in these rocks had a
detrital origin, possibly derived from the erosion of pre-
existing Archaean granites at In Ouzzal.
2.3.3. Magnetite-bearing quartzites (banded iron forma-
tion)
The main outcrops of banded iron formation occur in
the Alouki massif, where they are involved in map-scale
folds that can be followed over more than 20 km. These
rocks occur also in the areas of Ihouhaouene, Tin TchikTchik, Tekhamalt and Amesmessa in more or less con-
tinuous beds from 1 to 50 m thick repeated by isoclinal
folds (Fig. 2). While they display a practically constant
association with marbles and metanorites, they are also
encountered in the area of Ihouhaouene in direct con-
tact with fenites (carbonatite centres 1 and 2; Ouzegane,
1987; Guiraud et al., 1996). Throughout these areas, the
iron-bearing formations and their associated rocks makeup supracustal sequences forming basins (Fig. 3) that
are separated from domes of enderbites. The mineralogy
of the banded iron formation is generally simple, being
composed of quartz and magnetite. Magnetite is eitherdisseminated in the rock, or clustered together in beds
varying in thickness from 1 cm to 1 m. These rocks are
sometimes highly deformed with thin levels of pseu-
dotachylite. There are also some banded iron formations
with more varied mineralogy, notably containing asso-
ciations with corundum–quartz (Ihouhaouene; Guiraud
et al., 1996) and garnet–orthoferrosilite–almandine–
spinel (Tekhamalt; Ouzegane and Kienast, 1996;Badani-Djebloun, 1998).
2.3.4. Marbles
The marble layers are generally limited to isolated
lenticular bands (a few metres to 100 m thick), but some
very extensive outcrops are observed in the areas of Illa-saka, Ihouhaouene, Roccan, Tekhamalt (Fig. 2), Tirek
and Amesmessa (Fig. 1A). They generally form folded
layers with vertical axes, like the associated banded iron
formations. The In Ouzzal marbles exhibit a wide miner-
alogical diversity. Two main groups can be distinguished,
dolomitic marbles characterized by a paragenesis with
dolomite–olivine–spinel–phlogopite–amphibole–clinopy-
roxene, and dolomite-free marbles with calcite–quartz–grossularite–andradite–wollastonite (Benyahia, 1996;
Boureghda, 2000). Scapolite-bearing marbles are associ-
ated with these two categories, but are found in lesser
proportions.
The identification of the protoliths of the dolomitic
marbles was established by Fourcade et al. (1996), based
on the chemical composition and isotopic characteristics
of these marbles. The high Al and Mg contents of thedolomitic marbles could be due to the addition of a
chloritic component derived from the hydrothermal
alteration of a mafic/ultramafic source during carbonate
sedimentation. The carbonate sediment protolith would
be composed of varied proportions of calcite, dolomite
and chlorite. During granulite-facies metamorphism,
this impure dolomite produced forsterite–spinel marbles
with or without diopside. The isotope signatures ofoxygen (dO18 ¼ 7.9–18.9&) and carbon (dC13 ¼)0.8&
to )4.2&) are very heterogeneous, indicating that the
marbles of In Ouzzal have preserved their pre-meta-
morphic characteristics. The preservation of such an
isotopic heterogeneity implies the absence of homoge-
nizing fluids or percolation of CO2 of mantle origin
during the granulite-facies event (Fourcade et al., 1996).
2.3.5. Al–Mg–Ca granulites (paleoskarns)
Al–Mg–Ca granulites crop out especially in the area
of Tekhamalt (Fig. 2), in direct contact with charnoc-
kitic orthogneisses of alkali-granitic type, and are sys-
tematically associated with the olivine–spinel marbles as
in the areas of Alouki, In Hihaou, Tirek and Tekhamalt.They are banded rocks remarkable by the presence of
the association spinel–pargasite–anorthite and fassaite-
type clinopyroxene, with occasional pyrochlore and
216 K. Ouzegane et al. / Journal of African Earth Sciences 37 (2003) 207–227
relics of calcite. In the area of Alouki, there are rareassociations containing musgravite–sapphirine–spinel–
phlogopite–corundum–pyrochlore–scheelite–monazite
intercalated with layers of pargasite–clinopyroxene–
musgravite–spinel–anorthite–pyrochlore and calcite (Be-
nyahia, 1996). Musgravite, a beryllium-rich mineral
(5–6% Be; Boumaza-Benyahia et al., 2001), is very rare,
since there are only five known occurrences worldwide.
In the area of Tekhamalt, the dolomitic marbles incontact with charnockites (alkali-granitic orthogneisses)
develop Al–Mg–Ca granulites with diopside–anorthite–
spinel. Fourcade et al. (1996) interpret these rocks as
resulting from decarbonatization, i.e. paleoskarns,
based on their high W and Ag contents (300 ppm and
325 ppb, respectively). The process of decarbonatization
took place before the Paleoproterozoic granulite-facies
metamorphism, and is probably contemporary with theemplacement of alkali-granitic orthogneisses at around
2.65 Ga (Fourcade et al., 1996). In the area of Alouki,
Al–Mg–Ca granulites containing musgravite also result
from a metasomatic process related to these charnock-
itic granites (rich in Nb, Ta and Be) in contact with
dolomitic limestones (Benyahia-Boumaza et al., in
preparation).
2.4. Paleoproterozoic magmatic activity
The magmatic events that accompanied the Paleo-proterozoic granulite-facies metamorphism have re-
sulted in the emplacement of anorthosites, small masses
of cordierite-bearing monzogranitic gneisses (Peucat
et al., 1996) and carbonatites. In the area of Tirek,
syenites intruded along the shear zones over a distance
of more than 50 km (Haddoum, 1992) yield U/Pb zircon
dates of 1 991 ± 20 Ma (Semiani, 1995).
2.4.1. Anorthosites
Anorthosites crop out either in the form of metre-
scale disrupted lenses associated with the supracrustal
series or in more massive layers attaining 1 km thick.The massive anorthosites exposed in the area of Tike-
chitine show stratified structures evocative of cumulate
textures. Pyroxenes are variably distributed, sometimes
concentrated in more or less well defined beds of a few
decimetres to a few centimetres thick. In outcrop, we can
observe a sharp or gradual transition from anorthosites
to leuconorites, with field relations similar to those seen
in layered complexes (Ashwal, 1993). Pyroxene alsooccurs in metre-scale veins in the metanorites and garnet
pyroxenites, where these veins are folded along with the
country rocks. Plagioclase (labradorite–bytownite)
forms the essential mineral of the rock, and coexists with
orthopyroxene or clinopyroxene, accessory minerals
such as titanite, apatite, spinel and ilmenite and, less
constant, quartz, antiperthite and hornblende. Garnet
can be present surrounded by reaction rims with horn-blende-plagioclase. Very rare zircon is also observed.
The only dated anorthosite was sampled in the Alo-
uki area, where this rock-type occurs as veins (50 cm)
associated with metanorites. This rock shows a com-
position similar to the plagioclase-amphibole cumulates
observed in certain layered mafic intrusions, yielding an
age of 2002 ± 7 Ma (U/Pb on zircon; Peucat et al., 1996).
However, Sr–Nd isotopic analyses on ten samples froma more massive anorthositic unit in the Tikechitine area
yield older dates (Archaean, with an age around 3 Ga,
A€ııt-Djafer et al., in preparation).
2.4.2. Cordierite-bearing monzogranitic gneisses
Cordierite-bearing monzogranitic gneisses occurthroughout the In Ouzzal terrane, from North to South.
They form massive leucocratic layers, sometimes
exceeding 100 m in thickness and showing the same
deformation characteristics as the supracrustal series.
These rocks occur also in cm-thick veinlets associated
with Al–Mg granulites or cutting the metanorites. From
the chemical point of view, they represent metamor-
phosed S-type granites (Peucat et al., 1996). Quartz oc-curs in equant patches or polycrystalline plates.
Plagioclase is oligoclase; antiperthite coexists with fine
perthites that are sometimes transformed into micro-
cline. The rocks contain also biotite, garnet, cordierite,
ilmenite and zircon. These rocks show a peraluminous
composition (A/CNK¼ 1.05–1.08) and are very rich in
SiO2 (�78 wt.%), K, Ba and Rb, and poor in Ti, Al, Fe,
Mn, Mg, P, Ta, Nb, Ga, Y, Zn and REE. SHRIMP U–Pb dating of overgrowths and euhedral clear zircon
yielded 207Pb/206Pb age of 1983 ± 15 Ma (Peucat et al.,
1996).
2.4.3. Carbonatites and fenites
In the area of Ihouhaouene, numerous carbonatitemassifs (Fig. 2) occur that are systematically associated
with fenites at their contact with the granulites (Ou-
zegane, 1987; Ouzegane et al., 1988; Bernard-Griffiths
et al., 1988; Carpena et al., 1988; Fourcade et al., 1996).
These rocks display some very particular features, dif-
fering from usual carbonatites by the lack of felds-
pathoids and the abundance of wollastonite which
coexists with calcite and quartz. These rocks show anextreme mineralogical diversity, containing carbonates
(calcite, bastnaesite), phosphates (apatite, monazite and
britholite) and silicates (clinopyroxene, amphibole, bio-
tite, and potassic feldspar). Accessory minerals include
titanite, allanite, fluorite, magnetite and grossularite–
andradite garnet. In the field, a relative chronology
comprising several stages can be established for the
emplacement of the carbonatite complex (Ouzeganeet al., 1988; Fourcade et al., 1996). Two carbonatite
generations are distinguished. The fenites are cut by
sovite veins with mylonitized margins. These carbonatite
K. Ouzegane et al. / Journal of African Earth Sciences 37 (2003) 207–227 217
veins (1–500 m thick and up to 2 km long) can beanastomosed, forming a true network. The fragments in
the carbonatite breccias are made up of fenites rich in
clinopyroxene clusters surrounded by grossularite–
andradite, and potassic feldspar xenoliths. In the matrix
cementing the fragments, calcite predominate (50–70%).
These rocks are characterized by pink apatites (0.5–1.5%
REE, Ouzegane et al., 1988). The second generation of
intrusions is represented by pegmatitic carbonatite veinsof restricted size (maximum 5 m thick) cuts the brecci-
ated carbonatites. Very large crystals of apatite (up to 1
m; Fourcade et al., 1996) make up to 50% of the modal
composition. They contain many microinclusions such
as monazite, quartz, bastanaesite and britholite. The
britholite in exsolution in apatite can occupy more than
40% of the volume of the apatite. Substitutions of the
type P + Ca)REE +Si can account for the exception-ally high rare earth contents of these apatites (1–7%
REE) and of the britholites (30–62% REE, Ouzegane
et al., 1988). The brecciated carbonatites systematically
cut across two types of fenite––red or white––located at
the margins of the complexes in direct contact with the
granulites, from which they are derived by metasomatic
transformation (Fourcade et al., 1996). The wollas-
tonite-bearing white fenites show a clear foliation con-cordant with the foliation of the granulites, with vertical
to subvertical dips. The red fenites are rocks with
banding formed of dark clinopyroxene and pale-red
layers rich in potassic feldspar. Garnet, titanite, calcite,
apatite and quartz are in small amounts. Wollastonite
can be well developed in the white fenites, associated
with potassic feldspar, garnet and apatites rich in
britholite (Fourcade et al., 1996).The compositions of carbonatites and fenites from
the Ihouhaouene massifs are characterized by high
contents in light REE (LREE), Th, U, F, Ba and Sr, but
are relatively depleted in Nb, Ta, Hf, Zr and Ti (Ou-
zegane et al., 1988; Bernard-Griffiths et al., 1988;
Fourcade et al., 1996).The emplacement of carbonatites
in the Ihouhaouene area has been dated at 1 994 ± 15
Ma by U/Pb zircon (Bernard-Griffiths et al., 1988),which confirms the earlier result of All�eegre and Caby
(1972) who obtained an age of 2 090 ± 20 Ma on a flu-
oro-apatite rich in thorium. Carbonatite emplacement is
coeval with the functioning of ductile shear zones under
granulite-facies conditions (Ouzegane et al., 1988;
Fourcade et al., 1996). The isotopic signatures in the
fenites and the carbonatites represents one of the most
particular features of the Ihouhaouene massifs. In termsof eNd (¼)6.3 to +0.9) and ISr (0.7093–0.7104) at 1994
Ma, the radiogenic isotope composition of the carbon-
atites and d18O values of metasomatic clinopyroxenes
(¼ 6.9–8&), indicate that the fluids from which they
derive underwent an intense interaction with the crust
during their ascent. The isotopic composition of carbon
(d13C¼)3.5& to +9.7&) suggests that these fluids
probably originate from the mantle by degassing ofmantle-derived magmas at great depth (Fourcade et al.,
1996). The migration of fluids through the crust via
major shear zones could have redistributed the elements
dissolved in these fluids (starting from orthogneisses
with TTG composition), particularly the LREE, K, Sr
and Th (Fourcade et al., 1996).
3. Dome and basins structure reworked by Paleoprotero-
zoic tectonics
Geologically, the In Ouzzal terrane is characterizedby NE–SW to ENE–WSW closed structures trending
that correspond to domes of enderbitic orthogneiss (Fig.
2). The supracrustal formations are made up of meta-
morphosed sedimentary rocks and mafic/ultramafic
igneous rocks that occupy the basins (Fig. 3) between
these domes (Haddoum, 1992; Haddoum et al., 1994).
In certain parts of In Ouzzal, the supracustal synforms
and orthogneiss domes exhibit linear corridors neartheir contacts corresponding to shear zones. The shear
zones are preferentially formed in quartzites and mar-
bles that are often ultramylonites (Alouki, Ihouhaoune
and Tirek). In these shear zones, the deformation related
to vertical kinematics interferes with ductile strike-slip
deformation, in which the horizontal stretching direc-
tions are superimposed on NE–SW sinistral shearing in
Alouki and ENE–WSW dextral shearing in Tin TchikTchik (Fettous, 2001). Locally, these shear zones host
granulitic pseudotachylites with orthopyroxene recrys-
tallisation occupying tiny pull-apart structures and cm-
scale gashes indicating a NE–SW stretching during
NW–SE shortening (Fettous, 2001). The formation of
these very-high-temperature pseudotachylites is proba-
bly due to the rheology of these completely dehydrated
rocks (Clarke and Norman, 1993). In the linear corri-dors, the folds are well expressed and have a sheath
geometry consistent with ductile deformation during the
transcurrent shearing (Haddoum, 1992). The folding
affects all lithologies. In the Ihouhaouene area, the fe-
nites have planar structures that are concordant with the
foliation of the surrounding granulites with horizontal
mineral lineations. The strike of the foliations is oblique
to the shear zones, thus making it possible to recognizeconjugate movements that are sinistral (NE–SW) as well
as dextral (ENE–WSW). These observations are com-
patible with the NW–SE shortening recorded in the
surrounding granulites. The emplacement of the first
generation of carbonatites occurred during this trans-
current shearing. The foliation of the fenites in the most
highly deformed domains is involved in sheath folds that
accommodate the horizontal displacements. These foldsare well studied in the mylonitic zones, being attributed
to intense deformation with a strong shearing compo-
nent. Various studies on the structures forming these
218 K. Ouzegane et al. / Journal of African Earth Sciences 37 (2003) 207–227
domes and basins (Haddoum, 1992; Haddoum et al.,1994; Fettous, 2001) suggest a strong resemblance with
structures documented in Archaean terrains such as the
Dharwar Craton in the south of India. In this latter
area, they are interpreted as being related to deforma-
tion due relative vertical displacements between gneissic
diapirs and greenstone belts rocks that are said to be
‘‘sagducted’’ (Bouhallier et al., 1995; Choukroune et al.,
1997). In the In Ouzzal terrane, the history of Paleo-proterozoic deformation was firstly interpreted in terms
of two successive stages (Haddoum et al., 1994), the first
corresponding to nappe tectonics and a second stage
characterized by faulting along transcurrent shear zones.
More recent studies (Fettous, 2001; Mahdjoub, personal
communication) refutes this and suggests that Paleo-
proterozoic tectonics consisted only of a re-activation of
earlier deformation. The structural features observed atthis level––corresponding to the base of the crust––
suggest that deformation took place entirely under
granulite-facies conditions. All the structures are com-
patible with a homogeneous NW–SE shortening (Fet-
tous, 2001). This horizontal shortening accentuates the
vertical stretching and flattening of old structures in the
form of basins and domes, which explains their elliptical
shape and their NE–SW and ENE–WSW elongation(Fig. 3). Both in the enderbitic orthogneisses and in the
metasedimentary formations, this shortening is ex-
pressed by the presence of a foliation and generally
vertical mineral stretching lineations. According to
Fettous (2001), the homogeneous shortening of the do-
mes and basins, the offset of transcurrent shear zones
and the formation of pseudotachylites would corre-
spond to three successive stages of deformation, allbeing Paleoproterozoic. However, it appears more likely
that these stages are contemporaneous. The vertical
stretching of structures is accommodated by horizontal
displacements along corridors of transpressive shearing,
as suggested by models for the formation of tectonic
domes and basins in the Dharwar Craton (Bouhallier
et al., 1993; Bouhallier et al., 1995).
4. Paleoproterozoic paragenetic evolution and metamor-
phic conditions
The ages of 2100–1950 Ma on minerals by Rb/Sr
method (All�eegre and Caby, 1972), U/Th/Pb on zircon
(Lancelot et al., 1976; Peucat et al., 1996) and Sm/Nd on
garnet (Ben Othman et al., 1984; Peucat et al., 1996)
imply that the In Ouzzal terrane acquired its metamor-
phic imprint during the Eburnean orogeny.
The granulites of In Ouzzal are particularly well
suited for the reconstruction of the metamorphic historybased on the chemical compositions of minerals and
rocks. This approach makes it possible to determine the
variations of pressure, temperature and XH2O. The esti-
mation of the conditions of pressure and temperaturehas been carried out using Al–Mg granulites (Ouzegane,
1987; Kienast and Ouzegane, 1987; Bertrand et al., 1992;
Ait Djafer, 1996; Boumaza, 1996; Mouri et al., 1996;
Ouzegane and Boumaza, 1996; Adjerid, 2002), Al–Fe
granulites (Ait Djafer, 1996; Djemai, 1996; Ouzegane
et al., 1996), corundum–magnetite quartzites (Guiraud
et al., 1996), calc-silicate granulites (Benyahia, 1996)
and garnet pyroxenites (Ouzegane, 1987; Kienast andOuzegane, 1987; Djemai, 1996). The most complete se-
quence of reactions could be identified in the alumino-
magnesian granulites, where a prograde metamorphism
is recorded under granulite-facies conditions at extreme
temperatures (Ouzegane, 1987; Kienast and Ouzegane,
1987; Bertrand et al., 1992; Ouzegane and Boumaza,
1996; Ouzegane et al., 2003). Although there is a con-
tinuum in the succession of parageneses, the metamor-phic history can be subdivided into two major stages
(Fig. 7): a prograde stage taking place at a pressure of
10–11 kbar characterized by a rise in temperature from
800 to 1050 �C, followed by a decompression from 9 to 5
kbar at temperatures close to 900–1000 �C (Ouzegane,
1987; Bertrand et al., 1992; Ouzegane and Boumaza,
1996). The prograde stage led to the development of
very-high-temperature metamorphic conditions. It ischaracterized by the significant growth of a number of
minerals and the formation of characteristic mineral
associations such as sapphirine–quartz and sapphirine–
spinel–quartz. The metamorphism during decompres-
sion is characterized by the formation of increasingly
fine-grained symplectites with cordierite, sapphirine,
orthopyroxene and spinel.
4.1. Prograde stage
This early stage, illustrated particularly in the system
FeO–MgO–Al2O3–SiO2 (FMAS), is characterized by theequilibrium of primary parageneses such as orthopy-
roxene–corundum–garnet, orthopyroxene–corundum,
garnet–spinel, garnet–spinel–corundum, garnet–quartz–
sillimanite–orthopyroxene, orthopyroxene–sillimanite
and orthopyroxene–sillimanite–quartz. In the more
complex chemical systems, occur variable amounts of
biotite, potassic feldspar, plagioclase and rutile. The
evolution of parageneses in the quartz-bearing Al–Mggranulites of In Ouzzal can be represented in a pressure–
temperature grid adapted to the FMAS system (Fig.
7). This diagram is established using the Thermocalc
software, which includes data on sapphirine (V 2.75
Holland and Powell, 1998). Ouzegane et al. (2003)
modified the sapphirine enthalpy calculated by Holland
and Powell (1998) in order to fit the curves calculated by
Thermocalc to the slopes of experimental curves deter-mined for reactions such as pyrope + corundum + spi-
nel) sapphirine (Ackermand et al., 1975). Fig. 7 shows
the position of the invariant points [Sp] and [Opx] cal-
Fig. 7. Petrogenetic grid calculated in the FMAS system using Thermocalc. The P–T paths are derived from the study of quartz-bearing rocks. See
the text for discussion.
K. Ouzegane et al. / Journal of African Earth Sciences 37 (2003) 207–227 219
culated with a H2O values of 0.3 and 0.5. In this case,
the calculated spinel invariant point (9–10.5 kbar, 1050
�C) is compatible with the experimental data of Hensen
and Green (1973), Bertrand et al. (1991) and Harley and
Motoyoshi (2000). These authors give the following
conditions for the invariant point: 10.1 ± 1 kbar at 1020
�C, 9.5 ± 1 kbar at 1030 �C and 10.5 ± 1 kbar at 1050 �C,
respectively. In quartz-bearing Al–Mg granulites, theearliest reaction is garnet + quartz) orthopyroxene +
sillimanite (Fig. 7). The conditions of crystallization
during this early stage are estimated at around 9.5–
11.5 kbar and 1000 �C, using the calibration of the
garnet–hypersthene–sillimanite–quartz equilibrium as a
geobarometer (Bertrand et al., 1992); this result is in
agreement with the T–X diagram calculated by ‘‘Ther-
mocalc’’ at a pressure of 10.5 kbar (Fig. 8A). At 10 kbarand low fO2 conditions, the metamorphic peak tem-
perature is expressed by the association sapphirine–
quartz. Bertrand et al. (1991) show that this association
is stable above 1050 �C. This paragenesis can be formed
due to the crossing of the univariant reaction orthopy-
roxene + sillimanite) garnet + sapphirine + quartz (Fig.
8A). Orthopyroxene–quartz–sapphirine symplectites
around garnet have only been observed in the quartz-ites of Tekhamalt, along with evidence for the divari-
antreaction orthopyroxene + sillimanite) sapphirine +
quartz (Rahmani, 1992; Bertrand et al., 1992; Adjerid
et al., 2002; Adjerid, 2002). These symplectites appear to
develop in chemically distinct microdomains, since
reaction products involving garnet are richer in iron
than those lacking garnet (Fig. 8A). On the P–T grid
(Fig. 7), associations with sapphirine +quartz appear to
the right of the [Sp] invariant point, thus reflecting the
highest temperatures attained in the granulites.During the sequence of early prograde reactions,
garnet becomes enriched in iron (XMg decreasing from
0.64 to 0.50) and the Al2O3 content of the orthopyrox-
ene increases. The Al2O3 content of sapphirine decreases
in relation to a substitution of the type MgSi@AlAl
(Ouzegane, 1987; Bertrand et al., 1992; Ouzegane et al.,
2003). These observations, combined with thermody-
namic calculations and the topological constraints,clearly demonstrate that the high-pressure stage (10–11
kbar) is accompanied by a significant increase in tem-
perature (from 800 to 1050 �C and Fig. 7) under isobaric
conditions (Bertrand et al., 1992; Ouzegane and
Boumaza, 1996). During formation of the sapphi-
rine + quartz association, the temperature is extreme as
shown by the low value of Kd between hypersthene and
garnet (Kd: 2.06–1.99), the high Al2O3 content of theorthopyroxene (which reaches 11.8%) and the high py-
rope content in the garnet (maximum at 50–55 mol%).
Fig. 8. T–X pseudosections calculated in the FMASH system. Prograde paths for (A) quartz-bearing Al–Mg granulites and (B) corundum-bearing
Al–Mg granulites according to their XMg bulk composition. See text for discussion.
220 K. Ouzegane et al. / Journal of African Earth Sciences 37 (2003) 207–227
Thermometry based on the Fe–Mg exchange equilib-
rium and the solubility of alumina between garnet and
orthopyroxene yields temperatures close to 970 ± 70 �Cat 10 ± 1.5 kbar (Bertrand et al., 1992). This is com-
patible with the association sapphirine–quartz and the
grids calculated by Thermocalc. In addition, the Al–Mg
granulites of Ihouhaouene show reactions involving
phlogopite at very-high-temperature (900–1000 �C)
without partial melting in a liquid-absent KFMASH
system (Mouri et al., 1993; Mouri, 1995). One of the
hypotheses proposed by Mouri et al. (1996) to explainthe stability of the phlogopite + quartz assemblage at
very high temperature––without melting––is the pres-
ence of fluorine, which stabilizes biotite under extreme
granulite-facies conditions as shown by the experimental
work of Carrington and Harley (1995). Indeed, biotites
in the Al–Mg granulites of In Ouzzal have high fluorine
contents attaining 2–4%.In Al–Mg granulites with corundum or spinel, the
earliest reactions lead to the development of sapphirine
in large crystals (1–10 cm). The corundum is separated
from the orthopyroxene by a double corona of sapphi-
rine armouring the corundum and sillimanite, thus
suggesting the reaction orthopyroxene + corundum)sapphirine + sillimanite (Ouzegane, 1987; Bertrand et al.,
1992; Ouzegane et al., 2003). At 9 kbar, the associationhypersthene–corundum–sapphirine–sillimanite provides
temperatures of 795 �C for magnesian assemblages
and 850 �C for assemblages richer in iron (Bertrand
et al., 1992), which seems to indicate an increase in
K. Ouzegane et al. / Journal of African Earth Sciences 37 (2003) 207–227 221
temperature of 55 �C under isobaric conditions. Allthe prograde reactions are characterized by equilib-
rium mineral growth and textures with triple points.
A number of very rare prograde reactions (Ouzegane,
1987; Bertrand et al., 1992; Ouzegane et al., 2003) can
proceed until the complete disappearance of corundum
or spinel. These include the reactions: orthopyroxene +
corundum) garnet + sapphirine + sillimanite (Fig. 8B),
garnet + corundum + spinel) sapphirine and garnet +spinel)sapphirine+orthopyroxene. The prograde stage
can also be recognized in the scapolite marbles of
Ihouhaouene: in the system CaO- Al2O3–SiO2-Vapour
(CASV), the growth of wollastonite takes place at the
expense of calcite + quartz via the reaction cal-
cite + quartz)wollastonite + CO2. This reaction occurs
in response to an increase in temperature from 800 up
to 1000 �C at a pressure of around 10–11 kbar (Be-nyahia, 1996; Ouzegane et al., 2002). In the banded iron
formation of Ihouhaouene, the most extreme conditions
of pressure and temperature are represented by the
association corundum–quartz, with equilibrium condi-
tions estimated at 12 kbar and 1100 �C (Guiraud et al.,
1996).
4.2. Decompression stage
All primary and intermediate associations developed
during the prograde stage are destabilized during a
metamorphic evolution characterized by a significantdrop in pressure down to 5 kbar (Ouzegane, 1987;
Bertrand et al., 1992; Mouri et al., 1996; Ouzegane and
Boumaza, 1996; Adjerid, 2002; Ouzegane et al., 2003). A
P–X diagram was constructed in the FMAS system
using the program Thermocalc (Holland and Powell,
1998). This diagram proves particularly useful in
describing the evolution of the various assemblages as a
function of XMg in the rocks during a lowering of pres-sure. We fixed an aH2O value of 0.3 for the calculation of
this diagram (Fig. 9), thus taking account of the low
water activities encountered in granulite-facies rocks.
Fig. 9 shows the successive parageneses found in Al–Mg
granulites without garnet (XMg of the rock >0.80),
granulites with garnet (XMg ranging between 0.50 and
0.80) and Al–Fe granulites (XMg: 0.30–0.40). In the most
magnesian Al–Mg granulites with quartz (XMg >0.80,Fig. 9), the orthopyroxene, sillimanite and quartz are
systematically isolated by a corona of cordierite, sug-
gesting the reaction orthopyroxene+ sillimanite +
quartz) cordierite. This reaction occurs at a pressure
around 9 kbar at a temperature of 950 �C. This is in
agreement with the work of Annersten and Seifert
(1981), who show that magnesian cordierite can be
stable up to 11 kbar at 1000 �C. However, withincreasing iron in the system, this mineral can be sta-
ble up to 9± 0.5 kbar. The reaction orthopyroxene +
sillimanite) sapphirine + cordierite, which occurs in
Al–Mg granulites with corundum (XMg of the rock canreach 0.96; Ouzegane et al., 2003) as well as in the
quartz-free microdomains of Al–Mg granulites, indi-
cates pressures similar to the preceding reaction. In Al–
Mg granulites richer in iron (XMg close to 0.80), the
earliest divariant parageneses are represented by garnet–
sapphirine–sillimanite–quartz (Fig. 9). During the fall in
pressure, reactions involving garnet, such as the divariant
reaction garnet + sillimanite ) sapphirine + cordierite,take place before the crystallization of symplectites with
cordierite-spinel (Fig. 9). In the corundum-bearing Al–
Mg granulites and the Al–Mg granulites with or without
quartz, one of the latest reactions is orthopyroxene +
sapphirine) cordierite + spinel, which occurs at around
5–6 kbar (Fig. 9). In these Al–Mg granulites, various
chemical microdomains appear reflecting the different
XMg in minerals. Thus, between 7 and 8 kbar, the reac-tion garnet + sillimanite) cordierite + sapphirine is re-
lated to microdomains richer in iron than those involved
in the reaction garnet) orthopyroxene + cordierite +
sapphirine. Al–Fe granulite textures indicate that the
cordierite coronas and cordierite-spinel symplectites
were formed by decompression via the following reac-
tions: garnet + sillimanite + quartz) cordierite, garnet +
sillimanite) cordierite + spinel, garnet + sillimanite)cordierite + spinel + quartz. The latest-stage reaction
occurs following the growth of cordierite at the expense
of spinel–quartz, in relation to a fall in temperature to
750 �C at 5–6 kbar (Kienast and Ouzegane, 1987). The
marbles of In Ouzzal allow us to constrain the role of
fluids such as CO2 during decompression. In the scapo-
lite marbles, the decompression from 10 to 5 kbar is
marked by the appearance of anorthite and calcitefollowing the breakdown of meionite. The stability of
parageneses with calcite–quartz–grossularite–meionite–
anorthite provides evidence for XCO2 lower than 0.5
(Boureghda, 2000; Ouzegane et al., 2002). In the olivine-
spinel marbles, the reaction: 2 forsterite + 4 calcite +
2CO2 ) diopside + 3 dolomite takes place at XCO2 be-
tween 0.7 and 0.9 for temperatures close to 800–900 �C(Boureghda, 2000; Ouzegane et al., 2002). It appearsclearly that the buffering of XCO2 is internal, in relation
to the onset of various reactions at different stages in the
history of these rocks. Thus, CO2 is consumed during
the prograde stage in the scapolite marbles by the reac-
tion grossularite +CO2 ) 3 wollastonite + 2 calcite +
meionite. On the other hand, CO2 is released during the
late stages by the reaction meionite + 5 wollastonite) 3
grossularite + 2 quartz + CO2, at the same time as garnetcoronas are developed in association with quartz (Be-
nyahia, 1996; Ouzegane et al., 2002). As in the Archaean
marbles of Antarctica (Fitzsimons and Harley, 1994),
there is no exchange of CO2 between the surrounding
charnockitic rocks and the marbles, the latter behaving
like a closed system. This is in agreement with the very
heterogeneous isotopic signatures of these marbles,
P (
kbar
)
Fig. 9. P–X pseudosection calculated in the FMASH system for quartz-bearing, quartz-free Al–Mg granulites and Al–Fe granulites. The decom-
pression paths are drawn according to XMg bulk-rock composition. See the text for discussion.
222 K. Ouzegane et al. / Journal of African Earth Sciences 37 (2003) 207–227
which indicate they have preserved their pre-metamor-
phic features (Fourcade et al., 1996).
5. Interpretation and conclusion
The In Ouzzal terrane represents an Archaean block
reactivated in the Paleoproterozoic, which enables us
to investigate magmatic, metamorphic and structuralfeatures specific to the Archaean period and propose
a model for the formation of very-high-temperature
Paleoproterozoic granulites.
5.1. Archaean evolution (3.3–2.5 Ga)
Archaean geodynamic evolution can be approached
primarily owing to geochemical and geochronological
data obtained on the granitic rocks. The sialic material
of the In Ouzzal terrane was mostly formed during the
early Archaean, as shown by the TDM model ages which
are older than 3 Ga for all the felsic rocks of igneous
origin (All�eegre and Caby, 1972; Lancelot et al., 1976;
Ben Othman et al., 1984; Peucat et al., 1996). The oldestrocks dated in the In Ouzzal terrane are enderbitic or-
thogneisses of tonalitic and trondhjemitic composition
sampled from the areas of Tin Tchik Tchik and Roccan,
which yield ages around 3.3–3.2 Ga (U/Pb zircon, Peu-
cat et al., 1996). The isotopic data indicate that the
igneous suites correspond to juvenile material. Such a
sialic crust, made up of TTG and rocks of andesitic
affinity, was probably formed by accretion of island arcs
in a scenario resembling that of present-day plate tec-
tonics (Choukroune et al., 1997; De Wit, 1998). A new
suite of TTG was emplaced at 2.7 Ga. The isotopic dataon these TTG suggest the reworking––at least partial––
of an older crust (Nd model ages¼ 3.3 Ga) that could
have been formed during an earlier stage. Towards 2.65
Ga, A-type granites were emplaced with the chemical
signatures of rift-related granites. The mafic and ultra-
mafic granulites of In Hihaou, could also be of this age.
Detrital zircons yielding ages of 2.7 Ga in the metase-
dimentary rocks and the formation of skarns at thecontact between the marbles and the A-type granites
(2.65 Ga, U/Pb zircon) make it possible to date the
deposition of the metasedimentary formations at about
this period.
The presence of calc-alkaline granites of type CA1
and CA2, dated at 2.5 Ga (U/Pb zircon) reflects the
melting of a lower and middle crust showing a tona-
litic affinity acquired during the preceding stages andtransformed into granulites (Peucat et al., 1996). The
development of domes and basins structures during
K. Ouzegane et al. / Journal of African Earth Sciences 37 (2003) 207–227 223
homogeneous shortening at this stage fits with the modelof deformation of the Archaean crust proposed by
Bouhallier et al. (1995) and Choukroune et al. (1997) for
the Dharwar Craton in India.
5.2. Extreme metamorphic conditions during the Paleo-
proterozoic (2 Ga)
Because of the particular features displayed by the
IOGU, we cannot apply the simple model of a meta-
morphic belt formed by continental collision as in
modern mountain belts. The In Ouzzal terrane presentsa number of particularities, including: very-high-tem-
perature metamorphism up to 1100 �C (Kienast et al.,
1996; Guiraud et al., 1996; Ouzegane and Boumaza,
Fig. 10. Cartoons showing preferred models for the tectono-metamorphic evo
lithospheric thermal barrier and uprise of asthenosphere during an Eburnean
characteristic parageneses are also shown.
1996; Harley, 1998), limited partial melting despite thehigh temperatures involved, a style of deformation
comparable with that observed in Dharwar type (India)
Archaean cratons, the emplacement of syn-granulite-
facies carbonatites with a very peculiar geochemistry,
and the presence of anorthosites. The major question
posed by the development of the In Ouzzal granulitic
terrane during the Paleoproterozoic, with its extreme
metamorphic conditions, concerns the heat source forthis very-high-temperature event. Some other questions
are linked, such as the relationships that might exist
between anorthosites, carbonatites and the very-high-
temperature metamorphism, as well as the regional
tectonic style associated with the metamorphism. The
syn-granulite-facies deformation of In Ouzzal provides
lution and emplacement of carbonatites subsequent to delamination of
event in the In Ouzzal granulitic terrane. Evolution of P–T paths and
224 K. Ouzegane et al. / Journal of African Earth Sciences 37 (2003) 207–227
evidence for a homogeneous NW–SE shortening. Thestructures indicate a re-activation of Archaean vertical
stretching of the domes and basins, marked by the
vertical foliation observed in lithologies making up
these structures. The accentuation of this stretching is
compatible with a homogeneous shortening, trending
NW–SE on the regional scale, and accommodated by
transpressive shear zone corridors. We suggest that an
orogenic episode occurred at �2.1–2.0 Ga, during whichthe lower crust underwent homogeneous shortening. At
the same time, there was an extreme heating event re-
lated to an upwelling of the asthenosphere (Fig. 10). The
study of the Paleoproterozoic granulite-facies meta-
morphism of In Ouzzal indicates a clockwise P–T path
with an increase of temperature at constant pressure
(800–1050 �C, 10–11 kbar), followed by an isothermal
evolution with a significant fall in pressure (9–5 kbar).Based on these metamorphic data, we propose an evo-
lution for the In Ouzzal terrane in three principal epi-
sodes or stages (Fig. 10).
• The first stage corresponds to a continuation of Ar-
chaean domes and basins tectonics, which became
accentuated with time. During this stage, the block
must undergo both shortening and thickening (Fig.10, stage 1). The metamorphic evolution results in
an increase of pressure (up to 10 kbar) for classical
temperatures in the granulite-facies at the base of
the crust (700–800 �C).
• From the metamorphic point of view, the following
stage (Fig. 10, stage 2) is of fundamental importance,
since during this episode the In Ouzzal lower crust
underwent a strong reheating leading to extreme tem-peratures (up to 1100 �C) at constant pressure or in
slight decompression. Such temperatures, even at
the base of the crust, imply a considerable heat con-
tribution from depth, most probably linked to an
upwelling of the asthenosphere contemporary with
an important delamination of the lithospheric man-
tle. To bring the lower crust at T > 1000 �C, this
could be a result of frontal hypercollision that couldremove completely the lithospheric mantle bringing
the asthenosphere (1300 �C) close to the Moho (Black
and Li�eegeois, 1993). However, the crust became dehy-
drated during several periods of Archaean melting.
As a result, the crust is no longer fertile and cannot
undergo significant partial melting. Since heat is no
longer taken up by the formation of granites, the tem-
perature is not buffered to a maximum value by melt-ing processes around 700 �C or 800 �C. Therefore,
heat will be able to diffuse without any hindrance
and lead to extreme conditions of metamorphism
(this mechanism was already suggested by Vielzeuf
et al., 1990).
• As illustrated on Fig. 10, stage 3 represents the set of
phenomena preceding the exhumation of the oro-
genic belt. Indeed, such an important upwelling ofthe asthenosphere associated with greatly enhanced
heat flow is generally accompanied by extensional
tectonics. Although the importance of this extension
is difficult to assess in the In Ouzzal terrane, it may
be expressed by the emplacement of anorthosites
and carbonatites related to shear zones channelling
the ascent of CO2-rich fluids characteristic of the
mantle. Thus, the extreme metamorphic temperaturesas well as the presence of anorthosites and carbona-
tites would represent the effects of a phenomenon
whose timing remains to be defined. However, a ther-
mal anomaly of this magnitude is evidently unstable,
which necessarily implies a return to a more normal
regime characterized by a fall in temperature coupled
with decompression. This stage of decompression,
recorded in all the In Ouzzal formations, could corre-spond to the stress relaxation and isostatic re-equili-
bration that accompanies the recovery of the
lithospheric mantle during the post-collisional post-
orogenic quieter conditions, leading back to the re-
establishement of a thick cratonic lithosphere and
thus to the thermal equilibrium state (Black and
Li�eegeois, 1993), that will protect the In Ouzzal ter-
rane during the Pan-African orogeny.
Acknowledgements
We are indebted to J.P. Li�eegeois and M. De Wit for
detailed and constructive reviews. M.S.N. Carpenter
and J. Boissonnas are thanked for improving the Eng-
lish. This work was financed by cooperative programmebetween the Universities of Algiers (USTHB), and Paris
7 (00 MDU 476 ‘‘H�eeritage �eeburn�eeen et structuration
pan-africaine du Hoggar: �eetude g�eeologique et g�eeophy-
sique), and by ORGM in Algeria for logistic support
during field work’’. We are also extremely grateful for
the support of ICESA project.
References
Acef, K., Ouzegane, K., Kienast, J.R., 2001. Archean alkaline
charnockitic gneisses in the In Ouzzal granulitic Unit West Hoggar,
Algeria: evidence of pyrochlore and chevkinite. Special Abstract
Issue, EUG XI Strasbourg, France 571.
Ackermand, D., Seifert, F., Schreyer, W., 1975. Instability of
sapphirine at high pressures. Contribution to Mineralogy and
Petrology 50, 79–92.
Adjerid, Z., 2002. Traitement d’images (MEB) et �eequilibre des
r�eeactions dans les granulites de tr�ees haute temp�eerature de l’In
Ouzzal (Hoggar, Alg�eerie): exemple de la d�eestabilisation du grenat,
de la biotite et de l’osumilite. Unpublished Magister U.S.T.H.B.,
Alger, Algerie, 150 p.
Adjerid, Z., Ouzegane, K., Godard, G., Kienast, J.R., 2002. Les
paragen�eeses �aa quartz–saphirine–spinelle, l’autre �eevidence d’un
m�eetamorphisme extreme en temp�eerature, au cours de l’�eevolution
K. Ouzegane et al. / Journal of African Earth Sciences 37 (2003) 207–227 225
de l’unit�ee granulitique de l’In Ouzzal. Hoggar Occidental, Alg�eerie.20 �eeme R�eeunion des Sciences de la Terre, Nantes, France 45.
Ait Djafer, S., 1996. Relation cristallisation fusion et cheminement
pression temp�eerature dans les migmatites de l’In Ouzzal NW
Hoggar. Unpublished Magister, U.S.T.H.B., Alger, Alg�eerie, 188 p.,
unpublished.
Ait Djafer, S., Ouzegane, K., 1998. Fusion partielle et relation de
phases dans les granulites Al–Fe �aa hercynite–quartz d’Ihouhaou-
ene, In Ouzzal, Ouest Hoggar. Bulletin du Service de la Carte
g�eeologique de l’Algrie 9, 43–67.
A€ııt-Djafer, S., Ouzegane, K. Li�eegeois, J.P., Kienast, J.R., in prepa-
ration. Petrology and geochemistry of archean anorthositic
complexes from the In Ouzzal granulitic terrane (NW Hoggar,
Algeria).
All�eegre, C., Caby, R., 1972. Chronologie absolue du Pr�eecambrien de
l’Ahaggar occidental. Comptes Rendus de l’Acad�eemie des Sciences,
Paris 275, 2095–2098.
Anderson, J.L., 1983. Proterozoic anorogenic granite plutonism of
North America. In: Medaris, L.G., Byers, C.W., Mickelson, D.M.,
Shanks, W.C. (Eds.), Proterozoic Geology: Selected Papers from
an International Proterozoic Symposium, vol. 161. Geological
Society America, pp. 133–154.
Annersten, N., Seifert, F., 1981. Stability of the assemblage orthopy-
roxene–sillimanite–quartz in the system MgO–FeO–Al2O3–SiO2–
H2O. Contribution to Mineralogy and Petrology 77, 158–165.
Arndt, N.T., 1998. Magmatisme ultrabasique et basique au Pr�eecamb-
rien. In: Hagemann, R., Treuil, M. (Eds.), Introduction �aa la
g�eeochimie et ses applications. CEA.
Ashwal, L.D., 1993. Anorthosites. Springer-Verlag, Berlin. 422 p.
Attoum, A., 1983. Etude g�eeologique et structurale des mylonites Pan-
africaines et des min�eeralisations aurif�eeres associ�eees dans le secteur
de Tirek Hoggar, Alg�eerie. Th�eese 3�eeme cycle Montpellier, France
98.
Badani-Djebloun, A., 1998. P�eetrologie, cheminement pression-
temp�eerature et g�eeochimie des formations ferrif�eeres �aa hercynite–
quartz–corindon et ferrosilite de l’unit�ee granulitique de l’In Ouzzal
NW Hoggar. Unpublished Magister, U.S.T.H.B. Alger, Al�eeger,
128 p.
Badani-Djebloun, A., Ait Djafer, S., Ouzegane, K., Kienast, J.R.,
2000. P�eetrologie et g�eeochimie des formations ferrif�eeres de l’unit�ee
granulitique de l’In Ouzzal NW Hoggar. 18�eeme R�eeunion des
Sciences de la Terre, Paris, France 73.
Barker, F., 1979. Trondhjemite: definition, environment and hypoth-
esis of origin. In: Barker, F. (Ed.), Trondhjemites, Dacites and
Related Rocks. Amsterdam, Elsevier, pp. 1–12.
Bendaoud, A., Ouzegane, K., Kienast, J.R., 2001. The Archaean basic
and ultrabasic rocks of the In Ouzzal granulitic Unit Western
Hoggar, Algeria. Special Abstract Issue, EUG XI Strasbourg,
France 570.
Bendaoud, A., Ouzegane, K., Kienast, J.R., 2002. Mise en�eevidence
d’une s�eerie komatiitique de type Munro dans la r�eegion d’In Hihaou
In Ouzzal, Hoggar Occidental, Alg�eerie. 20 �eeme R�eeunion des
Sciences de la Terre Nantes, France 63.
Ben Othman, D., Polv�ee, M., Allegre, C.J., 1984. Nd–Sr isotopic
composition of granulites and constraints on the evolution of the
lower continental crust. Nature 307, 510–515.
Benyahia, O., 1996. Les granulites �aa silicates calciques dumoole In
Ouzzal NW Hoggar: Min�eeralogie g�eeochimie et relation de phases.
Unpublished Magister, U.S.T.H.B., Alger, Alg�eerie, 110 p.
Benyahia-Boumaza, S., Ouzegane, K., Godard, G., Kienast, J.R., in
preparation. Petrology of musgravite–sapphirine–pyrochlore bear-
ing Al–Mg–Ca granulites from Alouki area (In Ouzzal terrane,
NW Hoggar, Algeria).
Bernard-Griffiths, J., Peucat, J.J., Fourcade, S., Kienast, J.R., Ouzeg-
ane, K., 1988. Origin and evolution of a 2 Ga old syenite–
carbonatite complex Ihouhaouene, Ahaggar. Contribution to
Mineralogy and Petrology 100, 339–348.
Bernard-Griffiths, J., Fourcade, S., Kienast, J.R., Peucat, J.J., Mar-
tineau, F., Rahmani, A., 1996. Geochemistry and isotope Sr, Nd,
O study of Al–Mg granulites from the In Ouzzal Archaean
block Hoggar, Algeria. Journal of Metamorphic Geology 14, 709–
724.
Bertrand, P., Ellis, D.J., Green, D.H., 1991. The stability of sapphi-
rine–quartz and hypersthene–quartz assemblages: an experimental
investigation of the system FeO–MgO–Al2O3–SiO2 under H2O and
CO2 conditions. Contributions to Mineralogy and Petrology 108,
55–71.
Bertrand, P., Ouzegane, K., Kienast, J.R., 1992. P–T–X relationships
in the Precambrian Al–Mg rich granulites from In Ouzzal, Hoggar,
Algeria. Journal of Metamorphic Geology 10, 17–31.
Black, R., Li�eegeois, J.P., 1993. Cratons, mobile belts, alkaline rocks
and continental lithospheric mantle: the Pan-African testimony.
Journal of Geological Society of London 150, 89–98.
Black, R., Latouche, L., Li�eegeois, J.P., Caby, R., Bertrand, J.M., 1994.
Pan-African displaced terranes in the Tuareg shield (central
Sahara). Geology 22, 641–644.
Bonin, B., Azzouni-Sekkal, A., Bussy, F., Fellag, S., 1998. Alkali–
calcic and alkaline post-orogenic (PO) granite magmatism: petro-
logic constraints and geodynamic settings. Lithos 45, 45–70.
Bouhallier, H., Choukroune, P., Ball�eevre, M., 1993. Diapirism,
bulk homogeneous shortening and transcurrent shearing in the
Archaean Dharwar craton: the Holenarsipur area, southern India.
Precambrian Research 63, 43–58.
Bouhallier, H., Chardon, D., Choukroune, P., 1995. Strains patterns in
Archaean domes-and-basin structures: The Dharwar craton Kar-
nataka, South India. Earth and Planetary Sciences Letters 135, 57–
76.
Boumaza, S., 1996. P�eetrologie d’un nodule migmatitique �aa saphirine
d’In Hihaou In Ouzzal, Hoggar occidental: diffusion chimique et
comparaison avec les granulites Al–Mg de l’encaissant. Unpub-
lished Magister, U.S.T.H.B., Alger, Alg�eerie, 200 p.
Boumaza-Benyahia, S., Ouzegane, K., Fialin, M., Kienast, J.R., 2001.
Occurrence of Musgravite, an unusual beryllium oxide, in the calc-
silicates granulites from In Ouzzal. Special Abstract Issue, EUG XI
Strasbourg, France 571.
Boureghda, N., 2000. P�eetrographie, min�eeralogie et thermobarom�eetrie
des marbres de l’unit�ee granulitique de l’In Ouzzal Ouest Hoggar.
Unpublished Magister U.S.T.H.B., Alger, Alg�eerie, 154 p.
Boynton, W.V., 1984. Cosmochemistry of the rare earth elements:
meteorite studies. In: Henderson, P. (Ed.), Rare Earth Element
Geochemistry. Elsevier, pp. 63–107.
Caby, R., 1970. La chaine Pharusienne dans le NW de l’Ahaggar
Central Sahara, Al�eegrie: sa place dans l’orogen�eese du Precambrien
sup�eerieur en Afrique. Th�eese de Doctorat d’Etat, Montpellier,
Publication de la Direction des Mines et de la G�eeologie, Alger, 47,
289 p.
Caby, R., 1996. A review of the In Ouzzal granulitic terrane, Tuareg
shield, Algeria: its significance within the Pan-African Trans-
Saharan Belt. Journal of Metamorphic Geology 14, 659–666.
Caby, R., Moni�ee, P., 2003. Multiple subduction and differential
exhumation of Western Hoggar (southwest Algeria): new struc-
tural, petrological and geochronological evidence. Journal of
African Earth Sciences, this issue.
Carrington, D.P., Harley, S.L., 1995. Partial melting and phase
relations in high grade metapelites: an experimental petrogenetic
grid in the KFMAH system. Contributions to Mineralogy Petro-
logy 120, 270–291.
Carpena, J., Kienast, J.R., Ouzegane, K., Jehanno, C., 1988. Apatites
from In Ouzzal carbonatites NW Hoggar: the final thermal history
of an Archean basement. Geological Society of American Bulletin
100, 1237–1248.
Choukroune, P., Ludden, J.N., Chardon, D., Calvert, A.J., Bouhallier,
H., 1997. Archaean growth and tectonic processes: a comparaison
of the Superior province, Canada and the Dharwar Craton, India.
226 K. Ouzegane et al. / Journal of African Earth Sciences 37 (2003) 207–227
In: Burg, J.P., Ford, M. (Eds.), Orogeny Through Time, vol. 121.
Geological Society, pp. 63–98. Special Publication.
Clarke, G.L., Norman, A.R., 1993. Generation of pseudotachyllite
under granulite facies conditions and its preservation during
cooling. Journal of Metamorphic Geology 11, 319–335.
Condie, K.C., 1997. Plate Tectonics and Crustal Evolution. Oxford,
Butterworth Heinemann. 282 p.
Creaser, R.A., Price, R.C., Wormald, R.J., 1991. A-type granites
revisited: assessment of a residual-source model. Geology 19, 163–
166.
De Wit, M.J., 1998. On Archean granites, greenstones, cratons and
tectonics: does the evidence demand a verdict? Precambrian
Research 91, 181–226.
Djemai, S., 1996. Les pyrigarnites et les granulites alumineuses
d’Amesmessa, MOOle In Ouzzal, Hoggar: Relations de phases et
d�eeformation. Unpublished Magister U.S.T.H.B., Alger, Al�eegrie,
210 p.
Eby, G.N., 1992. Chemical subdivision of the A-type granito€ııds:
petrogenesis and tectonic implication. Geology 20, 641–644.
Eriksson, K.A., Krapez, B., Fralick, P.W., 1997. Sedimentological
aspects. In: De Wit, M., Ashwal, L.D. (Eds.), Oxford Monographs
on Geology and Geophysics, vol. 35, pp. 33–54.
Fettous, H., 2001. Les cisaillements lithosph�eeriques en conditions
anhydres et hydat�eees: exemple du Hoggar-Al�eegrie. Magister,
Unpublished USTHB, Alger, Alg�eerie, 220 p.
Fitzsimons, I.C.W., Harley, S.L., 1994. Garnet coronas in scapolite–
wollastonite calc-silicates from East Antarctica: the application and
limitations of activity corrected grids. Journal of Metamorphic
Geology 12, 761–777.
Fourcade, S., Kienast, J.R., Ouzegane, K., 1996. Metasomatic effects
related to channeled fluid streaming through deep crust: fenites
and associated carbonatites In Ouzzal Proterozoic granulites,
Hoggar, Algeria. Journal of Metamorphic Geology 14, 763–
781.
Giraud, P., 1961. Les charnockites et les roches associ�eees au suggarien
�aa faci�ees In Ouzzal, Sahara central. Bulletin de la Soc�eeit�ee G�eeolog-
ique de France 3, 165–170.
Goscombe, B., 1992. High-grade reworking of central Australian
granulites: metamorphic evolution of the Arunta complex. Journal
of Petrology 33, 917–962.
Gruau, G., Tourpin, S., Fourcade, S., Blais, S., 1992. Loss of isotopic
Nd, O and chemical REE memory during metamorphism of
komatiites: new evidences from eastern Finland. Contributions to
Mineralogy and Petrology 112, 66–82.
Guiraud, M., Kienast, J.R., Ouzegane, K., 1996. Corundum–quartz
bearing assemblage in the Ihouhaouene area In Ouzzal, Algeria.
Journal of Metamorphic Geology 14, 755–761.
Haddoum, H., 1992. Etude structurale des terrains arch�eeensdu moole In
Ouzzal Hoggar occidental, Alg�eerie. Unpublished Th�eese de Docto-
rat d’�eetat U.S.T.H.B., Alger, Alg�eerie, 214 p.
Haddoum, H., Choukroune, P., Peucat, J.J., 1994. Structural evolu-
tion of the Precambrian In Ouzzal massif, Central Sahara, Algeria.
Precambrian Research 65, 155–166.
Hadj-Kaddour, Z., Li�eegeois, J.P., Demaiffe, D., Caby, R., 1998. The
alkaline–peralkaline granitic post-collisional Tin Zebane dyke
swarm (Pan-African Tuareg shield, Algeria): prevalent mantle
signature and late agpaitic differentiation. Lithos 45, 223–243.
Harley, S.L., 1998. On the occurrence and characterization of
ultrahigh-temperature crustal metamorphism. In: Treolar, P.J., O’
Brien, P.J. (Eds.), What Drives Metamorphism and Metamorphic
Reactions?, vol. 138. Geological Society, pp. 81–107. Special
Publication.
Harley, S.L., Motoyoshi, Y., 2000. Al zoning in orthopyroxene in a
sapphirine quartzite: evidence for >1200 �C UHT metamorphism
in the Napier complex, Antarctica, and implications for the
entropy of sapphirine. Contributions to Mineralogy and Petrology
138, 293–307.
Helal, B., 1987. Etude p�eetrographique etg�eeochronologique d’une
quartzite ferrif�eere de l’Arch�eeen du bouclier Touareg In Ouzzal,
Alg�eerie. D.E.A Paris VI, 76 p.
Hensen, B.J., Green, D.H., 1973. Experimental study of the stability of
cordierite and garnet in pelitic compositions at high pressures and
temperaratures. III. Synthesis of experimental data and geological
applications. Contributions to Mineralogy and Petrology 38,
151–166.
Holland, T.J.B., Powell, R., 1998. An internally-consistent thermody-
namique data set for phases of petrological interest. Journal of
Metamorphic Geology 16, 309–343.
Kienast, J.R., Ouzegane, K., 1987. Polymetamorphic Al–Mg rich
parageneses in Archean rocks from Hoggar, Algeria. In: Kinnaird,
J., Bowden, P. (Eds.), African Geology Reviews, vol. 22. Wiley, J,
pp. 57–79.
Kienast, J.R., Fourcade, S., Guiraud, M., Hensen, B.J., Ouzegane, K.
(Eds.), 1996. Special Issue on the In Ouzzal Granulite Unit,
Hoggar, Algeria Journal of Metamorphic Geology 14, 659–808.
Lancelot, J.R., Vitrac, A., Allegre, C.J., 1976. Uranium and lead
isotopic dating with grain-by grain zircon analysis: a study of a
complex geological history with a single rock. Earth and Planetary
Science Letters 29, 357–366.
Lassel, K., 1990. Les gneiss charnockitiques du socle arch�eeen de l’In
Ouzzal. P�eetrologie, isotopes stables et inclusions fluides. D.E.A
Paris VII, France 70 p.
Le Fur, Y., 1966. Nouvelles observations sur la structure de
l’ant�eecambrien du Hoggar nord occidental, r�eegion d’In Hihaou.
Th�eese de trois�eeme cycle, Nancy, France.
Lelubre, M., 1952. Recherches sur la g�eeologie de l’Ahaggar central et
occidental, Sahara central. Thse d’�EEtat, Paris, tome 1, 354 p., tome
2, 385 p.
Li�eegeois, J.P., Navez, J., Hertogen, J., Black, R., 1998. Contrasting
origin of post-collisional high-K calc-alkaline and shoshonitic
versus alkaline and peralkaline granitoids. The use of sliding
normalization. Lithos 45, 1–28.
McDonough, W.F., Sun, S.S., Ringwood, A.E., Jagoutz, E., Hof-
mann, A.W., 1992. Potassium, rubidium, and cesium in the Earth
and Moon and the evolution of the mantle of the Earth.
Geochimica et Cosmochimica Acta 56, 1001–1012.
Mouri, H., 1995. Relations de phases th�eeoriques et naturelles dans le
syst�eeme KFMASH: exemple des granulites Al–Mg d’Ihouhaouene
Moole In Ouzzal, Hoggar, Alg�eerie. Th�eese de Doctorat de l’Univer-
sit�ee Paris VII, France, 210 p.
Mouri, H., Guiraud, M., Kienast, J.R., 1993. Al–Mg granulites of
Ihouhaouene, Hoggar, Algeria: an example of phase relationships
in the KFMASH system and melt absent equilibria. Comptes
Rendus de l’ Acad�eemie des Sciences Paris 316, 1565–1572.
Mouri, H., Guiraud, M., Hensen, B.J., 1996. Petrology of phlogopite–
sapphirine––bearing Al–Mg granulites from Ihouhaouene Mole
In Ouzzal-Hoggar Algeria: an example of phlogopite stable
at high temperature. Journal of metamorphic Geology 14, 725–
738.
Moussine-Pouchkine, A., Bertrand-Sarfati, J., Ball, E., Caby, R., 1988.
Les s�eeries s�eedimentaires et volcaniques anorog�eeniques
prot�eerozo€ııques impliqu�eees dans la chaııne Pan-Africaine: la r�eegion
de l’Adrar Ahnet, NW Hoggar, Alg�eerie. Journal of African Earth
Sciences 7, 57–75.
Ouzegane, K., 1987. Les granulites Al–Mg et les carbonatites dans la
s�eerie de l’In Ouzzal NW Hoggar, Alg�eerie. Nature et �eevolution de la
crouute continentale profonde pendant l’arch�eeen. Th�eese d’Etat,
Paris VII, France, 433 p.
Ouzegane, K., Boumaza, S., 1996. An example of very high temper-
ature metamorphism: orthopyroxene–sillimanite–garnet, sapphi-
rine–quartz, and spinel–quartz. Journal of Metamorphic Geology
14, 693–708.
Ouzegane, K., Kienast, J.R., 1996. Nature et �eevolution des s�eeries
m�eetamorphiques de tr�ees haute temp�eerature del’Unit�ee Granulitique
K. Ouzegane et al. / Journal of African Earth Sciences 37 (2003) 207–227 227
de l’In Ouzzal Ouest Hoggar. Bulletin du Service G�eeologique de
l’Alg�eerie 7, 133–157.
Ouzegane, K., Fourcade, S., Kienast, J.R., Javoy, M., 1988. New
carbonatites complexes in the archean In Ouzzal nucleus Ahaggar,
Algeria. Mineralogical and geochimical data. Contribution to
Mineralogy and Petrology 98, 277–292.
Ouzegane, K., Djemai, S., Guiraud, M., 1996. Gedrite garnet
sillimanite bearing granulites from Amesmessa area, south In
Ouzzal, Hoggar, Algeria. Journal of Metamorphic Geology 14,
739–753.
Ouzegane, K., Benyahia, O., Boureghda, N., Kienast, J.R., 2002.
Petrology of Archean marbles from the In Ouzzal granulitic terrane
western Hoggar, Algeria: an example of calcite–quartz–scapolite
and calcite–dolomite parageneses at very high temperatures. In:
Sixth International Conference On the Geology of the Arab World,
Cairo, Egypt, p. 19.
Ouzegane, K., Guiraud, M., Kienast, J.R., 2003. Prograde and
retrograde evolution in high temperature corundum granulites.
FMAS and KFMASH systems from In Ouzzal terrane, NW
Hoggar, Algeria. Journal of Petrology 44, 517–545.
Peucat, J.J., Capdevila, R., Drareni, A., Choukroune, P., Fanning, M.,
Bernard-Griffiths, J., Fourcade, S., 1996. Major and trace element
geochemistry and isotope Sr, Nd, Pb, O systematics of an Archaean
basement involved in a 2.0 Ga VHT 1000 C metamorphic event: In
Ouzzal massif, Hoggar, Algeria. Journal of Metamorphic Geology
14, 667–692.
Picciotto, E., Ledent, D., Lay, C., 1965. Etude g�eeochronologique de
quelques roches du socle cristallophyllien du Hoggar Sahara
central. Actes 151e Colloque Interne C.N.R.S. G�eeochronologie
absolue, pp. 277–289.
Rahmani, A., 1992. P�eetrologie et g�eeochimie de la serie granulitique du
massif du Khanfous In Ouzzal, Hoggar, Alg�eerie. Doctorat de
l’Universit�ee Paris VI, France, 204 p.
Robinson, P., Jaffe, H.W., 1969. Chemographic exploration of amphi-
bole assemblages from central Massachussets and Southwest New
Hamphshire. Mineral Society America Special Paper 2, 251–274.
Semiani, A., 1995. M�eetallog�eenie de la zone de cisaillement aurifre est-
ouzzalienne: structure, p�eetrologie et g�eeochimie des gisements d’or
de Tirek-Amesmessa Hoggar occidental, Alg�eerie. Th�eese Doctorat
de l’Universit�ee de Rennes I, France, 262 p.
Spear, F.S., 1982. Phase equilibria of amphibolites from the Post Pond
volcanics, Mt Cube quadrangle, Vermont. Journal of Petrology 23,
383–426.
Spear, F.S., 1993. Metamorphic phase equilibria and pressure–
temperature–time paths. In: Monograph Series. Mineralogical
Society of America, Chelsea, Michigan, USA. 799 p.
Sylvester, P.J., 1994. Archean granite plutons. In: Condie, K.C. (Ed.),
Archean Crustal Evolution, vol. 11. Elsevier, Amsterdam, pp. 261–
314.
Vielzeuf, D., Clemens, J.D., Pin, C., Moinet, E., 1990. Granites,
granulites, and crustal differentiation. In: Vielzeuf, D., Vidal, Ph.
(Eds.), Granulites and Crustal Evolution. NATO, pp. 59–85.