a. table of contents - foam update · econcore, dupont performance materials collaborate on...

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Foam Update June 2016 To Give Than To Receive - 1 - A. Table of Contents Contents A. Table of Content ............................................................................. 1 B. Editorial ........................................................................................... 2 C. News ................................................................................................ 4 D. Patents and Journals ..................................................................... 11 a. New Foaming Technique: .................................................... 11 b. Blowing Agents: .................................................................. 11 c. Foam products:..................................................................... 12 d. Applications: ........................................................................ 15 e. Degradable and Sustainable Foam: ..................................... 19 f. Thermoset Foam; PU and Others: ........................................ 19 g. Microcellular and Expanded Particle: ................................. 21

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Page 1: A. Table of Contents - Foam Update · ECONCORE, DUPONT PERFORMANCE MATERIALS COLLABORATE ON PRODUCTION OF HONEYCOMB PANELS Author(s) Laird, K. Sources Plastics Today Corporate/Assignee

Foam Update

June 2016

To Give Than To Receive - 1 -

A. Table of Contents

Contents

A. Table of Content ............................................................................. 1

B. Editorial ........................................................................................... 2

C. News ................................................................................................ 4

D. Patents and Journals ..................................................................... 11

a. New Foaming Technique: .................................................... 11

b. Blowing Agents: .................................................................. 11

c. Foam products: ..................................................................... 12

d. Applications: ........................................................................ 15

e. Degradable and Sustainable Foam: ..................................... 19

f. Thermoset Foam; PU and Others: ........................................ 19

g. Microcellular and Expanded Particle: ................................. 21

Page 2: A. Table of Contents - Foam Update · ECONCORE, DUPONT PERFORMANCE MATERIALS COLLABORATE ON PRODUCTION OF HONEYCOMB PANELS Author(s) Laird, K. Sources Plastics Today Corporate/Assignee

Foam Update

June 2016

To Give Than To Receive - 2 -

B. Editorial

Engineered Polymers in Foam Extrusion

Energy management has been a global subject in the last two decades not only

for petroleum source but also for carbon cycle. There is only one earth; no

room for negotiation. International collaboration platform was in place and

continued to become more complex. It sure affected plastics industry in

different ways. For polymeric foam, it is, in general, more like opportunity than

setback. Blowing agent emission has no doubt been a burden for lot of foam

producers. However, it encouraged more research and development making

energy management more appealing. Foam became a popular core material

with skin as a sandwich composite for wind blade first, then lightweighting in

the market segment dominated by fiber reinforced polymers. In the editorial of

Aug. 2015, amorphous polyetherimide (PEI) foam was discussed in the aircraft

interior application. Under Ultem®, Sabic offered extruded PEI foam board

made with chemical blowing agent which not only expands but plasticizes PEI

to accomplish 20 times expansion in the extrusion process. Sabic also offers

Ultem® honeycomb for similar applications. Fig. 1 shows the extruded PEI

plank product.

Solvay offers extruded closed-cell polyphenylsulfone (PPSU) foam board and

sheet with density around 3 lbs/ft3, or ≈ 50 kg/m3. PPSU’s chemical structure

is presented in Fig. 2. This amorphous polymer has a density of 1.29 g/cm3.

This material exhibits thermal insulation properties better than low density

polyethylene plank, yet it shows thermal stability at prolonged exposure to

temperatures ranging from -40 oC to 204 oC. This thermoplastic foam board

possesses high mechanical modulus, thermoformability, and excellent damage

tolerance and fire resistance. Its ductility as illustrated in Fig. 3 can avoid

scoring which is necessary for most rigid structural foam; such as X-PVC foam.

Fig. 1: Extruded PEI plank at 25 times expansion and 2.5cm

in thickness

Page 3: A. Table of Contents - Foam Update · ECONCORE, DUPONT PERFORMANCE MATERIALS COLLABORATE ON PRODUCTION OF HONEYCOMB PANELS Author(s) Laird, K. Sources Plastics Today Corporate/Assignee

Foam Update

June 2016

To Give Than To Receive - 3 -

For years, Solvay partnered with 3A Composite in structural applications. In

early 2016, this PPSU foam under TegraCoreTM obtained qualification

approval from Airbus to implement on its A350 XWB as a performance

lightweight material. The current challenge is in the die tooling and extrusion

processing to improve cell size and its uniformity, and more expansion.

Encountering challenge is inevitable in the civilization process. Determination

to overcome is a true character to survive, through which we all become

humble. Truly, it is from the surrounding we sharpen the endowed ability to

identify the mechanism and to make the most out of it and to live a life in

harmony. Without challenge, harmony may slide down to complacency. This

process would continue to humble us that we learn to fear the Creator to

become a good element in the long civilization process to make the society

better.

Editorial Office

Fig. 2: PPSU Chemical Structure

Fig. 3: PPSU foam is vacuum-thermal formable

Page 4: A. Table of Contents - Foam Update · ECONCORE, DUPONT PERFORMANCE MATERIALS COLLABORATE ON PRODUCTION OF HONEYCOMB PANELS Author(s) Laird, K. Sources Plastics Today Corporate/Assignee

Foam Update

June 2016

To Give Than To Receive - 4 -

C. News

ECONCORE, DUPONT PERFORMANCE MATERIALS COLLABORATE ON

PRODUCTION OF HONEYCOMB PANELS

Author(s) Laird, K.

Sources Plastics Today

Corporate/Assignee N/A

Publication Date May 9, 2016

Abstract:

Belgium-based EconCore N.V.

(Leuven), whose ThermHex technology

for the continuous production of

honeycomb sandwich materials has led

to earlier collaborations with companies

such as Tata Steel and Lanxess, has

announced that its newest partnership is

with DuPont Performance Materials on

the development and production of wide,

strong and rigid honeycomb panels, with

tunable properties, depending on the

choice of Dupont polymer used.

Already, Dupont’sZytel nylon resin and

Surlynionomer resin materials have been applied to produce cost-optimized lightweight

sandwich products with tough, resilient and high-temperature-resistant honeycomb cores.

The honeycomb cores are combined with skins made of Vizilon thermoplastic composite,

a very light, continuously reinforced fiber composite sheet based on a high-temperature-

resistant, heat-stabilized polyamide matrix. Within the in-line integrated ThermHex

technology, Zytel based honeycomb core can be welded with the Vizilon thermoplastic

composite, yielding sandwich panels with a very stable core-skin interfacial connection.

HP FINALLY UNVEILS WORLD-FIRST PRODUCTION-READY 3D-

PRINTING SYSTEM

Author(s) Sparrow, N.

Sources Plastics Today

Corporate/Assignee N/A

Publication Date May 19, 2016

Abstract:

HP (Palo Alto, CA) has introduced its 3D printers for industrial applications that have

been the subject of much speculation. On May 17, the company presented what it calls

the world’s first production-ready commercial 3D-printing system. The HP Jet Fusion

reportedly will produce parts up to 10 times faster and at half the cost of current 3D

Page 5: A. Table of Contents - Foam Update · ECONCORE, DUPONT PERFORMANCE MATERIALS COLLABORATE ON PRODUCTION OF HONEYCOMB PANELS Author(s) Laird, K. Sources Plastics Today Corporate/Assignee

Foam Update

June 2016

To Give Than To Receive - 5 -

printers.The two HP printers coming on the

market target business customers and are

designed to create prototypes as well as larger

batches of items such as small clamps, reports

Fortune. They are priced at $130,000, or

$155,000 if customers want extra post-

processing software and other tools. The 4200

model, which can be used to print 3D objects

in bulk, will retail for over $200,000

depending on the configuration, writes

Fortune.

FORD TO BECOME FIRST AUTOMAKER TO USE CO2-BASED FOAM AND

PLASTIC

Author(s) Laird, K.

Sources Automotive and Mobility, Sustainability

Corporate/Assignee N/A

Publication Date May 19, 2016

Abstract:

Ford has been developing and using

biomaterials in its vehicles for almost

two decades already. In North America,

soy foam is in every Ford vehicle;

coconut fiber backs trunk liners; recycled

tires and soy are in mirror gaskets;

recycled T-shirts and denim go into

carpeting; and recycled plastic bottles

become the REPREVE fabric first

applied in the 2016 F-150. And since 2013, the automaker has been working with several

companies, suppliers and universities to find applications for captured CO2.The new

foam is formulated by Novomer, a New York-based company that utilizes carbon dioxide

captured from manufacturing plants to produce innovative materials. Through a system of

conversions, Novomer produces a polymer than can be formulated into a variety of

materials, including foam and plastic that are easily recyclable.

Produced with up to 50 percent CO2-based polyols, the foam is showing promise as it

meets rigorous automotive test standards. Ford says that It could be employed in seating

and underhood applications, potentially reducing petroleum use by more than 600 million

pounds annually. The use of CO2-derived foam will further reduce the use of fossil fuels

in Ford vehicles and increase the presence of sustainable foam in the automaker’s global

lineup.

Page 6: A. Table of Contents - Foam Update · ECONCORE, DUPONT PERFORMANCE MATERIALS COLLABORATE ON PRODUCTION OF HONEYCOMB PANELS Author(s) Laird, K. Sources Plastics Today Corporate/Assignee

Foam Update

June 2016

To Give Than To Receive - 6 -

ARMACELL GROUP: ARMACELL GENERATED STRONG GROWTH IN 2015

Author(s) N/A

Sources EQS Group

Corporate/Assignee N/A

Publication Date May 19, 2016

Abstract:

Armacell, a global leader in flexible foam for the equipment insulation market and a

leading provider of engineered foams, delivered record results in 2015. Sales amounted to

EUR 540.2 million (2014: EUR 452.2 million), an increase of 19.5 % compared to 2014

and considerable outperformance of the market. This development was borne by strong

organic growth in both Advanced Insulation and Engineered Foams across all regions, as

well as, successful acquisitions in attractive growth markets. Currency translation gains

further contributed to the strong overall growth. In 2015, the Advanced Insulation

division contributed 77 % and the Engineered Foams business 23 % to group sales.

THERMOPLASTIC COMPOSITE TAKE OFF IN AIRCRAFT INTERIORS

Author(s) Malnati, P.

Sources Plastics Engineering

Corporate/Assignee N/A

Publication Date May, 2016

Abstract:

Structural thermoset composites have been used in the airframe construction for the wide-

bodied Boeing 787 Dreamliner and Airbus 380 jets. However, thermoplastic composite

(TPC) has proved useful in aircraft interiors. Sabic offered polyetherimide (PEI) in

sandwich composites, and for low density foam board or honeycomb core, whereas

Solvay provided low density foam made with polyphenylsulfonate (PPSU). Both PEI and

PPSU, shown below, are made in the extrusion foaming process. Their engineering and

fire resistance characteristics lend themselves into aircraft interiors segments.

FOAMING UP NICELY

Author(s) Evans, J.

Sources Plastics Engineering

Page 7: A. Table of Contents - Foam Update · ECONCORE, DUPONT PERFORMANCE MATERIALS COLLABORATE ON PRODUCTION OF HONEYCOMB PANELS Author(s) Laird, K. Sources Plastics Today Corporate/Assignee

Foam Update

June 2016

To Give Than To Receive - 7 -

Corporate/Assignee N/A

Publication Date May, 2016

Abstract:

In recent years, foam injection molding (FIM) has

proved out its benefits in reduced material usage,

reduced cycle time, and improved surface quality.

In automotive segment, FIM components are used

inside the engine hood; such as: engine cover and

fan shrouds. Trexel offered the state of art

injection and metering system to generate

microcellular morphology as shown below. When

application continues to increase, demand is also

increasing. Uniform cell size, more cell content,

and excellent surface quality are pressing voice of

customers (VOC).

TAG PACKAGING UNVEILS 100BIO BIODEGRADABLE FOAM FOOD

CONTAINERS

Author(s) N/A

Sources www.packaging-gateway.com

Corporate/Assignee N/A

Publication Date May 18, 2016

Abstract:

US-based Tag Packaging has unveiled a new biodegradable foam, 100BIO, for the food

packaging sector. Claimed to be the first 100% biodegradable foam, 100BIO features

sturdy, cold-resistant, heat-insulating, and shock-absorbing qualities. A collection of 16

items, such as cups, clamshells and sushi trays, have been included in the new range.

100BIO is made from Ingeo, which is a trademarked brand name for a range of polylactic

acid (PLA) biopolymers owned by NatureWorks. It is said to reduce carbon footprints

and does not contain heavy metals, harsh chemicals or carcinogens. Ingeo is a sugar-

based, biodegradable bioplastic currently being sourced from plants, such as corn or

sugarcane. Tag Packaging president Jea So said: "Everyone should be able to afford safe

and eco-friendly food packaging, and 100BIO will make it economically possible."

Established in 2014, Tag Packaging provides customised packaging solutions for the

baking and lunch-packing sectors.

STYROTEK: EXPANDED POLYSTYRENE BOXES FOR COLD-CHAIN FRUIT

SHIPPING

Author(s) Romanik, R.

Sources www.packworld.com

Corporate/Assignee N/A

Page 8: A. Table of Contents - Foam Update · ECONCORE, DUPONT PERFORMANCE MATERIALS COLLABORATE ON PRODUCTION OF HONEYCOMB PANELS Author(s) Laird, K. Sources Plastics Today Corporate/Assignee

Foam Update

June 2016

To Give Than To Receive - 8 -

Publication Date May 16, 2016

Abstract:

Styrotek’s specially designed

grape boxes protect and

prolong the storage time of the

grapes so they arrive field fresh

and juicy to the grocers’ aisle.

Manufactured from expanded

polystyrene (EPS), Styrotek’s

table grape boxes offer a

number of cold-chain benefits.

TAG PACKAGING DEVELOPS 100% BIODEGRADABLE FOAM FOOD

CONTAINERS

Author(s) N/A

Sources packaging-business-review.com

Corporate/Assignee N/A

Publication Date May 17, 2016

Abstract:

Tag Packaging has developed foam

containers for food packaging, free from

carcinogens and fully compostable.

BERRY PLASTICS REPORTS RECORD SALES IN Q2

Author(s) Embree, K.

Sources Packaging Business

Corporate/Assignee N/A

Publication Date May 12, 2016

Abstract:

Plastics producer Berry Plastics Group Inc. (Evansville, IN) reported fiscal second-

quarter earnings of $59 million. Record sales of $1.61 billion in the quarter were up 32%

from $1.22 billion in the year-ago period. The year-over-year increase was attributed to

net sales from the acquisition of Avintiv, along with an increase in volumes, partially

offset by a decline in selling prices due to the pass-through of lower raw material costs

Page 9: A. Table of Contents - Foam Update · ECONCORE, DUPONT PERFORMANCE MATERIALS COLLABORATE ON PRODUCTION OF HONEYCOMB PANELS Author(s) Laird, K. Sources Plastics Today Corporate/Assignee

Foam Update

June 2016

To Give Than To Receive - 9 -

and negative impact from foreign currency changes.Net

sales from the Consumer Packaging segment were $687

million, compared with $719 million in the year-ago

quarter. Despite that, operating profit rose around 3.1% to

$67 million from $65 million in the year-ago quarter.The

Health, Hygiene, & Specialties segment reported

revenues of $568 million, much higher than $133 million

recorded in the year-earlier quarter. Operating earnings also spiked to $53 million from

$10 million in the year-ago quarter. The operating EBITDA guidance for the 2016 fiscal

year to $1.19 billion.

RIGID POLYURETHANE FOAMS MARKET ANALYSIS, SIZE AND GROWTH

FORECASTS, 2012 TO 2020 | INDUSTRY REPORT BY HEXA RESEARCH

Author(s) N/A

Sources www.digitaljournal.com

Corporate/Assignee N/A

Publication Date N/A

Abstract:

Growing construction industry in emerging economies such as Brazil, India, Indonesia

and China are anticipated to drive the global rigid polyurethane foams market over the

next five years. Polyurethane occurs in several forms ranging from flexible or rigid foams

to strong and stiff elastomers. Flexible and rigid foams accounted for 60% of the total

polyurethane market in 2013. Rigid polyurethane foams applications are prominently

contributed to refrigeration and construction insulations. Increasing electronic and

construction industries across the globe are projected to bolster the rigid polyurethane

foams market growth over the forecast period. Industrialization in India and China is

expected to drive the global market in near future.

NORTH AMERICA MICROCELLULAR POLYURETHANE FOAM MARKET -

PROJECTED TO REACH $1,538.0 MILLION BY 2021 - RESEARCH AND

MARKETS

Author(s) N/A

Sources Business Wire

Corporate/Assignee N/A

Publication Date May 4, 2016

Abstract:

The North America microcellular polyurethane foam market is estimated to be at USD

1,211.0 million in 2016 and is projected to reach USD 1,538.0 million by 2021, at a

CAGR of 4.9% from 2016 to 2021. Microcellular polyurethane foams are innovative

materials that are highly durable and light in weight. They are used in varied industries,

such as automotive, aerospace, and construction, owing to their lightweight.

Page 10: A. Table of Contents - Foam Update · ECONCORE, DUPONT PERFORMANCE MATERIALS COLLABORATE ON PRODUCTION OF HONEYCOMB PANELS Author(s) Laird, K. Sources Plastics Today Corporate/Assignee

Foam Update

June 2016

To Give Than To Receive - 10 -

CALIFORNIA EYES LABELING FOR STYRENE; PS WON’T BE COVERED

UNDER RULE

Author(s) Putrich, G. S.

Sources Plastics News

Corporate/Assignee N/A

Publication Date May 2, 2016

Abstract:

Styren is the latest chemical to require a label warning California consumers of possible

carcinogens, yet polystyrene (PS) plastics product will not need a label under California’s

latest proposition 65 ruling, since the residual styrene in PS is too low (i.e. 5-10 ppb) to

be concerned.

Page 11: A. Table of Contents - Foam Update · ECONCORE, DUPONT PERFORMANCE MATERIALS COLLABORATE ON PRODUCTION OF HONEYCOMB PANELS Author(s) Laird, K. Sources Plastics Today Corporate/Assignee

Foam Update

June 2016

To Give Than To Receive - 11 -

D. Patents and Journals

a. New Foaming Technique

COMPOSITIONS AND STRUCTURES INCLUDING NONAGGREGATED

STABILIZED CHARGED POLYSACCHARIDE NANOFIBERS, METHODS OF

MAKING NONAGGREGATED STABILIZED CHARGED POLYSACCHARIDE

NANOFIBERS, AND METHOD OF MAKING STRUCTURES

Inventor(s) Meredith, III, J. C., Wu, J.

Sources US Pat.App.: 20160130370

Corporate/Assignee Georgia Tech Research Corporation

Publication Date May 12, 2016

Abstract:

Embodiments of the present disclosure provide compositions, structures such as films and

foams, methods of making nonaggregated stabilized charged polysaccharide nanofibers

(e.g., nonaggregated stabilized cationized chitin nanofibers), methods of making structures

such as films and foams, and the like.

FORMULATION CONTAINING BIOTENSIDES

Inventor(s) Jörg, P., Ulrike, K., Hans, W., Dirk, K., Jochen, K.

Sources EP 3002328

Corporate/Assignee Evonik Degussa GMBH

Publication Date April 6, 2016

Abstract:

The invention biotensidhaltige formulations comprising at least one further surfactant.

b. Blowing Agents

LIQUID-TYPE NUCLEATING AGENT FOR IMPROVING THERMAL

INSULATING PROPERTIES OF RIGID POLYURETHANE FOAMS BY HFC-

365MFC AS A BLOWING AGENT

Author(s) Lee, Y., Jang, M. G., Choi, K. H., Han, C., Kim, W. N.

Sources Journal of Applied Polymer Science 133, No.25, 2016, paper 3557, pp.7

Corporate/Assignee N/A

Publication Date March 12, 2016

Abstract:

The effects of liquid-type additives on the morphology, thermal conductivity, and

mechanical strength of polyurethane (PUR) foams were investigated. The PUR foams

synthesized with perfluoroalkane showed a smaller average cell diameter and a lower

thermal conductivity than PUR foams prepared with propylenecarbonate or acetone. The

Page 12: A. Table of Contents - Foam Update · ECONCORE, DUPONT PERFORMANCE MATERIALS COLLABORATE ON PRODUCTION OF HONEYCOMB PANELS Author(s) Laird, K. Sources Plastics Today Corporate/Assignee

Foam Update

June 2016

To Give Than To Receive - 12 -

average cell diameter of the PUR foams decreased from 228 to 155 μm and the thermal

conductivity decreased from 0.0227 to 0.0196 kcal/mh °C when the perfluoroalkane

content was 0.0 to 2.0 php (parts per hundred polyol by weight). The perfluoroalkane

likely acted as a nucleating agent during the formation of the PUR foams. The addition of

perfluoroalkane induced the smaller cells size of the PUR foams probably due to lower

surface tension of the polyol and perfluoroalkane mixture, resulting in high nucleation

rate. The smaller cell size appears to be the main reason for the improvement in the

thermal insulating and the mechanical properties of these PUR foams. The compressive

strength of the PUR foams prepared with perfluoroalkane was higher than the PUR foams

prepared with the propylenecarbonate and acetone. Based on the morphology, thermal

conductivity, and compressive strength, it is suggested that the perfluoroalkane is an

efficient liquid-type additive for the improving the thermal insulation of PUR foams.

c. Foam Products

ETHYLENE-BASED POLYMER COMPOSITIONS AND FOAMS

Inventor(s) Low, B. T.

Sources US Pat.App.: 20160137803

Corporate/Assignee Dow Global Technologies LLC

Publication Date May 19, 2016

Abstract:

The invention provides a composition comprising the following: A) a first polymer

selected from the following: i) an ethylene/.alpha.-olefin interpolymer; or ii) an

ethylene/.alpha.-olefin multi-block interpolymer; B) a second polymer selected from the

following: iii) an ethylene/.alpha.-olefin interpolymer; iv) an ethylene/.alpha.-olefin/non-

conjugated diene interpolymer; or v) an ethylene/.alpha.-olefin multi-block interpolymer;

and wherein the first polymer has a density from 0.880 to 0.910 g/cc, and the second

polymer has a density less than, or equal to, 0.867 g/cc, and wherein the weight ratio of

the first polymer to the second polymer is from 0.5 to 9.

POLYMERIC MATERIAL FOR USE IN THERMAL INSULATION

Inventor(s) Topolkaraev, V. A., McEneany, R. J., Scholl, N. T., Colman, C. W.,

Mleziva, M. M.

Sources US Pat.App.: 20160122491

Corporate/Assignee Kimberly-Clark Worldwide, Inc.

Publication Date May 5, 2016

Abstract:

A polymeric material for use in thermal insulation is provided. The polymeric material is

formed from a thermoplastic composition containing a continuous phase that includes a

matrix polymer and within which a microinclusion additive and nanoinclusion additive are

dispersed in the form of discrete domains. A porous network is defined in the material that

Page 13: A. Table of Contents - Foam Update · ECONCORE, DUPONT PERFORMANCE MATERIALS COLLABORATE ON PRODUCTION OF HONEYCOMB PANELS Author(s) Laird, K. Sources Plastics Today Corporate/Assignee

Foam Update

June 2016

To Give Than To Receive - 13 -

includes a plurality of nanopores having an

average cross-sectional dimension of about 800

nanometers or less. The polymeric material

exhibits a thermal conductivity of about 0.20

watts per meter-kelvin or less.

PEELABLE, FLEXIBLE AND TRANSPARENT PROCESS LINER

Inventor(s) Forsberg, O., Gustavsson, K.

Sources US Pat.App.: 20160121587

Corporate/Assignee Mondi AG

Publication Date May 5, 2016

Abstract:

The present invention provides a process liner for the preparation of foamed plastic blocks

or slabs which exhibits excellent mechanical properties including tear strength,

dimensional stability and flexibility while being transparent and allowing easy separation

from the produced foam material. The process liner comprising a transparent support

polymer film (A) and a transparent peelable polyolefin film (B) provided thereon, wherein

the support film (A) has a weight per area of 10-100 g/m.sup.2 and is made of a polymer

having a melting point of 130.degree. C. or more according to DSC measurement; and

wherein the peelable polyolefin film (B) has a weight per area of 10-50 g/m.sup.2 and is

made of a polyolefin having a melting point lower than the melting point of the polymer of

the support film (A) by 10.degree. C. or more. Furthermore, a method for producing the

process liner is provided and a process for the preparation of foamed plastic blocks or

slabs in a continuous production line.

LAYERED STRUCTURES

Inventor(s) Waggoner, M.

Sources US Pat.App.: 20160121577

Corporate/Assignee N/A

Publication Date May 5, 2016

Abstract:

Disclosed, among other things, are ways to manufacture layered structures. In one

embodiment, a foaming process may produce layered structures in reduced density plastics

with or without integral skins. In another embodiment, a foaming process may produce

deep draw structures in reduced density plastics with or without integral skins. In yet

another embodiment, a foaming process may utilize additives, blends, or fillers, for

example. In yet another embodiment, a foaming process may involve saturating a semi-

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Foam Update

June 2016

To Give Than To Receive - 14 -

crystalline polymer such as Polylactic Acid (PLA)

with high levels of gas, and then heating, which may

produce a reduced density plastic having high levels

of crystallinity. These processes may be used to

generate products with layered structures.

REACTIVE MATERIALS PACKAGING

Inventor(s) Hughes, K. D.

Sources US Pat.: 9,334,098

Corporate/Assignee N/A

Publication Date May 10, 2016

Abstract:

Devices are disclosed for the generation and

containment of reactive treatment agents.

Formulations containing these agents can be

applied widely as disinfectants, odor control

agents, decontamination and fumigation agents,

liquid, gas, and air treatment materials,

respiratory agents, food and beverage processing

agents, neutralization agents, nutritional and

dietary supplements, and in many industrial, residential, medical and military surface

treatment operations.

DISORDERED NANOPOROUS CRYSTALLINE FORM OF SYNDIOTACTIC

POLYSTYRENE, PROCESS FOR ITS PREPARATION AND ARTICLES

COMPRISING THE SAME

Inventor(s) Albunia, A. R., Bianchi, R., Di Maio, L., Galimberti, M., Guerra, G.,

Pantani, R., Senatore, S.

Sources US Pat.: 9,328,181

Corporate/Assignee Nano Active Film S.R.L.

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Foam Update

June 2016

To Give Than To Receive - 15 -

Publication Date May 3, 2016

Abstract:

There is described a new disordered nanoporous crystalline form

of syndiotactic polystyrene, characterized by a specific X-ray

diffractrogram, the process for its preparation and various articles

comprising this form of s-PS. This disordered nanoporous

crystalline form exhibits empty crystalline cavities of nanometric

sizes, and in this case performs the function of absorbing

molecules with low molecular mass and is useful in particular as

functionally active packaging for plant products.

LOW DENSITY NON-CROSSLINKED CLOSED/OPEN CELL

POLYPROPYLENE FOAMS WITH HIGH MECHANICAL PROPERTIES

Author(s) Escudero, J., Lopez-Gil, A., Laguna-Gutierrez, E., Rodriguez-Perez, M. A.

Sources Cellular Polymers 35, No.3, 2016, p.101-118

Corporate/Assignee N/A

Publication Date N/A

Abstract:

Low density polypropylene based foams with different cellular structures have been

produced by the improved compression moulding route using a high melt strength

polypropylene as polymer matrix. In addition, different types of nanoparticles have been

introduced in the formulation (multi-wall carbon nanotubes, organomodified nanoclays

and natural nanoclays) to modify the structure and properties. The results have showed a

clear correlation between the open cell content of the foams and the mechanical

properties in compression. In the unfilled polypropylene high specific mechanical

properties are only achievable with low values of open cell content. In comparison, for an

equal value of the interconnectivity between cells, the samples containing nanoclays

present much higher specific properties. This result is attributed to the reinforcement of

these nanoparticles in the solid matrix, due to an improved exfoliation during the foaming

process and the presence of a bimodal cellular structure. The produced foams have

interesting properties with stiffness similar to those of commercial polymer foams used

for the core of sandwich panels.

d. Applications

POUCH CASE FOR SECONDARY BATTERY AND POUCH TYPE SECONDARY

BATTERY INCLUDING THE SAME

Inventor(s) Hwang, S. J., Kim, S. H., Hwang, W. P., Jung, S. S., Yu, H. K.

Sources US Pat.App.: 20160133883

Corporate/Assignee LG Chem, Ltd.

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June 2016

To Give Than To Receive - 16 -

Publication Date May 12, 2016

Abstract:

A pouch case of the present disclosure

includes an inner resin layer, a metallic layer,

and an outer resin layer, wherein the resin

layer(s) include(s) a foaming activator

containing an isocyanate-based compound

and a polyol compound. Accordingly, since

the pouch case includes the inner resin layer

and/or the outer resin layer including the foaming activator, when moisture or the like is

permeated thereto due to an external factor, a protective layer including urethane-based

foam is formed in the outer resin layer or between the inner resin layer and an electrode

assembly in a short time, so that the pouch case and the electrode assembly may be

protected, moisture which is permeable into the electrode assembly may be blocked, and

separator cracking also may be prevented. Accordingly, explosion which may be caused

by moisture permeation, separator cracking, or a short circuit by contact between the

pouch case and the electrode assembly, or the like, may be prevented, and stability of a

pouch type secondary battery may thus be ensured.

METHOD FOR MANUFACTURING MOLDED FOAM PARTS IN A

PACKAGING SLEEVE AND SALES UNIT

Inventor(s) Munzenberger, H., Paetow, M., Ober, A.

Sources US Pat.App.: 20160129615

Corporate/Assignee N/A

Publication Date May 12, 2016

Abstract:

A method for producing molded foam parts for

construction and civil engineering has the

following steps: Inserting a packaging sleeve of the

molded foam part to be produced into a molding

tool, filling a flowable foaming material into the

packaging sleeve within molding tool, filling the

cavity defined by molding tool and packaging

sleeve with foam, and removing the molded foam

part produced, together with its packaging sleeve.

ANTIMICROBIAL FOAMS AND METHODS OF MAKING SAME

Inventor(s) Sanghi, S. K., Ali, M. B.

Sources US Pat.App.: 20160120176

Corporate/Assignee 3M Innovative Properties Company

Publication Date May 5, 2016

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Foam Update

June 2016

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Abstract:

Antimicrobial foams and methods of making

same. The antimicrobial foams can include a

polymeric foam having a wet-out time of at

least 250 sec; and a coating comprising an

antimicrobial material. The antimicrobial

material can include a quaternary ammonium

compound, and the antimicrobial material can

be covalently bound to the foam. The

antimicrobial foam can include at least 0.25

parts by weight of quarternary ammonium compound per 100 parts by dry weight of the

foam. The method can include providing the polymeric foam and an antimicrobial

material comprising a quaternary ammonium precursor. The method can further include

combining the foam and the quaternary ammonium precursor to form a combination; and

heating the combination to a temperature of at least 40.degree. C. to form an antimicrobial

foam comprising a quaternary ammonium compound covalently bound to the foam.

METHOD FOR MOLDING THREE-DIMENSIONAL FOAM PRODUCTS USING

A CONTINUOUS FORMING APPARATUS

Inventor(s) Taylor, Z. R.

Sources US Pat.App.: 20160096290

Corporate/Assignee N/A

Publication Date April 7, 2016

Abstract:

A continuous forming apparatus for molding foam material into foam products that

includes a first endless belt and a second endless belt that cooperates with the first endless

belt to mold the foam material. The continuous forming apparatus may also include a first

plurality of cleats and a second plurality of cleats opposed to the first plurality of cleats

that support the first endless belt and the second endless belt respectively. The first

plurality of cleats may include a three-dimensional abutment surface that provides

transverse and lateral support to the first endless belt. Additionally, the continuous

forming apparatus may include a first frame disposed to support the first plurality of

cleats, a second frame disposed to support the second plurality of cleats, and a drive

mechanism for imparting motion to the first endless belt, the second endless belt, the first

plurality of cleats, and the second plurality of cleats.

METHOD FOR PRODUCING A POLYPROPYLENE-BASED RESIN FOAM

SHEET

Inventor(s) Kimura, K., Tomohiro, M.

Sources JP 2016047607

Corporate/Assignee Sekisui Plastics Co., Ltd.

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Foam Update

June 2016

To Give Than To Receive - 18 -

Publication Date April 7, 2016

Abstract:

The present invention using a

polypropylene resin composition,

surface condition to provide a method of

manufacturing a polypropylene-based

resin foam sheet capable of obtaining a

good foam sheet. Method for producing

a polypropylene-based resin foam sheet

according to the present invention

comprises a polypropylene resin, a

specific polypropylene resin

composition comprising at least one of

olefin thermoplastic elastomer and

polyethylene plastomers used on, and

using a carbon dioxide as a blowing agent, the outer peripheral surface of the circle

comprising the step of performing extrusion foaming molding by the annular die 1, the

foamed portion 11A of the annular die 1 of the resin flow path 11, the ratio (inner die 3 3a

corner radii RI / corner radii RO of the inner circumferential surface 2a of the outer die 2)

is 1.1 or more and less than 7.0, the extrusion foam molding, the pressure on the outlet 11a

portion of the annular die 1 average 5MPa or more, is less than or equal to 20MPa.

ONE KIND OF HIGH-PRESSURE FOAM UNITS PU FOAM ROUND

Inventor(s) Lee, Y., Tang, X., Jia, G., Wang, S.

Sources CN 205097444

Corporate/Assignee Harbin Kai Ruida Technology Co., Ltd.

Publication Date March 23, 2016

Abstract:

One kind of high-pressure foam units PU round

bubble, bubble circle in order to solve the

existing PU foam units using low foaming

manner, resulting in different diameters and

flow marks problems. Several stirring blades

mounted on the shaft, the spiral angle and a

plurality of blades by intermittent double helix

arrangement, the blade is 5 ° ~ 15 °, a balance

between the grid and the end face of the

pressure buffer agitator shaft, the mixing head,

conical corridor, connecting rods, circular

corridor, chain drive cylinder cut-off

mechanism and pinch bubble mechanism are

arranged from bottom to top, the conical inner

wall of the tubular plastic film along the

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Foam Update

June 2016

To Give Than To Receive - 19 -

corridor, circular corridor and chain plate cylinder drive laying tube conical shape along

the inner wall of the corridor plastic film, a circular plate and the chain drive corridor

laying tube, the first raw material tank and a tank, respectively, the seventh and the low-

pressure feed pipe inlet is connected via a low pressure, a second material tank, the third

raw material cans, cans of raw materials fourth, fifth and sixth raw material tank tank

respectively through high pressure feed pipe and high pressure feed connection. The utility

model is used in the production of PU foam circle.

e. Degradable and Sustainable Foam

COMPOSITION AND METHOD FOR MAKING A CAVITATED BIO-BASED

FILM

Inventor(s) Cotton, R. N., Laverdure, K. S., Palta, D., Rodgers, B. D.

Sources US Pat.App.: 20160122490

Corporate/Assignee Frito-Lay North America, Inc.

Publication Date May 5, 2016

Abstract:

Composition and method for making a multi-

layer bio-based film having one or more

cavitated layers. In one aspect, the multilayer

flexible film has polylactic acid, an inorganic

filler, and a cavitation stabilizer making up at

least one film layer. In one aspect, the barrier

web has a cavitated bio-based film layer. In another aspect, the print web has a cavitated

bio-based film layer.

f. Thermoset Foam; PU and Others

PROCESS FOR PRODUCING FLEXIBLE POLYURETHANE FOAM

Inventor(s) Burdeniuc, J. J., Tobias, J. D., Jeon, Y. M., Keller, R. J.

Sources US Pat.: 9,334,382

Corporate/Assignee Air Products and Chemicals, Inc.

Publication Date May 10, 2016

Abstract:

A composition and process useful to make flexible polyurethane foams and in particular

flexible molded polyurethane foams is disclosed. The usage of dipolar aprotic liquids such

as DMSO, DMI, sulfolane, N-methyl-acetoacetamide, N,N-dimethylacetoacetamide as

well as glycols containing hydroxyl numbers OH#.ltoreq.1100 as cell opening aides for 2-

cyanoacetamide or other similar molecules containing active methylene or methine groups

to make a polyurethane foam is also disclosed. The advantage of using cell opener aids

results in a) no foam shrinkage; b) lower use levels of cell opener; c) foam performance

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Foam Update

June 2016

To Give Than To Receive - 20 -

reproducibility d) optimum physical properties. In addition, combining the acid blocked

amine catalyst together with the cell opener and the cell opener aid results in a less

corrosive mixture as well as provides a method that does not require mechanical crushing

for cell opening.

ISOCYANATE-BASED POLYMER FOAM COMPOSITE WITH IMPROVED

THERMAL INSULATION PROPERTIES

Inventor(s) Yin, Y., Chen, J. G., Wang, B., Ye, L., Parenti, V.

Sources US Pat.: 9,328,859

Corporate/Assignee Dow Global Technologies LLC

Publication Date May 3, 2016

Abstract:

This invention relates to rigid isocyanate-based

polymer foam and composites thereof comprising a

carbon black component comprising at least 50 weight

percent of a fluorinated carbon black. Said foam having

improved thermal properties, specifically, rigid

polyurethane and/or polyisocyanurate foams for use in

said insulation applications.

PLURAL COMPONENT SPRAY GUN FOR FAST SETTING MATERIALS

Inventor(s) Zittel, D. P., Sebion, M. J., Anderson, R. D., Linder, P. L., Pellin, C. J.,

Weinberger, M. T., Richter, M. C.

Sources US Pat.: RE46,002

Corporate/Assignee Graco Minnesota Inc.

Publication Date May 17, 2016

Abstract:

A plural component spray gun (1) is designed for

spraying quick setting materials such as foams,

polyurea and the like. Towards this end, the gun (1) is

designed so as to be easily serviceable with a minimum

of tools. For example, the side seal cartridges (18) and

(20) may be installed and removed without tools by

removing the retaining ring (9) and then extracting

them from the fluid housing (11). Those cartridges (18)

and (20) are easily disassembled and cleaned.

Similarly, the fluid housing (11) may be removed from

the handle/body (1) by unscrewing the lock ring (7) by

hand.

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Foam Update

June 2016

To Give Than To Receive - 21 -

FLAME-RETARDANT POLYURETHANE FOAMS WITH REDUCE

SCORCHING

Inventor(s) Jan-gerd, H., Heiko, T.

Sources EP 2985335

Corporate/Assignee Lanxess Deutschland GMBH

Publication Date February 17, 2016

Abstract:

The present invention relates to flame retardant

polyurethane foams with low core discoloration,

which contain as a flame retardant phosphorus-

containing propionic acid, and a process for preparing

such foams and their use.

A LIGHTWEIGHT HIGH PROPERTY OF POLYURETHANE FOAM

MATERIAL AND PREPARATION METHOD

Inventor(s) Zhang, G.

Sources CN 105273394

Corporate/Assignee Dongguan Wang Shi Functional Materials Technology Co., Ltd.

Publication Date January 27, 2016

Abstract:

The present invention relates to the technical field of polyurethane foam material, in

particular to a lightweight high physical properties of polyurethane foam and a preparation

method of the polyurethane foam by the following raw materials in parts by weight: 70 to

98 parts of polyurethane rubber, inorganic 1-10 parts foaming agent, 0-10 parts of organic

blowing agent and 1-10 parts. Polyurethane foam material of the present invention, light

weight, high physical properties, wear resistance, has good flexibility and softness, good

dimensional stability, environmental protection, recyclable, no smell.

g. Microcellular and Expanded Particle

POLYPROPYLENE RESIN FOAMED PARTICLES AND POLYPROPYLENE

RESIN IN-MOLD FOAM MOLDED ARTICLE HAVING EXCELLENT FLAME

RETARDANCY AND ELECTRIC CONDUCTIVITY

Inventor(s) Miura, S.

Sources US Pat.App.: 20160137805

Corporate/Assignee Kaneka Corporation

Publication Date May 19, 2016

Abstract:

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Foam Update

June 2016

To Give Than To Receive - 22 -

A polypropylene resin in-mold foam molded article that has a volume resistivity value of

10 .OMEGA.cm or more and 5,000 .OMEGA.cm or less and is produced from

polypropylene resin foamed particles including a polypropylene resin composition

containing 11 parts by weight or more and 25 parts by weight or less of an

electroconductive carbon black having a DBP absorption amount of 300 cm.sup.3/100 g or

more and 600 cm.sup.3/100 g or less and 3 parts by weight or more and 15 parts by weight

or less of melamine cyanurate relative to 100 parts by weight of a polypropylene resin has

a low open-cell ratio, excellent electric conductivity, and excellent flame retardancy. In

particular, a polypropylene resin in-mold foam molded article that is produced from

polypropylene resin foamed particles containing an inorganic foaming agent and

conventionally having low flame retardancy exhibits excellent flame retardancy.

ELECTROCONDUCTIVE POLYPROPYLENE RESIN FOAMED PARTICLES

AND ELECTROCONDUCTIVE POLYPROPYLENE RESIN IN-MOLD FOAM

MOLDED ARTICLE HAVING EXCELLENT FLAME RETARDANCY AND

ELECTRIC CONDUCTIVITY

Inventor(s) Miura, S.

Sources US Pat.App.: 20160141069

Corporate/Assignee Kaneka Corporation

Publication Date May 19, 2016

Abstract:

From electroconductive polypropylene resin foamed particles produced by foaming

electroconductive polypropylene resin particles including an electroconductive

polypropylene resin composition that contains 11 parts by weight or more and 25 parts by

weight or less of an electroconductive carbon black relative to 100 parts by weight of a

polypropylene resin and has a melt index of 1.0 g/10 min or more and 4.0 g/10 min or less

where the melt index is determined at a load of 5,000 g at 230.+-.0.2.degree. C., a

polypropylene resin in-mold foam molded article having excellent electric conductivity

and also having higher flame retardancy without any flame retardant can be obtained.

PORE INITIATION TECHNIQUE

Inventor(s) Topolkaraev, V. A., McEneany, R. J., Scholl, N. T., Carrillo, A. J., Mleziva,

M. M.

Sources US Pat.App.: 20160121523

Corporate/Assignee Kimberly-Clark Worldwide, Inc.

Publication Date May 5, 2016

Abstract:

A technique for initiating the formation of pores in a polymeric material that contains a

thermoplastic composition is provided. The thermoplastic composition contains

microinclusion and nanoinclusion additives dispersed within a continuous phase that

includes a matrix polymer. To initiate pore formation, the polymeric material is

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Foam Update

June 2016

To Give Than To Receive - 23 -

mechanically drawn (e.g., bending,

stretching, twisting, etc.) to impart energy to

the interface of the continuous phase and

inclusion additives, which enables the

inclusion additives to separate from the

interface to create the porous network. The

material is also drawn in a solid state in the

sense that it is kept at a temperature below

the melting temperature of the matrix

polymer.