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IJSRK Internat ional Journal of Scient if ic Research in Knowledge
www.i jsrpub.com
August 2013
Volume 1, Issue 8
Pages 238 – 307
Table of Contents
Article Author(s) page
The Relationship between Power Resources and the Procedures of Overcoming Employers’ Resistance against Organizational Changes among Managers of the University of Isfahan and Isfahan University of Medical Sciences, Iran
Azizollah Arbabisarjou, Sayyed Ali Siadat, Zahra-al-Saadat Mahmoudy, Narges Moayed, Shekoofe-al-Saadat Rezazadeh
238
Calculation of Lattice Parameters and Energy Band Structure and Density of States the β-ZrNCl with Ab Initio
Khatereh Sarvazad, Soroosh Zarghani
245
Democratic Regression in Nigeria: A Critical Discourse on the Character and Tendencies of the Political Parties as Explanatory Factors
Emma E.O. Chukwuemeka, Dennis S. Amobi, Bartholomew I. Ugwuanyi
254
An Investigation into Factors Affecting Productivity of Produces by Karoun Agriculture and Industry Company
Mehdi Basirat, Mehrafarin Latif, Ali Asghar Esfandiari
263
Assessing Relationships in Kenyan Sorghum Landraces by Use of Simple Sequence Repeat Molecular Markers
Kahiu Ngugi, Rachael Maswili, Cecilia Muchira
276
Inward FDI, Growth and Environmental Policy Maryam Asghari 288
Solvent-free Synthesis and Spectral Studies of Some 9-Anthryl-1H-Pyrazolines
Krishnamoorthy Guna Sekar, Ganesamoorthy Thirunarayanan
299
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 238-244, 2013 Available online at http://www.ijsrpub.com/ijsrk
ISSN: 2322-4541; ©2013 IJSRPUB
http://dx.doi.org/10.12983/ijsrk-2013-p238-244
238
Full Length Research Paper
The Relationship between Power Resources and the Procedures of Overcoming
Employers’ Resistance against Organizational Changes among Managers of the
University of Isfahan and Isfahan University of Medical Sciences, Iran
Azizollah Arbabisarjou1, Sayyed Ali Siadat
2*, Zahra-al-Saadat Mahmoudy
3, Narges Moayed
3, Shekoofe-al-Saadat
Rezazadeh4
1Faculty member, Health Promotion Research Center, Zahedan University of Medical Sciences, Zahedan, Iran
2Faculty member, School of Educational Sciences and Psychology, University of Isfahan, Isfahan, Iran
3M.A in educational administration, School of Educational Sciences and Psychology, University of Isfahan, Isfahan, Iran
4M.A in Curriculum, School of Educational Sciences and Psychology, University of Isfahan, Isfahan, Iran.
*Corresponding Author: E-mail: [email protected]
Received 12 May 2013; Accepted 18 June 2013
Abstract. The purpose of this study was to examine the relationship between power resources and the procedures of
overcoming employers‘ resistance against organizational changes among managers of the University of Isfahan as well as
Isfahan University of Medical Sciences in 2012-2013 academic years. The research was descriptive-correlative and samples
consisted of all the managers of the university of Isfahan as well as Isfahan University of Medical Sciences in 2012-2013
academic years using random sampling by which 108 managers were selected. The instruments used to collect data were two
questionnaires designed by the researcher consisting of 30 questions related to power resources of managers extracted from
French and Raven viewpoint and 28 questions covering procedures of overcoming employers‘ resistance against changes
according to Likert scale and classification. Stabilization coefficient was obtained by means of Cronbach alpha (0.86) in the
two questionnaires. The analysis of data was performed in descriptive (frequency, percent, mean, and deviation) as well as
inferential (analysis of multi –variable variance, and regression coefficient) statistics through SPSS. The results of the study
showed that there were no significant differences between the legal power of managers and the procedures used to overcome
the resistance of employers against organizational changes. There was a negative and significant relationship between
obligatory power and cooperation procedure. There was a positive and significant relationship between referential power and
cooperation procedure.
Key words: Manager‗s Sources of Power, Organizational Change, Resistance to Organizational Change, University.
1. INTRODUCTION
The change trend and the instrument diversity have
been increased in the beginning of the third
millennium (Caddy and Cochrane, 2001). These
changes and revolutions are observable in every
aspects of the daily life. Therefore, the organizational
change is an inevitable phenomenon. This is designed
and managed for improving organizations. According
to the global change, the organizations must change
themselves for adapting with environmental demands.
It is necessary that mankind, organizations, and
societies change themselves to survive in the today‘s
world. Hoy and Miskel (2012) pointed out that change
refers to the forces that maintain the fixed behavioral
styles in the organization. Generally, organizational
change is influenced by different internal and external
forces. In the today‘s competitive world, the
successful organization is one that adopts change in its
structural framework. The diversity and
comprehensiveness of change in so much that the
organizations are forced to adapt with them. It is
should be remembered that resistance to change may
leads to decrease efficiency and productivity, increase
job turnover, and increase group and organizational
conflicts. This also leads to decrease employees‘
satisfaction from their job and organization (Hoy and
Miskel, 2012). Many authors define resistance to
change differently for example Zander (1950) is the
first author that defines resistance to change refers to
the behaviors that tend to maintain individuals from
the effects of actual or fanciful change (Dent and
Gallway Goldberg, 1999; Bolognese, 2002). Zaltman
and Duncan (1977) define resistance to change as
―any conduct that serves to maintain the status quo in
the face of pressure to alter the status quo‖. Resistance
to change is a natural response of a human being or an
institution to any changes that disrupt the existing
equilibrium of living conditions or organizational
activities (Watson, 1971; Zaltman and Duncan, 1977).
The power is defined as the individuals‘ ability in
acquiring desirable results (French and Bell, 2006).
French and Raven (1960) recognized five sources of
power including legitimate, reward, coercive, expert
Arbabisarjou et al.
The Relationship between Power Resources and the Procedures of Overcoming Employers’ Resistance against
Organizational Changes among Managers of the University of Isfahan and Isfahan University of Medical Sciences, Iran
239
and referent (Robbins and Coulter, 2013; Hoy and
Miskle, 2012). The present study has been focused on
these sources. The methods of dominating the
resistance to change are including communication,
participation, offering facilities, transaction, using
individuals, and force (Robbins and Coutler, 2012;
Kotter, 1996). According to the above explanations,
this study was carried out to examine the relationship
between power resources and the procedures of
overcoming employers‘ resistance against
organizational changes among managers.
2. MATERIALS NAD METHODS
Given that this study is concerned with the status quo,
it employed descriptive research and since it studies
the relationship between power resources and the
procedures of overcoming employers‘ resistance
against organizational changes among managers, it
utilized correlation procedures (Law, 2004).
The study has been carried out in 2011- 2012
academic years. The settings researches were the
University of Isfahan and Isfahan University of
Medical Sciences in IRAN. The participants of the
research included 259 managers (including
chairpersons, assistants, deans of faculties, and head
of departments) in University of Isfahan and Isfahan
University of Medical Sciences. The sample size has
been determined through sampling formula in the
SPSS18. It implied that a sample of 108 managers is a
suitable sample for this population. In order to select
the sample members, stratified random sampling has
been employed.
Also, the results obtained from the formula are
completely consistent with the values of Kerjeci and
Morgan's Table( Kerjeci and Morgan,1970).The data
required for this study was compiled through library
research including studying textbooks, internal and
external journals or texts and surfing the databases in
the Internet and Intranet to achieve theoretical
fundamentals and use other . The instruments used to
collect data were two questionnaires designed by the
researchers consisting of 30 questions related to
power resources of managers extracted from French
and Raven viewpoint and 28 questions covering
procedures of overcoming employers‘ resistance
against changes according to Likert scale and
classification. . French and Raven's (1960 bases of
power are all founded on the perceptions of
individuals over whom the power might be exerted.
The Power resources are coercive, reward, legitimate,
referent and expert power (Hoy and Miskle, 2012). It
has used for data-collection instrument in the present
study. Validity of the questionnaire was content and
face validity that has been examined and confirmed by
some faculty members (Educational Administration,
Education, Psychology and Management) and
professors‘ modification and corrections. In order to
examine and confirm reliability of the questionnaire,
Cronbachs‘ Alpha Coefficient has been used. This
coefficient obtained 0.86 for our questionnaires that
confirm their reliability. To analyze the statistical
data, descriptive statistics techniques (including:
adjusting descriptive tables, mean, standard deviation)
and inferential (analysis of correlation, analysis of
variance) have been used.
3. RESULTS AND FINDINGS
The first question of this study to know is there any
relationship between manager‘s source of authority
and the methods of dominating employees‘ resistance
to change? The results that answer this question have
been presented in table 1.
Table 1: The results of regression test of net and gross weights of manager‘s source of authority and the methods using for
dominating the employees‘ resistance to change
Sources of authority Standard error Regression coefficient T Sig
Communications 0.14 0.19 1.55 0.12
Participation 0.08 0.19 1.62 0.11
Using facilities 0.16 0.14 1.07 0.29
Transaction 0.08 0.10 0.79 0.43
Using individuals 0.08 0.17 1.13 0.26
Coercion 0.09 0.17 1.65 0.11
The regression test revealed that the manager‘s
source of authority does not have any effect on the
methods used to dominate over employees‘ resistance
to change when P value is 0.11 (P > 0.05).
The second question of this study to know is there
any significant relationship between the manager‘s
reward authority and the employees‘ resistance to
change. The results that answer this question have
been presented in table 2.
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 238-244, 2013
240
Table 2: The results of regression test of net and gross weights of manager‘s reward authority and the methods using for
dominating the employees‘ resistance to change
Sources of authority Standard error Regression
coefficient
T Coefficient of
determination
(R2)
sig
Communications 0.17 0.19 1.62 0.09 0.11
Participation 0.09 0.42 3.26 0.17 0.001
Using facilities 0.09 0.35 2.36 0.17 0.02
Transaction 0.09 -0.009 0.08 0.09 0.95
Using individuals 0.09 -0.34 2.36 0.17 0.02
Coercion 0.11 -0.32 3.16 0.17 0.002
The regression test cleared that the manager‘s
reward authority influences communications,
participation, using facilities, transaction, using
individuals, and coercion. This also has not any effect
on the methods of employees‘ resistance to change.
The third question of this study to know is there any
significant relationship between the manager‘s
coercion authority and the employees‘ resistance to
change. The results that answer this question have
been presented in table 3.
Table 3: The results of regression test of net and gross weights of manager‘s coercion authority and the methods using for
dominating the employees‘ resistance to change
Sources of authority Standard error Regression
coefficient
T Coefficient of
determination
(R2)
sig
Communications 0.17 0.06 0.37 0.08 0.71
Participation 0.19 -0.17 2.04 0.12 0.04
Using facilities 0.09 0.11 0.75 0.08 0.45
Transaction 0.10 0.04 0.29 0.08 0.77
Using individuals 0.09 0.11 0.75 0.08 0.45
Coercion 0.11 0.19 1.84 0.08 0.07
The regression test demonstrated that the manager‘s coercion authority influence communications, participation, using facilities, transaction, using individuals,
and coercion. This also has not any effect on the methods of employees‘ resistance to change when P value is 0.07 (P > 0.05).
The fourth question of this study to know is there
any significant relationship between the manager‘s
expertise authority and the employees‘ resistance to
change. The results of this question have been
presented in table 4.
Table 4: The results of regression test of net and gross weights of manager‘s expertise authority and the methods using for
dominating the employees‘ resistance to change
Sources of authority Standard error Regression
coefficient
T sig
Communications 0.20 0.043 0.35 0.72
Participation 0.11 0.11 0.98 0.33
Using facilities 0.24 0.03 0.20 0.84
Transaction 0.12 0.07 0.55 0.58
Using individuals 0.11 0.25 1.65 0.10
Coercion 0.14 0.06 0.56 0.58
The regression test indicated that the manager‘s expertise authority has not any significant effect on the manager‘s source of authority (including
communications, participation, using facilities, transaction, using individuals, and coercion) when P value is 0.58. (P > 0.05).
Table 5: The results of regression test of net and gross weights of manager‘s reference authority and the methods using for
dominating the employees‘ resistance to change
Sources of authority Standard error Regression
coefficient
T Coefficient of
determination
(R2)
sig
Communications 0.17 0.13 1.18 0.09 0.24
Participation 0.09 0.28 2.76 0.29 0.007
Using facilities 0.20 0.03 0.22 0.09 0.83
Transaction 0.10 -0.26 2.39 0.29 0.02
Using individuals 0.09 -0.31 2.37 0.29 0.02
Coercion 0.12 0.01 0.15 0.09 0.88
The regression test showed that the manager‘s reference authority influence participation, transaction, and using individuals. This also has not any effect on the communications, using facilities, and coercion when P value is 0.88 (P > 0.05).
Arbabisarjou et al.
The Relationship between Power Resources and the Procedures of Overcoming Employers’ Resistance against
Organizational Changes among Managers of the University of Isfahan and Isfahan University of Medical Sciences, Iran
241
The fifth question of this study to know if is there
any significant relationship between the manager‘s
reference authority and the employees‘ resistance to
change. The results of this question have been
presented in table 5.
4. DISCUSSIONS AND CONLUSIONS
This study was aimed to study the relationship
between manager‘s source of authority and the
methods used for dominating the employees‘
resistance to change. Kan, Parry and Ken (2004)
reported that the present of rule is necessary to
accepting changes from employees‘ perspective in any
organization. They also believed that the employees
accept the actual and legal changes. Akmal and Miller
(2003) pointed out that the flexibility is one of the
most effective factors on the accepting change by
employees. Based on the results of our study and
similar studies, it can be concluded that the employees
accept the legal changes more easily than other
changes. On the other hand, it is necessary that the
managers have more flexibility in the changes
implementation so much that the employees can adopt
the changes in their works.
The results revealed that the managers‘ reward
authority can influence participation, using facilities,
using individuals, and coercion. Therefore, it can be
concluded that the managers use their reward
authority for designing the changes in accordance
with employees‘ abilities, consulting to solve
employees‘ problems. This also results in the
employees‘ less resistance to the organizational
changes. Hajiabadi (2001) and Safari (2003) indicated
that the manager‘s source of authority and the degree
of using every source influence the organizational
climate and the employee‘ trust positively.
The results of this study in terms of the
relationship between coercion authority and the
methods used by managers for dominating the
employees‘ resistance to change indicated that there
was a significant negative relationship between
manager‘s coercion authority and the employees‘
participation. On the other hand, these results reveal
that there is not any significant relationship between
other sources of manager‘s authority (including
communications, using facilities, transaction, using
individuals, and coercion) and the employees‘
resistance to change. In other words, using coercion
authority by managers influences employees‘
participation and even decreases its extent, while other
sources of manager‘s authority (including
communications, using facilities, transaction, using
individuals, and coercion) cannot influence the
employees‘ resistance to change. Therefore, it can be
concluded that using coercion authority not only has
not any positive effectiveness for organization, but
also this can decrease the employees‘ participation.
The results of the studies that have been done by
Safari (2003); Hoseyni (2003); Norbakhsh and
Mohamadi (2004); Mozafarian and Tatabaeian (2003)
indicate that the manager‘s coercion and punishment
authority is considered as the final mechanism for this
purpose. Because the managers believe that coercion
and punishment has not any positive benefits for their
managerial system.
Also the results of this study in terms of the
relationship between the manager‘s expertise reward
and the methods of dominating the employees‘
resistance to change indicate that there is not any
significant relationship between the manager‘s
expertise reward and the methods used for dominating
employees‘ resistance to change. In other words, the
use of expertise authority by organizational managers
cannot influence the methods of dominating the
employees‘ resistance to change (including
communications, using facilities, participation,
transaction, using individuals, and coercion). It is
should be remembered that final comment in this area
needs more studies and researches. Folger and
Skarlicki (1999); Akmal and Miller (2003); Ford
Ford, and D‘amelio (2008) found that prejudice and
injustice are the most effective factors on the
employees‘ resistance to change. Based on these
findings, it can be concluded that if the employees
perceive any injustice and prejudice in the
organization they will not accept these changes. On
the other hand, if the managers have desirable
knowledge and expertise in this area, they will believe
on the security, safety, and silence as the main
effective factors on the change acceptance. The results
of this study in terms of the relationship between the
manager‘s reference authority and the methods used
for dominating employees‘ resistance to change
indicate that there are significant correlations between
the reference authority and the methods of employees‘
resistance to change. In other words, if the
organizational managers use the reference authority
can improve their employees‘ participation positively.
This also can influence transaction methods and using
individuals negatively. Therefore, it can be concluded
that if the managers have favorable personality traits
can get the employees‘ confidence and increase their
employees‘ participation in the organizational. This
leads that they perceive the changes as instruments for
promoting the organizational goals and so decrease
the employees‘ resistance to change. Jameison and
Thomas (1998) indicated that using reference
authority is one of the most important sources of
authority for increasing organizational trust level. This
also increases the employees‘ participation in the
organization. Based on the results of the previous
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 238-244, 2013
242
studies and the results of our study, it can be
concluded that the reference authority has favorable
benefits for organizations and especially accepting
changes by employees. In order to this, the
psychological education is a suitable strategy for
improving managers‘ health. This also can be used to
promote the managers‘ personality traits and increase
employees‘ trust so much that the employees accept
the changes. Based on the results of this section that
indicates there is a significant relationship between
employee‘s reference authority and the methods used
by manager for dominating the employees‘ resistance
to change, it is suggested that the organizational
managers use the reference authority to improve the
employees‘ participation in the organizational efforts
and accepting changes. This means that the manager
must get employees‘ confidence, reward them,
promote their positions, and increase their salaries.
* Isfahan is located on the main north-south and
east-west routes crossing Iran, and was once one of
the largest cities in the world. It flourished from 1050
to 1722, particularly in the 16th century under the
Safavid dynasty, when it became the capital of Persia
for the second time in its history. Even today, the city
retains much of its past glory. It is famous for its
Islamic architecture, with many beautiful boulevards,
covered bridges, palaces, mosques, and minarets. This
led to the Persian proverb ―Esfahān nesf-e jahān ast‖
(Isfahan is half of the world). Numerous universities
have established in it and the University of Isfahan,
the Isfahan University of Medical Sciences and
Industrial University of Isfahan are the largest and
oldest public universities (Rajaeepour et al., 2011).
ACKNOWLEDGEMENT
The authors are thankful to Dr. Shakiba, Maryam,
M.D and Nosrati, Farimah ( MSc) for providing the
necessary facilities and technical assistants.
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French W, Bell H.C (2001). The Change Management
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Climate in Mashahd High Schools, M.A. Thesis
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University of Ferdwossi Mashahd, Mashahd,
Iran.( In Persian).
Hoseyni ST (2003). Examining the Relationship
between Authority Sources and Leadership
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Management, Kerman Branch, Islamic Azad
University, Kerman, Iran. ( In Persian).
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sample size for research activities. Educational
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Mozafari SA, Tabatabaeian SA (2003). Examining the
Relationship between Sources of Authority and
Effectiveness of the Performance of the Head of
Faculities and Head of the Physical Education
Departments from Faculty Members‘
Arbabisarjou et al.
The Relationship between Power Resources and the Procedures of Overcoming Employers’ Resistance against
Organizational Changes among Managers of the University of Isfahan and Isfahan University of Medical Sciences, Iran
243
Perspective. Journal of Sport and physical
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Relationship between Leadership Styles and
Sources of Authority among Head of Physical
Education Departments from Faculty Members‘
Perspective, Vol. 19, pp. 109-124.
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A, Ajdari Z, Yarmohammadzadeh P (2011).
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(In Persian).
Thomas, Craig W (1998). Maintaining and Restoring
Public Trust in Government Agencies and their
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International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 238-244, 2013
244
Assistant Professor, Dr. Azizollah, Arbabisarjou, RN,MSN, PhD, obtained his first academic degree in
1997 in the Nursing management field. He joined as faculty member to Zahedan University of Medical
Sciences, IRAN. He received his doctorate from University of Isfahan in field of Educational
Administration in 2011.Currently, Serves School of Nursing and Midwifery and the manager of
Curriculum development in EDC. He has published numerous referred papers about patient teaching,
knowledge management, management and so on in ISI, Non-ISI and Scientific-professional journals.
Dr. Arbabisarjou is teaching for Master students of Information Technology management, MBA and
Educational Administration. Also, he has conducted numerous consulting and research works for
masters‘ student and colleagues.
Professor in Education, Dr. Seyyed Ali, Siadat, PhD and faculty member at University of Isfahan. He
has obtained his doctorate from United States of America. He is teaching for undergraduates and
postgraduates students ( Masters and PhD) about Educations principles, Educational Administration,
Budgeting in Education, Accounting in Education, Theory and concepts in educational administration,
Knowledge Management, special English for postgraduates candidates. He has published numerous
referred papers about patient teaching, knowledge management, management, education and so on in
ISI, Non-ISI and Scientific-professional journals. Dr. Also, he has conducted numerous consulting and
research works for masters‘ student and colleagues and PhD candidates.
Narges Moayed obtained B.A in field of Educational Planning and Administration from University of
Isfahan in 2006. She received M.A from University of Isfahan in field of Educational Administration in
2008. She has published articles in the field of educational management and on topics related to it.
Currently, she teaches in schools and universities.
Zahra -Sadat Mahmoudi obtained B.A in field of Educational Planning and Administration from Isfahan
University in 2006. She received M.A from Isfahan University in field of Educational Administration in
2008. She interested in teaching and research activities and writing articles in the field of educational
management. Currently, she is preparing for entrance exam of PhD right now.
Rezazadeh, Shekoofe-al-Saadat, M.A in Curriculum, School of Educational Sciences and Psychology.
She has graduated from University of Isfahan. She interested in doing research in the field of
Knowledge management, Organizational Health, Cultural activities of students. Currently, she teaches
educational administration, Principles of planning, Methodology in behavioral sciences Payam Noor
university.
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 245-253, 2013 Available online at http://www.ijsrpub.com/ijsrk
ISSN: 2322-4541; ©2013 IJSRPUB
http://dx.doi.org/10.12983/ijsrk-2013-p245-253
245
Full Length Research Paper
Calculation of Lattice Parameters and Energy Band Structure and Density of States
the β-ZrNCl with Ab Initio
Khatereh Sarvazad*, Soroosh Zarghani
Department of Physics, Abadan Branch, Islamic Azad University, Abadan, Iran
*Corresponding Author: [email protected]
Received 18 April 2013; Accepted 29 June 2013
Abstract. In this article we will compute structural parameters, band structure and density of state for the β- ZrNCl compound,
based on the Density Functional Theory and the solution of the Kouhan-Sham equations. The calculations have been done
through PWscf software. In this study, soft pseudopotentials have been used for this compound. The volume of β-ZrNCl unit
cell decreases by increase of pressure. The pressure may cause different effects from various directions on the bonds. By
increasing the pressure, the amount of decrease in “c” constant is 1.3 more than of “a” constant and the reason is that β-ZrNCl
is an anistropical structure. Since the compressibility is low, it can be said this compound is very hard. The band structure
shows that this compound is a semiconductor with an indirect bandgap of 2.75 eV. By the partial density of state, it is
identified that the Nitrogen atom plays an important role in β- ZrNCl properties and the electrons of “ P” orbital in the” N”
atoms are very effective. The calculations have a good correlation with the experimental results.
Key words: density functional theory - structural parameters - pseudopotential - lattice constant - band structure-density of
state.
1. INTRODUCTION
Layered compounds have attracted a great deal of
attention due to their structural flexibility and
interesting physical properties including
superconductivity. Zirconium nitride chloride have
two forms: form “α” low temperature with layered
structure type FeOC1 and form “β” high temperature
with layer structure type CdBr2. The form “α “is very
resistant in humidity while the form “β” which is
considered in the research is stable even in the water.
β-ZrNCl has been found by Yamanaka in 1996
(Yamanaka, 1996). This compound is a special
layered structure and is composed of structural slabs
of {Cl –Zr -N–N –Zr- Cl}. Three such slabs are
stacked rhombohedrally along the c-axis to build the
unit cell (Chen, 2001).
β-ZrNCl was prepared by the reaction of Zr
(99.9%,325 mesh) with NH4CI(99.5%)at 650 0C for
30 min under the flow of NH3 gas(99.9,20-
50cm3/min). Obtained samples were purified by a
chemical vapor transport method (Kawaji, 1997;
Yamanaka, 1998). This composition is an n-type
semiconductor with an activation energy of 50-60
meV and it has a band gap of 3.4 eV(Ohashi, 1989).
Upon Li intercalation, the system turns into a metal
and superconducting state at low temperatures. This
is the first superconducting layered nitride (Taguchi,
2006; Takano, 2008). Figure (1) shows the crystal
structure of β-ZrNCl (Shamoto, 1998). According to
the studies, very few theoretically studies have been
done on this material. In this paper, calculations are
performed on the structural and electronic properties
of the β-ZrNCl composition which include computing
the lattice parameters, equilibrium volume V0 ,total
equilibrium energy E0, bulk module B0, its drive B0`,
compressibility, band structure, and density of the
states which later ,computation and comparing the
results made by the other researcher will be studied.
Fig. 1: The crystal structure β-ZrNCl
2. MATERIALS AND METHODS
The calculations have been done by using pseudo
potential method in the framework of Density
Functional Theory. In this study the method of
Sarvazad and Zarghani
Calculation of Lattice Parameters and Energy Band Structure and Density of States the β-ZrNCl with Ab Initio
246
instability (us-pp) was used, therefore, it is very
important to determine the pseudopotential exactly.
β-ZrNCl has the trigonal structure with the space
group mR3 and the lattice constants that have been
measured experimentally, are a=3.604 0A and
c=27.672 0A and used in the calculations (Adelmann,
2000). The calculations have been done with or
without considering spiny interactions. To
implementation energy convergence program is
considered that with 10 cycles. The kinetic energy
cutting the electronic wave functional based on plane
waves 40 ridberg are elected which a lattice of
12*12*14 k-mesh is created.
3. RESULTS AND DISCUSSION
3.1. Calculation of lattice parameters
One of the most important parameters in the
calculations is the lattice constant .It is experimentally
measured and is available; however, it should be
calculated in order to be conically.
After optimization “k” points and cut energy, there
is need to draw an energy graph the lattice parameters
and the smallest volume is obtained which is the
optimum volume and regarding to the studied
structure, the lattice parameters can be extracted. To
do this, convergence eigenvalue of structure energy
for the different parameters have been calculated.
Due to being self-equations, we can calculate the
amount of energy to arbitrary precision. Energy
changes based on volume is given by Mvrnagan, s
state equation; the minimum energy is obtained for
this compound by using this equation. One of these
results is shown in figure (2).
-150.86
-150.84
-150.82
-150.8
-150.78
-150.76
-150.74
-150.72
-150.7
-150.68
1400 1600 1800 2000 2200 2400 2600 2800
volume((a.u)^3)
en
erg
y(R
y)
Fig. 2: Energy diagram in terms of volume β-ZrNCl.
Following these calculations, other parameters
such as lattice constant, bulk module, derivate of the
bulk module to the pressure and compressibility has
been calculated. The results are given in table (1) and
compared with the both experimental and theoretical
data made by others. In this table a&c are lattice
constants, V0 is optimum volume, B is bulk module,
B` is derivative of bulk module, k is compressibility
and Emin is the minimum energy. According to
researches, very few studies have done on this
compound and no theoretical results have been
obtained.
The result show considering spiny interactions
have a little effect on the structural parameters and
improves the volume. Compressibility is defined
converse to the bulk module and the bulk module
represents the stability of the crystal, in other words,
the more module volume means the more crystal
stability.
Now we will study effect of pressure on β-ZrNCl.
The graph of dependency of volume on the pressure
for the combination has been shown in figure (3). The
graph clears that the volume of unit cell decreases by
increasing pressure. Since the compressibility is low,
it can be said this compound is very hard.
Graph of lattice parameters changes of a/a0 and
c/c0 based on the pressure were shown in figure (4).
According to the figure the lattice parameters
decreases by increasing pressure, and it also can be
seen that the amount of decrease in “c” constant is 1.3
more than of “a” constant and the reason is that β-
ZrNCl is anistropical structure and this is due to the
difference in the type of bonds along with a,c.
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 245-253, 2013
247
Table 1: The structural parameters calculated
Experimental
results(Istomin,
1999)
In view of the
interaction of spin
Regardless of
the spin
interactions
The calculated
parameters
311.38 321.486 321.484 30
0 )(AV
3.604 3.65916 3.65915 )( 0Aa
27.672 27.7586 27.7581 )( 0Ac
7.6769 7.5860 7.5859 ac /
- 131 131 )(kbarB
- 5.24 5.24 B
- 7.63*10-3 7.63*10-3 1)( kbarK
- -150.84007 -150.84005 )(min RyE
2000
2020
2040
2060
2080
2100
2120
2140
2160
2180
0 2 4 6 8 10 12 14
P(kbar)
V((
a.u
.)^
3)
Fig. 3: Diagram of dependency of volume on the pressure β-ZrNCl
0.975
0.98
0.985
0.99
0.995
1
1.005
0 2 4 6 8 10 12 14
P(kbar)
a/a
.,c/c
.
Series1
Series2
Fig. 4: Diagram of β-ZrNCl lattice parameters changes based on the pressure
3.2. Band structure calculations
Another important result that can be derived from
simulation of crystal properties is the graph of band
structure. Nature of the crystal whether it is metal or
not, measure of energy gap, if there is and its type
whether it is direct or not, also method of distribution
of the electron states in the different energies can be
derived from this graph. Accordance of this graph to
density curve of the states could be a reason to
accuracy of the calculations. Structures of the energy
band β-ZrNCl along with different symmetric lines
are shown in figure (5).
Sarvazad and Zarghani
Calculation of Lattice Parameters and Energy Band Structure and Density of States the β-ZrNCl with Ab Initio
248
Energy
Fig. 5: Diagram structure of the energy band β-ZrNCl regardless of the spin interactions.
In this curve Fermi energy is located in the
coordinate system origin, as it is clear from the figure
(5) the levels of energy did not cut the Fermi level .It
shows that β-ZrNCl compound has indirect band gap
of 2.75 eV in the point of . Table (2) shows the
calculated band structure of this method with other
methods. The structure of energy band of β-ZrNCl
combination regarding to spiny interaction shows that
this spiny interaction has no effect on the structure and
the calculated gap has a good agreement with other
results.
Table2: Band gap compared with the results obtained by others
Theoretical
results(Hase, 1999)
Experimental
results(Ohashi, 1989)
Experimental
results(Ohashi, 1984)
The
interaction
of spin
No
interaction of
spin
Band gap
1.6-2 3.4 3 2.75 2.75 )(eVEg
- - - indirect
indirect
Type of
gap in point
Γ
3.3. Density of states
Electron distribution in energy spectrum is described
by density of states. Density of state diagram β-ZrNCl
has been drawn based on energy at the range -10 eV to
10 eV in figure (6).
L Γ ∆
X
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 245-253, 2013
249
)(eV
state Dos
)(eV energy
Fig. 6: The β-ZrNCl total density of states diagram
In the density of state diagram, zero energy scale
presents Fermi level that it has been shown with
vertical line. As it is clear from figure, maximum of
the density of states is expanded from -4.5 eV to 0eV
and approximately density of states is zero from -4.5
eV to later. For more accurate investigation about
different orbitals participation, partial density of state
of atoms energy has been shown in the next figures.
According to these figures, it can be seen that N
atoms’ share to Zr and Cl is more in dos of all
compound. Therefore it can be concluded that N
atoms have a basic role to determine the electronic
properties of β-ZrNCl. In figure (7) dos share of each
Zr atom orbitals were compared to each other. As it is
clear from figure, in Fermi level, density of states “s”
orbital in the Zr atom is almost zero. For “d” orbital N
(Ef) is about 3 state/eV and for “p” orbital is about
0.3state/eV.
Dos share of “s” and “p” orbitals in the N atom are
compared in figure (8), for “s” orbital of N atom,
peaks of energy have been located in limits 1eV to
4eV. Density of states for “s” orbital in Fermi level is
almost 0.1 state/eV. It shows that “s” orbital of N
atom has a small role in compound properties
determining.
Energy peaks for “P” orbital in the N atom are
almost expanded from -3eV to 0eV. The “P” orbital of
Nitrogen atom has basic role in electronic properties
of all compound β-ZrNCl. The N(Ef) for “p” orbital of
N atom is about 4.5 state/eV.
)(eV
state Dos
)(eV energy
(a)
Sarvazad and Zarghani
Calculation of Lattice Parameters and Energy Band Structure and Density of States the β-ZrNCl with Ab Initio
250
)(eV
state Dos
)(eV energy
(b)
)(eV
state Dos
)(eV energy
(c) Fig. 7: The zirconium partial density of states diagram for a) d orbitals b)s orbitals c)p orbitals
)(eV
state Dos
)(eV energy
(a)
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 245-253, 2013
251
)(eV
state Dos
)(eV energy
(b) Fig. 8: The partial density of states diagram of nitrogen atom for a) s orbitals b) p orbitals
Curve of partial density of states of “s” and “p”
orbitals for Cl atom is shown in figure (9). As it is
clear from figure N (Ef) of “s” orbital of the chlorine
atom is about 0.1state/eV.
Therefore “s” electrons of Cl atom have little share
in total density of state and it basically shows
unoccupied states also the N(Ef) of “p” orbital of Cl
atom is about 2.5 state/eV.
The “p” orbital of Cl atom in fact has a greater role in
the electronic properties of total compound.
4. CONCLUSION
Calculation has been done by using Ab initio
method and looking at spiny interaction and obtained
structural parameter have good compatibility with
experimental consequences. Obtained consequences
determine that spiny interaction has insignificant
effect on structural parameters and the consequences
are an emphasis on the more difficulty and less
compressibility of β-ZrNCl compound.
According to compound band structure, it is
distinguished that energy levels have not been cut
fermi level, this expresses that β-ZrNCl is a
semiconductor with band gap of 2.75eV.
By looking at to the partial density of states
diagram, it is distinguished that N atoms have
important role to determine electronic properties of β-
ZrNCl. The partial density of state of N atom shows
that s orbital of N atom has an insignificant role, and p
orbital of Nitrogen atom has basic role in electronic
properties of all compound β-ZrNCl.
)(eV
state Dos
)(eV energy
(a)
Sarvazad and Zarghani
Calculation of Lattice Parameters and Energy Band Structure and Density of States the β-ZrNCl with Ab Initio
252
)(eV
state Dos
)(eV energy
(b) Fig. 9: The partial density of states diagram of chlorine atom for a) s orbitals b) p orbitals
ACKNOWLEDGEMENT
This article is adapted from the research projects
“Calculation of lattice parameters and energy band
structure and density of states the β-ZrNCl with Ab
initio” which is supported by Islamic Azad Universit
(IAU), Abadan Branch-Iran.
REFERENCES
Adelmann P, Renker B, Schober H, Braden M,
Fernandez-Diaz F (2000).Structural Study of
Superconducting Li-doped beta-ZrNCl. J of
Low Temp. Phys., 117: 449.
Chen X, Koiwasaki T, Yamanaka S (2001).High-
Pressure Synthesis and Crystal Structures of β-
MNCl (M=Zr and Hf). Hiroshima University,
739-8527.
Hase I, Nishihara Y (1999). Electronic Band Structure
of β-ZrNCl-based nanotubes. Phys. Rev. B 60,
1573
Hase I, Nishihara Y (2000). Electronic Band Structure
of β-ZrNCl-based nanotubes. Physica B 281 &
282, 788.
Istomin SY, Kohler J, Simon A (1999). High-Pressure
Synthesis and Crystal Structures of β-MNCl
(M=Zr and Hf). Physica C, 319: 219-228.
Kawaji H, Hotehama K, Yamanaka S (1997).Valence-
band Photoemission Study of β-ZrNCl and the
Quasi-two-dimensional superconductor
NaxZrNCl. Chem. Mater., 9: 2127.
Ohashi M, Nakano H, Yamanaka S, Hattori M (1989).
Valence-band Photoemission Study of β-ZrNCl
and the Quasi-two-dimensional superconductor
NaxZrNCl. Solid State Ionics, 33/32,97.
Ohashi M, Yamanaka S, Hattori M (1989). Valence-
band Photoemission Study of β-ZrNCl and the
Quasi-two-dimensional superconductor
NaxZrNCl. Ceram, J., Soc. Jpn., 97: 1175.
Ohashi M, Yamanaka S, Sumihara M, Hattori MJ
(1984). Superconductivity of Alkali Metal
Intercalated β-Zirconium Nitride Chloride,
AxZrNCl(A=Li,Na,K). Inclusion Phenom., 2:
289.
Shamoto S, Kato T, Miyazaki Y, Ohoyama K, Ohashi
M, Yamaguchi Y, Kajitani T (1998). Electronic
Band Structure of β-ZrNCl-based nanotubes.
Physica C306, 7-14.
Takano T (2008).Effects of Molecule Intercalation In
The Layered Nitride LixZrNCl Superconductor.
Phys. Rev. B77, 104518.
Taguchi Y (2006).Optical Properties of Layered
Superconductor LixZrNCl. Phys. Rev. Lett.
97,107001.
Yamanaka S (1996). Isotope Effect In LixZrNCl
Superconductors. Adv.Mater. 8,77.
Yamanaka S, Hotehama K, Kawaji H (1998). High-
Pressure Synthesis and Crystal Structures of β-
MNCl (M=Zr and Hf). Nature (London), 392,
580.
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 245-253, 2013
253
Khatereh Sarvazad is faculty member of physics department of Islamic Azad University, Abadan
Branch, Iran. She holds MSc in Physics from IAU, Khouzestan Science and Research Branch. She is
interested in research on her educational field; she organized a research project in Physics field.
She has written the present article based on her research project’s findings on Energy Band Structure
and Density of States. She wrote this manuscript as corresponding author with the assistant of Dr.
Soroosh Zarghani.
Dr. Soroosh Zarghani is faculty member of Physics department of Islamic Azad University of Abadan,
Iran. He holds MSc in Physics from Tehran Science and Research Branch. Iran. Then He was recruited
by Islamic Azad University of Abadan, Iran as a course instructor in Physics department since 2007; and
now he is student of physical occanography in University of Khoramshahr. He is interested in research
on his educational field, he organized a research project in Physics area. He has written the present
article based on his research project’s findings on Calculation of lattice parameters and energy band
structure and density of states the β-ZrNCl with Ab initio. He wrote this manuscript with the assistant of
Khatereh Sarvazad, faculty member of Physics department of Islamic Azad University of Abadan, Iran.
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 254-262, 2013 Available online at http://www.ijsrpub.com/ijsrk
ISSN: 2322-4541; ©2013 IJSRPUB
http://dx.doi.org/10.12983/ijsrk-2013-p254-262
254
Full Length Research Paper
Democratic Regression in Nigeria: A Critical Discourse on the Character and
Tendencies of the Political Parties as Explanatory Factors
Emma E.O. Chukwuemeka1*
, Dennis S. Amobi2, Bartholomew I. Ugwuanyi
3
1Associate Professor/Head, Department of Public Administration, Nnamdi Azikiwe University, Awka Nigeria
2Senior Lecturer, Department of Public Administration, Nnamdi Azikiwe University, Awka Nigeria
3Institute of Management and Technology, ENUGU, Nigeria
*Corresponding Author: Email: [email protected]
Received 19 June 2013; Accepted 12 July 2013
Abstract. Nigeria is being confronted with many problems. Very critical and cardinal among them, is the regression in
democratic practice. Indeed, observations and research findings point to the fact that proper democratic practice in Nigeria is
increasingly becoming elusive. This situation has become a source of worry to proponents of democracy and good governance.
In realization of the centrality of political parties in democratic activities and processes, the study examined the dominant
character and the tendencies of the political parties in Nigeria in an attempt to establish their relationship with the prevailing
democratic regression in Nigeria’s Fourth Republic. In doing this, the qualitative research method of gathering data through
secondary sources was adopted. Consequently, analysis in the study was based on content analysis technique. The basic
finding is that the character and tendencies of the political parties vitiate their will and capacity to play politics democratically
and to encourage or promote democratic ideals among the citizenry. To reposition the political parties to play the role of
enhancing democratic practice in Nigeria, it was recommended that political parties should embrace competition, co-operation
and compromise as necessary ingredients of democratic politics and embarks on political education to socialize the entire
citizenry into accepting, imbibing and exhibiting democratic values in their political activities. Political parties should be more
interested in politics based on ideology and principles and for national interest and not just for selfish personal, party or ethnic
gains.
Key words: Democracy, Democratic Regression, Political parties, Ideology, Electoral fraud
1. INTRODUCTION
In the contemporary world, all nations particularly the
developing ones, are striving for the enthronement of
democracy, for the enhancement and sustenance of its
proper practice. Indeed, the democratic craze
sweeping across the whole world is as a result of its
immense advantages of serving as a critical
framework for the expression and execution of the
will of the people and for overall good governance.
Nigeria embraced Democratic ideals since her
independence 53 years ago. She however has not all
this while been lucky to realize its proper and
sustainable practice (Alfa, 2011; Idala and
Uhunmwuangho, 2012; Ugwuanyi, 2011), rather what
she has over the years, witnessed is democratic
regression as evidenced in gross violation of basic
democratic tenets as reflected in the pervasive cased
of electoral fraud, irregular elections, irresponsible
and unaccountable political representation among
others.
Extreme cases of such violations in some cases led
to the truncation of democratic civilian government
and the enthronement of military rule. For instance,
the military takeover in January, 1966 and that of
1983 were partly as a result of gross undemocratic
practices (Ogundiya and Baba, 2004).
No doubt, various institutions such as the
government, the judiciary, the police, the electoral
bodies and the political parties contribute, in varying
measures, to the democratic regression in Nigeria. In
this study, however, the focus of discourse is on the
political parties and as they exist and operate in the
on-going Nigeria’s Fourth Republic. We feel impelled
to take this focus in realization of the relationship
between the character, activities and behavioural
tendencies of political parties and the extent, manner
and nature of democratic practice (Suileman, 2011).
In the context of the focus of the study, we shall
examine and discuss the dominant character and
prevailing tendencies of the political parties in the
democratic process, highlight their implications on the
realization of enhanced democratic practice and
ultimately make recommendations for repositioning
the political parties to play expected positive roles
towards enhancing the democratic practice in the on-
going Fourth Republic.
Chukwuemeka et al.
Democratic Regression in Nigeria: A Critical Discourse on the Character and Tendencies of the Political Parties as
Explanatory Factors
255
2. EXPLICATION OF THE MAJOR CONCEPTS
It is a common knowledge that most concepts and
terms in the social sciences discipline are ambiguous
and controversial in meaning as a result of the
differing angles and perspectives from which authors
and scholars define or explain them. We will attempt
to remove such contradiction on the key concepts here
through defining and particularly operationalizing
those to capture the contextual meaning which we
seek to impose on them. For this study, we explain the
following two key terms thus:
(1) Political party: Basically, a political party is an
organized group within a country with the aim of
gaining political power either alone or in co-operation
or alliance with other parties (Emma, 2008). It could
also mean an organization under which ambit people
aspire to and acquire political power in a state (Oji,
1997). Sartori (1976) simply defined a political party
as any political group indenfiable by an official label
that presents, at election, candidates for public office.
Leed (1968), in a more elaborate form, defines
political party as a group publicly organized with the
aim of gaining political power so as to carry out
policies which it feels will serve the national interest.
In the context of this definition, political parties
acquire their meaning and relevance in terms of the
purpose for which they are formed which essentially
and usually is better organization and management of
the affairs of the state for enhanced development.
Overall, the basic creteria or features of a political
party are that:
(I) It is pre-occupied in seeking the control of
governmental powers either singly or in coalition with
another or other parties; (II) Members of the party
have common interest, values, ideals and aspirations;
(III) Its basic interest is the promotion of national
interest; (IV) It is organized under a recognized label
or name.
Generally, without political parties, the
representative model of democracy would be
practically impossible. For this, in Nigeria, like in
other democratic climes, political parties have become
an established institution of democratic politics and as
such, operate a multi-party system. As at 2011, there
were 63 registered political parties that participated in
the general elections of 2011. Some of these political
parties are Peoples Democratic Party (PDP), Action
congress of Nigeria (ACN), Labour Party (LP), All
Peoples Grand Alliance (APGA), All Nigerian
Peoples Party (ANPP), Congress for Progressive
Change (CPC), Alliance for Democracy (AD),
Democratic Alternative (DA), Democratic People’s
Party (DPP) etc.
(2) Democracy: Democracy is a system involving
institutions and processes by which leaders acquire
power through popular mandate while institutions of
state derive their mandate from the constitution
(Oshimole, 2005). Democracy, in essence is about the
sovereignty of the power of the people and the
processes and institutions through which it is
delegated.
The earliest conceptualization of democracy points
to the direct and full participation of the adult citizens
in a polity in the decision on issues and events that
affect them and their country. Such, indeed, was
called direct democracy. However, in modern times
such direct and full participation of people is no more
very feasible and practicable as the modern societies
have become very complex. Indeed, given their sheer
geographical size, population and complex nature,
democracy at the national or state level has become
the indirect or representative type. Specifically, the
indirect or representative democracy is a democracy
in which people participate in taking and
implementing decisions on the common affairs of the
community indirectly through their representatives
elected or selected for that purpose. This modern idea
of democracy has made political parties very essential
and inevitable in its processes as its effective
functioning is built on the freedom of the citizens to
choose people to govern them from the political
parties.
In all, some of the basic features of democracy as
indentified and articulated by scholars like Nwabuzor
and Mueller (1986), Dahl (1981) Wiseman (1990)
include the facts that;
- There is more than one political party competing
for powers in a non-violent manner.
- There are regular elections based on universal
suffrage.
- Elections are fairly and freely conducted.
- There is the protection of civil and political
liberties.
- There is the rule of law.
- There is tolerance for opposition.
- Rulers and political representatives are held
accountable to the ruled by means of a variety of
political arrangements.
1.2. POLITICAL PARTIES AND DEMOCTARIC
PRACTICES: THE INTERFACE
Fundamentally, the developments of political parties
are linked to the emergence and growth of
representative democracy (Oji and Okafor, 2000).
Indeed, in modern democracies, political parties have
become the traditional platform for organizing and
carrying out political activities. In reality, ofcourse,
politics would be virtually impossible to conduct
effectively nor would elections be possible to conduct
or organize properly without political parties. This
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 254-262, 2013
256
point is becoming axiomatic in view of the fact that in
contemporary democratic governance, there is rapidly
increasing reliance on the electoral process as the
principal way of constituting and legitimizing
government at both the national, state or local
government levels (Alfa, 2011).
Scholars, in their various studies, have identified
the importance of the party system to the practice of
democracy. Katz (1986), for instance, notes that
modern democracy is essentially party democracy and
that political institutions and practices that are the
essence of democratic government would be
unthinkable without the political parties. Hilder
(2003) notes to the importance of political parties in
democratic governance as he observes that political
parties are the main intermediary between people and
power and that they, as well, organize and rationalize
politics. For Tyoden (1994), no political system can
be adjudged democratic without the central placement
of political parties in its political process. Adele
(2001) also notes the importance of political parties in
a democratic governance as he argues that the political
parties are the lubricant of democracy and without
which democracy cannot function as they provide the
only credible means of harnessing the variety of
public interests and opinions that are essential for
sustaining a democratic polity.
Another very fundamental importance of political
parties in a democracy is that it makes government
effective and responsive. This is because opposition
parties functions as pressure groups and as shadow
government. In this case, such pressure makes the
ruling party conscious of the fact that it could be voted
out and replaced in subsequent elections if it fails to
perform or run government effectively. In all and as
Diamon (1997: 23) notes; “Political parties remain
important as essential instrument for representing
political constituencies, aggregating interests,
demands and preferences, recruiting and socializing
new candidates for office, crafting policy alternatives,
setting the policy making agenda, forming effective
government and integrating groups and individuals
into the democratic process”.
In the specific context of Nigeria, the 1999
constitution, in recognition of the importance of
political parties in democratic practice, provides in
section 221 that political parties shall be the basis for
any candidate to canvass for votes at any election.
The political parties in Nigeria have a plethora of
roles to play in enhancing proper democratic practice.
Very fundamental is the socializing of their party
members and the general citizenry into imbibing and
exhibiting basic democratic values. For instance, the
political parties through conscious and systematic
political education and mobilization could inculcate
not only in their members but on the general public
the following democratic values of:
(I) seeing competition and opposition as necessary
ingredients of politics; (II) approaching the game of
politics with the spirit of sportsmanship where the best
have to win and the looser, at the end of the game,
congratulates the winner; (III) being accountable to
the electorates when they are voted into political
office; (IV) ensuring effective representation of the
electorates and their constituencies; (V) eschewing the
sit tight mentality or syndrome; (VI) eschewing
prebendal orientation to politics and public political
office; (VII) exhibiting participant political culture by
being interested and actually participating in the
politics of the state and governance.
3. AN OVERVIEW OF THE STATE OF
DEMOCRATIC REGRESSION IN NIGERIA’S
FOURTH REPUBLIC
From the preceding discussion, the fact that the
political parties play critical and tremendous role in
enhancing democratic practice is no more in doubt.
However, in Nigeria’s Fourth Republic (as it even was
in the First, Second and Third Republics), the
character, and tendencies of the political parties have
not in any reasonable measure, enhanced democratic
practice. Rather, they have posed serious challenges to
democratic consolidation, deeping and sustenance and
have resulted generally to democratic regression.
These unsupportive characters and tendencies to
proper democratic practice include the following:
(I) One, formation of political parties not based on
distinct and sustainable ideology: Basically, an
ideology is a set of ideas that constitute a political
party’s goals, expectations and actions. It crystallizes
and communicates the widely shared beliefs, opinions
and values of a party (Erikson and Tedin (2003). The
issue of ideology has been central to politics,
democracy and activities of political parties across
time and space (Shola, 2009). Unfortunately, political
parties in Nigeria lay less emphasis on organizing the
society better through a given ideology (Tatalo, 2013).
Rather, the emphasis is primarily and usually on
ephemeral and ad-hoe arrangements that do not
usually offer adequate guide and framework to run the
serious business of state governance. It appears that
other forces of identity particularly ethnicity and
religious have taken the place of ideology. This
character, no doubt has far reaching implications for
proper democratic practice. Indeed, as Umezulike
(1993:181) notes; “Where the existence and
operations of political parties do not rest on or are not
informed by any difference in opinion or fundamental
issues of principle, then their democratic values is
greatly reduced”.
Chukwuemeka et al.
Democratic Regression in Nigeria: A Critical Discourse on the Character and Tendencies of the Political Parties as
Explanatory Factors
257
The pervasive electoral fraud in Nigeria could,
partly, be attributed to the inability of the political
parties to work out sustainable ideology that will
endear them to the electorates. As Oji and Okafor
(2000) observe, the lack of articulate and sustainable
ideology has reduced party politics and democratic
practice to a bread and butter game where
monetization of the political process is the bed rock of
loyalty and support. This, no doubt, significantly
erodes the aim and process of democratization. Ezeife
(quoted in Aina, 2002) notes too that political parties
in Nigeria are not ideology based and that the
emphasis is on just winning election when ordinary
political parties are supposed to base their political
actions and election program on ideology. This
situation in Nigeria is unfortunate as ideology based
politics is essential in deepening democracy and in
giving the electorates a clear idea as to which party or
candidate to vote for in an election. Beyond this, clear
and distinct ideology and manifestoes provide a clear
benchmark and templates by which the performance
of political parties is eventually measured by the
electorates and the general public. Further, through a
distinct ideology, a political party is able to proffer an
alternative world view for the electorates which is
very essential in deepening democracy.
(II) Two, low institutionalization of the political
parties in Nigeria: Political institutionalization
basically refers to a process by which political parties
become established and acquire value and enduring
stability (Huttington, 1965). Although, the extent of
political party institutionalization varies with party
systems, it is usually measured based on some factors
such as age, internal democracy, splits and mergers,
electoral stability, leadership change, party coherence,
factionalization (Janda, 1993). Kaura (2008) argues
that the level of political party institutionalization has
a direct bearing on the extent to which a political party
can contribute to proper democratic practice.
Unfortunately, virtually all the political parties in
Nigeria’s Fourth Republic have not acquired the
required and necessary attributes of
institutionalization (Shola, (2009); Alfa, (2011). For
instance, in the case of party congruence, which
according to Janda (1980), refers to the degree of
compatibility in the attitudes and behaviour of party
members, the political parties in Nigeria are very low
on this point as people join political parties for
purposes other than national interest and service to the
people. In most circumstances, people with differing
orientation in life philosophy and principles, political
attitudes and behaviour come together as members of
one political party. This low level of party congruence
explains the weakness and instability of the political
parties in Nigeria. Further, there is no significant
existence of internal party democracy among the
political parties in Nigeria (Alfa, 2011). For instance,
the scale of the participations of party members in the
nomination process for candidates for general election
is very low. This is because most of the political
parties are extremely centralized that decision in
respect of the nomination of candidates are usually
made by the top party hierarchy or the “political God
fathers” or political merchants who “buy” certain
positions for their political godsons. The issue of
automatic return tickets for PDP incumbent members
in the National Assembly, State House of Assembly
and for state governors for 2011 general elections is
no doubt, far from reflecting internal party democratic
practice. Again, on the factor of leadership stability,
Nigeria political parties have so far not fared well. For
instance, it is observed that among the leading
political parties in Nigeria such as PDP, ACN, ANPP,
CPC, and others, there are regular dissolution of party
executives, suspension of party executives and
stalwarts for alleged anti-party activities and the
emergence of parallel executives. This, currently, is
the problem in APGA, Anambra state chapter. The
PDP, Enugu state chapter witnessed similar problem
in 2011 as two parallel executives existed then. Then
again, on the factor of factorization and defection
Nigeria political parties have been characterized by
high level of factionalization and defection of party
members. It may not be far from the truth that there
are usually not less than two factions or “line-ups” in
each of the major political parties in Nigeria. Again
party defection is very rampant in Nigeria and appears
to have become a permanent feature of Nigeria
democracy (Mba, 2011). More worrisome is that most
of the cases of defection are primarily results of
failure to realize one’s selfish personal ambition,
problems in power sharing formular and dwindling
fortunes of a party (Mba, 2011). Indeed, the regularity
and reasons for defections in Nigeria belittles the
essence of ideology and spirit of opposition in a
democracy.
Indeed, on a general note, 100% of the political
parties in Nigeria could be adjudged fragile entities
that are far from being described as institutionalized.
This situation is not supportive of enhance democratic
practice as political parties can only meaningfully
perform the necessary roles in advancing democracy
if it is highly institutionalized (Shola, 2009; Saliu and
Omotala, 2006).
(III) Three, ethnic leaning of the political parties:
Nigeria is a state consisting of several ethnic groups
with the three major or dominant ones being Hausa,
Yoruba and Ibo in the Northern, Western and Eastern
parts of the country respectively. Political parties in
Nigeria since her independence in 1960 have
continued to be formed on the lines of the ethnic
groups and for their interests. For instance, in the First
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 254-262, 2013
258
Republic, Northern Peoples Congress (NPC), and
Action Group (AG) and the National Council of
Nigeria Citizens (NCNC) emerged as Hausa, Yoruba
and Igbo party respectively. In the Second Republic,
National Party of Nigeria (NPN), Peoples Redemption
Party (PRP) and Great Nigeria Peoples Party (GNPP)
essentially had northern (Hausa) origin while Unity
Party of Nigeria (UPN) and Nigeria Peoples Party
(NPP) had mainly Yoruba and Ibo orientation in their
activities and leaning respectively. In the Third
Republic, the two political parties then, the Nigeria
Republican Convention (NRC) and the Social
Democratic Party (SDP) were not so much ethnic
oriented as the two political parties were formed by
the then military government and political aspirants
just had to join. In the Fourth Republic, however,
most of the parties still assume ethnic inclination or
leaning except the PDP that has, so far, assumed a
national spread and ownership. The CPC, ANPP, LP,
ACN and APGA among others all tend to lean
ostensibly either towards the Hausa, Yoruba or Igbo
ethnic group. In the circumstance of the political
parties assuming ethnic spread, ownership and
interest, it becomes very difficult for the political
parties to co-operate in the process of democratization
as the major emphasize and interest or concern is this
circumstance is primarily on how to win elections and
control the national resources for ethnic interest.
(IV) Four, encouragement and perpetration of
electoral fraud: Ordinarily, political parties are usually
of immense assistance in controlling electoral fraud
by first discouraging party members from using
fraudulent means to gain electoral victory. Second, by
providing assistance or information for successful and
conclusive prosecution of cases of electoral fraud.
Contrarily, electoral fraud in Nigeria is committed
with the active support and connivance of the political
parties (Human Rightswatch, 2003). This explains
why the political parties are usually very eager and
willing to secure the realize of their party members,
supporters or thugs accused of perpetrating electoral
fraud. Unfortunately by this action, the political
parties make their members and the general public to
believe that electoral fraud is not only good but a
veritable and easiest way to win elections. This
behavioural tendency has far reaching implications for
the enhancement of democratic practice in Nigeria.
Ijeoma (2002) in this respect notes that in the
circumstance of electoral fraud, the norms, ethics,
values and ethos of democracy are set aside while
people are forced or deceived into supporting or
voting for given political parties or candidates. In this
circumstance, the beauty of democracy which lies in
effective competition and opposition between or
among political parties is lost. This situation becomes
more critical and worrisome in consideration of the
fact that democracy thrives or flourishes better in a
multi or two party systems. In the circumstance of
intolerance to opposition as it obtains in Nigeria, a
ruling party, at the national, state or local government
level, would always use its power or position of
incumbency to force out opposition parties from the
electoral game or force them to join it. Following the
experience in the general elections of 2003, 2007 and
2011 in Nigeria, opposing political parties have come
to realize that it is not easy to dislodge a ruling party.
Hence, the need to join it. In this circumstance,
politicians versed in the art of political dialogue,
constructive criticism and skillful negotiations are
increasingly becoming irrelevant in Nigeria. In this
circumstance, indeed, the entire objective of political
pluralism becomes unrealizable.
Certainly, electoral fraud particularly as it relates
to election rigging and stealing of electoral mandates
harms the democratic process by, for instance, making
the people to become politically apathetic, alienated
and indifferent to the democratic process as they
realize that their votes may not eventually count in
determining who wins an election. Again, it does not,
on the side of political parties inculcate in them the
zeal and need to produce better policies, programs or
manifestoes or to present credible candidates for
election and does not, on the part of the individual
politicians too help to motivate or nuture their
political or democratic competences or potentials.
(V) Five, poor representation by the elected
candidates/poor governance by the ruling political
party: Indeed, political parties have become inevitable
in the context of representative democracy practiced
in most countries of the world today (Oji, and Okafor,
2000). Further the positive relationship between
democracy and good governance is globally
acclaimed. This is borne out of the belief that
democracy as based on the principle of the rule of law
and constitutionalism is capable of ushering in good
governance and societal development. Basically in a
representative democracy, people elect candidates to
represent them in government. The election and
representation could be in the status of the president
of the country, a state governor, a local government
chairman, a senator, a member of the House of
Representatives, a member of the state house of
Assembly or a councilor in the legislative arm of the
local government. The election of these
representatives is invariably on the basis of political
parties. The expectation of the electorates is that the
elected candidates will individually represent them
effectively and that the elected ruling party would
provide over all good governance for them and for the
entire period between elections. Such effective
representation and good governance if provided by the
candidates and political parties respectively re-enforce
Chukwuemeka et al.
Democratic Regression in Nigeria: A Critical Discourse on the Character and Tendencies of the Political Parties as
Explanatory Factors
259
people’s interest on a democracy as a system of
government. In Nigeria, however, what people have
been witnessing since the inception of the Fourth
Republic in 1999 is poor political representation and
bad governance. These are re-enforced by the
prevailing tendency of the political parties to concern
themselves more with enhancing their corporate
interest and that of their individual members at the
expense of the overall good governance for national
development. The implication of this for proper
democratic practice is that such induces the citizens to
develop feelings of apathy and cynicism towards
democratic and electoral activities specifically as they
begin to conceive acquisition and utilization of
political offices arising from elections as not serving
their interests or advancing their well being. Indeed, in
Nigeria, the prevalent and common observation is that
political representatives like senators, members of
House of Representatives, and members of the State
House of Assembly and even the local government
councilors pursue primarily their selfish private
interest and abandon all the pre-election commitments
and promises of effective representation. Rather, they
amass stupendous wealth, fly into their respective
poor constituencies in private jets, drive around in
posh cars and erect luxurious edifices, all to the
chagrin of the poor people that elected them (Akin,
2010).
(VI) Six, undue antagonisms by the political
parties against each other: It is a commonly held
belief that the survival of the democratic process is
directly linked to the ability of the political parties to
aggregate freely, articulate and organize sentiments in
the quest for acquisition and use of political power.
Two, democracy is all about competition, bargaining
and compromise that are expected to be facilitated by
political parties. However, the contrary is the case
among the political parties in Nigeria as there are
usually and frequently antagonisms, conflicts and
misunderstanding among them. For instance, the
ruling party in Nigeria, the PDP is always critical of
any move or opinion expressed by other political
parties. So also are the non-ruling or governing parties
(opposition parties) reigning invectives and
sometimes, unconstructive criticism on the ruling
party, PDP at every available opportunity
(Mohammed, 2006). Under these circumstances the
political parties cannot co-operate to ensure the
consolidation and sustainability of democracy in
Nigeria.
Following the character and behavioural
tendencies of the political parties in Nigeria as
discussed above, the democratic practice in Nigeria
since independence down to the Fourth Republic has
continued to be characterized by regression instead of
growth. This has continued to dim the hope of
democratic consolidation and sustenance. The
experience becomes more disturbing as 53 years is a
time long enough for democratic practice in Nigeria to
have become fully and properly entrenched. It is,
therefore, unfortunate that the undemocratic activities
of the political parties as witnessed in the First,
Second and Third Republics are still being
experienced today.
4. RECOMMENDATIONS
Putting Nigeria’s democratic practice on the path of
growth and sustainability lies essentially on the
following:
(1) The political parties generally eschewing
tendencies and activities that are in themselves
antithetical to the proper practice of democracy. In
this case, the political parties should:
(i) Allow for free and fair conduct of elections both
at inter-party and intra-party levels. It is further in this
direction recommended specifically that the ruling
party, the PDP at the national level need to allay the
fears of domination and marginalization by other
parties by creating grounds for free and fair political
activities and electoral conducts; (ii) Not be engaged
in politics primarily for selfish personal gains; (iii)
promote high quality representation of the electorates
and ensure general good governance
(2) The political parties must have a clear and
comprehensive ideology on which to operate and then
attempt to achieve electoral victory through presenting
good manifestoes. It is the ideology and the
manifestoes that will help to sharpen, clarify, and
crystallize the basis for choice of candidates or party
by the voters or the electorates.
(3) Politicians in Nigeria should eschew tribal or
ethnic politics and should form political parties with
national spread and ownership and which philosophy
and activities will be guided by national interest and
the need for advancement in the nation’s democratic
practice. They need too, to adhere to the provision in
the 1999 constitution of the Federal Republic of
Nigeria in section 222 paragraph (e) that the logo or
symbol of political parties should not contain ethnic or
religious connotation or give the appearance that the
activities of the party are confined to a part of the
geographical area of Nigeria.
(4) For the fact that building and sustaining a
democratic culture depends more on the internalized
democratic values and attitudes by the citizen than on
the drafting and existence of political or electoral
laws, we recommend with greater emphasis, that the
political parties should engage in systematic and
continuous mass political education and mobilization
of the people. Through this, the right political or
democratic attitude could be inculcated into the
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 254-262, 2013
260
citizens who would always naturally exhibit such in
their political life and activities. Indeed, the
performance of this function is very imperative
because the whole essence of the political parties
getting involved in democratization basically relates
to the mobilization and conscentization of the people
to accept, imbibe and exhibit democratic values and
tendencies in their political activities. It is possible
that through political education and sensitization, as
may be provided by the political parties, the Nigerian
citizens’ political attitudes and values could be
reformed and mobilized in the direction supportive of
proper and sustainable democratic practice.
Hopefully, with such a solid democratic culture
among the citizens, the nation’s democratic practice
could move from the state of regression to the state of
growth, consolidation and sustainability.
5. CONCLUSIONS
Political parties play critical roles in enhancing proper
democratic practice. Contrarily, in Nigeria, the
political parties make their own contribution, in more
measures, in the direction that results to regression of
democratic practice. Indeed, Nigeria political parties
are not helping to build democracy. Rather, they are
assisting in building institutionalized culture of
intolerance to opposition, formation of political
parties not based on a given ideology, formation of
political parties based on ethnic or religious sentiment,
prebendalism, poor political representation, bad
governance, electoral fraud/violence etc. For them to
play meaningful roles in growing democratic practice
in Nigeria, the political parties need to adopt the
recommendations as made above. This we believe is
possible if they realize that sacrifices need to be made
to ensure the growth and proper enthronement of
democracy and that when this is done, the dividends
of democracy would be enjoyed by all and sundry.
This is because democracy, if fully and properly
entrenched, creates on its own enabling condition or
framework for having good leaders, effective
representation and their corollary good governance.
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Management and Technology, Enugu Nigeria. He is married with children and widely published.
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 263-275, 2013 Available online at http://www.ijsrpub.com/ijsrk
ISSN: 2322-4541; ©2013 IJSRPUB
http://dx.doi.org/10.12983/ijsrk-2013-p263-275
263
Full Length Research Paper
An Investigation into Factors Affecting Productivity of Produces by Karoun
Agriculture and Industry Company
Mehdi Basirat1, Mehrafarin Latif
2*, Ali Asghar Esfandiari
3
1Assistant Professor and Head of Economics Department, Science and Research Branch, Islamic Azad University, Khouzestan,
Iran 2MA Student, Department of Economics, Science and Research Branch, Islamic Azad University, Khouzestan, Iran 3Assistant professor, Department of Economics, Science and Research, Islamic Azad University, Khouzestan, Iran
*Corresponding Author: [email protected]
Received 10 June 2013; Accepted 15 July 2013
Abstract. Due to the limitation of production factors, our world today is in a vital need for enhanced productivity, in both
developed and developing countries. Hence, productivity and provision of proper approaches will lead to the improvement of
economic situation. This study investigates productivity of production factors in Karoun agriculture and industry in the period
between 1981 and 2010. The results obtained from the fitting of the model indicate that variables have the condition for the
convergence test and there is a long-term balance correlation between the variables. In order to investigate the short-term
dynamics and its correlation with long-term relationships, error correction model (ECM) was used. Results obtained from this
model indicate that, as expected, ECM sign is negative and its value is 0.61. In order to calculate productivity, detailed
productivity method (mean and final productivity) was used. The results obtained from this study demonstrate that the main
variables, such as labour and capital, affect productivity. Tensions obtained from fitting of the model demonstrate the share of
each factor. The tension of capital and labour is respectively 0.013 and 0.373 in a way that productivity of capital was
increased in some years and decreased in some others, showing a fluctuant decreasing trend on the whole. On the other hand,
productivity of labour increased in some years and decreased in some years, but it showed a fluctuant increasing trend on the
whole.
Key words: productivity, production function, Karoun Agriculture and Industry Co., Total factor productivity (TFP),
Regressive distributed Lags (ARDL)
1. INTRODUCTION
Productivity is regarded as one of the important
concepts of economics as it shows the relationship
between the use of production factors and the
produce. On the whole, productivity could be
considered a combination of efficiency and
effectiveness. Efficiency refers to conducting a task
accurately and is related to beneficial use of the
resources. Effectiveness means accurate task, meaning
that it is possible to produce more outputs by a lesser
use of inputs although the output might not have the
quality desired by the consumer. In terms of
productivity, the first important issue is that the task
needs to be accurate and beneficial and then this tasks
needs to be performed in the best possible way. If
these two conditions are met, it could be ensured that
productivity has been realized. The increase in
productivity of production process will be translated
into usage of a certain level of inputs to have more
production (Abtahi and Kazemi, 2006).
The significant production inputs are the labour
and capital factors. Therefore, the two concepts of
productivity of labour and productivity of capital are
in fact the efficient use of the labour and capital
factors. In addition, total factor productivity (TFP)
shows the efficient use of the combination of the
mentioned factors. Growth of TFP not only effects of
quantitative growth of production inputs, but is also
one of the important factors that lead to economic
growth. It is in fact a type of management in the use
of production resources. Nowadays, sugar is regarded
as an important and strategic good and the ability is
producing this produce is both economically and
politically significant. However, the recent efforts of
the government in producing sugarcane and its
secondary produces are of great importance. Karoun
Sugarcane Agriculture and Industry is among the
centres for producing sugarcane and refining it into
sugar and the related produce in Iran (Khoozestan
province) (Saeedi, 2001). This article aims to answer
the following questions:
Is there is a strong and direct correlation between
capital and productivity in Karoun agriculture and
industry?
Has productivity of capital and labour increased in
the period under study?
Basirat et al.
An Investigation into Factors Affecting Productivity of Produces by Karoun Agriculture and Industry Company
264
1.1. Theoretical Foundation
Productivity is one of the new criteria for measuring
progress in production. This concept adopts an
economic perspective to investigate the application of
production factors as well as the access to pre-
determined goals. There is a difference here between
the concepts of production and productivity.
Production does not necessarily mean higher
productivity, but it is the produced output. On the
other hand, productivity is the ratio of produced
outputs to consumed inputs. Therefore, it is possible
that in a given year, production is increased but
productivity is decreased. For instance, the total
annual sugarcane harvest or sugar production of an
agency might be satisfactory without any satisfaction
with regard to improvement of productivity of the
inputs. In other words, the increase in production is
the result of the higher use of materials and inputs.
Meanwhile, if the ratio of the increase in production to
the increase in used materials shows a decrease in the
ratio of output to input, it indicates productivity of the
agency has decreased. In other words, productivity
decreases when the input illogically increases in
comparison to the output (Rahmati Andami, 2007).
When analysing the performance of an agency,
productivity, efficiency, and effectiveness are usually
considered to be the same and are used alternatively.
However, it should be noted that these words are
different from one another. Efficiency is the ratio of
actual output to the standard or required output, or it is
the ratio of the work that is done to the work that
needed to be done. Effectiveness refers to the degree
of achieving the goals and productivity refers to the
ratio of outputs to inputs.
A significant issue is that according to physical
laws in machines, efficiency, which is the result of
face capacity to present capacity, is never 1 and it is
always lower than 1. However, when it comes to
human beings, proper motivation and leadership could
help to make this quotient higher than 1.
Effectiveness is the degree of achieving the set goals.
In other words, effectiveness shows to what extent
efforts have been translated into the intended results.
However, the usage and productivity of resources for
achieving the goals is related to efficiency. In fact,
effectiveness is related to performance and human
satisfaction of performed efforts. Efficiency is related
to proper exploitation of resources; in other words,
productivity is the combination of efficiency and
effectiveness. It could be seen that efficiency has a
quantitative aspect but effectiveness has a qualitative
aspect. In addition, efficiency and effectiveness are
not necessarily in the same direction and their changes
are not the same. This is due to the fact that efficiency
includes the results and outputs that are not
necessarily all desirable and ideal. Therefore, proper
attention should be paid when using such terms as
efficiency, effectiveness and productivity. Based on
the above explanations, it could be said that
productivity has three criteria:
1. Efficiency (doing a task successfully); 2.
Effectiveness (performing the right task); 3.
Consistent application of production factors; in other
words, it means consistently performing a task
without wasting time or resources or without wasting
labour and machines. Therefore, productivity is
consistent performance of the right task and it
indicates efficiency, effectiveness and the consistency
of performance. The increase in productivity as the
result of better application of the inputs used in the
production process of an agency is usually translated
into an increase in production and a decrease in the
costs of production, thus benefiting the agency.
However, the opposite of this trend is not necessarily
right. In other words, the increase in profits could not
always be regarded as the increase of productivity.
This is because profits of an agency could be the
result of the increase in demands or the increase in the
products’ prices, thus not being related to the better
use of resources by an agency. Even when
productivity is low, an agency’s profits might
increase. The increase in profits could be the result of
better application of production resources (Varzeshi
and Esfandiari, 2009).
2. PREVIOUS STUDIES
Tavakoli et al. (2000) measured and analysed
productivity of production factors in large industry
groups in Iran in the period between 1972 and 1993.
They investigated the indices of productivity in the
two groups of detailed and total productivity of
production factors. In terms of detailed indices,
productivity of labour and capital was considered as
the ratio of production to the related input and in
terms of total productivity indices, productivity
growth was measured and analysed with regard to the
a series of production factors using basic solo and
divisia indices. Moreover, they used an exponential
function to estimate capital inventory. The results
obtained from calculation of productivity indices
indicated that detailed labour productivity had a 48.9
percentage growth and capital productivity had a 13
precent negative growth in the period under study.
Study of detailed productivity as per industrial
activities indicated that labour productivity had an
increasing trend except for paper and carton
industries. However, capital productivity showed a
growing trend only in the resources belonging to non-
metal mineral products, fundamental metals, and other
various industries and demonstrated a decreasing
trend in other industries.
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 263-275, 2013
265
Amini (2002) measured and analysed the factors
affecting productivity in non-oil sectors of the Iranian
economy and economic prospect in the third
development plan. He first explained the factors
affecting labour and capital productivity and then
investigated the total performance of non-oil sector
and the performance of each sub-sector in the period
between 1956 and 1999. He then provided a prospect
for them in the third development plan and calculated
the share of productivity of total factors of growth in
the period between 1956 and 1999. In this study,
agriculture sector demonstrated the best performance
and “other services” sector (including services other
than transport, warehousing, and communications)
had the worst performance with regard to efficiency of
using production factors. On the whole, production
sectors enjoyed a high degree of productivity in the
use of resources. In contrast, service sectors were
either not successful or only slightly successful in
terms of efficient use of production factors. Share of
productivity in production growth in the whole non-
oil sector was 13.8 precent and it was predicted to
increase to 20.6 precent in the Third Development
Plan.
Ghalambaz et al. (2008) estimated the production
factor and productivity models in Karoun Gas and Oil
Exploitation Co. productivity and its production
factors was estimated for the period between 1986 and
2008. In order to conduct this study, first the
reliability of variables was tested using the augmented
Dickey–Fuller test (DFT). Then, the error correction
model was estimated using Engle and Granger co-
integration approach. The results demonstrated that in
the period under study, the function is Cobb–Douglas
and the mean of productivity growth in Karoun Gas
and Oil Exploitation Co. is 8.3 precent. The tension is
0.64 for the labour, 0.15 for the capital and 0.55 for
energy. The result obtained by Wald test indicates that
in comparison to the scale, the return in increasing is
1.34. Ernesto (2002) conducted a study on the
productivity of industries in Mexico and found out
that the increasing competition in import and accesses
to US markets have a positive and significant effect
on the total productivity of production. In addition,
foreign investments too have a positive effect on the
productivity of factors in industries in this country,
although the overflow resulting from this capital to the
country’s industries is slight. Krueger and Tuncer
(2006) studied productivity growth in manufacturing
industries in Turkey based on public and private
sectors and claimed slower productivity growth
coincided with periods of a more stringent trade
regime their study also showed that despite the fact
that the rate of growth of TFP was about the same in
the public and private sectors, levels of inputs and
production factors in the public sector enterprises
were much higher than in their private sector
counterparts. Dirk Pilat (2009) compared productivity
of industries in South Korea with the productivity of
similar functions in the US and Europe. Although in
this study, productivity of some industries like leather,
metals and machineries was to a similar level as
European industries, the TFP of Korean industries was
26 precent of the productivity in the American
industries. According to Pilat, such factors as capital
intensity, savings as the result of production scales in
industries, and levels of education of the labour force
were among the most influential factors in the
difference between productivity of industries in South
Korea and the US. and Reddy (2010), studied the
productivity trend in Andhra Pradesh products in
India. In order to calculate the productivity of the four
industries of cotton, tobacco and coke, food products
and paper, Trans log production function and divisia
index were used. Their explanatory variables in
functions included capital inventory, labour force, and
consumed fuel. The variable of time was added to the
production functions as an input to study the technical
progress and the GDP was also used as a dependent
variable. After calculating TFP using divisia index,
they concluded that TFP in all industries except for
cotton products industry had a decreasing trend. TFP
index of cotton products industry was increased
during this period despite having some slight
fluctuations. Desini et al. (2010) used econometric
methods to study and test the role of internal
restructuring (such as using modern technology and
structural changes) and external restructuring (such as
entering and exiting the market and changes in market
share) on productivity growth in industries in
England. They concluded that external restructuring
affects 50% of changes in labour productivity and
90% of changes in the TFP. Thirtle and Bottomley
(2012) measured productivity of total production
factors in agriculture. This paper analyses the
relationship between production functions and TFP
index. The results showed that intensive growth in
agricultural productivity was proportional to other
economic sectors. Rosegrant and Evenson (2012)
investigated changes of efficiency in a paper whose
title was “Agricultural productivity and Growth
resources in south Asia”. The results showed that a
high rate of efficiency was estimated to invest in
public researches, which is indicative of profitability
and need for continuity of this investment. Efficiency
is the origin of wealth and growth possibility is
prepared in long-term based on new theories of
economic growth of efficiency.
Basirat et al.
An Investigation into Factors Affecting Productivity of Produces by Karoun Agriculture and Industry Company
266
Table 1: Summary of series Unit-Root test
Table 2: Summary of series Unit-Root test
Table 3: Autoregressive Distributed Lag Estimation ARD(1,2,0,1,1,2,0,0)
3. METHODOLOGY
The methodology used in this study is descriptive-
analytic. Te data used in this study was collected
using the library method from Karoun Agriculture and
Industry Co. in the period between 1981 and 2010.
3.1. Calculation of Productivity
In order to calculate productivity, two methods have
been recommended by economists: econometric and
non-parametric methods. In the econometric method,
calculation of productivity is performed through
estimating a production function or a cost function. In
the non-parametric method, productivity is determined
by using mathematical planning or by calculating the
index value (Abtahi and Kazemi, 2006). This study
used the first method. Therefore, if the production
functions is assumed to be as follows:
y= (x1 , x2 , … , xn) (1)
It is possible to calculate average productivity
APxi and final productivity MPxi of each production
factor, assuming that the following conditions are
fixed:
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 263-275, 2013
267
(2)
(3)
By estimating one production function, MPxi
could easily be calculated. With regard to Cobb–
Douglas function, MPxi is as follows:
(4)
Where Y refers to the product, Xi the input, and ei
the elasticity of each input.
3.2. Total Factor Productivity (TFP)
After the Second World War, many economists
focused their studies on TFP. TFP (labour and capital
simultaneously) in fact indicates the average
production for each unit of the whole production
resources. This index indicates the balance of the
changes in productivity of labour and capital. GDP
growth or added value in each economic sector is
performed in two resources (Valizadeh Zonooz,
2005).
1. Input Increase (Labour and Capital); 2.
Structural Improvement (machineries, equipment for
improving the quality of labour and management)
Detailed productivity, including labour and capital
productivity, might not be able to explain the increase
in the efficiency of production factors and thus the
current conditions of the industry. Meanwhile, TFP
could explain how production factors could be used
properly and productively as it takes into account the
changes in those factors that leave the biggest role in
the production process, and thus it could be used to
have proper economic policies by industrial-economic
policy-makers.
TFP growth rate could be calculated using the
following equation:
KPALPAPFT kL
(5)
where TFP is the total factor production growth,
APL is labour productivity growth, APK capital
productivity growth, nL is the productive tension of
labour input, nK is the productive tension of capital
input.
3.3. Regressive distributed Lags (ARDL)
Unreliability of the variables might lead to artificial
regression, and thus damage the confidence about
estimated coefficients. Therefore, based on the co-
integration theory in modern econometrics, when
using time series in estimation of the models, it is
necessary to use the approaches that take into account
both reliability and co-integration.
Using the models that have short-term dynamics
will help to have more exact estimated coefficients.
On the whole, a dynamic model is one in which
variables’ lags could be considered as in equation 6
(Tashkini, 2005).
(6)
In order to decrease biased estimators in smaller
samples, it is recommended to enter a large number of
lags for variables in the model.
(7)
The above model is called ARDL, in which:
(8)
(9)
L is the operator of the lag, Lnxt=xt-n is a vector of
fixed variables like intercept and the virtual variables
of time trend. Microfit software estimated the
equation times (m+1)k+
times. M is the maximum
number of lags that is set by the researcher and k is
the number of explanatory variables. Then, one
Schwartz-Bison, Akaike, Hannan Quinn criterion is
used to choose one of the questions:
3.4. Error Correction Model (ECM)
Co-integration between a series of economic variables
is the basis for using ECM. ECM is in to fact related
short-term fluctuations (short-term imbalance) of
variables to their long-term values. According to
Engle and Granger, each long-term correlation has a
short-term ECM that guarantees the balance and vice
versa.
These models are in fact a type of detailed balance
models in which forces affecting short-term
conditions and the speed of getting close to long-term
balance value are measured by entering the stable
error terms of a long-term correlation (Tashkini,
2005).
3.5. Research Model
The model used in this model is linear and Cobb–
Douglas (Debertin, 1997; Darisavi, 2001).
Ln SHT = Ln A+α1Ln Szk +α2Ln MAM+ α3 Ln
N+α4Ln I+α5Ln IM+α6Ln KF+ α7Ln MSIB
where SHT is produced sugar, SZK is the area
under cultivation; MAM is consumed water; N is the
labour, I is the Capital (equipment), IM is the
agricultural machinery asset, KF is the phosphorous
fertilizer, and MSIB is total frost time.
Basirat et al.
An Investigation into Factors Affecting Productivity of Produces by Karoun Agriculture and Industry Company
268
4. RESULTS
4.1. Reliability
Use of traditional econometric approaches for
experimental studies is based on the assumption that
variables are reliable. Therefore, augmented unit root
DFT is used. Based on the conducted tests, it could be
concluded that in Table 1, SHT, IM, N, MSIB, KF,
SZK variables are reliable and I and MAM variables
become reliable after one difference(Table 2).
Using the dynamic model’s coefficient, the long-
term correlation between the variables is tested. To do
this, the following equation is used to calculate the
required statistic.
106/0
138/0 -5/84
The statistic is -5.84. Therefore, comparing the
calculated value of -5.84 and the critical value
presented by Banerjee, Dolado and Master at the level
of 99%, (-5.04), the null hypothesis of the model is
rejected and the existence of a balance long-term
correlation between the model’s variables is
confirmed. The results obtained from estimating the
dynamic model indicate that capital, machinery assets,
labour, area under cultivation, and amount of
consumed water leave positive and significant effects
on production. In addition, phosphorous fertilizer and
the total frost hours have negative and significant
effect on production. Determining coefficient of the
model is 97% and the value of statistics of Durbin-
Watson test (2.76) and f=37.7620, show the high
explanatory feature of the model and lack of co-
integration and significant between general
coefficients in the estimated model (Table 3).
The following results could be gained by observing
the pathological tests:
a). F statistic to determine the presence or absence
of co-integration is 3.08 and the minimum level of
significance of the value in parenthesis is 0.10. Taking
into account the error level of 0.05 and comparing it
with the minimum level of significance in the null
hypothesis, which indicates there is no co-integration,
the hypothesis with regard to existence of co-
integration is rejected(Table 4).
b). F statistic to determine the right or wrong
function shape is 0.0017. Taking into account the
error level of 0.05 and comparing it with the minimum
level of significance of 0.96, the null hypothesis,
which indicates there is an accurate function shape, is
confirmed(Table 4).
c). F statistic for determining the similarity
variance is 0.33. Taking into account the error level of
0.05 and comparing it with the minimum level of
significance of 0.56, the null hypothesis, which
indicates there is no different variance, is
confirmed(Table 4).
The long-term correlation between the model’s
variables is estimated using the following equation:
LnSHT=0/013LI+0/059LIM+0/373LN+0/167LSZ
K-0/073LKF+2/02LMAM-0/112LMSIB-16/39C
(2/08) (2/10)(2/92)(3/03)(-2/21)(2/46)(-
3/17)(-1/78)
Values in the parenthesis are the t-statistic relayed
to the coefficients. The results obtained from
estimating the long-term dynamic model indicate that
production is positively and directly correlated with
labour, capital, machinery assets, area under
cultivation, and amount of consumed water. In other
words, each 1% increase in labour, capital,
machineries assets, area under cultivation, and the
amount of consumed water increase production as
much as 0.37, 0.013, 0.059, 0.16, and 2.02 precent
respectively. Production has a negative correlation
with the total number of frost hours and phosphorous
fertilizer, meaning that for each 1% increase in the
total number of frost hours and phosphorous fertilizer,
production decreases as much as 0.11 and 0.073
precent respectively(Table 5).
The Coefficient for the error correction term is
significant and its expected sign is negative. The value
of this coefficient is 0.61, meaning that about 61
precent of the deviations in the variable of production
from the long-term balance value is balanced after one
period (Table 6).
4.2. Stability Test
The stability of the coefficients is studied using the
CUSUM test, showing that the coefficients of the
estimated model in the period under study are stable
(Figure 1).
4.3. Reaction Function
Reaction functions show the reaction of endogenous
variables to shocks imposed on the model’s variables
(Figure 2).
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 263-275, 2013
269
Table 4: Diagnostic Tests
Table 5: Long-Run Estimation ARDL
Table 6: Error Correction Representation for the Selected ARDL Model
Table 7: Variance Decomposition
Basirat et al.
An Investigation into Factors Affecting Productivity of Produces by Karoun Agriculture and Industry Company
270
Fig. 1: CUSUM and CUSUMQ tests for coefficients stability of ARDL model
Fig. 2: Reaction Function
4.4. Variance Analysis Test
If a shock is imposed on the dependent variable, it
will show what the percentage of the fluctuations is
the result of the variable itself and which percentage is
the result of the fluctuations in the other variables.
The results obtained from this test indicate that on
average 55% of the fluctuations in the first five years
was the result of production logarithm, 4% was the
result of machineries assets logarithm, 2% was the
result of the logarithm of the area under cultivation,
18% was the result of the logarithm of the amount of
consumed water, 15% was the result of the logarithm
of the phosphorous fertilizer, and 2% was the result of
the logarithm of the total frost hours (Table 7).
Fig. 3: Variance Decomposition
4.5. Calculation of Productivity
The results obtained from calculating the detailed
productivity (final productivity and average
productivity) and TFP are provided in Table 8 and 9
based on the following equations:
(10)
(11)
where Y is the product, Xi is the input, and ei is the
tension of each of the inputs.
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 263-275, 2013
271
5. CONCLUSION
Enhancement of productivity is production factors
translated into a decrease in prices. The decrease in
the level of prices, including production factors, leads
to the decrease of average costs of production of
goods and services in the market and the increase of
profitability of products of manufacturing enterprises.
From the perspective of micro-economics, capital and
labour are two important factors in the function of
production and they play a significant role in
increasing production. Based on the type of
production function, which is linear and Cobb–
Douglas, it directly and increasingly affects
production. Agricultural section is one of important
economic sections in the country. Much attention is
payed to this section for its important role to supply
the people’s food and to provide the primary materials
of many industries. Low productivity is one of the
serious problems in Iran. This problem is observable
in all pre- and post-productivity steps. Efficiency
growth is a necessary factor for continued economic
growth in each country. In order to increase of
efficiency in Iran’s economy, we must pay special
attention to agricultural section which is one of the
important sections and the main economic activities in
the country. Because increasing of efficiency growth
according to special economic structure of the country
in this section can help us achieve economic goals.
Realizing direction of efficiency growth in Iran
agricultural section, either for having poor economic
infrastructures or for competition on the international
scene to reach better economic success, help us to lead
our productivity equipments and resources, according
to which we can reach our proper place in
international relations. So, doing productive projects
and their appropriation in different agricultural sub-
sections are necessary. The main variables like labour
and capital impact productivity. Productivity of the
labour was increased in some years and decreased in
some others, but it shows a fluctuating decreasing
trend on the whole. On the other hand, the results
obtained in this study demonstrate that capital
increased over the period of the study. On the other
hand, productivity of capital was increased in some
years and decreased in some years, but it showed the
highest amount of decrease in 2000. On the whole,
capital productivity has a fluctuant decreasing trend.
Therefore, labour and capital productivity was not
increased over the course of the study. Therefore,
since two types of capital is used, the productivity
trend of both types of capital is studied. Since the TFP
was increased in some years and decreased in some
others but had a fluctuant-increasing trend on the
whole and since capital and machinery asset was
increased over the course of the study, it could be said
that there is not a strong and direct correlation
between capital and productivity (Table 9). Based on
the estimation of the long-term coefficients of the
model, it could be claimed that all variables of the
model, except for phosphorous fertilizer and total frost
hours, are positively and significantly correlated with
production. In better words, each 1% increase in
labour, capital, machineries assets, area under
cultivation, and amount of consumed water increase
production as much as 0.37, 0.013, 0.059, 0.16, and
2.02 precent respectively. On the other hand, each 1%
increases in the total number of frost hours and
phosphorous fertilizer decreases production as much
as 0.11 and 0.073 precent respectively (Table 5).
Policy Recommendations:
1. Increasing labour productivity through increasing
the share of educated labour force in the total labour
force due to the high capability of the skilled
workforce in using modern technologies in production
2. More attention to the problems in the sugar
production machinery lines, and particularly with
regard to the sources of producing sugar wastage at
factories;
3. More beneficial use of dry days during the period
of harvest and doing harvest in the cooler months in
order to prevent the reduction of harvested sugarcane
at the end of the period, which usually coincides with
the hot days of the year;
4. More attention to destroying the weed and
particularly resistant weeds like cockspur grass, which
have become the main target of chemicals in recent
years.
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Table 8: Total Factor Productivity and partial productivity
Average
productivity
of Capital
Average
labor
productivity
Average
productivity
of Capital
Machinery
Average
productivity of
the Acreage
Elasticity
of
Capital
Elasticity
of
Capital
Machine
Elasticity
of Labor
0631 36-E 1900/3 9003990/1 19- E
49309/0
044949004/9 106994/1 140119/1 696/1
0630 33- E
6943/9
10330999/3 13- E
30069/6
966999699/3 106994/1 140119/1 696/1
0633 33- E
0040/0
19613199/0 13- E
33013/0
394360309/9 106994/1 140119/1 696/1
0636 39- E
9169/9
30996636/1 13- E
99939/0
393439630/9 106994/1 140119/1 696/1
0639 39- E
6693/9
96939160/1 19- E
03016/9
139149090/9 106994/1 140119/1 696/1
0634 34- E
1913/0
00969999/3 14- E
91660/3
919934490/9 106994/1 140119/1 696/1
0633 39- E
0663/9
31366109/1 14- E
99694/3
931109009/3 106994/1 140119/1 696/1
0639 60-E 0919/0 04069949/1 14- E
04409/3
163409069/6 106994/1 140119/1 696/1
0639 64- E 39100043/0 13- E 104933903/9 106994/1 140119/1 696/1
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 263-275, 2013
273
3033/9 33333/6
0630 69-E 334/3 3309106/1 19- E
66900/9
963933049/9 106994/1 140119/1 696/1
0691 63-E 3166/0 9393109/1 10- E
94434/0
96004936/9 106994/1 140119/1 696/1
0690 64-E 9999/6 94099499/0 14- E
93964/3
033990944/6 106994/1 140119/1 696/1
0693 63- E
9963/0
09603639/3 13- E
49130/3
649499404/4 106994/1 140119/1 696/1
0696 69- E
9943/6
39963090/1 13- E
33306/0
60494904/3 106994/1 140119/1 696/1
0699 60- E
1314/3
6399939/0 19- E
91169/3
940963393/3 106994/1 140119/1 696/1
0694 93-E4603/0 0010314/6 13- E60303/0 443419900/4 106994/1 140119/1 696/1
0693 96-E 9199/0 9134303/1 19- E
30094/6
300434363/4 106994/1 140119/1 696/1
0699 96-E 6666/3 39091990/1 19- E 9446/0 940399439/9 106994/1 140119/1 696/1
0699 93- E
9014/0
39363669/1 19- E
36369/0
61619994/30 106994/1 140119/1 696/1
0690 36- E
3409/6
9939340/0 19- E 0433/3 399990004/9 106994/1 140119/1 696/1
0691 93-E 1939/0 39069019/1 19- E
99309/3
933064493/9 106994/1 140119/1 696/1
0690 93-E 3369/3 1119919/0 13- E
10399/0
941069006/9 106994/1 140119/1 696/1
0693 99-E 0960/0 39990399/3 13- E
93036/0
143119609/9 106994/1 140119/1 696/1
0696 99- E
9330/9
33610103/1 19- E
30694/6
303930963/3 106994/1 140119/1 696/1
0699 93- E
3990/9
91016139/0 13- E
90990/0
199936630/9 106994/1 140119/1 696/1
0694 99- E
3404/3
40413949/1 13- E
99660/0
999309934/6 106994/1 140119/1 696/1
0693 93- E 303/0 60490993/1 13- E
09036/3
199341130/4 106994/1 140119/1 696/1
0699 93- E
0949/6
09430619/3 19- E
99969/3
309090046/4 106994/1 140119/1 696/1
0699 94- E
9990/3
06399099/3 13- E 130/9 406139090/3 106994/1 140119/1 696/1
0690 41- E
9693/3
99309093/1 19- E 1003/3 303643969/0 106994/1 140119/1 696/1
Table 9: Total Factor Productivity and partial productivity
Elasticity
of Acreage
Marginal
Productivity
of Capital
Marginal
Productivity
Capital
Machinery
Marginal
Productivity
of labor
Marginal
productivity
Acreage
Total Factor
productivity
0631 03939/1 99349/3 E 34- 66499/0 E 10- 043600160/1 939000309/1 09460/1
0630 03939/1 13909/3 E 39- 0649/3 E 19- 941913306/1 033930343/0 999039/0
0633 03939/1 4639/0 E 39- 99946/0 E 19- 690130444/1 399909699/0 339043/0
0636 03939/1 14614/3 E 30- 16033/0 E 19- 330304909/1 399063099/0 406963/0
0639 03939/1 04963/4 E 30- 39919/9 E 19- 394636339/1 093699369/0 949919/0
0634 03939/1 99109/0 E 39- 90904/0 E 13- 999333099/1 963993603/1 434969/0
0633 03939/1 99000/3 E 33- 91360/6 E 13- 193030044/1 990960030/1 499309/1
0639 03939/1 93334/3 E 66- 3933/0 E 13- 649943390/1 419390933/1 933066/1
0639 03939/1 99009/3 E 69- 03900/0 E 19- 333040404/1 390939903/1 309900/0
0630 03939/1 33614/6 E 63- 44909/3 E 19- 19330949/1 903694300/1 994196/1
Basirat et al.
An Investigation into Factors Affecting Productivity of Produces by Karoun Agriculture and Industry Company
274
0691 03939/1 34600/0 E 69- 90433/4 E 01- 390333014/1 900939303/1 13614/0
0690 03939/1 99109/9 E 69- 33904/0 E 13- 346910310/1 333993394/1 603394/0
0693 03939/1 09639/0 E 69- 43399/0 E 19- 003900013/0 904906019/1 119969/3
0696 03939/1 39493/4 E 91- 99009/9 E 19- 019094009/1 130960919/0 099109/0
0699 03939/1 96306/3 E 90- 34394/0 E 19- 909130303/1 190336369/0 496306/0
0694 03939/1 00339/3 E 99- 93300/9 E 19- 001339339/0 039936394/1 000143/3
0693 03939/1 99339/3 E 94- 90009/0 E 19- 041091449/1 091169399/1 101094/0
0699 03939/1 91403/9 E 94- 49993/9 E 10- 019036999/1 904063139/0 4310/0
0699 03939/1 64019/3 E 99- 30469/9 E 01- 343396463/1 436491363/6 904939/6
0690 03939/1 16136/4 E 34- 36334/6 E 10- 916993130/1 699990309/0 199393/3
0691 03939/1 96609/0 E 99- 36904/0 E-10 349049690/1 309496933/0 443969/0
0690 03939/1 31043/9 E 99- 99993/3 E 19- 696639469/1 936933493/0 969140/0
0693 03939/1 33939/0 E 90- 01300/0 E 19- 943330194/1 091639903/0 163449/3
0696 03939/1 06934/3 E 90- 90369/0 E 19- 399613900/1 031343693/0 639444/0
0699 03939/1 03309/0 E 99- 9639/9 E 19- 43443999/1 099043343/0 910930/0
0694 03939/1 04690/0 E 90- 99309/4 E 19- 003000199/1 339110633/1 900030/1
0693 03939/1 66390/0 E 99- 39403/0 E 19- 009903969/1 990633603/1 039004/1
0699 03939/1 9393/4 E 99- 39999/0 E 19- 904336414/1 043340339/1 939004/0
0699 03939/1 03096/6 E 99- 03344/9 E 19- 90390399/1 013999999/0 900990/0
0690 03939/1 33163/0 E 43- 36930/0 E 19- 390404330/1 490196140/0 961440/0
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 263-275, 2013
275
Mahdi Basirat holds a Ph.D. in economics and Assistant Professor and Head of Economics Department,
Science and Research Branch, Islamic Azad University, Khouzestan, Iran. His areas of interest include
econometrics and macroeconomics.
Mehrafarin Latif is a graduated student of M.A economics, Department of Economics, Science and
Research Branch, Islamic Azad University, Khouzestan, Iran in 2013.
Ali Asghar Esfandiari holds a Ph.D. in economics. His areas of interest include econometrics and
microeconomics.
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 276-287, 2013 Available online at http://www.ijsrpub.com/ijsrk
ISSN: 2322-4541; ©2013 IJSRPUB
http://dx.doi.org/10.12983/ijsrk-2013-p276-287
276
Full Length Research Paper
Assessing Relationships in Kenyan Sorghum Landraces by Use of Simple Sequence
Repeat Molecular Markers
Kahiu Ngugi1*
, Rachael Maswili1,2
, Cecilia Muchira1
1Department of Plant Sciences and Crop Protection, Faculty of Agriculture, College of Agriculture and Veterinary Sciences,
University of Nairobi, PO Box 30197-00100, Nairobi, Kenya 2Kenya Agricultural Research Institute- Katumani, PO Box 340-90100 Machakos, Kenya
*Corresponding Author: Email: [email protected]
Received 13 June 2013; Accepted 17 July 2013
Abstract. In the semi-arid areas of Kenya, the effects of climate change are accelerating the genetic erosion of many crops and
threatening food security of resource-poor farmers. This study analyzed the genetic diversity of the available Sorghum bicolor
L. germplasm using simple sequence repeat (SSR) markers with the aim of identifying varieties that can be selected to meet
food security needs of these marginal environments. Accessions from four agro-ecological regions were genotyped with 39
SSR markers chosen on the basis of their position in the genome and the large repeat sizes they represented. The alleles were
called using the Gene Mapper software (version 3.7), sizes assigned with the allelobin software and the subsequent data
analyzed with the Power Marker software (version 3.25). The Arlequin software (version 2.0) was used to calculate the
diversity indices and the intra-population structure. Genetic distances were calculated according to Rogers modified distance
and the accessions were clustered using principal component analysis (PCA). A mean polymorphic information content (PIC)
value of 0.536 was observed, indicating moderate levels of polymorphism. The variability within accessions among the
populations was 56.37%, within individual accessions was 38.85% and among geographical origins was 4.78%. A low level of
genetic differentiation (FST = 0.048) and a high inbreeding level (FIS = 0.59) showed an increased degree of allele fixation. The
results showed that though most of the accessions were similar, there was sufficient genetic diversity among and within
sorghum landraces in Kenya, which would be useful in the improvement of sorghum productivity.
Key words: genetic diversity; germplasm; microsatellites; Sorghum bicolor
1. INTRODUCTION
Sorghum (Sorghum bicolor (L.) Moench is the fifth
most important grain crop worldwide as far as
production and acreage are concerned (FAO, 2010).
It is the second highly produced cereal in Africa after
maize (Gerda and Christopher, 2007). Sorghum is a
drought-tolerant crop, well adapted to marginal and
semi-arid areas (Gerda and Christopher, 2007) where
annual rainfall is between 350 to 750 mm (Markus
and Gurling, 2006). The mean grain yield for sorghum
in Kenya has been reported to be as low as 700 kg/ha
(MOA, Kenya, 1996) and the crop is grown in the
drought-prone marginal areas of North Eastern,
Eastern, Nyanza and Coast Provinces (EPZ, 2005).
As in other crops, improved grain yield has been
realized by utilizing genetic variability (Rai et. al.,
1999). Selection of varieties to meet specific food,
feed and industrial needs from the local biodiversity is
of high importance in a country such as Kenya,
because most of the preferred traits have been
consciously accumulated across years. However,
many sorghum accessions have been lost or are under
serious risk of extinction and genetic diversity has
been decreasing at a high rate mainly because of
effects of climate change (Kabubo and Karanja,
2007). As a result, many useful alleles have been
eliminated. There is a need therefore to undertake a
comprehensive assessment of the current diversity
present in the local sorghum population for use in
crop improvement (Mohammadi and Prasanna, 2003).
Assessment of genetic variability provides a
foundation for making informed decisions regarding
the management and utilization of sorghum genetic
resources. The characteristics of the germplasm
analyzed here have been described by Ngugi and
Maswili (2010). In an effort to consolidate all the
information pertaining to genetic diversity of sorghum
land races in Kenya, an earlier study had analyzed 139
accessions of sorghum collected from diverse regions
of the country (Ngugi and Onyango, 2012) but unlike
the present study, breeders’ accessions had not been
included. This study sought to widen the assessment
of genetic diversity present in the land races by
including variation generated by plant breeders while
utilizing SSR molecular markers that have been
successfully applied in other studies for the same
purpose (Mohammadi and Prasanna, 2003).
In sorghum, a number of SSR markers developed
from various sources (Bhattramakki et al., 2000;
Ngugi et al.
Assessing Relationships in Kenyan Sorghum Landraces by Use of Simple Sequence Repeat Molecular Markers
277
Brown et al., 1996) are in the public domain and have
been employed to analyze genetic diversity. SSR
markers are preferred since they are codominant and
able to reveal a higher level of polymorphism than
other marker systems (Schloss et al., 2002). SSR
alleles can be separated by gel electrophoresis and be
visualized by silver-staining. SSR analysis is
amenable to multiplexing and allows genotyping to be
performed on large numbers of lines. SSR markers are
reproducible, exhibit uniform genome coverage and
are transferable between mapping populations
(Agrama and Tuinstra, 2004). These features, coupled
with the fact that they are highly informative and
abundant, makes SSRs ideal molecular markers for
genetic diversity analysis.
2. MATERIALS AND METHODS
A total of 148 sorghum accessions comprising
landraces and farmers’ varieties were collected from
the sorghum growing areas of Kenya, namely, the
North Eastern (Turkana, 19 accessions), parts of
Eastern Kenya (28 accessions), Coast (17 accessions)
and Western Province, (45 accessions) which included
Nyanza and Kakamega. A selected number of
breeders’ lines (39) were also included from Kenya
Agricultural Research Institute (KARI) Katumani,
KARI Lanet and KARI Kakamega. The accessions
were planted out for evaluation at KARI, Embu
station in a trial replicated three times using a 14 x 14
balanced lattice design. Each accession was sown in a
plot of three rows, each row being 3 m long, with a
between-row spacing of 75 cm and within-row
spacing of 25 cm. Phenotypic data was collected from
the middle two rows of each plot and recorded using
the International Plant Genetic Resources Institute
(IPGRI) characterization descriptor list.
Table 1: Summary of the phenotypic traits of the 148 sorghum accessions analyzed by SSR for their genetic diversity
Region/accessions No. of
accessions
D/FL
GW
(gm)
Leaf
no.
Node
no
PanBr
Panl
(cm)
Western 45 89 1.6 8 8 41 20.95
Turkana 19 92 1.4 10 10 40 22.09
Coast 17 99 1.7 10 10 55 24.6
Eastern 28 85 1.5 9 9 46 19.9
Breeders’ (KARI) 39 85 1.4 8 8 42 21.26
mean 88 1.5 9 9 43.2 21.07
ANOVA
Error 175.2189 0.3739 4.5668 4.3609 213.1441 39.0345
Mean squares 480.1 0.7964 18.130 18.534 488.1 79.24
V.R 2.74 2.13 3.97 4.25 2.29 2.03
F pr. <.0.001** <.0.001** <.0.001** <.0.001** <.0.001** <.0.001**
CV(%) 15.04 40.76 23.74 23.20 33.79 29.65
Broad-Sense H 0.943 0.044 0.423 0.422 0.957 0.868
Key : D/FL =Days to 50% flowering, GW (gm) =Weight of 100 grains in grams
Leaf no. =Number of leaves at maturity, Node no. =Number of nodes at maturity PanBr =Number of panicle branches, Panl (cm) =Panicle Length
V.R.= variance ratio; Fpr.=F probability; Broad-Sense H= broad-sense heritability
The following parameters were measured: (i) days
to 50% flowering (days); as the mean number of days
from sowing to the day on which 50 % of the plants
flowered scored on 5 randomly selected plants (ii)
100 seed weight; as the mean weight of 100 well-
developed grains collected from 5 selected plants and
expressed in grams (iii) number of leaves at maturity ;
as the mean number of 5 randomly selected plants
scored during physiological maturity (iv) number of
nodes at maturity; as the mean number of nodes
bearing branches from 5 randomly selected plants
scored at physiological maturity (iv) panicle branches;
as the mean number of panicles from 5 randomly
selected plants scored at physiological maturity (v)
panicle size; as the mean length of panicle in
centimeters scored from 5 randomly selected plants.
The analysis of variance (ANOVA) was done using
the GenStat Discovery Edition 3 soft-ware and the
results presented in Table 1. Broad-sense heritability
(H) was calculated as; (H) = s2G/ s2p = s2G /[s2G +
s2e/r] where; s2G is the genetic (or genotypic)
variance, s2p is the phenotypic variance, s2e is the
plot residual or error variance from the ANOVA and r
is the number of replications. Thirty-nine SSR
markers obtained through ICRISAT (International
Crops Research Institute for the Semi-Arid Tropics)
from diverse sources (Table 2) were used to genotype
the 148 sorghum accessions. The 39 SSR markers
were chosen firstly because they represented a wide
range of the repeat sizes (from di-nucleotides to hexa-
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 276-287, 2013
278
nucleotides) and secondly because these markers
revealed a high number of alleles and had wide
genome coverage as reported in previous studies
(Table 2). DNA of 14 days old seedlings was
extracted from leaves of 5 randomly selected plants
using a modified CTAB protocol (Mace et al., 2003)
and was loaded in the gel as one sample per well. The
samples were analyzed using agarose (0.8%) gel
electrophoresis and stained with ethidium bromide (10
mg mL-1). The concentration of DNA fragments was
estimated using the intensity of the band and diluted.
The results of successful amplification of a few of the
primers with lambda standards placed at ends of the
gel for comparison are shown in Fig. 1.
The PCR reactions for the 39 primers were done
using the GeneAmp" PCR SYSTEM 9600
thermocycler (PE-Applied Biosystems) and touch-
down PCR amplification. Genotyping was conducted
through capillary electrophoresis using the ABI
PRISM 3730 (PE-Applied Biosystems) sequencer and
the microsatellite alleles were sized within 0.3 base-
pair fragments. The alleles were called using Gene-
Mapper software and the internal GeneScanTM
–500
LIZ® Size Standard. A control sample DNA of the
accession BTx623 was included during the PCR and
capillary electrophoresis.
2.1. Genotypic Data Analysis
The Gene-Mapper version 3.7 software was used to
call the alleles and the sizes were assigned with the
Allelobin software. The Allelobin software also
generated the quality index of each marker as
indicated in Table 3. The data generated from the
Allelobin software were analyzed using the Power-
Marker version 3.25. The Power-Marker software was
used to calculate the polymorphic information content
(PIC), expected and observed heterozygosity,
genotype and allele numbers and frequencies for each
marker. Genetic diversity estimated by the Allelobin
software considered allele numbers, their allelic
frequencies and Nei’s unbiased estimate of gene
diversity (H) (Nei, 1987). The data were further
analyzed with the Arlequin version 2.0 software. This
software, in addition to calculating diversity indices,
analyzes disequilibrium tests, neutrality tests and
Hardy-Weinberg equilibrium (Schneider et al., 2000).
The analysis of molecular variance (AMOVA) was
done in Arlequin version 2.0 software to estimate the
significance of the variance components associated
with the different possible levels of genetic structure
(within individuals, within populations, within groups
of populations, among groups). Population
differentiation was elucidated using F-statistics
provided in the Arlequin software ((Schneider et al.,
2000), where FIS is the degree of inbreeding by the
total population, FIT reflects the total population
variability (non-homozygosity) and FST measures
genetic differentiation. Significance tests were
calculated based on 10,000 permutations. Tolerance
was set to a 5% level of missing data per locus. The
analysis considered the regions of origin namely,
Western, Turkana, Coast, Eastern and breeders’
material as sub-populations. Genetic distances were
calculated using Rogers modified distance (Wright,
1978). Pairwise genetic distance matrix was
calculated based on dissimilarity index by simple
matching, using Darwin software version 5.25. The
dissimilarity distance matrix was subjected to PCA
using Darwin Version 5.25 software (Apple Inc.,
APSL) to reveal a scatter plot (Fig. 2) of the first and
second axes of non-metric multi-dimensional scaling
(MDS).
3. RESULTS AND DISCUSSIONS
Most of the landraces flowered at 88 days and had
mean 100-grain weight of 1.5 g (Table 1). One
accession from Western Kenya had the highest 100-
grain weight. Both the number of leaves and number
of nodes at maturity for the majority of the accessions
were 9. Most of the accessions had 43 panicle
branches. The panicle length ranged between 5.6 cm
to 50.1 cm, with most of the sorghums having 21.07
cm long panicles. The highest coefficient of variation
(CV %) was found for 100-grain weight (40.76%),
followed by number of panicle branches (33.79%) and
panicle length (29.65). The lowest coefficient of
variation was 15.04 % for days to 50% flowering
(Table 1). There was less experimental error in the
measurement of days to flowering compared to the
other two traits.
The accessions from the Coast region were the
latest maturing (99 days), followed by those from
Turkana region (92 days). Eastern Kenya accessions
and breeders’ materials were the earliest maturing (85
days). The Coast region accessions had the highest
grain weight of 1.7 g, the highest number of panicle
branches (55) and the longest panicles (24.6 cm).
Turkana and Coast region landraces were the tallest,
as shown by the means of number of nodes and leaves
(10) and also had the largest panicle size. Again, as
shown in the ANOVA in Table 1, there were highly
significant differences among the landraces for all the
traits. Number of panicle branches and days to 50%
flowering had the highest broad-sense heritability
values of 0.957 and 0.943 respectively. The
phenotypic diversity in the land races did not vary
significantly. Indeed in all the traits recorded, the
breeders’ germplasm did not show any significant
variation from the local landraces, meaning that
whatever the differences observed, they were slight.
Ngugi et al.
Assessing Relationships in Kenyan Sorghum Landraces by Use of Simple Sequence Repeat Molecular Markers
279
Table 2: Location, composition and source of the 39 SSR markers used to genotype 148 Kenyan sorghum accessions
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 276-287, 2013
280
Table 3: Molecular characteristics of the 39 SSR markers used to analyze the 148 Kenyan sorghum accessions
A total of 349 alleles were observed across all loci
(Table 3). The number of alleles per locus ranged
from 2 for marker Xcup14 to 24 for marker Xtxp012.
Markers Xgap206 and CIR 238 had high number of
alleles (23 and 22 alleles, respectively). The highest
quality index was 0.516, which was scored by marker
CIR238, which also had the highest number of rare
alleles (Table 3). Marker Xtxp278 had the lowest
quality index of 0.088. The highest percentage of
abundant allele was 98.46% (allele 204) for marker
Xisep0310 and the lowest was 13.93 % (allele 200)
for marker Xtxp12. The total number of rare alleles
(alleles with frequencies of less than 5%) was 154,
giving a mean of 3.95 alleles per marker. Markers
Xcup02, CIR329, CIR300, CIR306 and CIR262 had
the lowest number of rare alleles (one each), whereas
the rest of the alleles had two or more rare alleles.
Markers CIR 238, Xgap206 and Xtp012 detected the
highest number of alleles, had the highest gene
diversity, the highest heterozygosity and PIC values
and were therefore the most informative (Table 4).
Ngugi et al.
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281
Table 4: Allelic frequencies, Genetic diversity and Heterozygosity values of SSRs genotyped in 148 Kenyan sorghum
accessions
Marker
Major
Allele
Frequency
Genotype
Number
Allele
Number
Gene
Diversity
Heterozygosity
PIC
Xtxp40 0.8345 10.0000 7.0000 0.2917 0.0608 0.2751
CIR286 0.4218 15.0000 8.0000 0.6429 0.2245 0.5758
Xcup02 0.7448 5.0000 4.0000 0.4112 0.0350 0.3729
Xtxp10 0.2872 19.0000 9.0000 0.8018 0.2297 0.7743
CIR329 0.4797 14.0000 6.0000 0.6749 0.2905 0.6280
Xtxp114 0.5980 6.0000 4.0000 0.5533 0.1284 0.4885
CIR238 0.2432 52.0000 22.0000 0.8804 0.4589 0.8707
Xtxp141 0.4830 24.0000 12.0000 0.7243 0.1837 0.7032
CIR223 0.6750 15.0000 8.0000 0.5071 0.2571 0.4729
Xtxp273 0.5426 16.0000 9.0000 0.6494 0.2248 0.6149
CIR276 0.9054 5.0000 4.0000 0.1731 0.0541 0.1613
Xcup061 0.7931 7.0000 6.0000 0.3374 0.0828 0.2952
Xtxp21 0.4759 17.0000 10.0000 0.7176 0.3034 0.6901
Xtxp278 0.9830 5.0000 4.0000 0.0336 0.0204 0.0334
CIR283 0.4595 18.0000 9.0000 0.6727 0.4595 0.6208
Xtxp321 0.3414 30.0000 16.0000 0.7770 0.2000 0.7490
CIR300 0.6351 7.0000 4.0000 0.5193 0.0743 0.4556
Gpsb067 0.6058 11.0000 7.0000 0.5278 0.3650 0.4502
SbAGB02 0.3818 18.0000 7.0000 0.7080 0.2095 0.6605
Xsep310 0.9831 4.0000 3.0000 0.0334 0.0203 0.0331
CIR240 0.4660 19.0000 14.0000 0.6837 0.2925 0.6361
Xgap84 0.5986 29.0000 17.0000 0.6248 0.4286 0.6126
Xtxp15 0.3209 21.0000 10.0000 0.7869 0.1689 0.7568
Xcup063 0.8571 5.0000 4.0000 0.2485 0.0136 0.2238
CIR306 0.6216 6.0000 3.0000 0.4803 0.1014 0.3772
Xcup53 0.9493 8.0000 5.0000 0.0980 0.0811 0.0967
CIR248 0.6276 9.0000 5.0000 0.5302 0.3931 0.4690
CIR262 0.7432 6.0000 3.0000 0.3927 0.1149 0.3320
Xgap72 0.4223 12.0000 7.0000 0.7122 0.0743 0.6665
CIR246 0.8074 7.0000 5.0000 0.3346 0.0405 0.3170
Xtxp136 0.4899 5.0000 3.0000 0.5570 0.6149 0.4580
Xcup14 0.6892 3.0000 2.0000 0.4284 0.1757 0.3366
Xtxp057 0.2329 32.0000 14.0000 0.8434 0.3904 0.8244
Xgap206 0.2153 52.0000 23.0000 0.9020 0.3942 0.8950
Gpsb123 0.2891 23.0000 10.0000 0.7924 0.2266 0.7635
Xtxp12 0.1413 52.0000 24.0000 0.9114 0.3623 0.9047
Xtxp145 0.4926 21.0000 13.0000 0.6973 0.3824 0.6661
Xtxp265 0.2245 42.0000 17.0000 0.8711 0.6463 0.8586
Xtxp320 0.2813 26.0000 11.0000 0.8052 0.2361 0.7798
Mean 0.5473 17.3333 8.9487 0.5727 0.2313 0.5359
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282
The PIC values ranged 0.03 0.9, with an average
value of 0.536. Similar mean PIC values for SSR loci
were reported by Brown et al., (1996); Kong et al.,
(2000); Geleta et al., (2006) and Agrama and Tuinstra
(2003). However, in the present study, the ranges of
PIC values were wider than those reported by the
foregoing authors. The mean diversity index per SSR
locus was 0.57. Pei et al., (2011) also detected an
overall genetic diversity of 0.60 for accessions and
0.54 for inbred lines using 29 SSR markers. The SSR
markers used here were able to detect high allelic
variability compared to those used by Agrama and
Tuinstra (2003). In Eritrean sorghum landraces, a total
of 208 alleles were observed, with a range of 7 to 28
alleles and a mean of 13.9 alleles per locus (Ghebru et
al., 2003). Menz et al., (2004) obtained a mean of 7.8
alleles among sorghum inbred lines. However
Perumal et al., (2007) recorded between 4 and 21
alleles using seven SSRs, which were similar to the
number of alleles found in this study. The differences
in the number of alleles observed in all these studies
can be attributed to sample sizes and to the number of
markers used. The bigger the sample size and the
more markers screened, the higher was the degree of
polymorphism that was detected. Menz et al., (2004)
analyzed 50 sorghum inbred lines and detected a mean
number of 7.8 alleles with a set of 100 SSRs, 1318
EcoRI/MseI Amplified Fragment Length
Polymorphism (AFLP) and 496 PstI/MseI AFLP
markers, whereas Pei et al., (2011) sampled 45
accessions and non-hybrids of sweet sorghum with 46
SSR markers and recorded a mean of 4.96 alleles per
locus. Another important factor contributing to the
differences in the data reported in these studies is the
manner in which the markers were distributed in the
genome. Where markers were uniformly distributed in
the genome, as was the case in this study, there was a
higher likelihood of obtaining more informative
diversity measures.
Table 5: Intra population Molecular diversity parameters of the 148 Kenyan accessions calculated according to Nei (1987).
Sub-population Western Turkana Coast Eastern Breeders' Mean Total
No. of polymorphic Loci 33 26 29 33 30 30.200
Number of gene copies 90 38 34 56 78 59.200 296
Number of alleles 6.28 4.44 4.79 5.51 6.48 27.510 1,073
Mean expected
heterozygosity(He)
0.558 0.497 0.5597 0.531 0.574 2.719
Mean Observed
heterozygosity (Ho)
0.229 0.172 0.273 0.218 0.254 1.146
Theta (H) under the infinite-
allele model
1.264 0.987 1.271 1.131 1.349 1.206
Table 6: AMOVA for 148 Kenyan sorghum accessions calculated according to Weir and Cockerham, (1996)
Source of variation Variance
components
Percentage
of variation
P-value FST
Among sub-populations 0.41544 4.78 <0.001
Among individuals
within sub-populations
4.89634 56.37 <0.001 0.0478
Within individuals 3.37500 38.85 <0.001
Fixation Indices
FIS 0.592
FST 0.048
FIT 0.612
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Assessing Relationships in Kenyan Sorghum Landraces by Use of Simple Sequence Repeat Molecular Markers
283
Fig. 1: A 2.5% Agarose gel image showing some of the amplifications of the optimised primers from the extracted genomic
DNA
Fig. 2: Principle co-ordinate scatter plot showing genetic distance estimates in the 148 Kenyan sorghum accessions
The mean observed heterozygosity level per
marker in the accessions was low (0.23) as compared
to the mean expected heterozygosity measured as
gene diversity (0.57), (Table 4). The major differences
between the observed heterozygosity and gene
diversity for all the microsatellite markers was an
indication of the presence of inbreeding among the
accessions (Table 4). The expected heterozygosity
(He) across the 39 loci was higher than the observed
heterozygosity (Ho), again confirming that there was
low cross-pollination rate among the accessions
(Table 5). The breeders’ germplasm presented higher
diversity than the Turkana accessions as implied by
the higher number of alleles in the population. The
Western region landraces had the highest gene copies
(90), whereas Coast region had the lowest gene copies
(34) (Table 5). A total of 296 gene copies, with a
mean of 59.2 per population were detected. All the
populations had a high number of polymorphic loci
ranging between 26 and 33. The overall mean
expected heterozygosity of 2.719 was higher than the
overall mean observed heterozygosity of 1.146 for all
the accessions. The theta (H) for all the five
populations (Table 5) had positive values, again
indicating the lack of heterozygotes (Table 4).
A clear genetic differentiation both among regions,
among individuals within the regions and within the
individuals is shown in Table 6. Of the total diversity,
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 276-287, 2013
284
56.37% was attributed to variation among accessions
within the sub-populations, 38.85% was attributed to
differences within the accessions whereas only 4.78%
was attributed to variation among the regions. In the
earlier study (Ngugi and Onyango, 2012) the
percentage variation among populations of 6.48% was
comparable to the one reported here but the within
accessions variation in the earlier study of 18.67%
was less, suggesting that inclusion of breeders’
germplasm indeed widened the genetic base. As
shown in Table 6, the value of FIS (level of
inbreeding) was 0.592 and this was almost equal to
the value of FIT (level of non-heterozygosity) which
was 0.612. This relatively high level of inbreeding is
consistent with earlier findings of increased degree of
allele fixation as shown in Tables, 4 and 5. The FST
(0.048) value observed in this study, although lower
than reported for other sorghum populations, was
significant and consistent to the one found earlier in
Kenya (Ngugi and Onyango, 2012). Ghebru et al.,
(2003) and Djé et al., (2000) recorded higher FST
values of 0.50 and 0.68 respectively than was the case
in this work. The high level of inbreeding among the
accessions may have arisen from the high degree of
selection practiced by farmers and breeders within
their germplasm leading to reduced effective
population sizes and therefore increasing the
opportunity for allelic fixation.
As shown in Table 7, Western, and Eastern regions
and the breeders’ germplasm had almost the same
inbreeding coefficient value. Sorghum material from
Turkana region had the highest FIS value, whereas
accessions from Coast region had the lowest, probably
because the accessions from the Turkana region were
more isolated from other populations but those from
the Coast region were exchanged more frequently
between farmers. The P (theta) values for the all the
sub-populations were positive another implication of
low heterozygosity in the germplasm.
The breeders’ germplasm and the Western region
accessions had the highest diversity with an average
number of alleles of 6.48 and 6.28 alleles per
accession respectively (Table 5). The lowest diversity
was in the Turkana sorghum with an average of 4.44
alleles per accession. The higher diversity detected
among breeders’ and Western region sorghum
populations may be attributed to the fact that Western
sorghums were collected over a broader area. They
also grow in an area bordering Uganda, providing an
additional opportunity for introgression with exotic
genetic material. Breeders’ germplasm has been
selected from diverse origins and crossed with
germplasm from other areas hence the higher
diversity. Turkana germplasm was genetically distant
from the rest of the germplasm but had low diversity
due to lack of introduction of land races and breeders’
varieties from other parts of the country. In addition,
the Turkana region is geographically isolated from the
rest of the regions and the local farmers who are
normally pastoralists do not consciously select for
grain or fodder traits. Associations among the 148
sorghum accessions based on cluster analysis revealed
a genetic distance range of 0.4 to 0.8. The accessions
grouped into three clusters, on the basis of their
geographical origins (Fig. 2) with a few accessions
from the Western, Coast, Eastern and breeders’
germplasm scattered across all the groups. Save for a
few exceptions, the accessions from Turkana were
found in cluster 2, those from Western and Eastern
regions were in cluster 3 while those from the Coast
region and breeders’ materials were placed in cluster
1.
The clustering indicated that although there is
considerable diversity among and within the
individual accessions, the Western, Coast, Eastern and
breeders’ sub-populations were not very different
from each other, a scenario that is possible where
there is unrestricted continuous movement of seeds by
farmers in these regions. Only the Turkana accessions
were able to group into their own sub-cluster again
confirming that the region may have received fewer or
no introduced sorghums from the other regions
leading to uniformity among the accessions within the
region.
Table 7: Population specific FIS indices (10,000 permutations) from sub-populations of the 148 Kenyan accessions
Pop Name FIS P ( FIS>=Obs FIS)
1 Western_Accessions 0.59870 0.000000
2 Turkana_Accessions 0.65132 0.000000
3 Coast_Accessions 0.54789 0.000000
4 Eastern_Accessions 0.60720 0.000000
5 Breeders_Accessions 0.56722 0.000000
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285
4. CONCLUSION
The high number of alleles observed for most of the
loci indicated that there is medium to high levels of
diversity in the landraces. High genetic variability was
observed among the three clusters and within the
accessions but there was less diversity between the
different geographical domains. The germplasm from
the Turkana region appears to be genetically distant
from the other domains and in addition has a low
within population diversity. High genetic diversity
was detected among the breeders’ germplasm and also
in the Western Kenya sorghum populations perhaps
due to increased diverse germplasm introductions in
both cases. The SSR loci in this study were able to
uniquely identify each sorghum accession and
therefore they would be useful in assessing the genetic
value of sorghum germplasm in future breeding
programs.
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Assessing Relationships in Kenyan Sorghum Landraces by Use of Simple Sequence Repeat Molecular Markers
287
Dr Kahiu Ngugi is a Senior Lecturer in Molecular Genetics and Plant Breeding at the Department of
Plant Sciences and Crop protection, Faculty of Agriculture, College of Agriculture and Veterinary
Sciences, University of Nairobi, Kenya. Dr Ngugi holds PhD and MPhil degrees in genetics from the
University of Cambridge, UK. He has worked previously with the Kenya Agricultural Research Institute
(KARI) for over 18 years and with CIMMYT, Mexico for 3 years. He has developed over 15 crop
varieties, has authored over 45 articles in peer-reviewed journals and written 2 books.
Rachel Maswili is a sorghum breeder and Senior Research officer with Kenya Agricultural Research
Institute (KARI) Katumani, Kenya and obtained her MSc degree in Plant Breeding and Genetics from
the University of Nairobi. She is actively involved in the development of crop varieties with different
agronomic, grain quality, biotic and abiotic stress tolerance parameters under arid agro-climate. She is
also involved in running of farmer participatory breeding trials and technology dissemination
technologies.
Cecilia Muchira is a Senior Technologist at the Department of Plant Sciences and Crop Protection,
Faculty of Agriculture, University of Nairobi, Kenya. She holds a Higher National Diploma and has
been working in Tissue culture and Molecular Genetics Laboratory for over 15 years and has been part
of the sorghum improvement research group.
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 288-298, 2013 Available online at http://www.ijsrpub.com/ijsrk
ISSN: 2322-4541; ©2013 IJSRPUB
http://dx.doi.org/10.12983/ijsrk-2013-p288-298
288
Review Paper
Inward FDI, Growth and Environmental Policy
Maryam Asghari
Assistant Professor at Shahid Ashrafi Esfahani University, Esfahan, Iran; E-mail: [email protected]
Received 01 May 2013; Accepted 16 July 2013
Abstract. Persistent disparities in regional economic conditions within developed countries continue to offer challenges to
policymakers. Yet the process of regional growth has become even more complex, owing in part to the expending role of inward
foreign direct investment. The role of FDI in stimulating regional growth is likely to be as strong as there is environmental
policy context. The main objective of this study is to empirically examine FDI inflow effect on the gulf Persian region‘s
economic growth as environmental policies improve over the period 1980 – 2012. The results show that FDI inflow help
increase of the region‘s economic growth, as environmental policy has improved. Porter hypothesis is valid in this region.
Key words: Foreign Direct Investment, Environmental Policy, Economic Growth, Porter Hypothesis and Gulf Persian Region.
JEL Classification: O13, O44, O53.
1. INTRODUCTION
The issue of foreign direct investment interacting
with economic growth in developing countries has
become increasingly important because many
developing countries have adopted a more liberal
policy towards FDI since the mid-1980s in order to
accelerate their economic growth.
According to Hermes and Lensink (1999), there
are different channels through which positive
externalities associated with FDI can occur: i)
competition channel: increased competition leads to
increased productivity; efficiency and investment in
human and/or physical capital, and also increased
competition may lead to changes in the industrial
structure towards more competitiveness and more
export-oriented activities; ii) training channel:
increased training of labor and management; iii)
linkages channel: foreign investment is often
accompanied by technology transfer; such transfers
may take place through transactions with foreign
firms; iv) demonstration channel: domestic firms
imitate the more advanced technologies used by
foreign firms.
To sum up, economic theory identifies a number of
channels through which FDI may exert an impact on
economic growth. These effects may be direct as well
as indirect. a. Direct impact: FDI flows can promote
growth if they lead to an increase in the investment
rate. b. Indirect impact: FDI flows can promote
growth if they lead to investments that are associated
with positive spillovers, which may enhance the
productivity of labor and capital in the recipient
economy.
Relevant literature on this issue might be divided
into two groups. The first is based on growth theory in
which FDI has been shown to boost economic
growth through technology transfer and diffusion
(Dimelis, 2005; Schneider, 2005), spillover effects,
productivity gains, and the introduction of new
processes, managerial skills and know-how in the
host countries (Girma, 2005; Li and Liu, 2005). In
addition, FDI can create an international network that
can help domestic products move across borders.
Also, a number of studies including those by Barro
and Sala-i-Martin (1995), Grossman and Helpman
(1991), Hermes and Lensink (2003), suggest that
FDI plays an important role in modernizing the
economy and promoting economic growth in host
countries, especially developing countries.
Several empirical studies indicate that the growth
effect of FDI is strongly dependent on the
institutional circumstances of the host or receiving
countries (Hermes and Lensink, 2003). While
others find that FDI inflow is positively
associated with economic growth only when
countries have previously achieved a certain level
of wealth (Blomstrom and Wolff, 1994), education
(Borenzstein et al., 1998), or financial development
(Alfaro et al., 2004; Hermes and Lensink, 2003).
On the other hand, Carkovic and Levine (2002) find
that these results are not robust when controlling for
simultaneity bias, while Townsend (2003) confirms
this result using data for less developed countries.
Overall, the diversity of these findings highlights the
difficulty in making generalised comments on the
FDI-growth nexus based on simple correlation based
analysis.
The second group of studies focuses on the
Asghari
Inward FDI, Growth and Environmental Policy
289
importance of factors explaining the existence of
multinational firms, which suggests that FDI is
attracted to host countries because of the possibilities
of higher returns. Viewed as a substitute for
domestic capital, FDI inflows increase with higher
domestic demand for capital generated by economic
growth in host countries. Expanding domestic
markets also make it possible for multinational firms
to exploit economies of scale (Ignatius et al., 1995).
Moreover, improvements in human capital
development, labour productivity and infrastructure
through economic growth would increase the
marginal return to capital, thereby expanding the
demand for investment including FDI (Zhang and
Markusen, 1999). In short, better economic
performance in host countries provides foreign
investors with a better investment environment and
greater opportunities for making profits, suggesting
the hypothesis of growth-driven FDI.
Mainstream economic theory has long held that
environmental regulations act as a major constraint on
economic growth (Jaffe et al., 2002; Magat, 1979;
Milliman and Prince, 1989). Environmental
regulations, according to the argument, increase a
firm‘s costs of production because of higher factor
costs and increased environmental compliance costs.
As a consequence, firms have fewer resources to
invest in research and development, productive
capacity, and other forms of technology. In the long
run, environmental regulations place firms at a
competitive disadvantage in the marketplace when
compared with their unregulated rivals. Moreover,
most economists argue that firms will adjust to
environmental regulations by relocating to regions or
countries where environmental regulations are less
stringent or nonexistent, resulting in significant job
loss and economic deterioration in the communities
left behind. The long-run effects of environmental
regulations on the economy, according to standard
economic theory, are a decline in firm productivity, job
loss, and a reduction in the U.S. standard of living.
Empirical research in economics has supported the
theoretical claim that environmental regulations
impede economic growth. In a highly cited study,
Jorgenson and Wilcoxen (1990) constructed a detailed
model of the economy that incorporated the
determinants of long-term economic growth. They
estimated the impact of environmental regulations on
the U.S. economy by simulating the growth of the
economy between 1973 and 1985 with and without
environmental regulations. According to their
findings, environmental regulations reduced annual
economic growth by about 0.2% per year. Gross
national product (GNP) by the early 1990s would
have been about 2.5% higher in the absence of the
regulations. In another study using the same
methodology, Jorgenson and Wilcoxen (1992)
assessed the impacts of the CAA Amendments of
1990 on the U.S. economy. They estimated that GNP
would have been about 3% higher by 2005 if it had
not been for the CAA regulations.
Barbera and McConnell (1986) attempted to
measure the effects of the environmental regulations
of the 1970s on economic productivity in several
manufacturing industries, including paper, chemicals,
stone, clay and glass, iron and steel and nonferrous
metals. Comparing industry productivity in the 1970s
with that in the 1960s, they found that environmental
regulations caused an annual reduction in the rate of
productivity growth of between 0.12% and 0.43% in
these industries. Gollop and Roberts (1983) measured
and analyzed the effect of sulfur dioxide emission
restrictions on the rate of productivity growth in the
electric power industry between 1973 and 1979. Their
econometric model incorporated the severity of the
emission standard, the extent of enforcement, and the
unconstrained emission rate of each facility. They
concluded that the annual productivity growth of
electric utilities declined by 0.59 percentage points
over the period. Gray and Shadbegian (1995) used
data from the Pollution Abatement and Control
Expenditures (PACE) survey to assess the effects of
environmental compliance costs on the productivity of
oil refineries. The PACE survey collects information
on the capital and operating costs of environmental
regulations for manufacturing industries in the U.S.
economy. Their cross-sectional estimates indicated
that $1 spent on pollution abatement by oil refineries
induced a productivity loss of $1.35.
Jaffe and Palmer (1997) studied the effects of
environmental regulations on technological innovation
among firms and industries in the U.S. economy. The
traditional economic assumption is that innovation
leads to higher levels of productivity and economic
growth but environmental regulations restrict this
process. Specifically, Jaffe and Palmer examined
pollution control expenditures, research and
development (R&D) spending data, and patent data in
a panel of industries between 1976 and 1989. Data on
pollution control expenditures were taken from the
PACE survey. They found some evidence that
increases in PACE spending were associated with
increases in R&D spending but no evidence that this
spending produced greater innovation as measured by
successful patent applications. In another study on
this question, Schmalensee (1994) argued that
although R&D devoted to environmental compliance
may increase with stricter environmental regulation;
this increase will likely come at the expense of other
research efforts that could have been more profitable.
The remainder of this paper is organized as
follows: Section 2 sets up an overview of the
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 288-298, 2013
290
relationships between technology transfer and FDI
inflow; Section 3 examines the relationships between
environmental policy and foreign direct investment;
Section 4 describes the dataset, the methodology used
and the main empirical results, and Section 5
summarizes the results.
2. ENVIRONMENTAL POLICY AND
TECHNOLOGY
If the imposition of environmental requirements can
stimulate invention and innovation that reduces the
cost of complying with those requirements, this has
profound implications for both the setting of
environmental policy goals and the choice of policy
instruments. It is useful to identify two major strands
of thought regarding the determinants of innovative
activity. We call these two broad categories of
modeling approaches the ―induced innovation‖
approach and the ―evolutionary‖ approach.
Within the induced innovation approach, firms
undertake an investment activity called ―R&D‖ with
the intention of producing profitable new products
and processes. The recognition that R&D is a
profit-motivated investment activity also leads to
the hypothesis that the rate and direction of
innovation are likely to respond to changes in relative
prices. Since environmental policy implicitly or
explicitly makes environmental inputs more
expensive, the ―induced innovation‖ hypothesis
suggests an important pathway for the interaction of
environmental policy and technology, and for the
introduction of impacts on technological change as
a criterion for evaluation of different policy
instruments. This raises the possibility that
environmental regulation can lead to a ―win-win‖
outcome in which pollution is reduced and profits
increased.
The traditional view among economists and
managers concerning environmental protection is that
it comes at an additional cost imposed on firms, which
may erode their global competitiveness.
Environmental regulations such as technological
standards, environmental taxes, or tradable emissions
permits force firms to allocate some inputs (labor,
capital) to pollution reduction, which is unproductive
from a business perspective. Technological standards
restrict the choice of technologies or inputs in the
production process. Taxes and tradable permits charge
firms for their emissions pollution, a by-product of the
production process that was free before. These fees
necessarily divert capital away from productive
investments.
The Porter hypothesis Asserts that stricter
environmental standards can spur innovations that
enhance competitiveness, and therefore that the right
kinds of environmental policies can greatly reduce
the costs of environmental policies and can even
make companies more profitable. This paper
provides an epilogue to a 1995 debate on the
Porter hypothesis that appeared in the Journal of
Economic Perspectives. Porter and van der Linde go
on to explain that there are at least five reasons that
properly crafted regulations may lead to these
outcomes:
First, regulation signals companies about likely
resource inefficiencies and potential technological
improvements.
Second, regulation focused on information
gathering can achieve major benefits by raising
corporate awareness.
Third, regulation reduces the uncertainty that
investments to address the environment will be
valuable.
Fourth, regulation creates pressure that motivates
innovation and progress.
Fifth, regulation levels the transitional playing
field.
Finally, they note, ―We readily admit that
innovation cannot always completely offset the cost of
compliance, especially in the short term before
learning can reduce the cost of innovation-based
solutions‖ (Porter and van der Linde, 1995).
Porter and other ―win-win‖ theorists have
argued that in a non-optimizing world, regulation
may lead to ―innovation offsets‖ that ―can not only
lower the net cost of meeting environmental
regulations, but can even lead to absolute
advantages over firms in foreign countries not
subject to similar regulations‖ (Porter and van der
Linde, 1995). Of course, the fact that firms engage in
non-optimizing behavior creates a possibility for
profit improvements, without suggesting that such
improvements would be the norm, would be
systematic, or even likely.
Porter and van der Linde (1995) provided case
studies of firms which adopted new technology in
response to regulation, and appear to have benefited,
but win-win theorists do not claim that all
environmental regulations generate significant
innovation offsets. Indeed, they emphasize that
regulation must be properly designed in order to
maximize the chances for encouraging innovation.
Quantitative evidence is limited—much of it from a
large related literature on the impact of environmental
regulation on productivity and investment— and
results seem to be industry and methodology
dependent.
Economists have been skeptical of the win-win
theory (Palmer et al., 1995; Oates et al., 1993). From
a theoretical perspective, it is possible to model
apparently inefficient firm behavior as the (second-
Asghari
Inward FDI, Growth and Environmental Policy
291
best) efficient outcome of imperfect information
and divergent incentives among managers or
between owners and managers in a principal/agent
framework.
From this perspective, the apparent inefficiency
does not have normative implications. Since firms are
doing the best they can give their information
environment, it is unlikely that the additional
constraints represented by environmental policy
interventions would be beneficial. On a more
concrete level, Palmer et al. (1995) surveyed firms
affected by regulation—including those cited by
Porter and van der Linde as success stories — and
found that most firms say that the net cost to them of
regulation is, in fact, positive.
For regulation to have important informational
effects, the government must have better information
than firms have about the nature of environmental
problems and their potential solutions. Furthermore,
while it seems likely that environmental regulation
will stimulate the innovation and diffusion of
technologies that facilitate compliance, creation and
adoption of new technology will typically require real
resources, and have significant opportunity costs.
Overall, the evidence on induced innovation and the
win-win hypothesis seems to be a case of a ―partially
full glass‖ that analysts see as mostly full or mostly
empty, depending on their perspective.
3. TECHNOLOGY TRANSFER AND FDI
INFLOW
While technology is an abstract term, three main
characteristics of technology can be identified
(Bassant and Chandra, 1999). Technology can be
characterized by the knowledge that is embodied in
products, processes and practices. Products comprise
the knowledge of how things work, their design, and
their interface with other products. Processes
comprise knowledge on how a product can be
produced or changed. And practices consist of the
routines necessary to manage the product-process
combination and the knowledge re-generation process.
There are many ways a firm can acquire new
technology besides its own investments into R&D
capital. Despite trade, FDI is potentially the most
important international vehicle of technology
transfer for firms. This source of productivity
growth has been particularly important for firms in
transition economies because of the urgent need to
restructure quickly. Foreign ownership often
provides local firms with efficient corporate
governance, as they, mainly privatized to insiders; do
not have incentives to restructure (Blanchard, 1997).
FDI may also be the cheapest means of technology
transfer, as the recipient firm normally does not have
to finance the acquisition of new technology. And
it tends to transfer newer technology more quickly
than licensing agreements and international trade
(Mansfield and Romeo, 1980). And since it has a
more direct effect on the efficiency of firms, it
also has the potential to create positive spillover
effects to local firms.
Multinational firms are among the most important
players in the world responsible for creating and
controlling technology. They facilitate putting
tangible and intangible resources available in
different countries to their most productive uses. As
part of the global profit-making operations of
multinational enterprises, FDI, by its nature, involves
the transfer of capital, technology and knowledge
from home to host countries. Using better
technologies offers possibilities to increase
productivity and hence economic growth and
development. Hence it is not surprising that many
countries view investments by those MNEs as one of
the most important means to acquire technology and
knowledge to upgrade their own production base.
However, it is difficult to paint an unambiguous
picture as to how FDI can transfer technology, and
how this technology is going to contribute to
development. It is not a priori clear that every type
of technology transferred is appropriate, and not
every investment made is by definition beneficial to
host country development.
While FDI is only one of several means
available for a firm to transfer technology outside
its home country (e.g. exporting products that
embody the technology or licensing its technology
to an agent abroad), for developing countries it
remains the most important means of acquiring new
technology. Technology transfer through FDI offers
benefits that other modes of transfer do not, for at
least three reasons:
Unlike trade in goods, where host countries
must try to imitate and learn from reverse
engineering, FDI involves the explicit transfer of
technology. In addition to the technology itself,
FDI brings needed complementary resources such as
management experience and entrepreneurial abilities,
which can be transferred through training
programmes and learning by doing. A World Bank
study using firm- level survey data on Czech
enterprises of different ownership shows that
domestic firms receiving FDI or involved in joint
ventures tend to provide training programs and
acquire new technologies more frequently than those
with no foreign partners (Djankov and Hoekman,
1999).
Technology spillovers through FDI can occur
between firms that are vertically integrated with the
MNC (inter-industry spillovers) or in direct
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 288-298, 2013
292
competition with it (intra-industry spillovers).
Kokko (1992) identifies at least four ways that
technology might be diffused from foreign
investment enterprise (FIE) to other firms in the
economy: (1) demonstration - imitation effect, (2)
competition effect, (3) foreign linkage effect, and (4)
training effect. Not all spillovers are positive as FDI
can generate negative externalities when foreign
firms with superior technology force domestic firms
to exit. These negative externalities are often called
also competition effect, crowding-out effect or
business-stealing effect.
Recent analyses of importance of technology
transfer and spillovers through FDI are typically
carried out using firm panel data. As mentioned
above, the evidence provides support for direct
technology transfer from MNCs to their affiliates,
while there is only a weak evidence of spillovers
to indigenous firms.
However, with the very recent exceptions of
Blalock (2001), Schoors and van der Tool (2001),
Smarzynska (2002) and Smarzynska and Spatareanu
(2002), all of the studies have focused on intra-
industry spillovers. Aitken and Harrison (1999) show
significant technology transfer to the affiliates and
some positive spillovers to domestic firms in
Venezuela located close to the affiliate, but there
were also negative spillovers to the domestic
economy as a whole. There were some positive
spillovers in other developing countries, but these
were limited to certain industries, such as those with
relatively simple technology in Morocco (Haddad
and Harrison, 1993), are export oriented as in
Indonesia (Blomström and Sjöholm, 1999), or have
sufficient human capital as in Uruguay (Blomström et
al., 1994). Earlier studies that did not use panel
data often found evidence of intra-industry
spillovers. These include a study by Caves (1974) of
Australian manufacturing in 1966, a study by
Globerman (1979) of Canadian industry in 1972 and
studies of Mexico in the mid-1970s by Blomström
and Persson (1983) and the mid-1980s by Blomström
and Wolff (1994). However, a study of US firms in
Europe shown that spillovers were localized and that
competition forced many local competitors out of
small markets (Cantwell, 1989). Recent analyses of
panel data for advanced countries provide little or no
evidence of spillovers in the 1990s. Girma, Green-
away and Wakelin (2001) provide evidence for the
United Kingdom, (Berry, et. al. 2001), for Ireland,
and Alverez et al. (2002) for Spain. There was also
some evidence of negative spillovers in Ireland.
On the other hand, empirical evidence (Kokko,
1994; Borensztein et al., 1998 and Kinoshita, 2000)
demonstrate that FDI can contribute to over- all
domestic productivity growth only when technology
gap between domestic and foreign firms is not too
large and when a sufficient absorptive capacity is
available in domestic firms. In other words,
technology spillovers from MNCs tend to occur more
frequently when the social capabilities of the host
country and the absorptive capacity of the firms in
the economy are high. While relatively backward
countries have a certain advantage in catching-up, it
becomes increasingly more difficult for the country
to build the necessary social capabilities and
absorptive capacities that allow firms to take
advantage of the technology spillovers that are
available in the economy. For this reason, R&D can
be thought of as having two complementary effects
on firm‘s productivity growth (Cohen and
Levinthal, 1989). First, R&D directly expands firm‘s
technology level by new innovations, which is called
innovation effect. On the other hand, it increases
firm‘s absorptive capacity ability to identify,
assimilate and exploit outside knowledge, which is
usually called learning or absorption effect. These
two important effects have to be included into a
serious investigation of spillovers through FDI.
4. ANALYTICAL FRAMEWORK AND DATA
4.1. Aggregate production function
The nature of relationship between FDI and economic
growth is not clearly understood. The theoretical and
empirical literature has identified some of the ‗pre-
conditions‘ necessary for FDI to stimulate national
growth, yet their importance may vary dramatically by
region. Although the mechanisms through which it
stimulates regional economies have largely been
ignored, ―new‖ growth theories imply a pivotal role for
FDI.
The endogenous growth literature has emphasized
the importance of both human and knowledge capital
in forestalling decreasing returns to capital
accumulation. As such, growth is not limited to
exogenous forces that drive the rate of technical
change; environmental policy or conditions that foster
human capital development, R&D, or an influx of
FDI may actually spur growth. Fundamental,
environmental policy is a composite bundle of
―know-how‖ and pollution reduction by FDI that
enhances technology transfer, skill diffusion and
pollutant industry replacement within the regions. As
such, besides directly affecting growth via
environmental policy is also expected to generate
indirect impacts via FDI. The role of environmental
policy in stimulating regional growth is likely to be as
strong as it is in a national context.
Observing from theory the possible growth
promoting role of FDI, our data analysis is modelled
Asghari
Inward FDI, Growth and Environmental Policy
293
in an aggregate production function (APF)
framework. The standard APF model has been
extensively used in econometric studies to estimate
the impacts of FDI inflows on growth in many
developing countries. The APF assumes that, along
with ―conventional inputs‖ of labour and capital used
in the neoclassical production function,
―unconventional inputs‖ like FDI may be included in
the model to capture their contribution to economic
growth. The APF model has been used by
Kohpaiboon, 2004; Mansouri, 2005; Feder, 1983;
Fosu, 1990 and Ukpolo, 1994).
Following Herzer et al. (2006), the general APF
model to be estimated is derived as:
(1)
where Yit denotes the aggregate production of
the economy (real GDP per capita) at time t, i is
country and Ait , Kit , L
it are the total factor
productivity (TFP), the capital stock and the stock of
labour, respectively.
Since we want to investigate the impacts of
interaction between environmental policy (EP) and
FDI inflows (FDIIN) to capture Porter hypothesis and
trade openness (OP) on economic growth through
changes in TFP, we assume therefore that TFP is a
function of EP*FDIIN and OP. Thus
(2)
Combining equations (2) with (1), we get:
(3)
Where and are constant elasticity
coefficients of output with respect to the Kit, Lit,
EPit*FDIINit and OPit . From equation (3), an explicit
estimable function is specified, after taking the
natural logs of both sides, as follows:
(4)
where all coefficients and variables are as
defined, t are the time specific intercepts, i
represents country-specific effects that summarize
the influence of unobserved variables such as
infrastructure, period average climate, history and
culture, and which are assumed to be distributed
independently across countries, with variance 2
,
is a constant parameter and is the white noise error
term.
4.2. Data descriptions
From equation (4) Y is defined as real GDP per capita;
FDIIN is the value of real gross foreign direct
investment inflows; EP is country‘s change in energy
production intensity (energy production/GDP) over
the period 1980 – 2012, together with the level of
energy production intensity in 1980. OP is the sum
of export and import values to GDP ratio; L is
measured as the volume of the total labour force, K is
proxied by the real value of gross fixed capital
formation. The annual time series data used is
sourced from the World Development Indicators
2013 edition published by the World Bank and covers
the period from 1980 to 2012.
4.3. The Results
We test the stationarity of variables in the model.
Therefore, we make the unit root test of Levin, Lin &
Chu and Im, Pesaran & Shin W-stat to test for it. The
results show that all variables are stationarity at level
(Table 1).
Given that OLS will yield biased results in the
presence of unobserved heterogeneity, either random
effects or fixed effects could be employed to obtain
consistent results. While the fixed effects model
treats the t and
i as regression parameters, the
random effects model treats them as components of
the random disturbance. We employ a Hausman test
to test for the inconsistency of the random effects
estimate. Furthermore, since heteroscedasticity
may be present in the sample because of large
variations in the variables, it needs to be tested for
in the estimations. A likelihood-ratio test is used that
compares a feasible general least squares regression
(FGLS henceforth) that is corrected for
heteroscedasticity with one that is not. Where the
null hypothesis of homoscedasticity could be rejected,
robust standard errors are used. A final
methodological issue concerns serial correlation in
the error term. A Wooldridge test for
autocorrelation in panel data is used to test for
autocorrelation.
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 288-298, 2013
294
Table 1: Variables Stationarity Tests in the Region
Variables Levin, Lin & Chu- Test Im, Pesaran and Shin W-stat -
Test
Statistic Prob Statistic Prob
Ln Yit -4.76166 0.0000 -5.38136 0.0000
Ln Kit -1.70375 0.0442 -9.23834 0.0001
Ln Lit -3.76847 0.0001 -3.94342 0.0000
Ln EPit 2.66335 0.0000 4.02245 0.0000
Ln FDIINit -5.33756 0.0000 -5.22526 0.0000
Ln OPit 5.20648 0.0000 3.58352 0.0000
Ignoring first order serial correlation still
results in consistent, but inefficient estimates of
the coefficients and biased standard errors (Baltagi,
2006). Therefore, where necessary, additional FE
models with (FGLS) correcting for AR(1) and FE
regressions with Driscoll and Kraay (1998) standard
errors are estimated and compared with the results of
the other specifications.
We estimate the equation (4) using fixed and
random effects using 1980–2012 panel data for the 4
Gulf Persian countries (Bahrain, Iran, Kuwait, Oman
and Saudi Arabic). All results are discussed in Table
2.
The all coefficients of the variables are
significantly, except OP coefficient. The results show
that the coefficients of physical capital, human capital,
and interaction between environmental policy and FDI
inflows are positive and significant.
A restrictive environmental policy lowers
aggregate output because it imposes an additional
constraint on the production possibilities set. But,
more stringent environmental policy stimulates
innovation and FDI inflow increases, so economic
growth increase. This result indicates that Porter
hypothesis is valid in this region.
Table 2: The Determinants of Economics Growth in the Region
Variables Random Effect Fixed Effect(1)
C
Ln Kit
Ln Lit
Ln EPit*FDIINit
Ln OPit
R2
Groups
Number of observation
Time periods
Breusch and Pagan LM test
Prob > chi2
Modified Wald Test for group-wise
heteroskedasticity(3)
Prob > chi2
7483.709 * (16.34)
-5.46e-08 * (-3.02)
2.79e-07 *
(11.37)
.000021* (6.55)
.0751517 (0.25)
0.6313
5
151
31
279.08
0.0000
5338.974* (11.49)
5.30e-08**
(2.12)
3.73e-07* (13.22)
7.14e-06**
(2.50)
.0438312 (0.20)
0.7284
5
151
31
52.481
0.0000
Hausman Test (2)
Prob > chi2
Wooldridge test for autocorrelation
in panel data
Prob > F
2(2)= 0.02
0.8759
47.809
0.0023 Note: T-statistics are shown in parentheses. Significance at the 99%, 95% and 90% confidence levels are indicated by * , **and ***, respectively.
The robust standard errors are White‘s heteroskedasticity-corrected standard errors
(1) The acceptation of model by the Hausman test. (2) The hausman test tests the null hypothesis that the coefficients estimated by the efficient random effects estimator are the same as the ones estimated by the
consistent fixed effects estimator. If they are (insignificant P-value, Prob>chi2 larger than .05) then it is safe to use random effects. If you get a significant P-
value, however, you should use fixed effects. (3) For FE regression model, the modified Wald test for groupwise heteroskedasticity is used while the Woolridge test for autocorrelation in panel data (Ho:
no autocorrelation) is applied.
5. CONCLUSIONS
Does FDI contribute relatively more to growth as
environmental policy has improved? Inward FDI
(foreign capital inflow) is an important vehicle for
augmenting the supply of funds for domestic
investment thus promoting capital formation in the
host country. The stringent environmental policy may
bring adoption of superior production technology and
innovation by FDI inflow to developing countries.
Asghari
Inward FDI, Growth and Environmental Policy
295
Firms learn or adopt better and highly developed
production technology and innovation, either through
intensive international markets competition or act as
sub-contractors to foreign business concerns.
In this paper, we examine the role of stringent
environmental policy in the relation between FDI
inflow and Gulf Persian region‘s economics growth
over 1980-2012. The results show more stringent
environmental policy stimulates innovation and FDI
inflow increases, and so economic growth increase in
the region.
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298
Assistant Professor Dr. Maryam Asghari got B.A in Mathematics from Isfahan University/Iran in
1998. She obtained M.A in economic science from Islamic Azad University, Khorasgan / Iran in
2002. She researched in CEMAFI laboratory, Sophia-Antipolis-Nice University/France, for
receiving PH.D over 2003-2009. She published many papers in international and Iranian journals the
issues of environmental economics, international economics, tourism and national security. She
teaches many courses such as natural resources, energy economics and microeconomics in Shahid
Ashrafi Esfahani University, Iran. She is the manager of research department of this university. Dr.
Maryam Asghari got best researcher award in Esfahan province in 2012. She is The Director-in-
Chief of International Journal of Economic Research and Analysis and cooperates closely with
several international journals.
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 299-307, 2013 Available online at http://www.ijsrpub.com/ijsrk
ISSN: 2322-4541; ©2013 IJSRPUB
http://dx.doi.org/10.12983/ijsrk-2013-p299-307
299
Full Length Research Paper
Solvent-free Synthesis and Spectral Studies of Some 9-Anthryl-1H-Pyrazolines
Krishnamoorthy Guna Sekar1,*
, Ganesamoorthy Thirunarayanan2
1Department of Chemistry, National College, Tiruchirappalli-620 001, India
2Department of Chemistry, Annamalai University, Annamalainagar-608002, India
*Corresponding Author: E-mail: [email protected]; [email protected]
Received 18 June 2013; Accepted 22 July 2013
Abstract. Totally ten 3-(9-anthryl)-4,5-dihydro-5-(3-substitutedphenyl)-
1H-pyrazolines have been prepared by solvent-free
cyclization of 2(E)-1-(substituted phenyl)-3-(9-anthryl)-2-propen-1-ones and hydrazine hydrate in presence of fly-ash:H2SO4
catalyst. These pyrazolines were characterized by their physical constants and spectroscopic data. The assigned infrared
νC=N, NH(cm-1
), NMR chemical shifts(ppm) of δNH, H4, H4′, H5 and C=N data are correlated with Hammett substituent
constants, F and R parameters using regression analysis. From the results of statistical analysis, the effects of substituent on
the above group frequencies have been discussed.
Key words: Solvent-free synthesis; 1H-Pyrazolines; IR and NMR spectra; Hammett correlations
1. INTRODUCTION
The 1H-pyrazolines are bi-nitrogen five membered
heterocyclic compounds. The substituted 1H-
pyrazoles have important biological activities due to
the presence of –N-N=C moiety in the pyrazoline ring
(Rahman and Siddiqui, 2010; Elguero et al., 1984).
The important biological activities are analgesic, anti-
inflammatory, anti-microbial (Sahu et al., 2008; Amir
et al., 2008), anti-amoebic, (Abid and Azam, 2006),
anti-tubercular (Shahar Yar et al., 2007),
antidepressant and anti-convulsant activities (Ozdemir
et al., 2007). Numerous solvent assisted and solvent-
free synthetic methods are reported for the synthesis
of pyrazoline derivatives (Levai, 2005; Siddiqui et al.,
2011; Azarifar and Ghasemnejad, 2003). Now-a-days
scientist and chemists preferred solvent-free synthetic
methods, due to the less hazardousness, lesser amount
of solvent usage, unpolluted for the environment, easy
handling procedure, shorter reaction time and higher
yields (Sasikala et al., 2012; Thirunarayanan et al.,
2013; Thirunarayanan and Sekar, 2013a; Siddiqui et
al., 2011; Azarifar and Ghasemnejad, 2003).
Many catalysts were employed for the synthesis of
pyrazoline derivatives by solvent assisted or solvent-
free methods such as Lewis-acids, bases and their
salts, aprotic organic acids (Sarkar et al., 2011;
Kalirajan et al., 2009; Misra and Sasmal, 2011), fly-
ash:H2SO4(Sasikala et al., 2012), pre-heated fly-ash
(Thirunarayanan and Sekar, 2013a), fly-ash:PTS
(Thirunarayanan and Sekar, 2013b), SiO2-H3PO4
(Thirunarayanan et al., 2013) with microwave
irradiation and ultrasound (Pizzuti et al., 2009).
Spectroscopic data are utilized for prediction of
ground sate equilibration of organic molecules such as
unsaturated ketones, aldehydes, alkenes, alkynes, acyl
halides and its esters (Sathiyamoorthy et al., 2013).
The effect of substituents on the functional group
of the molecules can be evaluated by the correlation
of the respective spectral group frequencies with
Hammett substituent constants, F and R parameters
using linear regression analysis (Shorter, 1973). The
correlation analysis is applied for the study of
electrochemical behaviour of organic molecules, E, Z,
s-cis- and s-trans configuration and isomers of
unsaturated systems, cis- and gauche- forms of
rotomers of ω-halo acyl compounds( Thirunarayanan
et al., 2011). Sasikala et al. (2012) have synthesised
some 5-bromo-2-thienyl based pyrazoline derivatives
by solvent-free method and studied the antimicrobial
activities. Sakthinathan et al. (Sakthinathan et al.,
2012) have synthesised and studied the effects of
substituent on 2-naphthyl based pyrazolines.
Ranganathan et al. (2012) have studied the effects of
substituents and solvent-free synthesis of some 5-
bromo-2-thienyl based pyrazolines.
The solvent-free synthesis and the Hammett
linearity on some pyrazoline-1-carbothioamides have
been studied by Thirunarayanan and Sekar (2013a, b).
Within the above view there is no information
available about solvent-free synthesis and the study of
spectral linearity on 9-anthryl based 1H-pyrazolines.
Therefore the authors have taken efforts to synthesize
some 3-(9-anthryl)-4,5-dihydro-5-(substituted
phenyl)- 1H-pyrazolines by solvent-free cyclization of
substituted styryl 9-anthryl ketones and hydrazine
hydrate and record their infrared and NMR spectra for
studying the effect of substituents.
Sekar and Thirunarayanan
Solvent-free Synthesis and Spectral Studies of Some 9-Anthryl-1H-Pyrazolines
300
2. EXPERIMENTAL
2.1. General
All chemicals used were procured from Sigma-
Aldrich and Merck chemical companies. The fly-ash
was collected from Thermal-II, Neyveli Lignite
Corporation, Neyveli, Tamilnadu. The infrared
spectra of all pyrazolines were recorded with KBr
discs in SHIMADAZU Fourier Transform
spectrophotometer. The NMR spectra of all
synthesised compounds were recorded in BRUKER
AV400 NMR spectrometer applying 400 MHz for 1H
and 100MHz frequencies for 13
C NMR spectra using
CDCl3 solvent and tetramethylsilane as standard. The
mass spectra of all pyrazolines were recorded in
SHIMADZU spectrometer using chemical ionization
technique.
2.2. Preparation and characterization of fly-ash:
H2SO4 catalyst
The fly-ash: H2SO4 catalyst was prepared by the
procedure published in literature (Thirunarayanan et
al., 2012). In a 50 mL Borosil beaker, 1 g of Fly-ash
and 0.8 mL (0.5 mol) of sulphuric acid were taken and
mixed thoroughly with glass rod. This mixture was
heated on a hot air oven at 85° C for 1 h, cooled to
room temperature, stored in a Borosil bottle and
tightly capped. This was characterized by infrared
spectra and SEM analysis.
Infrared spectral data of fly-ash: H2SO4 is ν (cm-1
):
3456(OH); 3010 (C-H); 1495, 1390(C-S); 1336,
1154(S=O); and op modes: 1136, 1090, 976, 890, 850,
820, 667, 658, 620, 580, 498, 425.
The SEM images of pure Fly-ash and Fly-ash:
H2SO4 at two different magnifications are shown in
Fig. 1(ad). Figures 1a and 1b depicted that the
crystallinity is found to be more in pure fly ash. The
spherical shaped particles are clearly seen at both
magnifications in Fig 1a and 1b. Fig. 1a reveals that
the globular structure of pure fly ash (round shaped
particle). This also seen from Fig. 1c and 1d that some
of the particles are slightly corroded by H2SO4
(indicated by arrow mark) and this may be due to
dissolution of Fly-ash by H2SO4. This will further
confirmed by Fig 1d, the well-shaped particles of pure
Fly-ash. Fig 1b is aggregated to Fig 1d due to
presence of H2SO4.
Fig. 1: SEM images of fly-ash: H2SO4 catalyst
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 299-307, 2013
301
2.3. Synthesis of 1H-pyrazolines
Appropriate equi-molar quantities of E-1-(substituted
phenyl)-3-(9-anthryl) ketones (0.2 mmol), hydrazine
hydrate (0.2 mmol) and 0.5 g of fly-ash: H2SO4 were
taken in a borosil glass tube and closed with lid.
These contents were subjected to microwave
irradiation (Scheme 1) for 4-6 m at 550W in a
microwave oven (Samsung Grill, GW73BD
Microwave oven, 230 V A/c, 50 Hz, 2450 Hz, 100-
750 W (IEC-705). The completion of reaction was
monitored by Thin Layer Chromatogram. The
reaction mixture was cooled to room temperature,
extracted with 10 mL of dichloromethane.
Evaporation of dichloromethane afforded the crude
product. Further it is purified by crystallization with
ethanol. The solid catalyst was reused for further
reaction runs. The analytical, physical constants and
mass fragments data are presented in Table 1.
Scheme 1: Solvent-free synthesis of 3-(9-anthryl)-5-(3-substituted phenyl)-4,5-dihydro-
1H-pyrazolines
Table 1: Analytical, physical constants and mass fragments (m/z) of 3-(9-anthyl)-4,5-dihydro-5-( substituted phenyl)-1H-
pyrazolines
[a]= (Misra and Sasmal, 2011)
Sekar and Thirunarayanan
Solvent-free Synthesis and Spectral Studies of Some 9-Anthryl-1H-Pyrazolines
302
3. RESULTS AND DISCUSSION
3.1. Infrared spectral study
In the present study on infrared correlaion, we
recorded the infrared spectra of ten synthesised 3-(9-
anthryl)-4, 5-dihydro-5-(substituted phenyl)- 1H-
pyrazolines, assigned the νNH and C=N (cm-1)
stretching frequencies as presented in Table 2. The
assigned frequencies are subjected to correlate with
Hammett substituent constants, F and R parameters
using single and multi-regression analysis (Swain and
Lupton, 1968). In infrared spectral correlations, the
Hammett equation was taken as shown in equation
(1).
ν = ρσ + νo (1)
where ν is the frequency of the pyrazoline series, ρ
is the slope with the meaning of linear coefficient, σ is
the constant in the Hammett equation and νo is the
frequency of parent member of the pyrazoline series.
Table 2: The infrared and nuclear magnetic resonance spectral data of 3-(9-anthyl)-4,5-dihydro-5-( substituted phenyl)-1H-
pyrazolines
The results of statistical analyses (Sakthinathan et
al., 2012; Sathiyamoorthy et al., 2013;
Thirunarayanan et al., 2013; Thirunarayanan and
Sekar, 2013a, b) are given in Table 3. From Table 3,
the correlation of νNH(cm-1
) frequencies were
satisfactory with Hammett σ, σI constants and F
parameters excluding H, 3-and 4-CH3 substituents.
The remaining Hammett substituent constants and R
parameters showed poor correlation. This was due to
the polar and resonance effects of the substituents
unable to predict the reactivity on the NH stretches
and it was associated with the resonance-conjugative
structure as shown in Fig. 2. The νC=N frequencies
correlation was satisfactory with Hammett substituent
constants and F and R parameters excluding 3- and 4-
CH3 substituents. All correlations related with νC=N
frequencies gave positive ρ values. This means that
the normal substituent effect operates in all pyrazoline
systems.
Some of the single parameter correlation of
infrared frequencies of the synthesised pyrazolines has
shown poor correlation. While seeking the multi-
regression analysis, these stretches satisfactorily
correlated with Swain-Lupton’s (Swain and Lupton,
1968) constants and F and R parameters. The
generated multi-correlation equations (2-5) are;
νNH(cm-1
) = 3414.21(±37.948) – 206.425σI (±84.171) – 10.871σR (±4.621) (2)
(R = 0.969, P > 95 %, n = 10)
νNH(cm-1
) = 3421.59(±40.710) – 224.299F (±88.127) – 18.343R (±6.996) (3)
(R = 0.970, P > 95 %, n = 10)
νC=N(cm-1
) = 1677.80(±3.886) + 11.792 σI (±8.620) + 24.971 σR (±8.921) (4)
(R = 0.980, P > 95 %, n = 10)
νC=N(cm-1
) = 1677.35(±4.117) + 14.918F (±5.891) + 20.418R (±7.041) (5)
(R = 0.981, P > 95 %, n = 10)
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 299-307, 2013
303
3. 2. 1H NMR spectral study
The 1H NMR spectra of synthesised 3-(9-anthryl)-4,5-
dihydro-5-(substituted phenyl)- 1H-pyrazoline
derivatives under spectral correlation study have been
recorded in deuteriochloroform solvent employing
tetramethylsilane (TMS) as internal standard. The
signals of the 3-(9-anthryl)-4,5-dihydro-5- (substituted
phenyl)-1H-pyrazoline NH and ring protons have
been assigned. They are calculated as AB or AA'
systems respectively. The chemical shifts (ppm) of H4
are at higher fields than those of H4′ and H5 in this
series of 3-(9-anthryl)-4,5-dihydro-3-(substituted
phenyl)- 1H-pyrazolines. This is due to the deshielding
of H4′ and H5 protons which are exist in different
chemical as well as magnetic environment. These H4
protons gave an AB pattern in all pyrazolines. The H4′
proton doublets of doublets are well separated from
the signals H5 and the aromatic protons. The assigned
chemical shifts (δ,ppm) of the pyrazoline ring NH, H4,
H4′ and H5 protons are presented in Table 2.
In nuclear magnetic resonance spectra, the
chemical shift (δ, ppm) depends upon the electronic
environment of the nuclei concerned. These assigned
chemical shifts were correlated with reactivity
parameters. In this correlation, the Hammett equation
may be used in the form as,
log δ= log δ0 + ρσ (8)
where δ is the chemical shift of the series, ρ is the
slope, σ is the Hammett sigma constants and δ0 is the
chemical shift of the parent compound of the series.
The assigned NH, H4, H4′ and H5 proton chemical
shifts (ppm) of synthesized 3-(9-anthryl)-5-
(substituted phenyl)-4,5-dihydro-1H-pyrazolines were
correlated with Hammett sigma constants, F and R
parameters. The NH, proton chemical shifts (δ, ppm)
have shown poor correlation with Hammett
substituent constants, F and R parameters. The H4,
protons chemical shifts (δ, ppm) correlation was
satisfactory with Hammett σI constants and F
parameters along with positive ρ values. The H4′
proton chemical shifts (δ, ppm) of the pyrazolines
gave satisfactory correlation with F parameters
excluding 2-OH and 4-OCH3 substituents. The
remaining Hammett substituent constants and R
parameters were failing in correlation. The H5 proton
chemical shifts (ppm) of synthesized 3-(9-anthryl)-5-
(substituted phenyl)-4,5-dihydro-1H-pyrazolines have
shown poor correlation with Hammett substituent
constants, F and R parameters. The reason for failure
in correlation was stated earlier and associated with
the resonance-conjugative structure shown in Fig. 2.
In view of the inability of the NH, H4, H4′ and H5
proton chemical shifts (ppm) of synthesized 3-(9-
anthryl)-5-(substituted phenyl)-4,5-dihydro-1H-
pyrazolines to produce satisfactory correlation
individually with Hammett, substituent constants, F
and R parameters, the authors think that it is
worthwhile to seek multiple correlations involving
either σI and σR constants or Swain-Lupton’s(Swain
and Lupton, 1968) F and R parameters. The multi-
regression correlated equations for NH, H4, H4′ and H5
proton chemical shifts (δ, ppm) are given in (9)-(16):
δNH(ppm) = 9.261(±0.266) +1.480(±0.059)σI – 1.197(±0.061)σR (9)
(R = 0.973, P > 95 %, n = 10)
δNH(ppm) = 9.217(±0.303) +1.563(±0.657) F - 0.763(±0.051) R (10)
(R = 0.969, P > 95 %, n = 10)
δH4(ppm) = 2.758(±0.252) +1.1199(±0.559)σI – 0.395(±0.052)σR (11)
(R = 0.960, P > 95 %, n = 10)
δH4(ppm) = 2.754(±0.282) +1.133(±0.611) F - 0.169(±0.040) R (12)
(R = 0.957, P > 95 %, n = 10)
δH4′(ppm) = 3.591(±0.046) +0.292(±0.102)σI – 0.294(±0.106)σR (13)
(R = 0.979, P > 95 %, n = 10)
δH4′(ppm) = 3.580(±0.056) +0.295(±0.112) F - 0.994(±0.097) R (14)
(R = 0.973, P > 95 %, n = 10)
δH5(ppm) = 6.163(±0.181) +0.447(±0.040)σI + 0.649(±0.041)σR (15)
(R = 0.905, P > 90 %, n = 10)
δH5(ppm) = 6.106(±0.194) +0.152(±0.042) F - 0.128(±0.033) R (16)
(R = 0.917, P > 90 %, n = 10)
Sekar and Thirunarayanan
Solvent-free Synthesis and Spectral Studies of Some 9-Anthryl-1H-Pyrazolines
304
Table 3: Results of statistical analysis of infrared ν(cm-1
) NH, C=N, NMR chemical shifts (δ,ppm) of NH, H4, H4′, H5, NH and C=N of 3-(9-anthryl-5-(substituted phenyl)-4,5-dihydro-1H-
pyrazole with Hammett σ, σ+, σI σR constants and F and R parameters.
r = correlation co-efficient; ρ = slope; I = intercept; s = standard deviation; n = number of substituents
International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 299-307, 2013
305
Fig. 2: The resonance-conjugative structure
3. 3. 13
C NMR spectra
Chemists and researchers (Sakthinathan et al., 2012;
Sathiyamoothry et al., 2013; Thirunarayanan et al.,
2013; Thirunarayanan and Sekar, 2013a, b) have
made extensive study of 13
C NMR spectra many of
ketones, styrenes and keto-epoxides. They
investigated the linear correlation of the chemical
shifts with Hammett substituent constants, F and R
parameters. The good, satisfactory and fair degree of
correlations was obtained in their investigations. In
the present investigation, the C=N carbon chemical
shifts (δ, ppm) of 3-(9-anthryl)-5-(substituted phenyl)-
4,5-dihydro-1H-pyrazolines have been assigned and
are presented in Table 2. Attempts have been made to
correlate the assigned C=N carbon chemical shifts (δ,
ppm) with Hammett substituent constants, field and
resonance parameters with the help of single and
multi-regression analysis for the prediction of
substituent effects. From Table 3, the C=N chemical
shifts (δ, ppm) has shown satisfactory correlation with
Hammett σ, σ+ and σI, substituent constants and F
parameters excluding 4-Cl substituents. The Hammett
σR constants and R parameters gave poor correlation.
The multi-regression analysis of these C=N chemical
shifts (δ, ppm) gave satisfactory correlation with
Swain-Lupton’s (Swain and Lupton, 1968)
parameters. The correlated equations are given in (17
and 18).
δC=N(ppm) = 155.34(±1.422) +9.375(±3.155)σI – 0.491(±0.137)σR (9)
(R = 0.977, P > 95 %, n = 10)
δC=N(ppm) = 154.76(±1.455) +10.952(±3.152) F + 0.146(±0.024) R (10)
(R = 0.980, P > 95 %, n = 10)
4. CONCLUSION
A series of more than 90% yields of 3-(9-anthyl)-4,5-
dihydro-5-(substituted phenyl)-1H-pyrazolines were
synthesised by fly-ash:H2SO4 catalyzed solvent-free
cyclization of (E)-3-(9-anthryl)-5-(substituted
phenyl)-2-propen-1-ones and hydrazine hydrate
under microwave irradiation. These pyrazolines were
characterised by their physical constants and spectral
data. The assigned spectral frequencies and chemical
shifts of the pyrazolines were correlated with
Hammett Substituent constants, F and R parameters.
The regression analysis shows satisfactory
correlations with these spectral frequencies.
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International Journal of Scientific Research in Knowledge (IJSRK), 1(8), pp. 299-307, 2013
307
Associate Professor Dr.Krishnamoorthy GunaSekar obtained his first Degree from Bharathidasan
University in National College, Tiruchirappalli in 1989. He later pursued Master’s Degree in
Chemistry in Bharathidasan University in National College,Tiruchirappalli in 1991. Dr. K. G. Sekar
received his Master of Philosophy and Doctorate Degree in Chemistry from Annamalai University,
Annamalainagar in 1993 and 1998.He has published over 50 referred articles in professional
journals and currently sits as the reviewer for 2 international journals. His current research is
focuses on physical organic chemistry and catalysis.. To data, he has published several scientific
articles related to oxidation kinetics and synthesis of organic compounds.
Dr. G. Thirunarayanan was completed his Master Degree of Chemistry with first class in
Bharathidasan University, Tiruchirappalli-620 024, India. The M. Phil. and Ph. D. research degrees
were persued in Annamalai University, Annamalainagar-608 002, India in the field of Physical
Organic Chemistry in 1999. His primary area of research is Synthesis, Green synthesis, Catalysis,
Spectral LFER studies and biological activities of Chalcones and their derivatives. At present Dr.
G. T. is a Faculty Member as Assistant Professor (SS) of Chemistry in Annamalai University. He
published more than 50 research articles in reputed referred national and international journals.