ABOUT THE CONTRIBUTORS

Here are included brief biographical sketches of only those authors who have contributed to this volume. Biosketches of contributors to Volume 2 are included in that volume.

Hans J. Ache is Professor of Chemistry at the Virginia Polytechnic Institute and State University. He obtained his Ph.D. degree in 1959 from the University of Cologne. He has over 100 publications to his credit and is the editor of "Positronium and Muonium Chemistry", an Adv. Chem. Sere Volume. His research interests are in the area of radiochemistry: application of nuclear probes to chemical problems and in hot atom chemistry.

E. W. Anackep is Professor of Chemistry, Montana State University, Bozeman, Montana. He received his Ph.D. degree in 1949 from Cornell University. He was the recipient of the NSF Science Faculty Fellowship, University of Oregon, 1964 - 1965. In 1967, he received the Faculty Research Award, Montana State Univer­sity. He has published a large number of papers in the field of solution behavior of surfactants.

K. S. Chan is presently with the Standard Oil Company of Ohio, Cleveland. He received his B.S. degree in Physics from Rangoon Arts and Science University, Burma in 1969, and M.S. and Ph.D. in Chemical Engineering from the University of Florida, Gainesville. His primary interests are the structural aspects of micellar solutions, flow through porous media and oil recovery processes.

Dean-Yang Chao is presently a postdoctoral fellow in the Macromoleculer Science Dept., Case Western Reserve University. He received his Ph.D. in 1977 from the University of Georgia. His main research interest is micelle kinetics and the physical chem­istry of macromolecules.

Mario Corti is affiliated with the Quantum Optics Section of CISE (Segrate - Milano, Italy). He is also Professor at the Istituto di Fisica dell' Universita di Milano. In the last five years, he has been working on quasielastic light scattering from pure fluids and micellar solutions.

507

508 ABOUT THE CONTRIBUTORS

Benjamin J. Czerniawski received his B.A. in Chemistry in 1978 from the University of Detroit, and was an undergraduate research participant.

StanZey s. Davis is Lord Trent Professor of Pharmacy, Uni­versity of Nottingham, U.K. His research interests include solu­tion thermodynamics, drug formulation and biopharmaceutics. He obtained his B.Pharm. and Ph.D. degrees from London University, and has held various appointments in the U.K. and the U.S. He has published over 100 papers in the field of colloid and pharma­ceutical science.

Vittorio Degiorgio is a Senior Researcher of the Italian National Research Council (CNR), and Professor of Quantum Elec­tronics at the University of Pavia. He has published tn the areas of quantum optics and statistical physics. His current research interests are in the applications of laser-light scattering tech­niques to micellar and macromolecular solutions, and in phase transitions and instabilities in open systems.

Ros&rio DeLisi is at the University of Sherbrooke on leave of absence from University of Palermo, Italy.

Edward A. Dennis is Associate Professor in the Department of Chemistry, University of California at San Diego. He received his Ph.D. degree in 1968 from Harvard University. He has published over 50 scientific papers. His research interests include micelle and membrane structure, NMR studies on phospholipid and surfactant conformation,and phospholipase mechanism.

Jacques E. Desnoyers is Professor at the Sherbrooke University, Sherbrooke, Canada. He received his B.Sc. (1958) and Ph.D. in 1961 from the University of Ottawa.

Belkacem Djermouni is presently working toward his Ph.D. degree on a scholarship from the government of Algeria at the Virginia Polytechnic Institute and State University. He obtained a B.S. degree in 1973 from the University of Algiers and completed his M.S. degree (3rd cy.cle docteur) in 1976 from the University of Strasbourg. His major research interests are in the applications of nuclear techniques to the solution of chemical problems.

FoZke E~iksson has been a Research Assistant in Physical Chemistry at Abo Akademi since 1972. His research is concerned with thermodynamic properties of surfactant solutions. He holds an M.Sc. degree.

ABOUT THE CONTRIBUTORS

Jan Christer Eriksson is Reader in Physical Chemistry at the Royal Institute of Technology, Stockholm. His research work has concerned surface thermodynamics, NMR studies of sur­factant association, and Auger electron spectroscopy. He holds a Ph.D. degree.

509

Raymond S. Farinato is a postdoctoral research chemist at the University of California, Berkeley. He received his B.S. in chemistry from R.P.I., and Ph.D. in physical chemistry in 1976 from University of Massachusetts based upon his graduate research dealing with light scattering studies of anisotropic moleculer and colloidal structures. He had a number of academic achievements including NSF NATO Fellowship in 1975, and Colloid and Surface Science Division travel grant.

EZeanor J. FendZer is Associate Professor of Chemistry at Texas A & M University. She obtained her Ph.D. degree in 1966 from the University of California, Santa Barbara. She was an NIH Research Career Development Awardee from 1971-1976. She has pub­lished more than 70 papers in the areas of micellar catalysis; NMR spectroscopy; and physical, organic, bioorganic and radiation chemistry. Also, she is co-author (with J.H. Fendler) of the book Catalysis in Micellar and Macromolecular Systems published in 1975. Her research interests include biomedical functions of surfactants.

F. Fujiwara is presently at the University of Campinas in the State of Sao Paulo, Brazil. He received his Ph.D. from the Uni­versity of Alberta. His research continues in the area of lyotro­pic liquid crystals, studying the static anisotropic magnetic susceptibility and dynamics of alignment.

Ron Giordano is a student at Northwestern University.

D. E. GuveZi holds B.Sc. and Ph.D. degrees. Research interests are micellar systems, study of hydrophobic bonding using micelles as model systems.

WiZZie L. Hinze is Assistant Professor of Chemistry at Wake Forest University. He received his B.Sc. and M.Sc. degrees from Sam Houston State University and Ph.D. from Texas A&M University in 1974. He moved to Wake Forest University in 1975. His research interests include development of spectral methods of analysis and the application of micellar and macromolecular systems to problems encountered in analytical and agricultural chemistry.

510 ABOUT THE CONTRIBUTORS

LevineZ G. Ionescu is Professor of Physical Chemistry, Universidade Federal de Santa Catarina, Santa Catarina, Brazil. Before his present position, he had a number of appointments in the United States. He received his Ph.D. in Physical Chemistry from New Mexico State University in 1970. His research interests are properties of surfactants, micelles and liquid crystals, micellar catalysis, membrane models, respiratory pigments, clath­rates or gas hydrates and chemistry of noble gases. He has pub­lished over 25 scientific articles.

Yan-Ching Jean is presently a Research Associate in the Chemistry Department, University of British Columbia. He received his B.S. from the Taipei Institute of Technology in 1968 and his Ph.D. in Chemistry in 1974 from Marquette University. During 1975 __ 1977, he was a Research Associate at Virginia Polytechnic Institute and State University where he carried out experimental work in positronium chemistry. He is presently studying the chemistry of muonium.

S. B. Kayes is Lecturer in Pharmaceutics. His research interest is colloid chemistry. He holds B.Sc. and Ph.D. degrees.

L. J. Magid is Assistant Professor of Chemistry, University of Tennessee. She obtained her Ph.D. in 1973 from the University of Tennessee. She did her graduate work at Rice University and was a National Science Foundation Fellow. She was outstanding senior at Rice University in 1969. Her current research interests are amphiphilic aggregates in apolar solvents, micellar catalysis, and l3 c spin-lattice relaxation times in normal and inverted amphiphilic aggregates.

Bernard McNicoZZ is currently engaged in doctoral research at l'Institut du Genie Chimique, Toulhouse, France. He is a M. Eng. graduate of Ecole Poly technique, Montreal.

Kenjiro Meguro is Chief Professor in the Department of Applied Chemistry, University of Tokyo. He received his Ph.D. in 1957 based on his research dealing with the dispersing action of surfactants. He was awarded the "Traeatise Prize" of the Japan Society of Color Material. He made a contribution toward forma­tion of the organization of surface chemistry community in Taiwan. At present, he is a Director and Vice President of the Japan Society of Color Material. He is on the Editorial Boards of Progress in Organic coatings, and Chemistry and Industry (published in Japan), and on the Advisory Board of J. Colloid Interface Science.

ABOUT THE CONTRIBUTORS 511

Kashmiri LaI MittaI* is presently employed at the IBM Corpor­ation in Hopewell Junction, N.Y. He received his B.Sc. in 1964 from Panjab University, M.Sc. (first class first) in Chemistry in 1966 from Indian Institute of Technology, New Delhi, and Ph.D. in Colloid Chemistry in 1970 from the University of Southern California. In the last few years, he has organized and chaired a number of very successful international symposia and in addition to this two-volume set, he has edited seven more volumes as follows: Adsorption at Interfaces, and Colloidal Dispersions and Micellar Behavior (1975); Micellization, Solubilization, and Microemulsions, Volumes 1& 2 (1977); Adhesion Measurement of Thin Films, Thick Films, and Bulk Coatings (1978); and Surface Contam­ination: Its Genesis, Detection, and Control, Volumes 1 & 2, (August, 1979). In addition to these volumes he has published about 40 papers in the areas of surface and colloid chemistry, adhesion, polymers, etc. He has given or is scheduled to give many invited talks on the multifarious facets of surface science, particularly adhesion, on the invitation of various societies and organizations in many countries, and is always a sought-after speaker. He is a member of many professional and honorary soci­eties, is a Fellow of the American Institute of Chemists, is listed in American Men and Women of Science and Who's Who in the East. Recently he has been appointed a member of the editorial boards of a number of scientific and technical journals. He started the highly-acclaimed short course on adhesion in the United States in 1976.

Pasupati MUkerjee is Professor at the School of Pharmacy, University of Wisconsin - Madison. He obtained his Ph.D. degree in colloid and physical chemistry from the University of Southern California in 1957. He has served as a member of the Executive Committee of the Division of Colloid and Surface Chemistry, ACS. He is currently a member of the Commission on Colloid and Surface Chemistry of IUPAC, and is a member of the Advisory Board of the Journal of Colloid and Interface Science. He is a fellow of AAAS.

G. I. MUkhayer is Senior Lecturer, Faculty of Pharmacy, Khartoum, Sudan. His research interest is colloid chemistry. He obtained his Ph.D. degree from the University of Aston, Birming­ham, U. K., in 1974.

Norbert MUlIer is a member of the Physical Chemistry faculty at Purdue University. He is the author of a chapter on NMR and of more than 50 research articles. His principal research inter­ests are in the use of NMR spectroscopy to study intermoleculer interaction phenomena in aqueous and nonaqueous solutions, includ­ing surfactant aggregation processes.

*As the editor of this two-volume set.

512 ABOUT THE CONTRIBUTORS

ctaude Ostiguy received B.Sc. (1976) and M.Sc. (1977) degrees from Sherbrooke University.

Geratd Perron is a Research Associate at Sherbrooke Univer­sity. He received B.Sc. (1968) and M.Sc. (1971) degrees from Sherbrooke University.

L. W. Reeves is Professor at the University of Waterloo, Waterloo, Canada. He was awarded the Ph.D. in 1954 and D.Sc. in 1965 from the University of Bristol. He has held a number of positions before coming to Waterloo. He became a Visiting Pro­fessor at the University of Sao Paulo in 1967. His current re­search is investigations at the molecular level into novel 1yome­sophases that orient in magnetic fields and with emphasis on the colloid, interface science and model membrane aspects. He was Noranda Lecturer for the Chemical Institute of Canada in 1969 and has given various invited plenary lectures in the area of NMR Spectroscopy and now in colloid and interface science.

Anthony A. Ribeiro is a postdoctoral fellow in the Department of Chemistry, University of California at San Diego, where he also received his Ph.D. degree in 1975. He will soon assume a staff position at the Magnetic Resonance Laboratory, Stanford University. His research interests are in the application of NMR spectroscopy to micelles, phospholipids, and peptides.

Mary F. Roberts is a postdoct-pra1 fellow in the Department of Chemistry, University of California at San Diego. She received her Ph.D. degree from Stanford University in 1974. She will soon assume the position of Assistant Professor of Chemistry, MIT. Her research interests are in the area of NMR studies on phospholipid conformation and the mechanism of phospho1ipases.

Robert J. Robson is a graduate student working toward his Ph.D. degree in the Department of Chemistry, University of Calif­ornia at San Diego. His research interests are in the area of micellar structure and phospholipid-detergent interactions.

Mitton J. Rosen is Professor of Chemistry, Brooklyn College, City University of New York. He received his Ph.D. from Polytech­nic Institute of New York in 1949. He has been a Visiting Profes­sor in Applied Chemistry, Hebrew University, Jerusalem on three different occasions. He is a consultant to Federal Trade Commis­sion and various industrial organizations. He has authored the book Surfactants and Interfacial Phenomena published in 1978; and co-authored the book Systematic Analysis of Surface-Active Agents. In addition, he has published about 35 research papers, mainly on surfactants, and is the recipient of four patents on surfactants. He has been very active in professional activities and honorary societies.

ABOUT THE CONTRIBUTORS

Steven N. Rosenthal attended Texas A & M University as a graduate student. His graduate research concerns the se1f­associatiOn behavior of naturally occurring surfactant systems. He has co-authored a review chapter.

513

Robert L. Rowell is Associate Professor in the Department of Chemistry, University of Massachusetts, Amherst. He received his Ph.D. degree in Phys:i.cal Chemistry from Indiana University in 1960. He has held a number of appointments before his present position. In 1973, he was a Visiting Professor, Department of Physical Chemistry, University of Bristol. He has been very active in pro­fessional societies (particularly American Chemical Society), has held a number of responsible positions, and has organized and chaired numerous symposia and sessions. He has been quite active as editor or co-editor and is presently the co-editor (with R. H. Ottewi11) of the Colloid Science Series published by Academic Press.

Donn Rubingh is employed as a Research Che~ist at the Proc­ter & Gamble Company's Uiami Valley Research Laboratories. He received his Ph.D. in Physical Chemistry from the University of Wisconsin, Madison. He has published in the area of surface and colloid science.

James Sangster is a Research Associate in the Department of Chemical Engineering, Ecole Polytechnic, Montreal. IIe received his Ph.D. from Edinburgh University. His fields of interest in­clude thermodynamics of aqueous solutions.

Zoltan A. Schelly is Associate Professor of Physical Chem­istry, University of Texas at Arlington. He received his B.Sc. degree in 1967 from the Technical University of Vienna. He has had faculty and research appointments at various universities. His main research interest is the dynamics of fast chemical and physical rate processes, including mice11ization and interfacial reactions.

Henry P. Schreiber is Professor of Chemical Engineering, Ecole Poly technique , Montreal. Before his present position, he spent 18 years with Canadian Industries Ltd. He graduated from University of Toronto. He is active in fields involving interfaces and macro­molecules.

Dinesh O. Shah is Professor of Chemical Engineering,Anesthe­sio1ogy and Biophysics at the University of Florida, Gainesville. He received his Ph.D. degree in 1965 from Columbia University. He received the University of Florida's "Excellence in Teaching Award" in 1972; "President's Scholar Award" in 1975; and "Outstanding Service Award" in 1976. He is the recipient of the "Best Paper

514 ABOUT THE CONTRIBUTORS

Award Trophy" given at the International Congress of Chemical Tech­nology in 1978. Presently, he is a Visiting Professor in Chemical Engineering, Petroleum Engineering,and Institute for Energy Studies of Stanford University. He is continuing his research in many areas including membranes, monomoleculer films~ liquid crystals, microemulsions, improved oil recoverY,and surface chemical aspects of lungs, vision and anesthesia.

N. Shoji is presently on the teaching staff of Shiba High School in Tokyo and at the same time he is carrying out his re­search at the Science University of Tokyo. He graduated in 1972 from the Science University of Tokyo and this \:as followed by post­graduate research dealing with micelles and obtained a Masters degree in Science from the same university.

Eric S. Smith received his B.A. in Chemistry in 1978 from the University of Detroit, and was an undergraduate research partici­pant.

Garland D. Smith is employed at the Continental Oil Company's R&D Facility in Ponca City, Oklahoma. He received his B.S. degree from the University of Iowa in 1969, and Ph.D. from the University of I-Jyoming based on his research dealing with micro­emulsions as model systems for metal1oproteins.

Per Stenius has been the Director of the Swedish Institute for Surface Chemistry, Stockholm, since 1977. Before this time he was in the faculty at Abo Akademi, Turku, Finland. His re­search has concerned mice11er solution, lyotropic liquid crystals and microemmulsions as well as suspensions of solids in aqueous solutions, in particular connected with pulp and paper industry. He holds a Ph.D. degree.

Ghulam Sumdani is at the University of Texas at Arlington on leave of absence from the University of Engineering and Technol­ogy, Lahore, Pakistan. He received his M.S. degree in 1966 from Panjab University, and is presently working on his thesis on fast reactions in oriented media.

Mario Suzuki is presently completing his Ph.D. degree. He completed his M.Sc. degree in 1975 at the University of Sao Paulo. He developed the new technique of orienting complex ions in lyo­tropic liquid crystals that are aligned by magnetic fields.

Tadashi Tokuhiro is Associate Professor of Chemistry, Univer­sity of Detroit. He received his Ph.D. degree in Physical Chemistry and Chemical Physics in 1962 from the Tokyo Institute of Technology. He has held a number of positions both in Japan and the U.S. before his present position. He has published about 30 scientific papers.

ABOUT THE CONTRIBUTORS 515

His research interests include NMR relaxation phenomena, NQR spec­troscopy in solids, structure and molecular dynamics of micelles, and liquid and solution structures.

Eric Tomlinson is currently Visiting Associate Professor, College of Pharmacy, Ohio State University from the School of Pharmacy and Pharmacology, Bath University, Bath, U.K. His re­search interests are solution thermodynamics and its application to biological systems, ion pairs, and drug formulation.

J. A. Vanin has been on the faculty of the University of Sao Paulo, Sao Paulo, Brazil. He completed his Ph.D. dissertation at the University of Sao Paulo in 1974 in the subject area of forma­mide oriented in lyotropic liquid crystals.

Raoul Zana is ~fuitre de Recherches at the Centre de Recherches sur les Macromolecules, C.N.R.S., Strasbourg, France. He received his D.Sc. in 1964 from the University of Strasbourg. His current research interests are ion-solvent interactions and micellar solu­tions.

SUBJECT INDEX

Pages 1-516 appear in Volume 1 Pages 517-940 appear in Volume 2

Absorbance Spectra of and in Surfactants, 411-422

Acridine Orange, 325-326 Acy1cho1inesters

aqueous stability of, 867-877 complexation with large ions,

867-877 possible mechanism of hydrol­

ysis of, 877 solubility product values for

interaction between a1ky1-sulfates and, (table), 874

Aggregation, contd. number, 442

effect of solvent, 440-449 solvent effects on, 427-449

Alcohol Ether Sulfates, 210-211 Alcohols

effect on c.m.c., 391-404 Alcohol Sulfates, 208-209 Alkylammonium Carboxylates, 456

aggregation of, 457-461 l3C Chemical shifts of, (table),

460 Adsorption of Surfactants on micellar chemical shifts of,

Electrodes, 601-604 459 AerosolOT relaxation times of, (table),

aggregation number of, (table), 460 446 A1kylammonium Salts

critical micelle concentration, aggregation parameters for, (table), 446 (table), 444

dc and ac polarograms of, 617 Alkylarylsulfonates electrical conductivity of, interfacial activity of, 841-

700-701 849 ultrasonic absorption studies

of, 473-482 Aggregate Size

cosolvent effect on, 430-432 Aggregation (see also Micelles,

and Micellization) in aqueous systems, 428-439

cosolvent effect, 430-439 in nonaqueous solvents, 455-

470, 473-482 in nonaqueous solvents of low

dielectric constant, 440-448

in polar nonaqueous solvents, 439-440

Alkylbenzene Derivatives, 199-204

Alkyl Sulfates (see also Sodium Dodecyl Sulfate) interaction with phenothia­

zines, 889-900 kinetic studies of, (table),

273 solubility product values for

interactions with acylcholi­nesters, (table), 874-875

Alpha Olefin Sulfonate, 211-212 Amine Oxide, 213

xvii

xviii

Amphiphilic Aggregation solvent effect on, 427-429

Analytical Chemistry use of surfactant and micellar

systems in, 79-115 Anionic Surfactant Micelle

partial cross-section of, 255 Aqueous-Organic Mixtures

thermodynamic properties of, 241-242

Aromatic Alcohols effect on c.m.c., 355-364

Association in Nonaqueous Sol­vents, 455-470

Azobenzene, 614

Benzoylacetoanilide, 408 Benzolyacetone, 408

absorption spectra of, 409 Bifunctional Micelles

cooperativity and acyl trans­fer processes in, 550-554

Bile Acid Esters, 456 self-association of, 463-470

Bile Acids chemical representation of,

577 structure of, 462

Bile Salt Micelles catalysis in, 575-594

Bimolecular Reactions catalysis of, 524-525 inhibition of, 524 rate-surfactant profiles in,

526-532 Binary Liquid Systems

mutual solubilities in, 879-887

Butanol as Cosurfactant, 724

Calcium Tolerance of Petroleum Sulfonates, 927-939

Catalysis by Functional Micelles 532-534

Catalytic Efficiency of Func­tional Micelles, 547-550

Cationic Surfactants c.m.c. of, 355-364

INDEX

Cetylpyridinium Chloride solubilization of organic liq­

uids in, (table), 168 Cetyltrimethylammonium Bromide,

408, 489, 724 aggregate dimensions by corre­

lation spectroscopy, (table),3l5

lighter scattering studies of, 311-320

micelles of, (some thermo­dynamic properties, table), 492

micelles of, (in water di­methyl sulfoxide), 487-494

molecular dynamics of, 503-505

proton spin lattice relaxation study of, 497-504

surface tension of, 489-490 Cetyltrimethylammonium Chloride,

408 light scattering studies of

311-320 Channel Surface Viscometer,

734-735 l3C Chemical Shifts for Cholates,

(table), 466 l3C NMR Measurements, 457 Coalescence of Emulsion Droplets

role of surfactants in, 817-837

Cofactor, 711 Commerical Surfactants, 195-216

alcohol ether sulfates, 210-211

alcohol sulfates, 208-209 alkylbenzene derivatives, 199-

204 alkylol amides, 213 alpha olefin sulfonate, 2ll~

212 amine oxide, 213 fatty alcohol derivatives, 204 glossary of, 196-197 nonionic surfactants, 205-208 other, 214 secondary alkane sulfonate,

212-213 Complex Coacervation, 8-12

INDEX xix

Complex Solubilization in Excess Surfactant, 14-17

Critical Micelle Concentration, contd.

Consumer Products dishwashing liquids, 216 liquid laundry products, 215 powdered laundry products, 215

Core Surface Area, (table), 253 Correlation Spectroscopy, 315 Cosolvent Effects, 430-439 Cosurfactant

effect on phase behavior of microemulsions, 635-641

optical salinity versus, 642 Counterion Association, Degree

of, (table), 258 Counterion Binding

and specificity, 257-259 cosolvent effect on, 430-432

Critical Micelle Concentration (c.m.c.) and solubility parameter of

surfactants, 372-375 determination of, (by electro­

chemical methods), 616-619 determination of, (by keto­

enol equilibria), 409-411 determination of, (by keto­

enol tautomerism), table, 412

in mixed solvents, (table), 369

of Aerosol OT, (table), 446 effect of solvents, 446

of alkyl sulfates, 873 of ammonium salt of dodecyl­

diethoxy sulfate, 369 of cationic surfactants, 355-

364 effect of aromatic alcohols, 355-364

of cetyltrimethylammonium bromide, 315, 421, 591 effect of dimethyl sulfox­ide, (table), 491

of dodecyltrimethylammonium chloride, 412

of hexadecylbenzyldimethyl­ammonium chloride effect of aromatic alcohols, 358

of hexadecyltrimethylammonium bromide effect of aromatic alcohols, 360

of mixtures of surfactants, 345-347

of nonionic surfactants (tables), 178, 441 effect of solvent (table), 441

of pentadecyl benzene sulfo­riate, 394

of petroleum sulfonate (TRS 10-80), 396, 399

of phenothiazines (table), 899 of polyethylene glycol n-dode­

cylether, 412, 418 of polyoxyethylene nonylphen­

yl ether, 412, 418 of sodium dodecyl benzene

sulfonate, 394 of sodium dodecyl sulfate,

369, 412, 429 effect of additives, 370 in ethanol-water mixture, 421

of synthetic and petroleum sulfonates, 391-404 effect of alcohols, 391-404 effect of dissolved oils, 391-404

of tetradecylbenzyldimethyl­ammonium chloride effect of aromatic alcohols, 358

of tetradecyltrimethylammonium bromide effect of aromatic alcohols, 359

of Triton X-lOO, 179, 412, 418

of Triton X-114, 369 of Triton X-305, 327 versus solubility parameter

plot for nonionic surf act­ants, 374

xx

Delayed Coincidence, 136 Decylpiperidinium

polarhead structures of, 261 Detergentless Microemulsions,

717-718 Differential Capacity Curves

in the Presence of Surfactant, 603

Diffusion Co-effici~nts of sodium dodecylsulfate,

(table), 381 Dimethylsulfoxide, 488, 499

micellar catalysis in, 575-594 Dipolar Aprotic Solvents

catalysis in, 575-594 Dissolved Oils

effect of, (on c.m.c. of syn­thetic and petroleum sulfo­nates) 391-404

Dodecylamine Solutions chemical equilibria in, 782-

784 surface activities of, 784-786

Dodecylammonium Propionate ultrasonic absorption studies

of, 473-482

Effective Polarities (Table), 165

Effect of Solubilization on c.m.c., 159-161 on micellar size, 161-163

Electrical Conductivity Model of wlO Micremulsion, 699-706

Electrical Double Layer, 255-256 Electrocapillary Curves in the

Presence of Surfactants, 602 Electrochemical Investigations

in Micellar Media, 599-620 Electrochemical Methods

determination of c.m.c. by, 616-619

Electrochemistry of Solubilized Substances, 607-615

Electrode Reaction effect of surfactant adsorp­

tion on, 604-606 Electrodes

adsorption on, 601-604

INDEX

Electrolyte Effect on micelle size and shape, 248 on micellization, 247-262

Electrophoretic Mobility, 400 Emulsion Droplets, Coalescences

of, 817-837 Emulsion Films

lifetime of, 836-837 rupture of, 833-836 thinning of, 831-833

Equivalent Alkane Carbon Number, 757, 802

Equivalent Conductance effect of aromatic alcohols on,

361-364 of cationic surfactants, 361-

364 of pentadecyl benz.ene sulfo­

nate, 398 of sodium dodecyl benzene sul­

fonate, 397 Excimer Emission, 568-569

Flotation of hematite using oleate,

786-790 of quartz using dodecylamine,

790 role of dimers in, 791-792

Floodaid, 141, 906-911 Fluid Flow in a Microemulsion

Flood, 642-645 Fluid Interfaces

rheological properties of, 733-746

Functional Micellar Catalysis, 541-555 and stereochemistry, 554-555 general features of, 554-545 of ester hydrolysis, 545-547

Functional Micellar Reagents structures of, 542-544

Functional Micelles, 519 catalysis by, 532-534, 541-

555 catalytic efficiency of, 547-

550 Froth Flotation, 777

INDEX

Headgroup Effects, 259-262 Hemi-micelle, Schematic Diagram

of, 793 Hemi-micellization, 793-796 Hexadecylbenzyldimethylammonium

Chloride, 356 Hydrodynamic Radius, 383

effect on aggregation number, 387

Hydoxyethyl Surfactant reactions in micelles of,

(table), 534

Ilkovic Equation, 607 Interaction

method of study of, 5-6 thermodynamics of, 35 types of, 5

Interaction, Factors Affecting, 17-37 ionic strength, 23-26 organic additives, 26-31 pH, 23 structure, 17-23 temperature, 31-37

Interaction Parameter in Mixed Surfactants, (table), 350

Interfacial Activity of Alkyl­arylsulfonates, 841-849

Interfacial Tension (see also Ultralow Interfacial Tension) effect of variables on, 403 variables controlling, 842-844

Inverted Aggregates, 440-448 Inverted Micellar Systems, 659 Ion or Surfactant - Selective

Electrode Method determination of c.m.c. by,

618-619 Ionic Interaction and Phase

Stability, 3-37 Ionic Interactions, Table of,

18-19 Ionic Spherical Micelle

schematic of, 81 Ionic Surfactants in Organic

Solvents, 473-482 effect of water, 478-479

Ionomolecular Complex, 778 Ionpair Association Constant in

Water, Table of, 9 Ionpair Formation, 7

Keto-enol Tautomerism application in the study of

effect of organic solvents, 418-422

application in the study of micellar property, 407-422

determination of c.m.c. by, 409-417

Kinetics of Micellization, 267-290 experimental methods, 269-272 theoretical treatments, 282-

290 Kinetic Studies of

alkylsulfates (table), 273 assorted surfactants (table),

276

xxi

micelle-guest dissociation and recombination (table), 277

simple anionic surfactants, (table), 274

simple cationic surfactants, (table), 274-275

Knife Edge Surface Viscometer, 735-736

Latex Particle Surfaces desorption of SDS from, 853-863

Lightscattering Measurements, 313, 393

Lighscattering Studies of cetyltrimethylammonium

bromide & chloride, 311-319 Lippert Equation Plots, 465 Lyomesophases

lightscattering studies of, 68-70

properties of, 65-68 use of, (in colloid and inter­

face science), 70-73 Lyotropic Liquid Crystals that

Align in Magnetic Fields, 63-74

xxii INDEX

Magnetic Fields and Lyotropic Micellar Catalysis of, or Micel-Liquid Crystals, 63-74 lar Effect on, contd.

Maximum Suppressive Action of trinitrobenzamide, 586-594 Surfactants, 606-607 unimolecular reactions (table),

Mediater-titrant (M-T) , 615 522 Micellar Applications Micellar Destruction, 422

in analytical separations, Micellar Emulsion, 709 110-115 Micellar Incorporation of Re-

in electroanalytical chemistry, actants, 525 108-110 Micellar Property of Surfactants

Micellar Catalysis and Inhibition, effect of additives, 370 519-536, 541-555, 559-570, 575- effect of alcohols, 391-404

594 effect of aromatic alcohols, in dipolar aprotic solvents, 355-364

575-594 effect of dissolved oils, by steroidal surfactants, 575- 391-404

594 effect of organic solvents, Micellar Catalysis of, or Micel- 419-422

lar Effect on effect of solvents, 427-449 bimolecular reactions (table), Micellar Rate Effects

522, 524-532 validity of the pseudophase electrode reactions, 599-620 model, 534-536 electron transfer reactions, Micellar Shapes

564-565 core surface area for monomer electro-oxidation reaction, for different, (table), 253

615 Micellar Systems ester hydrolysis, 545-547 and analytical parameters excitation energy transfer (table), 96

processes, 567-568 and analytical separations, excited state acid-base equili- 110-115

bria, 570-571 and electroanalytical chem-formation of the p-nitrophen- istry, 108-110

oxide ion from bis-p-nitro- effect of, (on spectral para-phenyl phenylphosphonate, meters), table, 91 581-587 effect of, (on stability con-

hydrolysis of N-~-butyl 2,4 stants of formation of dinitrotrifluoroacetanilide, metal-chelate complexes), 550 95

hydrolysis of PNPA (table), 549 studied by positron annihila-hydrolysis of p-nitrophenyl tion techniques, 129-150

hexanoate (PNPH) (table), 548 use in analytical chemistry, photochemical reactions, 559- 79-115

570 use in spectral methods of photoionization process, 563- analysis, 85-108

564 Micelle-Catalyzed Reactions quenching of excited states, (see Micellar Catalysis)

565-566 Micelle Formation (see also reactions of N-tert-butyl- Aggregation, and Micelliza-

2,4,6 tion)

INDEX

Micelle Formation, contd. effect of organic solvents on,

369-370, 419, 487-495 standard free energy of, 298-

302 Micelle-guest Dissociation and

Recombination (table), 277 Micelles

in analytical chemistry, 85-115

mixed, 186-191, 337-353 of nonfunctional surfactants

catalysis and inhibition by, (table), 522

solubi1izates in, 163-167 solubilization capacities of,

167-172 Micelle-Water Distribution Equil­

ibria, 157-159 Mice11ization

and adsorption, comparison of, 45-60

electrolyte effect on, 247-262 kinetics of, 267-290 thermodynamic functions of,

237 ... 241 Microemu1sion

schematic representation of an D/W, 692

Microemu1sion Flooding, 627-655 fluid flow in, 642

Microemu1sion Injection continuous, 645-649 finite, 652-653

Microemulsions an electrical conductivity

model of WID, 699-705 and inverted micellar systems,

659-669 as host for chemical reac­

tions, 709 brine and hydrocarbon solubil­

ity in, 639-641 detergent1ess, 717-718 interfacial tension versus

salinity for, 637 phase behavior of, 631-642

673-695, 714, 718, 725

xxiii

Microemu1sions, contd. reactions in, 707-718, 723-728 viscosity of, 638-639

Mixed Micelles, 186-191, 337-353 a theory for, 340-343 monomer concentrations in,

350-352 phospholipid conformation in,

190-191 with phospholipids, 186-190

Mixed Solvents c.m.c. in, (table), 369

Mixed Surfactants c.m.c. of, 345-347

Mineral-Water Systems, 777 Monomer-Micelle Equilibria,

155-163 Mutual Solubility in Binary

Liquid Systems influence of amphiphi1ic sub­

stances on, 879-886

Nonfunctional Micelles, 519 Nonidea1 Mixed Micelle Theory,

342 Nonionic Micellar Systems

and metal ions determination, 88

relaxation amplitude of, 323-333

Nonionic Surfactant Micelles 175-192 mixed micelles with phospho­

lipids, 175-192 Nonionic Surfactants

applied properties of, 207 c.m.c. by keto-enol tautomer­

ism, 413-417 c.m.c. versus solubility para­

meter plot for, 374 micellar structure of, 177 NMR studies of solution prop-

erties of, 184-186 properties of, 176-181 structure of, 177 synthesis of, 206-207

xxiv

Oleate Solutions chemical equilibria in, 780-782 surface activities of, 784-786

Optimal Salinity, 806 Orange OT

dc and ac po1arograms of the solubilized, 611

electrode process of, 613 transfer co-efficient of,

(table), 612

Parachors, Table of, 375 Partition coefficient of Sur­

factants, 809-811 Petroleum Su1fonates, 391-404,

756-762, 903 commerica1 sodium, (table), 929 tolerance of, (to the presence

of calcium ions), 927-940 Phase Behavior for the System

TRS 10-80, Brine, Alcohols, and Hydrocarbons, 673-695

Phase Diagrams for C6H6 - H20 - C5H1l0H - K

oleate, 880-881 p-xy1ene - H20 - nonionic sur­

factant, 883-884 water-hydrocarbon - oxyethy1-

ated-n-decano1, 919-924 water-She11f1ex 131 - oxyethy1-

ated decano1s, 922 water-sodium octanoate -

n-decano1 - n-octane, 664 Phase Equilibria in the Water­

Sodium - n-Octanoate - n De­canol, 662

Phenothiazines enthalpy/entropy plot for the

interaction with SDS, 896 interaction with a1ky1su1fates,

889-900 properties of, (table), 899 selected thermodynamic para­

meters for the interaction with SDS, (table), 893

solubility product values for interaction with SDS (table), 892

Phenothiazines, contd. structures of, 891

Phospholipids

INDEX

mixed micelles with nonionic surfactant micelles, 175-192

conformation in mixed micelles 190-192

Photochemical Reactions in Mi­cellar Systems, 559-570 site of solubilization of

molecules, 562 Photoionization in Micellar

System, 563-564 Polarographic Parameters, Table

of, 611, 612 Polarography

determination of micelle size and diffusion coefficient by, 620

Po1ydispersity, 254-255 Po1ydispersity Effects, 386-388 Po1ydispersity Index for Sodium

Dodecy1 Sulfate, Table of, 381 Po1yoxyethy1enated t-Octy1-

phenol, 58 Polystyrene Latex Particles

desorption of SDS from, 853-863

Positron Annihilation in Mi­cellar Systems, 138-150

Positron Annihilation Tech­niques and micellar systems, 129-150 study of location of solu-

bi1izate by, 142-150 Positron Lifetime Measurements,

133-138 Positronium Formation 130-132

experimental measurements of, 133-138

Positronium Reactions, 132-133 experimental measurements of,

133-138 Pre-Micellar Light Scattering

Maximum, 311-319 Pre-Micellar Maximum, 314 Proton Spin Lattice Relaxation

Study, 497-502

INDEX

Pseudophase Model of Micellar Rate Effects, 534-536

Quasielastic Light Scattering, 377-389

Quinoline, 710

Rate Constants for Ps-Nitroben­zene Interactions, 144 in surfactants, 145 in various solvents, 144

Reaction of a Solubilized Sub­stance on an Electrode

schematic model of, 601 Reaction in Micelles (see Micel­

lar Catalysis or Micelle Cat­alyzed Reactions)

Reactions in Microemulsion Media, 707-718, 723-728 phosphate ester hydrolysis,

723-728 photodegradation of chloro­

phyll, 712 reactions involving amino­

alcohols and metals, 713-717

reactions involving porphy­rins and metals, 709-713

Relaxation Amplitudes, 329-333 Relaxation Kinetics of Micelle

Systems, 324 Reversed Micelle, Schematic of,

82 Rheological Properties of Fluid

Interfaces, 733-746 Rupture of Emulsion Films, 833-

836

Salinity Gradient, 653-655 Secondary Alkane Sulfonate,

212-213 Second Order Rate Constants in

Aqueous and Micellar Pseudo­phases (Table), 531

Self-Association of Surfactants, 461

xxv

Serum Replacement Technique for Cleaning Latexes, 854-855

Setschenow Constant, 30 Sodium Cromoglycate, 11, 33 Sodium Dodecyl Benzene Sulfonate

light scattering measurements of, 395

surface tension of, 394 Sodium Dodecyl Sulfate (SDS)

aggregation number, 382 aggregation phenomena by

quasielastic light scatter­ing, 377-389

adsorption isotherm of, (on polystyrene latex par­ticles), 861

as maximum suppressor, 606 average diffusion co-efficient

(table), 381 chemical stability of acyl­

cholinesters in the pres­ence of, 872

c.m.c. in t-BuOH-water mix­tures, 429

desorption of, (from poly­styrene latex particle sur­faces), 853-863

effect of NaCl on aggregation of, 377-389

effect of, (on mutual solu­bility in binary liquid systems), 886

hydrodynamic radius of, (as a function of concentration of), 383

interaction with benzyltri­phenylphosphonium salts, 22

mechanism of formation of aggregates of, 383-385

shape of aggregates of, 385-386

solubility product values for interaction with pheno­thiazines (table), 892

Sodium Dodecyl Sulfate Micelles transfer free energies of

hydrocarbon gases from hydrocarbon liquids to, (table), 172

xxvi

Sodium Octanoate, 660 Sodium Octanoate Micelles

aggregation numbers of, (table), 306

model calculations for, 297-309

Sodium Octanoate - Water Sblu­tions, 302-307

Solubility Parameter versus c.m.c. of Nonionic Surfact­ants, 374

Solubility Product, 12-14 Solubility Product Values for

Interaction Between Alkyl­sulfate and Acylcholi­nesters (table), 874

Solvent Effects on Amphiphilic Aggregation (see also Aggre­gation), 427-449

Solubilizates location and distribution of,

163-167 Solubilization

and monomer-micelle equilibria, 155-163

and determination of c.m.c., 159-161

capacities of micelles, 167-172

in aqueous micellar systems, 153-172

Solvent Jump, 323-333 Spectra Parameters of Metal­

Chelate Complexes (Table), 91 Spin-Lattice Relaxation Rates,

(Table), 501 Spin-Lattice Relaxation Times for

Methyl Cholate (Table), 468 Standard Free Energy of Adsorp­

tion effect of addition of elec­

trolyte on, 54 effect of branching of alkyl

chain on, 51 effect of length of alkyl

chain on, 50 effect of size of the hydro­

philic group on, 53

INDEX

Standard Free Energy of Adsorp­tion, contd. effect of temperature, 57 effect of water structure

modifiers on, 59 Standard Free Energy of Micelli­

zation effect of addition of elec­

trolyte on, 54 effect of branching of alkyl

chain on, 51 effect of length of alkyl

chain on, 50 effect of size of the hydro­

philic group on, 53 effect of temperature, 57 effect of water structure

modifiers on, 59 Stability Constants for Forma­

tion of Metal Chelate Com­plexes, 95

Steroidal Surfactants catalysis in the presence of,

575-594 Sulfonate Surfactant Solutions

order-of-mixing effects in, 903-917

Surface Dilational Viscosity, 736-738

Surface Excesses, 369, 844 Surface Shear Viscosity, 734-736 Surface Viscometer

channel, 734-735 knife edge 735-736

Surface Viscosity as a Capillary Excess Transport Property, 746

Surface Wave, Longitudinal, 738-741

Surfactant Losses in a Micellar/ Polymer System, Mechanism of, 649-651

Surfactant Partitioning, 809-811 Surfactant-Selective Electrode

Method determination of c.m.c. by,

618-619 Surfactant Solutions

associative interactions in, 779

INDEX

Surfactant Solutions, contd. chemical equilibria in, 778-

784 Surfactant Systems

interfacial tension of, 801-814

phase behavior of, 801-814 Swollen Micellar Solution, 709 Synthetic Su1fonates, 391-404 Szyszkowski Equation, 48

Temperature Effect on diffusion co-efficient (table),

381 po1ydispersity index (table),

381 Tertiary Oil Recovery, 627-655

749-770 Tetradecylbenzy1dimethy1ammonium

Chloride, 356 Thermodynamic Functions

of micel1ization, 237-241 trends in, 229-237

Thermodynamic Properties of Aqueous-Organic Mixtures, 241-242

Thermodynamic Properties of Sur­factants direct measurement of, 221-243

Thermodynamic Relations, 224-229 Thermodynamic Substituent Con­

stant, 38 Thermodynamics of Aggregation

cosolvent effects on, 432-439 table of parameters of, 435-436

Thermodynamics of Mice11ization, 221-243, 297-309, 492-494 experimental techniques, 223-

224 Thinning of

a plane-parallel film, 823-825 emulsion films, 831-833

Trapped Oil Ganglion, Model Of, 752

Triton X-100 Micelles molecular weight of, (table),

180

Triton X-lOO Micelles, schematic drawings of, 183

Triton X-305, 325-326 TRS 10-18, 393

c.m.c. of, 396 electrophoretic mobility of,

400

xxvii

interfacial tension-of, 400 light scattering measurement

of, 399 osmotic pressure measurement

of, 400-401 TRS 10-80, 677, 756 TRS-16, 912-916 TRS-18, 932 Types of Interaction, 5

Ubiquinone -10, 615 U1tralow Interfacial Tension

and tertiary oil recovery 749-770

factors affecting, 754-769 theories of, 769-770

Ultrasonic Absorption Studies 473-482

Unimo1ecular Reaction micellar effects on, 521-524

Vapor Pressure Osmometry Studies, 457

Water-Dimethyl Sulfoxide Solu­tions study of formation of micelles

of cety1trimethy1ammonium bromide in, 487-494, 497-505