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ACS Midwest Regional Meeting – Final Program

Blake R. Peterson, Program Chair

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WEDNESDAY EVENING

KS Union

Ballroom

Sci-Mix

R. A. Altman, Organizer

6:00 pm - 8:00 pm

Poster Numbers: 66, 103, 200- 202, 206, 215, 226, 228, 231, 238, 240, 246, 248, 253, 256, 263, 270, 280-

283, 286, 289, 369, 377, 387, 395, 396, 454, 457, 466, 469, 473, 474, 501- 503, 505- 507, 510, 522, 525. See

subsequent listings.

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THURSDAY MORNING

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KS Union

Alderson

Analytical Applications of Microfluidics

Cosponsored by ANYL

Financially supported by Center for Molecular Analysis of Disease Pathways, Adams Institute for

Bioanalytical Chemistry

S. M. Lunte, Organizer, Presiding

M. A. Witek, Presiding

8:00 Introductory Remarks.

8:05 1. 3D nanostructuring of microfluidic devices by engineered colloidal self-assembly affords sensitive

immunosensing of exosomal biomarkers. P. Zhang, Y. Shang, M. He, Y. Zeng

8:20 2. Chiral separation of Pacific Blue-labeled amino acids for the detection of biosignatures in

extraterrestrial samples. K.M. Schilly, J. Creamer, M.F. Mora, P.A. Willis

8:35 3. Microfluidic devices for extracting cell-free DNA. C.D. Campos, M.A. Witek, S.A. Soper

8:50 4. Modular approach to microchip-based electrochemical detection using 3-D printing technology. A.S.

Munshi, R.S. Martin

9:05 5. Integrated microfluidics system for the analysis of Circulating Multiple Myeloma Cells (CMMCs)

using Fluorescent in-situ Hybridization (FISH) analysis. K. Weerakoon-Ratnayake, M.L. Hupert, M.A.

Witek, S.A. Soper

9:20 6. Direct integration of microdialysis sampling with microchip electrophoresis separation for

electrochemical detection of small molecule biomarkers in biological samples. S. Gunawarhana

UngawelDurayalage

9:35 Intermission.

9:45 7. Microchip-based approaches for studying nitric oxide release from endothelial cells. A. Townsend,

R.S. Martin

10:00 8. Microfluidic magnetic bead ELISA streamlined with pneumatic valves. Y. Yang, Y. Zeng

10:15 9. A novel detection method for microchip electrophoresis based on bipolar electrochemically

generated fluorescence. M.B. Wijesinghe, D. Gunasekara, S.M. Lunte

10:30 10. Measuring the time-of-flight (ToF) of single molecules using dual beam laser-induced

fluorescence. B. Young

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10:45 11. High-efficiency and rapid separations of biological samples using flow-gated capillary

electrophoresis. M. Gong

11:00 12. Optimization of hylene MP synthesis for production via microfluidics. Z. Peacock, S.M. Torres, T.

Robison

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KS Union

Kansas

Analytical Chemistry

Y. Zeng, Organizer, Presiding

8:00 Introductory Remarks.

8:05 13. Barriers in analytical chemistry: Broken instrumentation, and the modern instrumentation paradigm.

S.D. Abbott

8:20 14. Fabrication of a mixed-scale fluidic device for comprehensive molecular profiling from circulating

markers. B. Gross, V. Singh, J.M. Jackson, S.A. Soper

8:35 15. Electrochemical quantification of length mismatched DNA duplexes: Solution versus surface

hybridization effect. M. Shamsi, M. Taki, H. Palmer

8:50 16. Untargeted identification of polyphenol secondary metabolites in Sambucus nigra (subsp.

canadensis) flower extracts. P.H. Bruner, A.L. Thomas, C.M. Greenlief

9:05 17. Nanoscale electrophoresis separation of deoxynucleotide monophosphates. C. Amarasekara, C.E.

O'Neil, K. Weerakoon-Ratnayake, B. Gross, S.A. Soper

9:20 18. Targeted analysis approach for efficient mapping of full N-glycosylation site profile of highly

glycosylated proteins. M.R. Wijeweera Patabandige, E.P. Go, H.R. Desaire

9:35 19. Block copolymer-derived nanoporous films as platforms for electrochemical DNA sensors based on

a steam-loop probe. Z. Harandizadeh, T. Ito

9:50 Intermission.

10:00 20. Cyanogenic glycosides analysis in American elderberry: picrate paper and LC MS/MS method

development and validation. M.K. Appenteng, R. Krueger, H. Ingold, A.L. Thomas, C.M. Greenlief

10:15 21. A microfluidic IEF chip with scanning fluorescence detection. K. Sellens, A. Anye, C.T.

Culbertson

10:30 22. Single-molecule studies of Nile red incorporated in block copolymer thin films. H. Coceancigh, T.

Ito, D.A. Higgins

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10:45 23. Expediting duplex specific nuclease (DSN) mediated microRNA detection using a microfluidic

circulating device. X. Zhou, Y. Zeng

11:00 24. Diffusional studies of differently-charged molecules in self-assembled organic nanotubes using

imaging fluorescence correlation spectroscopy. G. Ghimire, R. Espinoza, H. Xu, S. Nagasaka, N. Kameta,

M. Masuda, D.A. Higgins, T. Ito

11:15 25. Improving brain delivery of a peptide via BBB (blood brain barrier) modulation and detection using

LC-MS-MS. K.R. Ulapane, T.J. Siahaan, P. Kiptoo, T. Williams

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KS Union

Pine

Biochemistry

H. R. Desaire, Organizer

J. Slusky, Organizer, Presiding

8:00 Introductory Remarks.

8:10 26. Role of fast protein dynamics in thymidylate synthase catalyzed hydride transfer. A.K. Ghosh, A.

Kohen

8:30 27. Improved methods to accurately quantify methionine oxidation in glycoproteins. J.T. Shipman, E.P.

Go, H.R. Desaire

8:50 28. Unraveling ionic liquid-iron porphyrin interactions to understand ionic liquid biodegradation. A.

Banerjee, J. Shah

9:10 Intermission.

9:30 29. Effect of small organic molecules on the assembly of the 20S proteasome core particle. A. Kante,

E.J. Deeds, D. Johnson, J. Karanicolas

9:50 30. Characterizing competitive binding of structurally diverse ligands with OSBP/ORP subfamily-1. J.I.

Nunez, A.T. Le, N.R. Kothapalli, A.W. Burgett

10:10 31. Mechanism study of a peptide diastereomer with anti-cancer activity. J. Yu, A.I. Herrera, T.B.

Shrestha, O. Prakash, D.L. Troyer, S.H. Bossmann

10:30 32. Electrostatic binding of wall teichoic acid re-sensitizes MRSA to oxacillin. M. Foxley, C.V. Rice

10:50 33. Interaction of 2-color multidrug resistance protein-1 biosensor with potential substrates in ensemble

FRET-based assay. B. Osa-Andrews, K.W. Tan, S.H. Iram

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KS Union

Malott

Catalysts and Catalytic Technologies for Fuels, Chemicals, & the Environment

Cosponsored by ENFL

J. J. Bravo-Suarez, Organizer, Presiding

8:00 Introductory Remarks.

8:05 34. Hydrophobization of catalyst surfaces for biomass upgrading reactions in aqueous and biphasic

systems. D. Resasco

8:35 35. Controlling product selectivity in the conversion of 2,3-butanediol to valuable products. K.L. Hohn,

Z. Alauda, Q. Zheng

8:50 36. Water's unique influence on acid site distribution in low Si/Al zeolites. J.L. White, K. Chen, M.

Abdolrahmani, S. Crossley, D. Resasco

9:05 37. Solid acid catalyzed depolymerization of various lignins into value added phenolic monomers. K.Y.

Nandiwale, A.M. Danby, A. Ramanathan, R.V. Chaudhari, B. Subramaniam

9:20 38. Liquid phase propylene epoxidation with Nb based mesoporous silicates. S.K. Maiti, A.

Ramanathan, B. Subramaniam

9:35 Intermission.

9:50 39. Microkinetic detail of ammonia decomposition through Y-procedure analysis of transient

experiments. S. Lwin, L. Wang, R. Kunz, W. Diao, D. Constales, G. Yablonsky, R. Fushimi

10:20 40. Carbon nanotube-supported catalysts prepared by a modified photo-Fenton process for Fischer-

Tropsch synthesis. H. Almkhelfe, X. Li, K.L. Hohn, P.B. Amama

10:35 41. Higher dispersion with increased activity of tungsten in bimetallic mesoporous silicates. A.

Ramanathan, R. Maheswari, H. Zhu, B. Subramaniam

10:50 42. Withdrawn

11:05 43. Synthesis and characterization of biochar-based carbon supported metal nanoparticles. S. Neeli, H.

Ramsurn

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KS Union

Big 12

Chemical Biology of Infectious Disease

Cosponsored by MEDI

T. E. Prisinzano, Organizer, Presiding

8:00 44. Chemical and macromolecular insights into ClpP modulation as an antibacterial strategy. A.S.

Duerfeldt

8:25 Discussion.

8:30 45. From betulinic acid to BMS-955176, a second generation HIV-1 maturation inhibitor. A. Regueiro-

Ren

8:55 Discussion.

9:00 46. Discovery of host-directed therapeutics for the treatment of Gram negative bacterial infections. A.J.

Duplantier, R.G. Panchal

9:25 Discussion.

9:30 47. Antibody recruiting molecules: vetting a new modality. M. Sender, B. Turunen, Y. Chen, C. Wells,

D. Smith, C. Leach

9:55 Discussion.

10:00 48. Development of first-in-class encephalitic alphavirus inhibitors with in vivo efficacy. J.E. Golden

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KS Union

Centennial

Organic & Medicinal Chemistry

R. A. Altman, Organizer

H. Malinakova, Organizer, Presiding

8:00 49. Ni-catalyzed alkene carboacylation of ortho-allylbenzamides. K.L. Vickerman, J.A. Walker, J.N.

Humke, L.M. Stanley

8:20 50. Directed stereoselective transition metal-catalyzed hydroboration and carbocupration of

cyclopropenes. A. Edwards, M.A. Rubin

8:40 51. Formal α-C–H allylation of amines by quinone mediated oxidation / Pd catalyzed allylation. L.M.

Mori Quiroz, M.D. Clift

9:00 52. Photo-induced oxidative decarboxylation-elimination for the synthesis of E/Z-enamides and

enecarbamates. K. Cartwright, S.B. Lang, J.A. Tunge

9:20 53. Anodic cyclization: Pathway control and the construction of a 5,7,5-tricyclic ring system. R. Feng,

R. Perkins, K.D. Moeller

9:40 Intermission.

9:50 54. Base catalysis enables access to α,α-difluoroalkyl(thio)ethers. D. Orsi, B.J. Easley, A.M. Lick, J.P.

Sorrentino, R.A. Altman

10:10 55. Oxidative functionalization of amine-containing molecules through quinone catalysis. X. Liu, B.

Haugeberg, J. Phan, T. O'Connor, S. Londhe, M.D. Clift, M. Leon

10:30 56. Applications of pyridine-oxazoline functionalized metal-organic frameworks for asymmetric

transition-metal catalysis. B.P. Schumacher, T. Goh, W. Huang, L.M. Stanley

10:50 57. Computational study of Lawesson's reagent mediated fluorenone dimerization forming 9,9'-

bifluorenylidene. A.J. Eckelmann, M.R. Siebert

11:10 58. Withdrawn

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KS Union

Jayhawk

Starting Companies in the Biotech Industry

C. Berkland, Organizer, Presiding

8:00 Introductory Remarks by J. Sabol.

8:05 Session Overview by C. Berkland.

8:15 Introduction of Panelists: S.A. Soper, C. Marich, M. Flynn, L. Stehno-Bittel, C. Berkland.

9:05 Intermission.

9:20 Whiteboarding a company, group excercise.

9:50 Panel Discussion.

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KS Union

Woodruff

Theory, Spectroscopy, & Materials

Cosponsored by COLL, INOR and PHYS

C. L. Berrie, J. D. Blakemore, C. G. Elles, C. K. Johnson, B. B. Laird, W. H. Thompson, Organizers,

Presiding

8:00 59. Computer-aided nanomaterial and nanostructure research and design. X.C. Zeng

8:30 60. Single particle tracking: Recent advances in methods and applications. C.F. Landes

9:00 Intermission.

9:15 61. Interfaces large and small: Connecting molecular response to macrscopic phenomena. C.J. Mundy

9:45 62. Harnessing the optical properties of metal nanoparticles for targeted action. A.J. Haes

10:15 Intermission.

10:30 63. Ultrafast electronic and nuclear structural dynamics of excited state transition metal centers for

solar energy conversion. L.X. Chen

11:00 64. Watching proteins dance. C.M. Cheatum

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KS Union

Ballroom

Undergraduate Symposium

Financially supported by Deciphera Pharmaceuticals, LLC

D. A. Vartia, Organizer

8:00 - 10:00

65. ChemisTea: A quantitative chemical analysis of tea. L. Nabulsi, P. Morehouse

66. Synthesis and structure-activity relationship (SAR) of carboxyl-substituted phenylalanine derivatives as

LAT1 substrates. L. Stoner, C. Hernandez, S. Springer, H. Chien, K. Giacomini, C. Colas, A. Schlessinger,

A.A. Thomas

67. Characterization of cinnamic acid derivatives as novel pain medications: Role of adenosine pathway. C.

Capellen, A. Priebe, M. Hunke, M. Pattabiraman, S. Chandra

68. Heart phenotype of an aged mouse model with a targeted deletion causing reduced bone trabecular

volume. D. Warton, J. Vallejo, N. Lara-Castillo, L.A. Wetmore, M. Johnson, M. Wacker

69. Developing new derivatives of 1,8-naphthalimide dyes via Suzuki coupling reaction. M. Xie, T. Ding, H.

Cao

70. Co-crystallization of coumarin derivatives. M. Reinmuth, A. Sinha, C.B. Aakeroy

71. Concentrate electrophoretically eluted DNA molecules in 3D printed devices. A. Mashmann, J. Dolphin,

K. Kounovsky-Shafer

72. Synthesis of a novel flavonoid dimer as a potential antibiotic. A. Millhuff, J.A. Morrill

73. Quantitative analysis of CdSe/ZnS quantum dots by x-ray fluorescence. H.E. Maunders, A.J. Runia, A.L.

Tietz, D.E. Weisshaar

74. Role of α5β1 integrin and Met in triple negative breast cancer metastasis. J. Soukup, S. Van slambrouck

75. Optimizing the hydrogenolysis of 4-L-phenylspinacine. D.D. Smith, A. Ghajarieh, M.R. Hulce

76. Synthesis of α-quaternary amino acids as potential LAT1 substrates. B. Venteicher, C. Hall, J. Campbell,

C. Hernandez, K. Giacomini, H. Chien, C. Colas, A. Schlessinger, A.A. Thomas

77. Biophysical characterization of Burkholderia type III secretion system minor translocon protein BipC. M.

Wilkinson, S. Dey, S. Yadava, R. De Guzman

78. Synthesis and evaluation of substituted-biaryl isothiocyanates. C.C. Fanta, K.J. Tlusty, A.L. Johnson,

J.R. Mays

79. Studying the binding interactions of alachlor and alachlor ESA using high performance affinity

chromatography. S. Trenhaile, A. Moser

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80. Nanomaterial-based supports for ultra-thin layer chromatography and ellipsometry. E. Johnson, S.

Beeram, E.L. Rodriguez, D. Peev, A. Nguyen, D.S. Hage, M. Schubert

81. Role of nonpolar interactions in the recognition of highly polar histone peptides. F. Poppinga, D.

Boamah, T. Lin, S. Basu, S. Chakravarty

82. SBAP-linked bioconjugation of oligonucleotides to quantum dots. B. Eichler, T. Hollinsworth, A.

Kroeger

83. How halogens on azo-dyes effect solvatochromism. P. Riegsecker, D.J. Peitz, P.A. Karr

84. Virtual screening of potential inhibitors of APOBEC3B: A promising cancer drug target. Z.D. Smith,

E.M. Leddin, B. Miller

85. Delivery of a peptide with anti-cancer activity using mesoporous silica nanoparticles. D. Hassen, J. Yu,

T.B. Shrestha, H. Wang, D.L. Troyer, S.H. Bossmann

86. Determination of electroendosmosis and electrophoresis in gel matrices for 3D printed devices. J.

Lallman, R. Flaugh, M. Kohlbek, K. Kounovsky-Shafer

87. Synthesis of analogues of Calcofluor White as antifungal agents. N. Love, D. Rane, B.R. Peterson

88. Preparation of Boc-His(Bn)(Boc)-OH as its tert-butylamine salt. D.D. Smith, J. Nguyen, M.R. Hulce

89. Identifying the binding location of atrazine and two of its metabolites on HSA using high performance

affinity chromatography. K. Frankenberg, A. Moser

90. Optimization of disulfide bond reduction for use in point-of-care microfluidic based devices with

applications in early cancer diagnosis. S. Cook, J. Sibbitts, C.T. Culbertson

91. Generation of benzyl isothiocyanate via photolysis of an ortho-nitrobenzyl-protected analogue. C.W.

Lang, E. Voigt, E.H. Pauley, J.R. Mays

92. Computational investigation of tryptophan dimer biosynthesis. J. Lundervold, J.A. Morrill

93. Phenylalanine derivatives containing polar substituents as LAT1 substrates for use in drug delivery. L.

Stoner, K. Finke, A. Anthony, J. Bauer, A. Flint, H. Chien, K. Giacomini, C. Colas, A. Schlessinger, A.A.

Thomas

94. Investigation of cybrid SH-SY5Y neuroblastoma cells as a model for mitochondrial contribution to cell

death in Alzheimer’s disease. A. Brake, L.A. Wetmore

95. Development of microchip electrophoresis based separation sensor for analysis of catecholamine

neurotransmitters in zebrafish brains. S. Schoneich, S. Gunawarhana UngawelDurayalage, S.M. Lunte

96. Direct amide coupling to carboxylic acids using microwave techniques. M. Brewer, G.P. Nora

97. Stability of BODIPYs towards trifluoroacetic acid: An experimental and computational study into the role

of the substituents at boron. D. Mason, M. Wang, M.H. Vicente, P.N. Bobadova-Parvanova

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98. Construction of a genetic device to investigate bacterial DNA replication. S. Anderson, L. Rahn-Lee,

L.A. Wetmore

99. Computational study of (2 + 4) retro-cycloadditions of conjugated planar disilenes. P.P. Gaspar, A. Seim

100. In silico drug design of heterocyclic cucurbitacin- inspired estrone analogs targeting EGFR in lung

cancer. T. Ostlund, F.T. Halaweish, K. Alseud

101. Synthesis and characterization of a DFDPP-CPDT polymer with ethynyl spacers by means of

Sonogashira coupling. H.P. Masching, C. Benson, J.L. Duffy-Matzner

102. Computational investigation of biflavonoid inhibitors of amyloid beta aggregation in Alzheimer's

Disease. S. Plassmeyer, P. Windsor, D. Mattock, B. Miller, B.H. Han

103. Using azide appended 2,3-naphthalimde as an approach for detection of H2S. A. Ahmad, H. Cao

104. Novel ethynyl-halo-hydroxyisoxazolines synthesis and investigation as potential antimicrobial agents.

K.G. Stevens, C. Jensen, J.L. Duffy-Matzner

105. Synthesis of water soluble rylene derivatives for sensor applications. E.C. Olson, C.H. Battle

106. Detection and quantification of N-acyl-L-homoserine lactones from Vibrio Harveyi culture. M.R. Wood,

T. Vasicek, K. Alkhatib, A. Diaz-Perez, P. Pysz, J.A. Stenken

107. In silico drug design of Curcurbitacins Inspired Estrone Analogs (CIEA) targeting Small Cell Lung

Carcinoma (SCLC). Z. Khan, F.T. Halaweish

108. Determination of lambda DNA concentration in 3D printed devices. C. Masters, J. Dolphin, A.

Maschmann, K. Kounovsky-Shafer

109. Thiol modulation: Activity profiling of sulfur containing covalent modifiers and known drugs. C. Clay,

J. Jun, S. Iqbal, P.R. Hanson

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KS Union

Ballroom

Undergraduate Symposium

Financially supported by Deciphera Pharmaceuticals, LLC

D. A. Vartia, Organizer

10:10 - 12:10

110. Catalytic activity of bis(2-pyridylmethyl)amine complexes containing coupled pendant arms in ATRA

reactions. J.M. Peterson, K.D. Oshin

111. Computational studies on the electrochemical reduction of CO2 on CuxNiy (x = 0-4; y = 4-x) clusters. T.

Creason, A.Z. Clayborne

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112. Development of a microbial transformations research project for the organic chemistry laboratory

curriculum. A. Cribb, C. Hillebrand, J.L. Torres Y Torres

113. Structural and functional characterization of a Yersinia pestis opine dehydrogenase involved in

metallophore biosynthesis. C.L. Davis, A.L. Lamb, J.S. McFarlane

114. Computational investigation of the aggregation of asphaltenes with various solvents and aggregation

inhibitors. B. Lawson, K.L. Humphries, J.D. Bickel, B. Miller

115. Utilizing tris(2-pyridylmethyl)proazaphosphatrane complexes as catalysts in ATRA reactions. K.L.

Sandquist, K.D. Oshin

116. Probing electron delocalization in low-valent organometallic platforms featuring the isocyanide junction

unit via a new 13C NMR approach. Z.A. Wood, M.D. Hart, M.V. Barybin

117. Synthesis, characterization, and catalytic activity of hollow Mn3O4 nanoparticles for cyclohexene

oxidation. C.M. Karki, J.D. Hoefelmeyer

118. Isolation of trace impurities in Antarctic ice for the purpose of analyzing "Old Faithful". L. Dirks, J.

Cole-Dai, K.M. Peterson

119. Selenium sorption to hematite at elevated temperature. J. Dunn-Wall, C. Freemyer, A. Miller

120. Fluorescent detection of the post-translational modification of PvdJ module 2 in Pseudomonas

aeruginosa. K. Brewer, T.A. Ronnebaum, A. Chilton, A.L. Lamb

121. Photon detection for precision laser spectroscopy. C. Kujawa, S. Pineda, A. Klose

122. Non-resonant two-photon excitation of phototriggers. E. Lorenzo, S. Senadheera, A.L. Houk, R.S.

Givens, C.G. Elles

123. Manipulation of femtosecond laser processed aluminum-1100 surface wetting behavior via coating by

silanes with long-chain alkyl or fluoroalkyl substituents. A. Tanbouza-Husseini, K.R. Everitt, S.A. Darveau,

C.L. Exstrom

124. Calculating activation rate constant values (kact) in ATRA reactions utilizing modified tris(2-

pyridylmethyl)amine (TPMA) based complexes. I.J. Bazley, K.D. Oshin

125. Chemobrain in zebrafish: Neurochemical assessments and evaluation of potential therapeutic treatments.

J. Loomis, T. Field, C. Stucky, M. Shin, M.A. Johnson

126. Investigating peptide selectivity and affinity to metal ions: Developing qualitative assays of peptide-

metal ion interactions using metal ion dependent dyes and cellulose membranes. M. Guile, C. Obinwa, K.

Yoshimatsu

127. Computational analysis of the anti-cancer drug cisplatin with the Thermus thermophilus ribosome. J.D.

Bickel, B. Miller

128. Mechanism elucidation of gold-catalyzed three-component reactions forming furans. M.J. Bakker, M.R.

Siebert

13

129. Isolation and characterization of a manganese(III) intermediate. E.G. Stewart-Jones

130. Enhancement of the hydrogen atom abstraction ability of [MnIII(OH)(dpaq)]+ by the addition of a redox

inactive Lewis acid. A.M. Donovan, D. Rice, T.A. Jackson

131. Detection of anti-staphylococcal activity by utilizing copper-dependent inhibitors with an extended

thiourea group. F. Rahman, A.P. Malalasekera, A. Delpe Acharige, M. Kalubowilage, A.G. Dalecki, K.R.

Schaaf, O. Kutsch, F. Wolschendorf, S.H. Bossmann

132. Cobalt(II) metal ion complexes of tapa with exogenous anionic ligands bound in the H-Bonding pocket.

N. Stumme, N. Sedore, K. Chabal, C. Milius, A. Ellern, D. Swenson, M. Zart

133. Effects of acid catalysts on the preparation of ambient-dried titania aerogels. L.M. Hansen, S.A.

Darveau, C.L. Exstrom

134. Syntheses and crystal structures of lanthanide dithiooxamide complexes. A. Bohanon, E.M. Villa

135. Removal of alkaline earth metals from produced brine using poly-acrylic acid. E. Albertson, K. Shafer-

Peltier, S. Randtke, E.F. Peltier

136. Photochromic switching in the plasmonic field of gold nanoparticles. W. Harmon, C.J. Otolski, C.G.

Elles

137. Investigating the use of CYCLAM derivatives as catalysts for ATRA reactions. C.J. LeWarne, K.D.

Oshin

138. Exploring actinide chemistry in environmentally relevant systems: Th(IV), U(VI), & Np(IV,V,VI)

bound by macrocyclic ligands. A. Blanes, E. Cole, M.C. Basile, T. Forbes

139. Tuning the reactivity of Mn(III)-hydroxo model complexes via ligand substitution. A.D. Burr, G.B.

Wijeratne, T.A. Jackson

140. Reaction dynamics of the TeMo6O246- ion in water. G. Kuhl, E.M. Villa

141. Supercell crystal structure of Na2Ga2(BO3)2O. G. Brown, R. Smith

142. Facile one-pot synthesis of WSe2 nanoparticles from the reaction between diphenyl diselenide and

tungsten hexacarbonyl. J.R. Blum, W.M. Colling, S.A. Darveau, C.L. Exstrom

143. An investigation of biaxial and uniaxial strain-induced effects in smectic and nematic liquid crystals. K.

Kurtenbach, M. Sadati

144. Effects of surface capping and pH on seeded growth. M.M. Scanlan, A.N. Chen, S.E. Skrabalak

145. Role of transition metal linkers in germanium cluster assemblies. D.D. Nguyen, A. Schnepf, A.Z.

Clayborne

146. Fabrication of WSe2 thin films via a mild-temperature selenization of chemical bath-deposited tungsten

oxide. M.E. Falconer, S.A. Darveau, C.L. Exstrom

14

147. Rotational analysis of the β 2Δi – X 2Πi transition of CuO using Intracavity Laser Spectroscopy (ILS). J.

Harms, T. Nair, R. Russell, L.C. O'Brien, J.J. O'Brien

148. Syntheses and crystal structures of lanthanide periodate compounds. R. Colin, E.M. Villa

149. Calibration of dye laser using laser absorption spectroscopy of iodine. S. Pineda, C. Kujawa

150. Effects of silica aerogel embedment on the wetting properties of femtosecond laser processed aluminum

1100 surfaces. K.R. Everitt, A. Tanbouza-Husseini, S.A. Darveau, C.L. Exstrom, E. Peng, J.E. Shield, G.

Gogos, R. Bell, C.A. Zuhlke, D.R. Alexander

151. Characterization of dentin slices and monitoring their remineralization by AFM-IR and nano-

indentation. A. VanLaecken, G. Sereda, J. Turner

152. Uniquely engineered doxorubicin-based pH responsive polymeric drug delivery device against breast

cancer. C. Crane, T. Nguyen, C. Ferrel, S. Aryal

153. Chemistry of tungsten-selenium nanocrystalline product formation from a mild-temperature reaction

between tungsten hexacarbonyl and selenium. W.M. Colling, J.R. Blum, S.A. Darveau, C.L. Exstrom

154. Characterization of metal-doped amorphous silica clusters via DFT simulations of py-FTIR. H. Leblanc,

A. Jystad, M. Caricato

155. Examination of the effect of different mole ratios of internally mixed sodium chloride-alanine aerosols

on their hygroscopic properties. M. Alfarra, D. Woods, S. Gottuso, J.P. Darr

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15

THURSDAY AFTERNOON

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KS Union

Malott

Catalysts and Catalytic Technologies for Fuels, Chemicals, & the Environment

Cosponsored by ENFL

J. J. Bravo-Suarez, Organizer, Presiding

12:30 Introductory Remarks.

12:35 156. Molecular and microkinetic modeling in catalysis. L. Arnadottir

1:05 157. Density functional theory and kinetic modeling for rational catalyst design. B. Liu, M. Zhou

1:20 158. Theoretical characterization of metal-doped amorphous silicates. A. Jystad, H. Leblanc, A.

Biancardi, M. Caricato

1:35 159. Using density functional theory calculations to determine Brønsted site acidity in zeolite. M. Zeets,

B. Wang

1:50 160. Investigation acidity inside pores of SBA 15 via single molecule spectroscopy. J. Xie, J. Xu, H.

Wang, K.L. Hohn

2:05 Intermission.

2:20 161. Catalysis for sustainable chemistry: Process development and catalyst characterization. A. Allgeier

2:50 162. Vapor phase ring rearrangement of furanic species over TiO2 supported catalysts. L.V. Herrera, S.

Crossley

3:05 163. Facet effect of ceria nanostructures on catalytic generation of hydroxyl radicals. T.J. Fisher, C.L.

Cheung, N. Shao, W. Mei, R. Sabirianov, N. Al-Aqtash, K. Tarawneh

3:20 164. Nanostructured electrocatalysts for hydrogen and oxygen evolution reactions. R. Gupta

3:35 165. New process to synthesize Rh2S3 precursor for RhxSy catalyst by Na2S and pretreated carbon for

HER/HOR in HBr solution. Y. Li, T.V. Nguyen

==================================================================

16

KS Union

Alderson

From Molecules to Nanomaterials: Applications in Energy & Catalysis

Cosponsored by COLL and INOR

C. L. Berrie, J. D. Blakemore, Organizers, Presiding

12:30 166. Artificial photosynthesis: Light capture, charge separation, and fuel production. G. Mohandass, Y.

Jang, M. Kincaid, C. Obondi, S. Yellappa, F. D'Souza

1:00 167. Effects of an unconjugated bipyridine ligand on H2 evolution with organometallic rhodium

complexes. D. Lionetti, V.W. Day, J.D. Blakemore

1:20 168. Vertically aligned carbon nanofibers with ultra-low platinum loading for oxygen reduction reaction.

A. Elangovan, J. Li

1:40 Intermission.

1:50 169. Bubble residence during water splitting reactions at structured semiconductor-electrocatalyst

interfaces. R. Coridan

2:20 170. Multifunctional metal-organic framework materials for applications in asymmetric catalysis. T.

Gadzikwa, K.P. Samarakoon, C.S. Satterfield

2:40 171. Supramolecular chemistry of phytate, myo-inositol hexakisphosphate. E. Haque, V.W. Day, K.

Bowman-James

3:00 172. Local hybrid perovskite photophysics. M.K. Kuno

==================================================================

KS Union

Big 12

Midwest ACS Graduate Awards Symposium

Financially supported by Wakarusa Valley ACS Local Section

M. A. Witek, Organizer, Presiding

12:30 Introductory Remarks & the Award Ceremony.

12:40 173. Beyond the diffraction limit: Super high resolution using microlens based nanoscopy. R.

Balaraman, J. Sharma, A. Pond, C. Zhou, P. Kohli

1:00 174. Shape memory superelastic poly(isocyanurate-urethane) aerogels (PIR-PUR) for deployable panels

and biomimetic applications. S. Donthula, C. Mandal, T. Leventis, J. Schisler, M. Adnan Saeed, C. Sotiriou-

Leventis, N. Leventis

17

1:20 175. First symmetric π-conjugated molecular linker asymmetrically anchored with isocyanide and

thiolate junctions. J. Applegate, N.R. Erickson, N. Gerasimchuk, M.V. Barybin

1:40 176. Design and synthesis of a series of bidentate ligands for coordinating with Re (I) and Ru (II) metal

centers as dyes for harvesting sunlight. V. KomReddy, D.P. Rillema

2:00 Intermission.

2:10 177. Mechanistic study of dye-decolorizing peroxidase from Enterobacter lignolyticus using kinetic

isotope and viscosity effects. R. Shrestha, G. Huang, D.A. Meekins, B.V. Geisbrecht, P. Li

2:30 178. Characterization of LiZnP nanoparticles by advanced solid-state NMR spectroscopy. A.

Venkatesh, M.A. White, J. Vela , A.J. Rossini

2:50 179. Synthesis and biological activity of siderophores from human pathogenic A. baumannii. T. Bohac,

J.A. Shapiro, T.A. Wencewicz

3:10 180. Withdrawn

==================================================================

KS Union

Centennial

Organic & Medicinal Chemistry

R. A. Altman, H. Malinakova, Organizers

J. D. Weaver, Presiding

12:30 181. Stereoselective syntheses of allenols and alkenols by 1,2-, 1,4- double hydride reductions of 3-

alkynyl- and 3-alkenyl-2-cycloalkenones. M.R. Hulce, B.L. Callahan

12:50 182. Synthesis and evaluation of oxygen analogues of a promising anticancer drug. R.A. Bunce

1:10 183. Iterative photocatalytic C—H functionalization: Rapid and programmable access to oligioarenes.

A. Arora, J.D. Weaver

1:30 184. Extension of the cavitand-mediation photocycloaddition approach: Interplay of weak interactions

on the 2+2 photocycloaddition of substituted cinnamic acids. M. Pattabiraman, T. Bokoskie, N. Vuong, A.

Kashyap

1:50 Intermission.

2:05 185. Ring-degenerate rearrangements of 1-substituted-4-imino-1,2,3-triazoles. J. Christensen, M.D.

Hanson, R.K. Zawistowski, J.T. Fletcher

2:25 186. Fluorescent logic gates as multi-input chemical sensors for neuronal imaging. L. Zhang, K.S.

Hettie, J.L. Klockow, C. Yin, T.E. Glass

2:45 187. Withdrawn

18

==================================================================

KS Union

Kansas

Spectroscopy Applied to Structure, Dynamics, & Imaging

Cosponsored by PHYS

C. G. Elles, C. K. Johnson, Organizers, Presiding

12:30 188. Surface plasmon coupled emission Raman spectroscopy measurements of the chemical

composition and thickness of thin films. E.A. Smith, C. Nyamekye, S. Weibel, J.M. Bobbitt

1:00 189. Extended photoluminescence lifetimes in optically enhanced CdTe/CdS QWs. W.M. Sanderson,

F. Wang, W.E. Buhro, R.A. Loomis

1:20 190. Charge transfer exciton and spin flipping at organic-TMD interfaces. T.R. Kafle, B. Kattel, T.

Wang, W. Chan

1:40 191. Temperature effect on bulk and thin film ionic liquids examined using vibrational spectroscopy and

calorimetry. J. Wrona, S.K. Shaw

2:00 Intermission.

2:20 192. Towards super-resolution ultrafast Raman imaging. R.R. Frontiera

2:50 193. Assignment of excited-state vibrational spectra from resonance-enhanced femtosecond stimulated

Raman scattering: Combining experiment and theory. M.S. Barclay, T.J. Quincy, C.G. Elles, M. Caricato

3:10 194. Probing higher-lying electronic states via mode-specific enhancement of excited-state resonance

Raman spectra. T. Quincy, M. Barclay, M. Caricato, C.G. Elles

==================================================================

KS Union

Jayhawk

Theory of Interfaces

B. B. Laird, W. H. Thompson, Organizers

K. R. Mitchell-Koch, Presiding

12:30 195. Rich phase behavior of confined water: Nano ice, nano bubble, low-density and high-density

liquid water. X.C. Zeng

1:10 196. Morphometric thermodynamics in 2D: Comparing theory to simulation. S. Martin, B.B. Laird

1:30 Intermission.

19

1:50 197. The role of substrate structure on heterogeneous nucleation. J.P. Palafox - Hernandez, B.B. Laird

2:30 198. Structure of the Al-Ga solid-liquid interface. P.R. Barry, J. Kern, B.B. Laird

2:50 199. Understanding the wetting behavior of octane-water-silica systems using Monte Carlo simulation.

W. Guo, J. Errington

==================================================================

KS Union

Ballroom

Organic & Medicinal Chemistry

R. A. Altman, H. Malinakova, Organizers

1:00 - 3:00

200. Synthetic lethal targeting of growth factor receptors. K. Knewtson, C. Perera, M.M. Lee, D. Hymel,

B.R. Peterson

201. New approach to disable resistance in MRSA. C.V. Rice, M. Foxley, S.N. Wright, A.K. Lam

202. Magnetic resonance characterization of peritoneal mesothelioma, psuedomyxoma peritonei and cirrhosis

ascites. M.R. Hulce, B.W. Loggie, G.K. Sirineni, P. Thomas

203. Synthesis and characterization of Chitosan derivatives for high performance gene delivery. Q. Wyatt,

A.M. McMullen, L. Kwok, R.S. Herati

204. Synthesis of functionalized bile acid macrocycles towards the construction of steroid-based molecular

cages. C.A. Knudtson, J.R. Dias

205. Cell permeable dibenzothiophene based fluorescent dye and O(3P) generators. J.T. Petroff, R.D.

McCulla

206. Multi-antigen I-domain conjugates against antigenic spreading in animal models for multiple sclerosis.

M.G. Moral, P. Kiptoo, T.J. Siahaan

207. Synthesis of small molecules to understand the mechanism of methylation of 2’-deoxyuridine-5’-

monophosphate byin flavin-dependent thymidylate synthase. D. Mondal, J. Yao, A. Kohen

208. Restoring susceptibility to methicillin-resistant Staphylococcus epidermidis. A.K. Lam, M. Foxley, C.V.

Rice

209. Conjugate addition of N-acetylcysteine to bisphenol A-3,4-quinone. D.E. Stack, B. Mahmud

210. Concept of copper-activatable drugs. T. Shrestha, A. Delpe Acharige, M. Kalubowilage, F.

Wolschendorf, S.H. Bossmann

20

211. Diastereoselective 7-exo-trig nucleophilic cycloaddition of tethered alkoxides to cyclopropenes en route

to homochiral medium ring scaffold with anti-mycobacterial activity. V. Maslivetc, A. Philippova, M.

Rubina, M.A. Rubin

212. Synthesis and efficacy evaluation of naphthalimide intercalating agents. R. Oelrich, M. Schneider, Y.

Salha, M.A. Lewis

213. Design and synthesis of novel OSW-1 scaffolds as precision cancer therapeutic agents. C.A. Malinky,

A.T. Le, S. Sakers, G. Nguyen, G. Manginelli, A.W. Burgett

214. Synthesis of five-membered SHetA2 Flex-Het analogues for preventing human ovarian cancer. D.

Bryant, D. Berlin, R.A. Bunce

215. Applications of the radical-polar crossover reaction to medicinal chemistry. S. Cullen, G.K. Friestad

216. Modular total synthesis of salvinorin A inspired designer opioids. A. Sherwood, S. Williamson, R.

Crowley, T.E. Prisinzano

217. Design, synthesis and biological study of hybrid drug candidates of nitric oxide releasing cucurbitacin-

inspired estrone analogs for treatment of hepatocellular carcinoma. M.A. Abousalim, M.A. Shaaban, M.K.

Abd El Hamid, Y.A. Elshaier, M.H. Abdelrahman, F.T. Halaweish

218. Design, synthesis and characterization of 1-(2-((4-(4-methoxyphenyl)-2,2-dimethyl-3-phenylchroman-7-

yl)oxy)ethyl)pyrrolidine (JAK15) analogs for treatment of ovarian cancer. J. Apraku, C.C. Subhash, F.T.

Halaweish

219. Development of novel electrophilic probes for chemical biology: Synthesis and reactivity profiling

studies using 19F NMR. J. Jun, A. Cassity, J.S. Jha, C. Clay, P.R. Hanson

220. Modular synthesis and reactivity profiling studies of diverse and stereochemically enriched C-, S-, and

P-based electrophilic macrocycles. G.C. Dissanayake, S. Javed, D. Vithanage, A. Ganguly, P.R. Hanson

221. Novel tetramic acid analogs: Synthesis and reactivity profiling of cysteine-reactive β-keto-vinyl sultams.

J.S. Jha, J. Jun, P.R. Hanson

222. Design, synthesis and reactivity profiling of cysteine-reactive electrophilic acyl sultams. S. Iqbal, M.A.

Khan, Q. Zang, C. Clay, E. Gao, J. Loh, N. Asad, P.R. Hanson

223. Study of epimetalated intermediates towards functional group transformations of pi-bonded organic

compounds. J. Gitua

224. Synthesis of vinyl cyclopropanes via anion relay cyclization. K.M. Allegre, N. Brennan, J.A. Tunge

225. Radical [1,3] rearrangements of Breslow intermediates. H. Wallace

226. Stereospecific decarboxylative benzylation of enolates: Scope, application, and mechanistic insights. T.

Li, M.L. Maliszewski, J.A. Tunge

227. Mechanism for the formation of benzo[e]-1,3-oxazin-4-ones from reactions of salicylic acids and

anilines with HATU. D. Leas, J. Wu, Y. Dong, J.L. Vennerstrom

21

228. Benzo[b]naphtho[2,1-d]selenophene-Se-oxide, Benzo[b]naphtho[1,2-d]selenophene-Se-oxide as

potential triplet atomic oxygen precursors. S.M. Chintala, R.D. McCulla

229. Synthesis of 5-amino-2-sulfonamdio-thiazole-4-carboxylic acids using microwave techniques. G.P.

Nora

230. Directed nucleophilic addition of phenoxides to cyclopropenes. P. Yamanushkin, M. Lu-Diaz, A.

Edwards, M. Rubina, M.A. Rubin

231. Developing methods for diversifying molecular scaffolds directly on a microelectrode array. K.D.

Moeller, N. Yeh

232. Study on the compatibility of manganese-mediated radical addition reaction with aromatic heterocycles.

M. Li, L. Goff, G.K. Friestad

233. Scope of the electrophilic groups for cyclization in the type-II Mn-mediated radical-polar crossover

annulation. R.L. Hein, G.K. Friestad

234. Novel triazole-containing tricyclic sultams: Intramolecular C–H functionalization of triazoles to generate

a small molecule library. V.U. Thomas, M.A. Khan, Q. Zang, E. Gao, P.R. Hanson

235. An efficient synthesis of P-sterogenic mono-, bi- and tricyclic P-heterocycles via one-pot sequential

enyne ring-closing metathesis/Diels-Alder protocol. D.A. Vithanage, S. Javed, A. Ganguly, G.C.

Dissanayake, P.R. Hanson

236. Diastereoselective six- and seven-membered ring closure via intramolecular nucleophilic attack by

nitrogen ylides on C=C bond of cyclopropenes. V. Maslivetc, A. Maslivetc, M. Rubina, M.A. Rubin

237. Exploring reactivityof N-heterocyclic carbenes (NHCs). H. Palencia, I. Monreal-Leyva, L. Berdugo

238. Synthesis of oxacycles via reaction of stabilized carbanions with peroxides. A. Horn, P.H. Dussault

239. Efficient synthesis of substituted 1H-indazoles. J. Annor-Gyamfi, R.A. Bunce

240. Practical and scalable total syntheses of complex benzannulated indole natural products via indole aryne

cycloaddition methodologies. Total synthesis of the trikentrins and herbindoles. Z. Albader, M. Rayhart, O.

Talavera, K.R. Buszek

241. Synthesis, characterization, and catalytic activity of chiral covalent organic frameworks. A. Volkov,

L.M. Stanley

242. Synthesis and biological screening of cucurbitacin-inspired estrone analogues targeting JAK/STAT3

pathway in pancreatic cancer. K. Alseud, F.T. Halaweish

243. Intramolecular C-H functionalization via C-vinylation: Synthesis of structurally unique triazole-fused

vinyl sultams. A. Cassity, J. Jun, N.M. Windmon, N. Asad, A. Diepenbrock, P.R. Hanson, K. Jeon

==================================================================

22

KS Union

Woodruff

Midwest Plenary Symposium

Financially supported by St. Louis Local Section

J. A. Heppert, Organizer

T. E. Prisinzano, Presiding

3:45 244. Can ionic liquids be disruptive enough to save the world? R.D. Rogers

4:35 Intermission.

4:40 245. From molecular dating to functional materials. C.B. Aakeroy

==================================================================

23

FRIDAY MORNING

==================================================================

KS Union

Ballroom

Biochemistry

H. R. Desaire, J. Slusky, Organizers

8:00 - 10:00

246. Perturbing the BfrB:Bfd interaction of Pseudomonas aeruginosa by chemical and genetic intervention

causes irreversible accumulation of iron in BfrB. A. Punchi Hewage, H. Yao, B. Nammalwar, K.K.

Gnanasekaran, S. Lovell, R.A. Bunce, J. Chandler, M.E. Rivera

247. Determination of the interaction of the transmembrane helices of IpaB in micelles by EPR Spectroscopy.

A. Chakravarty, R. N De Guzman

248. Identification of novel inhibitors of multidrug resistance protein 1 (MRP1). A. Sampson, K.W. Tan,

B.G. Peterson, S.H. Iram

249. Dynamic ligand-dependent FRET changes of 2-color Multidrug resistance protein-1 biosensor. B. Osa-

Andrews, K.W. Tan, S.H. Iram

250. Cellular effects of ligand binding to the oxysterol-binding protein family (OSBP/ORP4). B. Roberts,

Z.C. Severance, R. Bensen, N.R. Kothapalli, J.I. Nunez, M. Hongyan, S. Wu, A.W. Burgett

251. Neuroprotective properties of Ascorbic Acid against N-substituted derivative of Parkinsonian toxin 1-

methyl-4-phenylpyridinium (MPP+). B. Lickteig, D. Murphy

252. Solving the MSTery: Determining the Chemical Mechanism of Lyase Activity. C. Shelton

253. Interactions between the CS and cytochrome b5 reductase domains of human Ncb5or revealed by X-ray

crystallography. D.R. Benson, S. Lovell, N. Mehzabeen, K.P. Battaile, H. Zhu

254. Effects of macromolecular crowding and lipid composition on CYP2J2 stability and substrate

metabolism. H. Huff, A. Das

255. Pa-Bfd (Pseudomonas aeruginosa-bacterioferritin associated ferredoxin) fold is stabilized by a

phosphate ion. H.N. Wijerathne, H. Yao, S. Lovell, M.E. Rivera

256. Biosynthesis of opine metallophores by bacterial pathogens. J.S. McFarlane, C.L. Davis, A.L. Lamb

257. Importance of the C-terminus of ALDH7A1 for catalytic activity and oligomerization. J.W. Wyatt,

D.A. Korasick, A.R. Laciak, K.S. Gates, J. Tanner

258. Cloning of a periplasmic serine endoprotease of Escherichia coli. N. Mikita

24

259. PvdF as potential novel transformylase from Pseudomonas aeruginosa. N. Kenjic, A.L. Lamb

260. EPR reveals different conformations of Yersinia LcrG and Pseudomonas PcrG proteins. P. Guha

Biswas, P. Kaur, K. Kaur, A. McShan, S. Tachiyama, L. Song, R. De Guzman

261. 3D reconstruction of tetanus neurotoxin using negative stain electron microscopy and electron

tomography. P. ONeil, A. Machen, M.T. Fisher

262. Mutagenesis study on bio-orthogonal protein-peptide isopeptide bond forming systems. S.P. Kasson, K.

Yoshimatsu

263. Withdrawn

264. Study of anti-proliferative activity of cucurbitacins inspired esterione analogs on hepatocellular

carcinoma. S. Elgazwi, F.T. Halaweish, M. Mahnashi

265. Investigation on innate and adaptive immune response of Macrophage. S. Jo

266. G-quadruplex driven self-assembly of DNA origami dimer. S. Yang, W. Liu, R. Wang

267. Small molecules binding to Shigella Type III Secretion System (T3SS) tip protein IpaD. S. Dey, A.

Anbanandam, B. Mumford, R. De Guzman

268. 2-alkyl-4-quinolones of Pseudomonas aeruginosa as iron chelators in bacterial iron homeostasis. T.

Pahattuge, T. Williams, J. Chandler, M.E. Rivera

269. Investigating “stuffed” domains of NRPS assembly lines: PchF and PchE of pyochelin biosynthesis.

T.A. Ronnebaum, G.P. Horsman, S.J. Booker, T.E. Prisinzano, A.L. Lamb

270. Myopalladin’s role in cardiac muscle function and disease. V.K. Kadarla, M. Beck, M.L. Bang

271. Synthesis of (5-oxo-2-dibenzothienylmethyl)triphenylphosphonium and its localization in mitochondria

to study oxidative stress. A. Isor, R.D. McCulla

272. Towards synthetic cell surface receptors that control signal transduction. Y. Yin, C. Perera, D. Hymel,

B.R. Peterson

273. Synthetic mimics of cytochrome b5 as cell surface receptors. A. Andres, B.R. Peterson

==================================================================

25

KS Union

Big 12

Chemical Biology of Microbial Processes

M. E. Rivera, Organizer

A. L. Lamb, Presiding

8:00 274. Chemical biology of bacterial nanoinjectors. R. De Guzman

8:35 275. Functional models of chromosomal ParDE toxin-antitoxin systems. C. Bourne

9:10 276. Using biolayer interferometry to assess the kinetic stability of bacterial toxins for accelerated drug

discovery. M.T. Fisher

9:45 Intermission.

10:05 277. Iron-clad strategies of microbial growth: chemical biology of siderophores. A. Butler, Z. Reitz, G.

Maier, K. Dulaney

10:40 278. Developing microdialysis sampling as an in situ analysis tool for quorum sensing from biofilms.

J.A. Stenken

11:15 279. Copper-activated drugs to maximize the effects of nutritional immunity. S.H. Bossmann, F.

Wolschendorf

==================================================================

KS Union

Ballroom

Chemical Education

J. E. Headrick, Organizer

8:00 - 10:00

280. Developing teaching modules that incorporate next generation science standards in the secondary

science curriculum. N. Jackson, B.D. Hidaka, C.G. Elles

281. Addressing retention of general chemistry students via a new supplemental problem solving course:

CHE 198 at Missouri Western State University. S.L. Hiley, M.W. Ducey, D. Stasko

282. Withdrawn

283. VIVED Chemistry, a new interactive, educational, 3D platform for educators and students to enhance

learning chemistry. A.M. Cannon, J. Kersten, W. Baltz, Y.A. Letuchy, A. Patrick

284. Student produced videos for teaching. J.C. Easdon

26

285. Instrumental analysis project that teaches aspects of liquid chromatography. J. Hahn, D.W. Harak

286. Electrocatalysis projects for the undergraduate instrumental analysis laboratory. T.P. Ratz, D.W. Harak

287. Drafting and using a novel standard exam to measure how students apply chemistry to biology. D.

Morrone

288. Safety considerations when designing a new chemical engineering research laboratory. W.J. Gilbert, M.

Shiflett

289. ACS Division of Small Chemical Businesses (SCHB): Opportunities and benefits. J.E. Sabol

290. Calculation of wavefunctions made easy. J.R. Dias

==================================================================

KS Union

English

Chemical Education

J. E. Headrick, Organizer

A. A. Vartia, Presiding

8:00 291. Ad astra per exceLCA: Chemical accounting for the undergraduate researcher. J.R. Silverman, B.

Subramaniam

8:20 292. Lab for the pack: Redesigning first semester general chemistry lab for the students we have. B.M.

Neal, D.J. Styers-Barnett, A.R. Cutler, L.A. Bolyard

8:40 293. Revolutionizing undergraduate labs with benchtop NMR: An active learning approach. M.T.

Zamora, J.F. Araneda, S.D. Riegel

9:00 294. Incorporating an interdisciplinary course-based undergraduate research experience into an

introductory organic and biochemistry lab course. M.J. Harvey

9:20 Intermission.

9:35 295. Professionalism in chemistry II. S. Gamagedara

9:55 296. Flipping an organic chemistry class. M.A. Lewis

10:15 297. New organic chemistry reaction simulation that allows students to simultaneously view the 2D

scheme and 3D animation of reactions. A.M. Cannon, J. Kersten, W. Baltz, Y.A. Letuchy, A. Patric

==================================================================

27

KS Union

Alderson

From Molecules to Nanomaterials: Applications in Energy & Catalysis

Cosponsored by COLL and INOR

C. L. Berrie, J. D. Blakemore, Organizers, Presiding

8:00 298. X-ray transient absorption spectroscopy. L.X. Chen

8:30 299. Fabrication of micro and nano sized metal structures on Si (111) and Mica substrates: An Atomic

Force Microscope (AFM) and Particle Lithography (PL) approach. S.B. Ulapane, A.K. Borkowski, M.K.

Okeowo, J. Totleben Doolin, C.L. Berrie

8:50 300. Electrochromic diisocyanide-terminated bi- and terazulenic platforms chemically accessible with

three different molecular charges. N.R. Erickson, A.D. Spaeth, D.M. McGinnis, M.V. Barybin

9:10 Intermission.

9:20 301. Promoting adsorption of non-thiolated molecules to gold nanostars. A.J. Haes, W. Xi, H.T. Phan,

G. Lu

9:50 302. Design of ultrasmall intermetallic compound nanoparticles for electrocatalysis. Z. Qi, C. Xiao, T.

Goh, Y. Pei, W. Huang

10:10 303. Synthesis of highly dispersed and highly stable supported Au-Pt bimetallic catalysts by a two-step

method. X. Wang, X. Liang

10:30 Intermission.

10:40 304. Size-selective catalysts with an ultra-thin porous shell prepared by molecular layer deposition. Z.

Shang, X. Liang

11:00 305. Breaking the intrinsic limits of electrode materials in electrical energy storage using a hierarchical

core-shell structure. J. Li, J.E. Brown, G.P. Pandey, S. Klankowski, J. Acharya, J. Wu

==================================================================

28

KS Union

Jayhawk

Inorganic Chemistry

J. D. Blakemore, Organizer

D. Lionetti, Presiding

8:00 Introductory Remarks.

8:15 306. Hydrogen atom transfer reactivity by a series of N5-ligated oxomanganese (IV) complexes. A.A.

Massie, D. Rice, T.A. Jackson

8:30 307. Oxygen-exchange kinetics of the Anderson-type polyoxometalate ion IMo6O245-. M. Spriet, E.M.

Villa

8:45 308. Theoretical investigation into the reaction landscape of hydrogen atom abstraction by a MnIV(O)

complex. D. Rice, A.A. Massie, T.A. Jackson

9:00 309. Distinguishing between homogeneous and heterogeneous hydrogen-evolution electrocatalysis with

a quartz crystal microbalance. D.J. Sconyers, J.D. Blakemore

9:15 Intermission.

9:30 310. Synthesis and characterization of (Cp*H)Rh(diimine) complexes. Y. Peng, D. Lionetti, J.D.

Blakemore

9:45 311. Multielectron processes in a rhodium bipyridine complex relevant to hydrogen fuel production. W.

Moore, W. Henke, K. Prather, J.D. Blakemore

10:00 312. d-Electron count, ion-pairing and diagonal twist angles in metallo-bis(dithiolene) complexes. C.C.

Kirkpatrick, J.N. Truong, B.A. Kowert

10:15 Intermission.

10:30 313. Highly stable two and three lithium insertion in conformal amorphous V2O5 shells

electrodeposited on electrospun carbon nanofiber network as a flexible lithium ion battery cathode. J.E.

Brown

10:45 314. Varied extended singlet excited state lifetime via excimer formation as a MOF topology-

dependent function. J. Yu, P. Deria

11:00 315. Quantitative control of metal doping in TiO2 nanocrystals. S. Mia, S. Varapragasam, C.

Balasanthiran, J.D. Hoefelmeyer

11:15 316. Ag-TiO2 hybrid nanoparticles as active photocatalyst for hydrogen evolution. S. Varapragasam,

S. Mia, C. Balasanthiran, J.D. Hoefelmeyer

==================================================================

29

KS Union

Pine

Materials Chemistry

F. Tao, Organizer, Presiding

8:00 317. Crystal engineering of energetic materials: Co-crystals of tetrazole based explosives with modified

performance. J.C. Gamekkanda, C.B. Aakeroy, A. Sinha

8:20 318. Study of microwave effect on synthesis of hyperbranched CdS1-xSex supra quantum dots. M.

Yazdanparast, E.J. McLaurin

8:40 319. Physical and chemical applications of photodoping in electrodeposited cuprous oxide thin films. R.

Coridan, J.M. Lowe

9:00 320. Significance of inserting an oxidative ring-fusion aromatization step at the early stages of pyrolytic

carbonization of polybenzoxazines and other phenolic resins. H. Majedifar, S. Donthula, S. Mahadik, T.

Yazdeli, M. Adnan Saeed, N. Leventis, C. Sotiriou-Leventis

9:20 321. Synthesis and first MRI results of mesoporous silica-stabilized very small iron oxide contrast

agents. J. Covarrubias, H. Wang, T.B. Shrestha, D.L. Troyer, S.H. Bossmann

9:40 Intermission.

9:50 322. Scalable synthesis of block functionalized carbon nanotubes. L. Barrett, B.P. Grady, S. Crossley

10:10 323. Withdrawn

10:30 324. Solid-state landscape of a class of activated halogen bond donors. B. Sandhu, A. Sinha, C.B.

Aakeroy

10:50 325. Dynamic crosslinks through the reversible thia-Michael addition reaction. P. Getty, K. Greenman,

S.J. Rowan

11:10 326. Synthetic strategies for versatile functionalization of cavitands. N. Sarkar, C.B. Aakeroy, A.

Sinha

==================================================================

30

KS Union

Centennial

Organic & Medicinal Chemistry

R. A. Altman, H. Malinakova, Organizers

J. L. Markley, Presiding

8:00 327. Synthesis of dibenzothiophene sulfoxide derivatives and their potential for site-selective oxidation

of nucleic acids. J.C. Throgmorton, A. Eischen, L. Zhong, D.A. Baum, R.D. McCulla

8:20 328. Synthesis of endophenazines and analogues and their antimicrobial evaluation. K. Maddeboina, N.

Rodrigues de Almeida, V.R. Udumula, M.M. Conda-Sheridan

8:40 329. Synthesis of fluorescently labelled analogs of cyclophostin and cyclipostin. G.R. Gnawali, B.

Martin, C.D. Spilling

9:00 330. Synthesis and evaluation of tricyclic pyrone derivatives for the treatment of Alzheimer’s disease.

M. Zhang, I. Maezawa, B. Zou, S. Weerasekara, B. Hao, M.L. Weber, W.S. Cao, C. Pascual, X.S. Xie, L.

Jin, D.H. Hua

9:20 331. Development of pot-economical strategies for the synthesis of (–)-13-Desmethyl-lyngbouilloside

and novel electrophilic macrocycles. A. Ganguly, S. Javed, G.C. Dissanayake, D. Vithanage, P.R. Hanson

9:40 Intermission.

9:50 332. Syntheses of substituted 6-(Dimethylamino)-2-phenylisoindolin-1-ones for the inhibition of

luciferase. M.J. Gunaratna, M. Nakagomi, A. Ito, B. Hao, K. Apley, D.H. Hua

10:10 333. Synthesis of 1,3-anti diol containing bioactive natural products and analogs via modular, pot-

economical and library amenable protocols. S. Javed, A. Ganguly, G.C. Dissanayake, D. Vithanage, P.R.

Hanson

10:30 334. Synthesis of phostone and furanose phosphonates. R.R. Paudel, J.N. Ridenour, S. Dawadi, C.D.

Spilling

10:50 335. One-pot sequenatial strategies for the synthesis of polyol fragments: Applications in natural

product synthesis. C.N. Ndi, P.R. Hanson

11:10 336. Stream-lined synthesis of 3-Hydroxy-β-lactams: Norrish-Yang type II photocyclizations of β-

ketoformamides. J.L. Markley, T. Morse, N.P. Rath, T.A. Wencewicz

==================================================================

31

KS Union

Woodruff

Organic Synthesis & Catalysis

M. D. Clift, Organizer

J. A. Tunge, Organizer, Presiding

8:00 337. Highly selective preparation of heteroleptic Zn(II)-methylene bis(imidazoline) complexes through a

chirality driven self-assembly, and its applications toward building multi-functional dendrimer catalysts. S.A.

Moteki

8:30 338. Intra- and intermolecular functionalization of alkenes via transition metal-catalyzed activation of

amide C-N bonds. L.M. Stanley

9:00 339. Direct functionalization of alcohols using cobalt photocatalysis. D.B. Martin, D. Chambers, E.

Sodogar

9:30 340. Progress toward a tunable terpenoid synthesis strategy. A.J. Grenning

10:00 341. Cofactors as a source of inspiration for discovering new modes of catalytic activation. M.D. Clift

10:30 342. Stereoselective strategies for the synthesis of chiral amines with imine and enamine umpolung

reagents. S. Malcolmson, K. Li, P. Daniel, X. Shao, A. Weber, L. Tseng

11:00 343. New methods for chemical screening library construction and applications: Overcoming complex

barrier. R. Rafferty

==================================================================

KS Union

Divine 9

Physical Chemistry

M. Caricato, Organizer

X. Chen, Presiding

8:00 344. Diffusion of benzene and alkylbenzenes in nonpolar solvents. B.A. Kowert

8:30 345. Real-time TDDFT investigation of plasmon resonances in gold nanowires. R.D. Senanayake, D.

Lingerfelt, X. Li, C.M. Aikens

8:45 346. Enhancing the sensitivity of solid-state NMR for characterization of organolead halide perovskites.

M. Hanrahan, L. Men, B. Rosales, J. Vela , A.J. Rossini

9:00 Intermission.

9:15 347. Electronic coupling for donor-bridge-acceptor systems with a bridge-overlap approach: A

benchmark study. A. Biancardi, M. Caricato

32

9:35 348. Graphene field effect transistors as a high-throughput platform for measuring exciton dissociation

dynamics at organic interfaces. B. Kattel, T. Kafle, L. Qin, W. Chan

9:50 349. Residue based contributions to the thermodynamic properties of ubiquitin. N. Kariyawasam

Manachchige, E.A. Ploetz, P.E. Smith

10:05 Intermission.

10:20 350. Cu-oxo complexes supported in MOR zeolites as active sites for methane-to-methanol conversion.

J. Xu, B. Liu

10:35 351. Investigation of solvation effects on optical rotatory dispersion using the polarizable continuum

model. T. Aharon, P. Lemler, P.H. Vaccaro, M. Caricato

10:50 352. Ultrafast relaxation dynamics of trans-stilbene derivatives in confined organic capsules. C.J.

Otolski, A.M. Raj, V. Ramamurthy, C.G. Elles

==================================================================

KS Union

Malott

Theory of Interfaces

B. B. Laird, W. H. Thompson, Organizers

J. P. Palafox - Hernandez, Presiding

8:00 353. Surface potentials, surface spectroscopy, and solvation: A theoretical perpective. C.J. Mundy,

M.D. Baer

8:40 354. Understanding liquid structure and dynamics near amorphous SiO2 through simulations of sum

frequency generation spectra. P.N. Wimalasiri, P.C. Burris, J. Harvey, W.H. Thompson

9:00 Intermission.

9:15 355. Heterogeneous hydration dynamics around Candida Antarctica lipase B: Relationships with protein

dynamics and water structure. J.N. Dahanayake, K.R. Mitchell-Koch

9:55 356. Atomistic insights into nitrogen-cycle electrochemistry: NO electrochemical reduction on Pt

surfaces from first principles calculations. H. Chun, A.Z. Clayborne, V. Apaja, K. Honkala, J.P. Greeley

10:15 Intermission.

10:30 357. Accelerated nucleation and polymorph selection with trace additives: theory and simulation. B.

Peters

11:10 358. Removing the barrier to the calculation of activation energies and volumes: Diffusion and

reorientation in water. E.A. Piskulich, O. Mesele, W.H. Thompson

==================================================================

33

KS Union

Kansas

Spectroscopy Applied to Structure, Dynamics, & Imaging

C. G. Elles, C. K. Johnson, Organizers, Presiding

8:10 359. Resolving interfacial protein dynamics by Super Temporal-Resolved Microscopy (STReM). C.F.

Landes

8:40 360. In Situ biomolecular structural elucidation by super-resolution microscopy with single particle

averaging. J. Unruh

9:10 361. Methods of analyzing sparse data sets from time-correlated, single-photon counting experiments:

Application of the maximum likelihood and related methods to mixtures of rose bengal and rhodamine B. K.

Santra, E.A. Smith, J.W. Petrich, X. Song

9:30 Intermission.

9:50 362. Oscillatory enzyme dynamics and their role in enzyme-catalyzed reactions. C.M. Cheatum

10:20 363. Split-GFP assay to survey proteins, interactions, and dynamics of the inner nuclear envelope in

live cells. B.D. Slaughter

10:50 364. Spectroscopic imaging studies of micropolarity in plasmid DNA using a solvatochromic dye and

chemically graded surfaces. Z. Li, R. Kumarasinghe, D.A. Higgins

11:10 365. Energy landscape of the FMO antenna from C. tepidum and its L122Q and Y16F mutants: Low

temperature high resolution spectroscopic and modeling studies. A. Khmelnitskiy, R. Saer, R.E.

Blankenship, R. Jankowiak

==================================================================

34

KS Union

Ballroom

Analytical Chemistry

Y. Zeng, Organizer

10:10 - 12:10

366. Development and validation of high performance liquid chromatography method for quantitative

determination of 4-hydroxybenzoate and related renal cell carcinoma biomarkers in human urine. S.

Gamagedara, T. An-Yen, K.S. Dahal, N.T. Perera, B.K. Lavine

367. Development of a hydrogen exchange-mass spectrometry method to predict aggregation propensity of

protein therapeutics. J.P. Rincon, G. Meric, C. Calero-Rubio, C. OBrien, H. Shahfar, A.S. Robinson, C.J.

Roberts, D.D. Weis

368. Rapid prediction of deamidation rates of proteins to assess their long-term stability using hydrogen

exchange mass spectrometry (HX-MS). C.L. Demalgiriya Gamage, D.D. Weis

369. Sparse representation for hydrogen exchange mass spectrometry (HX-MS) data by using LASSO

optimization. Y. Shi, D.D. Weis

370. Hydrogen exchange mass spectrometry can reliably detect small fractions of destabilized protein in

comparability studies. T. Hageman, J. Arora, D.D. Weis

371. Identification of individual phenolic metabolites in American elderberry pomace extract utilizing high

performance liquid chromatography tandem mass spectrometry. R. Krueger, A.L. Thomas, C.M. Greenlief

372. High-throughput microfluidic separation of plasma from whole blood for downstream biomarker

detection. E.M. Mohr, C. Campos, S.A. Soper

373. Microfluidic affinity purification of cancer-specific extracellular vesicles. J.M. Jackson, M.A. Witek, S.

Pullagurla, D. Park, K. Herrera, M. Murphy, S.A. Soper

374. Label-free enumeration of Circulating Tumor Cells (CTCs) using μ-Coulter counter. C. Kong, M. Hu,

M.L. Hupert, S.A. Soper

375. Nano-coulter counter for the quantification of extracellular vesicles. J.D. Conner, S. Pullagurla, B.

Gross, S.A. Soper

376. Evaluation of minimal residual disease in acute leukemia using microfluidics and spectral time-delayed

integration multi-parameter flow cytometry. W. Hu, M. Jackson, M.A. Witek, S.A. Soper

377. Automated sealing system for digitalizing multiplexed biomarkers in femtoliter compartments. D. Lella,

Y. Zeng

378. Microfluidic-based exponential rolling circle amplification for exosomal microRNA detection. H. Cao,

Y. Zeng

35

379. Connecting land use and water quality: Agricultural and restored prairie outputs. A. Miller, A. Dere, C.

Jackson

380. Detection of metal ions by organic dyes on paper-based analytical devices. K. Yoshimatsu

381. Fabrication of polymer microneedle implants using an atomized spray process for controlled drug

delivery. M. Kim, S. Choi

382. Analysis of drug-protein interactions during diabetes by high-performance affinity chromatography. P.

Tao, Z. Li, R.E. Matsuda, D.S. Hage

383. Analysis of free drug fractions by high performance affinity chromatography: Interactions of

sulfonylurea drugs with human serum albumin. B. Yang, X. Zheng, D.S. Hage

384. Controlled drug release from solution blow spun core-shell nanofibers with blended shell. S. Park, S.

Choi

385. Soxhlet extraction of avocado endocarp and trituration of avocado mesocarp for biodiesel production.

A.J. Cruz, D. Kostner, I. Oraemesi, B. Maricle

386. Nanoscale solid-phase enzymatic reactor for biopolymer (DNA/RNA) disassembly. U.S. Athapattu,

S.A. Soper

387. Nanoparticle composition and reactivity contribute to the bacterial toxicity of nanoscale metal

phosphates. P.L. Clement, J.E. Kuether, J.R. Borgatta, T.A. Qiu, V. Feng, R.J. Hamers, C.L. Haynes

388. Ligands binded paramagnetic nanoparticles applied in enzyme activity studies. S. Jia, C.T. Culbertson

389. Vapor phase plotting of organotrichlorosilane sub-monolayer gradients. J. Bautista, J. Austin, A.

Forzano, M.M. Collinson, D.A. Higgins

390. Hydrogen peroxide detection in chemotherapy treated wistar rats. K.J. Garcia, R. Gehringer, A.I.

Bandara, M.A. Johnson

391. Evaluation of cyclic olefin copolymer as a new material for fabrication of microchip electrophoresis

devices for online monitoring of amino acids in brain dialysate. G.A. Bulgakova, N.J. Oborny, S.M. Lunte

392. Comparison of CE-UV and CE-MS as analysis methods for dynorphin peptides. E.A. Kurfman, A.M.

Al-Hossaini, M.B. Wijesinghe, S.M. Lunte

393. Entrapment of proteins in high-performance affinity columns for chromatographic studies of solute-

protein interactions. S. Poddar, E.L. Rodriguez, S. Azaria, D.S. Hage

394. On-column preconcentration of adenine nucleotides for analysis of brain tissues by CE. E.

Buyuktuncel, S. Gunawarhana UngawelDurayalage, S.M. Lunte

395. Single-cell analysis of nitric oxide production in stimulated RAW 264.7 macrophages by microchip

electrophoresis coupled with laser Induced fluorescence detection. J. Sibbitts, D.E. Patabadige, C.T.

Culbertson

36

396. Simultaneous detection and quantification of nitric oxide and superoxide using microchip

electrophoresis coupled with laser-induced fluorescence. D.B. Weerasekara, G. Caruso, C. Fresta, J. Siegel,

M.B. Wijesinghe, S.M. Lunte

397. Single-molecule tracking studies of charge-dependent translational and orientational dye motions within

surfactant- and solvent-filled silica mesopores. R. Kumarasinghe, D.A. Higgins, T. Ito

398. Impact of perturbing the BfrB:Bfd interaction on Pseudomonas aeruginosa biofilms. A. Soldano, M.E.

Rivera

399. Thermal characterization of lignin residue after high-temperature hydrotreatment. R. Roy, D.E. Raynie

400. Depolymerization of alkali lignin in the presence of subcritical water and Ni-G catalyst. B. Jadhav, D.E.

Raynie

401. Thermoplastic nanofluidic sensor for the florescence detection of chemotherapeutically induced damage

in genomic Dna. S. Vaidyanathan, K. Weerakoon-Ratnayake, S.A. Soper, D. Kaufman

402. Microfluidic platform for isolation of extracellular vesicles: Potential stroke biomarkers. S. Pullagurla,

M.A. Witek, J.M. Jackson, A. Baird, S.A. Soper

403. Effective identification of benzaldehyde product in oxidation reactions using Co(II)/TEMPO Catalytic

system. B. Sweetman, L. Handin, Y. Liu

==================================================================

37

FRIDAY AFTERNOON

==================================================================

KS Union

Alderson

Analytical Applications of Microfluidics

Cosponsored by ANYL

Financially supported by Center for Molecular Analysis of Disease Pathways; Adams Institute for

Bioanalytical Chemistry

S. M. Lunte, Organizer, Presiding

12:30 Introductory Remarks.

12:35 404. Using microchip electrophoresis and electrochemical detection to investigate cellular

communication. R.S. Martin

1:15 405. Microfluidic paper-based analytical devices for forensic applications. T. Cardoso, P. Garcia, R.

Channon, J. Adkins, C. Henry, W. Coltro

1:55 406. Enhancing the information content of single cell analysis on microfluidic devices using optical fiber

bridge. C.T. Culbertson, J. Sibbitts

2:35 Intermission.

2:45 407. Expanding the paper-microfluidics toolbox. E. Verpoorte, G.I. Salentijn, N.N. Hamidon, Y. Hong

3:25 408. Microfluidics for isolation of orthogonal populations of circulating tumor cells. M.A. Witek

4:05 Concluding Remarks.

==================================================================

KS Union

Big 12

Chemical Biology of Microbial Processes

M. E. Rivera, Organizer

R. De Guzman, Presiding

12:30 409. Biliverdin IXβ a signaling molecule for extracellular heme uptake by the opportunistic pathogen

Pseudomonas aeruginosa. A. Wilks

1:05 410. Biosynthetic mechanisms for antibiotics from the emerging biocontrol agents Lysobacter. L. Du

38

1:40 411. Using archaea for what they do best: Redirecting carbon and energy towards isoprene as an

anaerobic respiration/fermentation product. J. Aldridge, S. Carr, K.A. Weber, N.R. Buan

2:15 Intermission.

2:35 412. Unraveling the MSTery. A.L. Lamb

3:10 413. Mechanistic insights into bacterial dye-decolorizing peroxidases. P. Li, R. Shrestha, G. Huang,

B.V. Geisbrecht

3:45 414. Inhibiting the bacterioferritin (BfrB):bacterioferritin associated ferredoxin (Bfd) interaction in P.

aeruginosa causes iron homeostasis dysregulation. M.E. Rivera, H. Yao, A. Punchi Hewage, A. Soldano, S.

Lovell

==================================================================

KS Union

Jayhawk

Inorganic Chemistry

J. D. Blakemore, Organizer, Presiding

12:30 Introductory Remarks.

12:45 415. Preparation of transition metal cluster complexes containing NHC ligands. L.F. Szczepura, W.

Wilson, D.N. Huh

1:00 416. Assembly and characterization of heterobimetallic complexes of nickel with trivalent redox-

inactive cations. A. Kumar, J.D. Blakemore

1:15 417. Structural landscape assessment: N-heterocycle containing tritopic acceptors. S.N. Andree, A.

Sinha, M. Dakovic, C.B. Aakeroy

1:30 418. Halide-bridged coordination polymers from mono-picolyl biimidazoles and cadmium(II). C.A.

Gunawardana, A. Sinha, C.B. Aakeroy

1:45 Intermission.

2:00 419. Assessing the chemical variations in thorium, uranium, and neptunium bonding reactivity through

macrocyclic ligand encapsulation. M.C. Basile, E. Cole, A. Blanes, T. Forbes

2:15 420. Surface immobilization of molecular complexes of the f-elements. K.J. Cannon, D. Lionetti, J.D.

Blakemore

2:30 421. O-O bond activation by a series of Mn complexes supported by amide-containing ligands. J.

Parham, T.A. Jackson

2:45 422. Photodecomposition mechanisms of manganese tricarbonyl complexes. W.C. Henke, C.J. Otolski,

W. Moore, K.V. Prather, C.G. Elles, J.D. Blakemore

39

3:00 Intermission.

3:15 423. Noncovalent immobilization of a manganese electrocatalyst for CO2 reduction. K. Prather, J.D.

Blakemore

3:30 424. Morphology inherence from hollow metal-organic frameworks to hollow carbon polyherons in

preparing electrocatalysts. Y. Pei, Z. Qi, W. Huang

3:45 425. Development of new media for electrochemical CO2 conversion. T. Kerr, C. Shaughnessy, H. Lee,

D.J. Sconyers, B. Subramaniam, K.C. Leonard, J.D. Blakemore

==================================================================

KS Union

Pine

Materials Chemistry

F. Tao, Organizer, Presiding

12:30 426. Sorption kinetics and structural features of water confined in a 1-D metal organic nanotube. T.

Forbes, J. Leddy

12:50 427. Positron interactions with asymmetric materials. J. Van Horn, Y. Jean

1:10 428. Electrode wettability influences on the deep discharge capacity of Li−O2 batteries. F. Wang, X. Li

1:30 429. Organometallic self-assembled monolayer films of linear azulenic and biazulenic p-linkers

featuring asymmetric anchoring. M.K. Okeowo, J. Applegate, C.L. Berrie, M.V. Barybin

1:50 430. Epitaxial lift-off of electrodeposited single-crystal gold foils for flexible electronics. N.

Mahenderkar, Q. Chen, Y. Liu, A.R. Duchild, S. Hofheins, E. Chason, J.A. Switzer

2:10 Intermission.

2:20 431. Molecular structure of silicon nanocrystal surfaces characterized by multidimensional solid-state

NMR spectroscopy. M. Hanrahan, E. Fought, T.L. Windus, L. Wheeler, N. Anderson, N.R. Neale, A.J.

Rossini

2:40 432. Study of soy protein isolate as a functional modifier for polymer materials. Z. Zheng, B. Li

3:00 433. Characterization of energy-rich hydrochars from microwave-assisted hydrothermal carbonization of

coconut shell. S. Elaigwu, G. Greenway

3:20 434. K-Index: a quantitative tool that describes complex soft-matter nanomorphology and correlates it to

synthetic conditions. T. Yazdeli, S. Donthula, C. Sotiriou-Leventis, N. Leventis

3:40 435. Fighting the world’s most dangerous villain: Multidrug resistant bacteria. L. Chlebanowski, O.

Covarrubias-Zambrano, S. Barrett, D.L. Troyer, F. Wolschendorf, S.H. Bossmann

40

==================================================================

KS Union

Kansas

New Directions in Chemistry Education

D. D. Weis, Organizer, Presiding

12:30 Introductory Remarks.

12:35 436. Ripped from the headlines: Analytical chemistry in the news. C.T. Culbertson

1:05 437. Preliminary investigation of students' beliefs about their academic ability and how those beliefs

affect performance. L.M. Wojcinski

1:35 438. Enhancing learning by assessing process skills in STEM courses. R.S. Cole, J. Lantz, S.M. Ruder,

J.A. Schmidt-McCormack, G. Reynders

2:05 Intermission.

2:15 439. Infusing systems thinking in the general chemistry curriculum. T. Holme

2:45 440. Leveraging the Learner-Centered Teaching rubric to characterize instructional practices in

undergraduate chemistry courses. M.N. Stains, Z. Nelson, R.M. Erdmann

3:15 441. Promoting change where change is hard: Tales of a teaching postdoc. A.A. Vartia

3:45 Discussion.

3:55 Concluding Remarks.

==================================================================

41

KS Union

Centennial

Organic & Medicinal Chemistry

H. Malinakova, Organizer

R. A. Altman, Organizer, Presiding

12:30 442. Resorufamines as fluorescent probes of the endoplasmic reticulum. S. Phaniraj, Z. Gao, D. Rane,

B.R. Peterson

12:50 443. Liquid biopsy for early stage pancreatic cancer detection. O. Covarrubias-Zambrano, M.

Kalubowilage, A.P. Malalasekera, D.N. Udukala, H. Wang, S.O. Wendel, D.L. Troyer, S.H. Bossmann

1:10 444. Pacific blue-taxoids: New fluorescent probes of the anticancer properties of taxol. Z. Gao, M. Lee,

B.R. Peterson

1:30 445. Nanobiosensor for the arginase detection. M. Kalubowilage, A.P. Malalasekera, O. Covarrubias-

Zambrano, F. Rahman, H. Wang, D.L. Troyer, S.H. Bossmann

1:50 446. Molecular modeling of membrane glucose transporter (GLUT1) as target for anticancer drugs. S.

Almahmoud, X. Wang, J.L. Vennerstrom, H.A. Zhong

2:10 Intermission.

2:20 447. Peptide-nanosponges for advanced drug delivery. A.S. Yapa, M. Kalubowilage, H. Wang, P.

Thapa, T.B. Shrestha, J. Yu, O. Covarrubias-Zambrano, M. Pyle, D.L. Troyer, S.H. Bossmann

2:40 448. Design, synthesis and antimicrobial properties of self-assembled cationic amphiphilic peptides. N.

Rodrigues de Almeida, M. Samad, M.M. Conda-Sheridan

3:00 449. Developing potent and broad spectrum analogues of the antimicrobial peptide Citropin 1.1. M.

Samad, M. Conda-Sheridan

3:20 450. Synthesis of novel copper-activatable drugs against MRSA. A. Delpe Acharige, T. Shrestha, M.

Zhang, A.P. Malalasekera, H. Wang, M. Kalubowilage, F. Wolschendorf, S.H. Bossmann

3:40 451. Preparation and characterization of family of charged ammonium pocket with para-substituted

multi-functional receptors that target to anionic phospholipid found in bacterial membrane. M. Alsuri

==================================================================

42

KS Union

Ballroom

Physical Chemistry

M. Caricato, Organizer

12:30 - 2:30

452. Electronic structure, geometric properties, and catalytic performance of the multishell Au-nanoparticle

Au70S20[P(Ph3)]12. A. Frojd, S. Kenzler, H. Hakkinen, A. Schnepf, A.Z. Clayborne

453. Infrared studies of crystalline thiocyanate hydrates: Evidence of solid phase simultaneous vibrational

transitions. H.R. Krueger

454. Measurement of one-bond 1H-17O scalar couplings in organic solids and inorganic materials. S.L.

Carnahan, B. Lampkin, P. Naik, M. Hanrahan, I.I. Slowing, B. VanVeller, A.J. Rossini

455. Vapor-liquid equilibria: Ammonia and 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide.

T. Turnaoglu, M. Shiflett

456. Clathrate hydrate formation using fluorocarbons. A. Rocha, M. Shiflett

457. Simulations of ammonia adsorption for the characterization of acid sites in metal-doped amorphous

silicates. A. Jystad, A. Biancardi, M. Caricato

458. Structure determination of boron carbide thin films using solid state NMR spectroscopy. A. Alnafisah,

N.A. Oyler, T. Nguyen, M. Paquette

459. Analysis of the effect of glycine on the hygroscopic properties of sodium chloride aerosols. D. Birge, S.

Gottuso, A. Kanley, J.P. Darr

460. Electronic properties of [n]cyclacene series versus Möbius[n]cyclacene series. J.R. Dias

461. Solubility of vinyl fluoride in aqueous lithium bis(trifluoromethylsulfonyl)imide solutions. D.L.

Minnick, W.J. Gilbert, A. Rocha, M. Shiflett

462. Understanding catalytic bifunctionality of Cu/ZSM5 and Cu/Y zeolites for biomass conversions. J. Xu,

Q. Zheng, K.L. Hohn, B. Liu

463. Computational studies of Si3N3Hx (x = 0 - 9) clusters. K. Suh, G. Guirgis, C. Metz, A.Z. Clayborne

464. Infrared spectra of phosphoenolpyruvate in aqueous solutions: Vibrational frequency shifts of functional

groups due to presence of metal ions. R.E. Brenner, C.J. Wurrey, A. Fenton

465. Ultrafast interlayer electron transfer in incommensurate transition metal dichalcogenide homobilayers.

Y. Li, Q. Cui, F. Ceballos, S. Lane, Z. Qi, H. Zhao

466. Characterizing the structural overpotentials induced by bubble evolution during water electrolysis on

spatially-distributed electrocatalyst-semiconductor interfaces. Z. Schichtl, R. Coridan

43

467. Carrier dynamics in phosphorene and multilayer black phosphorous. P. Zereshki, F. Ceballos, M.

Bellus, S. Pan, H. Zhao

468. Using bulk-heterojunction and selective electron trapping to enhance the responsivity of perovskite-

graphene photodetector. L. Qin, B. Kattel, W. Chan

469. Understanding the dynamics of the resorcin[4]arene hexameric supramolecular assembly. A. Katiyar,

W.H. Thompson

470. Modeling the permeation of aromatic dipeptides across lipid bilayers. B. Lee, K. Kuczera

471. Stability of gold thiolate and gold chloride nanoclusters. G. Kuda Singappulige, C.M. Aikens

472. Disrupting protein-protein interactions to modulate the integrity of the blood brain barrier. J. He, T.J.

Siahaan, K. Kuczera

473. Electron and nuclear dynamics in [Au24Ag(SH)18]-1 and [Au13Ag12(SH)18]

-1 nanoparticles. P. Pandeya,

C.M. Aikens

474. Measuring accurate absolute Two-Photon Absorption cross sections using stimulated Raman scattering

as an internal standard. D.A. Stierwalt, A.L. Houk, C.G. Elles

475. Computational study of the interactions of hydrogen peroxide and water with reduced ceria surfaces. N.

Shao, N. Al-Aqtash, K. Tarawneh, C.L. Cheung, W. Mei, R. Sabirianov

476. Novel reaction cell design for simultaneous in situ diffuse reflectance UV-visible and FTIR

spectroscopies: Application to CO oxidation on gold catalysts. P.D. Srinivasan, J.J. Bravo-Suarez

477. Cavity-mediated catalysis via metal-organic supercontainers. Z. Wang, Y. Qiao, P. Jampani

==================================================================

KS Union

Malott

Physical Chemistry

M. Caricato, Organizer

B. A. Kowert, Presiding

12:30 478. Hydrogenated TiO2 nanomaterials for microwave absorption. X. Chen

1:00 479. Exploiting CO2-expanded liquids in hydroformylation: A molecular simulation approach. C.H.

Mendis, J.P. Palafox - Hernandez, B.B. Laird, W.H. Thompson

1:15 480. Reanalysis of the a 4Σ- - X 2Π1/2 transition of GeH using intracavity laser spectroscopy. J. Harms,

L.C. O'Brien, J.J. O'Brien

1:30 Intermission.

44

1:45 481. Evaluating cations' competitive interactions with water-soluble anionic polyelectrolytes using an

ion exchange model. M. Chen, K. Shafer-Peltier, E.S. Albertson, S. Randtke, E.F. Peltier

2:05 482. An EOM-CCSD-PCM benchmark for electronic excitation energies of solvated molecules. S. Ren,

M. Caricato

2:20 483. Development of gold nanostructures using AFM based nanopatterning of self-assembled

monolayers on silicon to study gold binding peptide tagged proteins. N.J. Kamathewatta, D.O. Deay, M.L.

Richter, C.L. Berrie

2:35 484. Phase equilibria, transport properties, and structure of CO2-expanded ethylene oxide and methanol.

E.A. Piskulich, B.B. Laird, W.H. Thompson

2:50 Intermission.

3:05 485. Effects of water and pH on electrocatalytic conversion of carbon dioxide in ionic liquid media. A.

Hailu, S.K. Shaw

3:20 486. Electronic coupling in diazulenic molecular rectifiers: A theoretical approach. T.C. Balduf, A.

Biancardi, M. Caricato

3:35 487. Positron interactions with natural and synthetic chiral quartz crystals in non-z orientations. F. Wu,

J. Van Horn, Y. Jean

==================================================================

KS Union

Woodruff

Cope Scholar Symposium: Synthesis and Catalysis

Cosponsored by ORGN

J. A. Tunge, Organizer

M. D. Clift, Organizer, Presiding

1:00 488. Development of a long term manufacturing route to HCV NS5b inhibitor, MK-3682. J. Limanto

1:30 489. Inter- and intramolecular aryl insertion reactions of borylnitrenes. F.J. Williams

2:00 490. Radical chemistry of the Breslow intermediate. M. McIntosh

2:30 491. New approaches to allylic fluorination and radiofluorination. H.M. Nguyen

3:00 492. Take a CAHB direct to chiral boronic esters, but don’t interrupt? J.M. Takacs

3:30 493. Stereoselective synthesis of saturated heterocycles via copper-catalyzed alkene difunctionalizations.

S.R. Chemler

==================================================================

45

KS Union

Ballroom

Inorganic Chemistry

J. D. Blakemore, Organizer

2:40 - 4:40

494. Nano-particles for water treatment synthesized from conjugated linoleic acid (CLA). M. Chen, C.T.

Jafvert

495. Early detection of non-small-lung cancer in liquid biopsies by ultrasensitive protease-activity analysis.

M. Kalubowilage, D.N. Udukala, A.P. Malalasekera, S.O. Wendel, H. Wang, A.S. Yapa, D.L. Troyer, S.H.

Bossmann

496. Benzalkonium-derived Mesoporous Silica Nanoparticles Against Micrococcus luteus. S. Barrett, L.

Chlebanowski, O. Covarrubias-Zambrano, D.L. Troyer, S.H. Bossmann

497. Catalyst for conversion of methyl ethyl ketone to butenes. Z. Alauda, H. Alatabi, Q. Zheng, K.L. Hohn

498. Simultaneous upgrading of furanics and phenolics via hydroxyalkylation/aldol condensation reactions.

T.V. Bui, T. Sooknoi, D. Resasco

499. Synthesis of novel rhenium selenide clusters containing isonitrile ligands. C.P. Chin, W. Wilson, D.N.

Huh, L.F. Szczepura

500. Photopatterned noble metal functional surfaces via galvanic replacement reactions on Cu2O thin films.

J.M. Lowe, R. Coridan

501. Hierarchical nano-on-microsized copper crystals on nickel foam for highly efficient electro-oxidation of

hydrazine. X. Yan, Y. Liu, K. Scheel, Y. Li, Y. Yu, X. Yang, Z. Peng

502. Supramolecular and coordination chemistry: search for new classes of carboxamide pincers. S.

Pramanik, S. Kaur, V.W. Day, K. Bowman-James

503. Preparation and investigation of the pKa of [Mnll(H2O)(dpaq2Me)]+ and the characterization of a one

electron oxidized version of [Mnlll(OH)(dpaq2Me)]+. A.A. Munasinghe, J. Parham, D. Rice, T.A. Jackson

504. Investigation of bis(μ-oxo)dimanganese(III,IV) and oxomanganese(IV) complexes: Comparison of

structure and reactivity. Y. Lee, A.A. Massie, T.A. Jackson

505. Bidentate ligands modulate hydrogen generation by [Cp*Rh] complexes. E.A. Boyd, K. Prather, D.

Lionetti, J.D. Blakemore

506. Investigation of actinide reactivity by synthesis with crown ethers. E. Cole, M.C. Basile, A. Blanes, T.

Forbes

==================================================================

46

KS Union

Ballroom

Materials Chemistry

F. Tao, Organizer

2:40 - 4:40

507. Binder free approach to synthesize nanostructured nickel compounds for energy storage applications. N.

Albeladi, C. Zhang, S.D. Bhoyate, K.S. Siam, P.K. Kahol, R. Gupta

508. Tea leaves derived carbon for high temperature energy storage devices. S.D. Bhoyate, C. Ranaweera, C.

Zhang, M. Hyatt, P.K. Kahol, R. Gupta

509. Orange peel derived highly flame retardant rigid polyurethane foam. C. Zhang, S.D. Bhoyate, M.

Ionescu, P.K. Kahol, R. Gupta

510. Hierarchically structured electrodes prepared from selective atomic layer deposition in self-assembled,

composite colloidal films. M.A. Norman, W. Perez, R. Coridan

511. Progress towards a large-scale synthesis of hollow Mn3O4 nanoparticles from the galvanic reaction

between MnO nanocrystals and Cu2+. B. Onserio, S. Varapragasam, J.D. Hoefelmeyer

512. Withdrawn

513. Development of high-load, hybrid ROMP reagents and scavengers immobilized on silica and Co/C

magnetic nano-particles for their application in sequestration and parallel synthesis. S. Faisal, J. Jun, T.A.

Klein, Q. Zang, P. Maity, P.C. Kearney, D. Stoianova, P.R. Hanson

514. Highly porous SiC & Si3N4 monoliths via carbothermal reduction of polymer-crosslinked sol-gel silica

powder compacts. P.M. Rewatkar, T. Taghvaee, M. Adnan Saeed, S. Donthula, T. Leventis, J. Schisler, C.

Sotiriou-Leventis, N. Leventis

515. Selective hydrogenation of citral over supported Pt catalysts: Insights into support effects. X. Wang, X.

Liang

516. Supported nickel nanoparticle catalysts synthesized by atomic layer deposition for dry reforming of

methane. Z. Shang, X. Liang

517. The role of surface-wettability in electrochemical reactions involving gas-phase reactants or products. H.

Mehrabi, R. Coridan

518. Electropolymerization of perfluoroalkylated thiophene- and aniline-based aromatic compounds for high-

performance batteries. E.L. Moen, J.C. Lawrence, S. Mao, J.H. Kramer, M.O. BaniKhaled, H. Sun

519. Evaluating the functional similarity of hydrogen and halogen bonding. A.M. Abeysekera, C.B.

Aakeroy, A. Sinha

47

520. SERS detection of toxins via substrates with anchored polymeric chains. R.S. Rodriguez, V.M. Szlag,

S. Jung, S. Bryson, M. Bourgeois, G.C. Schatz, T.M. Reineke, C.L. Haynes

521. Effect of nanostructure morphology and C=charge on esterase-release of ketoprofen from

supramolecular nanostructures. V.R. Udumula, M.M. Conda-Sheridan

522. Dielectric properties of soy protein isolate and its nanocomposites. M. Cox, Z. Zheng, B. Li

523. Effect of surface passivation on photothermal effect of gold nanorod. R. Marasini, A. Pitchaimani, T.

Nguyen, S. Aryal

524. Structural reorganization of silica wet-gels upon drying: Why aerogels shrink? C. Mandal, S. Donthula,

C. Sotiriou-Leventis, N. Leventis

525. Multiscale hierarchical nanoporous polyurethane aerogels based on α- and β-Cyclodextrin for CO2

sequestration, water vapor uptake and cationic dye separation. P.M. Rewatkar, M. Adnan Saeed, S.

Donthula, H. Majedifar, N. Leventis, C. Sotiriou-Leventis

526. One-step synthesis and characterization of “click-able” polymers for biomedical applications. W.

Alqahtani, S. Santra, R.A. Gross

527. Systematic route for heterobifunctionalization of polypropylene glycol polymers and

poly(propyleneglycol)-block-poly(ethyleneglycol) copolymers. J. Blankenship, K. Yoshimatsu

48

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