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    AD-A1IN

    535

    WISCONSIN UNIV-MADISON

    MATHEMATICS RESEARCH

    CENTER

    F/G 12/1

    MATHEMATICAL

    MODELINO OF TWO-PHASE

    FLOW.(U)

    MAR 82

    D A

    DREW

    DAAG29-8o-C-O00I

    UNCLASSIFIED

    MRC-TSR-2343

    NL

    Ei

    IIIIIIIIIIII

    IIIIIIIIIIIIIu

    EIIIIIIEIIIIIE

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    MRC Technical

    Summary

    Report

    #2343

    MATHEMATICAL

    MODELING

    OF TWO-PHASE

    FLOW

    S

    D. A.

    Drew

    Mathematics

    Research

    Center

    University

    of Wisconsin-Madison

    610

    Walnut

    Street

    Madison,

    Wisconsin

    53706

    March

    1982

    (Received

    February

    11,

    1982)

    Approved

    for

    public

    release

    D

    T

    I

    Cby

    Distribution

    unlimited

    ,E

    T

    L.LU.S.

    Army Research Office

    P.

    0.

    Box

    12211

    Fsearch Triangle

    Park

    rth Carolina

    27709

    8

    028

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    UNIVERSITY OF WISCONSIN

    -

    MADISON

    MATHEMATICS

    RESEARCH CENTER

    MATHEMATICAL MODELING OF TWO-PHASE

    FLOW

    D. A. Drew

    Technical

    Summary

    Report #

    2343

    March

    1982

    ABSTRACT

    A continuum mechanics

    approach to

    two-phase

    flow

    is reviewed.

    An

    averaging

    procedure is discussed

    and

    applied

    to

    the exact equations

    of

    motion.

    Constitutive

    equations are

    supplied and discussed for

    the

    stresses,

    pressure

    differences

    and the

    interfacial force. The

    nature

    of

    the resulting

    equations is

    studied.

    AMS

    (MOS) Subject

    Classification: 76T05

    Key Words:

    Two-Phase Flow,

    Constitutive equations

    Work

    Unit

    Number

    2

    -

    Physical

    Mathematics

    Spon-;ored by

    the United States

    Army under

    Contract No.

    DAAG29-80-C-041.

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    SIGNIFICANCE

    AND

    EXPLANATION

    Equations describing

    the

    motions

    of

    two materials,

    one

    dispersed

    throughout

    the other,

    are derived.

    There

    is some

    controversy

    over

    the

    ability

    of certain

    simplified

    forms

    of these

    equations

    to predict

    meaning-

    ful flows.

    Consequently,

    evidence

    is

    presented

    to

    verify

    the forms

    of

    various

    terms

    appearing

    in the equations.

    The consequences

    of

    the assumed

    forms

    are discussed.

    Accesston

    For

    NTIS

    GRA&I

    DTIC

    TAB

    Unannounced

    Justification

    By- -

    Distribution/

    Availability

    Codes

    'Avail

    and/or

    TI

    Dist

    Special

    CP

    The

    responsibility

    for

    the

    wording

    and views

    expressed

    in this

    descriptive

    summary

    lies with MRC,

    and not

    with

    the author of

    this report.

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    I.

    MATHEMATICAL

    MODELING

    OF

    TWO-PHASE

    FLOW

    D. A.

    Drew

    INTRODUCTION

    Dispersed

    two-phase

    flows

    occur

    in

    many

    natural and technological

    situations.

    For

    example,

    dust

    in

    air and

    sediment

    in

    water contribute

    to

    ernsion

    and

    silting, and can cause problems for machinery

    such as

    helicopters and

    power plants operating

    in such

    an environment.

    Also,

    many energy

    conversion and

    chemical

    processes

    involve two-phase flows.

    Boiling

    a fluid such as

    water or

    sodium and extracting

    the heat

    by

    condensation

    at a

    different

    location

    provides a practical

    energy flow

    process. Many

    kinds

    of

    chemical

    reactants and

    catalysts

    are

    mixed

    in

    a

    dispersion of fine

    particles to expose

    as much

    interfacial area

    as

    possible.

    In

    such a large class

    of

    problems,

    many

    diverse mechanisms

    are

    important

    in

    different situations.

    The

    models used for

    these

    different

    situations have

    many common

    features,

    such as

    interfacial drag.

    This

    paper

    examines

    the

    common

    features of

    dispersed

    two phase

    flows

    from a continuum mechanical approach. Since

    it is

    not

    universally

    accepted

    that such an

    approach is

    valid, we shall

    discuss

    some

    philosophical

    reasons

    for taking

    such

    an

    approach. The approach

    is

    based on the

    view that it is

    sufficient

    to describe

    each

    material

    as

    a

    continuum,

    occupying

    the same

    region

    in

    space.

    This new

    "material"

    consists of

    two

    interacting

    materials (called

    phases, even

    though they

    often

    are not

    different

    phases of the

    same material).

    The two phase

    material

    is

    often called

    the

    mixture.

    In

    analogy with continuum

    mechanics,

    we shall have

    to

    specify

    how the

    mixture interacts

    with

    itself.

    In

    ordinary continuum

    mechanics

    (ignoring thermodynamic

    Sponsored by

    the

    United States

    Army under Contract

    No.

    DAAG29-80-C-0041.

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    considerations) that

    requires

    a

    constitutive

    equation expressing

    the

    stress

    as a function of

    various fields.

    In two-phase

    flow

    mectianics, it

    requires

    specification

    of stresses for

    each

    phase, plus a

    relation for

    the

    interaction

    of the two materials.

    Researchers who

    do not subscribe

    to this

    view treat

    the mechanics

    of

    the

    two

    materials, plus

    the dynamics

    of the interface

    as fundamental,

    and use

    derived

    results

    and/or

    measurements

    to

    gain

    the understanding

    needed for

    their particular

    application. It

    is instructive

    to consider

    the

    approaches to gas

    dynamics.

    Most scientists believe

    that

    a gas

    is a

    collection

    of many molecules

    which move,

    vibrate, and

    interact

    in

    a

    complex,

    but describable

    way. Indeed,

    with the

    aid of

    large computers,

    molecular

    dynamics has made

    great strides

    in

    understanding such

    phenomena

    as shocks and

    phase

    transition,

    among

    others. In spite

    of the

    knowledge

    of the correctness

    of this

    model, many scientists

    and

    engineers use a

    continuum model

    for gas

    dynamics.

    Indeed,

    anyone

    wishing

    to describe, for

    example,

    the flow

    around

    an airfoil, would

    be

    hard

    pressed

    to find a

    computer big enough

    to do it as

    a problem

    in

    molecular dynamics. As

    a

    problem in continuum

    gas

    dynamics, it is

    still

    a

    large problem;

    however,

    it is done

    quite

    routinely

    numerically,

    including shocks.

    In addition,

    certain solutions

    to

    the

    continuum

    equations can

    be

    obtained analytically.

    While these are

    not always of

    direct technical

    interest,

    they often

    suggest

    phenomena

    or techniques

    which

    do have

    direct

    bearing on problems

    of

    interest. Experiments

    in

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    -3-

    gas

    dynamics can be useful. Without a model for

    comparison

    or

    scaling,

    however, one is limited

    to

    understanding

    only

    the

    particular

    geometry

    and scale of

    the

    experiment.

    The

    ability to infer

    is

    lost.

    While

    these

    points seem obvious

    for

    gas dynamics,

    they

    nevertheless

    should be

    discussed

    and understood for the

    analogous situation

    of two-

    phase flow mechanics.

    For a

    particular

    flow with ,nly

    a

    few

    particles

    which

    interact

    only slightly,

    it is

    best (and

    perhaps even

    necessary) to

    describe

    them

    molecularly ,

    that is, by

    predicting

    the

    trajectories of

    each one. If many particles are involved, it is

    better

    to

    use a

    continuum

    description.

    As in

    gas

    dynamics, both descriptions have their

    place.

    Furthermore,

    it

    is

    often

    instructive to try

    to

    ascertain

    what

    one model implies

    about

    the

    other,

    as in using the Boltzmann

    description

    of

    a

    gas

    to get

    continuum properties.

    The

    analogy

    is apt for

    a continuum description

    of

    two-phase

    flows. This paper will review the

    connection

    with the

    exact, or

    microscopic description

    through the

    application

    of

    an

    averaging process

    to the

    continuum mechanical

    equations

    describing

    the exact motion

    of

    each material

    at

    each

    point. If the

    exact

    flows

    were

    known,

    the

    averaged

    equations would be

    completely determined,

    and

    therefore

    unnecessary, since

    desired

    averaged information

    (such

    as the

    average

    concentration of particles) could

    be

    determined without using the

    averaged

    equations.

    The solutions are not

    known,

    nor is it necessary to

    the continuum approach that they

    be

    known.

    The

    resulting averaged

    eluations

    are assumed to describe a

    material

    (the mixture) for which the

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    -4-

    interactions

    must be specified. This specification

    is

    then

    done

    according

    to

    certain

    rules

    which

    are

    reasonable and not

    too

    limiting.

    We

    shall

    discuss these

    rules and their

    implications.

    The forms

    of the resulting

    equations

    are determined by the

    choice

    of

    a list

    of

    variables

    which

    are

    assumed

    to

    influence the

    interactions.

    The

    resulting

    equations have several

    unknown

    coefficients.

    These

    coefficients

    are assumed to be

    determinable

    by experiments.

    For the

    model

    we propose, we

    examine the

    experimental data

    and their

    implications

    on

    the

    coefficients.

    The result

    is, in

    essence, a

    recommendation for

    a model which

    has

    many

    known

    features of

    two-phase

    flow dynamics.

    An

    enlightened

    investigator can

    use the

    model

    to

    make

    predictions

    in

    a

    situation which

    falls

    within

    the

    range of

    assumptions

    made.

    The model

    can also be

    a starting point

    to obtain generalizations

    (such

    as

    the

    inclusion of

    electromagnetic effects).

    As with

    all models,

    it

    should never

    be

    used blindly, but

    with caution and

    careful

    examination

    of the

    results and

    implications.

    Historically,

    geophysical

    flows

    involving

    sediment

    and

    clouds were

    among the

    first two-phase

    flows observed from

    a scientific

    point

    of

    view. Sediment

    meant

    erosion and loss of

    property, or deposition

    and

    loss

    of navigability.

    Clouds signalled

    possible

    rainfall. The

    amounts

    could

    mean

    drought,

    bountiful

    harvests

    or

    devastating

    floods.

    An

    analytical

    description

    awaited the

    development

    of

    the

    calculus,

    fluid

    mechanics

    and

    partial differential equation

    theory. The

    industrial

    revolution spurred the need

    for

    understanding of all of

    basic science,

    including two phase

    flows, although the

    correlation

    between

    progress and

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    the

    acquisition

    of

    fundamental knowledge

    is not exact.

    For

    example,

    automobiles

    have

    worked

    reasonably

    well

    without

    a detailed knowledge of

    the

    flow

    and

    evaporation of

    fuel droplets; on the

    other

    hand, efficient

    design

    of fluidized beds

    have been reliant on

    the understanding and

    stabilizing effects obtained

    from

    analytical

    models.

    Early work on the

    form taken by beds of

    particles subject to forces

    due to

    flowing fluid (DuBuat 1786,

    Helmholtz

    1888,

    Blasius

    1912

    and

    Exner 1920)

    lead to interesting

    fundamental

    results

    such as the

    stability

    of

    the

    interface between

    two fluids

    and a

    practical

    understanding

    of the

    macroscopic

    properties of

    sedimentation

    and bed

    form

    evolution.

    A more

    microscopic

    look

    (Bagnold 1941)

    dealt

    with

    the

    mechanics

    of the

    interactions between

    the

    particles

    and

    the

    fluid, and

    the particles

    and

    the

    bed. A

    recent

    perspective

    is

    given

    by

    Engelund

    and Freds~e

    (1982).

    Developments in

    cloud physics occured in physical

    chemistry

    of

    nucleation and formation.

    The

    need

    for

    detailed

    mechanical

    considerations was low

    due to

    the

    fact that

    the

    vapor,

    nucleation sites

    and the

    formed droplets

    all

    flow with the surrounding air

    (until

    raindrops

    form).

    Porous

    medium

    theory, a two phase flow where

    the solid

    phase does

    not

    move

    appreciably,

    developed with some

    different concerns (Darcy

    1856), but Blot

    (1955) was

    instrumental

    in putting

    the empirical

    knowledge

    on

    a sound continuum

    basis. The

    desire

    to

    extract

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    -6-

    hydrocarbons

    from

    deep inside the earth's crust has given

    a

    great

    impetus to

    the

    study

    of

    flow in porous media.

    See Scheidegger's (1974)

    book for a discussion of porous

    bed modeling concerns.

    The next important milestone

    in

    the

    development of two-phase flow

    continuum

    mechanics theory was the development and use of equations of

    dusty gases

    in

    the

    1950's.

    Models for dusty gases are summarized

    by

    Marble (1970).

    Chemical processing in fluidized beds gave an urgency to the

    development

    of the theory of particle-fluid systems.

    Early theoretical

    papers

    include those

    of Jackson

    (1963), Murray (1965a,b),

    and Anderson

    and Jackson

    (1967, 1968).

    The flow regime

    involved in fluidization is

    one

    of the most

    difficult for particle-fluid flows. The

    particle

    concentrations are high,

    the dispersed phase

    is

    relatively

    dense,

    the

    dispersed

    phase

    undergoes

    a

    random

    micromotion, and

    often

    is is

    desirable to

    have chemical reactions

    occur in the

    flow.

    In

    the

    early 1960's

    the

    emergence

    of commercial atomic

    energy

    spurred

    the study

    of flows of steam and

    water.

    The

    work

    of Zuber (1964)

    was a

    pioneering landmark.

    Fluid-fluid

    flows have a difficulty

    not

    encountered in particle-fluid flows, namely that the shape

    of the

    dispersed-phase can change, resulting in

    changing interfacial

    area

    and

    consequent interactions between the fluids.

    In

    spite

    of much progress

    (Lahey & Moody

    1977),

    two phase flow studies

    in nuclear

    reactors are

    still

    a

    concern.

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    -7-

    The parallel development

    of

    mixture

    theory

    had some

    small

    influence

    on

    the

    progress

    of

    two-phase flows. Indeed,

    the

    concept

    of

    interpenetrating

    continuum

    is

    natural

    in

    mixtures where the

    dispersion

    occurs on the

    molecular level.

    The development

    of

    the

    ideas of

    diffusion by

    Fick

    (1855),

    the

    thermodynamic

    concepts in

    mixtures by

    Duhem (1893),

    Meixner (1943),

    Prigogine

    and

    Mazur (1951)

    lead naturally

    to the theory

    of mixtures

    expounded by

    Truesdell and Toupin

    (1960).

    The

    theory

    of

    mixtures,

    as applied to

    the specific

    mixtures

    where

    the two

    constituents remain

    unmixed,

    is

    the

    basis of the present

    work, and

    (whether

    explicitly

    recognized or not)

    much of the more specific

    previous

    work. Kenyon

    (1976)

    applies

    the

    mixture theory

    to multiphase

    flows. See

    also the

    review

    by

    Bedford and

    Drumheller (1982).

    By

    the

    1960's enough of the common

    features of the

    diverse two-

    phase flows

    were

    evident. Several

    influential books

    of a general nature

    appeared, including

    Fluid

    Dynamics of Multiphase

    Systems by Soo (1967),

    One-dimensional

    Two-Phase

    Flow, by Wallis (1969),

    and Flowin

    Gas-Solid

    Susensions,

    by

    Boothrcyd (1971).

    Wallis' approach

    was

    strongly

    influenced by

    gas-liquid

    flows,

    and

    dealt

    with

    the basic concept

    of

    interpenetrability by

    considering

    cross-sectionally

    averaged

    equations,

    and

    introduced

    constitutive

    assumption

    by

    quoting appropriate

    experiments. Soo's work

    was largely

    based on

    particle-fluid

    flows. He

    assumed

    interpenetrability from

    the

    start,

    and

    included

    forces

    in

    the

    particular momentum

    equation known

    from experiments or

    inferred

    from

    calculations.

    Boothroyd was

    interested

    in

    particle-gas flows,

    and

    contributed ideas on

    turbulence

    and

    drag reduction.

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    -8-

    A different, but

    somewhat related approach

    to the problem of

    a

    mechanical description of two-phase flows

    uses the

    single-particle or

    several interacting particle

    flow

    fields, along

    with

    an averaging

    approach

    to yield rheological

    or

    transport properties.

    The

    celebrated

    result

    in this area is the

    effective

    viscosity result due to

    Einstein

    (1906),

    which shows

    that in

    slow

    flow the

    mixture behaves like a fluid

    5

    with viscosity

    increased by a factor of 1

    +

    ,

    where a

    is

    the

    2

    volumetric concentration

    of

    particles. An approach outlined

    by

    Brinkman

    (1947)

    has been

    influential.

    The

    philosophical roots of

    this

    approach

    are elegantly

    discussed

    in the

    book LowReynolds Number H drod

    namics,

    by Happel and Brenner (1965).

    The idea

    is to

    use solutions of

    the flow

    equations in

    special

    cases (such as

    Stoke's

    flow around an

    array of

    spheres) to infer

    information about the flow

    (such

    as the

    total force on

    the

    particulate

    phase).

    Several aspects

    of this

    work have been

    discussed

    in

    this Review; see the

    papers

    by

    Brenner

    (1970),

    Batchelor

    (1974), Herczynski

    and

    Pienkowska

    (1980),

    Leal (1980) and Russel

    (1981).

    Several authors (Bedford

    & Drumheller

    1978,

    Drumheller

    & Bedford

    1980) have

    pursured a variational approach to two-phase

    flows,

    generalizing the work of

    Biot

    (1977).

    The variational

    formulation

    starts with

    Hamilton's principle,

    given

    by

    t

    I

    t

    2

    ft (T-V)dt

    f2

    6Wdt

    =0

    t6d

    0

    where

    6 represents the variation

    over an

    appropriate

    space

    of

    functions,

    T

    and

    V

    are

    the

    kinetic

    and

    potential energies,

    6W

    is

    the virtual work and

    t

    1

    and t

    2

    are

    two arbitrary

    times. A

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    -9-

    variational formulation has

    an

    advantage

    in

    that if it

    is desired

    to

    include

    a

    certain effect

    (for

    example,

    the

    virtual

    work), that

    effect

    would

    be included

    consistently in the

    mass,

    momentum, and

    kinetic energy

    equations.

    A

    more concrete

    and immediate

    advantage is

    in

    formulating

    numerical techniques, and

    specifically, finite element techniques,

    where

    variational formultion

    eases the

    translation of the

    partial

    differential

    equations into discrete

    equations.

    In

    order

    to use

    a variational formulation,

    it is

    necessary to

    define

    the

    variation 6,

    the

    kinetic

    and

    potential energies T

    and

    V

    and the

    virtual work 6w.

    Constraints must

    be

    included with

    Lagrange

    multipliers. Bedford

    & Drumheller (1982)

    note that

    Hamilton's

    principle

    is

    usually

    formulated with a

    control mass , that is, for

    material

    volumes. The

    problem

    of

    having

    two materials

    moving

    at

    different

    velocities

    is

    dealt with by assuming

    a control volume which

    coincides

    with

    a

    rigid

    surface

    through

    which no material of either

    phase passes.

    They use the technique to

    show how

    the

    effect

    of

    oscillations in

    bubble

    diameter

    can

    be included by

    including

    the

    kinetic energy of the

    liquid due to

    a change in

    bubble

    diameter. They similarly

    include

    virtual

    mass by arguing

    that relative

    accelerations

    increase

    the kinetic

    energy.

    A conceptual

    difficulty with the

    approach

    is

    that

    the

    user must

    decide

    which

    fluctuations

    contribute to the

    total

    kinetic

    energy,

    and

    which

    contribute

    to

    virtual work.

    For

    example, viscous drag is

    due

    to

    fluctuations of

    the

    fluid

    velocity

    near a

    particle,but

    is

    included

    as

    a

    virtual work

    term. A

    rule

    of

    thumb might be

    to consider

    whether the

    energy is recover-ible

    or not.

    Virtual work

    is

    associated with

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    unrecoverable

    energy,

    kinetic

    and

    potential

    energy

    with recoverable

    energy.

    Variational

    formulations

    (in general)

    do not

    mention

    the effect

    of

    Reynolds stresses, which

    are one

    manifestation

    of

    fluctuations.

    We

    conclude

    that

    while

    variational

    formulations

    are

    useful,

    it is

    not

    always

    straightforward

    to

    formulate

    them.

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    EQUATIONS OF MOTION

    We start

    by

    assuming

    that each material

    involved can

    be

    described

    as

    a continuum, governed

    by the

    partial differential equations of

    continuum mechanics. The materials

    are separated by

    an

    interface, which

    we

    assume

    to be a

    surface. At

    the

    interface,

    jump conditions

    express

    the conditions of conservation of mass and momentum.

    The equations of motion

    for

    each phase are (Truesdell

    and

    Toupin

    1960)

    (1)

    conservation

    of mass

    ap

    +

    V-PV

    = 0

    (1)

    at

    (2) conservation of linear momentum

    aPV +

    V-pvv =

    V.T

    + pf

    (2)

    at

    valid in the interior of each phase. Here P denotes

    the

    density, w

    the

    velocity, T

    the

    stress tensor, and f

    the

    body force density.

    Conservation of angular momentum

    becomes

    T = Tt, where t

    denotes

    the

    transpose. At

    the interface, the jump

    conditions

    are

    (1) jump

    condition

    for

    mass

    [[P(v - v.) 'n]] =

    0 (3)

    1

    (2) jump condition

    for

    momentum

    [[Pv(v -

    v )n-

    T'n]]

    = aKn

    . (4)

    Here [[

    ]

    denotes

    the

    jump across the interface, v

    i

    is that

    velocity

    of the

    interface,

    a is the surface tension, assumed to be a

    constant, K is the

    mean curvature

    of the interface, and n is the

    unit normal (Aris 1962). We shall assume

    that

    n points

    out oF

    phase

    k, and that the jump between f in phase k

    and

    f in

    phase

    I is

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    k

    defined by

    ([f]] = f _

    f , where

    a

    superscript

    k denotes

    the

    limiting value from

    the

    phase

    k side.

    As

    a

    sign

    convention for the

    curvature,

    we

    assume

    that

    K

    is

    positive (concave)

    toward

    -n.

    The

    mass

    of

    the interface

    has been

    neglected,

    and

    the surface stresses

    have

    been assumed

    to be

    in

    the form of

    classic

    surface

    tension.

    We do not

    discuss any

    thermodynamic

    relations in this

    paper.

    Thermodynamic

    considerations are

    important for

    many

    multiphase flows.

    Our discussion focuses

    on

    the mechanics of two-phase

    flows, hence we

    elect to

    forego a discussion of

    thermodynamics for

    the sake

    of

    simplicity.

    Constitutive

    equations

    must be

    supplied

    to

    describe the

    behavior

    of

    each

    material

    incolved. For

    example, if one

    material is

    an

    incompressible liquid,

    then

    specifying

    the value

    of

    p,

    and

    assuming

    T =

    -pI + p(Vv

    +

    (Vv)

    determines the nature of the

    behavior of the

    fluid in

    that

    phase.

    Similar considerations

    are

    possible for solid

    particles or a

    gas.

    The resulting

    differential

    equations,

    along with

    the

    jump

    conditions,

    provide

    a fundamental description

    of the

    detailed

    or exact

    flow.

    Usually,

    however, the

    details of

    the

    flow

    are

    not required.

    For

    most

    purposes of equipment or

    process

    design, averaged, or

    macroscopic

    flow information

    is

    sufficient.

    Fluctuations,

    or

    details in the flow

    must be

    resolved only to

    the extent that

    they effect

    the mean flow

    (like

    the Reynolds stresses

    effect the

    mean flow in

    a turbulent

    flow).

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    Averaging

    In order

    to

    obtain

    equations which

    do not

    contain

    the details

    of

    the

    flow,

    it

    has

    become customary to

    apply some sort of averaging

    process.

    It

    is not essential

    to do

    so; indeed,

    some researchers prefer

    to postulate macroscopic equations without reference

    to any microscopic

    equations.

    Certainly, the necessary

    terms in

    the

    macroscopic equations

    can

    be

    deduced

    without using

    an

    averaging process.

    One advantage

    of

    a

    postulational

    approach

    is

    obvious

    - not having

    to deal with

    the

    worries

    of

    the averaging process. The

    advantages of

    averaging are

    less obvious.

    First, the various

    terms appearing

    in the macroscopic equations are

    shown

    to arise

    from

    appropriate

    microscopic

    considerations. For

    example, stress terms arise from

    microscopic stresses (pressure, for

    example) and also from

    velocity fluctuations

    (Reynolds stresses).

    Knowledge of

    this fact does

    give a modicum of insight into

    the

    formulation of

    constitutive equations. If

    a

    term

    appeared

    in

    the

    averaging

    which

    was not

    expected in the postulational

    approach,

    then

    it

    would be obligatory

    to

    include

    it

    in the

    postulated

    model,

    or else

    explain why it is

    superfluous.

    An

    additional advantage

    of

    averaging is that

    the

    resulting

    macroscopic

    variables are related to microscopic variables. If

    the

    microscopic problem can

    be

    solved for

    some special situation, the

    solution

    can then

    be used to get

    values of the

    macroscopic variables.

    This cannot replace the

    need

    to

    postulate

    constitutive equations, but

    is

    can

    give

    insights

    into the types

    of terms expected

    to

    be

    important in

    the

    constitutive

    relations.

    The philosophy

    taken here is that

    whatever

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    information

    can

    be gained from

    averaging is

    worthwhile,

    and therefore we

    present a generic

    averaging

    method,

    and

    its

    results.

    If the reader

    fee-s

    that

    averaging is

    unnecessary,

    he

    can

    skip

    this

    section, and

    assume

    the equations

    (40) -

    (43) have

    been

    postulated,

    along with

    the

    interpretations given

    at the

    end

    of

    this Section.

    Averaging the

    equations

    of motion is

    suggested

    by the

    averaging

    approach

    to turbulence

    (see

    Hinze 1959).

    Time

    and

    space

    averages

    were

    the

    first

    to appear (Frankl

    1953, Teletov

    1958).

    These

    averages

    have

    been refined

    by weighting,

    by multiple

    application,

    and

    by

    judicious

    choice of

    averaging

    region.

    The

    highlights can

    be found

    in the

    work

    of

    Anderson

    and Jackson (1967),

    Vernier

    and Delhaye (1968),

    Drew

    (1971),

    Whitaker (1973),

    Ishii

    (1975),

    Nigmatulin (1979),

    and

    Gough (1980).

    Statistical

    averages

    are most

    convenient for

    the rheology

    work,

    see

    Batchelor

    (1974) for

    a

    summary.

    The application

    of statistical averages

    to the

    equations of

    motion is

    straightforward;

    the paper

    of

    Buyevich

    and

    Shchelchkova

    (1978)

    summarizes

    the approach

    nicely.

    Let

    ( > denote

    an averaging process

    so

    that if

    f(z,t)

    is

    an

    exact microscopic

    field, then

    (x,t)

    is

    the

    corresponding

    averaged

    field.

    We shall specify

    shortly the

    requirements

    which

    an average

    should possess,

    however,

    for now

    we merely suggest

    that it

    should be

    smoothing

    in

    the sense that

    no

    details

    appear

    in the

    averaged

    variables. Some

    examples

    of

    commonly

    used

    averages in multiphase

    flow

    are

    the time

    average:

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    2(X,t

    )

    212

    L 3+

    21/

    f(x',t)dxdx~dxl'

    (6)

    L

    x

    -

    1

    L x

    2 -

    -

    L x-

    L

    1

    2 2 2

    3

    2

    where

    L

    is an

    averaging

    length

    scale;

    a weighted

    space

    average

    3

    (x,t) =

    ff

    g(x-x )f(x ,t)dx

    (7)

    3

    R

    where

    ff g(s)ds

    =

    1,

    and various

    combinations of

    averages

    and/or

    3

    specific types

    of

    weightings.

    Also

    mentioned in the

    literature

    are

    ensemble

    averages:

    N

    (x,t)

    =

    f

    (x,t)

    (8)

    n=1

    n

    or

    5(x,t)

    = f

    f(x,t;w)dU(w)

    (9)

    where

    fn (x,t)

    or

    f(x,t;w)

    denote

    a realization

    of the

    quantity f

    over

    a set of

    possible

    equivalent

    realizations

    9.

    One

    way

    in

    which

    randomness

    might

    be

    introduced in

    a particular

    flow

    situation

    is

    by

    allowing the

    particles to

    have

    random

    initial

    positions.

    The averaging

    process is

    assumed to

    satisfy

    =

    +

    (10)

    =

    11)

    = c

    af

    < -

    (12)

    at,-

    at

    af a

    =

    (13)

    ax.

    x.

    1

    1

    The first

    three

    of these

    relations

    are

    called

    Reynolds rules,

    the

    fourth is

    called Liebnitz'

    rule, and

    the

    fifth is

    called Gauss'

    rule.

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    Some difficulty is

    encountered when trying

    to apply

    the

    average

    to

    the equations

    of motion

    for each phase.

    In

    order

    to do

    this, we

    introduce

    the

    phase

    function

    Xk(x,t) which

    is

    defined

    to

    be

    1 if x is in

    phase

    k at time t

    Xk(x~t)

    =

    1-(14)

    0

    otherwise

    .

    We shall deal with Xk as a generalized function, in particular in

    regard

    to differentiating

    it. Recall that a derivative of a generalized

    function can

    be

    defined in terms of a set of test functions , which

    axk

    are "sufficiently smooth and

    have

    compact support. Then and

    a

    Xk

    axk

    are

    defined

    by

    i

    aXk

    f

    ax (x,t)O(x,t)dxdt =

    - Xk(2,t) 21

    (m,t)dzdt ,

    (15)

    RxR

    a

    R3XR

    axk

    f

    xi

    (x,t)*(x,t)dxdt = - x

    X

    (x,t)dzdt (16)

    R3xR xi

    R

    3xR

    k

    ax.

    (xtdt(6

    It

    can

    be

    shown

    that

    axk

    a-+

    viVX

    0

    (17)

    a

    i

    k=

    in the sense of generalized functions To see this, consider

    ax

    k

    R + Vi'Vxk )Odt

    R3XR

    f X

    xk Lt

    v.vdxdt

    R

    3xR

    ka

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    a+

    Ov)dx)dt

    f

    (dJ

    - .v

    -

    dt

    R Wt)

    dx)dt

    dt

    k

    -

    x 0_---o8)

    since

    has compact support

    in t. Here

    Rk(t) is the

    region

    occupied

    by phase k at

    time t, and

    we

    assume

    that V

    i

    is

    extended

    smoothly through phase k

    (in

    order

    that the

    second

    line makes sense).

    If f

    is

    smooth except at

    S,

    then

    fVXk

    is

    defined

    via

    f R3RfVXkdxdt

    =

    - fR

    xkV(fo)dzdt

    = f c fR

    k

    W V(fo)dxdt

    = f

    fs

    nk

    f

    dSdt

    , (19)

    where n

    k

    is the

    unit normal

    exterior to phase k,

    and fk

    denotes

    the

    limiting value of f

    on the

    phase-k

    side

    of S.

    It

    is also clear

    that Vk is zero, except at the

    interface.

    Equation

    (19)

    describes

    the

    behavior

    of VX

    k

    at the

    interface.

    Note

    that

    it

    behaves

    as a "delta-function", picking

    out the

    interface

    S,

    and has the

    direction

    of the

    normal interior

    to phase

    k.

    This

    motivates

    writing

    ax

    VX

    k

    (20)

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    where aX/an

    is

    a

    scalar

    ,alued

    generalized function

    which

    has

    the

    property that

    fR3x

    R

    3n

    x,t)] x,t)dxdt

    =

    0_

    f

    (x,t)dSdt 21)

    The quantity

    ax/an then picks

    out

    the

    interface

    S.

    We

    write

    ax =

    s

    (22)

    where

    s

    is

    the

    average interfacial

    area

    per unit volume.

    Averaged

    Equations

    In order

    to

    derive

    averaged

    equations for the

    motion

    of each

    phase,

    we multiply the

    equation

    of conservation of

    mass valid in

    phase

    k (1)

    by

    Xk

    and average. Noting

    that

    aP

    a axk

    a

    =

    -

    +

    *

    iV.5xk

    (23)

    and

    X

    k

    V.pv =

    V.xkpv - PvVxk

    ,

    (24)

    we have

    t

    +

    V'

    =

    25)

    Similar considerations

    for

    the

    momentum equations

    yield

    a

    W-

    +

    . = V.

    +

    (26)

    k

    +

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    are

    the interfacial source terms.

    As

    noted,

    VXk

    picks out

    the

    interface, and

    causes

    discontinuous quantities

    multiplying

    it to

    be

    evalued

    on the phase-k

    side of

    the

    interface.

    The

    jump conditions are derived

    by

    multiplying equations

    (2.3)

    and

    (2.4)

    by ax/an,

    and recognizing

    that

    n = -2

    .

    We obtain

    2 2

    I

    c[p(vv.Hkvxk>

    =

    I

    rk =

    0

    (29)

    k=1 k=1

    2

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    There

    are two types

    of

    averaged

    variables which

    are

    useful

    in two-

    phase mechanics, namely the

    phasic, or Xk-weighted

    average, and the

    mass-weighted

    average.

    Which is

    appropriate is suggested by

    the

    appearance of

    the

    quantity

    in

    the

    equation of motion.

    The phasic

    average of the

    variable

    0

    is defined

    by

    k

    =

    /ak (34)

    and

    the mass weighted

    average of the

    variable P

    is

    defined

    by

    A

    4k =

    /akpk

    (35)

    It

    is convenient

    to write

    the stresses T

    k

    in

    terms

    of

    pressures

    plus extra

    stresses. Thus,

    T

    k

    =

    -pkI tk

    (36)

    It is

    expected that

    readers familiar

    with

    fluid dynamical concepts

    are

    familiar with the

    concept of

    pressure in fluids; in

    this

    case, Pk

    can

    be

    thought

    of

    as the

    average

    of

    the

    microscopic pressure.

    If one

    of

    the

    phases

    consists of solid

    particles, the

    concept

    is

    less

    familiar. In

    this

    case, the

    microscopic stress (involving

    small

    elastic deformations,

    for

    example)

    is

    thought of

    being made

    up of a

    spherical part (acting

    -qually in all

    directions)

    plus

    an

    extra stress.

    The

    spherical

    part,

    when

    averaged,

    yields

    the

    pressure Pk

    in equation (36).

    It

    has

    further become

    customary to

    separate various parts of the

    interfacial momentum

    transfer

    term.

    This

    is

    done by defining the

    interfacial velocity of

    the

    k

    th

    phase by

    k.

    r

    kk,= ,

    (37)

    and the interfacial

    pressure on

    the

    kth phase

    by

    Pk,iIVak

    12

    , 7

    k

    (38)

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    Equation

    (38) is the

    dot

    product

    of

    Va

    k

    of the standard

    definition

    (Ishii

    1975)

    of the

    interfacial

    pressure. The standard definition

    uses

    three equations

    to

    define one scalar quantity,

    and cannot

    be a

    generally

    valid

    definition. Here the remaining

    part

    of

    the contribution of

    the

    pressure

    at the interface is

    lumped

    with

    the viscous

    stress

    contribution

    at the interface, and is treated through

    the

    use

    of

    a

    constitutive

    equation.

    Thus, we write

    Kk =

    i

    - Pk,i k k

    4

    d (39

    d

    k k

    VXk

    -

    tVXk>

    is

    referred

    to

    as

    the

    interfacial

    force

    density,

    although

    it does not

    contain

    the effect of the

    average

    force on the interface due to the

    average interfacial

    pressure. The

    term

    -pk,i

    Vk,

    which does contain

    the

    force

    due to the

    average

    interfacial

    pressure,

    is sometimes referred to as the buoyant force.

    The

    reason for this terminology

    is, of

    course, that the buoyant force on

    an

    object

    is due to the distribution

    of

    the pressure

    of

    the surrounding

    fluid

    on

    its

    boundary.

    With

    equations (31) and (34) - (39), the

    equations

    of motion

    (25)

    and (26) become

    a

    +

    Vkkk

    k

    (40)

    aap

    -

    v

    k-

    -a

    p

    +*

    (= +a

    at k

    kvvk

    k kVPk k (t

    + k

    +

    kk,i +

    (pk,i - k)V

    k

    d

    (41)

    + q

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    The jump conditions

    (29) and (30) are

    2

    Z

    r

    k

    =

    o

    42)

    k=1

    2

    2 [

    r ~~ +p

    1

    d

    =.

    43)

    k1 k k,i +pk,i

    k

    +

    PO Mm(3

    =

    1

    Pkikm

    Adequate models for

    compressibility and phase

    change require

    consideration

    of

    thermodynamic processes.

    These are beyond the scope

    of

    this paper;

    therefore we shall

    restrict

    our

    attention

    to

    incompressible

    materials

    where

    no phase

    change occurs.

    Thus we assume that

    k

    =

    constant

    (44)

    and

    r = 0

    .

    (45)

    k

    In

    order to

    simplify

    the

    notation, we shall

    drop all

    symbols

    denoting averaging.

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    CONSTITUTIVE

    EQUATIONS

    In

    order to

    have a useable

    model

    for

    an

    ordinary

    single-phase

    material, relations

    must

    be

    given

    which

    specify

    how the

    material

    interacts

    with itself. These

    relations

    specify how the

    material

    transmits forces from

    one part

    of the body

    to

    another. For single-phase

    materials

    a relation between

    the

    stress and

    other field

    variables is

    usually required.

    For

    two-phase

    materials, where we

    desire to

    track

    both phases,

    we must

    specify

    the stresses for both

    phases and

    the way in

    which the

    materials

    interact across the

    interface. Thus, we require

    constitutive

    equations

    for the

    stresses (T

    +

    0

    k), the

    interfacial

    force

    density

    d, and

    the pressure

    differences

    pk

    - Pk,i'

    consistent

    with

    the equations

    of

    motion and the

    jump conditions.

    The

    fundamental process

    consists

    of proposing

    forms for the

    necessary

    terms

    within the

    framework of the

    principles

    of constitutive

    equations, finding

    solutions of

    the

    resulting

    equations,

    and

    verifying

    against

    experiments. The

    process can

    be

    iterative,

    with

    some

    experiment

    indicating that

    a

    more involved

    form is needed

    for

    some

    constituted

    variable. The

    ideal end result

    of

    the process is

    a set

    of equations

    which

    could be used to

    predict the

    behavior of the

    two-phase

    flow, for

    example with

    a computer code.

    With

    the equations

    should come

    a set of

    conditions

    for the

    validity of

    the values of

    the constants and

    other

    functions

    used

    in the

    constitutive

    equations.

    The stresses

    Tk +

    ak,

    the

    interfacial

    force density

    d and the

    pressure differences

    p- pki

    are assumed to

    be

    functions of a

    a

    k/at, Vak,

    Vk,

    VVk,

    3Vk/at

    ...

    where

    ...

    represents

    the

    material

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    properties, such

    as

    the

    viscosities

    and

    densities

    of the

    two materials,

    and

    other

    geometric

    parameters such

    as

    the

    average particle

    size, or the

    interfacial

    area density.

    For

    concreteness, we shall

    refer

    to

    phase one as the

    particulate,

    or

    dispersed

    phase and include in that

    description solid

    particles,

    droplets,

    or

    bubbles.

    Phase two is then the

    continuous,

    or carrier

    phase,

    and can be

    liquid

    or

    gas. We

    shall denote

    =

    a

    (46)

    so that

    1-a a

    (47)

    2

    It

    is evident

    that both

    a and 1-a

    need not

    be

    included

    as

    independent

    variables

    in

    forming

    constitutive

    equations.

    Drew and

    Lahey

    (1979)

    consider the general

    process of constructing

    constitutive

    equations. The

    principle of consequence

    is

    that of

    material

    frame indifference,

    or objectivity. This

    principle requires

    that

    constitutive

    equations be appropriately

    invariant

    under a change of

    reference

    frame. The motivation

    behind this

    assumption is

    that we

    expect the

    way in which

    a

    two-phase

    material distributes

    forces to be

    independent of the

    coordinate system

    used

    to

    express

    it.

    Those who

    doubt this

    principle

    often argue that the

    momentum equation is

    not frame

    indifferent,

    needing

    Coriolis forces

    and

    centrifugal forces to

    correct

    it

    in

    non-inertial frames.

    This argument is

    incorrect, since the

    appropriate

    formulation of the

    momentum

    equation deals not

    with

    "acceleration"

    but

    with

    "acceleration

    relative

    to

    an

    inertial

    frame .

    When formulated

    with the

    "acceleration

    relative to an

    inertial

    frame ,

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    the

    momentum

    equations

    are

    frame

    indifferent

    (Truesdell

    1977).

    This

    introduces

    an

    interesting

    question:

    Can

    the

    mixture

    know

    whether

    or

    not

    it is being

    referred

    to

    a inertial

    frame?

    That

    is, can

    the

    interfacial

    force

    and

    the

    Reynolds

    stresses

    depend

    on the

    reference

    frame?

    The

    principle

    of

    material

    frame

    indifference,

    as used

    here,

    claims

    that

    they

    cannot.

    Others

    claim

    that

    they

    must (Ryskin

    and Rallison

    1981).

    The

    principle

    of

    objectivity

    is

    now

    examined

    (Drew

    &

    Lahey

    1979).

    The

    approach

    we take

    deals

    with

    coordinate

    changes,

    but is equivalent

    to

    more abstract

    approaches

    (Truesdell

    1977).

    Consider

    a

    coordinate

    change

    from

    system

    z

    to

    system z

    ,

    given

    by

    =

    Q(t).z

    +

    b(t) ,

    (48)

    where

    Q(t) is

    an

    orthonormal

    tensor

    and

    b is

    a

    vector.

    A scalar

    is

    objective

    if its

    value is the

    same

    in

    both the

    starred

    and

    unstarred

    systems,

    that

    is,

    if

    0

    (X

    ,t) =

    xt) .

    (49)

    A

    vector

    is

    objective

    if it

    transforms

    coordinates

    correctly,

    that

    is,

    if

    v

    = Qv

    .

    (50)

    A tensor

    is

    objective

    if

    *

    t

    T

    = Q-TQ

    51)

    The

    scalar

    a

    is objective;

    however

    Da/3t

    is

    not.

    It

    is

    straightforward

    to

    show

    that

    D /Dt

    =

    a/3t +

    Vk

    -Va

    is

    objective.

    Let

    us next

    consider

    objective

    vectors.

    The

    volume

    fraction

    gradient

    Va is

    objective.

    If

    we

    differentiate

    (48)

    with respect to

    t

    following

    a

    materitl

    particle

    of

    phase

    k,

    we see

    that

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    =

    Q(t)k

    +

    )

    (52)

    Hence

    velocities

    are

    not objective. This

    is obvious

    physically, since

    the

    velocity

    of

    a point

    depends

    on

    the

    coordinate system.

    If

    we

    take

    equation (2.53),

    for k 1

    and

    2, and subtract, we

    have

    V

    1

    -

    2

    =

    Q (vl

    - 7

    2

    )

    (53)

    Thus, the relative

    velocity between the phases is objective.

    For acclerations,

    differentiating

    (52) following

    a material

    particle

    of

    phase

    j yields

    Dv

    .v

    QO

    + Qx

    + Qv.

    + Qv

    +

    b .

    (54)

    Dt Dt

    k

    Thus, subtracting

    the

    value

    for j =

    1, k = 1 from

    the value for

    j = 2, k =

    I yields the

    result that

    DI

    2

    Dv2

    12

    t

    Dt

    is objective.

    The

    list

    of tensors which

    we consider

    is motivated

    by the

    desire to

    model two-phase

    flows. Thus, velocity

    gradients

    (expressing rate

    of

    deformation)

    are included,

    but displacement gradients

    (expressing

    deformation)

    are not.

    It is well known

    (Truesdell and Toupin

    1960)

    that

    =

    -

    (V +

    (VVk) )

    (56)

    Dk,b

    2 k

    +

    are objective.

    We

    further note that

    V(,

    I

    -

    v

    is

    an

    objective

    tensor.

    Thus,

    the

    problem

    of

    forming

    constitutive equations

    reduces

    to

    expressing

    Tk +

    0

    k' k - Pk,i'

    (57)

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    in

    terms

    of

    a,

    Dka/Dt,

    Va,

    v - v

    2

    , D

    2

    vI/Dt

    -

    D

    1

    v

    2

    /Dt,

    Dib, D

    2

    ,bV(VI - v

    2

    )

    . (58)

    We

    shall assume that

    the materials are

    isotropic.

    This

    means

    that

    no

    direction is preferred

    in either

    material or in the

    way they

    interact. Note that

    a

    particular flow may occur

    in such a

    way that

    a

    preferred

    direction (down,

    for example)

    might

    emerge.

    In

    that case, the

    flow is

    anisotropic, but the materials

    and

    the mixture

    are isotropic.

    If

    f

    is

    a

    scalar,

    then

    f

    can depend

    on the

    scalars and

    the

    scalar

    invariants

    formed from the vectors and

    tensors in

    the list

    (58). The length of

    a vector is

    a

    scalar

    invariant,

    as

    are

    the

    trace,

    determinant

    and Euclidean

    norm of

    a tensor.

    If

    F is a

    vector, then

    F

    must be

    linear in all

    the

    vector

    in

    the

    list

    (58),

    plus any

    vectors

    which can be

    formed

    in

    an invariant way

    from the

    vectors and

    tensors in that list.

    Thus

    F

    =

    a. V.

    (59)

    1

    1

    where

    V

    i

    are the

    objective

    vectors

    so

    formed.

    Each scalar

    coefficient

    a

    i

    can be

    a function of all

    the scalars

    and scalar invariants.

    If F

    is a second

    order tensor, then

    F = E B .

    (60)

    j J

    where

    Y. are the

    objective tensors which can be

    formed

    from the

    list

    I

    (58).

    The

    scalars B. can be

    functions of all the

    scalars. If F

    is

    symmetric,

    we

    need only

    consider

    symmetric

    Y..

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    The general

    approach

    (Drew and Lahey 1979)

    gives a problem

    too big

    to

    be

    practical

    or

    meaningful.

    Thus,

    we shall

    consider

    here

    forms

    for

    the

    stresses,

    etc.,

    which

    we expect

    to

    be

    important in two-phase

    flows.

    Obviously,

    we shall

    have

    the constant

    worry that something

    has

    been forgotten; however,

    the alternative

    of

    stopping at

    this point,

    awaiting evaluation of

    over two-thousand scalar

    coefficients

    seems

    less

    attractive.

    Stresses

    Let

    us now

    discuss

    specific

    considerations for the specific

    constitutive equations needed.

    Let

    us

    begin with the

    stresses.

    The

    extra

    stress

    (viscous

    or

    elastic) and turbulent stresses are

    combined as

    T

    k

    + a

    k .

    Macroscopically,

    at least in

    the context of this model, one

    sees no

    way

    to

    separate them. Microscopically,

    one

    is

    due

    to

    the actual

    stresses, and the

    other

    is

    due

    to

    velocity fluctuations from the mean.

    In many

    cases

    of

    interest

    the extra

    stress

    is

    smaller than

    the

    turbulent

    stress,

    one

    reason

    being

    that

    any

    appreciable slip between the phases

    generates

    velocity fluctuations,

    which appear in this

    model

    in

    the

    turbulent stresses.

    These fluctuations can

    transport

    momentum.

    The

    conceptual situation is analogous

    to

    that for

    single-phase turbulent

    momentum transport, with

    eddies carrying momentum

    across

    planes

    parallel

    to

    the

    shearing direction

    and

    losing it into

    the

    mean

    flow.

    The

    fluctuations in single-phase

    turbulent flow are

    there because of

    instabilities in the

    laminar shear

    flow;

    in two-phaqe flow

    they also

    come from fluctuations

    generated

    due to

    the flow

    around individual

    particles.

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    Drew and Lahey

    (1981)

    have generated

    a model for

    the

    turbulent

    stresses

    in

    bubbly

    air-water

    flow. The model

    they deduce in

    this

    case

    has the form

    0 =

    2u2 D

    + a I +

    b2(

    I

    -

    V

    )(V -

    v

    2

    )

    61)

    2 2 2,b 2 2 1 -2

    1 2)

    T

    for the

    liquid

    phases. Here v2 is

    the

    eddy viscosity, a

    2

    is an

    22

    induced eddy pressure ,

    and b

    2

    is

    associated

    with

    bubble passages.

    T

    The

    parameters p

    2

    , a2 and b

    2

    depend on a,

    the

    bubble radius

    r,

    the

    relative velocity

    IVl -

    w

    2

    I

    and the

    Euclidean

    norm

    of

    D

    2

    ,b.

    Nigmatulin (1979) uses

    a

    cell

    model, assuming inviscid

    flow around a

    spherical

    particle in

    each

    cell,

    to calculate

    values

    of a

    2

    and b

    2

    .

    He

    obtains

    b =-

    (62)

    2

    2 2

    a2 IV

    - (2

    (63)

    a

    2

    -

    6

    2 1

    2

    He does

    not obtain a term

    involving

    the

    eddy viscosity

    because

    the

    cell

    model

    is unsuited to obtaining

    shear

    flow

    results.

    His results

    are

    valid

    for

    dilute

    flows.

    Other

    effects

    are

    present

    in

    most turbulent

    flows.

    Drew

    and Lahey (1981) used

    mixing lengths to

    evaluate the

    coefficients in

    eq.

    (61).

    The data

    available

    thus far

    (Serizawa 1975)

    allows

    only

    evaluation

    of the ratios of

    various Karman

    constants,

    nonetheless, the

    importance of

    the

    problem

    in

    nuclear

    reactor

    technology

    has spurred the

    acquisition of more

    direct

    data

    in

    special cases

    (Lance

    1981).

    This

    data should

    be

    available shortly, and should allow

    the

    evaluation

    of

    a

    2

    and

    b

    2

    for

    bubbly flows.

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    Evidence (Serizawa 1975) also

    indicates

    that

    a

    =

    O(

    2

    2

    (64)

    and is negligible in dispersed bubbly flows. A model for 0 analogous

    to

    eq.

    (61) is

    a=

    21TDI

    aI+ b v

    - v2)(v1 - v)

    (65)

    1 1,b

    1 1 1

    If the particulate phase follows the fluid phase closely, the quantities

    in

    equations (61) and (65) representing both velocity scales and mixing

    lengths of large eddy processes should be approximately equal. If this

    is

    the

    case,

    then

    T. P1

    T

    P1

    p

    2

    2(66)

    The remaining

    terms in eq.

    (65) arise

    at least in

    part

    due

    to

    the

    motion of the particles through the

    fluid.

    No constraints are placed on

    these coefficients.

    Ishii (1975) argues that for the

    viscous

    fluid phase,

    the

    average

    of the microscopic viscous stress lead to

    T

    =

    2j2

    D

    + P

    b(1-a) EVQ(V - V2)

    + (V

    - V

    2

    )V

    u

    ] (67)

    2 2 2,b

    2

    1-a

    1 72 1 - 2)a

    where P

    2

    is

    the exact

    viscosity

    of the

    fluid, and

    b is called the

    mobility

    of

    phase

    two.

    He argues that

    b(1-a)

    1

    for a near

    zero.

    No experimental evidence

    has

    been offered

    to

    verify

    (67).

    In the case when the

    particulate phase consists

    of

    solid

    particles,

    it is

    usually

    assumed that

    T

    = 0.

    If the particulate phase is

    also

    a

    viscous fluid, then it is sometimes assumed that

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    T

    I

    =

    2P1D1,b

    (68)

    This corresponds

    to

    Ishii's result (see

    eq.

    67))

    with

    b = 0.

    Murray

    (1965a)

    offers

    a

    model

    for a particle-fluid

    flow in which he

    assumes

    that

    the

    particles

    experience a viscous stress with a viscosity

    coefficient

    proportional to the fluid viscosity.

    His

    argument indicates

    that

    the force he is calculating is not a

    stress, but an

    interfacial

    force.

    Pressure Relations

    The pressure differences

    pk

    -

    Pk,i

    are

    discussed

    next.

    First, we

    note that with

    the

    assumption of

    local

    incompressibility of each

    phase,

    we

    must

    constitute

    all but one of P

    1

    1 P

    2

    1 Pl,i

    and P2,i. The

    other

    will then be a

    solution

    of the

    equations

    of

    motion.

    The simplest assumption

    for

    pressure differences,

    is to assume

    none. That is, assume Pk =

    Pk,i

    for

    k = 1,2. This assumes that

    there is instantaneous

    microscopic pressure equilibration which

    will

    be the case if the

    speed of sound

    in

    each phase

    is

    large compared with

    velocities of

    interest.

    In applications

    which do not deal with acoustic

    effects

    or

    bubble expansion/contraction, this assumption is adequate.

    For a

    discussion

    of

    bubble oscillation effects, see

    the

    article

    by van

    Wijngaarden (1972). Cheng

    (1982)

    studies the consequences of several

    modeling assumptions on wave propagation in a

    bubble

    mixture.

    In

    situations where

    surface tension is

    important and no contacts

    occur between

    the

    particles,

    we assume that the

    jump condition

    (4)

    becomes

    1 2

    p -p

    -O K ,

    (69)

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    where K'

    is

    the

    exact curvature

    of the interface.

    Multiplying

    by

    VX1

    and

    averaging

    gives

    (P1,i -

    P2,i

    )V

    a = aK V

    (70)

    where

    K is

    the

    average mean curvature. Since this equation holds

    for

    all

    Va,

    we

    have

    Pl,1

    - P 2,i

    = OK

    .(71)

    If

    the

    surface

    tension

    is

    negligible,

    equation (2.72)

    gives pl,i

    =

    P2,i

    When

    contacts occur between

    particles, these

    considerations

    are not

    always simple. The

    contacts provide mechanisms for causing the average

    pressure at

    the

    interface in one

    phase

    to be

    higher

    than

    the other.

    Consider solid particles

    submerged

    in fluid, with no

    motion, and with

    the

    particles

    under

    a compressive force (supporting

    their own weight, or

    the weight

    of

    an

    object, for example). The resulting

    stress will be

    transmitted from particle to

    particle

    through

    the areas of

    particle-

    particle

    contact.

    Just on

    the

    particle

    side

    of

    the

    interface where

    the

    contact

    occurs,

    the stress

    (pressure) level will

    be

    large. At places

    where

    no

    contact occurs,

    the stress

    will be equal to the pressure in the

    surrounding fluid.

    Under

    normal circumstances,

    the contact areas will

    be

    a

    small fraction of

    the total

    interfacial

    area.

    Thus, the

    approximation pli p

    2

    ,

    p.

    is

    usually valid. In the

    more

    general

    situation, these contacts may be

    intermittent, when the

    particles

    are

    bumping

    together,

    or

    may

    be

    constant,

    as

    when

    the

    particles

    are

    at

    rest. In

    this case, also,

    we

    expect P1,i

    =

    P2,i Pi

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    stuhmiller

    (1977)

    argues

    that

    p

    2

    - P2,i

    =

    P

    2

    IV

    2

    -

    V

    12

    (72)

    where F

    is taken

    to be

    a

    constant. The

    argument

    leading

    to

    (72)

    is

    exactly the

    calculation

    of

    form drag,

    which is

    usually

    part of

    the

    interfacial

    drag.

    It

    is not

    clear

    whether

    using (72)

    and

    a

    drag law

    (79)

    includes

    the

    form

    drag

    consistently.

    We shall

    assume that

    for

    the

    fluid

    phase,

    P

    2

    = pi. To

    allow for

    the

    possibility

    of

    the extra

    stress due to

    contacts,

    in the

    particulate

    phase

    when it

    consists

    of

    solid

    particles,

    we

    shall write

    PI = Pi,i

    + Pc = P2

    + Pc

    (73)

    where pc

    is the

    pressure in

    the

    particles due

    to

    contacts.

    A model

    is

    needed

    for

    PC.

    Several modelers

    (Gough

    1980,

    Kuo

    et

    al.

    1976)

    have

    used

    a model

    with Pc

    = pc(a),

    with Pc

    (a) =

    0

    for

    a

    < ac, where

    ac is

    the

    packing

    concentration

    of

    the

    particles,

    and

    pc (a) rapidly

    increasing

    for

    a

    > a

    .

    This

    further

    suggests

    an "incompressible"

    c

    model,

    with

    Pc

    = 0

    for

    a

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    the

    momentum

    jump

    condition becomes

    Kd

    + V +

    d- p V

    = oK

    Va

    * (75)

    +

    Pli

    M2 - 2,i

    Using

    condition

    (71),

    we

    have

    +d =

    0

    (76)

    1

    2

    Therefore, we need only provide a model for d. K then is determined

    1

    2

    by the jump condition (76).

    The

    interfacial momentum

    transfer

    1

    contains the forces

    on

    the

    particulate

    phase

    due

    to

    viscous

    drag,

    wake and boundary layer

    formation,

    and

    unbalanced

    pressure

    distributions

    leading to

    lift or

    virtual

    mass

    effects, except

    for the

    mean interfacial pressure.

    The

    model which

    we

    discuss here

    should

    contain,

    as much

    as

    possible,

    the

    above forces.

    Indeed, this

    motivates

    the inclusion

    of

    certain

    quantities

    in

    the list

    of

    variables

    (58).

    We postulate

    da

    1

    2

    v

    Kd

    =

    A v

    -

    v)

    +

    A

    2

    3-

    1 2 1

    2

    (T --

    +

    v

    1

    VV

    2

    ) (---

    +

    v

    2

    Vv

    1

    + A3(v

    2

    - v1)D + A(v -

    v)'D

    + A(v -v)V(v

    2

    - )

    32 1 1b

    4(2

    1

    2,b 5(2

    1 2

    + A6

    V - v2).[V(vl - v2)]t

    (77)

    where

    A, - A

    6

    are scalar functions of the invariants.

    The first

    term

    represents the classical drag forces.

    To conform

    with customary useage,

    we

    write

    C

    A 1

    P2

    1

    v1

    - v21

    (78)

    where r

    is

    the

    effective

    particle

    radius,

    and

    CD

    is

    the drag

    coefficient.

    It is

    usually assumed

    that CD

    =

    CD (a,Re), where

    0

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    -35-

    Re

    = 2P

    2

    IV

    - v

    2

    r/p

    2

    is

    the

    particle Reynolds number.

    A

    careful

    study, including extensive comparisons with data,

    is

    given

    by Ishii and

    Zuber (1979).

    Their

    conclusions

    for

    the drag

    coefficient are

    summarized

    in

    Table 1, which

    is adapted from

    their paper.

    The

    combination

    av

    2

    av

    1

    A2[(-

    + V.VV2) - (---l

    +

    V2 VVl)] +

    A

    (V

    - V) -

    v()

    (79)

    2 at

    1

    2

    at

    2 1

    5 2

    1

    *~2

    1

    is

    an

    acceleration

    term.

    Drew,

    Cheng

    and

    Lahey (1979)

    write

    A =a PC

    M(a)

    ,

    (80)

    A

    = A

    2(1-)(a))

    ,

    (81)

    where

    C is

    referred to

    as the

    virtual

    volume. If

    CVM =

    and no

    spatial

    velocity

    gradients are

    present, then (79)

    reduces to the

    classically

    accepted virtual

    mass force.

    It

    is

    less

    easy to

    obtain

    correlations

    for CVM than for

    C

    D

    , since the ratio

    of virtual

    mass

    forces

    to drag

    forces

    is

    of

    order

    V t

    /r,

    where

    V is

    a velocity

    scale and

    t

    is

    a

    time scale.

    In

    order for

    the virtual

    mass force to

    be

    appreciable,

    the

    time scale must

    be of

    the order r/V. For

    most

    multiphase

    flow

    applications,

    r

    is small,

    and

    V is not.

    Thus,

    we

    see virtual

    mass

    effects

    only

    at

    relatively

    high frequencies.

    Zuber (1964)

    considered

    finite concentration

    effects

    on virtual

    mass by

    considering

    a

    sphere

    moving

    inside

    a spherical

    cell . He

    obtained

    C

    (a)

    - 1 1+2a

    1 +

    3

    (82)

    VM = 2 --

    =2

    for

    small

    a.

    Nigmatulin (1976)

    also calculates

    the virtual

    mass

    coefficient from

    a

    cell

    model. He

    obtained

    C

    (a) -

    1-

    to 0 0).

    The

    VM = 2

    form

    of

    the

    acceleration

    which he derives

    is not

    objective.

    It

    is

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    possible that

    this

    is due

    to

    the inability

    of

    cell models

    to

    adequately

    deal with

    velocity

    gradient

    terms.

    The

    value of the

    virtual

    mass

    coetficient

    derived by van

    Wijngaarden

    (1976)

    is

    C (a)

    =

    0.5

    + 1.39a .

    (83)

    VM

    Moheyev (1977)

    obtained

    an empirical

    correlation

    C M(a)

    =

    0.5

    +

    2.1a

    (84)

    by using an

    electrodynamic

    analog. Thus,

    there seems

    to

    be a

    concensus

    that

    C + I

    as

    a +

    0.

    There

    is

    less

    agreement

    on the O(a)

    VM 2

    correction.

    In

    addition, there

    are

    several models

    in

    the

    literature

    (Wallis 1969,

    Hinze

    1972)

    which use

    non-objective

    forms of the

    virtual

    mass.

    There is

    no

    compelling

    evidence

    at this

    point as

    to

    whether the

    objective

    or

    non-objective

    forms

    conform more

    closely to

    reality.

    Cheng (1982)

    has

    done

    extensive

    predictions

    using

    virtual mass

    models for

    accelerating

    air-water

    bubbly

    flows. For low

    frequency

    small

    disturbances in

    a

    one-dimensional

    flow, he

    found

    that the

    value

    of

    CVM

    had a

    significant

    effect on the

    propagation

    speed,

    but

    that the

    data

    were

    scattered so

    that

    a particular

    value could

    not be

    estimated.

    For higher

    frequency

    waves (sound

    waves)

    and for

    critical

    flow,

    compressibility

    effects were

    important. For

    nozzle

    flow, the

    virtual

    mass effects

    were

    insignificant.

    None

    of

    the calculations

    showed

    any

    effect of

    different

    values of

    X.

    The

    term

    A4 (2 -

    v1)-D2,b

    (85)

    contains the

    effect of the

    lift.

    We

    write A

    = a L. On

    the other

    hand,

    the forces

    represented

    by A3

    (V

    2

    -

    vI) D and

    32aw-1

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    t

    A (V

    -

    V2 ).[V(V

    -

    v

    2)

    have no

    analogs

    in single

    particle

    calculations, and, no

    observations

    confirm

    their presence.

    Thus

    we

    assume A

    3

    = A

    6

    = 0. Very little

    experimental

    evidence for A

    4

    exists.

    Interfacial

    Geometry Models

    It is

    evident from eqs. 71) and (78) that

    a relation

    is

    needed for

    expressing the

    geometry of the

    interface. Several such relations

    have

    been used;

    however, none is so

    compelling as to be

    called general. The

    one

    which comes closest

    is

    due to

    Ishii (1975)

    (derived for

    the

    time

    average; the

    generalization

    is

    obvious). We shall

    discuss this later.

    First, we

    present the

    simplest

    models.

    If

    the

    particles are solid

    spheres each of

    the same

    radius

    r, we have

    4 3

    a

    =

    -y

    r

    n

    (86)

    where n

    is the

    number density.

    Other quantities

    of interest are

    immediately

    obtainable

    from

    a

    and

    r, for example,

    the average

    3a

    interfacial

    area per unit

    volume is

    ---. Note that n is

    conserved

    r

    since a is;

    specifically, we

    have

    an

    + V-n

    v

    1

    =

    0

    . (87)

    If the

    particles are not

    monodisperse, it may be

    necessary to derive

    a

    model where

    each

    size

    of

    particle is treated

    separately.

    Some recent

    efforts along these

    lines

    show

    great

    promise

    (Greenspan 1982).

    Particle

    breaking,

    agglomeration, or

    accretion/erosion

    also

    necessitates

    a more

    complicated model.

    An

    effort (without macroscopic

    mechanical

    considerations)

    is

    given

    by Seinfeld

    (1980).

    Both

    approaches

    are

    essential

    geared to an

    equation analogous

    to

    (87)

    for a number

    density.

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    A more

    general approach

    is suggested

    by Ishii

    (1975) (for time

    averaged equations), where he writes

    as

    O

    at

    + vs =

    i

    (88)

    where

    s

    is the

    interfacial area per unit

    volume, which

    in

    the

    present

    notation

    is , v.

    is

    the

    averaged interfacial velocity, and

    *i

    is a source

    of

    interfacial area, due to

    bulging of

    the

    interface.

    This

    approach is probably

    best suited

    to

    flows

    where the

    particulate

    phase

    (bubbles or drops) can

    coalesce or break up. It has not

    been

    investigated to any

    degree.

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    MODEL CONSIDERATIONS

    The

    main aspect of

    two-phase

    flows which

    makes

    them

    fundamentally

    different from

    a single-phase flow

    is

    the

    interfacial

    interaction terms,

    and,

    thus, in the absence of

    interfacial mass transfer

    the

    difference is

    d

    contained

    in

    the

    interfacial

    force Nk. The

    modeling of this term

    must

    proceed cirefully,

    with attention paid to

    any

    possible

    inconsistencies

    or

    untoward

    predictions.

    A canonical

    pioblem involving simplified two-

    phase

    flow models has

    surfaced in the

    literature;

    namely, that the

    one-

    dimensional,

    incompressible,

    inviscid

    flow equations

    without virtual

    mass effects are

    ill-posed as an

    initial

    value problem (Ramshaw

    & Trapp

    1978).

    To see this, consider

    the equations

    with

    CVM = 0 and L

    = 0.

    (This

    represents

    the

    model

    used in most

    practical

    calculations.)

    aa

    3a

    + ---

    = 0

    (89)

    -

    +

    2

    = 0

    (90)

    t , ax

    ap j v 3-Vl1)

    a

    p+A v

    91

    p1 (Y-

    + =w - - + A

    1 2

    - v

    1 )

    (1

    av

    av

    a2

    2 ap

    (1-a)p

    2 --

    + v

    2

    =

    -a-) ;

    +

    A (V

    1

    - v

    2

    ) (92)

    If

    the

    pressure is

    eliminated

    from

    system (89)

    -

    (92)

    and the

    resulting equations

    are

    expressed

    in

    the

    form

    A-2H

    + B

    2H

    =

    C,

    where

    t

    u = [,v

    1

    ,v

    2

    ] , A and

    B are

    3 x 3

    matrices

    and

    C is a 3-vector,

    dz.

    then the

    characteristics

    of the

    system are given

    by

    ,--Vi,

    i

    = 1,2,3,

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    where V. are the three

    characteristic

    values of

    det[AV-B] = 0.

    I

    Note that since

    C

    contains

    no

    derivative

    terms,

    it is

    not

    involved in

    determining

    the

    characteristics.

    The

    characteristic

    values V. for the

    system

    as

    given

    are a

    pair

    of complex conjugate

    roots

    V1

    = a iO

    (with

    0

    yk ), and V

    3

    = 0

    (resulting

    from the assumption of

    incompressibility).

    This

    implies (Garabedian

    1964)

    that

    the

    initial

    value problem is

    ill-posed.

    One

    implication

    of the

    ill-posed

    nature of the

    system

    can be seen

    as follows. Consider the

    linear stability

    of

    a constant solution.

    The

    solution

    of the linearized equations

    has the form u(x,t)

    =

    Vt+ikx

    u

    0

    + u

    1

    e

    , where k

    is

    real. Substitution into

    the

    linearized

    system results in the

    eigenvalue problem

    [A(u0 )v + B(u

    0)ik

    -

    C(u

    0)u

    = 0 (93)

    for V. The

    eigenvalue equation

    is

    C(u

    0

    )

    det[A(u - -

    B(u

    ----

    1 = 0

    o

    (94)

    0 k

    0

    k

    For

    k large, two roots of (94) are

    vi

    i

    (95)

    Thus,

    V

    k(8 -

    ai)

    *

    (96)

    1,2

    As long as 0

    , 0,

    one of the

    v's will have positive real part,

    indicating linear instability. Note, too, that as k increases, the

    growth

    rate lOkI increases.

    This

    shows

    that finer disturbances

    grow

    faster. This implies

    that at any

    t

    >

    0, maxlule

    t+ikx

    I

    can

    be made as

    large as

    desired by taking k sufficiently small.

    Contrast

    this with

    the

    behavior of

    an

    instability of a well-posed system, where

    the

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    vt~ikx

    solution u e

    can be

    made

    as small as

    desired

    at

    a

    finite

    t by

    making

    u

    1

    small,

    for

    any k. The

    instability in

    the

    well

    posed

    system

    has

    some

    realistic

    physical

    meaning, while the

    instability

    always

    present in the

    ill-posed

    system suggests

    that

    the model

    is not

    treating

    small scale

    phenomena correctly.

    The

    extension of

    the

    argument

    to

    three space

    dimensions

    is

    straightforward, and

    shows that the

    system is ill-posed in

    three

    dimensions also.

    The

    ill-posed nature of

    the model

    makes it

    desirable to

    seek

    physical

    modifications of that

    simple

    model to

    find a well

    posed

    model.

    An effort has

    been made

    to

    determine

    whether

    and/or to

    what

    extent

    virtual

    mass makes the

    inviscid model

    well

    posed.

    Lahey,

    et al.

    (1980)

    have

    shown that

    the

    model becomes

    well-posed for

    certain

    values

    of

    CVM. The value

    of

    CVM which makes

    the

    system well-posed

    is

    usually large

    unless

    a

    is extremely

    small, or

    other

    somewhat non-

    physical assumptions

    are

    made.

    Thus,

    even

    though

    it is

    a

    possible

    fix

    to the question

    of

    the

    well vs.

    ill-posed

    nature

    of the

    model,

    virtual

    mass

    does not seem

    to be the

    total

    answer.

    We note here

    that

    if the

    viscous and

    Reynolds stresses

    are

    included

    in the

    equation, and they

    are

    assumed

    to

    depend on

    Vvk,

    the

    equations

    become

    parabolic,

    and hence

    are

    well-posed

    if

    enough

    boundary

    conditions

    are used.

    Also

    Prosperetti

    and

    van Wijngaarden

    (1976)

    have

    shown that

    using

    certain compressibility

    assumptions in

    gas-liquid

    systems

    gives

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    real characteristics.

    Stuhmiller

    (1977)

    shows that

    his model

    including

    the

    form drag (see

    eq.

    72)

    gives real

    characteristics

    for

    sufficiently

    large

    F.

    The

    question of the

    role of the

    inviscid

    model

    remains. In

    single-

    phase

    fluid

    mechanics,

    the inviscid

    model

    is

    extremely

    important,

    and

    governs

    the

    flow

    outside of

    boundary

    layers,

    shear layers

    and

    oth