advanced cleaning product formulations · 2019. 2. 28. · the formulations in this book are...

ADVANCED

CLEANING PRODUCT FORMULATIONS

ADVANCED

CLEANING PRODUCT

FORMULATIONS

Household, Industrial, Automotive

by

Ernest W. Flick

Reprint Edition

r;:;::l NOYES PUBLICATIONS~ Westwood, New Jersey, U.S.A.

Copyright © 1989 by Ernest W. FlickNo part of this book may be reproduced or utilized inany form or by any means, electronic or mechanical,including photocopying, recording or by any informa-tion storage and retrieval system, without permissionin writing from the Publisher.

Library of Congress Catalog Card Number: 89-30274ISBN: 0-8155-1186-8Printed in the United States

Published in the United States of An1erica byNoyes PublicationsFairview Avenue, Westwood, New Jersey 07675

1098 7 6 5

Library of Congress Cataloging-in-Publ ication Data

Flick, Ernest W.Advanced cleaning product formulations: household, industrial,

automotive / by Ernest W. Flick.p. cm.

Includes index.ISBN 0-8155-1186-8 :1. Cleaning compounds. I. Title.

TP990.F56 1989668' .1- -dc19 89-30274

CIP

Preface

This book presents more than 800 up-to-date advanced cleaning product formu-lations for household, industrial and automotive applications. It is the result ofinformation received from numerous industrial companies and other organiza-tions. The data represent selections made at no cost to, nor influence "from, themakers or distributors of these materials. Only the most recent formulas havebeen included.

Formulation in the cleaning product industry has undergone significant changeduring the past few years. Raw materials costs have risen and manufacturers havebeen reluctant to pass along these increases. By changing formulations to im-prove cost/performance characteristics, manufacturers have been able to controlcosts but still enhance performance. This book presents manufacturers' sug-gested formulations which might meet these new performance criteria.

The formulations in this book are divided into the following sections and chap-ters:

I. Household/Industrial Cleaners1. Bathroom CI eaners (16)2. Dishwashing Detergents (57)3. Disinfectants (11)4. Floor Cleaners and Wax Strippers (41)5. General Purpose Cleaners (73)6. Laundry Products (143)7. Metal Cleaners (73)8. Oven Cleaners (10)9. Rinse Additives and Aids (96)

10. Rug, Carpet and Upholstery Cleaners and Shampoos (40)11. Wall and Hard Surface Cleaners (49)12. Window and Glass Cleaners (25)13. Miscellaneous Cleaners (129)

v

vi Preface

II. Automotive Cleaners14. Car and Truck Washes (51)15. Whitewall Tire Cleaners (8)16. Miscellaneous Cleaners (21 )

Parenthetic numbers indicate the number of products in each chapter. Eachformula is located in the chapter which is most applicable. The reader, seekinga formula for a specific end use, should check each chapter which could possiblyapply. In addition to the above, there are two other sections which will be help-fu I to th e reader:

'II. A chemical trademark section where each tradenamed rawmaterial included in the book is listed with a chemical de-scription and the suppl ier's name. The specifications whicheach raw material meets are included, if applicable.

IV. Main office addresses of the suppliers of trademarked rawmaterials.

Each formulation in the book lists the following information, as available, inthe manufacturer's own words:

• Description of end use and most outstanding properties.

• The percent by weight or volume of each raw material in-cluded in the formula, rounded to a decimal figure.

• Key properties of the formula, which are the features thatthe source considers to be more outstanding than other formu-lations of the same type.

• The formula source, which is the company or organizationthat supplied the formula. The secondary source may be theoriginating company and/or the primary source's publicationtitle, or both. A formula number is included, if appl icable.

The table of contents is organized in such a way as to serve as a subject index.

My fullest appreciation is expressed to the companies and organizations whosupplied the original starting formulations included in this book. I also thankthe suppliers of the raw materials included in these formulations, who furnishedinformation describing their trademarked raw materials.

Newburyport, MassachusettsApril 1989

Ernest W. FI ick

NOTICE

To the best of our knowl edge the informa-tion in this publication is accurate; however,the Publisher does not assume any responsi-bility or liability for the accuracy or com-pleteness of, or consequences arising from,such information. This industrial guide doesnot purport to contain detailed user instruc-tions, and by its range and scope could notpossibly do so. Mention of trade names orcommercial products does not constitute en-dorsement or recommendation for use bythe Author or Pu bl isher.

Some advanced cleaning products could betoxic if used improperly, and therefore duecaution should always be exercised in the useof these materials. Final determination of thesuitability and reliability of any informationor product for use contemplated by anyuser, and the manner of that use, is the soleresponsibility of the user. We strongly rec-ommend that users seek and adhere to amanufacturer's or supplier's current instruc-tions for handling each material they use.

The Author and Publisher have used theirbest efforts to include only the most recentdata available. The reader is cautioned toconsult the supplier in case of questions re-garding current availability_

viii

Contents and Subject Index

SECTION IHOUSEHOLD/INDUSTRIAL CLEANERS

1. BATHROOM CLEANERS 2Acid Tile and Bath Cleaner (Pearlized) 3Tile Cleaners 3Liquid Acid Toilet Bowl Cleaner 5Liquid Acid Toilet Bowl Cleaner (Disinfectant) 6Liquid Acid-Type Toilet Bowl Cleaner. 6Pearlescent Toilet Bowl Cleaner 7Toilet Bowl Cleaners 7Toilet Bowl Cleaner-Liquid 8Toilet Bowl Cleaner-Solid 9Toilet Bowl Cleaners, Solid Automatic 9

2. DISHWASHING DETERGENTS 11Dishwash Liquid Concentrate 12Dishwash Liquid from Concentrate-Premium Quality 12Dishwash Liquid from Concentrate--Good Quality 13Dishwash Liquid from Concentrate-Economy 13Dishwash Liquid from Concentrate-Generic 13Dishwash Liquid-Premium Quality 14Dishwash Liquid-Good Quality 14Dishwash Liquid-Economy 15Dishwash Liquid-Generic 15Hand Dishwash Liquid-High Quality 16Hand Dishwash Liquid-Good Quality 16Hand Dishwash Liquid-Economy (LAS/Ethoxysulfate/Ethoxylate) 17Liquid Dishwash (SLS/Sulfonic Acid-TEA/Surfactant) 17

ix

x Contents and Subject Index

High Active Dishwashing Detergent (30%) 18High Active Dishwashing Detergent (30%) with Skin Conditioner 19Light Duty Liquid Dishwash 20Light Duty Liquid Formulation Medium Cost Hand Dishwash 20Liquid Dishwashing Compound 21Liquid Dishwashing Detergents . . . . . . . . . 21Liquid Dishwashing Detergent (Premium) 23Liquid Dishwashing Detergent (Medium) 23Hand Dishwash ing Detergent 24Dishwash ing Detergent (24%) . . . . . . . . . . . . . . . . . 25Pearlescent Dishwashing Detergent. . . . . . . . . . 25Dishwash ing Detergents Liquid, Hand. . . . . . . . . 26Generic Dishwashing Detergent (14%). . . . . . . . . . . . 27Medium Active Dishwashing Detergent (25%) . . . . . . . 28Concentrated Liquid Machine Dishwashing Compound 29Institutional Liquid Machine Dishwashing Compound .. 29Medium Duty Liquid Machine Spray Wash. . . . . 29Automatic Dishwash ing Detergent (Powder). . . . 30Mechanical Dishwash ing Detergents . . . . . . . . . 30Dishwashing Detergents, Machine 32Dishwashing Detergent, Machine (Phosphates/Silicate/Surfactant) 34Dishwashing Detergent, Machine/Biodegradable 35Mach ine Dishwashing Detergent 35Dishwashing Detergent, Machine. . . . . . . . . . . . . . . . . . . . . . .36Dishwashing Detergent, Machine/Biodegradable. . . . . . . . . . . . .36Industrial Dishwash Formulation: Regular Duty, Good Quality,

Mild Liquid. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .37Industrial Dishwash Formulation: Good Quality Pot and PanCleaner. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 37

Industrial Dishwash Formulation: Alkaline Pot and Pan Cleaner 37Liquid Machine Dishwashing Concentrate 38Machine Dishwashing Detergent 38Automatic Dishwasher Detergent 38Machine Dishwashing Formulation. . 39Machine Dishwashing Powder. . . . . . . . . . . . . 39

3. DISINFECTANTS. . . . . . . . . . . . . . . . . . . . . . . 40Disinfectant Cleaner. . . . . . . . . . . 41General Disinfectant Solution 41General Disinfectant 41Disinfectant Cleaners 42Hospital Disinfectant 43San itizer-Liquid, Acid 43Sanitizer (Also for Spray)-Liquid, Clear 43Sanitizer: Liquid, Cloudy, Contains Chlorine 44San itizing Cleaner (Liquid, 12.5% A.M.) . . . . . . 44

4. FLOOR CLEANERS AND WAX STRIPPERSFloor Cleaners .

........... 45. 46

Contents and Subject Index xi

Floor Cleaner (Garage) 50Floor Cleaner-Low Foam Machine Applied 51Floor Cleaner, Low-Foam Machine Scrubbers 51Floor Cleaner with FBR , 53Floor Cleaner-Garage Floor 53Floor Cleaner/Wax Strippers 54Floor Wax Stripper 56Floor Cleaner/Wax Stripper-Powder 57Floor Cleaner/Wax Strippers 57Wax Stripper and Cleaner 58Liquid Non-Phosphate Floor Cleaner and Wax Stripper. 59Floor Wax Stripper 59Experimental Stripper 60Heavy Duty Wax Stripper 60Floor Finish Stripper 61Foaming Wax Stripper 61Wax Stripper 61Low Foaming Wax Strippers 62Wax Stri ppers 63Waxed Floor Cleaner 64Heavy Duty Floor Finish Stripper. . . . . . . 64

5. GENERAL PURPOSE CLEANERS 65Abrasive Cleaners, Liquid 66Alkaline All Purpose Industrial Cleaner 68All-Surface Household Cleaner 68All-Purpose Cleaners 69All-Purpose Cleaner (Aerosol) 72All-Purpose Cleaner with FBR 73All-Purpose (Wall/Tile/Floor Cleaner) 73All-Purpose Janitorial Cleaning Concentrate 73All-Purpose Concentrate Cleaners 74All-Purpose Cleaner (Liquid Concentrate) 75All-Purpose Liquid Concentrate Cleaner 75All-Purpose Heavy Duty Cleaner 76All-Purpose Liquid Industrial Cleaner 76All-Purpose Liquid Detergent 76All-Purpose Household Detergent 77All-Purpose Industrial Cleaner 77All-Purpose Light Duty Liquid Detergent 78All-Purpose Cleaner, Light Duty 78All-Purpose Cleaner 78All-Purpose Liquid Concentrate Cleaner 79All-Purpose Cleaner, Liquid 79All-Purpose Cleaner 79All-Purpose Liquid Detergents 80All-Purpose Liquid Pine Oil Detergent 81All-Purpose Spray Cleaner 82

xii Contents and Subject Index

All-Purpose Cleaner with Alkanolamides 82Caustic Cleaner 83Chlorine Cleaner (Kitchen and Bathroom) (Powder) 83Food Industry Cleaner-General Use Liquid 83Food Industry Cleaner-Powder 84General Cleaner-Alkal ine Cleaner 84General Cleaner-Houser-old 84General Purpose Cleaner-Household 85General Purpose Cleaner-Industrial 85General Purpose Cleaner 85General Pu rpose Spray and Wi pe CI eaners 86General Purpose Cleaner 88Heavy Duty Alkaline Cleaner 88Heavy Duty Cleaner 88Heavy Duty, Good Quality, All Purpose Spray, Wall/Tile/Floor

Cleaner 89Heavy Duty Cleaner 89Heavy Duty All Purpose Steam Cleaner 90Industrial Cleaner 90Light Duty Cleaner 90Light Duty, All Purpose Wall/Tile/Floor Cleaner 91Liquid Concentrate 91Liquid High Pressure Cleaner (Concentrate) 91Limonene Based All Purpose Cleaner, Clear Liquid 92Limonene Based Heavy Duty Cleaner/Degreaser 92Limonene Based Household Cleaner 93Limonene Based Household and Industrial Cleaner 94d-Limonene Spray Cleaner 94Liquid Cleanser 95Liquid General Purpose Alkaline Steam Cleaner-Heavy Duty 95Multi -Pu rpose CI eaner-Stri pper-CI eaner-Degreaser 95Multi-Purpose Cleaner Based on Limonene 96General Purpose Cleaner 96

6. LAUNDRY PRODUCTS 97Cold Water Detergent (Wool and Del icate Fabrics) 98Commercial Laundry Liquid 98Detergents for Fine Fabrics (Clear, Liquid, Without Phosphate) 99Detergent for Fine Fabrics (Liquid, with Phosphate) 100Fine Fabric Wash Detergent 100Detergent Paste with Phosphate 101Detergent Paste Without Phosphate 101Detergent-Softeners 102Dry-Blended Laundry Powder Containing Phosphate-Premium

Qual ity 104Dry-Blended Laundry Powder Containing Phosphate-High Quality .. 104Dry-Blended Laundry Powder Containing Phosphate-Premium

Qual ity . . . . . . . . . . . . . . . . . . . . . 105

Contents and Subject Index xiii

Dry-Blended Laundry Powder Containing Phosphate-Good Quality .. 105Dry-Blended Laundry Powder Containing Phosphate-Good

Quality 106Dry-Blended Laundry Powder Containing Phosphate-Regular

Quality 106Hand-Wash Laundry Liquid-Moderate Foam 107Hand-Wash Laundry Liquid-High Foam, Extra Mild 107Heavy Duty Commercial Laundry Detergent 108Industrial Laundry Detergent 108Heavy Duty Liquid Detergent (Transparent, Without Builder) 109Heavy Duty Powder 109Heavy Duty Liquid Laundry Detergent "HDL" 110Heavy Duty Liquid Without Phosphate 110Heavy Duty Liquid Laundry Detergents (36%) with Fabric

Softener 111Heavy Duty Liquid with Phosphate 112Heavy Duty Liquid Detergent 112Heavy-Duty Phosphate Free Laundry Powders 113Heavy-Duty Powdered Laundry Detergent 113Industrial Lau ndry Detergents 114Laundry Detergent-Commercial: High Quality Built Laundry

Liquid 115Lau ndry Detergents 115Laundry Detergents-Commercial-Unbuilt Liquids 116Laundry Liquid Concentrate 117Laundry Liquid from Concentrate-Good Quality 117Laundry Liquid from Concentrate-Store Brand 118Laundry Liquid from Concentrate-Economy 118Laundry Liquid from Concentrate-Generic 118Laundry Liquid with Enzymes-Premium Quality 119Laundry Liquid with Enzymes-Good Quality 119Laundry Liquids with Fabric Softener-Premium Quality 120Laundry Liquid with Fabric Softener-Good Quality 120Lau nd ry Liquid with Fabric Softener and Enzymes 121Laundry Paste 122Light Duty Liquid Detergent 122Concentrated Liquid Laundry Detergent 122Laundry Powders-Commercial 123Light Duty Liquids 124Liquid Detergents-Softener 125Liquid Detergents 128Liquid Laundry Detergent 133Laundry Detergent, Liquid-Emulsion Type 134Laundry Detergent, Liquid-Slurry Type 134Laundry Detergent, Liquid 135Laundry Detergent Liquid, Heavy Duty 136Laundry Detergent Powder 136Laundry Detergent Powders (Low-Foam) 137

xiv Contents and Subject Index

Laundry Detergent Powder-Low Phosphate 138Laundry Detergent Powder-No Phosphate 138Laundry Pre-Spotters (Water Based) 139Liquid Laundry Detergents 141Heavy-Duty Liquid Laundry Detergent 145Non-Phosphate Dry-Blended Laundry Powder-Premium Quality 146Non-Phosphate Dry-Blended Laundry Powder-Good Quality . .' 146Non-Phosphate Dry-Blended Laundry Powder-Premium Quality 147Non-Phosphate Dry-Blended Laundry Powder-Good Quality 147Non-Phosphate Dry-Blended Laundry Powder-Economy 147Powdered Laundry Detergent (Phosphate Type) 148Powdered Laundry Detergent (Nonphosphate Type) 148Regular Quality Built Laundry Liquids 149Two-Step Built Laundry Liquid Formulations 151Unbuilt Laundry Liquid-Super Premium Quality 152Unbuilt Laundry Liquids-Premium Quality 152Unbuilt Laundry Liquid-Regular Quality 153One-Half Cup Built Laundry Liquid-High Qual ity 154One-Half Cup Built Laundry Liquid-High Quality, High Foam 155Lau nd ry Prespotter 156Laundry Prespotter-Aerosol 156Aerosol-Type Prespotter-Solvent-Based-Premium Quality 157Aerosol-Type Prespotters-Solvent-Based-H igh Qual ity 157Laundry Prespotters-Pump Spray-Type-Premium Quality 158Pump Spray Prespotter-Water-Based-Good Quality 159Purnp Spray Prespotter-Water-Based-Reqular Quality 159Pump Spray Prespotter-Water-Based-Economy 159

7. METAL CLEANERS 160Metal Cleaners, Acid 161Metal Cleaners-Brightener for Aluminum 162Metal Cleaners, Heavy Duty 164Metal Cleaner, Heavy Duty Low-Foam 165Metal Cleaner, Heavy Duty Low-Foam, Low Temperature 166Metal Cleaner, Light Duty 166Metal Cleaner, Light Duty for Oil Rigs 166Metal Cleaners, Low-Foam Liquid 167Metal Cleaner, Medium Duty 168Metal Cleaners, Soak Tank 168Metal Cleaner-Spray on Type 169Metal CI eaner for Copper and Brass (Metal Pol ish) 169Metal Cleaner, Solvent-Emulsifier 170Acid Metal Cleaners 170Aircraft Cleaners 171AI kal ine Metal Degreasing Baths 172Alkaline Soak Tank CI·eaner for Aluminum 172Alkaline Soak Tank Cleaner for Brass 173Aluminum Brightener/Cleaner 173

Contents and Subject Index xv

Aluminum Cleaner and Brightener (Non-Hydrofluoric Type) 173Alkaline Metal Cleaner-High Quality 174Alkaline Metal Cleaner-Good Quality 174Aluminum Cleaner-Acid Aluminum Brightener 175Aluminum Cleaner-Alkaline Aluminum Cleaner with Phosphate 175Aluminum Brightener 176Aluminum Cleaners 176Caustic-Gluconate Soak Formulation 178Cold Metal Cleaners 178Copper Cleaner (Paste) 179Metal Cleaner (Soak Cleaner) 179Heavy-Duty Metal Cleaner 179Metal Cleaner-Alkaline Wash Powder-with Phosphate 180Metal Cleaner-AI kaline Wash Powder-Nan-Phosphate Powder 180Metal Cleaner-Paint Stripper 180Metal Clean ing-Pa int Removal 181Metal Cleaning-Rust Removal 181Metal Cleaning-Alkaline 181Metal Cleaning-Acid 181Metal Cleaner, Powder, for Spray Type 182Soak Tank Metal Cleaner, Powder, for Aluminum 182Rust Remover (Dip Part Cleaners) 183Silver Cleaning Bath 183Soak Tank Metal Cleaner 183Soak Tank Metal Cleaner, Powder, for Brass 184Soak Tank Metal Cleaner, Powder, for Zinc 184Soak Tank Metal Cleaner, Powder, for Magnesium 185Soak Tank Metal Cleaner, Powder, for Copper 185Spray Metal CI eaners 186Stem Metal Cleaners 186High Quality Metal Deoiling Liquid Concentrates (Oil Spill/Rig

Cleaners) 187

8. OVEN CLEANERS 188Aerosol Oven CI eaner. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 189Oven Cleaners 189Oven Cleaner, Liquid Type 190Oven Cleaner, Foam Spray Type 191Oven CI eaner 191Caustic Cleaners (Oven Cleaner or Paint Stripper) 192

9. RINSE ADDITIVES AND AIDS 194Rinse Additives Biodegradable, Machine Dishwashing 195Rinse Additives, Machine Dishwashing 196Rinse Aid Concentrates 199Dishwasher Rinse Aid 199Rinse Aid-Economical Type 200Rinse Aid-Low Density Type 200

xvi Contents and Subject Index

Rinse Aid-High Density Type 201Dishwasher Rinse Aids 201Rinse Aid for Dishwash 202Rinse Aid with Makon NF-5 202Rinse Aids for High Temperature Machines 203Rinse Aids for Low Temperature Machines 205Rinse Aids for Low Actives Formulations (10 wt % Surfactants) 208Rinse Aids for Hard Water Formulations 210

10. RUG, CARPET AND UPHOLSTERY CLEANERS AND SHAMPOOS 212Antistatic Carpet Shampoo 213Carpet Cleaner 214Carpet Cleaner (Foam Type) 214Carpet Cleaner (Scrub Type) 214Carpet Extraction Cleaner 215Carpet Extractor Cleaner 215Carpet Steam Cleaner 215Carpet Shampoo 216Carpet Shampoo, Aerosol 217Carpet Shampoos, Scrubbing Machine 217Carpet Sharnpoos, Steam Cleaner 218Carpet Shampoo Treatment, Soil Retardant and Antistat Cleaning

Technique-Pump Spray 220Carpet Shampoo Treatment, Soil Retardant and Antistat Cleaning

Technique-Aerosol 220Liquid Spray Vacuum CQrpet Cleaner 221Powdered Spray Vacuum Carpet Cleaner 221Premium Medium Duty Steam Extraction Carpet Cleaner 222Premium Heavy Duty Steam Extraction Carpet Cleaner with Butyl 222Heavy Duty Steam Extraction Carpet Cleaner 222Rug Cleaners 223Aerosol Rug Shampoo with Anticorrosive 224Rug Shampoo with Polymer 224Basic Rug Shampoo Concentrate 225Rug and Upholstery Shampoo-Low-Foaming Liquid 225Rug and Upholstery Shampoo-High-Foaming Liquid 225Rug Shampoos 226Rug Shampoo, Liquid Type 227Rug Steam Cleaner 228Rug Steam Cleaner-Non-Phosphate Powder 228Rug Steam Cleaner-Powder with Phosphate 228Rug and Upholstery Cleaner-IIDry Brittle" Liquid Cleaner-HighQuality 229

Rug and Upholstery Cleaner-IIDry Brittle" Liquid Cleaner-GoodQuality 229

Rug and Upholstery Cleaner-IIDry Brittle" Liquid Cleaner-Economy 230

Liquid Steam Cleaner for Carpets for Use in Hard Water Systems 230

Contents and Subject Index xvii

11. WALL AND HARD SURFACE CLEANERS 231All Purpose Hard Surface Cleaning Concentrates 232Hard Surface Cleaners 232Hard Surface Cleaner-All Purpose Creamy Scouring Cleanser 234Hard Surface Cleaner: All-Purpose Spray 235Hard Surface Cleaner: Liquid Concentrate 235Hard Surface Cleaner: Liquid Disinfectant 235Hard Surface Cleaner: Floor Cleaner/Wax Stripper 235Hard Surface Cleaner, Liquid, All Surface Bathroom Type 236Hard Surface Cleaner, All Surface Bathroom-Acid Type 236Hard Surface Cleaner, Degreasing Type 237Hard Surface Cleaners, All Purpose Type 237Hard Surface Cleaner 239Hard Surface Cleaner, General Purpose Type 240Hard Surface Cleaner, Heavy Duty Type 240Hard Surface Cleaner, Pine Oil Type-Economical 241Hard Surface Cleaner, Solvent Type 241Hard Surface Cleaners-All Purpose 242Hard Surface Cleaners-All Purpose Non-Phosphate PremiumQuality Liquid Concentrates 243

Hard Surface Cleaner Liquid Concentrates, High Quality withPhosphate 244

Hard Surface Cleaners-All Purpose Hard Surface Cleaner LiquidConcentrates 245

Hard Surface Cleaners-All Purpose 246Hard Surface Cleaners-All Purpose Pine Oil Cleaners 247Hard Surface Cleaners-All Purpose 248Hard Surface Sanitizer and Cleaner Disinfectant 249Hard Surface Cleaner/Fabric Pretreat 249Hard Surface Spray Cleaner 250Hard Surface and Floor Cleaner 250Liquid Hard Surface Cleaner, High Sudsing-Unbuilt 251Liquid Hard Surface Cleaner, Dilutable, Phosphate Built 251Liquid Hard Surface Cleaner Concentrates 252Wall Cleaner 252Wall Cleaner, Light Duty 252Wall Cleaner, Spray 252

12. WINDOW AND GLASS CLEANERS 253Acid Glass Cleaner 254Multi-Feature Glass Cleaner 254Ammoniacal WINDEX Type 255Window/Glass Cleaner (Good Quality) 255Glass Cleaner 256Glass Cleaners (All Purpose) 256Glass Cleaner, Ready to Use 258Glass Cleaners 258Glass Cleaner Concentrate 259

xviii Contents and Subject Index

Industrial Glass Cleaner 260Liquid Glass Cleaner 260Window/Glass Cleaner (Good Quality with Alcohol) 261Window and Glass Cleaners 261Window Cleaners 262Window Cleaner, Aerosol (Foam-Type) 263Window Cleaner, High Alcohol Type 264Window Cleaner, Concentrate 264Window Cleaners, Spray 265

13. MISCELLANEOUS CLEANERS 266Abrasive Cleaner-High Viscosity 267All-Surface Steam Cleaner 267AI kal ine Cleaner 268Asphalt Release Agents 268Barbecue Cleaner: High Alkaline 269Bottle Cleaner 269Bottle Wash Concentrate 269Bilge Cleaner-Solvent Emulsifier 270Bilge Cleaners 270Bottle-Wash Compound 271Bottle Washes, Mach ine 271Bowl Cleaner 272Butyl Cleaners (Heavy Duty Degreaser) 272Butyl Cleaner and Degreaser 273Carbon Cleaner 274Cosmoline Remover (Heavy Oil or Greasy-Wax Remover) 274Chain Lubricant 275CI P Cleaners 275Coffee and Tea Machine Cleaner (Concentrate) 275Concrete Cleaners 276Cutting and Grinding Fluid (Low Foam) 276Dairy Milkstone Remover 277Dairy Pipeline Cleaner (Low-Foam) 277Dairy Line Cleaners 278Dairy Pipel ine Cleaner 278Dairy CI eaners 279Degreasers, Degreaser Concentrates 280Degreasers, Solvent Degreasers, FI ush-Off Type 282Powder Degreasers 282Degreaser. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 283Spray Degreaser 283Heavy Duty Spray Degreaser 283High Foam Degreaser 284Non-Butyl Degreaser 284Non-Phosphate Non-Butyl Degreaser 284Industrial Strength Non-Butyl Degreaser 285Water-Based Solvent Degreaser 285

Contents and Subject Index xix

Drain Cleaners, Liquid 286Drain Cleaner, Liquid Type 286Dry Cleaning Solutions 287Dry Cleaning Compound 287Dry Cleaning Fluid 287Dry Cleaning Formulas 288Emulsifiable Solvent Cleaners (Garage Floor Cleaner) 289Foam ing Butyl Cleaner 289Foam Marker Concentrates 290Food Processing Equipment Cleaner, Spray 290Gel Rust Remover. . . . . . . . . . . . . . . . . 291Graffiti Removers. . . . . . . . . . . . . . . . . 291Glass/Bottle Liquid Cleaner Compound. . . 292Grill Cleaner 292Heavy Duty Cleaner 292Heavy-Duty Cleaner-Dry 293Heavy Duty Cleaner and Degreaser 293Heavy Duty Concrete Cleaner 293Heavy Duty Household Cleaner 294Heavy Duty Liquid Steam Cleaner 294Heavy Duty Paint Stripper 295High Alkaline Cleaners 295High Pressure Cleaner, Liquid, Clear 296High Pressure Cleaner, Acid 296High Pressure Steam Cleaner 296Hot Plate/Grill Cleaner 297Industrial Cleaner, Alkaline 297Liquid High Pressure Cleaner Concentrate 298Liquid High Pressu re Concentrate 298Liquid Acid Dairy Sanitizer and Cleaner 298Liquid Rust Remover 299Liquid Caustic Cleaner 299Low Foam Spray Washing Compound 299Lipstick Stain Remover 299Leather, Vinyl, Plastic Cleaner 299Leather Cleaner 300Medium Duty Steam Cleaner 300Oil Field Apparatus Cleaner 300Medium Duty Non-Caustic Steam Cleaner 301Paint Brush Cleaner. . . . . . . . . . . . . . . . . . 301Produce Peeling Formula 301Porcelain Cleaner 302Heavy Duty Pot and Pan Cleaner 302Powdered Caustic Cleaner 303Rust Remover-Liquid-Acid 303Rust Remover-Liquid-Alkaline 303Solvent Emulsion, Sludge and Carbon Cleaner 304Solvent Cleaner 304

xx Contents and Subject Index

Spotting Liquid for Dry Cleaning 304Spot Cleaner 305Synthetic Cleaner 305Steam Cleaner, Liquid 306Steam Cleaner Powder 306Steam Clean ing Compound 306Steam Cleaners 307Steam Cleaning Compounds 309Textile Softener 309Tank Cleaners 310

SECTION IIAUTOMOTIVE CLEANERS

14. CAR AND TRUCK WASHES 312Auto Shampoo 313Auto Shampoo (Non-Streaking) 313Automobile Foaming Spray 313Boat Wash and Car Cleaner 313Car Wash Detergent Powders 314Car Wash, Liquids 315Car Wash, Thickened Liquid 316Liquid Car Washes 316Liquid Car Wash Concentrate 316Car Wash, Powdered Type 317Car Wash, Liquid Type 317Car Wash Liquid Concentrates 318Car Wash Powders 319Car Wash Concentrates with Alcohol Ethoxylate 320Medium-Cost Car Wash 320Car Wash Detergent 321Hand Car Wash 321Car Shanlpoos 322Car Cleaner 322Car Spray Rinses 323Automatic Car Wash 323Manual Car Wash-Home Use 323Car Spray Wash. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 324Wand-Type Car Wash 324Medium Duty Truck and Rig Wash, Powder 325Heavy Duty Truck Cleaner 325Truck Washes 326Liquid Truck Washes 327Truck-Car Wash 328Liquid Spray Cleaner for Aluminum Trucks 328Vehicle Washes 328

Contents and Subject Index xxi

15. WHITEWALL TIRE CLEANERS 329Automobile Whitewall Tire Cleaner 330Foamy Whitewall Tire Cleaner, Liquid 330"White Lightning" Tire Cleaner 331White Wall Tire Bleach 331White Sidewall Tire Cleaner 331White Wall Tire Cleaners 332

16. MISCELLANEOUS CLEANERS 333Acidic Cleaner for Aluminum Trucks 334Carbu retor Cleaner 334Automobile Windshield Cleaners 335Engine Degreaser Concentrate 336Exterior Railcar Cleaner 336Powdered Hubcap Cleaner 336Solvent Emulsion Cleaner 337Vinyl Top Cleaner 337Windshield Washer Cleaners 338Windshield Washer Formulations 339Windshield Wash 340Windshield Washer Formulation 340

SECTION III: TRADEMARKED RAW MATERIALS 341

SECTION IV: SUPPLIERS' ADDRESSES 369

Section I

Household/Industrial Cleaners

1. Bathroom Cleaners

2

Bathroom Cleaners 3

ACID TILE & BATH CLEANER(PEARLIZED)

RAW MATERIALS

VAHIO~ CADG-HSCitric AcidR£WOPOL PCK2000(cold-mix pearl)REWOPOL PEG 6000 DS (PEG 150 Distearate)VA1{OX 1770Water

% By Weight

10.05.04.03.03.0

75.0

MixioS Procedure:Add PEG 6000 DS to 6DC water to disperse.Add the VARION CADG-HS while hot.Cool to 30C and then add the Citric Acid, PGK2000 and VAROX

1770

SOURCE: Sherex Chemical Co.: Industrial Formulation 51/01.7

TILE CLEANER

RAW MATERIALS

WaterPhosphoric Acid (85%)Hydroxyacetic Acid (50%)MAZER MAZON 41VerseneKelzan GUill Thickener

% By Weight

72.512. a10.04.00.51.0

SOURCE: Mazer Chemicals, Inc.: Household/Industrial T-20B:Formula 12

4 Advanced Cleaning Product Formulations

TILE CLEANER

RAW MATERIALS

WaterPLURAFAC 0-25 surfactantColloidal magnesium aluminum silicateCalcium carbonate

Use as is

% By Weight

60.754.3

30

SOURCE: BASP CORP.: Cleaning Formulary: Formulation #3425

TILE CLEANER

RAW MATERIALS

WaterSodiull1 xylene sulfonate (40%)Ethy]ene glycol butyl etherLinear alkyl aryl sulfonate (60%)PLURAPAC 0-25 surfactantSodium metasilicate pentahydrateTetrapotassium pyrophosphate

Use as is

% By Weight

77642236

SOURCE: BASP CORP.: Cleaning Formulary: Formulation #3246

Bathroom Cleaners 5

TILE CLEANER

RAW MATERIALS

WaterSodium HypochloriteSodium HydroxideAVANEL S-70

% By Weight

96211

Mixing ProcedureCharge vessel with ingredients in the order listed with

agitation

PROPERTIBS:This is a liquid tile cleaner suitable for a pump spray app-

lication. It has the advantage of leaving a streak-free shinewith no residue.

SOURCE: Mazer Chemicals, Inc.: AVANEL S Formula: Tile CleanerJM-03

LIQUID ACID TOILET BOWL CLEANER

RAW MATERIALS

NEODOL 25-12Bardac 22 (50%)Hydrochloric acid (35%)Cocobetaine (30%)Water, dye

PROPERTIES:Viscosity, 73F, cpsPhase coalescence temp., FpH

7>1761.0

% By Weight

3.05.0

20.03 •

to 100%

SOURCE: Shell Chemical Co.: NEODOL Formulary: SuggestedFormulation


LIQUID ACID TOILET BOWL CLEANER(DISINFECTANT) (HIGH QUALITY)

RAW MATERIALS

NEODOL 25-12Bardac 22 (50%)Hydrochloric acid (35%)Cocobetaine (30%)Water, dye

Properti.es:Viscosity, 73F, cpsPhase coalescence temp., FpH

1 1>1761.0

% By Weight

3 .05.0

50.03 .0

to 100'6


LIQUID ACID-TYPE TOILET BOWL CLEANER

RAW MATERIALS

SURFONIC N-60KerosenePhosphoric AcidWater

% By Weight

101 71 360

Mix \dater, SURFONIC N-60 and acid, then add kerosene wi thrapid agitation; dilute 1 to 100 with water. Use at 180 to I90F.

SOURCE: Texaco Chemical Co.: Suggested Formulation

Bathroom Cleaners 7

PEARLESCENT TOILET BOWL CLEANER(2878-029)

RAW MATERIALS

AWaterTRYFAC 5552 Phosphate EsterTriethanolamine (TEA)EMID 6500 Coconut Monoethanolamide

BWaterTetrasodium EDTA (40%)Sodium rnetasilicate pentahydrateEthylene glycol n-butyl ether

% By Weight

34.01 . 01.04.0

52.05.02.01.0

Blending Procedure:Part A: Add the water to the first blending tank and heat

to 70C. While mixing, add the other ingredients listed in Part A.Mix until uniform and then cool to room temperature.

Part B: Add the water to the second blending tank. Whilemixing, add the other ingredients listed in Part B. Mix untiluniform.

Add Part B to Part A and mix until uniform.

SOURCE: Emery Chemicals: Specialty Chemicals Formulary:Formulation 2878-029

TOILET BOWL CLEANER(2878-029)

RAW MATERIALS

Tetrasodium EDTA (40%)TRYCOL 5941 POE (9) Tridecyl AlcoholTHYFAC 5559 Phosphate EsterSodium carbonateEthylene glycol n-butyl etherDye, fragrance, etc.Water

% By Weight

5.00.50.31.05.0q.s.

to 100

BJending Procedure:Add the water to the blending tank. While mixing, add the

remaining ingredients in the order listed. Mix until uniforrn.

SOURCE: Emery Chemicals: Specialty Chemicals Formulary:Formulation 2878-02~


TOILET BOWL CLEANER 8-34

RAW MATERIALS

Deionized WaterAVANEL S-9037% HCl

% By Weight

87.55.07.5

Mixing Procedure:Cnarge vessel with ingredients in the order listed using

moderate agitation

This is a liquid toilet bowl cleaner, comparable in effi-ciency to the solid cleaners containing sodium bisulfide. Ithas the added advantage of superior detergency, with the con-venience of a liquid. It can be applied from a plastic squeezebottle. The other AVANELS could be used in this formula asdesired.

SOURCE: Mazer Chemicals, Inc.: AVANEL S Formula: S-34

TOILET BOWL CLEANER-LIQUID

RAW MATERIALS

NEODOL 25-12UreaEDTA (a)Water, dye, perfume

% By Weight

5.010.00.5

to 100%

(a) Ethylenediamine tetraacetic acid, tetrasodium saJt (100%basis) .

Properties:Viscosity, 73F, cpsPhase coalescence temp., FpH

5>176

10.6


Bathroom Cleaners 9

TOILET BOWL CLEANER-SOLID

RAW MATERIALS

NEODOL 25-12PEG (1400) (b)Urea

% By Weight

10.010.080.0

(0) Polyethylene glycol with molecular weight about 1400.

SOURC£: Shell Chemical Co.: NEODOL Formulary: Suggested.r' 0 r mu I at ion

TOILET BOWL CLEANER, SOLID AUTOMATIC

RAW MA'rERIALS

T~ITON N-~98 Surfactant (a)UreaSodium Sulfate, Anhydrous

% By Weight

25.010.065.0

100.0

Biocides, water soluble dyes, perfumes or silicone defoamerscan be added.

(a) TRITON N-998 Surfactant-100%

Iv] i x ingIn s t r u c t ion s :Stir and heat a mixture of TRITON N-998 Surfactant and urea

until it becomes clear. Add sodium sulfate and mix thoroughly.Con t i. n u e mj ~~ i n g whi 1e cool ing. Dis c h a r get 0 a sui tab 1e cont a ine r .The product is a semi-solid which compacts on standing.

Lit. Ref.: CS-435

SOURCE: Rohm and Haas Co.: Specialty Chemicals: Detergent Form-ulations for Industrial and Institutional Industry



RAW MATERIALS

TRITON N-998 Surfactant (a)UreaSodiuill Sulfate, Anhydrous

% By Weight

35.05.0

60.0100.0

Biocides, water soluble dyes, perfumes or silicone defoamerscan be added.

(a ) TRI 'rON N- 9 9 8 Sur f actant - 7 0 %

Mixing Instructions:Stir and heat a mixture of TRITON N-998 Surfactant and urea

until it becomes clear. Add sodium sulfate and mix thoroughJy.Continue mixing while cooling. Discharge to a suitable container.The product is a semi-solid which compacts on standing.

Lit. Ref.: CS-435

SOURCE: Rohm and Haas Co.: Specialty Chemicals: DetergentFormulations for Industrial and Institutional Industry:Suggested Formulation A


RAW MArrERIALS

TRITON N-998 Surfactant (100%)Urea

% By Weight

18.082.0

100.0

Biocides, water soluble dyes, perfumes or silicone defoamersCdn be added.

Mixing Instructions:Heat TRITON N-998 Surfactant in a stirred reactor until it

is molten. Add urea (melting point 133C.) while increasing thetemperature. Continue stirring until the mixture is a uniform,clear liquid. Package while hot. Upon cooling, the product willsolidify to a hard mass.

Lit. Ref.: CS-435

SOURCE: Rohm and Haas Co.: Specialty Chemicals: DetergentFormulations for Industrial and Institutional Industry

2. Dishwashing Detergents

11


DISHWASH LIQUID CONCENTRATE

RAW MATERIALS

Linear alkylbenzene sulfonate(lOO%) (a)NEODOL 25-3A(60%)FADEA (b)Preservative(s)Water

% By Weight

27.022.5

4.50.1

to 100%

(a) Dodecylbenzene sulfonic acid (DDBSA) plus an equivalentamount of caustic (NaOH) can be used. pH should be between 5.5and 7.5 before NEODOL 25-3A is added (adjust with more DDBSAor caustic)

(b) fatty acid diethanol amide.

Properties:Viscosity, 73B, cpsActive matter, %w

Blending Procedure:Dissolve preservative and alkylbenzene sulfonate in water.

Add NEODOL 2S-3A slowly to well stirred mixture, then addamide. Best results will be obtained if water is warm (e.g.120f) .

SOURCE: Shell Chemical Co.: The NEODOL Formulary: SuggestedFormulation

DISHWASH LIQUID FROM CONCENTRATE--PREMIUM QUALITY

RAW MATERIALS

ConcentrateEthanol SD-3AWater, dye, perfume

Properties:Viscositj, 73F, cpsClear point, F

24032

% By Weight

71.14.0

24.9


Dishwashing Detergents 13

DISHWASH LIQUID FROM CONCENTRATE--GOOD QUALITY

RAW MATERIALS

ConcentrateEthanol SD-3AWater, dye, perfume

Properties:Viscosity, 73F, cpsClear point, F

Blending Procedure:Dissolve the ethanol

concentrate slowly withcitric acid.

% By Weight

55.62.0

42.4

23541

or sodium sulfate in the water. Add thestirring. Adjust the pH to 6.5-7.0 using

DISHWASH LIQUID FROM CONCENTRATE--ECONOMY

RAW MATERIALS % By Weight

Concentrate 44.4Water, dye, perfume 55.6

Properties:Viscosity, 73F, cps 195Clear point, F 39

Blending Procedure:Dissolve the ethanol or sodi.um sulfate in the water. Add the

concentrate slowly with stirring. Adjust the pH to 6.5-7.0 usingcitri.c acid.

DISHWASH LIQUID FROM CONCENTRATE--GENERIC

RAW MATERIALS

ConcentrateSodium sulfate, anhydrouswater, dye, perfume

Properties:Viscosity, 73F, cps 220Clear point, F 39

Blendi.ng Procedure:Dissolve the ethanol or sodium sulfate in

the concentrate slowly with stirring. Adjustusing citric acid.

% By Weight

22.23.0

74.8

the water. Addthe pH to 6.5-7.0



DISHWASH LIQUID--PREMIUM QUALITY

RAW MATERIALS

NEODOL 25-3S(60%)C12 LAS (60%)FADEA (b)Sodium xylene sulfonate (40%)Sodium chlorideWater, dye, perfume, preservatives

(b) Fatty acid diethanol amide.

Properties:Viscosity, 73F, cps 270Clear point, F 38Adjust pH to 6.5-7.0 with citric acid.

% By Weight

18.330.04.08.53.0

to 100%


DISHWASH LIQUID--GOOD QUALITY

RAW MATERIALS

NEODOL 25-3S (60%)C12 LAS (60%)FADEAEthanolWater, dye, perfume, preservatives

(b) Fatty acid diethanol amide


% By Weight

12.525.02.53.0

to 100%



DISHWASH LIQUID--ECONOMY

RAW MATERIALS

NEODOL 25-3S (60%)C12LAS (60%)FADEA (b)Sodium xylene sulfonate (40%)Sodium sulfateSodium chlorideWater, dye, perfume, preservatives

(b) fatty acid diethanol amide


% By Weight

8.313.5

1.93.00.61 • 0

to 100%


DISHWASH LIQUID--GENERIC

RAW MATERIALS

NEODOL 25-3S (60%)C12 LAS (60%)FADEA (b)Sodium xylene sulfonate (40%)Sodium chlorideWater, dye, perfume, preservatives

(b) Fatty acid diethanol amide

Properties:Viscosity, 73f, cps 209Clear point, F 18Adjust pH to 6.5-7.0 with citric acid.

% By Weight

5.59.21 .21 .02.0

to 100%



HAND DISHWASH LIQUID--HIGH QUALITY

RAW MATERIALS

C12 LAS (60%) (a)NEODOL 91-8NEODOL 25-3S (60%)fADEA (b)EthanolWater, dye, perfume, preservatives

Properties:Viscosity, 73F, cpsPhase coalescence temp., FClear point, FpH

67>176328.6

% by Weight

26.04.88.03.23.0

to 100%

HAND DISHWASH LIQUID--GOOD QUALITY

RAW MATERIALS

C12 LAS (60 %) (a)NEODOL 91-8NEODOL 25-3S (60%)FADEA (b)Ammonium chlorideWater, dye, perfume, preservatives

% By Weight

16.73.05.02.00.2

to 100%

Properties:Viscosity, 73F, cpsPhase coalescence temp., FClear point, FpH

18>176328.3

(a) May use the appropriate amount of dodecylbenzene sulfonicacid (DDBSA) with an equivalent amount of sodium hydrox-ide to neutralize it.

(b) Fatty acid diethanolamide.

Blending Procedure:Effective stirring should be maintained during addition of

all ingredients, and each ingredient should be in solutionbefore the next is added. Best results will be obtained ifwater is warm (e.g. 100-120F).

1. Dissolve the preservative, linear alkylbenzene sodi.umsulfonate (LAS), ethanol (when indicated) and ammoniumchloride (when indicated) in water.

2. Add the NEODOL 91-8.3. Add the NEODOL 25-3S slowly with efficient stirring.4. Add the amide with efficient stirring.5. Add perfume and dye as needed to give the desired odor

and color.

SOURCE: Shell Chemical Co.: The NEODOL Formulary: SuggestedFormulations


HAND DISHWASH LIQUID-ECONOMY (LAS/ETHOXYSULFATE/ETHOXYLATE)

RAW MATERIALS

C12 LAS (60¥5) (a)NEODOL ~1-8NEODOL 25-35 (60%)fADEA (b)Amlnonium chlorideWater, dye, perfume, preservatives

% By Weight

8.31.52.51.00.3

to 100%

(a) May use the appropriate amount of dodecylbenzene sulfonicacid (DDBSA) with an equivalent amount of sodium hydrox-ide to neutralize it.

(b) Fatty acid diethanolamide.

Blending Procedure:Effective stirring should be maintained during addition of

all ingredients, and each ingredient should be in solutionbefore the next is added. Best results will be obtained ifwater is warm (e.g. 100-120F).

1. Dissolve the preservative, linear alkylbenzene sodiumsulfonate (LAS), ethanol (when indicated) and ammoniumchloride (when indicated) in water.

2. Add the NEODOL 91-8.3. Add the NEODOL 25-3S slowly with efficient stirring.4. Add the amide with efficient stirring.S. Add perfume and dye as needed to give the desired odor

and color.


LIQUID DISHWASH(SLS/SULFONIC ACID-TEA/SURFACTANT)

RAW MATERIALS

VARSULF S1.333Sodium Laureth Sulfate (28%)Linear Alkyl Benzene Sulfonic Acid/TEAWater

Mixing Procedure:Add the ingredients in the order shown.

% By Weight

4.042.017.0

qs100

SOURCE: Sherex Chemical Co.: Industrial Formulation 13:01.2


HIGH ACTIVE DISHWASHING DETERGENT(30%) (2887-051)

RAW MATERIALS

WaterCaustic soda (50% sodium hydroxide)Dodecylbenzene sulfonic acid (DDBSA)EMERSAL 6453 Sodium Laureth Sulfate (28%)TRYCOL 5967 POE (12) Lauryl AlcoholTetrasodium EDTAEMID 6515 Cocamide DEASodium xylene sulfonate (40%) (SXS)Citric acid (50%) (to pH 6.5-7.5)Dye, fragrance, opacifier and preservative

% By Weight

to 1003.3

13.020.0

2.00.53.0g.s.g.s.

as desired

Blending Procedure:Cnarge the water to the batching tank and add the raw mater-

ials in the order listed. Warm water will facilitate blendingof surfactants. The pH of the batch tank should not be higherthan 5 after the DDBSA has been added. If not, adjust the pHwith sodium hydroxide before proceeding. Add sodium xylenesulfonate to adjust the formula to approximately 150-300 cP(Brookfield Viscometer) .

Adjust the batch to the final pH before the dye (as an aqueoussolution) is added. If an opaque, lotion-type product is desired,0.15% of an opacifier may be added. One part WITCOPAQUE R-25(Witco) or E-288 (Morton) opacifier must be preblended with threeparts water before its addition to the batch tank. The final pHJ11 us t be ad jus ted befor e the 0 pa c i. fie r is add e d .



HIGH ACTIVE DISHWASHING DETERGENT (30%) WITH SKIN CONDITIONER(2878-115)

RAW MATERIALS

WaterCaustic soda (50% sodium hydroxide)Dodecylbenzene sulfonic acid (DDBSA)SodiuJn ethoxylated alcohol sulfate (60% active)Sodium xylene sulfonate (40%) (SXS)EMID 6515 Cocamide DEAETHOXYLAN 1686 PEG-75 LanolinTRYCOL 5967 POE (12) Lauryl AlcoholCitric acid (50%) (to pH to 6.5-7.5)Dye, fragrance, preservative and opacifier

% By Weight

to 1003. 3

13.010.05.03.00.52.0q.s.

as desired

Blending Procedure:Add the water, caustic soda and DDBSA to the batch tank.

The pH of this mixture should be greater than 5.0. A low pHmay cause corrosion of the blending tank and should be adjustedby the addition of more caustic soda. While mixing, add theremaining ingredients to the blending tank in the order listed.Stir until uniform.Note: If no claims are made regarding skin conditioning effects,the PEG-75 lanolin can be omitted. This results in improved foamlevels. The viscosity of the finished product can be adjusted byincreasing or decreasing the SXS.



LIGHT DUTY LIQUID DISHWASHFormulation 1

RAW MATERIALS

DIACID H-240NaLASNeodol 25-3SMonoethanolamineWater

Formulation 2

RAW MATERIALS

DIACID H-240NaLASNeodol 25-3SDiethanolamideWater

% By Weight

7.515.01.7.24.0q.s. *

% By Weight

6.012.0

9 . 52.5q.s. *

* q.s.--quantity sufficient to make 100% total

Petroleum-based hydrotropes have been used for many years asstabilizers in liquid dishwash detergents. DIACID surfactantswill assure good formulation stability, and unlike other hydro-tropes, will contribute to the viscosity. While DJACID is noteffective at low pH, when used above pH 7.8, it provides recoveryfrom freezing temperatures without altering foaming performance.

SOURCE: Westvaco Chemical Division: DIACID Surfactants:Formulation 1 and 2

LIGHT DUTY LIQUID FORMULATIONMEDIUM COST HAND DISHWASH

RAW MATERIALS

Water, 0.1.DESONOL SEDESONATE 60-SVaramide MA-lPE'rRO LBA L iqu idSodium ChlorideFormalinPerfume, Dye

% By ~veight

41.818.330.04.02.83 .00.1q.s.

Blending Procedure: Blend ingredients in the order listed.Adjust pH = 6.5-7.0 using Citric Acid.

Typical Properties:Viscosity = 190 cpsClear Liquid

SOURCE: DeSoto, Inc.: Suggested Formulation


LIQUID DISHWASHING COMPOUND

RAW MATERIALS

WaterESI-TERGE T-60ESI-TERGE 8-10

% By Weight

70.0025.00

5.00100.00

CAS RegistryNumber

27323-41-761789-19-3

Procedure:Add in order listed and agitate until uniform.

Specifications:% Solids% ActivepHVi.scosity

20.020.07.0-7.5Medium

SOURCE: Emulsion Systems Inc.: Technical Service BulletinCode S-10-1

LIQUID DISHWASHING DETERGENTManual--High SudsingMixed Surfactant Type

RAW MATERIALS

WaterSodium alkylbenzene sulfonateIGEPAL CO-710GAFAlv11 DE CDD- 518

% By Weight

66.120.910.0

3.0100.0

Perfume, colorants and opacifiers added, as desired, replacingwater.

Manufacturing Procedure:1. Di.ssolve sodium alkylbenzene sulfonate. (Note: Alternat-

ively, alkylbenzene sulfonic acid can be neutralized wi.th sodiumhydroxide to yield the same sodium alkylbenzene sulfonateactivity. )

2. Add remaining components in the order listed.

Physical Properties:pH (as is)pH (1%)Viscosi.tySpecific Gravity

10.68.7600 cps1.02

SOURCE: GAP Corp.: Formulary: Prototype Formulation GAF 5202


LIQUID DISHWASHING DETERGENT

RAW MATERIALS

WaterBIO SOFT D-62STEOL CS-460NINOL 128-EXTRAPreservative

Mixing Procedure:Adjust pH to 7.0-7.8

Properties:% active: 25.0

formulation No.: 45:1


RAW MATERIALS

WaterBIO SOFT D-62SrrEOL CS-4 6 0N1NOL 12~-EXTRAPreservative

Mixing Procedure:Adjust pH to 7.0-7.8

Properties:% active: 31.0

Formulation No.: 45:11


RAW MATERIALS

WaterBIO SOfT 0-62STEOL CS-460NINOL 128-~XTRAPreservative

Mixing Pcocedure:Adjust pH to 7.0-7.8

Properties:% Active: 35.0

Formulation No.: 45-111

SOURCE: Stepan Co.: Suggested Formulations

% By Weight

62.425.06.56.00.1

% By Weight

51.932.010.0

6.00.1

% By Weight

45.933.015.0

6.00.1


LIQUID DISHWASHING DETERGENT (PREMIUM)

RAW MATERIALS

BIO SOFT LO-150Sodium chloride

% By Weight

98.81.2

Mixing Procedure:Blend ingredients in order given. Adjust pH with sulfuric

acid.

Properties:AppearanceViscosity @ 25C, cpspH, as is% soJidsFreeze/thaw (3 cycles)

clear yellow liquid2006.3

50.6Pass

Performance:Equal to "New" Joy by three test methods: Colgate Mini-Plate

test, Stepan DW-X test, and the "Pellet test."

SOURCE: Stepan Co.: Formulation No. 60

LIQUID DISHWASHING DETERGENT (MEDIUM)

RAW MATERIALS

WaterSTEPANATE XBIO SOFlr LO-190

Mixing Procedure:Blend ingredients in order given.

Properties:AppearanceViscosity @ 25C, cpspH, as isSoJids, %Cloud point, CFreeze/thaw (3 cycles)

% By Weight

62.35.0

32.7

clear yellow liquid2908.432.0


LIQUID DISHWASHING DETERGENTManual--High Sudsing

Anionic Type

RAW MATERIALS

WaterSodium alkylbenzene sulfonateSodiulTI xylene sulfonateALIPAL CO-436GAfAIV1IDE CDD-518

% By Weight

54.620.44.0

18.03.0

100.0

Perfume, colorants and opacifiers added, as desired, replacingwater.

Manufacturing Procedure:1. Add sodium alkylbenzene sulfonate to water and sodium

xylene sulfonate. (Note: Alternatively, alkylbenzene sulfonicacid can be neutralized with sodium hydroxide to yield thesame sodium alkylbenzene sulfonate activity.)

2. Add the remaining components in the order listed.

Physical Properties:pH (as is)pH (1 %)ViscositySpecific Gravity

8. 78.1600 cps1.02

SOURCE: GAF Corp.: Formulary: Prototype Formulation GAF 5201

HAND DISHWASHING DETERGENT

RAW MATERIALS

MIRANOL CS CONC.DodecylDenzene Sulfonic AcidSodium HyJroxide, 50%Igepal CO-630Cedemide CXWater

% By Weight

15.012.03.03.03.0

64.0

SOURCE: Miranol Inc.: MIRANOL Products for Household/IndustrialApplications: Suggested Formulation


DISHWASHING DETERGENT(24%) (2878-114)

RAW MATERIALS

WaterCaustic soda (50% sodium hydroxide)Oodecylbenzene sulfonic acid (ODBSA)TRYCOL 6953 POE (12) NonylphenolSodium ethoxylated alcohol sulfate (60% active)EMIO 6514 Cocamide DEASodium xylene sulfonate (SXS)Citric acid (50%) (to pH 6.5-7.5)Fragrance, dye, opacifier and preservative

% By Weight

to 1003.3

13.02.07.52.03 .0q.s.

as desired

Blending Procedure:To the blending tank, add the water, caustic soda and OOBSA.

At this point, the pH should be greater than 5.0 to preventtank corrosion. If not, immediately add more caustic soda.Add the remainder of the ingredients in the order listed. Theamount of EMID 6514 and SXS can be adjusted to obtain the desiredviscosity. Increase EMID 6514 to increase viscosity. IncreaseSXS to decrease viscosity.

Adjust the batch to final pH before the dye (as an aqueoussolution) is added.

SOURCB: Emery Chemicals: Specialty Chemicals Formulary:formulation 2878-114

PEARLESCENT DISHWASHING DETERGENT(2878-115)

RAW MATERIALS

WaterCaustic soda (50% sodium hydroxide)Dodecylbenzene sulfonic acid (ODBSA)TRYCOL 5943 POE (12) Tridecyl AlcoholEMIO 6500 Cocamide MEAEMEREST 2350 Glycol StearateEMERSAL 6453 Sodium Laureth SulfateSodium xylene sulfonate (40%) (SXS)Citric acid (50%) (to pH 6.5-7.5)Dye, preservative and fragrance

% By Weight

to 1003.3

13.02.01.01 .0

15.03.0q.s.

as desired

Blending Procedure:To the batch tank, add the water, caustic soda and OOBSA.

At this point, the pH should be greater than 5.0. If not, immed-iately add more caustic soda. Heat the batch to 150-170F. Addthe TRYCOL 5943, EMID 6500 and EMEREST 2350. Mix until theEM~REST 2350 has completely dissolved. Cool to 110 F and addthe remaining ingredients. Adjust the batch to final pH beforethe dye (as an aqueous solution) is added.

Note: The viscosity of the finished product can be adjustedby increasing or decreasing the SXS.

SOURCE: Emery Chemicals: Specialty Chemicals Formulary: 2878-115


DISHWASHING DETERGENT LIQUID, HAND(Clear)

RAW MArrERIALS

TRITON X-l02 Surfactant orTRI~ON X-l00 Surfactant

Sodium Linear Alkylate Sulfonate (60%)LauricdiethanolamideEthanol'~va ter

Use Dilution: 1 oz./2 gal. water.

Lit. Ref: CS-407, CS-427

% Active

12.023.0

3 .. 02 .. 0

60.0100.0

SOURCE: Rohm and Haas Co.: Specialty Chemicals: DetergentFormulations for Industrial and Institutional Industry:Lit. Ref.: CS-407, CS-427

DISHWASHING DETERGENT LIQUID, HAND(Pink Opacified)

RAW MArrERIALS

THITON X-I02Sodiurn Linear Alkylate Sulfonate (60%)LauricdietnanolamideLatex E-284 (40%) (Opacifier)Calcozine Rhodamine BX Conc.EthanolWater

Use Dilution: 1 oz./2 gal. water

Lit. Ref: CS-407

% Active

12.023.03.02.0

(0.0025)2.0

58.0100.0+

SOURCE: Rohm & Haas Co.: Specialty Chemicals: DetergentFormulations for Industrial and Institutional Industry:Lit. Ref: CS-407


GENERIC DISHWASHING DETERGENT (14 %) (2887-051)

RAW MATERIALS

WaterCaustic soda (50% sodium hydroxide)Dodecylbenzene sulfonic acid (DDBSA)EMERSAL 6453 Sodium Laureth Sulfate (28%)EMID 6514 Cocamide DEATetrasodium EDTA (40%)Citric acid (50%) (to pH 6.5-7.5)Sodium chlorideFragrance, dye, preservative and opacifier

Blending Procedure:

% By Weight

to 1002.5

10.09.01 .00.5q.s.1.0

as desired

Charge water to batching tank, then add raw materials i.n theorder listed. The pH of the batch tank should be higher than 5after the DDBSA has been added. If not, adjust with the sodiumhydroxide before proceeding.

A preblend of the sodium chloride with sufficient water tosolubiJize will facilitate the blending of this viscosityenhancer. One percent salt (NaCl) should give a viscosity greaterthan 100 cP at 25C (Brookfield Viscometer). Excessive use ofsalt should be avoided or the formula will not be stable.

Adjust the batch to final pH before the dye (as an aqueoussolution) is added.

For an opaque, lotion-type product, add 0.15% of an opacifi.er.One part WITCOPAQUE R-25 (Witco) or E-288 (Morton) opacifiermust be preblended with 3 parts water before addition to batchtank. Final pH must be adjusted before the opacifier solutionis added.



MEDIUM ACTIVE DISHWASHING DETERGENT(25%) (2887-051)

RAW MATERIALS

WaterCaustic soda (50% sodium hydroxide)Dodecylbenzene sulfonic acid (DDBSA)TRYCOL 6953 POE (12) NonylphenolEMERSAL 6453 Sodium Laureth Sulfate (28%)EMIO 6514 Cocamide OEATetrasodium EDTA (40%)Sodium xylene sulfonate (40%) (SXS)Citric acid (50%) (to pH 6.5-7.5)Dye, fragrance, preservative and opacifier

Blending Procedure:

% By Weight

64.73.3

13.02.0

15.02.00.5

g.s. (-3.0)q.s.

as desired100.0

Charge the water (warm, if possible) to the batching tankthen add the remaining raw materials in the order listed. IfhepH of the mixture should be higher than 5 after the ODBSA hasbeen added. If not, adjust the pH with sodium hydroxide beforeproceeding. Add sodium xylene sulfonate to adjust the formulato approximately 150-300 cP (Brookfield Viscometer) .

Adjust the batch to the final pH before the dye (as an aq-ueous solution) is added. If an opaque, lotion-type product isdesired, 0.15% of an opacifier may be added. One part WITCOPAQUER-25 (Witco) or E-288 (Morton) opacifier must be prebJended withthree parts water before its addition to the batch tank. Thefinal pH must be adjusted before the opacifier soJution isadded.

SOURCB: Emery Chemicals: Specialty Chemicals Formulary:Formulation 2887-051


CONCENTRATED LIQUID MACHINE DISHWASHING COMPOUND

RAW MATERIALS

MIRANOL J2M CONC.Potassium Hydroxide, 45%Kas i 1 # 1Sodium GluconateTetrapotassium PyrophosphateWater

% By Weight

2.09.0

27.02.0

14.046.0

SOURCE: Miranol Inc.: MIRANOL Products for Household/IndustrialAppJications: Suggested Formulation

INSTITUTIONAL LIQUID MACHINE DISHWASHING COMPOUND

RAW MATERIALS

MIRANOL JEM CONC.Tetrapotassium PyrophosphateSod i UIn Ivletas i 1 ica te Pentahydra tevvater

% By Weight

3.010.010.077.0

SOURCE: Miranol, Inc.: MIRANOL Products for Household/IndustrialApplications: Suggested Formulation

MEDIUM DUTY LIQUID MACHINE SPRAY WASH

RAW MATERIALS

MIRANOL J2M CONC.Potassium Hydroxide, 45%Kasil #1Gluconic AcidWater

% By Weight

1 .020.022.08.0

49.0

SOURCE: Miranol Inc.: MIRANOL Products for Household/IndustrialApplications: Suggested Formulation


AUTOMATIC DISHWASHING DETERGENT (POWDER)

RAW MATERIALS

SodiuJfl tripolyphosphate, densei-1AKON NF-5Britesil H-20CDB ClearonSoda ash, dense

% By Weight

40.03.0

30.02.0

25.0

White free flowing powder11.0

Mixing Procedure:Cnarge olender with soda ash. Add MAKON NF-5 and mix for one

minute. Add remaining ingredients and mix for one minute.Properties:

AppearancepH, at 1 %

Use Instructions:As per dishwasher manufacturer's instructions.

Performance:- excellent performance at low temperature- low foam & defoaming of food soils- no spotting, etching or streaking on glass wares- hardwater tolerance

Comments:MAKON NF-5 is an excellent low foaming and defoaming surfact-

ant

SOURCE: STEPAN CO.: Formulation No. 22

MECHANICAL DISHWASHING DETERGENTChlorinated Type

RAW MATERIALS

ANTAROX BL-330Sodium metasil~cate 5-H20Clearon COBSod i Udl tr ipo] yphosphate, powderSodium carbonate (It. density)

% By Weight

2.020.03.0

40.035.0

100.0

Manufacturing Procedure:1. Disperse ANTAROX BL-3302. Add sodium metasilicate

Clearon COB.Physical Properties:

pH (1%)Specific Gravity

in sodium tripolyphosphate.5-H20, sodium carbonbate and

11.2.70



MECHANICAL DISHWASHING DETERGENTLiquid Type

RAW MATEHIALS

IG~PAL CO-730 (1% active)GANrrREZ AN-1.4:)Potassiull1 hydroxide (50% acti.ve)Sodium silicate (46% active)AL~TAROX BL-330TetrapotassiuIn pyrophosphate (60% active)Water

% By Weight

0.51.03.0

17.03.0

63.312.2

100.0

Manufacturing Procedure:1. Dissolve GANTREZ AN-149 in IGEPAL CO-730/water mixture by

stirring at room temperature for eight hours. Heat to45-50C if not totally in solution.

2. Maintain heat at 45C and add rest of ingredients indiv-idually.

Physical Properties:pH (as is)pH (115)ViscositySpecific Gravity

13.210.41060 cps1.14

SOURCE: GAF CORP.: Formulary: Prototype Formulation GAF 5233

MECHANICAL DISHWASHING DETERGENTChlorinated Type

RAW MATERIALS

ANTAROX 13L-330Sodium tripolyphosphate, powderSodium metasilicate 5-H20Trisodium phosphate, chlorinated

% By Weight

2.048.020.030.0

100.0

Manufacturing Procedure:1. Disperse ANTAROX BL-330 onto sodium tripolyphosphate.

Mix well to avoid lumping of surfactant and powder.2. Add sodium metasilicate 5-H20. Add trisodium phosphate,

chJorinated. Mix thoroughly.

PhysicaJ Properties:pH (1.%)Specific Gravity

11.4.78

SOURCE: GAF CORP.: Formulary: Prototype Formulation GAF 5227


DISHWASHING DETERGENT, MACHINE(Chlorine-Releasing Agent)

RAW MATERIALS

TRITON CF-54 SurfactantSodi.um CarbonateSodium Tripolyphosphate (STPP)Sodium Metasilicate (Anhydrous)Sodium Dichloro-s-triazinetrione (CDB Clearon)

% By Weight

2.041.030.025.0

2.0100.0

Mixing Instructions:Thoroughly blend TRITON CF-54 Surfactant and soda ash, STPP,

and sodiurn metasilicate. Add chlorine-release agent.

Direction for Use:Add 2-4 tablespoons per load in household dishwashers.

SOURCE: Rohm and Haas CO.: Specialty Chemicals: DetergentFormulations for Industrial and Institutional Industry:Lit. Ref.: CS-412

DISHWASHING DETERGENT, MACHINE

RAW MATERIALS

WaterACRYSOL ASE-I08 StabilizerPotassium Hydroxide (50% solution)Tetca~otassium pyrophosphate (anhydrous)Potassium Silicate (40% solution)TKITON Cf-32 Surfactant (95% active)Dye

% By Weight

0.8911.1040.0020.0025.00

3.000.01

Mixing Instructions:Add the components slowly in the order listed with subsurface

agitation. Be sure each ingredient is completely solubilized ordispersed before adding the next one. A mixture that providesturbulence is recommended, but vortices should be avoided. Var-iations on the formulation are possible, but compatibility andproduct stability should be carefully evaluated.

Percent SolidspH (50% aqueous solution)Bulk Density, lbs./gal.Specific Gravity @ 25CViscosity, cps @ 25C

54.911.812.231.47

960

SOURCE: Rohm & Haas Co.: Specialty Chemicals: DetergentFormulations for Industrial and Institutional Industry:Lit. Ref: CS-432, CS-500



RAW MATERIALS

WaterACRYSOL ASE-108 StabilizerPotassium Hydroxide (45% solution)Tetrapotassium Pyrophosphate (anhydrous)Tetrasodium EthylenediaminetetraacetateTRITO~ CF-32 Surfactant (95% active)Dye

% By Weight

43.536.91.56

40.005.003.000.01

Percent SolidspH (0.5% aqueous solution)Bulk Density, lbs./gal.Specific Gravity @ 25CViscosity cps. @ 25C

49.810.411.951.43

280

SOURCE: Rohm and Haas Co.: Specialty Chemicals: DetergentFormulations for Industrial and Institutional Industry:Lit. Ref: CS-432/CS-500

DISHWASHING DETERGENT, MACHINE-A(Chlorine-Releasing Agent)

RAW MATERIALS

TRITON CF-10 Surfactant orTRITON CF-32 Surfactant

SOJium Tripolyphosphate (STPP)Sodium Metasilicate (Anhydrous)Sodium Dichloro-s-triazinetrione (CDB Clearon)

% By Weight

3.050.045.0

2.0100.0

Mixing Instructions:Thoroushly blend TRITON CF-detergent with builders.Add chlorine-release agent.

Directions for Use:Add 2-4 tablespoons per load in household dishwashers.

SOURCE: Rohm and Haas Co.: Specialty Chemicals: DetergentFormulations for Industrial and Institutional Industry:Lit. Ref: CS-432/CS-436


DISHWASHING DETERGENT, MACHINE-B(Chlorine-Releasing Agent)

RAW MATERIALS

TRITON CB-I0 Surfactant orTRITON CF-32 Surfactant

Sodium Tripolyphosphate (STPP)Sodium Metasilicate (Anhydrous)Soda Asl1Sodium Dichloro-s-triazinetrione (CDB Clearon)

% By Weight

2.034.040.022.02.0

100.0

Mixing Instructions:Thoroughly blend TRITON CF-detergent with builders.Add chlorine-release agent.

Directions for Use:Add 2-4 tablespoons per load in household dishwashers.Less costly version.

SOURCE: Rohm & Haas Co.: Specialty Chemicals: DetergentFormulations for Industrial and Institutional Industry:Lit. Ref: CS-432, CS-436

DISHWASHING DETERGENT, MACHINE (PHOSPHATES/SILICATE/SURFACTANT)

RAW MATERIALS

~va terACRYSOL ASE-I08 StabilizerPotassium Hydroxide (45% solution)Tetrapotassium Pyrophosphate (anhydrous)Trisodium Phosphate (anhydrous)Sodium Silicate (37.5%)TRITON CF-32 Surfactant (95% active)Dye

% By Weight

50.496.901 .27

20.005.00

13.333.000.01

34.6811 .010.85

1.30380

Properties:Sol ids, %pH (0.5% Ag. Soln.)Bulk Density, lb./gal.Specific Gravity @ 25CViscosity cps @ 25C

Mixing Procedure:Slowly add ingredients in listed order with subsurface agit-

ation in a vessel equipped with baffles and a 4-blade turbineimpeller. Avoid high-speed agitation and vortex formation whichmay entrap air bubbles. Dissolve or disperse each ingredientcompletely before adding.



DISHWASHING DETERGENT, MACHINE/BIODEGRADABLE-B(Chlorine-Releasing Agent)

RAW MATERIALS

TRITON DF-18 Surfactant (90%)Soda AshSod i um I"1e ta s i 1 ica te (Anhydrous)Sodium Trirolyphosphate (STPP)Sodium Oichloro-s-trazinetrione (CDB Clearon)

% By Weight

2.241.024.830.02.0

100.0

Mixing Instructions:Thoroughly blend TRITON DF-18 Surfactant with builders.Add chlorine-release agent.

Direction for Use:Add 2-4 tablespoon per load in household dishwashers.

SOURCE: Rohm and Haas Co.: Specialty Chemicals: DetergentFormulations for Industrial and Institutional Industry:Lit. Ref.: CS-405

MACHINE DISHWASHING DETERGENT

RAW MATERIALS

Sodium tripolyphosphateSodium carbonatePLURAr'AC HA-43 surfactant or

PLURONIC 25R2 polyolSodium metasilicdteSodium sulfateChlorinated isocyanurate

% By Weight

3510

32525

2

SOURCE: BASP Corp.: Cleaning Formulary: Formulation #3500



RAW MATERIALS

WaterACRYSOL ASE-108 StabilizerPotassium Hydroxide (45% solution)Tetrapotassium Pyrophosphate (anhydrous)Trisodium Phosphate (anhydrous)Sodium Nitrilotriacetate*TRITON CF-32 Surfactant (95% Active)Dye

* Sequestrant for use with hard water

% By Weight

55.766.901 .33

25.005.003.003.000.01

37.710.81.33

11. 1180

2-4 tbsp./gal.

Properties:SoliJs Content, %pH (0.5% age soln)Specific Gravity @ 25CB u I J( Density, lb. / g a IViscosity cps/25CUse Level

Mixing Procedure:Slowly add ingredients in listed order with subsurface agit-

ation in a vessel equipped with baffles and a 4-blade turbineimpeller. Avoid high-speed agitation and vortex formation whichmay entrap air bubbles. Dissolve or disperse each ingredientcompletely before adding the next one. Disperse dye in a smallamount of water withheld from the initial charge.

SOURCE: Rohm and Haas Co.: Specialty Chemicals: DetergentFormulations for Industrial and Institutional Industry:Lit. Ref: CS-432, CS-500

DISHWASHING DETERGENT, MACHINE/BIODEGRADABLE

RAW MATERIALS

TRITON Of-18 Surfactant (90%)Sodium lIydroxideSodium Metasilicate (Anhydrous)Sodium Tripolyphosphate (STPP)Sodium Dichloro-s-triazinetrione (CDB Clearon)

% By Weight

2.241.024.830.02.0

100.0

Mixing Instructions: Thoroughly blend TRITON Df-18 Surfactantwith builders. Add chlorine-release agent.

Directions for use:Add 2-4 tablespoon per load in household dishwashers.

SOUKCE: Rohm and Haas Co.: Specialty Chemicals: DetergentFormulations for Industrial and Institutional Industry:Lit. Ref.: CS-405


INDUSTRIAL DISHWASH FORMULATION: REGULAR DUTY, GOOD QUALITY,MILD LIQUID


6.82.35.00.81.38.01.80.6

to 100%

4537

7.4

NEODOL 91-6NEODOL 91-2.5DDBSA (98%)BADEASodium hydroxide (50%)Sodium xylene sulfonate (40%)Sodium tripolyphosphate, anhydrous basisSodium hexametaphosphateWater, dye, perfume, preservativesProperties:

Viscosity, 73F, cpsClear point, FpH

INDUSTRIAL DISHWASH FORMULATION: GOOD QUALITY POT AND PANCLEANER


NEODOL 91-6NEODOL 91-2.5DDBSA (98%)FADEASodium hydroxide (50%)Sodium hexametaphosphateSodium xylene sulfonate (40%)Water, dye, perfume, preservativesProperties:

Viscosity, 73F, cpsClear point, FpH

83378.6

10.54.58.83.32.22.05.0

to 100%

INDUSTRIAL DISHWASH FORMULATION: ALKALINE POT AND PAN CLEANER


NEODOL 91-6NEODOL 91-2.5NEODOL 25-35 (60%)DDt35A (98%)FADEADiethanolamineSodium hexametaphosphateWater, dye, perfume, preservativesProperties:

Viscosity, 73F, cpsClear Point, FpH

12234

9. 1

8.62.92.95.93.52.62.0

to 100%

SOURCE: Shell Chemical Co.: NEODOL Formulary: Formulations


LIQUID MACHINE DISHWASHING CONCENTRATE

RAW MATERIALS

MIRANOL J2M CONC.Potassium Hydroxide, 45%Kasil #1Tetrapotassium Pyrophosphate'dater

% By Weight

1.57.0

20.010.561.0

SOURCE: Miranol Chemical Co.: MIRANOL Products for Household/Industrial Applications: Suggested Formulation

MACHINE DISHWASHING DETERGENT

RAW MA'fERIALS

ALKAW£T CFSodium carbonateSodjum metasilicate, anhydrousSodi.um tripolyphosphate

% By Weight

2.018.030.050.0

SOURCE: Lonza: Product Information: ALKAWET CF: FormulationC-99-91

AUTOMATIC DISHWASHER DETERGENTPowder

Raw !vIa ter ia 1s

SURfONIC LF-17Sodium Metasilicate, anhydrousSodium TripolyphosphateSodium Carbonate

SOURCE: Texaco Chemical Co.: Suggested Formulation

% By Weight

2373725


MACHINE DISHWASHING FORMULATION

RAW MATERIALS

MAZER MACOL 40Tetrasodium PyrophosphateSodium TripolyphosphateSodium Metasilicate, PentahydrateChlorinated CyanurateSodium CarbonateWater*

% By Weight

3.035.020.010.02.0

18.012.0

Procedure:1. Spray a mixture of the MACOL 40 and water* onto the Tetra-

sodiulO pyrophosphate (alone or mixed with the other anhydrousinorganic salts) while continually mixing, whereby nydrationand simultaneous absorption of the surfactant occur.

2. Add the hydrated Sodium Metasilicate to the hydrated phos-phates, still mixing.

3. Add the Chlorinated Cyanurate to the mixture and continuemixing until homogenized and a dry, free-flowing, granular prod-uct is obtained. Chlorine-containing compounds which may also beused in this process include trisodium phosphate (chlorinated),trichlorocyanuric acid, salts of di-chlorocyanuric acid, dichlor-odimethylhydantoin (Halane) and other organic chlorine-activecompounds.

Maximum chlorine stability is obtained when the MACOL 40, dil-uted with water, is completely absorbed by the phosphate mixture.Step 1 avoids temperature control problems and eliminates theneed for an aging period.

In Step 2, hydrated Metasilicate does not promote agglomera-tion. It is essential that the Metasilicate be added after thephosphate mixture has hydrated and absorbed the surfactant, toavoid discoloration and degradation.

* The amount of water used should not exceed that shown in theformulation.

SOURCE: Mazer Chemicals, Inc.: Household/Industrial T-20B:Formulation 1

MACHINE DISHWASHING POWDER

RAW MATERIALS

MIRANOL JEM CONC. orMIRANOL J2M CONC.

Nitrilotriacetic AcidSodium Metasilicate PentahydrateSodium ChloroisocyanuratePolyethylene Glycol

% By Weight

0.741.055.32.01.0

SOURCE: Miranol Chemical Co.: MIRANOL Products for Household/Industrial Applications: Suggested Formulation

3. Disinfectants

40

Disinfectants 41

DISINFECTANT CLEANER

RAW MATERIALS

REWOTEHIC AM-V1,2 PropyleneglycolIngasan OP 300REVlOQUAT B 50Tetrapotassium PyrophosphateTrilon H, liquidWater

Mixing Procedure:lv1ix ingredi ents wi th water in order shown.

SOURCE: Sherex: Industrial Formulation 5:05.4

GENERAL DISINFECTANT SOLUTION

RAW MATERIALS

VARION COGVARIQUArr 5 U1"1CGlyoxal (40%)Water

% By Weight

20.06.00.55.06.01.0

qslOO

% By Weight

17.010.05.0

68.0

Mixin~ Procedure:Dissolve the 50MC into the water and add the Glyoxal and the

CDG.


GENERAL DISINFECTANT

RAW MATERIALS

VARION COGVARI QUA l' S 0 fvlCGlyoxal (40%)Hater

% By Weight

17.010.05.0

qs100

Nixing Procedure:Add SOMC and glycol to water followed by the COG.



DISINFECTANT CLEANERS*LIQUID CONCENTRATE WITH PHOSPHATE

RAW MATERIALS

NBODOL 25-9Bardac 22 (50%)Tetrapotassium pyrophosphatewater, dye, perfume

% By Weight

7.510.08.0

to 100%

Properties:Viscosity, 73F, cpsPhase coalescence temp., fpH

Use Concentration: 1-2 oz/gal.

3615810.6

HOSPITAL/CLINICAL STRENGTHRAW MATERIALS

NEODOL 25-9.bardac 22 (50%)EDTASodium carbonateBarguat MD-50 (50%)Sodium xylene sulfonate (40%)Water

% By Weight

7.015.06.03.0

10.05.0

to 100%


Use Concentration:For hospital use: 2 oz/gal.For institutional, non-hospital

31.>1.76

9.7

use: 1. oz/gal.

NON-PHOSPHATE LIQUID CONCENTRATERAW MATERIALS % By Weight

15>176

12.0

NEODOL 25-9Bardac 22 (50%)EDTASodium carbonateSodium metasilicate, pentahydrateSodium xylene sulfonate (40%)Pine oilWater, dye, perfumeProtJerties:

Viscosity, 73F, cpsPhase coalescence temp., fpH

Use Concentration: 2 oz/gal.* Cleaners making a disinfectant claim require EPA

registration.

6.09.05.01.00.95.05.0

to 100%

SOURCE: Shell Chemical Co.: The NEODOL Formulary: Formulations

Disinfectants 43

HOSPITAL DISINFECTANT


WaterVARIQUArr 50 MCVAROX 365Versene 100SodiuIn Hydroxide

84.29.64.01.50.7

SOURCE: Sherex: Industrial Formulation 35:5.4.2

SANITIZER--LIQUID, ACID

RAW MATERIALS

HOSTAPUR SAS 60GENAMINOX CS (amine oxide; 30~)Nonylphenol + 9 EOHydrochloric acid (37%)Phosphoric acid (85%)Water, parfume, dyestuff

% By Weight

7,55,05,0

10,010,0

ad 100,0

liquid

cloudy, stable

cloudy, viscous,400 mPas1,0cloudy, stable

Production procedure:HOSTAPUR SAS 60, GENAMINOX CS and Nonylphenol + 9 EO will be

dissolved in water. Afterwards one should add phosphoric acid,hydrochloric acid, parfume and dyestuff.Tests

Appearance at 20CViscosi.typH-Value (1%)Cloud point (-5C)Stabi.lity (4 Mon./40C)Freeze and thaw-test

SOURCE: Hoechst/Celanese: Formulation D-6016

SANITIZER(ALSO FOR SPRAY)--LIQUID, CLEAR


HosrrAPUR SAS 30GENAMINOX KC (amine oxide, 30%)Sodium hydroxide (100 %ig)Medialan LDSodium nypochlorite (150 gil active)LOSER GX 5 (AlkylarylpolyglycoJether)Water

10.010.01.02.5

50.05.0

21.5

Tests:pH-value (1%)Viscositystability (-5C)

11.348 mPasclear



SANITIZER: LIQUID, CLOUDY, CONTAINS CHLORINE

RAW MATERIALS

HOSTAPUH SAS 60GENAM1NOX CS (amine oxide; 30%)Sodiumhydroxid (100%)Sodiumhypochlorite (150 gil active)Water, parfume

% By Weight

2,53,31,0

50,043,2

Production procedure:HOSTAPUR SAS, GENAMINOX CS, parfume and NaOCl will be

dissolved in cold water and the other ingredients will beadded afterwards.

Note:This solution is cloudy but stable!Offers an excellent chlorine stability.

Tests:pH-value (10%)Viscosityfreeze and thaw testCloud point (-5C)Stdbility (4 Mon/40C)

12,540 mPaso.k.cloudy, stableo.k.


SANITIZING CLEANER(LIQUID, 12.5% A.M.)

RAW MATERIALS

HOSTAPUR SAS 60Nonylphenolethoxilate (6 EO)Lauryldimethylamine Oxide (30%)Phosphoric Acid (85%)~va te r

% By Weight

15.03.05.0

10.0AD100.0

Production Procedure:Dissolve HOSTAPUR SAS and nonionic in water. Add phosphoric

acid and GENAMINOX CS.

Tests:pH Value (10% Aqueous Solution T.Q.)Viscosity


1.7800 MPAS

4. Floor Cleaners and Wax Strippers

45


FLOOR CLEANER

RAW MATERIAL

DOWANOL PM glycol etherwateroleic aci.dtrietnanolarnine

Mix in order listed.

% By Weight

14581 612

SOURCE: Dow Chemical U.S.A.: The Glycol Ethers Handbook:Suggested Formulation

FLOOR CLEANER

RAW MATERIALS

WaterTriethanolamineM-PYROLOleic Acid

% By Weight

58.012.01 4.016.0

100.0

Manufacturing Procedure:Add oleic acid to water and, slowly, the rest of the compon-

ents.

Physical Properties:pH (as is)pH (1%)Viscosi t~iSpecific Gravity

8.28.030 cps1.01

SOURCE: GAF Corp.: Formulary: Prototype Formulation GAP 5352

Floor Cleaners and Wax Strippers 47

FLOOR CLEANER

RAW MATERIALS

Sodium carbonateTRYCOL 6964 POE (9) NonylphenolAcrysol ICS-lSodium xylene sulfonate (SXS)Ammonia (28 Be)Fragrance and dyeWater (soft)

% By ~ve ight

2.06.04.05.01 • 2

as desiredto 100

Blending Procedure:Add the water to the blending tank. While mixing, add the

ingredients to the blending tank in the order listed. Mixuntil uniform.


FLOOR CLEANER(Stable to 120F)

RAW MATERIALS

MAZER MACOL NP 9.5Sodium TripolyphosphateTri Sodiulo PhosphateNa Metasilicate PentahydrateMAZER MAPHOS 60AWater

% By Weight

78222

79

SOURCE: Mazer Chemicals, Inc.: Household/Industrial T-20B:Formulation 7


FLOOR CLEANERcloudy, liquid

RAW MATERIALS

HOSrfAPUH. SAS 60Nonylphenol + 4 EOOleic acidTriethanolaminWhite spiritTerpentinoilEDTAWater, dyestuff, perfume

% By Weight

10,05,02,02,0

30,010,0

2,039,0

8,9200 mPaso.k.cloudy but stable

Production process:HOSTAPUR SAS 60, NP-4 and EOTA will be mixed with perfume

before adding oleic acid, TEA, white spirit, terpentinoil andwater. This solution is cloudy but stable.Tests:

pH-value (10 ~ig)Vi.scosi tyfreeze and thaw testStability (4 Mon./40C)

SOURCE: Hoechst/Celanese: Formulation 0-4006

FLOOR CLEANER

RAW MATERIALS

waterAcrysol ASE-108 Polymer (18%)Sodium Hydroxide (10%)Sodium NitriteSodium Pentachlorophenate (Mitrol G-ST)TRITON X-100 Surfactant

% By Weight

82.284.722.800.150.05

10.00100.00

Mixing Procedure:Mix ACRYSOL ASE-108 Thickener with 1 part \vater and add to

the rest of the water. Add caustic slowly with agitation, thenother ingredients in listed order and mix completely.Note: Cleaners containing a mixture of sodium salts and nonionic

surfactant may discolor white vinyl tiles. Avoid excessivecleaner concentrations and prolonged contact.

Properties:Solids Content, % 11.33Appearance: Opaque off-white viscous liquidUse Level: 1 oz./4 gallons water



FLOOR CLEANERConcentrate

RAW MATERIALS

GAfAC LO-529Sodium tripolyphosphateTetrasodium pyrophosphateWater

% By Weight

6.03.03.0

88.0100.0

Manufacturing Procedure:1. Dissolve solids in the total amount of water.2. Add GAFAC LO-529. Mix thoroughly.

Physical Properties:pH (as is)pH (1 %)ViscositySpecific Gravity

13.98.9

60 cps1.02

SOURCE: GAF Corp.: Formulary: Prototype Formulation GAP 5354

FLOOR CLEANER

RA~v MATERIAL

GAFAC LO-S29GAFAMIDE COD-S18Tetrasodium pyrophosphate (60% active)Trisodium phosphateDiethylene glycol monoethyl etherWater

% By Weight

5.01.02.01.01 .0

90.0100.0

Perfume and colorants added, as desired, replacing water.

Manufacturing Procedure:1. Dissolve tetrasodium pyrophosphate in water. Add tri-

sodium ~hosphate. Dissolve thoroughly.2. Add GAFAC LO-529 and GAFAMIDE CDD-518.3. Add solvent.

Physical Properties:pH (as is)pH ( lSi»ViscositySpecifi.c Gravity

11.09.0

290 cps1.01



FLOOR CLEANERLiquid, Opaque


Wax (HOECHST-WACHS VP KST)HOSTAPUR SAS 60NonyJphenolethoxilate (10 EO)Isotridecylalcohol Ethoxilate (8 EO)Polyoxipropylen-Polyoxiethylen Condensate (GENAPOL PF 20)EDTA-SolutionMethyl GlycoleWater (rIot, 60C)Water (Cold), Dye, Perfume Oil

20.03.01.02.02.01.01.0

39.031.0

10.4Approx. 65 MPASOpaqueO.K.

Production Procedure:Melt HOECHST-WACHS VP KST and dissolve it in hot water.Add HOSTAPUR SAS, Nonylphenolethoxilate, Isotridecylalcohol-Ethoxilate, Polyoxipropylen-Polyoxiethylen Condensate and theEDTA solution. Mix Methyl Glycole with the cold water and addit to the cooled off solution. Dye and perfume will be addedin the end.

Tests:pH Value (10% Aqueous Solution T.O.)ViscosityStability (-5C)freeze and Thaw Test

SOURCE: Hoecnst/Celanese: Formulation D-4004

FLOOR CLEANER (GARAGE)

RAW MATEHIALS

TRITON X-114 SurfactantTallow Soap (Excelsior Soap)Dipropylene Glycol Methyl Ether (Dowanol DPM)Trisodium Phosphate (TSP)Sodium Metasilicate PentahydrateWater

% By Weight

2.52.06.53.03.0

83.0100.0

Mixing Instructions:Stir TRITON X-114 and Dowanol DPM until homogeneous.Add tallow soap, then water after soap dissolves.Add TSP and metasilicate.

Directions for Use:Apply directly to oil spots. Allow 5 minutes to penetrate.Flush with water.

SOURCE: Rohm and Haas Co.: Specialty Chemicals: DetergentFormulations for Industrial and Institutional Industry:Lit. Ref.: CS-409


FLOOR CLEANER-LOW FOAM MACHINE APPLIED*

RAW MATERIALS

NEODOL 91-6Triton H-66Tetrapotassium pyrophosphatePotassium hydroxide (45%)Water, dye, perfume


Use Concentration: 1-2 oz/4 gaJ.

51371 3.4

% By Weight

3.04.08.01.5

to 100%

* CAUTION: This solution may discolor vinyl tiles if allowedto remain for lengthy periods.


FLOOR CLEANER, LOW-FOAM MACHINE SCRUBBER

RAW MATERIALS

T~ITON 02-12 SurfactantTetra~otassium Pyrophosphate (TKPP)TRITON H-66 Surfactant (50%)Water

Appearance: Clear solution to 40C (104F.)

% By Weight

4.0B.O

10.078.0

100.0




RAW MATERIALS

TRITON X-114 SurfactantTRITON H-66 Surfactant (50%)Tetrapotassium Pyrophosphate (TKPP)Potassium Hydroxide (4S~)Water

Use Dilution: 1 to 2 oz./4 gal. water

% By Weight

3.04.08.02.5

82.5100.0

SOURCE: Rohm & Haas Co.: Specialty Chemicals: DetergentFormulations for Industrial and Institutional Industry:Lit. Ref.: CS-409, CS-433


RAW MATERIALS

WaterACRYSOL ASE-108 Thickener (18%)Potdssium Hydroxide (45%)Tetrapotassium Pyrophosphate (Anhydrous)T~isodium Phosphate (Anhydrous)Potassium Silicate (Kasil #6)TRITON DF-12 Surfactant

Mixing Procedure: Add in listed order.

% By Weight

53.278.333.4

22.05.05.03.0

100.0

Properties:Solids Content, %AppearanceViscosity cps 2SCUse Level

38.83Milky emulsion500 (3 days after preparation)1-2 oz./4 gallons water

SOURCE: Rohm and Haas Co.: Specialty Chemicals: DetergentFormulations for Industrial and Institutional Industry:Lit. Ref.: CS-415, CS-SOO


FLOOR CLEANER WITH FBR

RAw l"lATEHIALS

l)Sodium tripolyphosphate (STP)Tetrapotassium pyrophosphate~Vd ter

% By Weight

2.22.2

95.6

7.0

Mixiny ProcedureStir in STP and Pyrophosphate into water. Stir solution until

clear. Stir in ~BR using good dgitation.

SOURCE: Sherex Chemical Co.: Industrial Formulation 28:1.3

FLOOR CLEANER-GARAGE FLOOR

RAW MATERIALS

NEODOL 91-6rr r iton H- 6 6Butyl OXITOLTrisodium phosphate, anhydrous basisSodium metasiJ.icate, pentahydrateWater, dye, perfume

Properties:Viscosity, 73F, cps 6Pnase coalescence temp., F 126pH 13

% By Wei.ght

5.04.06.51.33.0

to 100%

BlenJing Procedure for Garage Floor Only:Add builders last with vigorous mixing until homogeneous.

SOURCE: Shell Chemical Co: NEODOL Formulary: Suggestedformulation


FLOOR CLEANER/WAX STRIPPER

RAW MATERIALS

WaterKLEAHFAC AA-270 surfactantTetrapotassium pyrophosphatePotassium hydroxide (45%)

% By Weight

83692

Suggested use concentration: 2-4 oz. per gallon of water

SOURCE: BASF Corp.: Cleaning Formulary: Formulation #3476

FLOOR CLEANER/WAX STRIPPER*

RAW MATERIALS

WaterSodium Hydroxide (50%)Triton QS-44 Surfactant (80%)Sodium Metasilicate, AnhydrousTetrapotassium Pyrophosphate (TKPP)Tetrasod i Ulll Pyropnospha te (TSPP)

% By Weight

74.03.43.20.4

12.07.0

100.0

* Addition of 1% Ammonium Hydroxide will allow easy removalof ~olimer finish from most types of floors.

Mixiny Instructions:Mix in listed order, agitating to complete uniformity before

adding next ingredient.

Properties:AppearancepHViscosity, cps.

Use Dilution:Cleaning - 4 oz./gal. waterStripping - 16 oz./gal. water

clear13.410

SOURCE: Rollm and Haas Co.: Specialty Chemicals: DetergentFormulations for Industrial and Institutional Industry:Lit. Ref.: CS-410


FLOOR CLEANER AND WAX STRIPPER

RAW MATERIALS

MAZER I'-1ACOL 25Oleic AcidMEATetrasodium PyrophosphateWater

% By Weight

10555

75

SOURCE: Mazer Chemicals, Inc.: Household/Industrial T-20B: 6

FLOOR CLEANERS AND WAX STRIPPER

RAW MATERIAL

SURFOUIC N-95[vlonoethano 1deni neAlkaline DuildersWater, dye, fragrance

% By Weight

11-2

As desiredAs desired*

FLOOR CLEANER AND WAX STRIPPER

RAW MATERIALS

SURfOtlJIC N-85Tetrapotassium** pyrophos~hateTrisodium phosphateWater, dye

% By Weight

821

As desired*

* These products should be diluted with water 20 to 1 when usedas a WdX stripper and 80 to 1 when used for general cJeaning.

** Or tetrasodium

'fhe detergency and wetting properties of SURFONIC N-95 areutiJized in industrial floor cleaners and wax strippers.Inclusion of Inonoethanolarnine provides wax stripping capability.

SOURCE: Texaco Chemical Co.: SURFONIC N-Series Surface-ActiveAgents: Suggested Formulations


FLOOR CLEANER/WAX STRIPPER*


WaterDipropylene Glycol Methyl Ether (DOWANOL DPM)MonoethanolarnineTRITON N-101 Surfactant or

TRITON X-100 SurfactantTetrasodium Ethylenediaminetetraacetate (VERSENE 100-39%)Sodium Hydroxide (50%)TRITON QS-30 Surfactant (90%)Sodium Metasilicate, Anhydrous

77.04.00.5

5.06.01.03.03.5

100.0

* Addition of 1% Ammonium Hydroxide will allow easy removal ofpolymer finish from most types of floors.

Mixing Instructions:Mix in listed order agitating to complete uniformity before

adding next ingredient.

Properties:AppearancepHViscosity, cps.

Use Dilution:Cleaning: 8 oz./gal. waterStripping:16 oz./gal. water

clear13.310

SOURCE: Rohm and Haas Co.: Specialty Chemicals: DetergentFormulations for Industrial and Institutional Industry:Lit. Ref.: CS-408, CS-427, CS-439

FLOOR WAX STRIPPER

RAW MATERIALS

DOWANOL PM glycol ethertrisodium phosphateTriton X-IOO surfactantwater

% By Weight

8.02.58.5

81.0

Dissolve trisodium phosphate in water. Then mix in theTriton X-IOO followed by DOWANOL PM.

SOU~CE: Dow Chemical U.S.A.: The Glycol Ethers Handbook:Suggested Pormulation


FLOOR

advanced cleaning product formulations · 2019. 2. 28. · the formulations in this book are...

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