air pollution by industries
TRANSCRIPT
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Air Pollution by Industries
Tikam chand
M.Tech. (Energy)
Deptt. of Mechanical Engg. , MNIT, Jaipur
(email: [email protected])
Abstract
Industries play major part of increasing air
pollution which effects the environment.
Today it is necessary to take action over
pollution and take some actions to reduce it.
This paper discuss the pollutants generate by
the industries, there effects. Control
techniques used in the some countries in their
industries of steel, cement, oil etc are also
discuss
1. Introduction
Air is an important natural resource
providing the basis of life on earth. Pollution
had been known to exist for centuries, but
it became an issue of serious concern only in
the last 200 years or so, mostly due to
the industrial revolution. Atmospheric
pollution occurs because the release of air
pollutants takes place at a rate much faster than they
can be accommodated by the environment and
removed from the atmosphere without causing
serious harm. Air pollution is a release into
the atmosphere of any substances, e.g.
Chemicals or airborne particles, which are
harmful both to the human and animal health
as well as the health of wider environment.
Air pollution is defined as the
addition of various hazardous chemicals,
particulate matter, toxic substances and biological
organisms into the Earth's atmosphere Industries
can discharge contaminants into the air.
Approximately 11% of public complaints
about air quality in the region are about
odour or dust from industry.
The problem with industrial air pollution is
that the release of toxins from plants and
industrial institutions is very high for the per
capita allowance. More air pollution problems are caused by industrial institutions
than anything else, and many of these
institutions are in chronic violation of air
pollution regulations. Industrial air
pollution is one of our biggest air pollution
problems in the world. In every country we
have problems with the toxic gases that are
released into the air every day while our
products are made and our trash is burned.
2. Origin of industrial pollution
Industrial air pollution can be from the
following:-
-Pollution from thermal power plants.
-Pollution due to chemical fertilizers, food, pesticide
and pharmaceutical industries.
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-Pollution due to cement, steel, paper, sugar
industries.
-Pollution due to textile and textile related industries.
-Pollution due to petroleum and other industries.
-Pollution due to atomic units.
3. Types of air pollutants
Carbon Dioxide (CO2) – This is one of the
major gas pollutants in the atmosphere.
Major sources of CO2 are due to burning of
fossil fuels and deforestation. Industrially
developed countries like USA, Russia etc.,
and account for more than 65% of CO2
emission. Less developed countries with 80%
of world’s population responsible for about
35% of CO2 emission. Due to high growth
reported from less developed countries in last
decade, it is estimated that, the Carbon
dioxide emissions may rise from these areas
and by 2020 their contribution may become
50%. It has also been seen that, Carbon
dioxide emissions are rising by 4% annually.
As ocean water contains about 60 times more
CO2 than atmosphere; CO2 released by the
industry leads to disturbance of equilibriumof concentration of CO2 in the system. In
such a scenario, the oceans would absorb
more and more CO2 and atmosphere would
also remain excess of CO2. As water warms,
ocean’s ability to absorb CO2 is reduced.
CO2 is a good transmitter of sunlight, but
partially restricts infrared radiation going
back from the earth into space. This produces
the so-called “Greenhouse Effect” that
prevents a drastic cooling of the Earth during
the night. This so-called “Greenhouse Effect”
is responsible for GLOBAL WARMING.Currently Carbon Dioxide is responsible for
major portion of the global warming trend.
Nitrogen oxides (NOx) – They come mainly
from nitrogen based fertilizers, deforestation,
and biomass burning. Nitrogen oxides
contribute mostly as atmospheric
contaminants. These gases are responsible in
the formation of both acid precipitation and
photochemical smog and causes nitrogen
loading. These gases have a role in reducing
stratospheric ozone.
Sulfur Dioxide (SO2) – Sulfur dioxide is
produced by combustion of sulfur-containingfuels, such as coal and fuel oils. SO2 also
produced in the process of producing Sulfuric
Acid and in metallurgical process involving
ores that contain sulfur. Sulfur oxides can
injure man, plants and materials. As
emissions of sulfur dioxide and nitric oxide
from stationary sources are transported long
distances by winds, they form secondary pollutants such as nitrogen dioxide, nitric
acid vapor, and droplets containing solutions
of sulfuric acid, sulfate, and nitrate salts.
These chemicals descend to the earth’s
surface in wet form as rain or snow and in
dry form as a gases fog, dew, or solid
particles. This is known as acid deposition or
acid rain.
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Chlorofluorocarbons(CFCs) –
Chlorofluorocarbons, also known as Freons,
are greenhouse gases that contribute to global
warming. CFCs are responsible for loweringthe average concentration of ozone in the
stratosphere.
Smog – Smog is the result from the
irradiation by sunlight of hydrocarbons
caused primarily by unburned gasoline
emitted by automobiles and other combustion
sources. Smog is created by burning coal and
heavy oil that contain mostly sulfur impurities.
Dust - Generation of fine particulates and
dust are inherent in the process of Cement
industries, but most are recovered and
recycled. The sources of dust emission
include clinker cooler, crushers, grinders and
material-handling equipments. Material-
handling operations such as conveyors result
in fugitive dust emission.
4. Effects of industrial pollution
Global Warming - Global warming is
largely considered one of the most hazardous
and serious complications associated with air
pollution caused by industries. The liberation
of certain gases such as methane, or CH4,
and carbon dioxide, or CO2, together known
as greenhouse gases, is often considered to be
prime factors causing global warming. These
greenhouse gases often result in an increase
in the atmospheric temperature, causing
global warming. Global warming has various
serious implications both on the ecological balance as well as human health. It often
results in the melting of glaciers and
snowcapped mountains, resulting in an
increase in the water levels of seas and rivers,
eventually increasing the risk of floods.
Apart from this, global warming also often
has numerous serious health risks on humans
such as increase in diseases like Lyme,malaria, cholera, dengue and plague, among
others.
Acid Rain - Industries often emit large
amounts of nitrogen and sulphur gases
into the Earth's atmosphere. When
these gases react with water vapors in
the atmosphere, they often change into
more aggressive gases, namely nitric
acid and sulphuric acid respectively.
The rain containing large amounts of
these acids is known as acid rain. Acid
rain has various health and natural
dangers. It results in the erosion of
monuments and buildings, makes the
soil acidic in nature, resulting in
reduction of plant and animal growth,
among other issues. Apart from these,
acid rain causes serious health
disorders such as cancer, skin
disorders and even death.
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Respiratory Disorders - The emission of
various gases such as carbon
monoxide, or CO, often results in
various respiratory disorders such as bronchitis, asthma, chronic obstructive
pulmonary disease, or COPD, in
individuals. CO damages air passages
in individuals, leading to respiratory
disorders. However, if carbon
monoxide is present in increased levels
in the atmosphere, it can even cause
the death of the person, by inhibitingoxygen intake by combining with
hemoglobin.
Ozone Layer Depletion - The ozone layer is
a gaseous blanket that helps in
supporting and sustaining life on Earth
by protecting us from various
hazardous radiations such as UV rays.
Hence, the addition of some of the
above mentioned pollutants often
damages the atmosphere, thus causing
various health risks in humans such as
skin disorders like rashes, irritation
and even cancer in severe cases.
5. Control Techniques
Industrial activities are so different, one from
the other, it is impossible to arrive at any
single solution—or even any single set of
solutions—to the variety of pollution
challenges that they present. There are many
approaches that can be adopted, but generic
measures to provide financial or other
incentives at the plant level seem to work the
best. However, there are opportunities for
improving machines and other devices thatmany different factories and industries use.
Industrial Boilers and Motors
Industrial boilers burn coal, oil and other
fossil fuels or very often gases that are by products of the production process, to
generate hot water or steam used in a variety
of ways. Chemical plants, for example, use
the heat to change one substance into
another. Paper mills will use it to “pulp”
wood, which creates the raw material for
paper. Because boilers are common to so
many industrial processes, boosting their efficiency will sharply reduce emissions.
Similarly, electric motors are widely used in
industrial applications, so increasing their
efficiency will also reduce pollution. Motors
that have been used most commonly in the
past have efficiencies ranging from 60 to 90
percent, but versions are now available to
reach 95 percent.
Better Boilers- One specific way of
improving the efficiency of boilers deserves
special mention because is can be used so
widely, but isn’t in the U.S.
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Cogeneration of heat and power-In the vast
majority of cases, the largest single
improvement in efficiency and reduction in
air pollution that can be made at an industrialfacility is through the adoption of
cogeneration—also known as combined heat
and power, distributed generation, or
recycled energy—which is the simultaneous
production of two or more forms of energy
from a single fuel source. Most often, fuel is
burned to generate electricity and the leftover
heat, which otherwise would simply bereleased into the air, is used to make
chemicals, process food or the like.
Cogeneration facilities can extract 80 to 85
percent of the energy in fuel, significantly
reducing the air pollution compared to
facilities where electricity and heat are
produced separately. The engine used to
generate electricity canvary from large
diesels to giant turbines, but the approach is
the same: make the electricity and use the
heat that would otherwise be wasted. The
heat can also be used to provide air
conditioning, using absorption chillers in
which heat is used to run a compressor
instead of electricity, in which case it is
called trigeneration. Whatever the name,
cogeneration is used widely in Europe, but is
the exception not the rule in the United
States. Most of the nation’s CHP stations are
small facilities, operated on college
campuses, military bases or offices, hospitals
and other commercial facilities.
Increasing boiler efficiency-Increasing
boiler efficiency, thus reducing air pollution,
can be accomplished in a variety of ways:
1.Proper maintenance, which can include awide range of options, such as blowing soot
from surfaces, tune ups, and reducing excess
air.
2.Reducing the need for steam and, thus use
of the boiler, by eliminating leaks, insulating
pipes, recovering heat. These can boost
system efficiency by 5 to 40 percent, and
costs are usually recovered in one to twoyears.
3. Improving the operating system by, for
example, installing devices that allow loads
to be automatically controlled, which also
saves money by reducing fuel consumption.
4. Switching from coal or oil to natural gas,
this reduces operating costs and extends the
plant’s lifetime by eliminating corrosion and
other damage from pollution-rich fuels.
Electric Motor System
Motors produce air pollution indirectly using
electricity, so the emission reductions that
result from improving efficiency will dependon the type of fuel used by the generator. The
amount of electricity consumed by these
motors can be huge. In California, for
example, one-third of the electricity is used
to move water. Standard motors operate with
an efficiency of 60 to 70 percent for small
devices of a few kilowatts, to 92 percent for
large motors of 100 or more kilowatts. High-
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efficiency motors operate in the range of 83
to more than 95 percent.
Some of the opportunities lie in improving
the efficiency with which the output of a
motor is used, not in the motor itself. One
analysis of an industrial pumping system, for
example, found that only 49 percent of the
energy output of the electric motor was
actually converted into work to move the
liquid. Optimizing system design rather than
simply choosing components can lead to
improvements of 60 percent using existing
technology. One study found that replacing
traditional power-transmission “V” belts with
modern flat belts could improve efficiency
from 85 to 98 percent. Adjustable-speed
electronic drives that better match
mechanical load reduce electricity demand.1
An energy-efficient motor costs more to buy,
with a price typically 15 to 30 percent above
that of a standard motor. But over a typical
10-year operating life, a motor can easily
consume electricity valued at over 57 times
its initial purchase price. So, for example,
with the purchase of a $1,600 less-efficientmotor, a buyer may be committing much
larger electricity bills. In the case of the
$1,600 motor, paying a bit more up front—
say, $400—will reduce electricity
consumption by 3 percent, saving $2,760.
Purchasing new or replacement energy-
efficient motors makes good economic sense.
Now for a closer look at three specific
industrial sectors that are the largest
consumers of energy and sources of air
pollution: cement kilns, steel making and oil
refineries.
Cement Kilns
Cement production consumes vast amounts
of energy and raw materials, so what comes
out of the smoke stack is not pretty. The
pollutant emitted in largest quantity is carbon
dioxide. Cement accounts for roughly 22
percent of the carbon dioxide emitted by the
world’s industries. This is for two reasons:
First, the raw material for cement is
limestone, or calcium carbonate—seashells
deposited millions of years ago. One of the
first steps in cement production is to
“decarbonize” it, or drive off the carbondioxide that it contains by burning. Older
kilns do this in a huge rotating kiln in which
the mass of materials is so wet that the
process takes roughly 30 minutes and large
amounts of energy.
Second, producing the heat for baking burns
huge quantities of fuel, usually whatever is
the cheapest, which means it’s usually the
dirtiest as well. The owners will burn
whatever they get their hands on, everything
from coal and used tires to hazardous wastes
and city trash. As a result, for every ton of
Portland cement produced, roughly one ton
of carbon dioxide is emitted, as well as other
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pollutants such as black carbon, dioxins,
mercury and the like. Because so much of
carbon dioxide comes from “decarbonizing”
the essential ingredient of cement, it mightseem likely that cutting emissions would be
tough. Not so. Emissions can also be sharply
reduced by substituting other materials for
limestone to produce so-called “blended”
cements. Substitute materials include blast
furnace slag from steel mills and fly ash from
coal-fired power plants. Blended cement sets
a bit more slowly, but produces a stronger and longer-lasting concrete. In some nations
(e.g., The Netherlands), all concrete is made
from blended cement. Individual states
determine how much pollution is emitted
from cement kilns because they are the
principal customers. The state highway
department sets specifications for concrete
used to build highways, and their
counterparts who build schools, courthouses
and the like do the same for them, and those
who write the building codes determine what
architects and contractors do. Requiring
blended cement might not be as simple as
snapping fingers, but it is certainly no
herculean task. Other pollution can be cut by
switching from a wet kiln to the more
efficient, and hence cleaner, dry process.
Then there’s the question of fuel: kiln
operators are willing to use any fuel that will
sustain a flame, but that needn’t be the case.
The kilns could just as easily burn natural gas
instead of coal, used tires or hazardous waste.
For that matter, burning isn’t required at all,
just heat. That can be provided by the sun’s
energy or electricity.
Dust in Cement Plant and CHP
Several mechanical equipments are used in
cement manufacturing plant to control /
collect dust. These are:
Dust collector - A dust collector (bag house)
is a typically low strength enclosure that
separates dust from a gas stream by passing
the gas through a media filter. The dust is
collected on either the inside or the outside of
the filter. A pulse of air or mechanical
vibration removes the layer of dust from the
filter. This type of filter is typically efficient
when particle sizes are in the 0.01 to 20
micron range.
Cyclone - Dust laden gas enters the chamber from a tangential direction at the outer wall
of the device, forming a vortex as it swirls
within the chamber. The larger articulates,
because of their greater inertia, move
outward and are forced against the chamber
wall. Slowed by friction with the wall
surface, they then slide down the wall into a
conical dust hopper at the bottom of thecyclone. The cleaned air swirls upward in a
narrower spiral through an inner cylinder and
emerges from an outlet at the top.
Accumulated particulate dust is deposited
into a hopper, dust bin or screw conveyor at
the base of the collector
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Electrostatic Precipitator - In an
electrostatic precipitator, particles suspended
in the air stream are given an electric charge
as they enter the unit and are then removed by the influence of an electric field. A high
DC voltage (as much as 100,000 volts) is
applied to the discharge electrodes to charge
the particles, which then are attracted to
oppositely charged collection electrodes, on
which they become trapped. An electrostatic
precipitator can remove particulates as small
as 1 μm (0.00004 inch) with an efficiencyexceeding 99 percent.
Steel Making
The iron and steel industry is the largest
energy-consuming manufacturing industry in
the world, accounting for 10 to 15 percent of
the annual industrial energy consumption.
Annual world steel production has increased
from about 100 million tons in 1945 to about
770 million tons in 1990, and is expected to
grow further, by about 1.7 percent a year,
mainly because of an increase in steel
consumption in developing countries. Air
pollution, sometimes in prodigious amounts,
is produced at several stages in making steel.
Options for reducing pollution in each stage
are:
Coking: coke oven emissions are highly toxic
—is to assure that the oven doors are tightly
closed. But an even better option is to make
steel without coke, using a process nowemployed in South Africa and South Korea.
Casting: Continuous casting in which the
steel is rolled immediately, thus avoiding the
energy and pollution from reheating, is
employed widely in other countries,
especially Japan.
Cogeneration: Many of the gases produced
during the production of steel can themselves
be burned to generate electricity. Doing so
increases efficiency and eliminates air
pollution.
Oil Refineries
Refining is most energy intensive industry
and the source of immense amounts of air
pollution Refinery pollution and energy
consumption can both be reduced through a
variety of measures.
Process integration- So many streams of
different fluids are constantly passing
through a refinery, undergoing conversions
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that are so complex and numerous that they
inevitably reach a point where there is a
“pinch” in the system that slows things down
and cuts efficiency. To avoid these, analystshave developed a methodology to optimize
the system called, not surprisingly “pinch
analysis.” In recent years, it has been
extended to virtually every aspect of refinery
operation, in part because it has greater
potential for increasing efficiency than any of
the more traditional measures, such as
cogeneration.
Energy recovery-At various points in the
refining process fluids are lost that could be
captured and used either in the refining
process itself or to generate electricity. Some
of these are burned, or flared, as they are
vented to the air. Capturing these and using
them, either by re injecting them into the
stream of refinery fluids or burning them for
electricity generation, increases efficiency
and reduces air pollution.
Heat recovery-In a modern refinery most
processes operate at high temperatures and
pressures alike. The crude oil that enters the process is loaded with contaminants that can
and do foul pipes, furnaces and other
components, reducing the efficiency with
heat. By one estimate the economic value of
these losses is roughly $2 billion a year.
Textile industries
Textile industry is the source of air pollutants
like Carbon dioxide, Aerosol fumes and
gases, Toxic gases, Smoke and Dust.
General control measure
-Use of Electrostatic precipitator
-Use of scrubber
-Use of oxidizer
-Height of chimneys: Chimneys height
should not be less than 30 meters and release
the pollutants not in the vicinity of livingorganism
-Gravitational & inertial separator: These are
working on gravitational and inertial
concepts of collecting, filtering etc of the
particulate matter. Eg. Settling chambers,
dynamic separator and wet cyclones &
multiple cyclones.
- Filters: Woven or sintered metal beds of
fibers, metal turning, fibrous mats &
aggregate bed filter, paper filters and fabric
filters are used for the filtration of particulate
matter like dust, lint and fumes
Conclusion
There are many techniques which can be
used to reduce the air pollution by industries.
Every industry has a potential to reduce the
emission. Developed countries are used these
techniques and getting good results. May
these techniques increase the overall cost and
having a high payback period but it is
essential to use these techniques in order to
reduce the pollution, these technique will
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give profit in the future In India these
techniques must be use to make the
environment pollution free. As in every other
sector of the economy, ranging from herds of dairy cattle to fleets of cars,
there is no lack of solutions in the industrial
sector. They abound. But, just as in every
other sector, those charged with making
decisions are motivated only by making
profit, as much as possible and as quickly as
possible. They will not save us, so we must
save ourselves.
References
1. Bonneville Power Administration,
“Energy-Efficient Electric Motor
Selection Handbook,” Jan., 1993,
2. Price, L. & Worrell, “Global EnergyUse, CO2 Emissions and the Potential for
Reduction in the Cement Industry,”
Cement Energy Efficiency Workshop,
Organized by IEA in cooperation with
WBCSD, Paris, France, Sep.4-5, 2006,
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Pollution on COPD". RT: for Decision
Makers in Respiratory Care.
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