algapūr™ hsho algae oil - biochim.it
TRANSCRIPT
AlgaPūr™ HSHO Algae OilA stable and luxurious liquid bio-based oil, created by the transformative powers of microalgae.
© 2019 The Lubrizol Corporation.2
INCI
TrioleinCFDA approved
Emollient in skin and hair care
products
APPLICATION
Microalgae converting sugars into
triglyceride oils
ORIGIN
AlgaPūr™High Stabil ity High Oleic (HSHO) Algae Oil
Triglyceride oil containing over 90% of beneficial Omega-9 Oleic acid in the form of trioleate ester.
Lubrizol is globally collaborating with Corbion, and is the
exclusive source for AlgaPūr™ HSHO Algae Oil in the beauty and personal care markets
© 2019 The Lubrizol Corporation.3
37 h
5.9 h
3.5 h
0.34 h
AlgaPūr™ HSHO
Algae Oil
Olive Oil
Synthetic Triolein
Sunflower Oil
The stable liquid bio-based oil
Induction Time (h) at 120 ˚C*
Advantages for formulators
1. No evolution of odor and color over time
2. Less antioxidant required
3. Operation flexibility
*Test performed with Rancimat** Extrapolation from Oxidation time values measured at 100, 120, 130, 155 and 180 °C
Induction Time at 25˚C**
4.8 years
6 months
1.5 months
3-4 days
© 2019 The Lubrizol Corporation.4
Sugarcane Algae Oils
Algae cells with oil
A simple and control led manufacturing process with low environmental footprint
Low carbon footprint Energy provided by waste sugarcane material
Low water consumption Rain-fed
Low land usage One of the highest yielding sources of sugar
© 2019 The Lubrizol Corporation.5
The perfect blend of stabi l ity, versati l i ty and sustainabi l ity
• Unprecedented oxidative stability
• Excellent solubility profile with most oils
• Negligible level of free fatty acid for eye mildness
Ingredient Features
Formulation Benefits
• Easy to emulsify
• Neutral odor and pale, yellow color
• Silky (not greasy) after-feel
Sustainable Benefits
• Low environmental footprint
• Natural, Palm free and fully traceable
© 2019 The Lubrizol Corporation.6
Addit ional information about AlgaPūr™HSHO Algae Oil
1. Sensory and Moisturization
2. Compatibility with other oils
3. More about Sustainability
4. Formulation examples
Sensory and Moisturization
© 2019 The Lubrizol Corporation.8
1
2
3
4
5
Gloss Whiteness Absence of
Odor
Pick-Up Spreadability Richness Matte Absorbency
Synthetic TrioleinSunflower Oil
Olive Oil
AlgaPūr™ HSHO Algae Oil
A pleasant sensory profi le with good absorbency and si lky sl ippery feel
Wt%
DI water q.s.
Carbopol® Ultrez 21 Polymer 0.45
Glycerine 5.00
Disodium EDTA 0.20
Emollient(*) 15.00
Glucate™ DO Emulsifier 4.03
Glucamate™ SSE-20 Emulsifier 0.97
Phenoxyethanol 0.50
Oils have been evaluated in the following formulation backbone
Blind test performed by 6 expert sensory panelists Each formulation is evaluated individually along 8 parameters using a scale from 1 to 5 (1 being negative and 5 being positive).
In the jar On the skin
© 2019 The Lubrizol Corporation.9
Improved skin moisturization up to 2 hours after applicat ion
26%*
26%*
22%
11%
AlgaPūr™ HSHO Algae Oil
Synthetic Triolein
Sunflower Oil
Olive Oil
Mean Increase (%) after 2hours vs T0
*p-value<0.01
Moisturization kinetics performed with a Corneometer on neat emollients and 14 volunteers.
Compatibility with other oils
© 2019 The Lubrizol Corporation.11
Soluble with a large diversity of oi l compounds
Esters• Caprylic / Capric Triglyderide• C12-15 Alkyl Benzoate• Neopentyl Glycol Diethylhexanoate• Diisobutyl Sebacate• Isostearyl Isostearate• Diisostearyl Dimer Dilinoleate• Cocoyl Adipic Acid /
Trimethylolpropane Copolymer
Vegetal Oils• Sunflower Oil• Olive Oil• Jojoba Oil• Soybean Oil
Non-Polar Oils• Mineral Oil• Isohexadecane• Petrolatum
Silicones• Cyclopentasiloxane• Phenyl trimethicone
All results obtained at 25ºCCompatible all ratios (10. 50 and 90%)
© 2019 The Lubrizol Corporation.12
AlgaPūr™ HSHO Algae Oil – Typical Characterist ics
Property Typical (Result)
Appearance Clear pale to golden yellow color
OSI (heat stability at 110°C) ≥ 80h
Free fatty acids ≤ 0.2 %
Karl Fisher Moisture ≤ 0.15 %
Peroxide Value (meq/kg) ≤ 10.0
Fatty acid composition :
C18:1 ≥ 90 %
Total Polyunsaturates ≤ 1.9 %
Total Saturates ≤ 4.0 %
© 2019 The Lubrizol Corporation.13
The highest level of saturated + monounsaturated fatty acidsFatty acid profile measured by Gas chromatography–mass spectrometry
Fatty Acid Profile
Area %
C16:0 C18:0 C16:1 C18:1 C18:2 C18:3
AlgaPūr™ HSHO Algae Oil
1.98 0.19 1.36 95.00 1.47 ND
Synthetic Triolein 1.05 0.19 3.73 92.01 3.03 ND
Sunflower Oil 8.71 0.14 4.57 33.88 52.69 ND
Olive Oil 14.29 1.41 4.22 73.67 6.41 ND
Best-in-class sustainability
& traceability profile
© 2019 The Lubrizol Corporation.15
A low environmental footprint A lgae o i l s p roduced in Braz i l
1. Low carbon footprintLower carbon footprint than nearly all major commercial plant-derived oils
2. Low land use impact Sugar cane feedstock is one of the highest yielding sources
3. Low water consumption Lower water consumption than most commercial plant-derived oils
© 2019 The Lubrizol Corporation.16
Low carbon footprint
2 Primary drivers
Low carbon footprint of the sugarcane feedstock
The waste sugarcane material (bagasse) provides the energy to
power both the sugar mill and the co-located Corbion facility.
A l g a e o i l p r o d u c e d i n C o r b i o n ’ s B r a z i l f a c i l i t y h a s a l o w c a r b o n f o o t p r i n t ( i n c l u d e s c a r b o n e m i s s i o n s a s s o c i a t e d w i t h l a n d u s e c h a n g e ) .
Source: thinkstep (2016) Cradle-to-Gate Study of Competing Bio-Based Oils. Third Party Reviewed to ISO 1404/44 Standards. Includes land use change.
© 2019 The Lubrizol Corporation.17
Low land use impact A l g a e o i l p r o d u c e d f r o m s u g a r c a n e f e e d s t o c k i n B r a z i l h a s a g r e a t e r o i l y i e l d p e r h e c t a r e t h a n m o s t o t h e r o i l p r o d u c i n g c r o p s .
MT Oil / Hectare
0 1 2 3 4
Soybean Oil
Sunflower Oil
Palm Kernel Oil
Canola Oil
Olive Oil
Algae Oil
Palm Oil
Source: Murphy, D. J. (2009). Global oil yields: Have we got it seriously wrong? AOCS. http://www.aocs.org/Membership/informArticleDetail.cfm?ItemNumber=1102
Palm Oil Source: Lotte S. Woittiez, Mark T. van Wijk, Maja Slingerland, Meine van Noordwijk, Ken E. Giller, Yield gaps in oil palm: A quantitative review of contributing factors, European Journal of Agronomy, Volume 83, 2017, Pages 57-77, ISSN 1161 0301. http://www.sciencedirect.com/science/article/pii/S1161030116302131
Algae Oil Source: Based on FAO (Food and Agriculture Organization of the United Nations. (2012). FAOSTAT Database. Rome, Italy: FAO. http://faostat3.fao.org/home/E and Corbion data) and Corbion data
© 2019 The Lubrizol Corporation.18
Low water consumptionA l g a e o i l p r o d u c t i o n i n B r a z i l c o n s u m e s l e s s w a t e r t h a n p r o d u c t i o n o f n e a r l y a l l o t h e r m a j o r c o m m o d i t y o i l s .
Source: thinkstep (2016) Cradle-to-Gate Study of Competing Bio-Based Oils. Third Party Reviewed to ISO 1404/44 Standards. Includes land use change.
© 2019 The Lubrizol Corporation.19
Origin of the Sugarcane
In Brazil, Corbion
requires that its
suppliers do not grow
or source sugarcane in
the Amazon, Pantanal
or Upper Paraguay
Basin Biomes
Location of Corbion’s Brazil facility is more than 2000km away from the Amazon Rainforest.
Map source: NIPE-Unicamp, IBGE and CTC (2018), Brazilian Sugarcane Sector: Recent Developments and the Path Ahead
© 2019 The Lubrizol Corporation.20
Corbion Cane Sugar Code
Extension of Corbion supplier code includingadditional principles and criteria around landrights, biodiversity good agricultural practices andbiodiversity.
The code is based on the raw material standardsset out by BONSUCRO with additional social andethical standards to which Corbion holds itssuppliers.
Corbion audits its suppliers on a regular basis toensure compliance.
In 2018, 99% of our cane sugar supplierscommitted to the Corbion Cane Sugar code.
Formulations
© 2019 The Lubrizol Corporation.22
Natural Moisturizing Face Lotion with Algae OilF-0158
INCI Name Weight % Trademane
A. 1. Deionized Water 66.00
2. Propanediol 5.00
3. Glyceryl Caprylate 0.50
4. Sphingomonas Ferment Extract 0.50
B. 5. Triolein 10.00 AlgaPūr™ HSHO Algae Oil
6. Isostearyl Isostearate 10.00 Schercemol™ 1818 Ester
7. Isostearyl Hydroxystearate, 2.00 Schercemol™ SHS Ester
8. Glyceryl Stearate 2.73
9. Cetearyl Alcohol 1.27
C. 10. Water (and) Glycerin (and) Backhousia
Citriodora Leaf Extract (and)
Leuconostoc/Radish Root Ferment Filtrate
2.00 Actismart™ Lemon Myrtle
Product Properties:Appearance: White cream / pH: 6.5 – 7.5 / Viscosity (mPa·s)**: 7,500 – 10,000 **Viscosity Brookfield® RVDVI+ at 20 rpm, Spindle #5
May contribute to skin soothing
Natural Algae Oil with silky after feel
Natural derived esters
Rich and soft after feel
© 2019 The Lubrizol Corporation.23
Lasting Face Moisturizer with Algae OilF-0159
Product Properties:Appearance: White emulsion / pH: 5.0 – 6.0 Viscosity (mPa·s)**: 8,000 – 12,000 **Brookfield RV, 20rpm, 24 hr) spindle #5
INCI Name Weight % Trademane
A. 1. Deionized Water 53.15
2. Acrylates/C10-30 Akyl Acrylate Crosspolymer 0.20 Pemulen™ EZ-4U Polymeric Emulsifier
3. Carbomer 0.20 Carbopol® Ultrez-30 Polymer
4. Glycerin 10.00
5. Disodium EDTA 0.20
B. 6. Triolein 20.00 AlgaPūr™ HSHO Algae Oil
7. Cetearyl Ethylhexanoate 4.00 Schercemol™ 1688 Ester
8. Cetearyl Acohol 1.00
9. Polyglyceryl-3 Laurate 0.25 Hydramol™ TGL Ester
C. 10. Sodium Hydroxide (18%) 0.50
11. Water (and) Xanthan Gum (and) Caprylyl Glycol
(and) Phenoxyethsnol (and) Glucose (and)
Chondrus Crispus (Carrageenan) Extract (and)
Ethylhexyl Glycerin
7.00 Lipomoist™ 2013 Molecular Film
12. Water (and) Pseudoalteromonas
Exopolysaccharides (and) Citric Acid (and) Sodium
Salicylate
3.00 Hyadisine® Marine Ingredient
13. Phenoxyethanol 0.50
Efficient emulsion stabilizerMild and PEG-free Easy to process
Co-emulsifier to reduce particle size
Improves formulation spreading
Enhance skin hydration by creating a
thin barrier on the skin
High water retaining capacity
suggesting a hyaluronic-like
moisturization behavior
Water resistant, yet breathable film
Natural Algae Oil with silky after feel
Efficient Thickener Rich and cushiony sensoryUltra easy to process
© 2019 The Lubrizol Corporation.24
Trademarks
Carbopol®, Hyadisine® are registered trademarks of The Lubrizol Corporation or its affiliates
Actismart™, Hydramol™, Lipomoist™, Pemulen™ and Schercemol™ are trademarks of The Lubrizol
Corporation or its affiliates
AlgaPūr™ is a trademark of Corbion
Brookfield® is a registered trademark of Brookfield AMETEK, Inc.
Ronaflair® is a registered trademark of Merck KGaA
25
The information contained herein is being furnished for informational purposes only, upon the express condition that the User makes its own assessment of the appropriate use of such information. While the information contained herein is believed to be reliable, no representations, guarantees or warranties of any kind are made as to its accuracy, suitability for a particular application or the results to be obtained here from. Lubrizol Advanced Materials, Inc. ("Lubrizol") cannot guarantee how any products associated with this information will perform in combination with other substances or in User’s process. Due to the variations in methods, conditions and equipment used commercially in processing these materials, no warranties or guarantees are made as to the suitability of the information/products for the applications disclosed. Lubrizol shall not be liable and the User assumes all risk and responsibility for, any use or handling of any material beyond Lubrizol's direct control. LUBRIZOL MAKES NO WARRANTIES, EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, THE IMPLIED WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. It is the User’s sole responsibility to determine if there are any issues relating to patent infringement of any component or combination of components relating to the supplied information. Nothing contained herein is to be considered as permission, recommendation, nor as an inducement to practice any patented invention without the permission of the patent owner.© Copyright 2019 Lubrizol Advanced Materials, Inc.
Thank you
Lubrizol Advanced Materials, Inc.
9911 Brecksville Road
Cleveland, OH 44141
800-379-5389
216-447-5000
www.lubrizol.com/personal-care
For more information, samples and/or starting formulations with complete processing instructions and supplier references please contact:
Back Up
© 2019 The Lubrizol Corporation.28
Rancimat Method
1. Samples placed into disposable glass reaction vessels
2. Samples heated in two independently controlled blocks
3. Filtered air passed through sample
4. Oxidation products are transferred to measuring cell and absorbed in water
5. Conductivity is continuously monitored