alpine frostschutz scheibenklar konzentrat section 1 ... frostschutz... · supplier of these...

Safety Data Sheet

according to Regulation (EC) No 1907/2006

Alpine Frostschutz Scheibenklar Konzentrat

Revision date: 05.06.2018 Product code: MIT0010 of 12

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.3. Details of the supplier of the safety data sheet

Mitan Mineralöl GmbHCompany name:

Street: Industriestraße 8

D-49577 AnkumPlace:

+49 (0)5462/7470-50 Telefax:+49 (0)5462/7470-33Telephone:

[email protected]:

e-mail (Contact person): [email protected]

www.mitan-oil.deInternet:

Giftinformationszentrum Nord (Göttingen)

+49 (0)551/19240

1.4. Emergency telephone

number:

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Regulation (EC) No. 1272/2008

Hazard categories:

Flammable liquid: Flam. Liq. 3

Serious eye damage/eye irritation: Eye Irrit. 2

Specific target organ toxicity - repeated exposure: STOT RE 2

Hazard Statements:

Flammable liquid and vapour.

Causes serious eye irritation.

May cause damage to organs through prolonged or repeated exposure.

2.2. Label elements

Regulation (EC) No. 1272/2008

Hazard components for labellingethanediol, ethylene glycol

Signal word: Warning

Pictograms:

H226 Flammable liquid and vapour.

H319 Causes serious eye irritation.

H373 May cause damage to organs through prolonged or repeated exposure.

Hazard statements

P501 Dispose of contents/container to Dispose of waste according to applicable legislation..

Precautionary statements

GB - EN Print date: 05.06.2018Revision No: 1,04

mailto:[email protected]

http://www.mitan-oil.de

Safety Data Sheet




P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if

present and easy to do. Continue rinsing.

P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water

or shower.

P337+P313 If eye irritation persists: Get medical advice/attention.

P314 Get medical advice/attention if you feel unwell.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No

smoking.

P102 Keep out of reach of children.

No information available.

2.3. Other hazards

SECTION 3: Composition/information on ingredients

3.2. Mixtures

Hazardous components

QuantityChemical nameCAS No

EC No Index No REACH No

Classification according to Regulation (EC) No. 1272/2008 [CLP]

64-17-5 ethanol, ethyl alcohol 50-100 %

200-578-6 603-002-00-5 01-2119457610-43

Flam. Liq. 2, Eye Irrit. 2; H225 H319

107-21-1 ethanediol, ethylene glycol 10-<25 %

203-473-3 603-027-00-1 60-3027001

Acute Tox. 4, STOT RE 2; H302 H373

Full text of H and EUH statements: see section 16.

Labelling for contents according to Regulation (EC) No 648/2004

< 5 % anionic surfactants, perfumes.

SECTION 4: First aid measures

4.1. Description of first aid measures

Self-protection of the first aider Remove casualty to fresh air and keep warm and at rest. Change

contaminated, saturated clothing.

General information

Medical treatment necessary. Provide fresh air. If unconscious place in recovery position and seek medical

advice.

After inhalation

Wash with plenty of water. Immediately remove any contaminated clothing, shoes or stockings. Medical

treatment necessary. After contact with skin, wash immediately with plenty of water and soap.

After contact with skin


Safety Data Sheet




After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time , then consult an

ophthalmologist immediately. In case of accident or unwellness, seek medical advice immediately (show

directions for use or safety data sheet if possible).

After contact with eyes

Rinse mouth immediately and drink plenty of water. Induce vomiting when the affected person is not

unconscious. Medical treatment necessary.

After ingestion

4.2. Most important symptoms and effects, both acute and delayed


4.3. Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Water spray jet0 Carbon dioxide (CO2)0 Foam0 Extinguishing powder. In case of major fire and large

quantities: Water spray jet

Suitable extinguishing media

Full water jet

Unsuitable extinguishing media

5.2. Special hazards arising from the substance or mixture

Flammable. Vapours can form explosive mixtures with air. In case of fire may be liberated: Carbon dioxide

(CO2). Sulphur dioxide (SO2) Nitrogen oxides (NOx)

In case of fire: Wear self-contained breathing apparatus. Full protection suit

5.3. Advice for firefighters

Use water spray jet to protect personnel and to cool endangered containers. Suppress gases/vapours/mists

with water spray jet. Collect contaminated fire extinguishing water separately. Do not allow entering drains or

surface water.

Additional information

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Remove all sources of ignition. Provide adequate ventilation. Do not breathe gas/fumes/vapour/spray. Avoid

contact with skin, eyes and clothes. Use personal protection equipment. Protective equipment Remove

persons to safety. Provide adequate ventilation. Wear breathing apparatus if exposed to

vapours/dusts/aerosols.

Do not allow uncontrolled discharge of product into the environment. Danger of explosion Prevent spread over

a wide area (e.g. by containment or oil barriers). Do not allow to enter into surface water or drains.

6.2. Environmental precautions

Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the

recovered material as prescribed in the section on waste disposal.

6.3. Methods and material for containment and cleaning up

Safe handling: see section 7

6.4. Reference to other sections


Safety Data Sheet




Personal protection equipment: see section 8

Disposal: see section 13

SECTION 7: Handling and storage

7.1. Precautions for safe handling

If handled uncovered, arrangements with local exhaust ventilation have to be used. Do not breathe

gas/fumes/vapour/spray. Keep container tightly closed. Store in a cool dry place. Keep away from heat. Protect

from sunlight. Provide adequate ventilation as well as local exhaustion at critical locations.

Advice on safe handling

Keep away from sources of ignition - No smoking. Take precautionary measures against static discharges.

Vapours can form explosive mixtures with air.

Advice on protection against fire and explosion

7.2. Conditions for safe storage, including any incompatibilities

Keep container tightly closed. Keep locked up. Store in a place accessible by authorized persons only. Provide

adequate ventilation as well as local exhaustion at critical locations. Keep in a cool, well-ventilated place. Keep

away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Requirements for storage rooms and vessels

Do not store together with: Oxidizing agent. Pyrophoric or self-heating substances.

Advice on storage compatibility

Store in a cool dry place.

Further information on storage conditions

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Exposure limits (EH40)

Categoryfibres/mlmg/m³ppmSubstanceCAS No Origin

TWA (8 h)20Ethane-1,2-diol, vapour107-21-1 52 WEL

STEL (15 min)40 104 WEL

TWA (8 h)1000Ethanol64-17-5 1920 WEL

STEL (15 min)- - WEL


Safety Data Sheet




DNEL/DMEL values

CAS No Substance

DNEL type Exposure route Effect Value

64-17-5 ethanol, ethyl alcohol

Consumer DNEL, acute inhalation local 950 mg/m³

Consumer DNEL, long-term dermal systemic 206 mg/kg bw/day

Worker DNEL, acute inhalation local 1900 mg/m³

Consumer DNEL, long-term inhalation systemic 114 mg/m³

Consumer DNEL, long-term oral systemic 87 mg/kg bw/day

Worker DNEL, long-term dermal systemic 343 mg/kg bw/day

Worker DNEL, long-term inhalation systemic 950 mg/m³

107-21-1 ethanediol, ethylene glycol

Worker DNEL, long-term inhalation local 35 mg/m³

Worker DNEL, long-term dermal systemic 106 mg/kg bw/day

Consumer DNEL, long-term inhalation local 7 mg/m³

Consumer DNEL, long-term dermal systemic 53 mg/kg bw/day

PNEC values

SubstanceCAS No

Environmental compartment Value


Marine water 0,79 mg/l

Freshwater sediment 3,6 mg/kg


Freshwater 10 mg/l

Marine water 1 mg/l

Freshwater sediment 37 mg/kg

Marine sediment 3,7 mg/kg

Soil 1,53 mg/kg

8.2. Exposure controls

If handled uncovered, arrangements with local exhaust ventilation have to be used. Do not breathe

gas/fumes/vapour/spray.

Appropriate engineering controls


Safety Data Sheet




Remove contaminated, saturated clothing immediately. Draw up and observe skin protection programme.

Wash hands and face before breaks and after work and take a shower if necessary . When using do not eat or

drink. Change contaminated, saturated clothing. Do not breathe gas/fumes/vapour/spray. Avoid contact with

skin, eyes and clothes. When using do not eat, drink or smoke.

Protective and hygiene measures

Suitable eye protection: goggles.

Eye/face protection

When handling with chemical substances, protective gloves must be worn with the CE-label including the four

control digits. The quality of the protective gloves resistant to chemicals must be chosen as a function of the

specific working place concentration and quantity of hazardous substances. For special purposes, it is

recommended to check the resistance to chemicals of the protective gloves mentioned above together with the

supplier of these gloves. DIN EN 374 Suitable gloves type: NBR (Nitrile rubber)

Hand protection

Wear suitable protective clothing.

Skin protection

In case of inadequate ventilation wear respiratory protection.

Respiratory protection

blue

LiquidPhysical state:

Colour:

9.1. Information on basic physical and chemical properties

SECTION 9: Physical and chemical properties

fruityOdour:

pH-Value (at 20 °C): 8

Changes in the physical state

-63,5 °CMelting point:

78 °CInitial boiling point and boiling range:

23 °CFlash point:

Flammability

not applicableSolid:

not applicableGas:

The product is not: Explosive In case of insufficient ventilation and/or through use, explosive/highly flammable

mixtures may develop.

Explosive properties

2,5 vol. %Lower explosion limits:

13,5 vol. %Upper explosion limits:

>363 °CIgnition temperature:

Auto-ignition temperature

not applicableSolid:

not applicableGas:

not determinedDecomposition temperature:


Safety Data Sheet




No self-ignition up to the melting point.

Oxidizing properties

59 hPaVapour pressure:

(at 20 °C)

Density (at 20 °C): 0,89 g/cm³

Water solubility: easily soluble

Solubility in other solvents

not determined

not determinedPartition coefficient:

Vapour density: not determined

not determinedEvaporation rate:

9.2. Other information

not determinedSolid content:

SECTION 10: Stability and reactivity

10.1. Reactivity

Flammable. No information available.

10.2. Chemical stability

The product is stable under storage at normal ambient temperatures.

10.3. Possibility of hazardous reactions

No known hazardous reactions.

Keep away from sources of heat (e.g. hot surfaces), sparks and open flames. Vapours can form explosive

mixtures with air.

10.4. Conditions to avoid


10.5. Incompatible materials

Carbon monoxide

10.6. Hazardous decomposition products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity

Based on available data, the classification criteria are not met.


Safety Data Sheet




Chemical nameCAS No

SourceSpeciesDoseExposure route Method


RatLD50 6200

mg/kgIUCLIDoral

inhalative (4 h) vapour LC50 95,6 mg/l Rat RTECS


ATE 500

mg/kgoral

RabbitLD50 10600

mg/kgGESTISdermal

Irritation and corrosivity

Causes serious eye irritation.

Skin corrosion/irritation: Based on available data, the classification criteria are not met.

Sensitising effects


Carcinogenic/mutagenic/toxic effects for reproduction


STOT-single exposure


May cause damage to organs through prolonged or repeated exposure. (ethanediol, ethylene glycol)

STOT-repeated exposure

Aspiration hazard


The mixture is classified as hazardous according to regulation (EC) No 1272/2008 [CLP].

Additional information on tests

SECTION 12: Ecological information

12.1. Toxicity

The product is not: Ecotoxic.

CAS No Chemical name

[h] | [d]Aquatic toxicity Dose SourceSpecies Method

ethanol, ethyl alcohol64-17-5

Acute crustacea toxicity 48 h IUCLIDEC50 9268 -

14221 mg/l

Daphnia magna

ethanediol, ethylene glycol107-21-1

Acute fish toxicity 96 h Experimental dataLC50 72860

mg/l

Pimephales promelas

(fathead minnow)

12.2. Persistence and degradability

The product has not been tested.


Safety Data Sheet




CAS No Chemical name

SourceValueMethod d

Evaluation

ethanol, ethyl alcohol64-17-5

Biodegradation >70% 5

Readily biodegradable (according to OECD criteria).

12.3. Bioaccumulative potential


Partition coefficient n-octanol/water

Log PowChemical nameCAS No

64-17-5 -0,31ethanol, ethyl alcohol

107-21-1 -1,36ethanediol, ethylene glycol


12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment



12.6. Other adverse effects

Avoid release to the environment.

Further information

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Advice on disposal

Do not allow to enter into surface water or drains. Dispose of waste according to applicable legislation.

Waste disposal number of used product

WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the manufacture, formulation,

supply and use (MFSU) of basic organic chemicals; other organic solvents, washing liquids and

mother liquors; hazardous waste

070104

Waste disposal number of contaminated packaging

WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and

discarded chemicals; discarded organic chemicals consisting of or containing hazardous

substances; hazardous waste

160508

This material and its container must be disposed of as hazardous waste. Handle contaminated packages in the

same way as the substance itself.

Contaminated packaging

SECTION 14: Transport information

Land transport (ADR/RID)

14.1. UN number: UN 1170

ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)14.2. UN proper shipping name:


Safety Data Sheet




314.3. Transport hazard class(es):

14.4. Packing group: III

Hazard label: 3

Classification code: F1

Special Provisions: 144 601

Limited quantity: 5 L

Excepted quantity: E1

Transport category: 3

30Hazard No:

Tunnel restriction code: D/E

Inland waterways transport (ADN)


14.2. UN proper shipping name: ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)

14.3. Transport hazard class(es): 3


Hazard label: 3

F1Classification code:

144 601Special Provisions:



Marine transport (IMDG)


ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)14.2. UN proper shipping name:

14.3. Transport hazard class(es): 3


Hazard label: 3

144, 223Special Provisions:



EmS: F-E, S-D

Air transport (ICAO-TI/IATA-DGR)


ETHANOL (ETHYL ALCOHOL)14.2. UN proper shipping name:


Safety Data Sheet




314.3. Transport hazard class(es):

III14.4. Packing group:

Hazard label: 3

Special Provisions: A3 A58 A180

Limited quantity Passenger: 10 L

Y344Passenger LQ:


355IATA-packing instructions - Passenger:

60 LIATA-max. quantity - Passenger:

366IATA-packing instructions - Cargo:

220 LIATA-max. quantity - Cargo:

14.6. Special precautions for user

Warning: Combustible liquid.

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

EU regulatory information

99,99 % (889,911 g/l)2010/75/EU (VOC):

100 % (890 g/l)2004/42/EC (VOC):

Additional information

Regulation (EC) No. 648/2004 (Detergents regulation).

National regulatory information

Observe restrictions to employment for juvenils according to the 'juvenile

work protection guideline' (94/33/EC).

Employment restrictions:

1 - slightly water contaminatingWater contaminating class (D):

15.2. Chemical safety assessment

Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information

Abbreviations and acronyms

ADR: Accord européen sur le transport des marchandises dangereuses par Route

(European Agreement concerning the International Carriage of Dangerous Goods by Road )

IMDG: International Maritime Code for Dangerous Goods

IATA: International Air Transport Association

GHS: Globally Harmonized System of Classification and Labelling of Chemicals

EINECS: European Inventory of Existing Commercial Chemical Substances

ELINCS: European List of Notified Chemical Substances


Safety Data Sheet




CAS: Chemical Abstracts Service

LC50: Lethal concentration, 50%

LD50: Lethal dose, 50%

Classification for mixtures and used evaluation method according to Regulation (EC) No. 1272/2008 [CLP]

Classification procedureClassification

Flam. Liq. 3; H226 On basis of test data

Eye Irrit. 2; H319

STOT RE 2; H373

H225 Highly flammable liquid and vapour.

H226 Flammable liquid and vapour.

H302 Harmful if swallowed.

H319 Causes serious eye irritation.

H373 May cause damage to organs through prolonged or repeated exposure.

Relevant H and EUH statements (number and full text)

The information is based on present level of our knowledge. It does not, however, give assurances of product

properties and establishes no contract legal rights. The receiver of our product is singulary responsible for

adhering to existing laws and regulations.

Further Information

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety

data sheet.)


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