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aluminium technologies 3.11.2015
Term paper topics Cenk Eken ultrasonic processing of aluminium melts
Murat Teke assesment of melt quality via K-mold method
Emre Açıcı applications of aluminium foams
Gazican Özkan injection casting of aluminium alloys
Engin Kılınç
Mehmet Ağılkaya high integrity casting processes
Haluk Erdemir additive manufacturing of aluminium alloys
Serhan Köktaş rheo-casting of aluminium alloys and their
applications
Alper Güneren friction stir processing of aluminium alloys
Emre Baran production of aluminium foams
Berkay Oral FSW automotive aluminium
Erkut Özer casting of hypereutectic Al-Si alloys and their
applications
İzzet Nahid Demir Casting of Al-Mg based foundry alloys and
their applications
Mehmet Yasak surface treatment of aluminium alloys
Kürşat Kambur severe plastic deformation of aluminium alloys
steel vs aluminium for automotive applications
Papers in word format due on 22.12.2015 Presenations of the papers on 29.12.2015 & 5.1.2016
Midterm exam (%25)
10.11.2015, Tuesday
09:30
you will be responsible for every
topic we will have covered up until
the end of this lecture!
Hot tearing ● Hot tear cracks may be encountered in the
casting after solidification.
● The section that have solidified may induce
stresses on the other sections which are yet to
solidify.
● Cracks may initiate if these semi-solid regions are
too thick and the feeding is insufficient.
● Alloy composition has a significant impact on hot
tearing.
● Alloy composition directly affects the supply of
liquid eutectic phase for the feeding of the
solidifying regions.
Hot Tears
initial stage:
Hexagonal
grains
surrounded by
liquid film
Application of tensile
strain leads to grain
impingement and the
creation of
intergranular pools
Continuous
extension leads
to the opening
of tears
Hot Tears Characteristics of Hot Tears
● Ragged, branching crack
● Generally intergranular
● Dendritic morphology on failure surface
● Heavily oxidised failure surface
● Often located at hot spot
● Random occurrence and extent
● Alloy specific
Hot tearing parameters that need to be controlled to avoid hot
tears:
Casting design
effectiveness of the grain refinement practice
Stiffness of the mold
Tensile stresses
that develop during
solidification
Hot tearing
Hot tearing in a
DC cast 7XXX
billet produced
by ETİ
Aluminium!
Hot tearing
Hot tearing in a
DC cast 7XXX
billet produced
by ETİ
Aluminium!
● Alter casting design
● Chill hot spots
● Reduce constraint from mould
● Add brackets and webs
● Employ effective grain refinement
● Reduce casting temperature
● Adjust/optimise alloying
● Reduce contracting length
prevention of hot tears
● It may be possible to alter the geometry of the casting
to reduce stress concentrations and hot spots, for
example, by providing generous radii at vulnerable
sections.
● Local hot spots can be reduced by local chilling which
will strengthen the metal by taking it out of the
susceptible temperature range.
● There are various ways of reducing the mould strength
so that it provides less constraint to the contracting
casting.
● Brackets and webs can be placed across a vulnerable
corner or hot spot to provide mechanical support and
to enhance local cooling.
prevention of hot tears
● A reduction in the casting temperature can sometimes
help, probably because it reduces the grain size.
● Grain refinement should help to reduce tear initiation
since the strain will be spread over a greater number of
grain boundaries.
● increasing the volume fraction of eutectic liquid may
help by increasing the pre-tear extension and by
decreasing the cracking susceptibility.
● Finally, it is sometimes possible to site feeders
carefully so that the casting is effectively split up into
a series of short lengths to reduce the strain
concentration.
prevention of hot tears
Cold cracks ● Form below the solidus temperature
● Straighter and smoother than hot tears
● Transgranular or intergranular
● Can be oxide-free (if formed at low T’s)
Sources of stress
Differential cooling
Mould/core restraint
Phase transformation
Heat treatment
Prevention
Reduce stress raisers
avoid abrupt changes of section
eliminate oxide defects
Reduce mould/core restraint
Eliminate or use alternative heat
treatments
Reduction in quenching stresses
Rates of cooling of a
20mm diameter
aluminium bar when
quenched by various
means from 500 C.
Effect of quenching
medium on ductility
time, s
intermetallics
Permanent mould cast
Al-12 Si alloy with %1
Fe; -Al5FeSi needles
-AlFeSi intermetallic
“chinese script”
morphology
Fe-based intermetallic particles
Cracks that form due to the stress concentration at the tip of AlFeSi intermetallic needles.
-AlFeSi needles physically block interdendritic melt
flow and lead to micro shrinkage.
-Al5FeSi particles exhibit an acicular morphology and have a very negative impact on ductility.
Fe-based intermetallic particles
Lamellar granular undermodified
Modified overmodified
modification
Silicon modification 1. seviye
2. seviye
3. seviye
4. seviye
5. seviye
6. seviye
lack of modification A fatigue crack that follows unmodified Silicon
particles in
an aluminium
cylinder
head
casting.
segregation
c0
cs ck
tem
pera
ture
composition
segregation
6XXX alloys 7XXX alloys
Compositional fluctuations that scale with the
dendritic structure: dendritic segregation-coring
As-cast 206 alloy (4.4% Cu-0.3 %Mg-0.3 %Mn)
50m 50m
segregation
Segregation in the as-cast component can be largely
eliminated by a high temperature soak called
homogenization. Homogenization is a must for parts
that will be
subjected to
forming
Operations.
Homogenization anneal
High temperature annealing treatment to remove
dendritic segregation!
We use Fick’s Law to estimate the T and t of the
heat treatment to be employed to eliminate
compositional fluctuations
x = D.t
X is the distance over which diffusion will take
place; dendrite arm spacing, t is time and D is
diffusion coefficient.
Homogenization anneal
Homogenization anneal An aluminium casting with a dendrite arm spacing of DAS 100
micron is annealed at 480C.
The homogenization anneal time to eliminate Mg segregation:
t = x2/D
For Mg diffusion in aluminium at 480C
D = 1x10-14 m2/s.
t = (0.0001m)2 / 1x10-14 m2/s
= 106 s = 278 h
If DAS were = 10 microns
t = (0.00001m)2 / 1x10-14 m2/s
= 1x104 s < 3 h
Segregation in strip casting
● impair surface quality
● impair machinability
● reduce mechanical properties
● decrease corrosion resistance!
● increase porosity!
● produce pinholes in foils!
● reduce fluidity and castability!
● cause filter blockage!
Casting
quality
Process
efficiency
Nonmetallic inclusions melt quality
Oxides
B
A
1 mm
Oxide inclusions Extrageneous oxide inclusions
Possible defects
defect inclusions (mainly oxides)
Possible main
cause
Retention system for oxide skin of metal
not efficient enough; the two metal
fronts hit together
Ways to avoid
defects
Use and optimize oxide retention
systems; fronts with oxides should be
brought into overflows
Possible defects
overflow
Defect Shrinkage porosity
Possible main cause Feeding of large cross sections is not
good enough.
Way to avoid defects Dimension runner and gating systems for
good feeding; use numerical simulation to
control and optimise them.
Possible defects
Possible defects
why aluminium
castings?
● Roughly two thirds of all aluminium castings are
automotive where the use of aluminum castings
continues to grow at the expense of iron castings.
● Although aluminium castings are significantly more
expensive than ferrous castings, there is a continuing
market requirement to reduce vehicle weight and to
increase fuel efficiency.
● Aluminium castings are widely used in cars for engine
blocks, cylinder heads, pistons, rocker covers, inlet
manifolds, differential casings, steering boxes,
brackets, wheels etc.
● Al castings in EU cars is expected to reach 200 kg by
year 2020.
Properties of castings
Easy to cast!
● Al-Si alloys with sufficient Si exhibit outstanding
flowing properties during casting and facilitates
the casting of huge complex components.
● Design features can be produced easily with
minimum tolerances.
● The mold filling capacity of 3xx.x alloys is
exceptionally high!
● Hence, 3xx.x alloys are preferred in the casting of
big complex parts.
Aluminium casting alloys
High strength!
● High strength levels are possible through heat
treatment!
● High strength and tougness can be achieved by a
precise mold design that allows for rapid cooling
during solidification.
● Highest strength values are possible with 2xx.x
alloys; however, casting of these alloys is
relatively more difficult and requires special
attention.
● These alloys are selected for aerospace
applications where strength is a critical issue.
Aluminium casting alloys
Surface quality
● A very high surface quality is possible by a
careful selection of the casting alloy.
● 5xx.x and 7xx.x alloys offer outstanding surface
quality.
● However, casting of these alloys is difficult and
they are employed only in those applications
where surface quality is a must!
● For example, rulman uygulamaları için 7xx.x
alloys are preferred for bearing applications
owing to their high surface quality.
Aluminium casting alloys
aluminium casting processes
Aluminium production routes Primary production 99.7 wt%Al
Shape casting Cont. casting
Direct Chill
(DC) casting
Twin roll
casting/TRC
Twin-belt
casting/TBC
Coiled sheet Slab/ingot
castings
hot-cold rolling/
extrusion Cold rolling
sheet/foil Profile/sheet/foil
Sand casting
Permanent casting
Pressure casting
alloying
melting+melt treatment
casting Foundry alloys Wrought alloys
Semi-cont casting
Aluminium alloys can be cast with several processes:
Sand casting
permanent mould (gravity die) casting
low pressure diecasting, (metal die+sand cores)
Pressure diecasting
Lost Foam casting
Squeeze casting
Investment casting
plaster moulding precision casting techniques
(for aerospace castings)
some alloys are suitable for more than one casting
method.
Shape casting processes
Selection of casting process
● Sand casting for high quality casting of
inticate components!
● Sand casting for a limited number of parts
(as in casting of prototypes)!
● Permanent mould casting for high strength
parts with high elongation values!
Sand cores can be used in permanent mould
casting (but not in pressure die casting!).
Selection of casting process ● Low pressure die casting bottom feeding with
a linear melt flow high quality castings!
● LPDC offers solidification under pressure
(although low) reduced shrinkage!
● LPDC offers advantage particularly in the casting
of round symmetrical parts!
● High Pressure Die Casting is the most popular
and most widely used casting process!
● HPDC is limited to uncored castings!
● HPDC if high quality surface and minimum
finishing are essential.
● Gravity and low pressure diecasting are inherently
slow because the die is effectively out of use
during the time that the casting is solidifying.
● When the casting is removed, the die must be
reloaded with cores and closed before the next
casting is poured.
● This may take 10 minutes or more for a large,
complex casting such as a cylinder block.
● In order to achieve the high production rates
required by automotive manufacturers, expensive
multiple die sets are required.
Sand Casting
re-usable, permanent patterns are used to make the sand
moulds.
The preparation and the bonding of this sand mould is
the critical, the rate-controlling step of this process.
Half mould with
cores and an
example of a cast
air intake for a
turbocharger
Sand Casting
Mould designing is
a particularly
complex art.
riser runner
sand core
Bottom board
gate
Sand Casting
With the
exception of
pressure
diecasting,
green sand
casting is the
most
productive
casting
process.
Sand Casting
Sand casting includes green sand
core assembly processes
lost foam process
● It accounts for 12–15% of all aluminium castings.
● It is generally used for high-volume production.
● Two main routes are used for bonding the sand moulds:
The "green sand" consists of mixtures of sand, clay
and moisture.
The "dry sand" consists of sand and synthetic
binders cured thermally or chemically.
● The sand cores for forming the inside of hollow parts
of the casting are made using dry sand components.
Sand Casting
● With sand casting, productivity is not affected by
the solidification time but only by the rate at which
the sand mould/core package can be produced.
(In GDC and LPDC, the die is effectively out of use
during the time that the casting is solidifying.)
● With automatic green sand moulding and cold-box
coremaking, mould/core packages can be made and
assembled in times which enable high production
rates to be achieved without the need for the costly
multiple tooling sets needed by diecasting.
● Moulding machines can produce moulds at the very
high rate of one every 12 seconds.
Sand Casting processes
Green sand casting ● The slower rate of cooling of sand castings
compared with die castings leads to smaller
temperature gradients and a wider solidification
time range, making feeding more difficult.
● The grain structure of slower-cooled sand cast
aluminium is usually regarded as inferior to that
of chill cast alloys.
● To counter this potential problem, moulding sand
based on magnetite ore can be used to increase
the chilling effect.
Green sand casting ● There has also been some concern that aluminium
alloys may pick up hydrogen from moisture in the
green sand, but it is not a problem if the sand
system is correctly controlled to avoid excessive
water.
● Unlike green sand used for iron casting, it is not
necessary to have coal dust in the sand to improve
casting surface finish.
● To make high integrity sand castings, the melt
must be carefully treated to remove hydrogen and
oxides from the melt and must be grain refined
and modified.
● The simplest method of filling moulds rapidly and
without introducing oxide defects into the casting is by
using ceramic foam filters in the running system.
● Ceramic filters remove already entrained oxide and
reduce turbulence downstream of the filter.
● Top pouring through a filter is an efficient way of filling
sand moulds, giving high yield and excellent mechanical
properties.
● To produce shrinkage porosity-free castings,
directional solidification must be encouraged, with the
use of feeders to supply liquid metal to the last sections
of the casting to solidify.
● Simulation techniques are increasingly being used to
design running and feeding systems.
Green sand casting
Green sand casting The traditional green sand casting process, combined
with high-speed moulding lines, is a very flexible
process with high productivity for the manufacture of
aluminium castings.
For automotive applications, the process is used to
cast:
Intake manifolds
Oil pan housings
Structural parts
Chassis parts
Green sand castings
Automated green sand casting ● AGSC offers a reasonable alternative to conventional
die casting processes (high pressure/low pressure
/vacuum-assisted or not).
● This holds for middle and high volume series,
especially for automotive applications.
● Manufacturing in high pressure die casting is limited
by wall-thickness and design. I.e. producing a
complicated inner structure by using lost cores is
still not economically feasible in this process.
● Low pressure die casting's productivity is limited by
solidification time, leading to cycle times of
typically several minutes.
● Automated green sand casting has no such limits.
Examples of AGSC castings
From left:
Heat Exchanger
Hat Profile
Brake Calipers
Knuckles
wheel
Automated green sand casting
● The AGSC casting process is a container-less sand
casting process.
● The mold is divided upright.
● Front and rear mold half are formed by the shaped
faces of every sand block.
● Stacked on a conveyor belt, the pouring cavity is
between two blocks each.
● Insertion of individual cores or whole core packets
is possible and can be carried out in an automated
manner.
● The finished molds are pushed forward when a
new sand block is added.
Automated green sand casting
can produce and fill up to 400 sand molds per hour.
By using multiple cavities for smaller parts an hourly output
surpassing all other casting processes is achievable.
Automated green sand casting
Complete Control of Mold Filling Combined With High
Productivity
Overview of the AGSC Process
Core package casting ● the entire sand mould consists of single sand cores,
● industrially applied first in 1970 using low pressure
filling by means of an electromagnetic pump.
● Due to low productivity, the process is restricted to
low volume series.
● However, the increasing interest in the outstanding
dimensional quality and possible complexity of
the castings led to further developments and thus,
(e.g.) the Core Package System (CPS®) has
become an established casting process for the
volume production of engine blocks.
Core package for
V6 engine block
Partly assembled core
package for a 4-cylinder
engine block
Core package casting
4-cylinder engine block produced with the CPS® process
the mould is not destroyed at each cast but is permanent,
being made of a metal such as cast iron or steel.
There are a number of die casting processes.
● High pressure die casting is the most widely used,
representing about 50% of all light alloy casting
production.
● Low pressure die casting currently accounts for about
20% of production and its use is increasing.
● Gravity die casting accounts for the rest, with the
exception of a small but growing contribution from the
recently introduced vacuum die casting and squeeze
casting process.
Die Casting
Classifications of die casting processes.
Die Casting Processes
High Pressure die casting half of all light alloy castings are made by the
pressure die casting process, in which the liquid
metal is injected at high speed and high pressure into
a metal mould.
It is the most widely used casting
process for aluminium alloys.
● In high pressure diecasting, molten alloy is injected under
pressure into a highly accurate split metal mould.
● The die halves are closed and locked together hydraulically
to withstand the high injection pressure.
● Molten metal is introduced through a pouring slot into the
shot tube, then a steel plunger forces the liquid metal into
the die cavity under pressure.
● Once the die is filled, pressures are maintained on the
casting until solidification is complete.
● The metal solidifies rapidly because of the good thermal
contact with the water-cooled die.
● the die set is opened to eject the finished casting together
with its sprue, the process is then repeated.
High Pressure Die Casting
High pressure die casting
High pressure die casting High filling speeds and high pressures are distinct
features of HPDC.
Aluminium alloys are cast in cold-chamber diecasting machines.
High pressure die casting HPDC machines are size rated by the closing force.
a fairly common 600 ton HPDC machine
Source: IdraPres
● Die filling times are very short, castings with wall
thickness of 3–4 mm are filled in less than 0.1
seconds.
● Cycle times depend on size and section thickness of
the component, being typically 40 shots/h for a 5 kg
component.
● Production rates are fast, the process can be highly
automated, and dimensional accuracy and surface
finish are excellent.
● Thin-walled components are possible and little or
no machining is needed on the cast component since
holes, grooves and recesses can be finish cast.
High pressure die casting
High Pressure Die Casting ● Dies are expensive but can survive more than 105
shots. The process is therefore most suitable for
long runs of castings.
● With an highly automated operation, the HPDC
process is capable of extremely high levels of
productivity.
Bar = 105Pa = 0.1MPa
● One drawback of the process is that almost
inevitably some air is trapped in the die with the
liquid metal.
● Lack of internal soundness is a cause for concern
when strength and leak tightness are required.
● Turbulence and air bubble entrapment often cause
poor metallurgical properties and leaks.
● special precautions must be taken to limit gas
inclusions which cause blistering during subsequent
heat-treatment or welding of the casting product.
High pressure die casting
● For this reason, the process has mainly been used
for castings which do not require the highest
strength.
● Another disadvantage is that sand cores cannot
be used, since the high pressure liquid metal
would penetrate the core.
High Pressure Die Casting
Die issues ● Dies are made of hot work tool steels.
● Dies must be correctly heat treated to achieve
the maximum life.
● Die design is clearly crucial to the success of the
process.
● the die must be designed to withstand the large
forces involved. Mechanical strength of the die is
critical!!
High pressure die casting-summary
● Rapid filling of the die
● Rapid solidification under pressure
● Density and the surface quality is high
● Fine grain structure
● Good (!!) mechanical properties and fatigue
resistance
● air entrapped in the die gas porosity
● Turbulence during die filling gas porosity
● Thick sections are not as strong as thin sections
● in other casting processes, however, thickness
is increased when strength is required.
● HPDC parts are used as cast!
● Heat treatment, welding and machining are not
employed for HPDC castings!
● HPDC dies must be stronger than permanent
moulds used in gravity die casting; Hence, are
more costly!
● A minimum of 10,000 parts must cast for
economy!
● Suitable for small parts and thin sections.
High pressure die casting-summary
B
B
A
1 mm
1 mm
High pressure die casting
Transmission cases are one
of the largest automotive
parts commonly diecast
Productivity is usually
enhanced via multi-
cavity die designs, e.g.
4 to 8 cavities per die.
Production rates are up
to 100 parts per hour
per cavity.
High pressure die casting
Metallurgical design considerations:
● Part ductility is limited by process considerations
to <3% on average.
● Die castings should not be used for load bearing
safety critical parts.
● Die castings are not heat treatable.
● Die castings are generally produced using
secondary (recycled) alloys; this reduces cost.
● Fatigue properties of die castings are good so long
as the very smooth as-cast surface is not machined
away.
High pressure die casting
Macrostructure: Die castings exhibit three regions
internally:
● The surface skin –dense and fine. The skin gives
die castings good fatigue life. It should not be
machined away unless absolutely necessary.
● The interior body of the casting – sound metal.
● The core – at the centre of the part, the core is
usually porous. It may not be present in high
quality parts. It is harmless in many applications.
Core porosity may be a combination of entrained
air and shrinkage.
High pressure die casting
Low magnification view of a
section through a typical die
cast part
High pressure die casting Macro section showing
entrained air frozen into a high
pressure die cast part
Entrained Air makes HPDC parts non-heat treatable. Air
bubbles entrapped under high pressure during solidification
will cause HPDC parts to blister during solutionising.
Common Al Die casting Alloys:
AlSi8Cu3 (AA 380) Rp0.2%=160 MPa, Rm =325 MPa,
A5=0.5-3%
AlSi10Cu (AA 383) Rp0.2%=150 MPa, Rm =310 MPa,
A5=1-3%
These are the most common alloys in use for
general-purpose die castings.
General utility castings, transmission cases, blocks
etc.
High pressure die casting
Popular alloys in Al-Si system
Special Purpose Al Die casting Alloys
AlSi5 (AA C443) Rp0.2%=110 MPa, Rm =230 MPa, A5=9%
Where exceptional ductility at moderate strength is
required. Increased corrosion resistance (low Cu). (eg.
steering wheels)
AlSi12 (AA 413) Rp0.2%=140 MPa, Rm =300 MPa, A5=0.5-2%
For intricate thin castings.
AlSi17Cu4Mg (AA 390) Rp0.2%=240 MPa, Rm=280 MPa,
A5=1% A hypereutectic wear-resistant alloy. Used for
parent bore engine blocks, compressor parts, pulleys,
brake shoes.
Caution: HPDC Properties are very process/part
dependent
High pressure die casting
Al18Si (AA 391) Alloy Microstrucuture - Primary Si Imparts Wear Resistance
Typical AlSi8Cu (AA 380 microstructure), Hypoeutectic Al-Si plus Fe phases
High pressure die casting
Low pressure diecasting ● A metal die is mounted above a sealed furnace
containing molten metal.
● A refractory-lined tube, called a riser tube or stalk,
extends from the bottom of the die into the molten
metal.
● When air is introduced into the furnace under low
pressure (15–100 kPa), the molten metal rises up the
tube to enter the die cavity with low turbulence, the
air in the die escaping through vents and the parting
lines of the die.
● When the metal has solidified, the air pressure is
released allowing the still-molten metal in the riser
tube to fall back into the furnace.
the die is filled from a pressurised crucible below, and
pressures of up to 0.7 bar are usual.
Low Pressure Die Casting
Low-pressure die
casting is especially
suited to the
production of
components that are
symmetric about an
axis of rotation. Light
automotive wheels
are normally
manufactured by this
technique.
Pressurising
gases
Fill stalk
Low pressure die casting ● Mould filling is controlled by regulating the pressure in
the casting furnace.
● The melt flows through the riser tube which is
positioned under the melt surface of the furnace and
fills the mould very smoothly with clean melt from the
bottom up.
● After mould filling, solidification starts from the
opposite end of the mould in the direction of the tube.
● By increasing the pressure in the casting furnace, good
feeding is guaranteed.
● Cycle times are long since the casting is connected to
the big melt volume by the riser tube during
solidification.
Low pressure die casting
LPDC is used in the
production of
aluminium wheels and
big V-engine blocks in
hypereutectic
aluminium alloys and
in the casting of air-
cooled cylinder heads
for motor cycles.
Low pressure die casting
LPDC cast V-8
cylinder block
● The process is capable of making high quality
castings.
● directional solidification may be achieved with
correct die design.
● This may eliminate the need for risers, the casting
being filled and fed from the bottom.
● Because there is usually only one ingate and no
feeders, casting yield is exceptionally high,
generally over 90%.
● Good dimensional accuracy and surface finish are
possible and complex castings can be made using
sand cores.
Low pressure diecasting
● Dies must be coated with a suitable dressing to avoid
welding of the molten aluminium to the die and to control
the rate of heat extraction.
● The dressings are the same as those used for gravity
diecasting.
● They are sprayed with the die at a temperature of 120–
200°C to facilitate a quick dry.
● The die must then be reheated above working temperature
before casting metal.
● It is very important that particular care is taken in cleaning
dies regularly, say once per week, by “shot”-blasting using
glass beads, otherwise tolerance and surface finish of the
castings will soon deteriorate.
● Die life is normally around 30 000–50 000 “shots”.
LPDC-Die design
● Sand cores made by any of the usual processes –
shell, cold box, hot box etc.– can be used.
● As with any casting process, cores must be
permeable and provision made for venting core
gases to avoid gas defects in the castings.
● Where complex coring is needed, such as for
cylinder heads, it is usual to preassemble a core
package which can quickly be inserted into the die
to avoid slowing down the casting cycle.
LPDC-Cores
● The process is rather slow since the die must be
filled slowly to avoid turbulence and air
entrapment.
● The casting must solidify progressively from the
extremities back to the gate and the gate must
solidify before the pressure can be released.
● Cycle times are similar to gravity diecasting,
about 9 shots per hour are typical for a
component such as a cylinder head.
LPDC-Cycle time
LPDC-Alloys cast The commonly used aluminium alloys include:
● Al–Si5Cu3 (LM4, US 319)
● Al–Si12 (LM6, US 413)
● Al–Si7Mg (LM25, US A356)
It is usual to fully treat the metal by degassing,
grain refining and modifying.
LPDC-typical applications ● Aluminium automotive parts:
● wheels,
● cylinder heads,
● blocks,
● manifolds
● housings
● Critical aerospace castings
● Electric motor housings
● Domestic kitchenware such as pressure cookers
● Large castings up to 150 kg (Al) can be made but
can only be justified in special cases because of
high die costs.
● The process produces castings of high quality, both
metallurgically and dimensionally:
● The metal is drawn from the bottom of a bath of
molten alloy, avoiding the contaminated surface
layer,
● The mould is filled gently without turbulence so
avoiding oxide entrapment,
● Solidification is directional, enabling constant
feeding of the casting by maintenance of pressure
from below,
● casting extraction is relatively damage-less to the
die: dimensional accuracy should be maintained
throughout the life of the die.
LPDC-Casting quality
● Although metal is drawn from below the surface of
the melt, oxide inclusions may still be present due to
the turbulence arising when the furnace is topped up
from the transfer ladle.
● The density of aluminium oxide is close to that of the
metal itself so oxide inclusions may not all float to the
surface.
● Further turbulence is introduced in the furnace by the
fall of the metal in the riser tube each time a casting
is made and the pressure released.
● Casting quality can be improved by fitting a ceramic
foam filter in the sprue to prevent inclusions from
entering the casting.
LPDC-Casting quality !!!
● Casting tolerances in low pressure diecasting are
similar to those of gravity diecasting.
● Variation in the dosing of die coating is one of the
main reasons for dimensional inaccuracies.
● Die distortion over time will also affect dimensions
of the castings.
LPDC-Casting quality
● Gravity die casting is the simplest die-casting
process.
● It enables castings to be produced with only a very
modest capital investment, although plenty of hard
physical work is required!
● However, it can also be automated with either
horizontally or vertically-parted dies.
● Good quality castings can be produced if sufficient
care is taken to design running and gating systems
which minimise surface turbulence in the metal as
it flows into the die.
Gravity Die Casting (GDC)
gravity die casting ● one of the standard processes for the manufacture of
high-integrity automotive castings.
● precision technology for the production of large
batch quantities.
● used in carousel casting units or in shuttle technique
particularly for the manufacture of engine castings.
● Optimum heat dissipation from the solidifying
casting through the die leads to short solidification
times.
● This results in castings which have good mechanical
properties, especially after an additional heat
treatment.
gravity die casting In gravity die casting processes, the melt is
metallurgically treated in the holding furnace, which
is positioned near the dies.
components of a
casting mould
(gravity die
casting).
Cores (inner
parts of the
mould) are
generally made
of bonded sand.
Gravity die casting is suitable
for mass production and for fully mechanised casting.
gravity die casting
gravity die casting ● The molten metal is poured under gravity into a
refractory-coated permanent mould or die.
● The technique is sometimes known as “permanent
mould” or “chill” casting.
● The dies are made of a fine-grained, pearlitic cast
iron or a low alloy steel.
● Simple retractable cores may be made of high
grade alloy steel, but resin bonded sand cores are
used to produce complex internal shapes.
gravity die casting ● With the exception of pressure diecasting, the
process is the most widely used of the aluminium
casting methods due to its inherent simplicity and
the metallurgical quality and complexity of
castings that can be made.
● The process is used for castings made in numbers
from 1000 to more than 100 000 per year, for
example manifolds, cylinder heads, water pump
housings etc.
● Casting size ranges from less than 1 kg to over 50
kg.
● The dies are coated with a refractory-based coating.
● The coating reduces the heat transfer to the die so that cooling
rates are faster than in sand moulds but slow enough for complex
castings to be filled satisfactorily.
● Different coatings are available which allow faster or slower
cooling as the shape and section of the casting requires.
● The time before the casting can be extracted from the die may
vary from 4–10 minutes depending on the type of casting.
● The process is therefore relatively slow.
Solidification times of Al castings made by different processes
gravity die casting
gravity die casting-Running and feeding
● The gravity die casting process produces castings of high
metallurgical quality. Metallurgical structures and
properties benefit from the chilling achieved by gravity
die casting.
● The objective of running the metal into the cavity is to
make entry as smooth as possible, avoiding turbulence
which would introduce oxide film defects.
● The speed of filling is a compromise between getting the
metal to the furthest point of the die quickly enough to
avoid misruns, and pouring slowly enough to avoid
turbulence.
● Bottom gating is the traditional way of achieving
turbulence-free filling but bottom gated castings have
poor yields and incorrect thermal gradients.
● Feeders need to be at the top of the casting and
must be the last masses to freeze, but optimum
directional solidification is not easy to achieve
when the metal is bottom gated and has to
traverse the die cavity and any cored passages
before reaching the feeders.
● One way of improving feeding is to tilt the die
when pouring in such a way that the last metal is
poured into the feeder.
● Special tilting machines are available to allow
this to be done.
gravity die casting-running and feeding
● The widespread use of ceramic foam filters and
insulating feeders has greatly improved the
quality of gravity castings in recent years.
● A recent development has been the use of direct
pouring methods, either through a filter fitted
directly in the die or through a combined
filter/feeder.
● This greatly improves yield, achieves turbulence-
free filling and also feeds the casting with the
hottest metal.
gravity die casting-running and feeding
The usual alloys cast by gravity die casting are:
AlSi5Cu3, A319
AlSi12, A413
AlSi7Mg, A356
● AlSi12, A413, being the eutectic alloy, has the
best fluidity and is good for thin section castings
but its machining characteristics are poor.
● AlSi7Mg has good fluidity and good machining
properties, it can be heat treated and is
corrosion resistant.
● Al–Si5Cu3, A319 has somewhat lower fluidity due
to its low Si content and has good machinability.
melting and metal treatment
● It is advantageous for a foundry to use the
minimum number of different alloys, allowing
bulk melting to be used for the majority of the
castings.
● Since gravity diecasting is capable of making high
quality castings and is used for critical castings
such as cylinder heads, hydraulic castings etc., it
is usual to fully treat the metal by degassing,
grain refining and modifying.
Melting and metal treatment
● Permanent moulds are manufactured from high
alloy steels (hot work tool steels (H13) are used in
the manufacture of pressure die casting moulds).
● Casting quality is superior with respect to that
obtained in sand casting.
● Preferred for parts with high surface quality and
with limited dimensional tolerances.
● Mechanical properties in gravity die cast parts are
at least 20% better than sand cast counterparts.
● Up to 100.000 shots can be produced with
permanent moulds.
gravity die casting
● Minimum wall thickness must be 3mm (2 mm is
possible in small parts.
● Weight of castings range between several hundred
grams and several hundred kilograms.
● In addition to producing ever more complicated
cylinder heads for petrol and diesel engines,
gravity die casting is also used for the manufacture
of diesel engine blocks with cast-in grey iron
liners.
● Some foundries use gravity die casting to produce
cylinder blocks weighting 300 kgs.
gravity die casting
Gravity diecasting
Thin section (<5 mm) gravity die castings cool so quickly that
it is sometimes considered unnecessary to grain refine or
modify the alloy.
For castings having sections above 5 mm, grain refinement is
beneficial and modification of eutectic alloys (10–13% Si) may
be used.
Melting practice for high quality gravity die castings and low
pressure die castings is generally the same as for sand casting.
In some less-critical gravity die castings, a small amount of gas
in the metal may be beneficial since dispersed gas porosity
may be considered less harmful than shrinkage.
The metal is melted as usual using the appropriate cover flux.
Degassing is not usually necessary.
Skim off the dross and cast.
Special requirements for gravity diecasting
● The die casting processes are limited by their poor
productivity since it is necessary to wait for the metal
to solidify before the die can be opened.
● As an example, the cycle time for producing a typical
die-cast cylinder head is about 5 - 7 minutes,
although this can be as long as 15 minutes for larger
variants, such as a Jaguar cylinder head.
● Therefore, die casting should be restricted to thin-
walled components.
● The other limitations with all forms of die casting are
the high cost of the dies themselves and their
limited lives as a result of thermal fatigue which
causes craze-cracking of the working faces.
gravity vs pressure die casting
● Porosity that is almost inevitable in pressure die
casting degrades mechanical properties and leads to
blisters after heat treatment.
● Gravity die castings have less porosity; are more sound
and leak tight.
● Gravity die castings can be machined with no evidence
of porosity on the surface. Pressure die cast
components, on the other hand, cannot be machined
due to the presence of porosity!
● surface quality is higher in pressure die casting
● A machined pressure die casting may be stronger
than a permanent mold casting. However, the latter
is more reliable because of less porosity.
gravity vs pressure die casting
● Pressure die casting is superior with thin sections and
due to closer dimensional tolerances.
● Die-tooling costs are lower.
● Parts that cannot be cast with pressure die casting
due to sand cores can be cast with the gravity die
casting route.
● Pressure die casting is faster and yields more parts in
unit time.
● Dies in pressure die casting must be stronger than in
gravity casting and are thus more expensive
● Cost per part is lower (for high volume production)
● Alloys for die casting are few as high castability is a
must!
gravity vs pressure die casting
casting processes-comparison property sand gravity pressure
strength good best good
density good best medium
repetability medium good best
tightness good best medium
Cost per part medium good best
Production rate medium good best
Alloy variability best good medium
tolerances medium good best
Design flexibility best good medium
dimensions best good good
Surface quality medium good best
Tool preparation best good good
Cost of die best good medium
● The use of modern die casting techniques improves the
metallurgical quality of die castings.
● Heat treatment is possible with some processes so
extending the application of the die casting to
components such as hydraulic manifolds, brake callipers,
engine brackets, suspension arms, engine blocks etc.
● One limitation of pressure die casting is that complex
cored castings cannot be made.
● It is not possible to use sand cores since the high
injection pressure causes metal penetration.
● Special salt cores have been used, but are difficult to
remove from the casting.
● Coring is limited to using tool steel “pulls”.
Applications of die castings
Metal handling in the die casting foundry
● The commonly used pressure diecasting alloys
contain 8–10% Si and 2–3% Cu with around 1% Fe.
● The presence of iron reduces the tendency for the
casting to “solder” to the steel die but it tends to
deposit inclusions in melts that are held for any
length of time.
● The most frequently used alloys are:
● Al–Si8Cu3Fe (LM24, US A380)
● Al–Si10Cu2Fe (LM2)
● Al–Si9Cu3Fe (LM26)
Metal handling in the die casting foundry ● Metal is normally melted in a bulk melter, either electric
induction or gas-fired shaft or crucible furnaces.
● For many years, it was not considered worthwhile to degas
the alloy before casting (because some gas porosity is
accepted as inevitable).
● Furthermore, the cooling rate in the die is so fast that
grain refinement and modification are also not required.
● However, it is found that treatment of the liquid alloy by a
Rotary Degassing Unit is effective in removing non-metallic
inclusions, reducing sedimentation of hard iron–manganese
inclusions as well as lowering gas content.
● Increasingly diecasters are using Rotary Degassing in the
transfer ladle for this reason.
● Some diecasters find that modification with strontium is
also valuable.
Metal treatment ● It is important to keep melting and holding furnaces clean
to prevent hard inclusions of corundum from entering the
castings.
● Regular use of a cleaning flux, is recommended.
● Bulk melting is carried out under a covering/drossing flux
to ensure minimum metal loss, forming a complete cover,
adding half early and the rest at final melt down.
● The metal is poured into the transfer ladle and degassed.
Modification may also be done at the same time.
● Note that sodium modification is not suitable since the
metal may be held for a long time in the holding furnace
before use.
● In the holding furnace, a low temperature flux can be
used as a cover to reduce metal loss.
Die coating ● Refractory die coatings are not used for pressure
diecasting, since high heat transfer is needed to cool the
casting quickly and achieve fast casting cycle times.
● However, the die must be sprayed between each shot with
a lubricant.
● The die cycles at a high temperature (250–300°C) and at
regular intervals molten metal is injected at high pressure.
● All the alloys cast commercially will attack and weld to
steel dies.
● The lubricant must protect the expensive die from direct
metallurgical attack and erosion as well as lubricate slides,
cores, ejector pins etc. to prevent them seizing at the high
operating temperature.
● The coating also has a cooling function.
Share of Al castings market held by various processes
The pressure diecasting process is such a powerful casting
process, producing castings of such excellent surface finish
and dimensional accuracy, that many developments have
been made to overcome the basic problem of low internal
integrity of the castings due to air entrapment.
Vacuum diecasting
The shot tube and die cavity are evacuated before metal
injection to reduce the amount of air that is trapped.
Pore-free diecasting
The cavity is flushed with oxygen rather than air. The oxygen
should then combine with the liquid aluminium, forming
oxide which is less harmful than gas entrapment.
Modification of the diecasting process
Vacuum die casting of precision engineered die cast products Used when no surface
flaws such as blisters etc
are forgiven. When high
temperature powder
coating is an essential
step in manufacturing
cycle.
Indirect squeeze casting
● Metal is injected into a closed die cavity by a small
diameter piston which also exerts sustained pressure during
solidification.
● a special thermally insulating die release agent is used to
provide a significant thermal barrier between the casting
and the die during filling allowing the metal to be fed
further into the die cavity without freezing.
● When pressure is applied to the full cavity, the die coating
is compressed reducing its insulating effect.
● The metal velocity during filling is controlled to ensure
non-turbulent flow so that air entrapment is minimised.
● When the cavity has been completely filled, the pressure is
applied (from 60 to 100 MPa).
Modification of the diecasting process
● It is most important that the temperature gradients
within the die are controlled so that the casting
freezes directionally towards the gate area.
● This gate area is made deliberately very thick so that
it will be the last area to solidify.
● In this way, all the metal freezes under pressure
reducing the possibility of shrinkage porosity.
● The low metal velocities used do not wash release
agent from the die faces so that contact between the
alloy and the die steel is reduced.
● There is no need to use high-iron alloys to prevent
Soldering.
Modification of the diecasting process
● The resulting physical properties of the castings
are much enhanced over conventional pressure
diecastings.
● the gas content is low so that heat treatment is
possible and hydraulic integrity good. Indirect
squeeze castings can be used for critical
components such as brake callipers and hydraulic
components.
Modification of the diecasting process
disadvantages:
● large, thin, wall castings are not possible,
● yield is reduced because of the large gate section
that must be used,
● shot rates are slower than in conventional
pressure diecasting and
● the machines are expensive.
Modification of the diecasting process
Investment Casting ● wax patterns are coated with a refractory (i.e. the
patterns are invested in alternate layers of slurry and
stucco), and are subsequently melted out to leave a
hollow shell into which the metal is cast.
● It is an extremely slow process and the production rate is
governed by the time to make the mould.
● The production of a wax pattern might take only 1 or 2
minutes but most ceramic shell moulds require between 7
and 14 coats and take at least 24 hours and sometimes as
long as several days to complete.
● However, it is now normal practice to make several
hundred moulds automatically in one batch and, of
course, each mould may comprise several dozen or over a
hundred small components.
Investment Casting Processes Stages in investment (lost wax) casting
● Make wax pattern in die
● Assemble patterns onto 'tree'
● Build up ceramic shell mould
● Dewax and fire shell
● Pour metal and allow to solidify
● Remove shell
● Separate castings from runner system
and fettle
● The actual LFC-process uses patterns of
expandable polystyrene (EPS) for industrial
applications.
● These patterns, directly foamed to shape, are
immersed in a moulding box with binderless sand.
● The liquid metal, which is poured into the cups of
the downsprues, vaporises the EPS pattern, which
is precisely replaced by the metal.
● With the possibility of assembled patterns very
complex shapes can be created and the castings
can be reproduced with remarkable dimensional
accuracy.
The Lost Foam Casting process
The Lost Foam Casting process ● the filling rate of the mould is determined by the rate at
which the EPS pattern is destroyed by the liquid alloy.
● This in turn is greatly affected by the properties,
particularly permeability, of the coating.
● The result is an essentially turbulence-free mode of
filling, whether from the bottom, side or top.
● Due to the freedom from turbulence and its associated
trapping of oxide films, lost foam aluminium castings can
be of high metallurgical integrity.
● The process is therefore increasingly used for critical
automotive castings such as cylinder heads and blocks,
water , brackets, inlet manifolds up to about 20 kg
weight.
● LFC offers the possibility of a direct production of
nearly any complex geometry including
complicated undercuts and cavities without tapers
and the need for considerable finishing work.
● Compared to the conventional sand casting
methods it has economical and ecological
advantages.
● It is still used for rapid prototyping of intricate
components or large castings.
The Lost Foam Casting process
Stages in the 'lost foam' process
● Produce expanded polystyrene pattern
● Assemble patterns onto runner system
● Coat with ceramic slurry and dry
● Embed in sand and vibrate to consolidate
● Pour metal
● Remove from sand
● Clean and fettle castings
The 'lost foam' process
Pattern making.
First step in the LFC-process is the pre-expansion of EPS
beads. After maturing the beads are blown into a mould
forming the pattern sections. The mould is then steamed to
expand the beads further and tightly fill the cavity of the
mould. Hot steam and expansion of the beads causes them to
weld together.
Cluster assembly. Complicated parts including undercuts and
hidden cavities cannot be moulded in one working step, but
are assembled from pattern segments into a final pattern.
Joining techniques used are gluing, heated platen welding and
plugging. In order to increase the efficiency of the total
process several patterns are combined into a cluster and
supplied with a common gate system, also made of EPS.
The ‘lost foam’ process
Pattern assembly
Source: BMW AG
Landshut
Cluster with
two cylinder
heads
The ‘lost foam’ process
Coating:
● The clusters are coated with a refractory coating layer
by immersion in a water soluble ceramic slurry.
● The coating layer has the function of guiding the
gasification process of the pattern and to form a
barrier between the moulding material and the gas-
filled bubble which exists between the still solid EPS-
pattern and the intruding aluminium melt.
● After the coating has dried, a thin, hard and
permeable coating remains.
● The coatings are typically applied to a foam cluster by
dipping, spraying or pouring.
The ‘lost foam’ process
Embedding in sand:
● After the coating has dried, the cluster is placed in a flask
and backed up with unbonded quartz sand without
chemical additives.
● The sand is compacted through vibration with various
frequencies, which causes the sand to fill all hidden
cavities of the patterns.
coating Sand fill compaction
The ‘lost foam’ process
Coating of a cluster with two cylinderheads
The ‘lost foam’ process
Pouring: During the filling process the molten metal flows via
the gate system into the EPS-patterns, which is gasified, filling
up the cavity and replacing exactly the pattern geometry.
During this stage it is important to avoid turbulences, support
the casting cavity wall and to realise a progressive elimination
of the foam pattern.
The gas originating
from EPS decomposition
permeates the coating
layer and escapes into
the sand, possibly
supported by an
external vacuum.
The ‘lost foam’ process
Permeable coating
Form filling velocity and type of metal flow, i.e.
laminar or turbulent, determine the part's quality by
influencing the amount of oxide inclusions and
porosity.
Specifically, the following sets of parameters have to
be tuned to each other:
● permeability of coating,
● optional external vacuum,
● metal temperature,
● EPS-pattern density and type of adhesive,
● geometry of the gating / riser system and of the
patterns
The ‘lost foam’ process
Dumping, quenching and trimming:
After solidification of the casting, the sand can be removed
from the flask and be prepared for the following moulding.
Clusters are quenched and knocked-off from the gate system.
The castings are purged and controlled w.r.t. defects. In
many applications the castings don't require any further
mechanical finishing.
The ‘lost foam’ process
● Low tooling cost: Though tools are expensive, their
life is long, up to 500 000 cycles are possible. So for
long-running, high volume parts overall tool costs
are much lower than for conventional casting
process. For shorter running parts the advantage is
less and may even be a disadvantage.
● Reduced finishing: There is a major advantage on
most castings since finishing is restricted to
removing ingates.
● Reduced machining: For many applications,
machining is greatly reduced and in some cases
eliminated completely.
Advantages
● Ability to make complex castings: For suitable
applications, the ability to glue patterns together
to make complex parts is a major advantage.
● Reduced environmental problems: Lost Foam is
fume-free in the foundry and the sand, which
contains the EPS residues, is easily reclaimed using
a simple thermal process. (binder-less recirculated
sand/no sand reclaiming system)
● high productivity
● high flexibility
● potential for Rapid Prototyping
● good surface quality.
Advantages
● The process is difficult to automate completely;
cluster assembly and coating involve manual
labour unless a complete casting plant is dedicated
to one casting type so that specialised mechanical
handling can be developed.
● Methoding the casting is not easy and a good deal
of experimentation is needed before a good
casting is achieved.
● Cast-to-size can be achieved but only after several
tool modifications because the contractions of
foam and casting cannot yet be accurately
predicted.
Disadvantages
● long lead times are inevitable for new castings.
● it is difficult to achieve the highest metallurgical
quality in Al castings because of the need to cast at
rather higher than normal temperatures. (However,
new thermally insulating coatings are available for
the patterns and allow lower casting temperatures.)
● possible deformation of pattern during sand fill and
compaction,
● possible entrapment of plastic residues caused by
non-optimised gating systems,
● large number of process parameters need to be
controlled for optimum form filling.
Disadvantages
Lost foam casting
Cylinder heads
BMW AG Landshut
The Lost Foam casting process
● The usual alloys used for sand and gravity casting
can be cast successfully by Lost Foam and the
methods of melting and treatment are the same.
● The automotive industry is a major user.
● The inlet manifold was the first successful high
volume application.
● Cylinder heads are being made in growing numbers.
Use of Lost Foam gives the designer rather more
freedom to cool the working face effectively, the
combustion chambers can be formed “as-cast”,
avoiding an expensive machining operation, and
bolt holes can be cast.
Applications
● Lost Foam offers significant design advantages
over other casting processes for cylinder blocks;
features can be cast in, such as the water pump
cavity, alternator bracket, oil filter mounting pad.
● Oil feed, drain and coolant lines can also be cast
more effectively.
● A variety of other automotive parts are being made
including water pump housings, brackets, heat
exchangers, fuel pumps, brake cylinders.
Applications
Semi-solid processing
Semi-solid-route?
Solid feedstock
forging
Liquid alloy
Pressure die casting
solid (%60)-liquid (%40): Semi-solid forging
3: forging
2: thixo-route
B→ A
T 1
2
3
solid (<%10)-liquid (>%90): Semi-solid casting
1: pressure die casting
Thixocasting ● This process makes use of the thixotropic
behaviour of semi-solid metallic alloys.
● Slugs of aluminium alloy are inductively heated
into a semi-solid state; the slug is introduced into
the shot sleeve by a robot arm.
● the globular feedstock behaves like a solid (high
viscosity) if not sheared.
● As soon as shearing occurs, viscosity decreases by
orders of magnitude.
● Under certain conditions this effect is reversible.
Metallic alloys have strong thixotropic behaviour if:
● it is possible to bring the metal homogeneously to
the required semi-solid state, i.e. enough
solidification range is present,
● a microstructure with very fine and round grains
exists.
All semi-solid forming processes are characterised by:
● 10 to 70% solid phase during forming,
● Thixotropic properties: initially the metal's viscosity
is high. After being sheared its viscosity decreases
strongly.
● the metal solidifies during forming.
Thixocasting
Specific properties of the products:
● Since only part of the metal is liquid, shrinkage
porosity is reduced.
● Solidification takes place very rapidly and little
heat extraction is necessary.
● Since the viscosity of the metal is high, mould
filling occurs in a very laminar way.
● Net-shape parts can be produced.
Thixocasting
Process steps of Thixocasting Liquid metal is first DC-cast to fine grained billets which are
then reheated to the semi-solid state and formed to the final
product..
This process has
been mainly used
during the last 20 years
Thixocasting
● The metal used has to show very fine and spherical
grains to increase the shear thinning effect during
forming.
● DC-casting is normally combined with strong
electromagnetic stirring. This leads to fine rosette
like grains.
● During re-heating the metal, grains become
spherical, as required for semi-solid forming,
● During forming, the weak bridges between the
grains break, leading to a strong reduction of
viscosity (shear thinning).
Metallurgical aspects of SS process
Metallurgical aspects of SS process Microstructure of
AlSi7Mg0.3 before
re-heating
Microstructure of
AlSi7Mg0.3 after
re-heating
Rheocasting Liquid metal is directly cooled down to the semi-solid state
and processed to the final product. Since 1999, this process
family is gaining new attention
Process steps of Rheocasting
● During cooling the liquid to the semi-solid state,
some specific conditions have to be fulfilled to get
the fine grains required.
● A very high amount of grain seeds have to be built.
This can be produced by using chemical grain
refiners, suitable thermal conditions or mechanical
vibrations in the melt,
● During the process of partial solidification, the
many grain seeds grow and, after touching their
neighbours, get spherical.
Rheocasting
Rheocasting
Microstructure of AlSiMg0.3 alloy ready for forming
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