gordes zeolite presentation(gordes)
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The address where Turkish zeolite is
sought for in the World!
The Founder of the Öztürk Group, Fikret Öztürk, who started his private business at the beginning of the 80’s, has since made some unique achievements in the business world. By
investing in the future he attained a position of respect in business circles. He made the Öztürk
Group a multi-faceted company with his entrepreneurial spirit. The steady success accomplished
in the field of petrol trade and distribution directed the company towards business sectors with a
huge growth potential such as real estate development and food. Today, the Öztürk Group is
noted for its professional management, high performance companies, sound financial
infrastructure and ongoing innovative project launches.
Established in 1992, OPET Petrolcülük A.ù. is engaged in distribution and International trading of oil
products. In 2002, the Koç Holding Energy Group became a 50% shareholder in Opet. Since its inception, OPET has been heavily investing in infrastructure. Its storage capacity (terminals) gives
Opet a significant competitive edge, of which capacity has reached 845,930 cubic meters. Having been increasing its market share continuously the company’s goal is to become the first choice of
Turkish consumers. Opet’s efforts are based on ensuring customer satisfaction through improved
quality while protecting the environment and strictly complying with all applicable laws and
regulations.With its robust infrastructure and realistic vision, and its faith in Turkey, Opet has become
the fastest and most steadily growing oil company of the last decade in Turkey.Currently, there are
1600 petrol stations across Turkey under Opet and SUNPET.
www.opet.com.tr
Türk Hava Yolları A.O. and OPET Petrolcülük A.ù. have each 50% interest in the company THY OPET Havacılık Yakıtları A.ù. established on September 18, 2009 with a 75-million-dollar investment
budget to operate in the field of fuel storage and refueling of aircrafts. Combining the aviation expertise of Turkish Airlines that proceeds on its path to become one of the
leading airlines of Europe with Opet’s long-established presence in the fuel sector, THY OPET aims
to become a landmark company in each category in which it operates at home and abroad with a
focus on “Unconditional Customer Satisfaction and High Quality” with its experienced and qualified workforce.
Having commenced jet fuel supply and into plane operations on July 1, 2010 with its strong technical
infrastructure and the specially equipped state-of-the-art refuellers and dispensers, THY OPET was
capable of providing supply and into plane services in all airports Turkey-wide as of the end of 2010.
THY OPET is a company that aims to meet the fuel requirements of national and global airlines,
including THY. THY OPET operates at all airports in Turkey today.
www.thyopet.com
Opet Petrolcülük A.ù. carries out its Mineral Oil production operations at its facility located at İzmir Atatürk Organized Industrial Zone. Opet Fuchs A.ù
facility which is capable of producing 30,000 tons of mineral oil and 6 million units of car care products on an annual basis via a single shift has the
following certificates: TS EN ISO 9001: 2000 Quality Management System and TS EN ISO 14001:2004 Environmental Management System, TS
18001:1999 OHSAS - Occupational Health and Safety Administration System and TS 16949 Quality Management System for Automotive and Relevant Spare Part Producers. It has also obtained Ford Q1 and TSE EN ISO/IEC 17025 Laboratory Accreditation Certificates. Opet Fuchs A.ù a broad product
range in the Mineral Oil and Car Care Market with our FMY branded products approved by Opet, Fuchs, Rom, Wynn's, Türk Traktör and Ford Otosan.
Approved by the internationally respected engine producers such as MAN, Volvo, Mercedes Benz, and Ford, our products are preferred by the consumer.Opet MineralOilsand Rom Car Care Products are also exported to more than20countries.
Opet Fuchs A.ù., a company established in partnership with FUCHS PETROLUB AG, the biggest independent mineral oil producer of the world, in 2005 to engage in the
production and distribution of industrial oils, is every day
progressing on its way to become the leader of the
industrial oil market in Turkey.
www.opetfuchs.com
Regnum is a leading property developer with projects in Turkey, Bulgaria and the UK. Regnum offers a diverse range of projects suitable for different levels of investment and requirements. City projects in Istanbul and London
offer potentially significant capital appreciation and healthy rental yields for its investors. Regnum’s lifestyle
projects are currently located in the beach resort of Bodrum-Turkey and the ski resort of Bansko-Bulgaria offering
secure well managed complexes of the highest quality.
Completed projects include: Sky Residence, Elitkent and Astrum Towers in Istanbul, Bargylia in Bodrum,
Carya Golf Club in Belek-Antalya, the office & logistics project, Gimat, in Ankara, Crystal Luxury Ski &
Spa Apartments in Bansko and Helion Place in London. Current projects include: Solarkent in Istanbul,
Escana in Bodrum, and a project in the vicinity of Tower Bridge in London. Regnum is also working on major gated community projects in Turkey around the İstanbul and Antalya areas.
Future plans include: projects in Kosuyolu and Cobancesme, in Istanbul, Belek in Antalya, Plovdiv in
Bulgaria and Royal Mint Street in London-UK.
www.regnum.com.tr
Güvenok Logistics has been conducting transportation operations of OPET warehouses and renders transportation service to all OPET dealers who demand it, and carries out the transportation operations of
OPET Commercial Industrial Fuels department. Furthermore, it has been executing all the transportation
operations of TÜPRAù since June2006. Operating in accordance with EMRA and State Highways transportation standards, which are requirements to be observed by the fuel transportation sector, Güvenok
A.ù. has adopted the principle of safe and high quality service. The company conducts outgoing supply
operations in HSE-S standard via ADR Certified tankers and trailers, meeting ADR standards.
www.guvenok.com.tr
www.caryagolf.com
Carya Golf Club invites you to experience Turkey’s first heathland inspired
golf course and share our traditional style golf club, which we hope you will
make a home away from home during your stay in Antalya’s Belek region.
Our outstanding golf course has been designed by Thomson Perrett &Lobb Golf Course Architects, the international golf course design practice founded by
five time British Open Champion Peter Thomson. As you would expect, a very
special
and memorable round of golf awaits you.
Carya Golf Course is a naturally beautiful golf course set on undulating sand hills. Inspired by the classic heathland courses found in the UK where Peter
Thomson enjoyed much success as a player in the 1950’s and 1960’s, the
spectacular Par 72 layout measures 6,563metres (7,177 yards) from the championship tees, with free flowing golf holes running through the pine forest.
Based upon 30 years of experience in business, Öztürk Group is now the owner of Gordes Zeolite that takes part in the area of
the most productive zeolite deposits thus the group has started to provide services in the mining sector during the last quarter of 2011, as well.
Our company which had been known as “Enli Mining” in the world natural zeolite literature with its qualified and comprehensive sectorial
backgroud since 1998, is now named as “Gordes Zeolite” which is the name of this distinguished region we produce clinoptilolite raw material.
Gordes Mining is one of the well-known manufacturers of natural zeolite in the world in terms of the purity of the product and innovation. The area
we produce this industrial raw material, which has the ability of solving many problems naturally, such as air-water-soil pollution and global
warming, has become a preferred mineral deposit and a requested name worldwide in recent years.
Production land of Gordes Mining has features of high quality clinoptilolite structure. It is the only private field in the country that contents high
grade of clinoptilolite type of Zeolite, as the mostly sought and the most widely used type of zeolite among the other 7 types of zeolite which have
commercial importance. In addition, our mine is the only one in the world, including two different recipes of clinoptilolite (potassium and calcium
clinoptilolite) in the same quarry. The mine has a rich source containing potassium, sodium and calcium clinoptilolite -type Clinoptilolite.
Furthermore, our clinoptilolite products differ from the others in the market in terms of purity and functionality. Quality of our products is also
revealed by the academic studies and industrial trials in universities and industrial foundations.
Gordes has undertaken an important mission in the representation of Turkey's
high quality zeolite -based products in the world's natural zeolite platform even it
is the leading Turkish company that has provided to EU market with the local
commercial coded products, enabling the sector to survive. For more than 17
years, our company has been dealing with the marketing and sales business of
clinoptilolite based products all over the world. Technical Team of the Company
is experienced in using and applications with zeolite based products in scope of
agricultural and animal feed industry, especially in Turkey. Gordes Zeolite is a
leading company that has offered the natural zeolite with the specifications in
mass quantities.
www.gordeszeolite.com
The commercial brands are now indispensable in this market. The product i.e. Agro-Clino,
Clino-San, Nat-Min 9000 code are preferred to almost all zeolite based products in the
global market. The R&D works in our company is of the utmost importance and the
production is carried out complying with the quality requirements of ISO 22000-2005 and
ISO 9001-2008. Considering the benefits of our products, it is obviously seen that our
products are more functional and cost effective compared to other raw materials and
products in the market.
Our mission is to process this industrial raw material using the most advanced technologies
and provide it with the most useful forms and recipes for the service of humanity.
The need of humanity for nature and natural, is increasing every day. We believe, this
stone has life in it and we desire to make this wonder of nature a part of our lives by the special products we developed, and provide humanity a clean, lively World.
www.gordeszeolite.com
Mine Deposit Information
City Town Village Location Licence number
Starting time to mine
Licence group, acording to Law for Mining in Turkey
Mine type
Production land
Manisa Gördes Kıranköy Hekim Damları
32242
1998 IV-a
Mineral, Zeolite
3231,41 hectar (32 km2)
Mine Deposit Information 144 million tons (proven), 1,5 billion tons geological reserve. Deposit determined by a
professional team from Istanbul Technical University. It was also accepted by Republic
of Turkey, Ministry of Energy & Natural Resources. Land is also declared by General Directorate of Mineral Resource & Exploration. In this publication, lower tuff unit has
more than 85% of zeolite (clinoptilolite), 1,1 billion tons, proven, but covered reserve is
estimated about more than 10 billion tons according to this production
The map for location: Production land is about 150 km far from Izmir Port.
About Zeolite
Zeolites are described as hydrated aluminum silicates. According to the lexical meaning of the term “Zeolite” means
"boiling stone” . It was discovered by
Freiherr Axel Fredrick Cronstedt, a famous
Swedish mineralogist, in 1756.
Millions of years ago, the zeolites have been formed due to the chemical reaction of ash and lavas as a result of volcano
explosion with the lakes and sea water.
The varieties such as the temperature
geological location-water/ash ratio provide
the zeolites with unique specifications. 50
natural zeolite types have been defined
with different compositions in last200
years. Clinoptilolite is the one that has
been widely used with industrial purpose
featuring
the
commercial
value.
The cage-shaped structure of zeolites makes a wide internal and outer surface area for ion
exchange and chemical reactions. The pores cover the volume by 50%. These pores function
as the molecular sieve. Zeolites are naturally loaded negative and capable of high ion
exchange. Due to the porous structure and high ion exchange capacity, the zeolites are
capable to keep and absorb many kinds of gas and odor, water and moisture, petrochemical substances, low level radioactive elements, ammonium, toxins, heavy metals and many
solutions. Thanks to environmentally friendly and low costs, zeolite is used in many industrial
areas and a variety of environmental projects.
CLINOPTILOLITE
Millions tons of zeolites are used globally every year. The most widespread zeolite group is
clinoptilolite. Main usage areas are; agricultural products (fertilizer additive and soil amendment), construction sector, radioactive and other pollution refinement. Clinoptilolite have hundreds of usage
areas thanks to their high cation exchange, heavy metal removal, water retention capacity and large
surface area.
Some of them are as follows;
Mineral fertilizer additive and soil conditioner for
animal and farming applications
Mineral fertilizer additive and soil conditioner for
gardening applications
Building and construction material
Cement additive
Removal of oil spills
Desiccants
Water filtration
Domestic purposes
Carrier of pesticide and herbicide
Animal feed additive
* Anti-caking agent / flow agent
- Toxin-binder - Feed pellet-binder
Cleaning of marine oil and surface damp
Processing of animal waste
Odor control
Cleaning of chemical spills, hazardous waste
Waste treatment
Natural filtrating material for drinking water and
waste water treatment
Cleaning of waste
Carrier of colloidal materials
Products with vitamin
Nuclear improvement
Carrier of enzymes, antibiotics, glucose, sugar
Food additive
GORDES ZEOLITE (CLINOPTILOLITE) Gordes zeolite is in clinoptilolite structure. It is highly pure as can be seen on the photograph
demonstrating its crystal structure. Our products are in potassium-calcium alumina silicate
structure.
Chemical structure of our Gordes zeolite products are as follows:
Element: % by weight Si =
29.4
- 30.1 Al =
5.6
-6.1 Fe =
0.05
- 0.25 Mg =
0.1
- 0.6 Ca =
0.9
- 1.3 Na =
0.2
- 0.5 K=
1.9
- 2.7
SEM Photograph of Gordes Clinoptilolite (Crystalline structure )
Unit cellular chemistry of Gordes clinoptilolite (chemical
formulation) is as follows;
(Na 0.5 K 2.5) (Ca 1.0 Mg 0.5)(Al 6 ,Si 30) O 72 . 24 H2O
Description: Natural potassium, calcium, magnesium, sodium, hydrate
alumina- silicate mineral.
GORDES ZEOLITE (CLINOPTILOLITE )
In its chemical composition, main oxide components
except trace elements are;
Oxide Component
% (By Weight)
SiO2
67.11
Al2O3 11.84 Fe2O3 1.47
Some of the physical characteristics are;
Natural rock, white, beige,
MgO 1.15 CaO 2.18
Color
Hardness (according to Mohs hardness scale)
almond green
3
Na2O
0.38
Specific Weight
2,1 g/cm³
K2O 3.44 Ignition loss 12.5
Visible porosity 35% Water absorption capacity 135% Water retention capacity 20-50% Thermal stability:
840 °C
Surface area (BET)
40͘79 m²/g
NH4 ion exchange
capacity:
1,7-2,1 meq/g
Thermal stability Up to 840 °C Clinoptilolite crystal size 5-15 μ m
pH stability: 1,5-11,5
Average pore radius 0,041 μ m
Capacity of water
absorption by weight:
20-40%
Quiet homogenous, containing 85- Mineralogical feature: 99% clinoptilolite. Gangues are
Feldspar, mica and clay.
Current Product Line of Gordes Zeolite Mining Corporation
CLINO-SAN
Clinoptilolite for many of miscellaneous purposes
Animal feed additive,
NAT-MIN 9000
Covers EU feed lows
(Contents minimum 90 % Clinoptilolite, up to 99 %) Fertilizer additive and soil amendment , for all uses in agriculture
AGRO-CLINO
High C.E.C., water adsorption capacity, covers Organic Farm Input Material, EC 2092/91,
Annex II Fertilizer additive and soil amendment, especially for grasses, golf courses and horticultural applications.
CLINO-ÇİM
High C.E.C., water adsorption capacity, covers organic farm input material, EC 2092/91,
Annex II
Animal litter ZETA
High C.E.C., ammonium adsorbent, odour and moisture removing, Drinking and waste water treatment, FILTER-CLINO
High C.E.C., ammonium adsorbent, and heavy metal adsorbent, particle size is optional
CLINOPTILOLITE For current and other applications, prepared according to demands, special material
FEED ADDITIVE PRODUCTS
Nat-Min 9000 is a product that is safely used by factories that produce feed for dairy and beef cattle, broiler and laying hens, sheep and turkey raising. Using high CEC feature, it retains water, oil and many molten minerals (Na, CA, Ammonium) in its channels, releases them effectively during digestion and provides an
effective, well balanced and healthy diet.
Nat-Min 9000 is mixed with the feed (2%, approximately 1-2 tablespoons to 1 liter of feed) of the pets,
poultries, bovine and ovine animals. Product may also be added to the drinking water of aminals, at the same
rate. It supports digestion, removes hazardous substances(such as ammonia, ammonium, heavy metals,
mycotoxins) quickly from their metabolisms and enhances growth of animals. You can safely use Nat-Min
9000 which is produced from totally natural minerals.
Nat-Min 9000 provides improvement of the appetite of the animals, regulation of digestion system and
strengthening of the immune system.
AGRICULTURAL PRODUCTS
Using AGRO-CLINO in Plant Nutrition
Clinoptilolite releases its natural nutritional elements into soil by ion exchange. Thus, nutritional elements enrich the soil. It also maintains cation exchange and
water retention feature for a long time since it is not dissolved in water.
AGRO-CLINO as Soil Conditioner AGRO-CLINO is an excellent soil conditioner with its high cation exchange capacity, water retention and adsorption
features. In a research conducted in China, yield of the products like potato, corn and wheat has increased between 5,8 - 14,14% by its addition to soil in certain quantities. It was stated that clinoptilolite improved water regime of the soil and
prevented washing of the nutritional elements in soil.
Effects of AGRO-CLINO on Benefiting from Fertilizer • AGRO-CLINO can function in plant nutrition as ionic fertilizer additive by translocation with ammonium and
potassium. Besides, the most important macro-nutritional elements, potassium and nitrogen and the most important
micro elements, iron, copper, manganese and zinc can be provided by means of AGRO-CLINO.
• AGRO-CLINO prevents nitrogen fertilizer from being washed with high selectivity of clinoptilolite against ammonia and
high ammonium exchange capacity. • As the particle size of clinoptilolite decreases, its surface area and water retention capacity increases. Moisture rate
detained in the soil increased as well, based on the implemented clinoptilolite dosage.
USAGE
Turf can be mixed with chemical fertilizer and farm fertilizer and used in cultivation of all plants under field
and greenhouse conditions. In fruit trees such as apple, cherry, peach, nut, apricot, quince, plum and banana, it is mixed with soil to
branch knot at root level.
Amount to be used depends on the plant and soil structure.
For fruit trees:
2-6 kg/tree
For industrial plants:
50 kg/da For vegetables:
50 kg/da Greenhouses:
150-200 kg/da Cereal production:
50 kg/da Nut production:
2,5 - 5 kg/da Strawberry production:
100-150 kg/da
ANIMAL LITTER PRODUCTS
ZETA is a 100% natural product that can be used directly or mixed with other base plate materials with its high water retention capacity, and ability to adsorb ammonia
gas due to its ion exchange feature. Both of the positive features of the product can
be clearly seen in animal base plate applications.
Unpleasant odor caused by ammonia is one of the most serious health problems
encountered in stables of cattle, poultry coops and living environment of pets.
UREA + WATER = = > AMMONIA GAS + CARBON DIOXIDE GAS ZETA’s function can be summarized as removing the moisture on the base plate and
ammonia gas that occurs. Therefore, a base plate material with higher water
retention capacity is required.
USAGE ZETA is used by mixing with wood shavings or other adsorbent materials such as bentonite.
ZETA also keeps the living environment of animals sterile. It is already known that gelling feature of sepiolite and bentonite is fine. However, ZETA has to be coupled with these products when natural and permanent solution is sought for odor control.
We serve you ZETA in 25 kg. packages.
FILTER PRODUCTS Products Features
Product Name
FILTER CLINO
FILTER CLINO is produced from clinoptilolite, which
is one of the calcium alumina-silicate group minerals and used globally for filtration and refinement applications. FILTER-CLINO is used for
gas separation in drinking water, domestic and
industrial waste water refinement and filter and
refinement material in odor control applications.
Usage Purpose Produced from watery potassium, calcium alumina- silicate Clinoptilolite mineral. Natural mineral fertilizer
additive and soil amendment
Color Whitish beige, white, almond green Specific weight 2.1 g/cm3
Bulk density 0,6 - 1,0 g/cm3
Water retention capacity 20-40% Visible porosity, mean
35 -40%
FILTER CLINO’s Function
Chemical composition
SiO2 = 66-69
Na2O = 0.5 Al2O3 =11-12
K2O = 3-3.5 Water Filtration Applications
Fe2O3 = 1.0-1.7
BaO < 0.1 Urban drinking water
TiO2 < 0.1
SrO < 0.1 Pool water
MgO = 1
LOI = 12-14 Industrial waste water
CaO = 2
FILTER CLINO can absorb pollution in water with
its cation exchange, molecular sieve and
NH4 exchange capacity 1,6 - 2,0 meq/g (Mean) = 1,8 meq/g
adsorbent features, Helps to increase clarity of water,
Filtrates grains below 0,1 micron, Filtrates ammonium, heavy metal ions and
bacteria, Adsorbs ammonium ions, reduces chloramines,
odor and eye burns.
CO2 adsorption capacity Clinoptilolite unit-cellular chemistry
Clinoptilolite Crystal Size
Mean pore diameter size
Surface Area
94 mg CO2/g (Na 0.5 K 2.5) (Ca 1.0 Mg 0.5)(Al 6 ,Si 30) O 72 . 24 H2O
(5-15 mμ)
0,041 μ m
40,79 (m2/g)
Clinoptilolite thermal resistance
(High, up to 840o C')
Particle size 1 -3 m ; 1 - 4 mm, 3 - 7 mm, 4 - 9 mm or in other preferential sizes
Regeneration: FILTER CLINO is rechargeable and can be used again and again. It can be recharged generally
through a sodium chloride salted water process. 20 g NaCl solution is prepared with 1 liter of water. FILTER CLINO is
well washed before using in filtration system. After recharging, salted water solution will contain ammonium. FILTER
CLINO is replaced by time due to saturation and saturated FILTER CLINO can be used as soil amendment as well.
Using FILTER CLINO in Urban Drinking Water Filtration: FILTER CLINO’s function has three aspects;
Physical filtration; micro sized grains (< 4 micron) are adsorbed on the blanks of mineral grains Chemical filtration; FILTER CLINO is a fine cation exchanger used in removing heavy metals ( Pb, Cu, Cd, Zn, Co,
Cr, Mn, As, Hg, etc) and ammonium, Adsorbs bacteria, algae and various coloring substances). Thanks to its wide surface area, molecular sieve, high cation exchange feature, FILTER CLINO can be used instead
of quartz sand in filtration environments where quartz sand is used. FILTER-CLINO in Aqua Culture Applications: Fish population significantly declined due to reasons such as pollution
of the seas with industrial and domestic waste and demolition of fish beds due to excessive hunting. This event, led
people to different areas to meet the needs of fish. Fish farms and salmon production plants were established in the
seas and fresh waters. In such systems, where closed or circulatory water tanks are used, ammonium occurs as a result of separation of
excrement and feed remnant, which has a toxic effect for fish.
FILTER-CLINO is used in cleaning these waters much more effectively and safely compared to standard biological
systems thanks to its selectivity against Ammonium and Ammonium exchange capacity. FILTER CLINO in Industrial Waste Water Filtration: Heavy metal ions contained by waste water have been
restricted according o EU environmental laws. FILTER CLINO adsorbs easily many monovalent and divalent heavy
metals and also used as an adsorbent or cation exchanger in industrial applications.
Usage FILTER CLINO can bu used directly in filter media. For drinking water treatments; it is mixed with quartz sand in equal
proportions. It can be also mixed with active carbon, resin or other filter materials. It can be regenerated by NaCl
solution easily.
Packaging In 25 or 50 kg pp bags.
AQUARIUM PRODUCT
Filter Clino-Bio, can be used safely in aquariums as a large ornamental stone and filtrating material.
Product reduces the amount and adverse effects of ammonia, and the fish live in a healthy
environment where they can also use as feed.
Because its appearance is like a natural tuff, Filter Clino-Bio will match easily with other ornamental
stones and materials in the aquarium.
Filter Clino-Bio is provided in 10-25 kg packages.
CERTIFICATES OF MINE LİCENCES from MINISTRY OF ENERGY & NATURAL SOURCES
CERTIFICATES
CERTIFICATES ...
www.gordeszeolite.com
Headquarters Ankara Cad. No:81 Kat:18 D:123, 35580 Bayraklı/İzmir - TURKEY
Phone : +90-232-3485656, +90-232-3484311 Fax : +90-232-3484310
export@gordeszeolite.com
Production Plant Bodamaz Mevkii, Gördes/Manisa – Turkey
Phone & Fax : +90 236-547-30-17
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