international workshop towards a ... · 2. neutron activation analysis –naa neutrons for...

InternationalWorkshop

Towards aEuropean Research InfrastructureforHeritage

ScienceFlorence,2017March29th

SalaCapitolare,exConvento del Maglio,ViaCherubini5

FIXLAB:Accesstolarge-scale facilities

MichelMenu

MCC-C2RMF,PalaisduLouvre,Paris,France

CNRS,PSL,UMR8247,IRCP

michel.menu@culture.gouv.fr

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Purpose

Accesstolarge-scale facilities fortheCHcommunity:researchers inHeritage Sciencetosolve majorquestionsposed inarcheometry,conservationandpreservation.

Access provided tocomplementary nondestructiveinstrumentations

applied either onmicrosamples orwhole CHobjects

Elemental,structural,chemical analysis

NeutronandX-raycontrast radiography/tomography,chemical

analysis

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Whatistheorganic

contentofa

hermeticallyclosed

EgyptianPottery?

EmmanuelAbraham,MaryelleBessou,AnneZiegle,M.-C.Herve,L.Szentmiklosi,etal..Terahertz,X-rayandneutroncomputed tomography ofanEighteenth Dynasty Egyptiansealed pottery.Applied Physics A,SpringerVerlag,2014,117(3),pp.963-972.

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Neutronimaging +Promptgammaactivation=>thecontentcould consist ofgerminated seeds (orany other dried organicmaterial)such asbarley that was astaple cereal ofancient Egypt.

8Cork=ball oflinen

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MTA Atomki, Debrecen, Hungary

VandeGraaffaccelerator

ZitaSzikszai

szikszai@atomki.mta.hu

IBA

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Ionisationdesexcitation

X

Diffusion

onnucleusCoulombbarrier

P.I.X.E.

R.B.S.

Nuclearreaction

N.R.A.

p,d,

a

ERDA

IBAtechniques

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BNC-Wigner

HAS Centre for Energy Research

HAS Wigner Research Centre for Physics

The BNC-Wigner (Budapest) FIXLAB B(HU)

It takes advantages of the large-scale facilityBudapest Research Reactor operated by theCentre for Energy Research (EK). The national andinternational research programs are co-ordinatedby the Budapest Neutron Centre (BNC), aconsortium of EK and the Wigner Research Centrefor Physics (Wigner). Both EK and Wigner areresearch centres of the Hungarian Academy ofSciences.

The most attractive feature of BNC Wigner fornon-destructive study of CH objects is theavailability of a broad selection of neutron-basedexperimental techniques (PGAA, PGAI-NT, NAA,RAD, TOF-ND, SANS), in combination withcomplementary non-neutron methods (external-beam PIXE, XRF, etc.) on the same campus.

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1.PROMPTGAMMA

ACTIVATIONANALYSIS–

PGAA

2.NEUTRONACTIVATION

ANALYSIS– NAA

NEUTRONSFOR

ELEMENTALANALYSIS

NEUTRONSFORIMAGING

1. RADIOGRAPHY

2. NIPS-NORMA

Sample

chamber

Motorize

dsample

stage

NR/

NT

Neutron

beam

1.TIMEOFFLIGHT

NEUTRONDIFFRACTION– TOF-ND

2.SMALLANGLE

NEUTRONSCATTERING- SANS

NEUTRONSFOR

STRUCTURALSTUDIES

photograph,X-rayradiograph,neutronradiograph,PGAIdata

concentrationanddistributionofchloride ionsiniron artefactsWatkinson etal.Archaeometry 2013

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BNC-Wigner’s

IPERIONCHteam

BNC-WignerrepresentativeforGeneralAssembly:Dr.László ROSTArosta.laszlo@wigner.mta.hu

substitute:Dr.Zsolt KASZTOVSZKY kasztovszky.zsolt@energia.mta.hu

AccessBoardrepresentative:Dr.László SZENTMIKLÓSIszentmiklosi.laszlo@energia.mta.hu

substitute:Dr.Adél LENlen.adel@wigner.mta.hu

Partner-levelresponsibleforcommunication(PCR):Prof.Dr.Zoltán SZÕKEFALVI-NAGYszokefalvi-nagy.zoltan@wigner.mta.hu

substitute:Dr.László ROSTArosta.laszlo@wigner.mta.hu

Partner-levelqualityofficer(PQO)Dr.Zsolt KASZTOVSZKYkasztovszky.zsolt@energia.mta.hu

substitute:Boglárka MARÓTImaroti.boglarka@energia.mta.hu

FIXLABrepresentative(PRP):Dr.Imre KOVÁCSkovacs.imre@wigner.mta.hu

substitute:György KÁLIkali.gyorgy@wigner.mta.hu

Responsibleforadministrative/financialissues(IPERIONCoordinationOffice(ICO)liaison:Katalin PÁNCZÉL-BAJNOKbajnok.katalin@wigner.mta.hu

BNCUserWelcomeDesk:Dr.Zsolt KASZTOVSZKY

kasztovszky.zsolt@energia.mta.hu (technicalmatters)Katalin PÁNCZÉL-BAJNOK

bajnok.katalin@wigner.mta.hu (culturalheritagematters)

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11beamlines used forcultural

heritage related research

Micro-XRFandX-rayabsorption(speciation)

XRD,small-angleX-rayscattering

FT-IRspectroscopy,UV/visluminescenceimaging

X-raymicrotomography

Photo-emission spectroscopy…

Anatomix

SoleilIPERION-CHleader:FrédériqueFraissard

frederique.fraissard@synchrotron-soleil.frParis,Gif-sur-Yvette,Fr

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TomographybeamlinesatSOLEIL

PSICHE

ANATOMIXFast and phase contrast imaging

PUMA

Resolution Energy

Fast imaging Phase contrast imaging

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Microbeam beamlines atSOLEIL

Energy

Spot size

LUCIA

NANOSCOPIUM

DIFFABS

PUMA

HERMES

10µm

1µm

10nm

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PUMA

“PhotonsUvliséspourlesMatériauxAnciens”Optimizedforancientmaterials60%(?)beamtimereservedforancientmaterials

Hard X-rays (4 - 60 keV)Imaging 2D

Fluorescencecontrast,diffractionandabsorptionresolution 3µm

Imaging 3DAbsorptionandphasecontrast d’absorptionresolution ≈1µm

Opentousers:early 2018

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SOLEIL‘team’

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AGLAEleader:ClairePachecoclaire.pacheco@culture.gouv.fr

LouvrePalace,Paris,Fr

IBA

2MVtandemaccelerator basedanalytical system

100%dedicated toCH

AGLAE

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AGLAE

Recent Applications

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Byzantine glassweights,6-7thcentury AD

B.Tobias,Univ.ofInnsbruck,Austria

Questionsandaims:• detailedcomposition• identificationoftracesofothercolours• connectionwithchronology,technology…

CharacterizationoftheMedievalglassartefactsfromMiranduolo site,

Chiusdino,Italy

I.Posedi,Univ.ofEvora,Portugal

Questionsandaims:• detailedcomposition• characterisationofdeteriorations• connectionswithestablishedregionalproductioncentres…

Ion beam analysis of glass objects

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MedievalKashiproject

ProjectLeader:LadanAKBARNIAInstitution:BritishMuseum– IranianWorld

AGLAE

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AGLAE

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AGLAE

E-RIHSFrattheUCP

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Ø InE-RIHS-FR

+LMC14 (Saclay,Fr)

+Museum’sanalyticalplatform(Paris,Fr)whichconsistsin

severaltechnicaltools:

- bio-organicmassspectrometrytechnicalplatform

- NuclearMagneticResonanceTechnicalplatform

- FluorescenceMicroscopyandDigitalImagingcentre

- ElectronMicroscopytechnicalplatform

- IsotopicAnalysistechnicalplatform

- AST-RX:X-RayTomographytechnicalplatform

- UMS2700:theMuseum’s5technicalplatformsfor

integrativesystematics

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Thanksforyourattention

MichelMenu

MCC-C2RMF,PalaisduLouvre,Paris,France

CNRS,PSL,UMR8247,IRCP

michel.menu@culture.gouv.fr

FIXLABFirenze,29March2017

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NewAGLAEproject

AGLAE’s adventure during M1-M18

themoveofAGLAEfortheNewAGLAEnext phase