ir spectrum of a (nujol, cm
Post on 14-Feb-2022
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NH2·HOTfA
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83,3
cm-1
%T
IR spectrum of A (Nujol, cm-1)
1H NMR spectrum of A (DMSO-d6, 25 ºC)
13 C APT NMR spectrum of A (DMSO-d6, 25 ºC)
NH2·HOTfB
CO2MeH
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64,5
cm-1
%T
IR spectrum of B (Nujol, cm-1)
1H NMR spectrum of B (DMSO-d6, 25 ºC)
13 C APT NMR spectrum of C (DMSO-d6, 25 ºC)
NHMe·HOTf
C
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84,9
cm-1
%T
IR spectrum of C (Nujol, cm-1)
1H NMR spectrum of C (DMSO-d6, 25 ºC)
13 C APT NMR spectrum of C (DMSO-d6, 25 ºC)
NH2Pd
AcO 2
1a-OAc
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81,2
cm-1
%T
IR spectrum of 1a-OAc (Nujol, cm-1)
1H NMR spectrum of 1a-OAc (DMSO-d6, 25 ºC)
13 C APT NMR spectrum of 1a-OAc (DMSO-d6, 25 ºC)
NH2Pd
Cl 2
1a-Cl
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85
9092,5
cm-1
%T
IR spectrum of 1a-Cl (Nujol, cm-1)
1H NMR spectrum of 1a-Cl (DMSO-d6, 25 ºC)
13 C APT NMR spectrum of 1a-Cl (DMSO-d6, 25 ºC)
NH2Pd
Br 2
1a-Br
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95,9
cm-1
%T
IR spectrum of 1a-Br (Nujol, cm-1)
1H NMR spectrum of 1a-Br (DMSO-d6, 25 ºC)
NH2Pd
I 21a-I
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85
89,6
1/cm
%T
IR spectrum of 1a-I (Nujol, cm-1)
1H NMR spectrum of 1a-I (DMSO-d6, 25 ºC)
13 C APT NMR spectrum of 1a-I (DMSO-d6, 25 ºC)
NH2Pd
Cl 21b-Cl
CO2MeH
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70,7
cm-1
%T
IR spectrum of 1b-Cl (Nujol, cm-1)
1H NMR spectrum of 1b-Cl (DMSO-d6, 25 ºC)
13 C APT NMR spectrum of 1b-Cl (DMSO-d6, 25 ºC)
NH2Pd
I 21b-I
CO2MeH
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65
69,3
1/cm
%T
IR spectrum of 1b-I (Nujol, cm-1)
1H NMR spectrum of 1b-I (DMSO-d6, 25 ºC)
13 C APT NMR spectrum of 1b-I (DMSO-d6, 25 ºC)
NHMePd
Cl 2
1c-Cl
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8586,8
cm-1
%T
IR spectrum of 1c-Cl (Nujol, cm-1)
1H NMR spectrum of 1c-Cl (DMSO-d6, 25 ºC)
13 C APT NMR spectrum of 1c-Cl (DMSO-d6, 25 ºC)
NHMePd
Br 2
1c-Br
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9596,9
cm-1
%T
IR spectrum of 1c-Br (Nujol, cm-1)
1H NMR spectrum of 1c-Br (CDCl3 + TMS, 25 ºC)
NHMePd
I 21c-I
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84,3
1/cm
%T
IR spectrum of 1c-I (Nujol, cm-1)
1H NMR spectrum of 1c-I (DMSO-d6, 25 ºC)
13C NMR spectrum of 1c-I (DMSO-d6, 25 ºC)
PdN
I 2
CMe2
2
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98,7
cm-1
%T
IR spectrum of 2 (Nujol, cm-1)
1H NMR spectrum of 2 (DMSO-d6, 25 ºC)
13 C APT NMR spectrum of 2 (DMSO-d6, 25 ºC)
PdNH2
PhosS Cl
3a-Cl
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85
88,0
cm-1
%T
IR spectrum of 3a-Cl (Nujol, cm-1)
1H NMR spectrum of 3a-Cl (CD2Cl2, 25 ºC)
3a-Br
PdNH2
PhosS Br
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105107,0
cm-1
%T
IR spectrum of 3a-Br (Nujol, cm-1)
1H NMR spectrum of 3a-Br (CD2Cl2, 25 ºC)
NH2Pd
PhosS I3b-I
CO2MeH
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76,1
1/cm
%T
IR spectrum of 3b-I (Nujol, cm-1)
1H NMR spectrum of 3b-I (CDCl3 + TMS, 25 ºC)
PdN
Ph3P I
CMe2
4
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115117,5
cm-1
%T
IR spectrum of 4 (Nujol, cm-1)
1H NMR spectrum of 4 (CDCl3 + TMS, 25 ºC)
13 C APT NMR spectrum of 4 (CDCl3+ TMS, 25 ºC)
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