overview of polish carbon capture...

Overview of Polish carbon capture

research

Adam Tatarczuk, Institute for Chemical Processing of Coal

tatarczuk@ichpw.zabrze.pl

Carbon Capture

Forum

18th November 2014

Strategic Programme

2

Advanced Technologies of Energy Generation

Planned co-financing from

National Research and Development Center (Poland)

in 2010-2015 about PLN 300 000 000

Overall Target :

Development of the technologies which implementation will

have an impact on achievement of the EU 3x20 goals:

These targets, set three key objectives for 2020:

• A 20% improvement in the EU's energy efficiency;

• Raising the share of EU energy consumption produced

from renewable resources to 20%;

• A 20% reduction in EU greenhouse gas emissions from

1990 levels.

Gerard Lipiński „ Strategic Programme: Advanced Technologies of Energy Generation", Forum Energetyków

GRE 2014.

The main technology options for CO2

capture from power plant

3

Pre combustion

4

Project No. 3:

Development of coal gasification technology for highly efficient

production of fuels and electricity

Contractors:

AGH University of Science and Technology (Leader),

Główny Instytut Górnictwa (GIG), Institute for Chemical Processing of Coal

(IChPW), Silesian University of Technology, KGHM Polska Miedź S.A.,

Katowicki Holding Węglowy S.A., TAURON Polska

Energia S.A., TAURON Wytwarzanie S.A., TAURON

Wydobycie S.A., Grupa Azoty - ZAK S.A.

Co-financing PLN 80 000 000

Budget PLN 80 000 000 + non-financial and voluntary

contractors contribution

Gerard Lipiński „ Strategic Programme: Advanced Technologies of Energy Generation", Forum Energetyków

GRE 2014.

Project No. 3 – selected research

5 A. Strugała, P. Burmistrz, K. Kogut„ Zadanie badawcze nr 3: „Opracowanie technologii zgazowania węgla dla

wysokoefektywnej produkcji paliw i energii elektrycznej”, Forum Energetyków GRE 2014.

Pressurized CFB pilot gasifier

Institute for Chemical Processing of

Coal (IChPW)

Capacity: 100 kg coal per hour

Underground gasification pilot plant

Central Mining Institute

Capacity: 600 kg coal per hour

Oxy combustion

6

Project No. 2:

Development of a technology of oxy - fuel combustion for

pulverized fuel and fluidized-bed furnaces integrated with CO2 capture

system

Contractors:

Częstochowa University of Technology (Leader),

Silesian University of Technology,

Wrocław University of Technology,

Institute for Chemical Processing of Coal (IChPW), TAURON-Wytwarzanie

S.A., Institute of Power Engineering, PGE S.A. /

Turów Powerstation, Foster Wheeler Energia

Polska Sp. z o.o.

Co-financing PLN 80 000 000

Budget approx. PLN 87 400 000

Gerard Lipiński „ Strategic Programme: Advanced Technologies of Energy Generation", Forum Energetyków

GRE 2014.

Project No. 2 – Oxy combustion main

research

7 T. Czakiert, W. Nowak„ Spalanie tlenowe dla kotłów pyłowych i fluidalnych zintegrowanych z wychwytem CO2–

Projekt Strategiczny NCBR”, Forum Energetyków GRE 2014.

Pressurized CFB oxy combustion

pilot reactor (0,2 MW)

Institute for Chemical Processing of

Coal (IChPW)

Capacity: 25 kg coal per hour

PC pilot boiler for oxy combustion

research (0,5 MW)

Institute of Power Engineering

Project No. 2 – Oxy combustion selected

research

8 T. Czakiert, W. Nowak„ Spalanie tlenowe dla kotłów pyłowych i fluidalnych zintegrowanych z wychwytem CO2–

Projekt Strategiczny NCBR”, Forum Energetyków GRE 2014.

VPSA CO2 capture mobile pilot

plant

Częstochowa

University of Technology / Tauron

Flue gas capacity: 100 m3/h

Air separation mobile pilot plant

Wrocław University of Technology

Post combustion and efficiency improvement

9

Project No. 1:

Development of technology for highly efficient “zero-emission”

coal units integrated with CO2 capture from exhaust gases.

Contractors:

Silesian University of Technology (Leader),

Wrocław University of Technology, Institute for Chemical Processing of Coal

(IChPW),

Kraków University of Technology, Częstochowa University of Technology,

Łódź University of Technology, Warsaw University of

Technology, Institute of Flow Machinery of the Polish

Academy of Sciences, AGH University of Science and

Technology, RAFAKO S.A., TAURON-Wytwarzanie S.A.

Co-financing PLN 69 965 500

Budget approx. PLN 73 000 000

Gerard Lipiński „ Strategic Programme: Advanced Technologies of Energy Generation", Forum Energetyków

GRE 2014.

Project No. 1 – Post combustion research

10

Column diameter: 300 mm

Column height: 15,0 m

Number of devices: 40

Measurements: 180 points

Solvent: 30% MEA

solution

Solvent stream: up to1600 dm3/h

Gas stream: up to 200 m3n/h

Tested gas:

Flue gases from

coalfired boiler

Bussines partner - TAURON

11

Jaworzno Power Plant

Electric power installed: 1535

MWe

Maximal thermal power: 371,6

MWt

Łaziska Power Plant

Electric power installed: 1155

MWe

Maximal thermal power: 196 MWt

IChPW CO2 capture process scale-up

strategy

12

Lab stand for CO2 capture process – 5 m3/h

PDU for CO2 capture process – 100 m3/h (IChPW Zabrze)

The Mobile Pilot Plant – 200 m3/h

Experimental apparatus of CO2 absorption kinetics and equilibrums in amine blends

Pilot plant assembly at Jaworzno Power

Plant – 15.04.2014

13

Pilot plant commissioning at Jaworzno –

5.05.2014

14

15

Deep desulphurization

module

Amine scrubbing module

The Mobile Pilot Plant flow diagram

Split streams versus single stream amine

configuration-streams CO2 fraction

16

Inlet stream

Middle of theabsorber

Outlet stream

0

2

4

6

8

10

12

14

Lean strem to topand semi-lean to

middle of absorberLean stream directedto top and middle of

absorberLean stream to top of

absorber

13.48 13.48 13.44 10.45

7.01

6.18 1.84 1.99 2.69

CO

2 f

racti

on

[%

vo

l.]

Case A Case B

Case C

91.4

84.4

11.26 11.21

3.80 3.90

0

2

4

6

8

10

12

14

16

18

20

0

20

40

60

80

100

With regenerator internal heaters Without regenerator internal heaters Re

gen

era

tio

n e

nerg

y d

em

an

d [

MJ/k

gC

O2]

CO

2 in

let

str

eam

co

ncen

trati

on

[%

vo

l.]

CO

2 r

em

oval

rate

[%

vo

l.]

Effect of regenerator internal heating on

removal efficiency and regeneration energy

17

Reg. energy

demand

CO2 concentration

CO2 removal rate

Operational difficulties

18

• CO2 concentration fluctuations in inlet flue

gas stream

• Additional Venturi scrubber demister due to

flue gases moisture

• Rapid corrosion

in blower

ok. 1,85 [% vol.] CO2 inlet concentration

[% vol.]

Inlet flue gas stream [kg/h]

Outlet stream [kg/h]

CO2 outlet concentration [%

vol.]

Mobile Pilot Plant research summary at

TAURON facilities

19

• The pilot plant campaigns successfully demonstrated reliable operation allowing the removal of over 55

000 kg of CO2 from real flue gas.

• The energy requirement for MEA as solvent was found about 3,6 MJ/kgCO2 with 90% CO2 removal

efficiency due to the application of technological modifications.

• The completed test campaigns can become a baseline for extended comparisons with world data

• Operational experience was gained during test campaigns which can be helpful in designing amine

installations on a larger scale

Parameter Value

Number of campaigns 23

Number of tests 300

Operation time 1400 h

CO2 removed approx. 55 000 kg

Block diagram of demo CCS PLANT

20

ChłodzenieOdsiarczanie

Dmuchawa AbsorberWymiana ciepła

ChłodzenieRegeneratorRekupertor

Chłodzenie CO2 Sprężanie Osuszanie TSAASR ASR

AGR

AN

AGR

AN

Reclaimer

Wyparka

Oczyszczony AGR

AGR

AGR AGR

Spaliny

Gazoczyszczony do

komina

Woda do oczyszczalni

Roztwór odsiarczający

Zużyty roztwór odsiarczający

Kondensat Para

Para Kondensat

ChemikaliaZużyty roztwór amin

Woda chłodząca zasilanie

Woda chłodząca powrót

CO2

Do zatłaczania

1

Kondensat

4 7 8

6

910111216

3

Woda demin do uzupełnienia

Wodachłodząca zasilanie

Woda Chłodzącapowrót

1314

5

Kondensat

Odsiarczanie Usuwanie CO2 Sprężanie CO2

Odsiarczony gaz do komina

2

Woda do oczyszczalni

15

Amine

scrubbing

Desulfurizatio

n

CO2

compression

Integration with Power

Plant

Demo Plant Capacity = 175 tonnes of CO2/h

21

Clean Coal Technology Centre

in Zabrze (Upper Silesia, Poland)

Testing plant

for solid

fuels

gasification Testing plant for CO2

removal in absorption

process

Testing plant for pressure oxy-combustion of

solid fuels

in Circulating Fluidized Bed

Acknowledgments

22

• Presented results were obtained from research work co-financed by the National Centre of Research and

Development in the framework of Contract SP/E/1/67484/10 – Strategic Research Programme –

Advanced technologies for energy generation: Development of a technology for highly efficient zero-

emission coal-fired power units integrated with CO2 capture.

23

”A journey of a thousand miles

begins with a single step”

• Chinese philosopher Laozi (604 bc - 531 bc)

Thank you for

attention.