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Off-base Drinking Water Sample Results,Level 2 Laboratory Report, Level 4 Laboratory Report, Electronic Data Deliverable, Data Validation Report, and the Sample Location Figure, SDG 320-24179
Ault FieldNaval Air Station Whidbey IslandOak Harbor, Washington
February 2019
Approved for public release: distribution unlimited
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ANALYTICAL REPORTTestAmerica Laboratories, Inc.TestAmerica Sacramento880 Riverside ParkwayWest Sacramento, CA 95605Tel: (916)373-5600
TestAmerica Job ID: 320-24179-1Client Project/Site: Whidbey Island
For:CH2M Hill Constructors, Inc.1100 NE Circle BlvdCorvallis, Oregon 97330
Attn: Tiffany Hill
Authorized for release by:12/19/2016 8:57:55 AM
Laura Turpen, Project Manager I(916)374-4414laura.turpen@testamericainc.com
The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accreditedparameters, exceptions are noted in this report. This report may not be reproduced except in full,and with written approval from the laboratory. For questions please contact the Project Managerat the e-mail address or telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic signature isintended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents
Client: CH2M Hill Constructors, Inc.Project/Site: Whidbey Island
TestAmerica Job ID: 320-24179-1
Page 2 of 24TestAmerica Sacramento
12/19/2016
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2Definitions/Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13QC Association Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15Lab Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24
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Definitions/GlossaryTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
Qualifiers
LCMS
Qualifier Description
U Undetected at the Limit of Detection.
Qualifier
M Manual integrated compound.
Glossary
These commonly used abbreviations may or may not be present in this report.
¤ Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CNF Contains no Free Liquid
DER Duplicate error ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision level concentration
MDA Minimum detectable activity
EDL Estimated Detection Limit
MDC Minimum detectable concentration
MDL Method Detection Limit
ML Minimum Level (Dioxin)
NC Not Calculated
ND Not detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit
QC Quality Control
RER Relative error ratio
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TestAmerica Sacramento
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Case NarrativeClient: CH2M Hill Constructors, Inc. TestAmerica Job ID: 320-24179-1Project/Site: Whidbey Island
Job ID: 320-24179-1
Laboratory: TestAmerica Sacramento
Narrative
CASE NARRATIVE
Client: CH2M Hill Constructors, Inc.
Project: Whidbey Island
Report Number: 320-24179-1
With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of
the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.
TestAmerica Sacramento attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the
applicable methods. TestAmerica's operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.
TestAmerica utilizes USEPA approved methods and DOD QSM, where applicable, in all analytical work. The samples presented in this report were analyzed for the parameter(s) listed on the analytical methods summary page in accordance with the method(s) indicated. A
summary of QC data for these analyses is included at the back of the report.
All parameters for which TestAmerica Sacramento has certification were evaluated to the QSM specified reporting convention or to the client specified format if different from QSM. Parameters not certified under QSM, if any, were evaluated to the detection limit (DL) and include qualified results where applicable.
The sample(s) that contain constituents flagged with U are undetected. The result associated with this flag is the limit of detection (LOD). Calculations are performed before rounding to avoid round-off errors in calculated results.
All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.
All solid sample results are reported on an "as received" basis unless otherwise indicated by the presence of a % solids value in the method header.
This laboratory report is confidential and is intended for the sole use of TestAmerica and its client.
RECEIPTThe samples were received on 12/08/2016; the samples arrived in good condition, properly preserved and on ice. The temperature of the
coolers at receipt was 1.5 C.
An extended TAT was requested by the client via an email on December 8. Samples received on December 8 and 9 were requested to
have a due date of December 19, 2016.
PFOA/PFOS
Samples WI-AF-3RW23-1216 (320-24179-1), WI-AF-3FB23-1216 (320-24179-2), WI-AF-3RW24-1216 (320-24179-3), WI-AF-3RW24P-1216 (320-24179-4), WI-AF-3FB24-1216 (320-24179-5), WI-AF-3RW25-1216 (320-24179-6), WI-AF-3FB25-1216
(320-24179-7), WI-AF-3RW26-1216 (320-24179-8), WI-AF-3FB26-1216 (320-24179-9), WI-AF-3RW27-1216 (320-24179-10), WI-AF-3FB27-1216 (320-24179-11), WI-AF-3RW28-1216 (320-24179-12), WI-AF-3FB28-1216 (320-24179-13), WI-AF-3RW29-1216
TestAmerica SacramentoPage 4 of 24 12/19/2016
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Case NarrativeClient: CH2M Hill Constructors, Inc. TestAmerica Job ID: 320-24179-1Project/Site: Whidbey Island
Job ID: 320-24179-1 (Continued)
Laboratory: TestAmerica Sacramento (Continued)
(320-24179-14) and WI-AF-3FB29-1216 (320-24179-15) were analyzed for PFOA/PFOS in accordance with 537. The samples were
prepared on 12/09/2016 and analyzed on 12/16/2016.
No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
TestAmerica SacramentoPage 5 of 24 12/19/2016
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Detection SummaryTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
Client Sample ID: WI-AF-3RW23-1216 Lab Sample ID: 320-24179-1
No Detections.
Client Sample ID: WI-AF-3FB23-1216 Lab Sample ID: 320-24179-2
No Detections.
Client Sample ID: WI-AF-3RW24-1216 Lab Sample ID: 320-24179-3
No Detections.
Client Sample ID: WI-AF-3RW24P-1216 Lab Sample ID: 320-24179-4
No Detections.
Client Sample ID: WI-AF-3FB24-1216 Lab Sample ID: 320-24179-5
No Detections.
Client Sample ID: WI-AF-3RW25-1216 Lab Sample ID: 320-24179-6
No Detections.
Client Sample ID: WI-AF-3FB25-1216 Lab Sample ID: 320-24179-7
No Detections.
Client Sample ID: WI-AF-3RW26-1216 Lab Sample ID: 320-24179-8
No Detections.
Client Sample ID: WI-AF-3FB26-1216 Lab Sample ID: 320-24179-9
No Detections.
Client Sample ID: WI-AF-3RW27-1216 Lab Sample ID: 320-24179-10
No Detections.
Client Sample ID: WI-AF-3FB27-1216 Lab Sample ID: 320-24179-11
No Detections.
Client Sample ID: WI-AF-3RW28-1216 Lab Sample ID: 320-24179-12
No Detections.
Client Sample ID: WI-AF-3FB28-1216 Lab Sample ID: 320-24179-13
No Detections.
Client Sample ID: WI-AF-3RW29-1216 Lab Sample ID: 320-24179-14
No Detections.
TestAmerica Sacramento
This Detection Summary does not include radiochemical test results.
Page 6 of 24 12/19/2016
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Detection SummaryTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
Client Sample ID: WI-AF-3FB29-1216 Lab Sample ID: 320-24179-15
No Detections.
TestAmerica Sacramento
This Detection Summary does not include radiochemical test results.
Page 7 of 24 12/19/2016
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Client Sample ResultsTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
Lab Sample ID: 320-24179-1Client Sample ID: WI-AF-3RW23-1216Matrix: WaterDate Collected: 12/05/16 10:45
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.043 U 0.054 0.014 ug/L 12/09/16 18:50 12/16/16 00:47 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.027 0.0085 ug/L 12/09/16 18:50 12/16/16 00:47 1Perfluorooctanoic acid (PFOA) 0.022 U M
0.13 0.043 ug/L 12/09/16 18:50 12/16/16 00:47 1Perfluorobutanesulfonic acid (PFBS) 0.099 U
13C2 PFHxA 95 70 - 130 12/09/16 18:50 12/16/16 00:47 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 94 12/09/16 18:50 12/16/16 00:47 170 - 130
Lab Sample ID: 320-24179-2Client Sample ID: WI-AF-3FB23-1216Matrix: WaterDate Collected: 12/05/16 10:46
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.046 U 0.057 0.015 ug/L 12/09/16 18:50 12/16/16 02:16 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.029 0.0090 ug/L 12/09/16 18:50 12/16/16 02:16 1Perfluorooctanoic acid (PFOA) 0.023 U
0.13 0.045 ug/L 12/09/16 18:50 12/16/16 02:16 1Perfluorobutanesulfonic acid (PFBS) 0.10 U
13C2 PFHxA 91 70 - 130 12/09/16 18:50 12/16/16 02:16 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 93 12/09/16 18:50 12/16/16 02:16 170 - 130
Lab Sample ID: 320-24179-3Client Sample ID: WI-AF-3RW24-1216Matrix: WaterDate Collected: 12/06/16 09:05
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.043 U 0.053 0.014 ug/L 12/09/16 18:50 12/16/16 02:45 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.027 0.0084 ug/L 12/09/16 18:50 12/16/16 02:45 1Perfluorooctanoic acid (PFOA) 0.021 U M
0.12 0.042 ug/L 12/09/16 18:50 12/16/16 02:45 1Perfluorobutanesulfonic acid (PFBS) 0.098 U
13C2 PFHxA 100 70 - 130 12/09/16 18:50 12/16/16 02:45 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 97 12/09/16 18:50 12/16/16 02:45 170 - 130
Lab Sample ID: 320-24179-4Client Sample ID: WI-AF-3RW24P-1216Matrix: WaterDate Collected: 12/06/16 09:10
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.042 U 0.052 0.014 ug/L 12/09/16 18:50 12/16/16 03:15 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.026 0.0082 ug/L 12/09/16 18:50 12/16/16 03:15 1Perfluorooctanoic acid (PFOA) 0.021 U
0.12 0.041 ug/L 12/09/16 18:50 12/16/16 03:15 1Perfluorobutanesulfonic acid (PFBS) 0.096 U
13C2 PFHxA 86 70 - 130 12/09/16 18:50 12/16/16 03:15 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 82 12/09/16 18:50 12/16/16 03:15 170 - 130
TestAmerica Sacramento
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Client Sample ResultsTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
Lab Sample ID: 320-24179-5Client Sample ID: WI-AF-3FB24-1216Matrix: WaterDate Collected: 12/06/16 09:06
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.044 U 0.055 0.014 ug/L 12/09/16 18:50 12/16/16 03:45 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.028 0.0086 ug/L 12/09/16 18:50 12/16/16 03:45 1Perfluorooctanoic acid (PFOA) 0.022 U
0.13 0.044 ug/L 12/09/16 18:50 12/16/16 03:45 1Perfluorobutanesulfonic acid (PFBS) 0.10 U
13C2 PFHxA 91 70 - 130 12/09/16 18:50 12/16/16 03:45 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 94 12/09/16 18:50 12/16/16 03:45 170 - 130
Lab Sample ID: 320-24179-6Client Sample ID: WI-AF-3RW25-1216Matrix: WaterDate Collected: 12/06/16 09:15
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.045 U 0.057 0.015 ug/L 12/09/16 18:50 12/16/16 05:13 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.028 0.0089 ug/L 12/09/16 18:50 12/16/16 05:13 1Perfluorooctanoic acid (PFOA) 0.023 U
0.13 0.045 ug/L 12/09/16 18:50 12/16/16 05:13 1Perfluorobutanesulfonic acid (PFBS) 0.10 U
13C2 PFHxA 81 70 - 130 12/09/16 18:50 12/16/16 05:13 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 77 12/09/16 18:50 12/16/16 05:13 170 - 130
Lab Sample ID: 320-24179-7Client Sample ID: WI-AF-3FB25-1216Matrix: WaterDate Collected: 12/06/16 09:16
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.042 U 0.053 0.014 ug/L 12/09/16 18:50 12/16/16 05:43 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.027 0.0083 ug/L 12/09/16 18:50 12/16/16 05:43 1Perfluorooctanoic acid (PFOA) 0.021 U
0.12 0.042 ug/L 12/09/16 18:50 12/16/16 05:43 1Perfluorobutanesulfonic acid (PFBS) 0.097 U
13C2 PFHxA 87 70 - 130 12/09/16 18:50 12/16/16 05:43 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 89 12/09/16 18:50 12/16/16 05:43 170 - 130
Lab Sample ID: 320-24179-8Client Sample ID: WI-AF-3RW26-1216Matrix: WaterDate Collected: 12/06/16 10:30
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.045 U 0.057 0.015 ug/L 12/09/16 18:50 12/16/16 06:13 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.028 0.0089 ug/L 12/09/16 18:50 12/16/16 06:13 1Perfluorooctanoic acid (PFOA) 0.023 U
0.13 0.045 ug/L 12/09/16 18:50 12/16/16 06:13 1Perfluorobutanesulfonic acid (PFBS) 0.10 U
13C2 PFHxA 95 70 - 130 12/09/16 18:50 12/16/16 06:13 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 94 12/09/16 18:50 12/16/16 06:13 170 - 130
TestAmerica Sacramento
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Client Sample ResultsTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
Lab Sample ID: 320-24179-9Client Sample ID: WI-AF-3FB26-1216Matrix: WaterDate Collected: 12/06/16 10:31
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.042 U 0.052 0.013 ug/L 12/09/16 18:50 12/16/16 06:42 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.026 0.0082 ug/L 12/09/16 18:50 12/16/16 06:42 1Perfluorooctanoic acid (PFOA) 0.021 U
0.12 0.041 ug/L 12/09/16 18:50 12/16/16 06:42 1Perfluorobutanesulfonic acid (PFBS) 0.095 U
13C2 PFHxA 83 70 - 130 12/09/16 18:50 12/16/16 06:42 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 81 12/09/16 18:50 12/16/16 06:42 170 - 130
Lab Sample ID: 320-24179-10Client Sample ID: WI-AF-3RW27-1216Matrix: WaterDate Collected: 12/06/16 10:40
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.046 U 0.058 0.015 ug/L 12/09/16 18:50 12/16/16 07:12 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.029 0.0091 ug/L 12/09/16 18:50 12/16/16 07:12 1Perfluorooctanoic acid (PFOA) 0.023 U
0.14 0.046 ug/L 12/09/16 18:50 12/16/16 07:12 1Perfluorobutanesulfonic acid (PFBS) 0.11 U
13C2 PFHxA 97 70 - 130 12/09/16 18:50 12/16/16 07:12 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 92 12/09/16 18:50 12/16/16 07:12 170 - 130
Lab Sample ID: 320-24179-11Client Sample ID: WI-AF-3FB27-1216Matrix: WaterDate Collected: 12/06/16 10:41
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.045 U 0.057 0.015 ug/L 12/09/16 18:50 12/16/16 07:41 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.028 0.0089 ug/L 12/09/16 18:50 12/16/16 07:41 1Perfluorooctanoic acid (PFOA) 0.023 U
0.13 0.045 ug/L 12/09/16 18:50 12/16/16 07:41 1Perfluorobutanesulfonic acid (PFBS) 0.10 U
13C2 PFHxA 91 70 - 130 12/09/16 18:50 12/16/16 07:41 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 88 12/09/16 18:50 12/16/16 07:41 170 - 130
Lab Sample ID: 320-24179-12Client Sample ID: WI-AF-3RW28-1216Matrix: WaterDate Collected: 12/06/16 15:35
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.045 U 0.056 0.014 ug/L 12/09/16 18:50 12/16/16 08:11 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.028 0.0088 ug/L 12/09/16 18:50 12/16/16 08:11 1Perfluorooctanoic acid (PFOA) 0.022 U
0.13 0.044 ug/L 12/09/16 18:50 12/16/16 08:11 1Perfluorobutanesulfonic acid (PFBS) 0.10 U
13C2 PFHxA 81 70 - 130 12/09/16 18:50 12/16/16 08:11 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 78 12/09/16 18:50 12/16/16 08:11 170 - 130
TestAmerica Sacramento
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Client Sample ResultsTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
Lab Sample ID: 320-24179-13Client Sample ID: WI-AF-3FB28-1216Matrix: WaterDate Collected: 12/06/16 15:36
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.043 U 0.053 0.014 ug/L 12/09/16 18:50 12/16/16 08:41 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.027 0.0084 ug/L 12/09/16 18:50 12/16/16 08:41 1Perfluorooctanoic acid (PFOA) 0.021 U
0.12 0.042 ug/L 12/09/16 18:50 12/16/16 08:41 1Perfluorobutanesulfonic acid (PFBS) 0.098 U
13C2 PFHxA 96 70 - 130 12/09/16 18:50 12/16/16 08:41 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 97 12/09/16 18:50 12/16/16 08:41 170 - 130
Lab Sample ID: 320-24179-14Client Sample ID: WI-AF-3RW29-1216Matrix: WaterDate Collected: 12/06/16 17:05
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.046 U 0.058 0.015 ug/L 12/09/16 18:50 12/16/16 09:10 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.029 0.0091 ug/L 12/09/16 18:50 12/16/16 09:10 1Perfluorooctanoic acid (PFOA) 0.023 U
0.14 0.046 ug/L 12/09/16 18:50 12/16/16 09:10 1Perfluorobutanesulfonic acid (PFBS) 0.11 U
13C2 PFHxA 89 70 - 130 12/09/16 18:50 12/16/16 09:10 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 92 12/09/16 18:50 12/16/16 09:10 170 - 130
Lab Sample ID: 320-24179-15Client Sample ID: WI-AF-3FB29-1216Matrix: WaterDate Collected: 12/06/16 17:06
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.047 U 0.058 0.015 ug/L 12/09/16 18:50 12/16/16 09:40 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.029 0.0092 ug/L 12/09/16 18:50 12/16/16 09:40 1Perfluorooctanoic acid (PFOA) 0.023 U
0.14 0.046 ug/L 12/09/16 18:50 12/16/16 09:40 1Perfluorobutanesulfonic acid (PFBS) 0.11 U
13C2 PFHxA 92 70 - 130 12/09/16 18:50 12/16/16 09:40 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 90 12/09/16 18:50 12/16/16 09:40 170 - 130
TestAmerica Sacramento
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Surrogate SummaryTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)Prep Type: Total/NAMatrix: Water
Lab Sample ID Client Sample ID (70-130) (70-130)
13C2 PFHxA13C2 PFDA
95 94320-24179-1
Percent Surrogate Recovery (Acceptance Limits)
WI-AF-3RW23-1216
91 93320-24179-1 MS WI-AF-3RW23-1216
101 96320-24179-1 MSD WI-AF-3RW23-1216
91 93320-24179-2 WI-AF-3FB23-1216
100 97320-24179-3 WI-AF-3RW24-1216
86 82320-24179-4 WI-AF-3RW24P-1216
91 94320-24179-5 WI-AF-3FB24-1216
81 77320-24179-6 WI-AF-3RW25-1216
87 89320-24179-7 WI-AF-3FB25-1216
95 94320-24179-8 WI-AF-3RW26-1216
83 81320-24179-9 WI-AF-3FB26-1216
97 92320-24179-10 WI-AF-3RW27-1216
91 88320-24179-11 WI-AF-3FB27-1216
81 78320-24179-12 WI-AF-3RW28-1216
96 97320-24179-13 WI-AF-3FB28-1216
89 92320-24179-14 WI-AF-3RW29-1216
92 90320-24179-15 WI-AF-3FB29-1216
98 97LCS 320-141539/2-A Lab Control Sample
105 105MB 320-141539/1-A Method Blank
Surrogate Legend
13C2 PFHxA = 13C2 PFHxA
13C2 PFDA = 13C2 PFDA
TestAmerica Sacramento
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QC Sample ResultsTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)
Client Sample ID: Method BlankLab Sample ID: MB 320-141539/1-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 142414 Prep Batch: 141539
LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.048 U 0.060 0.016 ug/L 12/09/16 18:50 12/15/16 23:48 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
0.024 U 0.00940.030 ug/L 12/09/16 18:50 12/15/16 23:48 1Perfluorooctanoic acid (PFOA)
0.11 U 0.0480.14 ug/L 12/09/16 18:50 12/15/16 23:48 1Perfluorobutanesulfonic acid (PFBS)
13C2 PFHxA 105 70 - 130 12/15/16 23:48 1
MB MB
Surrogate
12/09/16 18:50
Dil FacPrepared AnalyzedQualifier Limits%Recovery
105 12/09/16 18:50 12/15/16 23:48 113C2 PFDA 70 - 130
Client Sample ID: Lab Control SampleLab Sample ID: LCS 320-141539/2-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 142414 Prep Batch: 141539
Perfluorooctanesulfonic acid
(PFOS)
0.300 0.245 ug/L 82 70 - 130
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Perfluorooctanoic acid (PFOA) 0.152 0.129 ug/L 85 70 - 130
Perfluorobutanesulfonic acid
(PFBS)
0.673 0.511 ug/L 76 70 - 130
13C2 PFHxA 70 - 130
Surrogate
98
LCS LCS
Qualifier Limits%Recovery
9713C2 PFDA 70 - 130
Client Sample ID: WI-AF-3RW23-1216Lab Sample ID: 320-24179-1 MSMatrix: Water Prep Type: Total/NAAnalysis Batch: 142438 Prep Batch: 141539
Perfluorooctanesulfonic acid
(PFOS)
0.043 U 0.150 0.106 ug/L 70 70 - 130
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Perfluorooctanoic acid (PFOA) 0.022 U M 0.0759 0.0539 ug/L 71 70 - 130
Perfluorobutanesulfonic acid
(PFBS)
0.099 U 0.336 0.248 ug/L 74 70 - 130
13C2 PFHxA 70 - 130
Surrogate
91
MS MS
Qualifier Limits%Recovery
9313C2 PFDA 70 - 130
Client Sample ID: WI-AF-3RW23-1216Lab Sample ID: 320-24179-1 MSDMatrix: Water Prep Type: Total/NAAnalysis Batch: 142414 Prep Batch: 141539
Perfluorooctanesulfonic acid
(PFOS)
0.043 U 0.159 0.120 ug/L 75 70 - 130 14 30
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Perfluorooctanoic acid (PFOA) 0.022 U M 0.0804 0.0621 ug/L 77 70 - 130 17 30
Perfluorobutanesulfonic acid
(PFBS)
0.099 U 0.356 0.303 ug/L 85 70 - 130 18 30
TestAmerica Sacramento
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QC Sample ResultsTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
Method: 537 - Perfluorinated Alkyl Acids (LC/MS) (Continued)
Client Sample ID: WI-AF-3RW23-1216Lab Sample ID: 320-24179-1 MSDMatrix: Water Prep Type: Total/NAAnalysis Batch: 142414 Prep Batch: 141539
13C2 PFHxA 70 - 130
Surrogate
101
MSD MSD
Qualifier Limits%Recovery
9613C2 PFDA 70 - 130
TestAmerica Sacramento
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QC Association SummaryTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
LCMS
Prep Batch: 141539
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 537320-24179-1 WI-AF-3RW23-1216 Total/NA
Water 537320-24179-2 WI-AF-3FB23-1216 Total/NA
Water 537320-24179-3 WI-AF-3RW24-1216 Total/NA
Water 537320-24179-4 WI-AF-3RW24P-1216 Total/NA
Water 537320-24179-5 WI-AF-3FB24-1216 Total/NA
Water 537320-24179-6 WI-AF-3RW25-1216 Total/NA
Water 537320-24179-7 WI-AF-3FB25-1216 Total/NA
Water 537320-24179-8 WI-AF-3RW26-1216 Total/NA
Water 537320-24179-9 WI-AF-3FB26-1216 Total/NA
Water 537320-24179-10 WI-AF-3RW27-1216 Total/NA
Water 537320-24179-11 WI-AF-3FB27-1216 Total/NA
Water 537320-24179-12 WI-AF-3RW28-1216 Total/NA
Water 537320-24179-13 WI-AF-3FB28-1216 Total/NA
Water 537320-24179-14 WI-AF-3RW29-1216 Total/NA
Water 537320-24179-15 WI-AF-3FB29-1216 Total/NA
Water 537MB 320-141539/1-A Method Blank Total/NA
Water 537LCS 320-141539/2-A Lab Control Sample Total/NA
Water 537320-24179-1 MS WI-AF-3RW23-1216 Total/NA
Water 537320-24179-1 MSD WI-AF-3RW23-1216 Total/NA
Analysis Batch: 142414
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 537 141539320-24179-1 WI-AF-3RW23-1216 Total/NA
Water 537 141539320-24179-2 WI-AF-3FB23-1216 Total/NA
Water 537 141539320-24179-3 WI-AF-3RW24-1216 Total/NA
Water 537 141539320-24179-4 WI-AF-3RW24P-1216 Total/NA
Water 537 141539320-24179-5 WI-AF-3FB24-1216 Total/NA
Water 537 141539MB 320-141539/1-A Method Blank Total/NA
Water 537 141539LCS 320-141539/2-A Lab Control Sample Total/NA
Water 537 141539320-24179-1 MSD WI-AF-3RW23-1216 Total/NA
Analysis Batch: 142415
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 537 141539320-24179-6 WI-AF-3RW25-1216 Total/NA
Water 537 141539320-24179-7 WI-AF-3FB25-1216 Total/NA
Water 537 141539320-24179-8 WI-AF-3RW26-1216 Total/NA
Water 537 141539320-24179-9 WI-AF-3FB26-1216 Total/NA
Water 537 141539320-24179-10 WI-AF-3RW27-1216 Total/NA
Water 537 141539320-24179-11 WI-AF-3FB27-1216 Total/NA
Water 537 141539320-24179-12 WI-AF-3RW28-1216 Total/NA
Water 537 141539320-24179-13 WI-AF-3FB28-1216 Total/NA
Water 537 141539320-24179-14 WI-AF-3RW29-1216 Total/NA
Water 537 141539320-24179-15 WI-AF-3FB29-1216 Total/NA
Analysis Batch: 142438
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 537 141539320-24179-1 MS WI-AF-3RW23-1216 Total/NA
TestAmerica Sacramento
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Lab ChronicleClient: CH2M Hill Constructors, Inc. TestAmerica Job ID: 320-24179-1Project/Site: Whidbey Island
Client Sample ID: WI-AF-3RW23-1216 Lab Sample ID: 320-24179-1Matrix: WaterDate Collected: 12/05/16 10:45
Date Received: 12/08/16 10:00
Prep 537 JER12/09/16 18:50 TAL SAC141539
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 277 mL 1.00 mL
Analysis 537 1 142414 12/16/16 00:47 CBW TAL SACTotal/NA
Client Sample ID: WI-AF-3FB23-1216 Lab Sample ID: 320-24179-2Matrix: WaterDate Collected: 12/05/16 10:46
Date Received: 12/08/16 10:00
Prep 537 JER12/09/16 18:50 TAL SAC141539
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 262.3 mL 1.00 mL
Analysis 537 1 142414 12/16/16 02:16 CBW TAL SACTotal/NA
Client Sample ID: WI-AF-3RW24-1216 Lab Sample ID: 320-24179-3Matrix: WaterDate Collected: 12/06/16 09:05
Date Received: 12/08/16 10:00
Prep 537 JER12/09/16 18:50 TAL SAC141539
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 281.4 mL 1.00 mL
Analysis 537 1 142414 12/16/16 02:45 CBW TAL SACTotal/NA
Client Sample ID: WI-AF-3RW24P-1216 Lab Sample ID: 320-24179-4Matrix: WaterDate Collected: 12/06/16 09:10
Date Received: 12/08/16 10:00
Prep 537 JER12/09/16 18:50 TAL SAC141539
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 286.9 mL 1.00 mL
Analysis 537 1 142414 12/16/16 03:15 CBW TAL SACTotal/NA
Client Sample ID: WI-AF-3FB24-1216 Lab Sample ID: 320-24179-5Matrix: WaterDate Collected: 12/06/16 09:06
Date Received: 12/08/16 10:00
Prep 537 JER12/09/16 18:50 TAL SAC141539
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 272.5 mL 1.00 mL
Analysis 537 1 142414 12/16/16 03:45 CBW TAL SACTotal/NA
Client Sample ID: WI-AF-3RW25-1216 Lab Sample ID: 320-24179-6Matrix: WaterDate Collected: 12/06/16 09:15
Date Received: 12/08/16 10:00
Prep 537 JER12/09/16 18:50 TAL SAC141539
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 265 mL 1.00 mL
Analysis 537 1 142415 12/16/16 05:13 CBW TAL SACTotal/NA
TestAmerica Sacramento
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Lab ChronicleClient: CH2M Hill Constructors, Inc. TestAmerica Job ID: 320-24179-1Project/Site: Whidbey Island
Client Sample ID: WI-AF-3FB25-1216 Lab Sample ID: 320-24179-7Matrix: WaterDate Collected: 12/06/16 09:16
Date Received: 12/08/16 10:00
Prep 537 JER12/09/16 18:50 TAL SAC141539
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 282.6 mL 1.00 mL
Analysis 537 1 142415 12/16/16 05:43 CBW TAL SACTotal/NA
Client Sample ID: WI-AF-3RW26-1216 Lab Sample ID: 320-24179-8Matrix: WaterDate Collected: 12/06/16 10:30
Date Received: 12/08/16 10:00
Prep 537 JER12/09/16 18:50 TAL SAC141539
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 264.6 mL 1.00 mL
Analysis 537 1 142415 12/16/16 06:13 CBW TAL SACTotal/NA
Client Sample ID: WI-AF-3FB26-1216 Lab Sample ID: 320-24179-9Matrix: WaterDate Collected: 12/06/16 10:31
Date Received: 12/08/16 10:00
Prep 537 JER12/09/16 18:50 TAL SAC141539
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 288.2 mL 1.00 mL
Analysis 537 1 142415 12/16/16 06:42 CBW TAL SACTotal/NA
Client Sample ID: WI-AF-3RW27-1216 Lab Sample ID: 320-24179-10Matrix: WaterDate Collected: 12/06/16 10:40
Date Received: 12/08/16 10:00
Prep 537 JER12/09/16 18:50 TAL SAC141539
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 259.1 mL 1.00 mL
Analysis 537 1 142415 12/16/16 07:12 CBW TAL SACTotal/NA
Client Sample ID: WI-AF-3FB27-1216 Lab Sample ID: 320-24179-11Matrix: WaterDate Collected: 12/06/16 10:41
Date Received: 12/08/16 10:00
Prep 537 JER12/09/16 18:50 TAL SAC141539
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 264.8 mL 1.00 mL
Analysis 537 1 142415 12/16/16 07:41 CBW TAL SACTotal/NA
Client Sample ID: WI-AF-3RW28-1216 Lab Sample ID: 320-24179-12Matrix: WaterDate Collected: 12/06/16 15:35
Date Received: 12/08/16 10:00
Prep 537 JER12/09/16 18:50 TAL SAC141539
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 269 mL 1.00 mL
Analysis 537 1 142415 12/16/16 08:11 CBW TAL SACTotal/NA
TestAmerica Sacramento
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Lab ChronicleClient: CH2M Hill Constructors, Inc. TestAmerica Job ID: 320-24179-1Project/Site: Whidbey Island
Client Sample ID: WI-AF-3FB28-1216 Lab Sample ID: 320-24179-13Matrix: WaterDate Collected: 12/06/16 15:36
Date Received: 12/08/16 10:00
Prep 537 JER12/09/16 18:50 TAL SAC141539
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 281.4 mL 1.00 mL
Analysis 537 1 142415 12/16/16 08:41 CBW TAL SACTotal/NA
Client Sample ID: WI-AF-3RW29-1216 Lab Sample ID: 320-24179-14Matrix: WaterDate Collected: 12/06/16 17:05
Date Received: 12/08/16 10:00
Prep 537 JER12/09/16 18:50 TAL SAC141539
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 258.4 mL 1.00 mL
Analysis 537 1 142415 12/16/16 09:10 CBW TAL SACTotal/NA
Client Sample ID: WI-AF-3FB29-1216 Lab Sample ID: 320-24179-15Matrix: WaterDate Collected: 12/06/16 17:06
Date Received: 12/08/16 10:00
Prep 537 JER12/09/16 18:50 TAL SAC141539
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 256.5 mL 1.00 mL
Analysis 537 1 142415 12/16/16 09:40 CBW TAL SACTotal/NA
Laboratory References:
TAL SAC = TestAmerica Sacramento, 880 Riverside Parkway, West Sacramento, CA 95605, TEL (916)373-5600
TestAmerica Sacramento
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Certification SummaryClient: CH2M Hill Constructors, Inc. TestAmerica Job ID: 320-24179-1Project/Site: Whidbey Island
Laboratory: TestAmerica SacramentoUnless otherwise noted, all analytes for this laboratory were covered under each certification below.
Authority Program EPA Region Certification ID Expiration Date
A2LA 2928-01DoD ELAP 01-31-17
Analysis Method Prep Method Matrix Analyte
TestAmerica Sacramento
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Method SummaryTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
Method Method Description LaboratoryProtocol
EPA537 Perfluorinated Alkyl Acids (LC/MS) TAL SAC
Protocol References:
EPA = US Environmental Protection Agency
Laboratory References:
TAL SAC = TestAmerica Sacramento, 880 Riverside Parkway, West Sacramento, CA 95605, TEL (916)373-5600
TestAmerica Sacramento
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Sample SummaryTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
Lab Sample ID Client Sample ID ReceivedCollectedMatrix
320-24179-1 WI-AF-3RW23-1216 Water 12/05/16 10:45 12/08/16 10:00
320-24179-2 WI-AF-3FB23-1216 Water 12/05/16 10:46 12/08/16 10:00
320-24179-3 WI-AF-3RW24-1216 Water 12/06/16 09:05 12/08/16 10:00
320-24179-4 WI-AF-3RW24P-1216 Water 12/06/16 09:10 12/08/16 10:00
320-24179-5 WI-AF-3FB24-1216 Water 12/06/16 09:06 12/08/16 10:00
320-24179-6 WI-AF-3RW25-1216 Water 12/06/16 09:15 12/08/16 10:00
320-24179-7 WI-AF-3FB25-1216 Water 12/06/16 09:16 12/08/16 10:00
320-24179-8 WI-AF-3RW26-1216 Water 12/06/16 10:30 12/08/16 10:00
320-24179-9 WI-AF-3FB26-1216 Water 12/06/16 10:31 12/08/16 10:00
320-24179-10 WI-AF-3RW27-1216 Water 12/06/16 10:40 12/08/16 10:00
320-24179-11 WI-AF-3FB27-1216 Water 12/06/16 10:41 12/08/16 10:00
320-24179-12 WI-AF-3RW28-1216 Water 12/06/16 15:35 12/08/16 10:00
320-24179-13 WI-AF-3FB28-1216 Water 12/06/16 15:36 12/08/16 10:00
320-24179-14 WI-AF-3RW29-1216 Water 12/06/16 17:05 12/08/16 10:00
320-24179-15 WI-AF-3FB29-1216 Water 12/06/16 17:06 12/08/16 10:00
TestAmerica Sacramento
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Login Sample Receipt Checklist
Client: CH2M Hill Constructors, Inc. Job Number: 320-24179-1
Login Number: 24179
Question Answer Comment
Creator: Edman, Connor M
List Source: TestAmerica Sacramento
List Number: 1
TrueRadioactivity wasn't checked or is
-
ANALYTICAL REPORT
Job Number: 320-24179-1
Job Description: Whidbey Island
For:CH2M Hill Constructors, Inc.
1100 NE Circle BlvdCorvallis, OR 97330
Attention: Tiffany Hill
_____________________________________________
Approved for release.Laura TurpenProject Manager I12/19/2016 8:58 AM
Laura Turpen, Project Manager I880 Riverside Parkway, West Sacramento, CA, 95605
(916)374-4414 laura.turpen@testamericainc.com
12/19/2016
TestAmerica Laboratories, Inc.
TestAmerica Sacramento 880 Riverside Parkway, West Sacramento, CA 95605
Tel (916) 373-5600 Fax (916) 372-1059 www.testamericainc.com
12/19/2016Page 1 of 263
mailto:laura.turpen@testamericainc.comhttp://www.testamericainc.comhttp://
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Table of ContentsCover Title Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Data Summaries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
Default Detection Limits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
Manual Integration Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
Reagent Traceability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26
COAs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35
Organic Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85
LCMS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85
Method 537 DOD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85Method 537 DOD QC Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86Method 537 DOD Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98Standards Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160
Method 537 DOD ICAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160Method 537 DOD CCAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 183
Raw QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 216
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Table of ContentsMethod 537 DOD Blank Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 216Method 537 DOD LCS/LCSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 220Method 537 DOD MS/MSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 224
Method 537 DOD Run Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 232Method 537 DOD Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 237
Shipping and Receiving Documents . . . . . . . . . . . . . . . . . . . . . . . . . . . 260
Client Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 261
Sample Receipt Checklist . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 263
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Definitions/GlossaryTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
Qualifiers
LCMS
Qualifier Description
U Undetected at the Limit of Detection.
Qualifier
M Manual integrated compound.
Glossary
These commonly used abbreviations may or may not be present in this report.
¤ Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CNF Contains no Free Liquid
DER Duplicate error ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision level concentration
MDA Minimum detectable activity
EDL Estimated Detection Limit
MDC Minimum detectable concentration
MDL Method Detection Limit
ML Minimum Level (Dioxin)
NC Not Calculated
ND Not detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit
QC Quality Control
RER Relative error ratio
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TestAmerica Sacramento
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CASE NARRATIVE
Client: CH2M Hill Constructors, Inc.
Project: Whidbey Island
Report Number: 320-24179-1
With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.
TestAmerica Sacramento attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the applicable methods. TestAmerica's operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.
TestAmerica utilizes USEPA approved methods and DOD QSM, where applicable, in all analytical work. The samples presented in this report were analyzed for the parameter(s) listed on the analytical methods summary page in accordance with the method(s) indicated. A summary of QC data for these analyses is included at the back of the report.
All parameters for which TestAmerica Sacramento has certification were evaluated to the QSM specified reporting convention or to the client specified format if different from QSM. Parameters not certified under QSM, if any, were evaluated to the detection limit (DL) and include qualified results where applicable.
The sample(s) that contain constituents flagged with U are undetected. The result associated with this flag is the limit of detection (LOD). Calculations are performed before rounding to avoid round-off errors in calculated results.
All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.
All solid sample results are reported on an "as received" basis unless otherwise indicated by the presence of a % solids value in the method header.
This laboratory report is confidential and is intended for the sole use of TestAmerica and its client.
RECEIPTThe samples were received on 12/08/2016; the samples arrived in good condition, properly preserved and on ice. The temperature of the coolers at receipt was 1.5 C.
An extended TAT was requested by the client via an email on December 8. Samples received on December 8 and 9 were requested to have a due date of December 19, 2016.
PFOA/PFOSSamples WI-AF-3RW23-1216 (320-24179-1), WI-AF-3FB23-1216 (320-24179-2), WI-AF-3RW24-1216 (320-24179-3), WI-AF-3RW24P-1216 (320-24179-4), WI-AF-3FB24-1216 (320-24179-5), WI-AF-3RW25-1216 (320-24179-6), WI-AF-3FB25-1216 (320-24179-7), WI-AF-3RW26-1216 (320-24179-8), WI-AF-3FB26-1216 (320-24179-9), WI-AF-3RW27-1216 (320-24179-10), WI-AF-3FB27-1216 (320-24179-11), WI-AF-3RW28-1216 (320-24179-12), WI-AF-3FB28-1216 (320-24179-13), WI-AF-3RW29-1216 (320-24179-14) and WI-AF-3FB29-1216 (320-24179-15) were analyzed for PFOA/PFOS in accordance with 537. The samples were prepared on 12/09/2016 and analyzed on 12/16/2016.
No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
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Detection SummaryTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
Client Sample ID: WI-AF-3RW23-1216 Lab Sample ID: 320-24179-1
No Detections.
Client Sample ID: WI-AF-3FB23-1216 Lab Sample ID: 320-24179-2
No Detections.
Client Sample ID: WI-AF-3RW24-1216 Lab Sample ID: 320-24179-3
No Detections.
Client Sample ID: WI-AF-3RW24P-1216 Lab Sample ID: 320-24179-4
No Detections.
Client Sample ID: WI-AF-3FB24-1216 Lab Sample ID: 320-24179-5
No Detections.
Client Sample ID: WI-AF-3RW25-1216 Lab Sample ID: 320-24179-6
No Detections.
Client Sample ID: WI-AF-3FB25-1216 Lab Sample ID: 320-24179-7
No Detections.
Client Sample ID: WI-AF-3RW26-1216 Lab Sample ID: 320-24179-8
No Detections.
Client Sample ID: WI-AF-3FB26-1216 Lab Sample ID: 320-24179-9
No Detections.
Client Sample ID: WI-AF-3RW27-1216 Lab Sample ID: 320-24179-10
No Detections.
Client Sample ID: WI-AF-3FB27-1216 Lab Sample ID: 320-24179-11
No Detections.
Client Sample ID: WI-AF-3RW28-1216 Lab Sample ID: 320-24179-12
No Detections.
Client Sample ID: WI-AF-3FB28-1216 Lab Sample ID: 320-24179-13
No Detections.
Client Sample ID: WI-AF-3RW29-1216 Lab Sample ID: 320-24179-14
No Detections.
TestAmerica Sacramento
This Detection Summary does not include radiochemical test results.
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Detection SummaryTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
Client Sample ID: WI-AF-3FB29-1216 Lab Sample ID: 320-24179-15
No Detections.
TestAmerica Sacramento
This Detection Summary does not include radiochemical test results.
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Client Sample ResultsTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
Lab Sample ID: 320-24179-1Client Sample ID: WI-AF-3RW23-1216Matrix: WaterDate Collected: 12/05/16 10:45
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.043 U 0.054 0.014 ug/L 12/09/16 18:50 12/16/16 00:47 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.027 0.0085 ug/L 12/09/16 18:50 12/16/16 00:47 1Perfluorooctanoic acid (PFOA) 0.022 U M
0.13 0.043 ug/L 12/09/16 18:50 12/16/16 00:47 1Perfluorobutanesulfonic acid (PFBS) 0.099 U
13C2 PFHxA 95 70 - 130 12/09/16 18:50 12/16/16 00:47 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 94 12/09/16 18:50 12/16/16 00:47 170 - 130
Lab Sample ID: 320-24179-2Client Sample ID: WI-AF-3FB23-1216Matrix: WaterDate Collected: 12/05/16 10:46
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.046 U 0.057 0.015 ug/L 12/09/16 18:50 12/16/16 02:16 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.029 0.0090 ug/L 12/09/16 18:50 12/16/16 02:16 1Perfluorooctanoic acid (PFOA) 0.023 U
0.13 0.045 ug/L 12/09/16 18:50 12/16/16 02:16 1Perfluorobutanesulfonic acid (PFBS) 0.10 U
13C2 PFHxA 91 70 - 130 12/09/16 18:50 12/16/16 02:16 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 93 12/09/16 18:50 12/16/16 02:16 170 - 130
Lab Sample ID: 320-24179-3Client Sample ID: WI-AF-3RW24-1216Matrix: WaterDate Collected: 12/06/16 09:05
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.043 U 0.053 0.014 ug/L 12/09/16 18:50 12/16/16 02:45 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.027 0.0084 ug/L 12/09/16 18:50 12/16/16 02:45 1Perfluorooctanoic acid (PFOA) 0.021 U M
0.12 0.042 ug/L 12/09/16 18:50 12/16/16 02:45 1Perfluorobutanesulfonic acid (PFBS) 0.098 U
13C2 PFHxA 100 70 - 130 12/09/16 18:50 12/16/16 02:45 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 97 12/09/16 18:50 12/16/16 02:45 170 - 130
Lab Sample ID: 320-24179-4Client Sample ID: WI-AF-3RW24P-1216Matrix: WaterDate Collected: 12/06/16 09:10
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.042 U 0.052 0.014 ug/L 12/09/16 18:50 12/16/16 03:15 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.026 0.0082 ug/L 12/09/16 18:50 12/16/16 03:15 1Perfluorooctanoic acid (PFOA) 0.021 U
0.12 0.041 ug/L 12/09/16 18:50 12/16/16 03:15 1Perfluorobutanesulfonic acid (PFBS) 0.096 U
13C2 PFHxA 86 70 - 130 12/09/16 18:50 12/16/16 03:15 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 82 12/09/16 18:50 12/16/16 03:15 170 - 130
TestAmerica Sacramento
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Client Sample ResultsTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
Lab Sample ID: 320-24179-5Client Sample ID: WI-AF-3FB24-1216Matrix: WaterDate Collected: 12/06/16 09:06
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.044 U 0.055 0.014 ug/L 12/09/16 18:50 12/16/16 03:45 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.028 0.0086 ug/L 12/09/16 18:50 12/16/16 03:45 1Perfluorooctanoic acid (PFOA) 0.022 U
0.13 0.044 ug/L 12/09/16 18:50 12/16/16 03:45 1Perfluorobutanesulfonic acid (PFBS) 0.10 U
13C2 PFHxA 91 70 - 130 12/09/16 18:50 12/16/16 03:45 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 94 12/09/16 18:50 12/16/16 03:45 170 - 130
Lab Sample ID: 320-24179-6Client Sample ID: WI-AF-3RW25-1216Matrix: WaterDate Collected: 12/06/16 09:15
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.045 U 0.057 0.015 ug/L 12/09/16 18:50 12/16/16 05:13 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.028 0.0089 ug/L 12/09/16 18:50 12/16/16 05:13 1Perfluorooctanoic acid (PFOA) 0.023 U
0.13 0.045 ug/L 12/09/16 18:50 12/16/16 05:13 1Perfluorobutanesulfonic acid (PFBS) 0.10 U
13C2 PFHxA 81 70 - 130 12/09/16 18:50 12/16/16 05:13 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 77 12/09/16 18:50 12/16/16 05:13 170 - 130
Lab Sample ID: 320-24179-7Client Sample ID: WI-AF-3FB25-1216Matrix: WaterDate Collected: 12/06/16 09:16
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.042 U 0.053 0.014 ug/L 12/09/16 18:50 12/16/16 05:43 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.027 0.0083 ug/L 12/09/16 18:50 12/16/16 05:43 1Perfluorooctanoic acid (PFOA) 0.021 U
0.12 0.042 ug/L 12/09/16 18:50 12/16/16 05:43 1Perfluorobutanesulfonic acid (PFBS) 0.097 U
13C2 PFHxA 87 70 - 130 12/09/16 18:50 12/16/16 05:43 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 89 12/09/16 18:50 12/16/16 05:43 170 - 130
Lab Sample ID: 320-24179-8Client Sample ID: WI-AF-3RW26-1216Matrix: WaterDate Collected: 12/06/16 10:30
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.045 U 0.057 0.015 ug/L 12/09/16 18:50 12/16/16 06:13 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.028 0.0089 ug/L 12/09/16 18:50 12/16/16 06:13 1Perfluorooctanoic acid (PFOA) 0.023 U
0.13 0.045 ug/L 12/09/16 18:50 12/16/16 06:13 1Perfluorobutanesulfonic acid (PFBS) 0.10 U
13C2 PFHxA 95 70 - 130 12/09/16 18:50 12/16/16 06:13 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 94 12/09/16 18:50 12/16/16 06:13 170 - 130
TestAmerica Sacramento
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Client Sample ResultsTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
Lab Sample ID: 320-24179-9Client Sample ID: WI-AF-3FB26-1216Matrix: WaterDate Collected: 12/06/16 10:31
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.042 U 0.052 0.013 ug/L 12/09/16 18:50 12/16/16 06:42 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.026 0.0082 ug/L 12/09/16 18:50 12/16/16 06:42 1Perfluorooctanoic acid (PFOA) 0.021 U
0.12 0.041 ug/L 12/09/16 18:50 12/16/16 06:42 1Perfluorobutanesulfonic acid (PFBS) 0.095 U
13C2 PFHxA 83 70 - 130 12/09/16 18:50 12/16/16 06:42 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 81 12/09/16 18:50 12/16/16 06:42 170 - 130
Lab Sample ID: 320-24179-10Client Sample ID: WI-AF-3RW27-1216Matrix: WaterDate Collected: 12/06/16 10:40
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.046 U 0.058 0.015 ug/L 12/09/16 18:50 12/16/16 07:12 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.029 0.0091 ug/L 12/09/16 18:50 12/16/16 07:12 1Perfluorooctanoic acid (PFOA) 0.023 U
0.14 0.046 ug/L 12/09/16 18:50 12/16/16 07:12 1Perfluorobutanesulfonic acid (PFBS) 0.11 U
13C2 PFHxA 97 70 - 130 12/09/16 18:50 12/16/16 07:12 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 92 12/09/16 18:50 12/16/16 07:12 170 - 130
Lab Sample ID: 320-24179-11Client Sample ID: WI-AF-3FB27-1216Matrix: WaterDate Collected: 12/06/16 10:41
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.045 U 0.057 0.015 ug/L 12/09/16 18:50 12/16/16 07:41 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.028 0.0089 ug/L 12/09/16 18:50 12/16/16 07:41 1Perfluorooctanoic acid (PFOA) 0.023 U
0.13 0.045 ug/L 12/09/16 18:50 12/16/16 07:41 1Perfluorobutanesulfonic acid (PFBS) 0.10 U
13C2 PFHxA 91 70 - 130 12/09/16 18:50 12/16/16 07:41 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 88 12/09/16 18:50 12/16/16 07:41 170 - 130
Lab Sample ID: 320-24179-12Client Sample ID: WI-AF-3RW28-1216Matrix: WaterDate Collected: 12/06/16 15:35
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.045 U 0.056 0.014 ug/L 12/09/16 18:50 12/16/16 08:11 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.028 0.0088 ug/L 12/09/16 18:50 12/16/16 08:11 1Perfluorooctanoic acid (PFOA) 0.022 U
0.13 0.044 ug/L 12/09/16 18:50 12/16/16 08:11 1Perfluorobutanesulfonic acid (PFBS) 0.10 U
13C2 PFHxA 81 70 - 130 12/09/16 18:50 12/16/16 08:11 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 78 12/09/16 18:50 12/16/16 08:11 170 - 130
TestAmerica Sacramento
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Client Sample ResultsTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
Lab Sample ID: 320-24179-13Client Sample ID: WI-AF-3FB28-1216Matrix: WaterDate Collected: 12/06/16 15:36
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.043 U 0.053 0.014 ug/L 12/09/16 18:50 12/16/16 08:41 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.027 0.0084 ug/L 12/09/16 18:50 12/16/16 08:41 1Perfluorooctanoic acid (PFOA) 0.021 U
0.12 0.042 ug/L 12/09/16 18:50 12/16/16 08:41 1Perfluorobutanesulfonic acid (PFBS) 0.098 U
13C2 PFHxA 96 70 - 130 12/09/16 18:50 12/16/16 08:41 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 97 12/09/16 18:50 12/16/16 08:41 170 - 130
Lab Sample ID: 320-24179-14Client Sample ID: WI-AF-3RW29-1216Matrix: WaterDate Collected: 12/06/16 17:05
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.046 U 0.058 0.015 ug/L 12/09/16 18:50 12/16/16 09:10 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.029 0.0091 ug/L 12/09/16 18:50 12/16/16 09:10 1Perfluorooctanoic acid (PFOA) 0.023 U
0.14 0.046 ug/L 12/09/16 18:50 12/16/16 09:10 1Perfluorobutanesulfonic acid (PFBS) 0.11 U
13C2 PFHxA 89 70 - 130 12/09/16 18:50 12/16/16 09:10 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 92 12/09/16 18:50 12/16/16 09:10 170 - 130
Lab Sample ID: 320-24179-15Client Sample ID: WI-AF-3FB29-1216Matrix: WaterDate Collected: 12/06/16 17:06
Date Received: 12/08/16 10:00
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.047 U 0.058 0.015 ug/L 12/09/16 18:50 12/16/16 09:40 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.029 0.0092 ug/L 12/09/16 18:50 12/16/16 09:40 1Perfluorooctanoic acid (PFOA) 0.023 U
0.14 0.046 ug/L 12/09/16 18:50 12/16/16 09:40 1Perfluorobutanesulfonic acid (PFBS) 0.11 U
13C2 PFHxA 92 70 - 130 12/09/16 18:50 12/16/16 09:40 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C2 PFDA 90 12/09/16 18:50 12/16/16 09:40 170 - 130
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Default Detection LimitsClient: CH2M Hill Constructors, Inc. TestAmerica Job ID: 320-24179-1Project/Site: Whidbey Island
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)Prep: 537
0.14Perfluorobutanesulfonic acid (PFBS) ug/L
Analyte Units MethodDLLOQ
0.048 537
0.060Perfluorooctanesulfonic acid (PFOS) ug/L0.016 537
0.030Perfluorooctanoic acid (PFOA) ug/L0.0094 537
TestAmerica Sacramento
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Surrogate SummaryTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)Prep Type: Total/NAMatrix: Water
Lab Sample ID Client Sample ID (70-130) (70-130)
13C2 PFHxA13C2 PFDA
95 94320-24179-1
Percent Surrogate Recovery (Acceptance Limits)
WI-AF-3RW23-1216
91 93320-24179-1 MS WI-AF-3RW23-1216
101 96320-24179-1 MSD WI-AF-3RW23-1216
91 93320-24179-2 WI-AF-3FB23-1216
100 97320-24179-3 WI-AF-3RW24-1216
86 82320-24179-4 WI-AF-3RW24P-1216
91 94320-24179-5 WI-AF-3FB24-1216
81 77320-24179-6 WI-AF-3RW25-1216
87 89320-24179-7 WI-AF-3FB25-1216
95 94320-24179-8 WI-AF-3RW26-1216
83 81320-24179-9 WI-AF-3FB26-1216
97 92320-24179-10 WI-AF-3RW27-1216
91 88320-24179-11 WI-AF-3FB27-1216
81 78320-24179-12 WI-AF-3RW28-1216
96 97320-24179-13 WI-AF-3FB28-1216
89 92320-24179-14 WI-AF-3RW29-1216
92 90320-24179-15 WI-AF-3FB29-1216
98 97LCS 320-141539/2-A Lab Control Sample
105 105MB 320-141539/1-A Method Blank
Surrogate Legend
13C2 PFHxA = 13C2 PFHxA
13C2 PFDA = 13C2 PFDA
TestAmerica Sacramento
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QC Sample ResultsTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
Method: 537 - Perfluorinated Alkyl Acids (LC/MS)
Client Sample ID: Method BlankLab Sample ID: MB 320-141539/1-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 142414 Prep Batch: 141539
LOQ DL
Perfluorooctanesulfonic acid (PFOS) 0.048 U 0.060 0.016 ug/L 12/09/16 18:50 12/15/16 23:48 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
0.024 U 0.00940.030 ug/L 12/09/16 18:50 12/15/16 23:48 1Perfluorooctanoic acid (PFOA)
0.11 U 0.0480.14 ug/L 12/09/16 18:50 12/15/16 23:48 1Perfluorobutanesulfonic acid (PFBS)
13C2 PFHxA 105 70 - 130 12/15/16 23:48 1
MB MB
Surrogate
12/09/16 18:50
Dil FacPrepared AnalyzedQualifier Limits%Recovery
105 12/09/16 18:50 12/15/16 23:48 113C2 PFDA 70 - 130
Client Sample ID: Lab Control SampleLab Sample ID: LCS 320-141539/2-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 142414 Prep Batch: 141539
Perfluorooctanesulfonic acid
(PFOS)
0.300 0.245 ug/L 82 70 - 130
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Perfluorooctanoic acid (PFOA) 0.152 0.129 ug/L 85 70 - 130
Perfluorobutanesulfonic acid
(PFBS)
0.673 0.511 ug/L 76 70 - 130
13C2 PFHxA 70 - 130
Surrogate
98
LCS LCS
Qualifier Limits%Recovery
9713C2 PFDA 70 - 130
Client Sample ID: WI-AF-3RW23-1216Lab Sample ID: 320-24179-1 MSMatrix: Water Prep Type: Total/NAAnalysis Batch: 142438 Prep Batch: 141539
Perfluorooctanesulfonic acid
(PFOS)
0.043 U 0.150 0.106 ug/L 70 70 - 130
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Perfluorooctanoic acid (PFOA) 0.022 U M 0.0759 0.0539 ug/L 71 70 - 130
Perfluorobutanesulfonic acid
(PFBS)
0.099 U 0.336 0.248 ug/L 74 70 - 130
13C2 PFHxA 70 - 130
Surrogate
91
MS MS
Qualifier Limits%Recovery
9313C2 PFDA 70 - 130
Client Sample ID: WI-AF-3RW23-1216Lab Sample ID: 320-24179-1 MSDMatrix: Water Prep Type: Total/NAAnalysis Batch: 142414 Prep Batch: 141539
Perfluorooctanesulfonic acid
(PFOS)
0.043 U 0.159 0.120 ug/L 75 70 - 130 14 30
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Perfluorooctanoic acid (PFOA) 0.022 U M 0.0804 0.0621 ug/L 77 70 - 130 17 30
Perfluorobutanesulfonic acid
(PFBS)
0.099 U 0.356 0.303 ug/L 85 70 - 130 18 30
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QC Sample ResultsTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
Method: 537 - Perfluorinated Alkyl Acids (LC/MS) (Continued)
Client Sample ID: WI-AF-3RW23-1216Lab Sample ID: 320-24179-1 MSDMatrix: Water Prep Type: Total/NAAnalysis Batch: 142414 Prep Batch: 141539
13C2 PFHxA 70 - 130
Surrogate
101
MSD MSD
Qualifier Limits%Recovery
9613C2 PFDA 70 - 130
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QC Association SummaryTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
LCMS
Prep Batch: 141539
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 537320-24179-1 WI-AF-3RW23-1216 Total/NA
Water 537320-24179-2 WI-AF-3FB23-1216 Total/NA
Water 537320-24179-3 WI-AF-3RW24-1216 Total/NA
Water 537320-24179-4 WI-AF-3RW24P-1216 Total/NA
Water 537320-24179-5 WI-AF-3FB24-1216 Total/NA
Water 537320-24179-6 WI-AF-3RW25-1216 Total/NA
Water 537320-24179-7 WI-AF-3FB25-1216 Total/NA
Water 537320-24179-8 WI-AF-3RW26-1216 Total/NA
Water 537320-24179-9 WI-AF-3FB26-1216 Total/NA
Water 537320-24179-10 WI-AF-3RW27-1216 Total/NA
Water 537320-24179-11 WI-AF-3FB27-1216 Total/NA
Water 537320-24179-12 WI-AF-3RW28-1216 Total/NA
Water 537320-24179-13 WI-AF-3FB28-1216 Total/NA
Water 537320-24179-14 WI-AF-3RW29-1216 Total/NA
Water 537320-24179-15 WI-AF-3FB29-1216 Total/NA
Water 537MB 320-141539/1-A Method Blank Total/NA
Water 537LCS 320-141539/2-A Lab Control Sample Total/NA
Water 537320-24179-1 MS WI-AF-3RW23-1216 Total/NA
Water 537320-24179-1 MSD WI-AF-3RW23-1216 Total/NA
Analysis Batch: 142414
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 537 141539320-24179-1 WI-AF-3RW23-1216 Total/NA
Water 537 141539320-24179-2 WI-AF-3FB23-1216 Total/NA
Water 537 141539320-24179-3 WI-AF-3RW24-1216 Total/NA
Water 537 141539320-24179-4 WI-AF-3RW24P-1216 Total/NA
Water 537 141539320-24179-5 WI-AF-3FB24-1216 Total/NA
Water 537 141539MB 320-141539/1-A Method Blank Total/NA
Water 537 141539LCS 320-141539/2-A Lab Control Sample Total/NA
Water 537 141539320-24179-1 MSD WI-AF-3RW23-1216 Total/NA
Analysis Batch: 142415
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 537 141539320-24179-6 WI-AF-3RW25-1216 Total/NA
Water 537 141539320-24179-7 WI-AF-3FB25-1216 Total/NA
Water 537 141539320-24179-8 WI-AF-3RW26-1216 Total/NA
Water 537 141539320-24179-9 WI-AF-3FB26-1216 Total/NA
Water 537 141539320-24179-10 WI-AF-3RW27-1216 Total/NA
Water 537 141539320-24179-11 WI-AF-3FB27-1216 Total/NA
Water 537 141539320-24179-12 WI-AF-3RW28-1216 Total/NA
Water 537 141539320-24179-13 WI-AF-3FB28-1216 Total/NA
Water 537 141539320-24179-14 WI-AF-3RW29-1216 Total/NA
Water 537 141539320-24179-15 WI-AF-3FB29-1216 Total/NA
Analysis Batch: 142438
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 537 141539320-24179-1 MS WI-AF-3RW23-1216 Total/NA
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Lab ChronicleClient: CH2M Hill Constructors, Inc. TestAmerica Job ID: 320-24179-1Project/Site: Whidbey Island
Client Sample ID: WI-AF-3RW23-1216 Lab Sample ID: 320-24179-1Matrix: WaterDate Collected: 12/05/16 10:45
Date Received: 12/08/16 10:00
Prep 537 12/09/16 18:50 JER141539 TAL SAC
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA
Analysis 537 1 142414 12/16/16 00:47 CBW TAL SACTotal/NA
Client Sample ID: WI-AF-3FB23-1216 Lab Sample ID: 320-24179-2Matrix: WaterDate Collected: 12/05/16 10:46
Date Received: 12/08/16 10:00
Prep 537 12/09/16 18:50 JER141539 TAL SAC
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA
Analysis 537 1 142414 12/16/16 02:16 CBW TAL SACTotal/NA
Client Sample ID: WI-AF-3RW24-1216 Lab Sample ID: 320-24179-3Matrix: WaterDate Collected: 12/06/16 09:05
Date Received: 12/08/16 10:00
Prep 537 12/09/16 18:50 JER141539 TAL SAC
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA
Analysis 537 1 142414 12/16/16 02:45 CBW TAL SACTotal/NA
Client Sample ID: WI-AF-3RW24P-1216 Lab Sample ID: 320-24179-4Matrix: WaterDate Collected: 12/06/16 09:10
Date Received: 12/08/16 10:00
Prep 537 12/09/16 18:50 JER141539 TAL SAC
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA
Analysis 537 1 142414 12/16/16 03:15 CBW TAL SACTotal/NA
Client Sample ID: WI-AF-3FB24-1216 Lab Sample ID: 320-24179-5Matrix: WaterDate Collected: 12/06/16 09:06
Date Received: 12/08/16 10:00
Prep 537 12/09/16 18:50 JER141539 TAL SAC
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA
Analysis 537 1 142414 12/16/16 03:45 CBW TAL SACTotal/NA
Client Sample ID: WI-AF-3RW25-1216 Lab Sample ID: 320-24179-6Matrix: WaterDate Collected: 12/06/16 09:15
Date Received: 12/08/16 10:00
Prep 537 12/09/16 18:50 JER141539 TAL SAC
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA
Analysis 537 1 142415 12/16/16 05:13 CBW TAL SACTotal/NA
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Lab ChronicleClient: CH2M Hill Constructors, Inc. TestAmerica Job ID: 320-24179-1Project/Site: Whidbey Island
Client Sample ID: WI-AF-3FB25-1216 Lab Sample ID: 320-24179-7Matrix: WaterDate Collected: 12/06/16 09:16
Date Received: 12/08/16 10:00
Prep 537 12/09/16 18:50 JER141539 TAL SAC
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA
Analysis 537 1 142415 12/16/16 05:43 CBW TAL SACTotal/NA
Client Sample ID: WI-AF-3RW26-1216 Lab Sample ID: 320-24179-8Matrix: WaterDate Collected: 12/06/16 10:30
Date Received: 12/08/16 10:00
Prep 537 12/09/16 18:50 JER141539 TAL SAC
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA
Analysis 537 1 142415 12/16/16 06:13 CBW TAL SACTotal/NA
Client Sample ID: WI-AF-3FB26-1216 Lab Sample ID: 320-24179-9Matrix: WaterDate Collected: 12/06/16 10:31
Date Received: 12/08/16 10:00
Prep 537 12/09/16 18:50 JER141539 TAL SAC
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA
Analysis 537 1 142415 12/16/16 06:42 CBW TAL SACTotal/NA
Client Sample ID: WI-AF-3RW27-1216 Lab Sample ID: 320-24179-10Matrix: WaterDate Collected: 12/06/16 10:40
Date Received: 12/08/16 10:00
Prep 537 12/09/16 18:50 JER141539 TAL SAC
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA
Analysis 537 1 142415 12/16/16 07:12 CBW TAL SACTotal/NA
Client Sample ID: WI-AF-3FB27-1216 Lab Sample ID: 320-24179-11Matrix: WaterDate Collected: 12/06/16 10:41
Date Received: 12/08/16 10:00
Prep 537 12/09/16 18:50 JER141539 TAL SAC
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA
Analysis 537 1 142415 12/16/16 07:41 CBW TAL SACTotal/NA
Client Sample ID: WI-AF-3RW28-1216 Lab Sample ID: 320-24179-12Matrix: WaterDate Collected: 12/06/16 15:35
Date Received: 12/08/16 10:00
Prep 537 12/09/16 18:50 JER141539 TAL SAC
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA
Analysis 537 1 142415 12/16/16 08:11 CBW TAL SACTotal/NA
TestAmerica Sacramento
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Lab ChronicleClient: CH2M Hill Constructors, Inc. TestAmerica Job ID: 320-24179-1Project/Site: Whidbey Island
Client Sample ID: WI-AF-3FB28-1216 Lab Sample ID: 320-24179-13Matrix: WaterDate Collected: 12/06/16 15:36
Date Received: 12/08/16 10:00
Prep 537 12/09/16 18:50 JER141539 TAL SAC
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA
Analysis 537 1 142415 12/16/16 08:41 CBW TAL SACTotal/NA
Client Sample ID: WI-AF-3RW29-1216 Lab Sample ID: 320-24179-14Matrix: WaterDate Collected: 12/06/16 17:05
Date Received: 12/08/16 10:00
Prep 537 12/09/16 18:50 JER141539 TAL SAC
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA
Analysis 537 1 142415 12/16/16 09:10 CBW TAL SACTotal/NA
Client Sample ID: WI-AF-3FB29-1216 Lab Sample ID: 320-24179-15Matrix: WaterDate Collected: 12/06/16 17:06
Date Received: 12/08/16 10:00
Prep 537 12/09/16 18:50 JER141539 TAL SAC
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total/NA
Analysis 537 1 142415 12/16/16 09:40 CBW TAL SACTotal/NA
Laboratory References:
TAL SAC = TestAmerica Sacramento, 880 Riverside Parkway, West Sacramento, CA 95605, TEL (916)373-5600
TestAmerica Sacramento
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Certification SummaryClient: CH2M Hill Constructors, Inc. TestAmerica Job ID: 320-24179-1Project/Site: Whidbey Island
Laboratory: TestAmerica SacramentoUnless otherwise noted, all analytes for this laboratory were covered under each certification below.
Authority Program EPA Region Certification ID Expiration Date
A2LA 2928-01DoD ELAP 01-31-17
Analysis Method Prep Method Matrix Analyte
TestAmerica Sacramento
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Method SummaryTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
Method Method Description LaboratoryProtocol
EPA537 Perfluorinated Alkyl Acids (LC/MS) TAL SAC
Protocol References:
EPA = US Environmental Protection Agency
Laboratory References:
TAL SAC = TestAmerica Sacramento, 880 Riverside Parkway, West Sacramento, CA 95605, TEL (916)373-5600
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Sample SummaryTestAmerica Job ID: 320-24179-1Client: CH2M Hill Constructors, Inc.
Project/Site: Whidbey Island
Lab Sample ID Client Sample ID ReceivedCollectedMatrix
320-24179-1 WI-AF-3RW23-1216 Water 12/05/16 10:45 12/08/16 10:00
320-24179-2 WI-AF-3FB23-1216 Water 12/05/16 10:46 12/08/16 10:00
320-24179-3 WI-AF-3RW24-1216 Water 12/06/16 09:05 12/08/16 10:00
320-24179-4 WI-AF-3RW24P-1216 Water 12/06/16 09:10 12/08/16 10:00
320-24179-5 WI-AF-3FB24-1216 Water 12/06/16 09:06 12/08/16 10:00
320-24179-6 WI-AF-3RW25-1216 Water 12/06/16 09:15 12/08/16 10:00
320-24179-7 WI-AF-3FB25-1216 Water 12/06/16 09:16 12/08/16 10:00
320-24179-8 WI-AF-3RW26-1216 Water 12/06/16 10:30 12/08/16 10:00
320-24179-9 WI-AF-3FB26-1216 Water 12/06/16 10:31 12/08/16 10:00
320-24179-10 WI-AF-3RW27-1216 Water 12/06/16 10:40 12/08/16 10:00
320-24179-11 WI-AF-3FB27-1216 Water 12/06/16 10:41 12/08/16 10:00
320-24179-12 WI-AF-3RW28-1216 Water 12/06/16 15:35 12/08/16 10:00
320-24179-13 WI-AF-3FB28-1216 Water 12/06/16 15:36 12/08/16 10:00
320-24179-14 WI-AF-3RW29-1216 Water 12/06/16 17:05 12/08/16 10:00
320-24179-15 WI-AF-3FB29-1216 Water 12/06/16 17:06 12/08/16 10:00
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Lab Name: Job No.:
SDG No.:
LCMS MANUAL INTEGRATION SUMMARY
TestAmerica Sacramento 320-24179-1
Instrument ID: Analysis Batch Number:A6 140688
Lab Sample ID: Client Sample ID:
Date Analyzed: Lab File ID:
COMPOUND NAME RETENTIONTIME
MANUAL INTEGRATIONDATEANALYSTREASON
STD 320-140688/2 IC
05DEC2016A6A_004.d12/05/16 17:26 GC Column: Acquity ID: 2.1(mm)
Perfluoroheptanoic acid Split Peak barnettj 12/06/16 10:0019.37Perfluorooctanoic acid (PFOA) Split Peak barnettj 12/06/16 10:0020.05
Lab Sample ID: Client Sample ID:
Date Analyzed: Lab File ID:
COMPOUND NAME RETENTIONTIME
MANUAL INTEGRATIONDATEANALYSTREASON
STD 320-140688/3 IC
05DEC2016A6A_005.d12/05/16 17:55 GC Column: Acquity ID: 2.1(mm)
Perfluoroheptanoic acid Split Peak barnettj 12/06/16 10:0319.38Perfluorooctanoic acid (PFOA) Split Peak barnettj 12/06/16 10:0320.05
Lab Sample ID: Client Sample ID:
Date Analyzed: Lab File ID:
COMPOUND NAME RETENTIONTIME
MANUAL INTEGRATIONDATEANALYSTREASON
CCV 320-140688/9 CCVL
05DEC2016A6A_011.d12/05/16 20:53 GC Column: Acquity ID: 2.1(mm)
Perfluoroheptanoic acid Split Peak barnettj 12/06/16 10:0819.38Perfluorooctanoic acid (PFOA) Split Peak barnettj 12/06/16 10:0820.05
537
12/19/2016Page 23 of 263
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Lab Name: Job No.:
SDG No.:
LCMS MANUAL INTEGRATION SUMMARY
TestAmerica Sacramento 320-24179-1
Instrument ID: Analysis Batch Number:A6 142223
Lab Sample ID: Client Sample ID:
Date Analyzed: Lab File ID:
COMPOUND NAME RETENTIONTIME
MANUAL INTEGRATIONDATEANALYSTREASON
CCV 320-142223/2 CCVL
15DEC2016A6A_002.d12/15/16 08:03 GC Column: Acquity ID: 2.1(mm)
Perfluoroheptanoic acid Split Peak barnettj 12/15/16 15:0519.38Perfluorooctanoic acid (PFOA) Split Peak barnettj 12/15/16 15:0520.05
537
12/19/2016Page 24 of 263
-
Lab Name: Job No.:
SDG No.:
LCMS MANUAL INTEGRATION SUMMARY
TestAmerica Sacramento 320-24179-1
Instrument ID: Analysis Batch Number:A6 142414
Lab Sample ID: Client Sample ID:
Date Analyzed: Lab File ID:
COMPOUND NAME RETENTIONTIME
MANUAL INTEGRATIONDATEANALYSTREASON
320-24179-1 WI-AF-3RW23-1216
15DEC2016A6A_035.d12/16/16 00:47 GC Column: Acquity ID: 2.1(mm)
Perfluorooctanoic acid (PFOA) Split Peak westendorfc
12/16/16 10:4320.05
Lab Sample ID: Client Sample ID:
Date Analyzed: Lab File ID:
COMPOUND NAME RETENTIONTIME
MANUAL INTEGRATIONDATEANALYSTREASON
320-24179-3 WI-AF-3RW24-1216
15DEC2016A6A_039.d12/16/16 02:45 GC Column: Acquity ID: 2.1(mm)
Perfluorooctanoic acid (PFOA) Assign Peak westendorfc
12/16/16 10:4520.05
537
12/19/2016Page 25 of 263
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REAGENT TRACEABILITY SUMMARY
Lab Name:
SDG No.:
Job No.: 320-24179-1TestAmerica Sacramento
Reagent IDExpDate Date
Prep DilutantUsed
ReagentFinalVolume
Parent Reagent
Reagent IDVolumeAdded ConcentrationAnalyte
LC537SPIM_00012 Perfluorobutane Sulfonate 3366 ng/mL10000 uL 375 uL01/28/17 07/28/16LC537-HSP_00010 Methanol, Lot 090285Perfluorobutanesulfonic acid (PFBS)
3366 ng/mL
Perfluoroheptanoic acid 381.857 ng/mLPerfluorohexanesulfonic acid 1134.68 ng/mLPerfluorononanoic acid 736.695 ng/mLPerfluorooctanoic acid (PFOA) 760.489 ng/mLPerfluorooctanesulfonic acid (PFOS)
1502.49 ng/mL
LC537-PFBS_00006 Perfluorobutane Sulfonate 89.76 ug/mL10 mL 0.44 mL01/28/17 07/28/16.LC537SPIM_00012 Methanol,
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