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  Fitness for Service and API 579 Presented by: Ray Delaforce 3/26/2013  1 First consider Unfitness for Service First consider Unfitness for Service Here are some of the problems – first we consider corrosion This is generalised corrosion of steel The red areas are Hematite The black spots are Magnetite Red Hematite is flaky and porous. Hemati te is t he main problem 3/26/2013  2

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  • 3/26/2013

    1

    Fitness for Service and API 579

    Presented by:

    Ray Delaforce

    3/26/2013 1

    First consider Unfitness for Service

    First consider Unfitness for Service

    Here are some of the problems first we consider corrosion

    This is generalised corrosion of steel

    The red areas are Hematite

    The black spots are Magnetite

    Red Hematite is flaky and porous. Hematite is the main problem

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  • 3/26/2013

    2

    First consider Unfitness for Service

    First consider Unfitness for Service

    This another very typical example

    The white flecks are from insulation that has been removed

    3/26/2013 3

    First consider Unfitness for Service

    First consider Unfitness for Service

    This is galvanic corrosion of aluminium and steel in sea water

    Note the presence of red Hematite on the steel

    3/26/2013 4

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    3

    First consider Unfitness for Service

    The various mechanisms of Corrosion

    General corrosion Occurs over large surfaces Generally in the form of Hematite

    Crevice corrosion Where crevices give limited access to contained fluid Often where parts are fitted together but not welded

    Microbial corrosion Caused by microorganisms Often producing Hydrogen Sulfide Giving rise to accelerated corrosion

    High temperature corrosion Causes chemical deterioration Causing products that migrate to the grain boundaries

    3/26/2013 5

    First consider Unfitness for Service

    Consider for a moment the chemistry of corrosion

    3/26/2013 6

    Fill then as follows: 1 tap water, 2 boiled water with at film of oil as a seal to keep air out, 3 dessicant

    Take 3 test tubes and set them up in a stand each with a nail

    1 2 3

    The nails in tubes 2 and 3 are the only ones that do not rust

    Corrosion requires both Oxygen and Water to produce rust

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    First consider Unfitness for Service

    Consider for a moment the chemistry of corrosion

    3/26/2013 7

    Here we have a piece of steel immersed in water

    The OH- ions and are distributed in the water

    O2 + 2H2O + 4e-

    4HO-(OH- is a hydroxyl ion)

    By oxidation, the iron loses 2 electrons

    Fe Fe2+ (Iron ion) + 2e-

    At a site in the metal, an Anode is formed with the Iron ions

    Fe2+

    anode

    In the presence of O2, hydroxyl ions are formed

    OH-

    OH-OH-

    OH-OH-

    First consider Unfitness for Service

    Consider for a moment the chemistry of corrosion

    3/26/2013 8

    Negative OH- ions combine with positive Fe2+ ions, to form Iron Hydroxide

    Fe2+

    anodecathode

    OH-

    OH-OH-

    OH-OH-

    Fe2+ + 2OH- Fe(OH)2

    The Iron Hydroxide is deposited on the plate at another site

    Fe(OH)2

    Forming a Cathode

  • 3/26/2013

    5

    First consider Unfitness for Service

    Consider for a moment the chemistry of corrosion

    3/26/2013 9

    Negative OH- ions combine with positive Fe2+ ions, to form Iron Hydroxide

    Fe2+

    anodecathode

    Fe2+ + 2OH- Fe(OH)2

    The Iron Hydroxide is deposited on the plate at another site

    Fe(OH)2

    Forming a Cathode

    The electrons lost by the Iron now migrate through the metal

    e-

    In the presence of O2 the Iron Hydroxide Oxidises further

    4Fe(OH)2 + O2 Fe2O3.H2O + 2H2O Iron Oxide Red Rust

    This rust is known as Hematite

    OH-

    We now move on to API 579

    What to do when a vessel suffers wear and tear

    3/26/2013 10

  • 3/26/2013

    6

    We now move on to API 579

    After some time in service, a vessel can suffer damage

    3/26/2013 11

    General corrosion Pitting corrosion Grooves and gouging Surface cracks Susceptibility to brittle facture Welding misalignment Dents Fire damage

    In this presentation we are going to consider just a few of the effects of wear and tear

    Consider a new cylinder

    Look at the requirement per ASME VIII, Division 1

    P = 1,5 MPa Design pressureD = 1500 mm Inside diameterc = 3 mm Corrosion allowanceS = 138 Mpa Allowable (design) stressE = 0,85 Joint Efficiency

    According to the code the required thickness is by PV Elite:

    If the thickness is below 12,7038 mm there is a code violation

    But, that is for new construction so select a 14 mm plate.

    3/26/2013 12

  • 3/26/2013

    7

    Now consider the same cylinder after several years service

    Some local general corrosion is detected like this

    In some locations the thickness is reduced to 11 mm (was 14 mm)

    According to the original (new) calculation:

    The corroded required thickness was 12,7038 3 = 9,7038 mm The chosen plate thickness was 14 mm The corroded thickness is still thick enough at 11 mm Corrosion allowance is reduced to 11 9.7038 = 1,296 mm BUT: we still need a corrosion allowance of 1,5 mm for future . service !

    3/26/2013 13

    Now consider the same cylinder after several years service

    We need 1,5 mm corrosion allowance for the remaining life

    The corroded required thickness was 12,7038 3 = 9,7038 mm The chosen plate thickness was 14 mm The corroded thickness is still thick enough at 11 mm Corrosion allowance is reduced to 11 9.7038 = 1,296 mm BUT: we still need a corrosion allowance of 1,5 mm for future . service !

    The remaining metal available for corrosion is only 1,296 mm

    According the original code, we would be in violation !

    Remember: The Code is for new construction

    Clearly we need additional technical assistance

    3/26/2013 14

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    8

    API 579 is the help we need

    This is Fitness For Service, and modifies the code requirement

    It allows us to use thinner plate, but certain criteria must be met

    It provided a procedure to assess the corrosion damage

    These are the steps that initially must be followed:

    First a grid must be set over the corroded area The at the node points, thicknesses have to be surveyed An analysis must be carried out for future service

    Then we must consider the future possibilities:

    Can vessel be put back into service, or, Must the operating pressure be reduced Must the future service life be reduced Must a repair be carried out Must the vessel be scrapped !

    API 579 can answer these questions

    3/26/2013 15

    API 579 Level 1 Assessment

    The first step: Survey the corroded area for thickness at the nodes

    C1 C2 C3 C4 C5 C6 C7 C8

    M1

    M2

    M3

    M4

    M5

    M6

    M7

    1 Overlay the corroded area with a grid

    2 Label the circumferential and longitudinal lines in the grid

    3 Measure the thicknesses at the node points

    3/26/2013 16

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    9

    Next: Make a table of the thickness measurements inches

    0.48

    0.75

    0.55

    0.36

    0.48

    049

    0.75

    0.360.75 0.48 0.47 0.55 0.48 0.49 0.75

    1 Find the smallest thickness in the circumferential direction

    2 Find the smallest thickness in the longitudinal direction

    2 Complete finding the minimum thicknesses in each direction

    API 579 Level 1 Assessment

    3/26/2013 17

    Next: Find the absolute smallest thickness tmm

    0.48

    0.75

    0.55

    0.36

    0.48

    049

    0.75

    0.360.75 0.48 0.47 0.55 0.48 0.49 0.75

    Here is the Critical Thickness Profile (CTP) in the longitudinal direction

    We can plot the CTP to find the average thickness

    API 579 Level 1 Assessment

    3/26/2013 18

  • 3/26/2013

    10

    Here is the plot of the CTP (critical thickness profile)

    0.470.55

    0.36

    0.48 0.49tmm

    1,5 1,5 1,5 1,5

    This is the grid distance.

    Now, we need the Critical Length LQ = 0,4581 (read from Table 4.5)

    Thickness to be used in the assessment tc

    tc = Original thickness Corrosion allowance = 0,75-0,1 = 0,65 in

    L

    L = Q(D.tc)1/2 = 0,4581.(48,2.0.65) =2,564 in (D corroded)

    2,564 in

    API 579 Level 1 Assessment

    3/26/2013 19

    Now we need the thicknesses t1 and t2

    0.470.55

    0.36

    0.48 0.49tmm

    1,5 1,5 1,5 1,5

    L

    2,564 in

    API 579 Level 1 Assessment

    t1 t2

    From the geometry t1 = 0,522 in and t2 = 0,463 in

    Find the average thickness tam

    tam = this shaded area divided by L tam = 0,426 in

    tcmin From the code = = = 0,430 inP.R

    S.E-0,6.P

    300.24,1

    20000.0,85-0,6.300

    tam Corroded = tam - FCA = 0,426 0,1 = 0,326 in

    (FCA = Future corrosion allowance)

    Conclusion: Fails Level 1 assessment - try Level 2 assessment

    FCA

    API 579 Level 2 Assessment

    3/26/2013 20

    tam

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    11

    API 579 Level 2 Assessment

    tam Corroded = tam - FCA = 0,426 0,1 = 0,326 in

    We have already computed the corroded average thickness:

    We need the Remaining Allowable Strength Factor RSFa

    The calculated required thickness (code formula) tcmin= 0,430 in

    This is normally taken as RSFa= 0,9

    Now: RFSa x tcmin = 0,9 x 0,430 = 0,387 in

    The remaining thickness Fails Level 2

    We can drop the MAWP of the component

    3/26/2013 21

    API 579 Reduced MAWP

    tam Corroded = tam - FCA = 0,426 0,1 = 0,326 in

    We have already computed the corroded average thickness:

    MAWP = = = 228,1 psi t.S.E

    R+0,6.t

    0,326.20000.0,85

    24,1+0,6.0,326

    Thus the MAWP has to be reduced from 300 psi to 228,1 psi

    This method used the formal grid, but we can take random points

    3/26/2013 22

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    12

    API 579 Consider Random Points

    First, we make a table of the random point thicknesses

    Next we compute the average thickness

    tam = (trd)1

    N i =1

    N

    = 12,0667 mm

    Next we compute (trd tam) for each point

    3/26/2013 23

    API 579 Consider Random Points

    First, we make a table of the random point thicknesses

    Next we compute (trd tam) for each point

    Then compute (trd tam)2 for each point

    3/26/2013 24

  • 3/26/2013

    13

    API 579 Consider Random Points

    First, we make a table of the random point thicknesses

    Next we compute (trd tam) for each point

    Then compute (trd tam)2 for each point

    Find the value S

    3/26/2013 25

    API 579 Consider Random Points

    First, we make a table of the random point thicknesses

    Find the value S

    S = (trd-ta,)2

    i =1

    N

    = 12,9333 mm

    3/26/2013 26

  • 3/26/2013

    14

    API 579 Consider Random Points

    Now compute the Coefficient Of Variance COV

    COV = =1

    tam

    S

    N-1[ ]

    0,5 1

    12,0667

    12,9333

    14-1[ ]

    0,5

    = 0,080 or 8%

    Because COV is less than 10% we can use the average thick. tam

    Now the original nominal thickness tnom = 16 mm

    LOSS is the amount of corrosion that has already taken place

    LOSS tnom - tam= 16 12,0667 = 3,9333 mm

    We now have to use code formula to compute required thickness

    3/26/2013 27

    API 579 Consider Random Points

    This is the cylinder we with which are dealing

    P = 3,85 MPa Current MAWPD = 484 mm Inside diameterS = 96,196 MPa Allowable design stress E = 1,0 Joint Efficiencyc = 2 mm Corrosion allowance Also FCAtnom = 16 mm Actual new thickness of the cylinder

    From the code formula:

    tcmin = = = 10,1670 mmP.(R+c+LOSS)

    S.E-0,6.P

    3,85.(242+2+3,9333)

    96,196.1,0-0,6.3,85

    tam FCA = 12,0667 2,0 = 10,0667mm

    The cylinder is not thick enough for future service per Level 1

    We can:

    Reduce the MAWP, or, Reduce the future corrosion allowance (FCA) Try Level 2 assessment

    3/26/2013 28

  • 3/26/2013

    15

    API 579 Consider Random Points Level 2

    We already know the tam FCA = 10,0667 mm

    The minimum measured thickness tmm- FCA = 8 mm

    tlim = max(0,2.tnom; 2,5) = max(0,2.16; 2,5) = 3,2 mm

    Compute max(0,5.tcmin ; tlim) = max(0,5.10,167; 3,2)

    = 5,0835 mm

    Level 2 assessment passes

    3/26/2013 29

    Simple calculation Remaining Life

    Suppose we have the following data over a period of 5 years

    The total uniform corrosion is 2,5 mm for the 5 years We need to know the remaining life of a head

    This is the head whose remaining life we require:

    P = 1,5 MPa MAWP if the headD = 2500 mm Original Diameter (New)c = 3 mm Original corrosion allowanceS = 120 Mpa Design stress of the materialE = 1,0 Joint efficiency

    Uniform corrosion rate = 2,5 / 5 = cRate = 0,5 mm per year

    tFinal = = = 15,645 mmP.D

    2SE0,2P

    1,5.2500

    2.120.1,00,2.1,5

    t = Current corroded thickness = 20 mm

    3/26/2013 30

  • 3/26/2013

    16

    Simple calculation Remaining Life

    tFinal= 15,645 mm, and t = 20 mm and cRate = 0,5 per year

    Remaining corrosion = 20 - 15,645 = 4,355 mm

    Remaining life = 4,355 / corrosion rate = 4,355 / 0,5 = 8,71 years

    This assumes the corrosion continues at a uniform rate

    We move onto something else now

    3/26/2013 31

    Simple Example Pitting Corrosion

    This is a typical example of pitting corrosion

    The Level 1 assessment is very simple

    3/26/2013 32

  • 3/26/2013

    17

    Simple Example Pitting Corrosion

    First, we get the data for the cylinder original design

    D = 60 in Inside diametertnom = 0,75 in Original thicknessLOSS = 0,05 in Uniform metal loss so farFCA = 0,07 in Future corrosion allowanceS = 17500 psi Design stress E = 0,85 Joint Efficiency

    Step 1: Find the worst the area with the highest number of pits

    Step 2: Measure maximum pit depth wmax= 0,3 in

    Step 3: Get the value tc from this equation

    tc = tnom LOSS FCA = 0,75 0,05 0.07 = 0,63 in

    Step 4: Get the remaining thickness ratio Rwt from this equation

    tc

    tc + FCA-wmax

    0,63

    0,63 + 0,07-0,3Rwt = = = 0,6349

    3/26/2013 33

    Simple Example Pitting Corrosion

    tc = 0,63 in Rwt = 0,6349 LOSS = 0,05 in FCA = 0,07 in

    Step 5: Get the effective inside radius of the shell Rc

    Rc = D/2 + LOSS + FCA = 30+0,05+0,07 = 30,12 in

    Step 6: Compute the MAWP of the cylinder

    MAWP = = = 307 psiS.E.tc

    Rc+0,6.tc

    17500.0,85.0,63

    30,12+0,6.0,63

    Step 7: Check to see if the MAWP has to be reduced

    3/26/2013 34

  • 3/26/2013

    18

    Simple Example Pitting Corrosion

    Here is an example of a pit measuring guage

    We move on to a new subject

    3/26/2013 35

    Out of Roundness - Peaking

    This is what is meant by peaking:

    The ends of the cylinder at straight instead of cylindrical

    Measure the peak height = 0,31 in

    We perform a Level 2 assessment

    3/26/2013 36

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    19

    Out of Roundness - Peaking

    Get all the data for this cylinder

    36 in

    0,31 in

    Do = 36 in cylinder outside diametertnom = 0,5 in wall thicknessP = 315 psi design pressureE = 1,0 joint efficiencyFCA = 0,05 in future corrosion allowanceEY = 25,2.10

    6 psi Elastic ModulusSa = 16 800 psi design stressHf = 3,0 factor for secondary stress from API 579

    0,5 in

    LOSS= 0 in metal lost so far

    3/26/2013 37

    Out of Roundness - Peaking

    Get all the data for this cylinder

    Do = 36 in cylinder outside diametertnom = 0,5 in wall thicknessP = 315 psi design pressureE = 1,0 joint efficiencyFCA = 0,05 in future corrosion allowanceEY = 25,2.10

    6 psi Elastic ModulusSa = 16 800 psi design stressHf = 3,0 factor for secondary stress from API 579

    LOSS= 0 in metal lost so far

    3/26/2013 38

    Wall thickness to be used in the assessment tc

    tc = tnom LOSS FCA = 0,5 0,0 0,05 = 0,45 in

    Get the current membrane stress from the Code m

    m = = = 12 474 psiP.(Ro- 0,4.tc)

    tc.E

    315(18 - 0,4.0,45)

    0,45.1,0

    R internal radius = Ro tnom + FCA + tc/2 = 17,775 in

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    20

    Out of Roundness - Peaking

    Induced extra bending stress ratio SP

    3/26/2013 39

    is Poissons Ratio = 0,3

    SP = ( )0,5 = ( )0,5

    12(1- 2)PR3

    EY.tc3

    12(1- 0,3 2)315.17,7753

    25,5.106.0,453

    = 2,88

    From SP and /R and Figure 8.13 to get Cf = 0,83

    Out of Roundness - Peaking

    Induced extra bending stress ratio SP

    3/26/2013 40

    is Poissons Ratio = 0,3

    SP = ( )0,5 = ( )0,5

    12(1- 2)PR3

    EY.tc3

    12(1- 0.3 2)315.17,7753

    25,5.106.0,453

    = 2,88

    From SP and /R and Figure 8.13 to get Cf = 0,83

    We need 3 other values: Rb1, Rb2 and Rbs the calculation is long

    Rb1 = 3,43, Rb2 =3,43 and Rbs= -1,0 (no calculation shown)

    Finally, compute the Remaining Strength Factor RSF

    Hf.Sa

    m.(1+Rb1)+LOSS(1+Rbs)RSF = min( ; 1,0)

    3,0.16 800

    12,474.(1+3,43)+0= min( ; 1,0 ) = 0,91

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    Out of Roundness - Peaking

    RSF = 0,91 from the previous slide

    3/26/2013 41

    RSF allowed = 0,90 API 579 requirement

    Conclusion: passed, cylinder can be put into service

    A word or two about grooves

    A groove can be thought of as a blunt crack in the vessel

    3/26/2013 42

    This can be analysed mathematically (modeled as) as a half ellipse

    The two important dimension are: crack length a, and tip radius r

    ar

    Adjacent to the edge of the crack, the stresses increase

    Sa

    Sc

    Sa is the average stress, and Sc is the increased stress

    Sa / Sc is known as the Stress Concentration Factor (scf)

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    A word or two about grooves

    A Cambridge researcher, Inglis did the mathematical work

    3/26/2013 43

    ar

    Sa

    Sc

    This is the equation he devised for the scf

    scf = 2 + arIf the crack tip has a very sharp radius, the scf if very high

    The stress can be in the Plastic range of the stress-strain diagram

    A word or two about grooves

    A Cambridge researcher, Inglis did the mathematical work

    3/26/2013 44

    This is the equation he devised for the scf

    scf = 2 + arIf the crack tip has a very sharp radius, the scf if very high

    The stress can be in the Plastic range of the stress-strain diagram

    strain

    stress

    elastic range

    plastic range

    Yield point

    0,2%

    This can be a source of fatigue problems

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    23

    A word or two about grooves

    A Cambridge researcher, Inglis did the mathematical work

    3/26/2013 45

    This is the equation he devised for the scf

    scf = 2 + arIf the crack tip has a very sharp radius, the scf if very high

    The stress can be in the Plastic range of the stress-strain diagram

    This can be a source of fatigue problems

    We have not analysed grooves and pitting

    This is the end of the presentation

    3/26/2013 46

    Thank you for watching this presentationAre there any questions