appendix a5: probability plots of heavy metals and trace

145
A5-1 Appendix A5: Probability Plots of Heavy Metals and Trace Constituents from Full-Scale Column Tests This appendix contains probability plots for the heavy metal, and trace constituent, influent and effluent values from the long-term, full-column tests. These plots were created using SigmaPlot as it was necessary to correctly plot data series having missing observations. Values less than the laboratory detection limit are not substituted on these plots. As an example, if only 30% of the samples had observed values, the probability plots started at the 70 th percentile. The concentrations were plotted using log 10 - transformed values as most of these constituents are likely log-normally distributed. As in AppendixA4, straight lines indicate good fits with normal distributions (but log-normal for these constituents), parallel plots indicate similar standard deviations, and well- separated plots indicated likely significant differences between influent and effluent concentrations. These plots are organized by each of the following 29 constituents: the observations for each media column test for each constituent. The order of the constituents is as follows (all have observations for total and filtered forms shown, except for mercury as only total mercury was evaluated): Antimony, total and filtered Arsenic, total and filtered Aluminum, total and filtered Boron, total and filtered Calcium, total and filtered Cadmium, total and filtered Copper, total and filtered Iron, total and filtered Magnesium, total and filtered Manganese, total and filtered Nickel, total and filtered Lead, total and filtered Mercury, total Thallium, total and filtered Zinc, total and filtered The order of the media column data, for each of the constituents, is as follows: Granular activated carbon (GAC) Peat moss (PM) Rhyolite sand ( R ) Site filter sand (S) Site zeolite (Z) Surface modified zeolite (SMZ)

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A5-1

Appendix A5: Probability Plots of Heavy Metals and Trace Constituents from Full-Scale Column Tests This appendix contains probability plots for the heavy metal, and trace constituent, influent and effluent values from the long-term, full-column tests. These plots were created using SigmaPlot as it was necessary to correctly plot data series having missing observations. Values less than the laboratory detection limit are not substituted on these plots. As an example, if only 30% of the samples had observed values, the probability plots started at the 70th percentile. The concentrations were plotted using log10-transformed values as most of these constituents are likely log-normally distributed. As in AppendixA4, straight lines indicate good fits with normal distributions (but log-normal for these constituents), parallel plots indicate similar standard deviations, and well-separated plots indicated likely significant differences between influent and effluent concentrations. These plots are organized by each of the following 29 constituents: the observations for each media column test for each constituent. The order of the constituents is as follows (all have observations for total and filtered forms shown, except for mercury as only total mercury was evaluated):

Antimony, total and filtered Arsenic, total and filtered Aluminum, total and filtered Boron, total and filtered Calcium, total and filtered Cadmium, total and filtered Copper, total and filtered Iron, total and filtered Magnesium, total and filtered Manganese, total and filtered Nickel, total and filtered Lead, total and filtered Mercury, total Thallium, total and filtered Zinc, total and filtered

The order of the media column data, for each of the constituents, is as follows:

Granular activated carbon (GAC) Peat moss (PM) Rhyolite sand ( R ) Site filter sand (S) Site zeolite (Z) Surface modified zeolite (SMZ)

A5-2

Mixed Rhyolite sand – surface modified zeolite (R-SMZ) Mixed Rhyolite sand – surface modified zeolite – granular activated carbon (R-SMZ-

GAC) Mixed Rhyolite sand – surface modified zeolite – granular activated carbon – peat

moss (R-SMZ-GAC-PM) Layered site filter sand – site zeolite – granular activated carbon (S-Z-GAC layered)

The locations of the major sections, by constituent, of Appendix A5 are: Antimony, Total .................................................................................................................. 4 

Antimony, Filtered .............................................................................................................. 9 

Arsenic, Total .................................................................................................................... 14 

Arsenic, Filtered ................................................................................................................ 19 

Aluminum, Total ............................................................................................................... 24 

Aluminum, Filtered ........................................................................................................... 29 

Boron, Total ...................................................................................................................... 34 

Boron, Filtered .................................................................................................................. 39 

Calcium, Total................................................................................................................... 44 

Calcium, Filtered............................................................................................................... 49 

Cadmium, Total ................................................................................................................ 54 

Cadmium, Filtered ............................................................................................................ 59 

Copper, Total .................................................................................................................... 64 

Copper, Filtered ................................................................................................................ 69 

Iron, Total ......................................................................................................................... 74 

Iron, Filtered ..................................................................................................................... 79 

Magnesium, Total ............................................................................................................. 84 

Magnesium, Filtered ......................................................................................................... 89 

Manganese, Total .............................................................................................................. 94 

Manganese, Filtered .......................................................................................................... 99 

Nickel, Total ................................................................................................................... 104 

Nickel, Filtered ............................................................................................................... 109 

Lead, Total ...................................................................................................................... 114 

Lead, Filtered .................................................................................................................. 119 

Mercury ........................................................................................................................... 124 

Thallium, Total ............................................................................................................... 126 

Thallium, Filtered ........................................................................................................... 131 

A5-3

Zinc, Total ....................................................................................................................... 136 

Zinc, Filtered ................................................................................................................... 141 

A5-4

Antimony, Total Total Antimony

Granular Activated Carbon (GAC)

Antimony, Total (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total AntimonyPeat Moss (P)

Antimony, Total (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-5

Total AntimonyRhyolite Sand (R)

Antimony, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total AntimonySite Sand (S)

Antimony, Total (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-6

Total AntimonySite Zeolite (Z)

Antimony, Total (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total AntimonySurface Modified Zeolite (SMZ)

Antimony, Total (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-7

Total AntimonyRhyolite Sand - Surface Modified Zeolite (R - SMZ)

Antimony, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total AntimonyRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Antimony, Total (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-8

Total AntimonyRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Antimony, Total (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total AntimonyLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Antimony, Total (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-9

Antimony, Filtered Dissolved Antimony

Granular Activated Carbon (GAC)

Antimony, Dissolved (g/L)

10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved AntimonyPeat Moss (P)

Antimony, Dissolved (g/L)

10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-10

Dissolved AntimonyRhyolite Sand (R)

Antimony, Dissolved (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved AntimonySite Sand (S)

Antimony, Dissolved (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-11

Dissolved AntimonySite Zeolite (Z)

Antimony, Dissolved (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved AntimonySurface Modified Zeolite (SMZ)

Antimony, Dissolved (g/L)

10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-12

Dissolved AntimonyRhyolite Sand - Surface Modified Zeolite (R - SMZ)

Antimony, Dissolved (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved AntimonyRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Antimony, Dissolved (g/L)

10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-13

Dissolved AntimonyRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Antimony, Dissolved (g/L)

10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved AntimonyLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Antimony, Dissolved (g/L)

10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-14

Arsenic, Total Total Arsenic

Granular Activated Carbon (GAC)

Arsenic, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total ArsenicPeat Moss (P)

Arsenic, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-15

Total Arsenic

Rhyolite Sand (R)

Arsenic, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total ArsenicSite Sand (S)

Arsenic, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-16

Total ArsenicSite Zeolite (Z)

Arsenic, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total ArsenicSurface Modified Zeolite (SMZ)

Arsenic, Total (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-17

Total Arsenic

Rhyolite Sand - Surface Modified Zeolite (R - SMZ)

Arsenic, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total ArsenicRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Arsenic, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-18

Total Arsenic

Rhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Arsenic, Total (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total ArsenicLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Arsenic, Total (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-19

Arsenic, Filtered Dissolved Arsenic

Granular Activated Carbon (GAC)

Arsenic, Dissolved (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved ArsenicPeat Moss (P)

Arsenic, Dissolved (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-20

Dissolved Arsenic

Rhyolite Sand (R)

Arsenic, Dissolved (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved ArsenicSite Sand (S)

Arsenic, Dissolved (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-21

Dissolved Arsenic

Site Zeolite (Z)

Arsenic, Dissolved (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved ArsenicSurface Modified Zeolite (SMZ)

Arsenic, Dissolved (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-22

Dissolved Arsenic

Rhyolite Sand - Surface Modified Zeolite (R - SMZ)

Arsenic, Dissolved (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved ArsenicRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Arsenic, Dissolved (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-23

Dissolved Arsenic

Rhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Arsenic, Dissolved (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved ArsenicLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Arsenic, Dissolved (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-24

Aluminum, Total Total Aluminum

Granular Activated Carbon (GAC)

Aluminum, Total (g/L)

1e+1 1e+2 1e+3 1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total AluminumPeat Moss (P)

Aluminum, Total (g/L)

1e+2 1e+3 1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-25

Total AluminumRhyolite Sand (R)

Aluminum, Total (g/L)

1e+1 1e+2 1e+3 1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total AluminumSite Sand (S)

Aluminum, Total (g/L)

1e+2 1e+3 1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-26

Total Aluminum

Site Zeolite (Z)

Aluminum, Total (g/L)

1e+1 1e+2 1e+3 1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total AluminumSurface Modified Zeolite (SMZ)

Aluminum, Total (g/L)

1e+2 1e+3 1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-27

Total Aluminum

Rhyolite Sand - Surface Modified Zeolite (R - SMZ)

Aluminum, Total (g/L)

1e+2 1e+3 1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total AluminumRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Aluminum, Total (g/L)

1e+1 1e+2 1e+3 1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-28

Total Aluminum

Rhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Aluminum, Total (g/L)

1e+2 1e+3 1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total AluminumLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Aluminum, Total (g/L)

1e+1 1e+2 1e+3 1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-29

Aluminum, Filtered Dissolved Aluminum

Granular Activated Carbon (GAC)

Aluminum, Dissolved (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved AluminumPeat Moss (P)

Aluminum, Dissolved (g/L)

10 100 1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-30

Dissolved Aluminum

Rhyolite Sand (R)

Aluminum, Dissolved (g/L)

10 100 1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved AluminumSite Sand (S)

Aluminum, Dissolved (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-31

Dissolved Aluminum

Site Zeolite (Z)

Aluminum, Dissolved (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved AluminumSurface Modified Zeolite (SMZ)

Aluminum, Dissolved (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-32

Dissolved Aluminum

Rhyolite Sand - Surface Modified Zeolite (R - SMZ)

Aluminum, Dissolved (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved AluminumRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Aluminum, Dissolved (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-33

Dissolved Aluminum

Rhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Aluminum, Dissolved (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved AluminumLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Aluminum, Dissolved (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-34

Boron, Total Total Boron

Granular Activated Carbon (GAC)

Boron, Total (g/L)

100 1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total BoronPeat Moss (P)

Boron, Total (g/L)

100 1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-35

Total Boron

Rhyolite Sand (R)

Boron, Total (g/L)

100 1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total BoronSite Sand (S)

Boron, Total (g/L)

100 1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-36

Total Boron

Site Zeolite (Z)

Boron, Total (g/L)

100 1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total BoronSurface Modified Zeolite (SMZ)

Boron, Total (g/L)

100 1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-37

Total Boron

Rhyolite Sand - Surface Modified Zeolite (R - SMZ)

Boron, Total (g/L)

100 1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total BoronRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Boron, Total (g/L)

100 1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-38

Total Boron

Rhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Boron, Total (g/L)

100 1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total BoronLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Boron, Total (g/L)

100 1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-39

Boron, Filtered Dissolved Boron

Granular Activated Carbon (GAC)

Boron, Dissolved (g/L)

100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved BoronPeat Moss (P)

Boron, Dissolved (g/L)

100 1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-40

Dissolved BoronRhyolite Sand (R)

Boron, Dissolved (g/L)

100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved BoronSite Sand (S)

Boron, Dissolved (g/L)

100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-41

Dissolved Boron

Site Zeolite (Z)

Boron, Dissolved (g/L)

100 1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

c

Dissolved BoronSurface Modified Zeolite (SMZ)

Boron, Dissolved (g/L)

100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-42

Dissolved Boron

Rhyolite Sand - Surface Modified Zeolite (R - SMZ)

Boron, Dissolved (g/L)

100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved BoronRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Boron, Dissolved (g/L)

100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-43

Dissolved Boron

Rhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Boron, Dissolved (g/L)

100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved BoronLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Boron, Dissolved (g/L)

100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-44

Calcium, Total Total Calcium

Granular Activated Carbon (GAC)

Calcium, Total (g/L)

1e+3 1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total CalciumPeat Moss (P)

Calcium, Total (g/L)

1e+3 1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-45

Total Calcium

Rhyolite Sand (R)

Calcium, Total (g/L)

1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total CalciumSite Sand (S)

Calcium, Total (g/L)

1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-46

Total CalciumSite Zeolite (Z)

Calcium, Total (g/L)

1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total CalciumSurface Modified Zeolite (SMZ)

Calcium, Total (g/L)

1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-47

Total Calcium

Rhyolite Sand - Surface Modified Zeolite (R - SMZ)

Calcium, Total (g/L)

1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total CalciumRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Calcium, Total (g/L)

1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-48

Total Calcium

Rhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Calcium, Total (g/L)

1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total CalciumLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Calcium, Total (g/L)

1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-49

Calcium, Filtered Dissolved Calcium

Granular Activated Carbon (GAC)

Calcium, Dissolved (g/L)

1e+3 1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved CalciumPeat Moss (P)

Calcium, Dissolved (g/L)

1e+3 1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-50

Dissolved Calcium

Rhyolite Sand (R)

Calcium, Dissolved (g/L)

1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved CalciumSite Sand (S)

Calcium, Dissolved (g/L)

1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-51

Dissolved Calcium

Site Zeolite (Z)

Calcium, Dissolved (g/L)

1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved CalciumSurface Modified Zeolite (SMZ)

Calcium, Dissolved (g/L)

1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-52

Dissolved Calcium

Rhyolite Sand - Surface Modified Zeolite (R - SMZ)

Calcium, Dissolved (g/L)

1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved CalciumRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Calcium, Dissolved (g/L)

1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-53

Dissolved Calcium

Rhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Calcium, Dissolved (g/L)

1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved CalciumLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Calcium, Dissolved (g/L)

1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-54

Cadmium, Total Total Cadmium

Granular Activated Carbon (GAC)

Cadmium, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total CadmiumPeat Moss (P)

Cadmium, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-55

Total CadmiumRhyolite Sand (R)

Cadmium, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total CadmiumSite Sand (S)

Cadmium, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-56

Total Cadmium

Site Zeolite (Z)

Cadmium, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total CadmiumSurface Modified Zeolite (SMZ)

Cadmium, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-57

Total Cadmium

Rhyolite Sand - Surface Modified Zeolite (R - SMZ)

Cadmium, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total CadmiumRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Cadmium, Total (g/L)

0.1 1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-58

Total Cadmium

Rhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Cadmium, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total CadmiumLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Cadmium, Total (g/L)

0.1 1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-59

Cadmium, Filtered Dissolved Cadmium

Granular Activated Carbon (GAC)

Cadmium, Dissolved (g/L)

0.1 1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved CadmiumPeat Moss (P)

Cadmium, Dissolved (g/L)

0.1 1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-60

Dissolved Cadmium

Rhyolite Sand (R)

Cadmium, Dissolved (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved CadmiumSite Sand (S)

Cadmium, Dissolved (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-61

Dissolved Cadmium

Site Zeolite (Z)

Cadmium, Dissolved (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved CadmiumSurface Modified Zeolite (SMZ)

Cadmium, Dissolved (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-62

Dissolved Cadmium

Rhyolite Sand - Surface Modified Zeolite (R - SMZ)

Cadmium, Dissolved (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved CadmiumRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Cadmium, Dissolved (g/L)

0.1 1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-63

Dissolved Cadmium

Rhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Cadmium, Dissolved (g/L)

0.1 1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved CadmiumLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Cadmium, Dissolved (g/L)

0.1 1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-64

Copper, Total Total Copper

Granular Activated Carbon (GAC)

Copper, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total CopperPeat Moss (P)

Copper, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-65

Total Copper

Rhyolite Sand (R)

Copper, Total (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total CopperSite Sand (S)

Copper, Total (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-66

Total CopperSite Zeolite (Z)

Copper, Total (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total CopperSurface Modified Zeolite (SMZ)

Copper, Total (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-67

Total Copper

Rhyolite Sand - Surface Modified Zeolite (R - SMZ)

Copper, Total (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total CopperRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Copper, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-68

Total Copper

Rhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Copper, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total CopperLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Copper, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-69

Copper, Filtered Dissolved Copper

Granular Activated Carbon (GAC)

Copper, Dissolved (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved CopperPeat Moss (P)

Copper, Dissolved (g/L)

10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-70

Dissolved Copper

Rhyolite Sand (R)

Copper, Dissolved (g/L)

10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved CopperSite Sand (S)

Copper, Dissolved (g/L)

10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-71

Dissolved Copper

Site Zeolite (Z)

Copper, Dissolved (g/L)

10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved CopperSurface Modified Zeolite (SMZ)

Copper, Dissolved (g/L)

10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-72

Dissolved Copper

Rhyolite Sand - Surface Modified Zeolite (R - SMZ)

Copper, Dissolved (g/L)

10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved CopperRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Copper, Dissolved (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-73

Dissolved Copper

Rhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Copper, Dissolved (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved CopperLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Copper, Dissolved (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-74

Iron, Total Total Iron

Granular Activated Carbon (GAC)

Iron, Total (g/L)

1e+1 1e+2 1e+3 1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total IronPeat Moss (P)

Iron, Total (g/L)

1e+1 1e+2 1e+3 1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-75

Total Iron

Rhyolite Sand (R)

Iron, Total (g/L)

1e+1 1e+2 1e+3 1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total IronSite Sand (S)

Iron, Total (g/L)

100 1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-76

Total Iron

Site Zeolite (Z)

Iron, Total (g/L)

1e+1 1e+2 1e+3 1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total IronSurface Modified Zeolite (SMZ)

Iron, Total (g/L)

1e+1 1e+2 1e+3 1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-77

Total Iron

Rhyolite Sand - Surface Modified Zeolite (R - SMZ)

Iron, Total (g/L)

1e+2 1e+3 1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total IronRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Iron, Total (g/L)

1e+1 1e+2 1e+3 1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-78

Total Iron

Rhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Iron, Total (g/L)

1e+1 1e+2 1e+3 1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total IronLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Iron, Total (g/L)

1e+0 1e+1 1e+2 1e+3 1e+4 1e+5

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-79

Iron, Filtered Dissolved Iron

Granular Activated Carbon (GAC)

Iron, Dissolved (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved IronPeat Moss (P)

Iron, Dissolved (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-80

Dissolved IronRhyolite Sand (R)

Iron, Dissolved (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved IronSite Sand (S)

Iron, Dissolved (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-81

Dissolved IronSite Zeolite (Z)

Iron, Dissolved (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved IronSurface Modified Zeolite (SMZ)

Iron, Dissolved (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-82

Dissolved Iron

Rhyolite Sand - Surface Modified Zeolite (R - SMZ)

Iron, Dissolved (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved IronRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Iron, Dissolved (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-83

Dissolved Iron

Rhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Iron, Dissolved (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved IronLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Iron, Dissolved (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-84

Magnesium, Total Total Magnesium

Granular Activated Carbon (GAC)

Magnesium, Total (g/L)

1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total MagnesiumPeat Moss (P)

Magnesium, Total (g/L)

1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-85

Total MagnesiumRhyolite Sand (R)

Magnesium, Total (g/L)

1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total MagnesiumSite Sand (S)

Magnesium, Total (g/L)

1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-86

Total Magnesium

Site Zeolite (Z)

Magnesium, Total (g/L)

100 1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total MagnesiumSurface Modified Zeolite (SMZ)

Magnesium, Total (g/L)

1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-87

Total Magnesium

Rhyolite Sand - Surface Modified Zeolite (R - SMZ)

Magnesium, Total (g/L)

1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total MagnesiumRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Magnesium, Total (g/L)

1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-88

Total Magnesium

Rhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Magnesium, Total (g/L)

1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total MagnesiumLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Magnesium, Total (g/L)

1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-89

Magnesium, Filtered Dissolved Magnesium

Granular Activated Carbon (GAC)

Magnesium, Dissolved (g/L)

1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved MagnesiumPeat Moss (P)

Magnesium, Dissolved (g/L)

1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-90

Dissolved Magnesium

Rhyolite Sand (R)

Magnesium, Dissolved (g/L)

1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved MagnesiumSite Sand (S)

Magnesium, Dissolved (g/L)

1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-91

Dissolved Magnesium

Site Zeolite (Z)

Magnesium, Dissolved (g/L)

100 1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved MagnesiumSurface Modified Zeolite (SMZ)

Magnesium, Dissolved (g/L)

1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-92

Dissolved Magnesium

Rhyolite Sand - Surface Modified Zeolite (R - SMZ)

Magnesium, Dissolved (g/L)

1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved MagnesiumRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Magnesium, Dissolved (g/L)

1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-93

Dissolved Magnesium

Rhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Magnesium, Dissolved (g/L)

1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved MagnesiumLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Magnesium, Dissolved (g/L)

1000 10000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-94

Manganese, Total Total Manganess

Granular Activated Carbon (GAC)

Manganese, Total (g/L)

0.1 1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total ManganesePeat Moss (P)

Manganese, Total (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-95

Total ManganeseRhyolite Sand (R)

Manganese, Total (g/L)

0.1 1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total ManganeseSite Sand (S)

Manganese, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-96

Total Manganese

Site Zeolite (Z)

Manganese, Total (g/L)

0.1 1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total ManganeseSurface Modified Zeolite (SMZ)

Manganese, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-97

Total Manganese

Rhyolite Sand - Surface Modified Zeolite (R - SMZ)

Manganese, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total ManganeseRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Manganese, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-98

Total Manganese

Rhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Manganese, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Total ManganeseLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Manganese, Total (g/L)

0.1 1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-99

Manganese, Filtered Dissolved Manganese

Granular Activated Carbon (GAC)

Manganese, Dissolved (g/L)

0.1 1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved ManganesePeat Moss (P)

Manganese, Dissolved (g/L)

0.1 1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-100

Dissolved Manganese

Rhyolite Sand (R)

Manganese, Dissolved (g/L)

0.1 1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved ManganeseSite Sand (S)

Manganese, Dissolved (g/L)

0.1 1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-101

Dissolved Manganese

Site Zeolite (Z)

Manganese, Dissolved (g/L)

0.1 1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved ManganeseSurface Modified Zeolite (SMZ)

Manganese, Dissolved (g/L)

0.1 1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-102

Dissolved Manganese

Rhyolite Sand - Surface Modified Zeolite (R - SMZ)

Manganese, Dissolved (g/L)

0.1 1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved ManganeseRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Manganese, Dissolved (g/L)

0.1 1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-103

Dissolved Manganese

Rhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Manganese, Dissolved (g/L)

0.1 1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved ManganeseLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Manganese, Dissolved (g/L)

0.1 1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-104

Nickel, Total Total Nickel

Granular Activated Carbon (GAC)

Nickel, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total NickelPeat Moss (P)

Nickel, Total (g/L)

0.1 1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-105

Total Nickel

Rhyolite Sand (R)

Nickel, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total NickelSite Sand (S)

Nickel, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-106

Total NickelSite Zeolite (Z)

Nickel, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total NickelSurface Modified Zeolite (SMZ)

Nickel, Total (g/L)

0.1 1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-107

Total Nickel

Rhyolite Sand - Surface Modified Zeolite (R - SMZ)

Nickel, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total NickelRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Nickel, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-108

Total Nickel

Rhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Nickel, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total NickelLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Nickel, Total (g/L)

0.1 1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-109

Nickel, Filtered Dissolved Nickel

Granular Activated Carbon (GAC)

Nickel, Dissolved (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved NickelPeat Moss (P)

Nickel, Dissolved (g/L)

0.1 1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-110

Dissolved NickelRhyolite Sand (R)

Nickel, Dissolved (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved NickelSite Sand (S)

Nickel, Dissolved (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-111

Dissolved Nickel

Site Zeolite (Z)

Nickel, Dissolved (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved NickelSurface Modified Zeolite (SMZ)

Nickel, Dissolved (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-112

Dissolved Nickel

Rhyolite Sand - Surface Modified Zeolite (R - SMZ)

Nickel, Dissolved (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved NickelRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Nickel, Dissolved (g/L)

0.1 1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-113

Dissolved Nickel

Rhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Nickel, Dissolved (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved NickelLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Nickel, Dissolved (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-114

Lead, Total Total Lead

Granular Activated Carbon (GAC)

Lead, Total (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total LeadPeat Moss (P)

Lead, Total (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-115

Total Lead

Rhyolite Sand (R)

Lead, Total (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total LeadlSite Sand (S)

Lead, Total (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-116

Total Lead

Site Zeolite (Z)

Lead, Total (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total LeadSurface Modified Zeolite (SMZ)

Lead, Total (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-117

Total Lead

Rhyolite Sand - Surface Modified Zeolite (R - SMZ)

Lead, Total (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total LeadRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Lead, Total (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-118

Total Lead

Rhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Lead, Total (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total LeadLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Lead, Total (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-119

Lead, Filtered Dissolved Lead

Granular Activated Carbon (GAC)

Lead, Dissolved (g/L)

1 10

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved LeadPeat Moss (P)

Lead, Dissolved (g/L)

1 10

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-120

Dissolved LeadRhyolite Sand (R)

Lead, Dissolved (g/L)

1 10

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved LeadSite Sand (S)

Lead, Dissolved (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-121

Dissolved Lead

Site Zeolite (Z)

Lead, Dissolved (g/L)

1 10

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved LeadSurface Modified Zeolite (SMZ)

Lead, Dissolved (g/L)

1 10

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-122

Dissolved Lead

Rhyolite Sand - Surface Modified Zeolite (R - SMZ)

Lead, Dissolved (g/L)

1 10

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved LeadRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Lead, Dissolved (g/L)

1 10

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-123

Dissolved Lead

Rhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Lead, Dissolved (g/L)

1 10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved LeadLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Lead, Dissolved (g/L)

1 10

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-124

Mercury

MercuryRhyolite Sand - Surface Modified Zeolite (R - SMZ)

Mercury (g/L)

0.01 0.1 1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

MercuryRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Mercury (g/L)

0.01 0.1 1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-125

Mercury

Rhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P

Mercury (g/L)

0.01 0.1 1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

MercuryLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Mercury (g/L)

0.01 0.1 1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-126

Thallium, Total Total Thallium

Granular Activated Carbon (GAC)

Thallium, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total ThalliumPeat Moss (P)

Thallium, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-127

Total ThalliumRhyolite Sand (R)

Thallium, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total ThalliumSite Sand (S)

Thallium, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-128

Total ThalliumSite Zeolite (Z)

Thallium, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total ThalliumSurface Modified Zeolite (SMZ)

Thallium, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-129

Total ThalliumRhyolite Sand - Surface Modified Zeolite (R - SMZ)

Thallium, Total (g/L)

0.1 1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total ThalliumRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Thallium, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-130

Total ThalliumRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Thallium, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total ThalliumLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Thallium, Total (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-131

Thallium, Filtered Dissolved Thallium

Granular Activated Carbon (GAC)

Thallium, Dissolved (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved ThalliumPeat Moss (P)

Thallium, Dissolved (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-132

Dissolved Thallium

Rhyolite Sand (R)

Thallium, Dissolved (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved ThalliumSite Sand (S)

Thallium, Dissolved (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-133

Dissolved ThalliumSite Zeolite (Z)

Thallium, Dissolved (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved ThalliumSurface Modified Zeolite (SMZ)

Thallium, Dissolved (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-134

Dissolved ThalliumRhyolite Sand - Surface Modified Zeolite (R - SMZ)

Thallium, Dissolved (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved ThalliumRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Thallium, Dissolved (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-135

Dissolved ThalliumRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Thallium, Dissolved (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved ThalliumLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Thallium, Dissolved (g/L)

1 10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-136

Zinc, Total

Total ZincGranular Activated Carbon (GAC)

Zinc, Total (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total Zinc

Peat Moss (P)

Zinc, Total (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-137

Total ZincRhyolite Sand (R)

Zinc, Total (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total ZincSite Sand (S)

Zinc, Total (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-138

Total ZincSite Zeolite (Z)

Zinc, Total (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total ZincSurface Modified Zeolite (SMZ)

Zinc, Total (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-139

Total ZincRhyolite Sand - Surface Modified Zeolite (R - SMZ)

Zinc, Total (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total ZincRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Zinc, Total (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-140

Total ZincRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Zinc, Total (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

Total ZincLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Zinc, Total (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluentPermit Limit

A5-141

Zinc, Filtered Dissolved Zinc

Granular Activated Carbon (GAC)

Zinc, Dissolved (g/L)

10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved ZincPeat Moss (P)

Zinc, Dissolved (g/L)

10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-142

Dissolved ZincRhyolite Sand (R)

Zinc, Dissolved (g/L)

10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved ZincSite Sand (S)

Zinc, Dissolved (g/L)

10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-143

Dissolved ZincSite Zeolite (Z)

Zinc, Dissolved (g/L)

10 100 1000

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved ZincSurface Modified Zeolite (SMZ)

Zinc, Dissolved (g/L)

10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-144

Dissolved ZincRhyolite Sand - Surface Modified Zeolite (R - SMZ)

Zinc, Dissolved (g/L)

10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved ZincRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon (R - SMZ - G) Mixed Media

Zinc, Dissolved (g/L)

10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

A5-145

Dissolved ZincRhyolite Sand - Surface Modified Zeolite - Granular Activated Carbon - Peat Moss (R - SMZ - G - P)

Zinc, Dissolved (g/L)

10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent

Dissolved ZincLayered Site Sand - Site Zeolite - Granular Activated Carbon (SZG)

Zinc, Dissolved (g/L)

10 100

0.01

0.1

1

10

30

50

70

90

99

99.9

99.99InfluentEffluent