aquatic sediments
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Aquatic SedimentsAuthor(s): C. F. Powers, W. D. Sanville and F. S. StaySource: Journal (Water Pollution Control Federation), Vol. 48, No. 6, 1976: Literature Review(Jun., 1976), pp. 1433-1439Published by: Water Environment FederationStable URL: http://www.jstor.org/stable/25039038 .Accessed: 03/11/2013 16:59
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Literature Review
Sewage, Bay Park, N. Y. Jour. Research,U. S. Geol Surv., 3, 93 (1975).
116. Ragone, S. E, and Vecchioli, J, Chemical
Interaction during Deep Well Recharge,
Bay Park, New York. Groundwater, 13,17
(1975).117. Wellings, F. M, et al, Pathogenic VirusesMay Thwart Land Disposal. Water ir
Wastes Eng., 12, 3, 70 ( 1975).118. Bader, J. S, d al, Selected References on
Ground-Water Contamination, the United
States of America and Puerto Rico. Listed
in New Publications of the Geological Sur
vey, List 799, U. S. Dept. of the Interior,
Geological Survey (1975).119. Fields, T, Jr., and Lindsey, A. W, Landfill
Disposal of Hazardous Wastes: A Review
of Literature and Known Approaches.
U. S. EPA Rept. No. SW-165 (1975).120. Ground Water Pollution from Subsurface
Excavations : Part XL Water Well Jour.,
22,2,37(1975).'
121. Needle, B, and Garland, G, Dumps: A
Potential Threat to Ground Water Sup
plies. Water Well Jour, 22, 1 (1975).122. Behnke, J, A Summary of the Biogeochem
istry of Nitrogen Compounds in Ground
Water. Jour. HydroL, 27, 155 (1975).123. McNabb, J. F, and Dunlap, W. J, Subsur
face Biological Activity in Relation toGround-Water Pollution. Groundwater,
13,33 (1975).124. Allen, M. J, and Geldreich, E. E, Bacterio
logical Criteria for Ground-Water Quality.
Groundwater, 13, 45 (1975).125. Farquhar, G. J, and Rovers, F. A, Guide
lines to Landfill Location and Managementfor Water Pollution Control. SanitaryLandfill Study, Final Report, Vol. IV,Office of Research Administration, Project
#8083-4, Univ. of Waterloo (1975).126. Walker, W. R, and Cox, W. E, Private
Contraints on Ground-Water Contamina
tion. Jour. Hyd. Div., Proc. Amer. Soc.Civil Engr., 101 (HY10), 1333 (1975).
127. H?tes, F. L, Subsurface Environment?Pri
vate Property or Public Domain? by W.
R. Walker and W. E. Cox (Nov. 1975).Jour. Hyd. Div., Proc. Amer. Soc. Civil
Engr., 101 (HY10), 1365 (1975).128. Kaufman, M. I, and McKenzie, D. J, Up
ward Migration of Deep-Well Waste In
jection Fluids in Floridan Aquifer, SouthFlorida. Jour. Res., U. S. Geol. Surv., 3,261 (1975).
129.Faulkner,
G.L,
andPascale, C. A,
Moni
toring Regional Effects of High PressureInjection of Industrial Waste Water in a
Limestone Aquifer. Groundwater, 13,197 (1975).
130. Conrad, E. T, and Hopson, N. E, Outlooksfor the Future of Deep Well Disposal.
Water Resources Bull, 11, 370 (1975).
131. Forrestal, L, Deep Mystery. Environ
ment, 17,8,25 (1975).132. Cherry, J. A, et al., Contaminant Hydro
geology, Part 1 Physical Processes. Geo
science Canada, 2, 2, 76 (1975).133.
Wang,M.
S,and
Cheng,R.
T,A
Studyof Convective-Dispersion Equation by
Isoparametric Finite Elements. Jour. Hy
drol.,24, 1/2,45 (1975).134. Schwartz, F. W, On Radioactive Waste
Management: An Analysis of the Parameters Controlling Subsurface Contaminant
Transfer. Jour. HydroL, 27, 1/2, 33
(1975).135. Farquhar, G. J, and Seitz, W. J, A Map
ping Technique for Landfill Location.Sanitary Landfill Study Final Report Vol.Ill, Office of Research Administration,
Univ. of Waterloo, Project No. 8083-4,(1975).
136. Bovey, R. W, et al, Occurrence of 2,4,5-Tand Picloram in Subsurface Water in theBlacklands of Texas. Jour. Environ.
Qual., 4, 1, 103 (1975).137. LaFleur, K. S, Movement of Prometryne
through Congaree Soil into Ground Water. Jour. Environ. Qual, 4, 1, 132
(1975).138. Moon, K. A, Municipal Waste Disposal and
Ground-Water Pollution. MassachusettsAudubon Society, Lincoln, Mass. (1975).
139. Rajagopal, R, et al., Water Quality andEconomic Criteria for Rural Wastewaterand Water Supply Systems. Jour. Water
Poll. Control Fed., 47, 1834 (1975).140. Smith, S. O, and Myott, D. H, Effect of
Cesspool Discharge on Ground-Water
Quality on Long Island, New York. Jour.Amer. Water Works Assn., 67, 456 (1975).
141. Sherrill, M. G, Ground-Water Contamination in the Silurian Dolomite of Door
County, Wisconsin. Groundwater, 13,209 (1975).
Aquatic sediments
C. F. Powers, W. D. Sanvtlle, and F. S.
Stay, Corvallis Environmental Research
Laboratory, EPA, Corvallis, Ore.
Sediment-Water Interactions
Exchangeof materials between sediment
and water and the relative importance ofthe sediments as a nutrient source were
investigated in several laboratory and fieldstudies. Bannerman et al.1 carried out
laboratory experiments on the mobility of
inorganic phosphorus in Lake Ontario
-Vol. 48, No. 6, June 1976 1433
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Literature Review
sediments using cores from 15 locations.
Based on the flux range obtained, the an
nual contribution of inorganic phosphorusfrom the sediments to the lake water was
estimated at about 10percent
of the ex
ternal loading. Fillos and Swanson2 con
ducted long-term experiments in laboratoryreactors on nutrient release rates from lake
and river sediments. Emphasis was on
orthophosphat?, but oxygen uptake andammonia and iron release rates were also
measured.
Sagher et al.3 evaluated the microbial
availability of phosphorus from surficialsediments using algae and indigenous sedi
ment populations as test organisms. Algalcell counts, ATP measurements, and threedifferent phosphorus extractions providedinformation on the utilization of differentsediment phosphate forms. Hydraulic
dredging in Lake Herman, South Dakota,was monitored by Churchill et al.4 In
creased total phosphorus was the only significant change in water quality, but thiscould not positively be attributed to dredging. Phosphorus content of return flowfrom dredged material deposited near thelake was less than that of the lake waterat the dredging site.
Lerman and Lietzke 5used 90Sr and 137Csconcentrations in Lakes Erie and Ontarioto verify a theoretical model of the rela
tionship between the concentration of dissolved chemical species in a lake and uptake by the sediment. They concluded
that adsorption of the two tracers by sediment particles could be treated as a linear
exchange reaction and that distributionof radionuclides in the sediments could bebased on a model which assumed a mean
steady input for the years 1953-1969. Copper cycling in a shallow, soft-water eutro
phic lake treated since the early 1960's with
copper sulfate was investigated bySymmes.6 The results indicated that ap
proximately96
percentof the
copperre
mained in the sediments.
Sampling and Analytical Methods
Sasseville et al.7 described a light weight,portable, large-volume, interstitial water
squeezer. All components in contact with
the sample were coated to prevent metallic
contamination; exposure to air was mini
mal. A large-volume shallow water corer
for quantitative sampling of benthic populations in various substrate
typeswas de
signed and evaluated by Thayer et al.8
Density of organisms was greater and co
efficient of variation less than for a van
Veen sampler; this was attributed to the
increased depth obtained by the corer. Astream gravel sampler developed by O'Con
nor 9 collected less biomass than colonization cans but more than a Surber sampler.In addition, it was capable of obtainingstratified samples 60 cm into the substrate.
In an evaluation of sedimentation traps,Kirchner10 concluded that collection of
material on a unit- area basis was independent of trap aperture size. With the
exception of shallow and unstratified lakes,he also found traps to be a dependable
method for estimating sedimentation.A high-resolution, lithium-compensated
germanium detector was used in a prototype device by Moxham et al.11 to perform
in situ neutron activation analyses of sediments. Differences in neutron flux densitybetween saturated and dry materials were
attributed to the water content of the sam
ple. In a comparison of three different
extraction procedures for mercury in sedi
ments, Agemian et al.12 found that thesulfuric-nitric acid and hydrochloric-nitricacid methods yielded similar precision and
results, whereas the hydrofluoric acid-aqua
regia method was less precise and gavehigher values. A method for determination of mercury in sediments by automatedcold vapor atomic absorption was devel
oped by Agemian and Chau.13 The systemcould be used for analysis of twenty
samples per hour with a sensitivity of 10
ppb Hg.McQuaker and Fung14 developed a re
ductive pyrolysis-flame ionization tech
niquefor the determination of total and
organic carbon in sediments. Analysistime was less than five minutes and the use
of a single suspension permitted direct
comparison of total carbon, organic carbon,and carbohydrate concentrations. Recov
ery of petroleum hydrocarbons by the
1434 Journal WPCF
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Literature Review
hexane, benzene, and chloroform extraction methods was compared on estuarinewater and sediments by Walker et al.15
Reciprocal shaking with benzene as a solvent
providedthe most efficient extraction.
Chemical-Physical Characterization
The distribution of nutrients and humicmaterials in water and sediments has been
investigated. Hwang et al.16 determinedthe distribution of total, inorganic, and or
ganic phosphorus in various size fractionsof lake sediments. The three forms ex
hibited a bimodal distribution with the
greatest concentrations in the >20/x and
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Literature Review
Water and sediment samples were collected from an 80 km course of the Ten
nessee River by Perhac.28 Results sug
gested that upstream heavy metals were
dissolved fromcarbonates, transported
downstream, and incorporated into the
clayey sediments behind a dam.Steele and Wagner,29 in a survey of the
sediments on a 130 mile section of theBuffalo River in northern Arkansas, foundthat Fe, Cu, Cr, Ni, Mn, Pb, K, and Nadecreased downstream as the drainage area
increased in carbonate rock and decreasedin shale. Sediments downstream increasedin Mg, Ca, Zn, and Cd. The distribution
of As, Sb, Hg, Cr., Co, Fe, Al, and C insurface sediments of Puget Sound were
examined by Crecelius et al.30 A coppersmelter and a chlor-alkali plant were two
major sources of As, Sb, and Hg contamination. No elevated concentrations of theother elements measured could be attributed to inputs by man. Most of the mer
cury found in both contaminated and non
contaminated sediments was associated
with easily oxidizable organic matter.Walters et al.31 determined the occurrence
of ten trace metals and minor elements insediment cores from Lake Erie. Significantenrichment for most metals was found
within the upper 30 cm of sediment but inabout half the cores the heavy metal content decreased in the top interval. Instudies of plutonium cycling and sedimentation in Lake Michigan, Wahlgren and
Nelson32 found that the major fraction of239Pu and 137Cs fallout inputs had been
rapidly transported to the sediments. Theresidual fractions in the water column
were generally homogeneously distributed
throughout the lake in particle size fractions
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Literature Review
international conference on the transportof persistent chemicals in the aquatic en
vironment, with emphasis on heavy metalsand pesticides. Topics covered includedbed sediment
transport,sediment-water
interchange, chemical transformations, bio
logical uptake, and distribution of thesesubstances.
Subjects relating to sedimentation processes in lakes received attention from a
number of investigators. Robbins and
Edgington42 used 210Pb and 137Cs measure
ments to determine the rate of sedimentation in Lake Michigan. Analysis of coresfrom eight locations indicated that modernsedimentation rates differed little from av
erage rates for the last 7,000 years. Armentano and Woodwell43 used the 210Pb
method to determine sedimentation ratesin a Long Island marsh. Wolery and
Walters 44 developed a model to describemodern sedimentation rates for westernLake Erie using strata containing highmercury concentrations. Two geographical areas where the most mercury would
likely be released were identified by themodel for remedial action. Chemical
analysis by Bortleson and Lee45 on sediment cores from Lake Monona, Wisconsin,demonstrated definite changes in chemical
stratigraphy related to human settlementof the area. Increases in P, Fe, Mn, Al,and K were shown to have occurred in the
uppermost sediments since the mid- to late1800's.
Cranwell,46 in studies on six English lakesof various trophic states, examined the re
lationship of the composition of sedimen
tary fatty acids to environmental factors.The distribution in chain length of then-alkanoic acids was shown to indicate therelative contribution of terrestrial andautochthonous organic matter to sediment.
Pigment analyses carried out by Gorhamand Wright47 on profundal surface sedi
ments in Minnesota lakes demonstratedthat sedimentary organic matter was derived mainly from autochthonous mate
rials, and that rising concentrations of fossil
pigments clearly indicate the onset of cultural euthrophication. Banin et al.48 foundthat clay minerals were responsible for 98
99 percent of the specific surface area ofLake Kinneret, Israel, sediments. Althoughthe carbonate fraction constituted abouthalf of the sediment by weight, it represented less than one-half of one
percentof
the specific surface area.
Biological Considerations
Kuznetsov49 noted a major parallel between soils and lake sediments in the roleof microorganisms in the mineralization of
organic materials, although the typicalhorizons of terrestrial soils do not occur in
aquatic sediments. He discussed differ
ences between sediments found in eutrophic and oligotrophic lakes, the role of bacteria in the carbonate cycle, the formationof iron-manganese deposits, and the silica
cycle. Grimes50 showed that fecal coliform concentrations increased significantlyin the immediate vicinity of a maintenance
dredging operation in the MississippiRiver. The increase was attributed to re
lease of sediment-bound bacteria by the
disturbance and relocation of sediments.Biochemical reactions involved in the de
composition of organic matter in sedimentsof a facultative oxidation pond were in
vestigated by Brockett and Orchard.51
Deep ponds appeared to promote biochemical activity closely associated with an
aerobic conditions, resulting in a more
efficient production of methane. From
laboratory studies of biologically-inducedtransformations of
clay-sized sediments,Wall et al.52 concluded that an environment with a high microbial population,
carbonate substrate, and anaerobic condi
tions was most conducive to biologicaldegradation of sediment. The vertical distribution of adenosine triphosphate (ATP)
was determined seasonally in salt marshsediments by Christian et al.53 ATP con
centrations were greatest in the surface
centimeter, and microbial carbon and ni
trogen made up a small fraction of the
sedimentary total.
References
1. Bannerman, R. T, et al, Phosphorus Mobil
ity in Lake Ontario Sediments (IFYGL).
-Vol. 48, No. 6, June 1976 1437
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Literature Review
Proc. 17th Conf. Great Lakes Res., 158
(1974).2. Fillos, J, and Swanson, W. R, The Release
Rate of Nutrients From River and Lake
Sediments. Jour. Water Poll. Control
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Phosphorus to Microorganisms. Univer
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OWRT-A-040-WIS (1975); NTIS PB-240822/7SL.
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017, Office of Research and Development(1975).
5. Lerman, A, and Lietzke, T. A, Uptake and
Migration of Tracers in Lake Sediments.
Limnol & Oceanog., 20, 497 (1975).6. Symmes, K. H, Preliminary Investigation
Into Copper Cycling in Indian Lake, Massa
chusetts: A Lake Treated Annually with
Copper Sulfate. University of Massachu
setts Water Research Center, Completion
Report W75-11039, Project No. OWRT-A
064-MASS (1975); NTIS PB-244 716/7SL.7. Sasseville, D. R, et al, A Large-Volume
Interstitial Water Sediment Squeezer for
Lake Sediments. Limnol & Oceanog.,19, 1001 (1974).
8. Thayer, G. W, et al, A Large Corer for
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Water. Limnol & Oceanog., 20, 474
(1974).9. O'Connor, J. F., An Apparatus for Sampling
Gravel Substrate in Streams. Limnol. &
Oceanog., 19, 1007 (1974).10. Kirchner, W. B, An Evaluation of Sediment
Trap Methodology. Limnol & Oceanog.,
20, 657 (1975).11. Moxham, R. M, et al, In Situ Neutron Acti
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12. Agemian, H, d al, A Comparison of theExtraction of Mercury from Sediments byUsing Hydrochloric-Nitric Acid, SulphuricNitric Acid and Hydrofluoric Acid-AquaRegia Mixtures. Analyst (G. B.), 100, 253
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057-WIS (1975); NTIS PB-244 503/9SL.19. Engler, R. M, and Patrick, W. H. Jr., Nitrate
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1438 Journal WPCF
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Literature Review
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Western Basin of Lake Erie. Proc. 17th
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Marine and estuarine pollution
D. J. Reish, California State University,Long Beach
T. J. Kauwling, University of Southern
California, Los Angeles
A. J. Mearns, Southern California CoastalWater Research Project, El Segundo
Review articleslf 2 summarized the fateof organic compounds in the marine en
-Vol. 48, No. 6, June 1976 1439
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