ar307852o no tentatively identified compound (tic) was detected during the analysis of these...
TRANSCRIPT
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
REGION mCENTRAL REGIONAL LABORATORY
201 DEFENSE HIGHWAY __ ......SUITE 200 BRANCH
ANNAPOLIS. MARYLAND 21401
DATE : June 28, 1995
SUBJECT: Region III Data QA Review
FROM : Cynthia E. CaporaleRegion III ESAT RPO (3ES30)
TO : Frank VavraRegional Project Manager (3HW23)
Attached is the organic data validation report, for the Osborne DumpSite (DAS R3115, SDG No. N/A) completed by the Region IIIEnvironmental Services Assistance Team (ESAT) contractor under thedirection of Region III ESD.
The Regional Acceptance Form (RAF) for DAS R3115 will be mailed ata later date.
If you have any questions regarding this review, please call me at(410) 573-6832.
Attachment
cc: Ted Buchwalter, USGS
TID File: 03950623
AR307852 Printed on Recycled Paper
Environmental Systems & Tecnnoiogies Co.Environmental Services Assistance Teams* Phone: (410) £68-7705Region 3 Fax:(410)268-84721419 Forest Drive. Suite 104Annapolis, Maryland 21403
DATES JUNE 27, 1995SUBJECTS ORGANIC DATA VALIDATION (M3 LEVEL)SITES OSBORNE DUMP DAS R3115 ,
FROM: HARI PRASAD^. MAHBOOBEH MECANIC*DATA REVIEWER SENIOR OVERSIGHT CHEMIST
TOS CYNTHIA E. CAPORALEESAT REGIONAL PROJECT OFFICER
THROUGH: DALE s. BOSHART. ESAT TEAM MANAGER
OViSKVXISW
DAS R3115 consisted of two (2) aqueous samples and four (4)associated field blanks submitted to the Chemtech Laboratory(CHEM) for low concentration volatile organics analysis. Thesamples were analyzed as a Delivery of Analytical Services (DAS)project according to the .Superfund Analytical Method for LowConcentration Organics (10/92). . '""-•--.
All samples were successfully analyzed for all target volatilecompounds. All instrument and method sensitivities wereaccording to the specified method.
MINOR PROBLEM
o Several compounds failed the precision criteria during theinitial and continuing calibrations (%RSD, %D > 30%) . Thereported results for methylene chloride have been qualifiedWJH, unless superseded by the "B" qualifier subsequentlymentioned. The precision values for the other compoundswere not grossly exceeded (< 50%) and their quantitationlimits were not qualified. See Table I in Appendix E.
NOTES
The laboratory incorrectly reported in the case narrativethe dates of sample receipt as March 3 and 4, 1995 insteadof May 3 and 4, 1995. This discrepancy has been rectifiedduring the data validation by correcting the case narrative,
AR307853
Page 2 of 2. . - ' - ' •
o During the analysis of*the fiald and laboratory blanks, thefollowing compounds were detected at tha maximumconcentrations given below. Tha reported results for thesecompounds in tha affected samples which are < lOx tha commonlaboratory blank contaminant concentrations or < 5x- thaother blank contaminant concentrations have been qualified»B».
Compound Concentr at ion (ucr [1*\
Chloromethane 0.9 JHathylena chloride* 1.62-Butanone* 1.1Toluene 0.9 JEthyl benzene 0.6 Jo-Xylene , 0.6 J
* Common Laboratory Contaminant
o The laboratory incorrectly reported on Form 7A (continuingcalibration)- tha %D for 2-hexanone as 106 which has beencorrected to 10.6 during the data validation.
o No Tentatively Identified Compound (TIC) was detected duringthe analysis of these samples. See Forms IB in Appendix D.
All data for DAS R3115 were reviewed, in accordance with thaNational Functional Guidelines for Evaluating Organic andInorganic Analyses with modification for use within Region III.The text of the report addresses only those problems affectingusability.ATTACHMENTS
Appendix A - Glossary of Data QualifiersAppendix B - Data Summary FormsAppendix C - Results as Reported by the Laboratory for All
Target CompoundsAppendix D - Tentatively Identified CompoundsAppendix E - Support Documentation '
DCN:HP506A06.OSB
Appendix A
Glossary of Data Qualifiers
AR307855
GLOSSARY OF DATA QUALIFIER CODES (ORGANIC)
CODES RELATING TO IDENTIFICATION(confidence concerning presence or absence of compounds)
U a Not detected. The associated number indicatesapproximate sample concentration necessary to bedetected.
NO CODE =» Confirmed identification,B = not detected substantially above the level reported
in laboratory or field blanks.R = Unusable result. Analyte may or may not be present
in the sample. Supporting data necessary toconfirm result.
N =» Tentative identification. Consider present.Special methods may be needed to confirm itspresence or absence in future sampling efforts.
CODES RELATED 2Q OUANTITATION(can be used for both positive results and samplequantitation limits):
J =» Analyte present. Reported value may not beaccurate or precise.
K = Analyte present. Reported value may be biasedhigh. Actual value is expected to be lower.
L =* Analyte present. Reported value may be biased low.Actual value is expected to be higher.
UJ = Not detected, quantitation limit may be inaccurateor imprecise.
UL =* Not detected, quantitation limit is probablyhigher.
OTHER CODES
NJ = Qualitative identification questionable djue to poorresolution. Presumptively present at approximatequantity.
Q =» No analytical result. • ^
AR307856
Appendix B
Data Summary Forms
AR3078S7
<M
t feift . s « •
g g11
1;f128
I J . .• •
3
if
lu :C *s *: B X H _ »'3.. * * ' • *•>* « P •S- o f-^s€*s* 5*tsslllr5
jjjjjjjjj;
I I i I
is HI "U? S| ;! '
ft.
i.>:•
iisiu- •
1
!€I.
red
COcc.
i;«:S! =ft
-r
111 !>! I-Wf|il«|||l|lplccvC£ *{ff $I1 !-'!•- * if |iJfllfflfi-M|J I]||/|l|i
f i ££L£«'fgeS.ilrfJ&r&vifl.'ifI
sftsiH
-ActionU
fi'-ItI;f i -~~u.
•>*
V
^
~ ~. ~ ~ "•. T T "?* "" "" ~" """""" T TT~.'n
**
4
1
L.
-e
-
.-"-;:- •• •» -
"*W ••
I
S8
iift •
1 ff
i
M.
iM
Appendix CResults as Reported by the Laboratory
for all Target Compounds
fifi3078SO
1A SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET
1150502A01Lab Name: CHEMTECH _____ Contract: US EPA REGION II
Project No.: A499-S Site: _____ Location: _________ Group: ____
Matrix: (soil/water) WATER * Lab Sample ID: O41895
Sample wt/vol: 25.0 (g/mL) ML Lab File ID: L1258.D
Level: (low/med) ____.__ Date Received: 5/3/gS
% Moisture: notdec. ______ Date Analyzed: 5/6795
GC Column: DB624___' ID: . 0.53 (mm) Dilution Factor: 1.0
Soil Extract Volume: (uL) Soil Aliquot Volume: ______ (uL)
Concentration Units:CASNo. Compound (ug/L or ug/Kg) ug/L Q
75-71-874-87-375-01-4 '74-83-975-00-375-35-475-09-2S7-64-175-15-0156-60-575-34-3156-59-474-97-557-66-378-93-371-55-656-23-571-43-2107-06-279-01-678-87-5106-93-475-27-410061-01-5108-88-310061-02-679-00-5127-18-4124-48-1108-90-7100-4M
DichlorodifiuorometbaneChloromethaneVinyl ChlorideBromoiugthane :•Cbloroethane. 1,1-DichloroetheneMetbylene ChlorideAcetoneCarbon Disulfidetrans-l,2-Dichloroethene1.1-Dichloroethanecis-l,2-DichloroetheneBromochloromethaneChloroform2-Butanone1 , 1 , 1 -TrichloroethaneCarbon TetrachlorideBenzene1,2-DichloroethaneTrichloroethene1 ,2-Dichloropropane1 -DibromoethaneBromodichloromethanects-1 ,3-DichloropropeneToluenetrans- 1 ,3-Diciuoropropeue1 , 1 ,2-TrichloroethaneTetrachloroetheneDibromochloromethaneChlorobenzeneEthylbenzene .m&p-xyleneso-xylene
f
0.75
0.
,
1
uuuuuuJB.UUU
-OJuuuuuuuuuuuuuJu
- tfuuuuuu
Page 1 of2 mr\nninf IFORMIVOA An 30 7 00 I 3/90
1A SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET
1150502A01Lab Name: CHEMTECH ____________ Contract: US EPA REGION II
Project No.: A499-S Site: _____ Location: •______ Group: ___
Matrix: (soil/water) WATER * Lab Sample ID: O41895
Sample wt/vol: 25.0 (g/mL) ML Lab File ID: L12S8.D
Level: (low/med) _____ Date Received: 5/3/95
% Moisture: notdec. _____ Date Analyzed: 5/6/95
GC Column: DB624_______ ID; 0.53 (mm) Dilution Factor 1.0
Soil Extract Volume: _____(uL) x Soil Aliquot Volume: _______ (uL)
Concentration Units:CASNo. Compound (ug/L or ug/Kg) ug/L Q
100-42-575-25-2108-10-1591-78-679-34-5541-73-1106-46-7J5-50-1J6-12-8
StyreneBromoform4-Metbyl-2-pentanone2-Hexanone1 , 1 ,2,2-Tetracnloroethane1 ,3-Dichlorobenzene1 ,4-Dichlorobenzene1 ,2-Dichlorobenzene1 ,2-Dibromo-3-chloropropane
11 *55
' *
\
UUUUUUUUU ——
'----
*i
CMVOCOf*.CDCOor
Page 2 of 2 . .FORM IVOA 3/90
000011
1A SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET
1150502A07Lab Name: CHEMTECH •-^•-_______ Contract: US EP,A REGION IB
Project No.; A499-S Site: _____ Location: ___________ Group:___
Matrix: (soil/water) WATER * Lab Sample ID: 041898
Sample wt/vol: 25.0 (g/mL) ML Lab File ID: L1255.D
Level: (low/med) _____ Date Received: 5/3/95
% Moisture: not dec. _____ Date Analyzed: 5/6/95
GC Column: DB624 ID; 0.53 (mm) Dilution Factor: 1.0_______•_________————>«~ «—————————— f ~" ~™" ~™'
Soil Extract Volume: . (uL) Soil Aliquot Volume: (uL)
Concentration Units:CASNo. Compound (ug/L or ug/Kg) . ug/L Q
75-71-874-87-375-01-474-83-975-00-375-35-475-09-267-64-175-15-0156-60-575-34-3156-59-474-97-557-66-378-93-371-55-656-23-571-43-2107-06-279-01-678-87-5106-93-475-27-410061-01-5108-88-310061-02-679-00-5127-18-4124-48-1108-90-7100-41-4
DichlorodifluoromethaneChloromethaneVinyl ChlorideBromomethaneCbloroethane1,1-DichloroetheneMethylene ChlorideAcetoneCarbon Disulfide •trans-1 ,2-Dichloroethene1,1-Dichloroethanecis-l,2-DichloroetheneBromochloromethaneChloroform2-Butanone1.1,1-TrichlorocthaneCarbon TetrachlorideBenzene1,2-DichloroethaneTcichloroetbene1 ,2-Dichloropropane1,2-DibromoethaneBromodichloromethaneds-1 ,3-DichloropropeneToluenetrans-1 ,3-Dichloropropene1, 1,2-TrichloroethaneTetrachloroetheneDibromochloromethancChlorobenzencEthylbenzenem&p-xyleneso-xylene
10.9 *1111
1.65
t • • ' ' '
-~"S
" .
. .
>.
UJUUUUJBUUU
-^ uUU .UUUUUUUUUUUUU
- -UUUUUUU
Page 1 of2FORMIVOA AR3Q7863 CCC017 3/9°
1A SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET ——————————
11SOS02A07Lab Name: CHEMTECH ___________ Contract: US EPA REGION II _________
Project No.: A499-S Site: _____ Location: _________ Group: __
Matrix: (soil/water) WATER * Lab Sample ID: O41898 >
Sample wt/vol: 25.0 (g/mL) ML Lab File ID: L1255.D
Level: (low/med) _____ Date Received: 5/3/95
% Moisture: not dec. _____ Date Analyzed: 5/6/95
GC Column: DB624_________ ID; 0.53 (mm) Dilution Factor: 1.0
Soil Extract Volume: _____(uL) ' Soil Aliquot Volume: _______ (uL)
Concentration Units:CASNo. Compound (ug/L or ug/Kg) ug/L Q
100-42-575-25-2108-10-1591-78-679-34-5541-73-1106-46-795-50-196-12-8
StyreneBromofbrm4-Methyl-2-pentanone2-Hexanone1,1,2,2-Tetrachloroethane1,3-Dichlorobenzene1,4-Dichlorobsnzene1,2-Dichlorobenzene1 ,2-Dibromo-3-chloropropane
11 »55
.
•* • %
»
uuuuuuuuu
"- -..•
»
GOP »CDCOcc.
Page2of2 . -FORM.VOA
1A SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET
1150503 ACSLab Name: CHEMTECH ; ______ Contract: US EPA REGION III
Project No.: A499-S Site: _____ Location: _________ Group: ___
Matrix: (soil/water) WATER * Lab Sample ID: 041899
Sample wt/vol: 25.0 (g/mL) ML Lab File ID: L12S9.D
Level: (low/med) - ' Date Received: 5/4/95
% Moisture: not dec. ______ Date Analyzed; 5/6/95
GC Column: DB624 ID: 0.53 (mm) Dilution Factor: 1.0. i •——•— t , - ^ —Soil Extract Volume: _____(uL) Soil Aliquot Volume: (uL)
Concentration Units:CASNo. Compound (ug/L or ug/Kg) ugfL , Q
75-71-874-87-375-01-474-83-975-00-375-35-475-09-257-64-175-15-0156-60-575-34-3156-59-474-97-567-66-378-93-371-55-656-23-571-43-2107-06-279-01-678-87-5106-93-475-27-410061X11-5108-88-310061-02-679-00-5127-18-4124-48-1108-90-7100-41-4
DichlorodifluoromethaneChloromethaneVinyl ChlorideBromomedianeChloroefhane1,1-DichloroethcneMetbylene Chloride
, AcetoneCarbon Disulfidetrans-1.2-Dichl6roediene1,1-Dichloroethanetis-l,2-DichIoroetheneBromocbJoromethaneChloroform2-Butanone1 , 1 , 1 -TrichloroethaneCarbon TetrachlorideBenzene1.2-DichloroethaneTrichloroethene1 ,2-Dichloropropane1,2-DibromoethaneBromodichloromethanecis-l,3-DichloropropeneToluenetrans-l,3-Dichloropropene1,1 -TrichIoroethaneTetrachloroetheneDibromochloromethaneChlorobenzeneEmylbenzenem&p-xyleneso-xylene
10.9 *111125
.
0.9
. . .•%
0.61
0.6
UJUUUUUUUU '
- UUU .UUUUUUUUUUUJU
- TJUUUJUJ
: Page 1 of 2 . 'I FORMIV04JR307865 OQCO?4 3/9°
1A SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET
1150503A08Lab Name: CHEMTECH ___________ Contract: US EPA REGION II
Project No.: A499-S Site: _____ Location: _________ Group:
Matrix: (soil/water) WATER * Lab Sample ID: O41899
Sample wt/vol: 25.0 (g/mL) ML Lab File ID; L1259.D
Level: Oow/med) _____m Date Received: 5/4/95
% Moisture: not dec. _____ Date Analyzed: 5/6/95
GC Column: DB624_________ ID: 0.53 (mm) Dilution Factor 1.0
Soil Extract Volume: _____(uL) Soil Aliquot Volume: __._____ (uL)
Concentration Units:CASNo. Compound (ug/L or ug/Kg) ug/L Q
100-42-575-25-2108-10-1591-78-679-34-5541-73-1106-46-795-50-196-12-8
StyreneBromofonn4-Methyl-2-pentanone2-Hexanone1 , 1 .2,2-Tetrachloroethane1 ,3-Dichlorobenzene1 ,4-Dichlorobenzene1 ,2-Dichlorobenzene1 ,2-Dibromo-3-chIdropropane
1•U5511I11
. .
, .
- -" X
uuuuuuuuu
----.
•r
10oor .CDCO0=BO:
Page 2 of 2FOKM.VOA 3*0
• • ; • ' lAji • • • • . . - . SAMPLE N O .VOLATILE ORGANICS ANALYSIS DATA SHEET
1150503A11Lab Name: CHEMTECH ' _______ Contract: US EPA REGION II
Project No.: A499-S Site: _____• Location: ___________ Group: ___
Matrix: (soil/water) WATER '""•'•''' * Lab Sample ID: O41900
Sample wt/vol: 25.0 (g/mL) ML Lab File ID: L1260.D
Level: (low/med) ____. Date Received: 5/4/95
% Moisture: not dec. _____ . Date Analyzed: 5/6/95
GC Column: DB624_____' ID; 0.53 (mm) Dilution Factor: 1.0
Soil Extract Volume: (uL) . Soil Aliquot Volume: ______ (uL)
• Concentration Units:CASNo. Compound1 (ug/L or ug/Kg) ug/L Q
75-71-874-87-375-01-474-83-975-00-375-35-475-09-267-64-175-15-0156-60-575-34-3156-59-474-97-557-66-378-93-371-55-656-23-571-43-2107-06-279-01-678-87-5106-93-475-27-410061-01-5108-88-310061-02-679-00-5127-18-412448-1108-90-7100-41-4
DichlorodifluoromethaneChloromethaneVinyl ChlorideBromomethanfiChloroetbane1,1-DichloroedieneMethylene ChlorideAcetoneCarbon Disulfidetrans-1 ,2-Dichloroethene1,1-Dichloroethanecis-1 ,2-DichloroetheneBromochlorometiiane(jnlorotbnn2-Butanone1,1,1-TrichloroetfaaneCarbon TetrachlorideBenzene1 ,2-DichloroethaneTrichloroethene1,2-Dichloropropane1 ,2-Dibromoethane
• Bromodichloromethanecis-1 ,3-DichloropropeneToluenetrans-1 ,3-Dichloropropene1,1,2-TrichloroethaneTetrachloroetheneDibromochloromethaneChlorobenzeneEmylbenzenem&p-xyleneso-xylene
11.2*
5
-
5
'•*
U
UUUUJBUUU
- UUUUUUUUUUUUUUUU
- "UUUUUUU
10COr-»*ooor
Page.lof2
.000032.-""
1A SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET
1150503A11Lab Name: CHEMTECH_______________ Contract: US EPA REGION II •
Project No.: A499-S Site: _____ Location: _________ Group:
Matrix: (soil/water) WATER * Lab Sample ID: O41900M ^ H ^ M ^ H * i
Sample wt/vol: 25.0 (g/mL) ML Lab Ftle ID: L1260.D
Level: (low'med) _____ Date Received: 514195
% Moisture: not dec. _____ Date Analyzed: 5/6795
GC Column; DB624 _______ ID; 0.53 (mm) Dilution Factor 1.0
Soil Extract Volume: _____(uL) Soil Aliquot Volume: ______ (uL)
Concentration Units:CASNo. Compound (ug/L or ug/Kg) ug/L Q
100-42-575-25-2108-10-1591-78-679-34-5541-73-1106-46-795-50-176-12-8
StyreneBromofbrm4-Methyl-2-pentanone2-Hexanone1 , 1 ,2,2-Tetrachloroethane1 ,3-Dichlorobenzene1 ,4-Dichlorobenzene1 ,2-Dichlorobenzenel,2-Dibromo-3-chloropropane
-•
-
11 »5511111
•• .V
,
• -
UuUuuuuuu
- ^-.
»
COUD00r*.oCOor
Page2of2» FORMIVOA CCC033
1A, i SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET
1150503A14Lab Name: CHEMTECH Contract: US EPA REGION IT
Project No.: A499-S Site: _____ Location: .______ Group: ___
Matrix: (soil/water) WATER • * Lib Sample ID: O41901
Sample wt/vol: 25.0 (g/mL) ML Lab File ID: L1256.D
Level: (low/med) . • Date Received: 5/4/95
% Moisture: not dec. ^_____ Date Analyzed; 5/6/95
GC Column: DB624 _____( ID; 0.53 (mm) Dilution Factor 1.0
Soil Extract Volume: ______(uL) Soil Aliquot Volume: ____• (uL)
Concentration Units:CASNo. Compound (ug/L or ug/Kg) ug/L
75-71-874-87-375-01-47443-975-00-375-35-475-09-257-64-175-15-0156-60-575-34-3156-59-474-97-567-66-378-93-371-55-656-23-571-43-2107-06-279-01-678-87-5106-93-475-27-410061-01-5108-88-310061-02-679-00-5127-18-4124-48-1108-90-7100-41-4
DichlorodifluoromethaneChlorometbaneVinyl Chloride ,BromometbaneChloroethane. 1,1-DichloroetbeneMetbylene ChlorideAcetoneCarbon Disulfidetrans'l ,2-Dichloroethenel,l-DichloroetE25etis-l,2-DichloroetheneBromochloromethaneChloroform2-Butanone1,1, 1-TrichloroethaneCarbon TetrachlorideBenzene1 ,2-DichIoroethaneTrichloroethene .1 ,2-Dichloropropane1,2-DibromoethaneBromodichloromethanecis-1 ,3-DichloropropencToluenetrans-1 ,3-Dichloropropene1 , 1,2-TrichloroethaneTetrachloroemeneDibromochJoromethaneChlorobenzeneEtbylbenzenem&p-xyleneso-xylene
10.9*11 ,1125
5
.^
11
UJUUUUUUUU
.--,uUo .UUUUUUUUUUUUU
- UUUUUUU
oor»-oCOor
Page 1 of 2 •FORM I VGA . , v 000039 3/9°
1A SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET
1150503A14Lab Name: CHEMTECH ___ Contract: US EPA REGION II _________
Project No.: A499-S Site: _____ Location: _________ Group: ___
Matrix: (soil/water) WATER * Lab Sample ID: O41901
Sample wt/vol: 25.0 (g/mL) ML Lab File ID: L1256JD
Level: (low/med) _____ Date Received: 5/4/95
% Moisture: not dec. _____ Date Analyzed: 5/6/95
fy<v>i»miv DB624 _____ ID; 0.53 (mm) Dilution Factor: 1.0
Soil Extract Volume:. ___ (uL) Soil Aliquot Volume: ______ (uL)
Concentration Units:CASNo. Compound (ug/L or ug/Kg) ug/L Q
100-42-575-25-2108-10-1591-78-679-34-5541-73-1106-46-7>5-50-l96-12-8
StyreneBromofbtm4-Methyl-2-pentanone2-Hexanone1 . 1 ,2,2-Tetrachloroethane1,3-Dichlorobenzenel.4-Dichlorobenzene1,2-Dichlorobenzenel,2-Dibromo-3-chloropropane
11*55
\
UUUUUUU .UU
~--~-
*•
CDroors.oooor.
Page 2 of2
FOMIIVO* 000040 3/9°
1A* SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET
1150503 A15Lab Name: CHEMTECH__________" Contract: US EPA REGION II _____-
Project No.; A499-S Site: _____ Location: _________ Group: ___
Matrix: (soil/water) WATER' ! * Lao Sample ID: O41902
Sample wt/vol: 25.0 (g/mL) ML Lab File ID: L1257.D
Level: Oow/med) _____ Date Received: 5/4/95
% Moisture: not dec. . Date Analyzed: 5?6/95
GC Column: DB624________ ID; 0.53 (mm) • Dilution Facton 1.0
Soil Extract Volume: _____(uL) Soil Aliquot Volume: ____ (uL)
Concentration Units:CASNo. Compound (ug/L or ug/Kg) ug/L Q
75-71-874-87-375-01-4.74-83-975-00-375-35-475-09-2 ;J7-64-175-15-0156 0-575-34-3156-59-474-97-557-66-378-93-371-55-656-23-571-43-2 .107-06-279-01-678-87-5106-93-475-27-410061-01-5108-88-310061-02-679-00-5.127-18-4124-48-1108-90-7100-41-4
DichloFodifhiOFOmethaneChloromethane-Vinyl ChlorideBromomethaneChloroemane1,1-DichloroethencMetbylene ChlorideAcetoneCarbon Disulfide .trans-1 ,2-Dichloroediene1, 1-DIchloroethanecis-1 ,2-DichloroetheneBromochloromethaneChloroform2-Butanone1,1,1-TrichloroetfaancCarbon TetrachlorideBenzene1,2-DichloroethaneTrichloroethene1 ,2-DichIoropropane1,2-DibromoethaneBromodichloromethanecis-1 .3-DichloropropencToluenetrans- 1 ,3-Dichloropropene1,1,2-TrichloroethaneTetrachloroetheneDibromochloromethaneChlorobenzeneEthylbenzenem&p-xyleneso-xylene
. •*•
251
-5
.\
UUUUUUUUUU
- -~ uUuuuuuuuuuuuuuu
- *uuuuuuu
oo
Page 1 of2
HBIITO*' OOC046
1A SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET
1150503A15Lab Name: CHEMTECH_______________ Contract: US EPA REGION II ______.
Project No.: A499-S Site: _____ Location: _________ Group: ______ *—'
Matrix: (soil/water) WATER * Lab Sample ID: O41902 ,
Sample wt/vol: 25.0 (g/mL) ML Lab Hie ID; L1257.D
Level: (low/med) _____ Date Received: 5/4/95
% Moisture: notdec. _____ Date Analyzed: 5/6/95
GC Column; DB624________ ID; 0.53 (mm) Dilution Factor 1.0
Soil Extract Volume: _____(uL) - Soil Aliquot Volume: ______ (uL)
Concentration Units:CASNo. Compound (ug/L or ug/Kg)
100-42-5 Styrene75-25-2 Bromoform108-10-1 4-Methyl-2-pentanone591-78-6 2-Hcxanone79-34-5 1,1,2,2-Tetrachloroethane541-73-1 1,3-Dichlorobenzene106-46-7 1,4-Dichlorobenzcne95-50-1 1,2-Dichlorobenzene76-12-8 l,2-Dibrorao-3-chloropropane
11 *55
•
_•
uuuuuuuuu
- --
t
_ *
C\Jr>.oor,.oCOor
•-. Page 2 of 2I FORMIVOA 000 04 ? 3/90
Appendix DTentatively Identified Compounds
AR307873
IE SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS 1150502A01
Lab Name: CHEMTECH__________:______ Contract: US EPA REGION III
Project No. A499 Site: _____ Location: _________ Group:
Matrix: (soil/water) WATER * Lab Sample ID; O41895
Sample wt/vol: 25.0 . (g/mL) ML Lab File ID: LI258.D
Level: (low/med) _______ Date Received: 5/3/95
* Moisture: not dec. _______ Date Analyzed: 5/6/95
GC Column: DB624______ ID: 0.53 (mm) OUurion Factor: 1.0
Soil Extract Volume: ________(uL) Soil Aliquot Volume: m_____ (uL)
Concentration Units:Number TICs found: 0 (ug/L or ug/Kg) ug/L
:AS Number1.2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.
Compound Name RT Est-Conc.
•
• ^
- —— ¥-
0.
»
CO
oCOa:
FOEM.voA.-nc 000012 3/9°
IE SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS 1150502A07
Lab Name: CHEMTECH ______________ Contract: US EPA REGION m
Project No. A499 Site: _____ Location: _________ Group:
Matrix: (soil/water) WATER Lab Sample ID: O41898
Sample wt/vol: 25.0 (g/mL) ML . Lab File ID: LI255.D
Level: (low/med) _______ ' Date Received: 5/3'/95
% Moisture: notdec. _______ Date Analyzed: 5/6795
GC Column: DB624______ ID; 0.53 (mm) Dilution Factor 1.0
Soil Extract Volume: _______j(uL) Soil Aliquot Volume: _____ (uL)
Concentration Units:Number TICs found: 0 . (ug/L or ug/Kg) ug/L
: AS Number1.2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.
Compound Name RT. EsL, Cone;
_
•~w'
0
«
.
LOr*GO
oCOor
FORMIVOA-TIC OOC019 3/90
..••:*' IE v SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS 1150503 AOS
Ub Name: CHEMTECH________________ Contract: US EPA REGION III
Project No. A499 <$..vt.rSte:_____ Location: •.,,...y Group:
Matrix: (soil/water) WATER * Lab Sample ID: O41899
Sample wt/vol: 25.0 (g/mL) ML Lab File ID; L1259.D
Level: flow/med) _______ Date Received: 5/4'/95
% Moisture: not dec. _______ Date Analyzed: 5/6/95
GC Column: DB624 ID: 0.53 (mm) Dilution Factor: 1.0
Soil Extract Volume: _______.(uL) Soil Aliquot Volume: _____ (uL)
Concentration Units: •Number TICs found: 0 (ug/L or ug/Kg) ug/L
:AS Number•!..'•2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.
Compound Name
*
. — .
•
.
RT (Est. Cone.
.
- —— ~
Q
,
«
CO
COor
FORM I VOA-TIC ^ 3/9000002G
IE SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS 1150503A11
Lab Name: CHEMTECH_________________ CovttacK US EPA REGION III
Project No. A499 Site: _____ Location: _________ Group: _____ s—'
Matrix: (soil/water) WATER Lab Sample ID: O41900 ______
Sample wt/vol: 25.0 (g/mL) ML Lab File ID: L1260.D
Level: (tow/med) _______ Date Received: 5/4/95
% Moisture: not dec. ________ Date Analyzed: 5/6/95
GC Column: DB624_______ ID; 0.53 (mm) Dilution Factor 1.0
Soil Extract Volume: ____ (uL) . Soil Aliquot Volume: _________ (uL)
Concentration Units:.Number TICs found: 0 (ug/L or ug/Kg) ug/L
: AS Number1.2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.
Compound Name.
-
.
R1 (Est. Cone.1
_.
-
..
^ '
Q
--
•
GOoCO0=
FORM I VOA-TIC _ A 3/90
•' IE SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS 1150503A14
Lab Name: CHEMTECH________________ Contract: US EPA REGION III
'ProjectNo. A499 . ...Site:_____ Location: .. • Grouj
Matrix: (soil/water) WATER * Lab? Sample ID: O41901
Sample wt/vol: 25.0 (gtoL) ML Lab File ID: L1256.D
Level: Oow/med) _______ Date Received: S/4/95
% Moisture: not dec. _______ Date Analyzed: _S/6/95__
GC Column: DB624______ ID; 0.53 (mm) Dilution Factor • 1.0
Soil Extract Volume: - ______(vL) Soil Aliquot Volume; • (uL)
Concentration Units:Number TICs found: 0 (ug/L or ugAKg) . ug/L
: AS Number1.2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.
Compound Name
- .•
'
RT Est. Cone.
V
Q
»
CDr—•CO
COcc.
FORMIVOA-TIC OOC041 3/90
. IE SAMPLE NO.VOLATILE OROAN1CS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS 1150503A15
Lab Name: CHEMTECH ______________ Contract: US EPA REGION III
Project No. A499 Site: _____ Location: _________ Group: _____
Matrix: (soil/water) WATER Lab Sample ID: O41902 '______
Sample wt/vol: 25.0 (g/mL) ML Lab File ID; L1257.D
Level: (low/med) _______ Date Received: 5/4/95
% Moisture: notdec. . Date Analyzed: _5/6/95__
GC Column: DB624______ ID; 0.53 (mm) 'Dilution Factor 1.0
Soil Extract Volume:' _____ (uL) Soil Aliquot Volume: ______ (uL)
Concentration Units:Number TICs found: 0 (ug/L or ug/Kg) ugfl.
:AS Number1.2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.
Compound Name
•
RT,, EstConc.
„
.* -
Q
.
»
cr»r»-oooCOcc
FORM I VOA-TIC A n n A A Q 3/90OOC048
Appendix ESupport Documentation
Page 1 of 2
TABLE I
ENVIRONMENTAL PROTECTION AGENCY REGION IIICALIBRATION OUTLIERSVOLATILE BSL COMPOUNDS
*PROJECT HO.JR3115 ______ CONTRACTOR ESAT
Instrument iDi VOA1DATE /TIME*
ichlorodifluoromethaneChlororoethaneBromotnethaneVinvl ChlorideChloroethaneHethvlene ChlorideAcetoneCarbon Disulfide1 . 1— D; .chloroethene1.1-D:. Chloroethane •ciB-l,2-Dichloroethenetrans-1 . 2-DichloroetheneChloroform
,Jl . 2-Dichloroethane2-Butanone1.1. 1-TrichloroethaneCarbon Tetrach J.orideBromod ichloromethane_1 . 2-Dichloroorot>anecis-1 , 3-Dichlorot>rot>ene"•ichloroethene
t .bromochloromethaneT^ 1 . 2-TrichloroethaneBenzenetrane-1 , 3-Dichlorot>rot>eneBrornof orm4-Hethvl-2-Pentanone2-HexanoneTetrachleroetheneJbromochlorontet lane1.1.2. 2 Totrac iloroe thaneTolueneChlorobenzene_Ethv:LbenzeneStvreneJ.2-<1J pfO jIjj3— 1
SichlorobenzeneCvlenee9: c ilorobenzene
1 , 4-d ilorobenzene1.2-d: .bromo-3-ehloroorooane1 . 2-D .bromoethaneo-Xvlene
ReviewInitia
AFFECTEDSAMPLES t
orLfl/Datei HP 06/21/95
Init. Cal.OS/06/RF
. •
.
95 - 10i22%RSD
32.2
32.731. S
*
I
.II
All eamoles onthis caoe.
Cont. Cal.05/06/95 -RF %D
35.8
5»44
*
C*
«
1150S02A0111S0502A0711S0503A0811E0503A1111S0503A1411S05O3A15LCSSTORAGE BLANKVBLKO1
Cont. Cal..*
RF
-.
%D *
»
ee 1act pace of this table for DEFINITION OF CODES.
AH30788I
Page 2 of 2
DEFINITION OP CODBS USED IN TABLE I
I » %RSD exceeded 30% in the initial calibration, positive results arequalified "J". When the %RSD'exceeded 50%, quantitation limits arequalified "UJ-.
C • %D exceeded 30% in the continuing calibration, positive results arequalified "J". When the %D exceeded 50%, quantitation limits are.qualified -OJ".
7 » RP less than 0.05 in the calibration. All quantitation limits arequalified "R" and positive results are qualified "L".
+ • The "B" qualifier, denoting blank contamination, supersedes thequalifier issued in this table. . .
R » The "R" qualifier, denoting unusable results, supersedes the "P"qualifier issued in this table.
1R307882
6AVOLATILE ORGANICS INITIAL CALIBRATION DATA
Ub Name: CHEMTECH________ Contract: US EPA REGION III
Project No.: A499-S_____ Site: • Location: _____ Group: ______Instrument ID: VOA1_____ Calibration Date(s): 5/6/95 5/6/95Heated Purge: (Y/N) _ Calibration Times: 8022 1338GC Column DB624 ID; 0.53 (mm) Sw jV., XW£i«>cJ.' (VtL
^
V, ;
LabFUelD: RRF1 -L1249.D RRF2 -=RRF5 - L1247.D RRF10 - L125I.D RRF25 -
COMPOUNDlichlorodifiuoromethane!7hlnmm fhat»
Vinyl Chloride *Bromomethane • *aioroethane,1-Dichloroethene *Methylene ChlorideAcetone:arbon Disulfiderans- 1 .2-Dichloroethene1,1-Dichloroethane *cis-1. 2-DichloroetheneBromochloromethanf! . *Chloroform • *2-Butanone,1,1-Trichloroethane *Carbon Tetrachloride *Benzene '1,2-Dichloroethane *'ricnloroetbene *1 ,2-Dichloropropanc,2-Dibromoethane *Bromodichloromethane *is-l,3-Dichloropropene *Toluene *rans-1.3-Dichloropropene *1,1.2-Trichloroethane *retrachloroethene *Mbromochloromethane *hlorobenzene *imylbenzene *n&n-xylenes *Htylene *Jtyrene *Bromoform *4-Methyl-2-pentanone
RRF10.3490.4040.3590.1930.2990.6130.5780.1901.2070.6290.8560.6670.5130.8350.1930.9760.6911.7150.4400.5250.7430.4080.8090.8051.9600.6290.3410.6780.5771.2142.4061.4961.6991.1000.3820.564
RRF20.4070.3830.3850.2590.2720.6470.3710.1141.2020.6580.8890.6690.4860.7910.1430.9190.7001.5560.3850.5080.6310.3340.7610.7471.5020.5480.2690.5500.4850.9181.8191.2251.3590.8730.2700.301
RRF50.3760.4240.4070.1790.2880.7170.4250.1371.3150.7140.9380.7450.5650.8820.1381.0460.8601.8290.4790.9110.7360.3630.8730.8641.5840.6540.3490.6510.6011.0262.0181.3811.5160.9940.3880.319
RRF100.1690.4080.4120.2030.2660.7030.3620.0961.2610.7010.8740.7210.5370.8470.1320.9120.7651.6040.4080.5530.6230.3670.7990.7941.4570.5940.2960.5830.5180.9571.8391.2431.354
• 0.9230.2620.312
L1250.DL1248.D
RRF250.3930.4030.4060.1650.2460.7130£420.0911.2540.6910.8730.7090.5000.8320.1220.9860.8221.7250.4110.5740.6320.3590.7890.7871.5020.5910.2830.6130.5200.9861.8651.2971.3450.9620.20?0.286
RRF0.3390.4040.3940.2000.2740.6790.4160.1261.2480.6790.6860.7020.5200.8370.1450.968 -0.7681.6860.4250.6140.6730.3660.8060.7991.6010.6030.3080.6150.5401.0201.9891.3281.4550.97004)020.356 i
•
%RSD28.73.65.618.17.56.823.132.£3.75.13.54.86.03.919.05.79.66.48.527.49.07.35.25.312.96.711.78.48.711.312.4r8.410.68.826.2-35.T}
**
*
*
**
«****
***** .*********
CO0303
COCC
* Compounds with required minimum RRF and maTimum 5&RSD values.All other compounds must meet a minimum RRF of 0.010.
Page 1 of2FORMVIVOA OOC053'90
6AVOLATILE ORGANICS INITIAL CALIBRATION DATA
Lab Name: CHEMTECH________ Contract: US EPA REGION III
Project No.: A499-S_____ Site: _____ Location: _____ Group:Instrument ID: VOA1_____ Catfbration Date(s): 5/6/95 5/6/95
Heated Purge: (Y/N) __ Calibration Times: 1022 1338
GC Column DB624 ___ ID; 0.53 (mm)Lab File ID: RRF1 -L1249.D RRF2 -RRF5 - L1247.D RRF10 » L1251.D RRF25 -
COMPOUND2-Hexanone1,1,2,2-Tetrachloroethane *1,3-Dichlorobenrene *1,4-DichIorobenzene *1,2-Dichlorobenzene *1 .2-Dibromo-3-chloropropane
.
'
:
4-Bromofiuorobenzene
RRF10.4830.4541.2051.2021.0830.089
0.779
RRF20.2820,4330.9520.9720.8170.080
0.544
RRF50.2640.4421.0531.0800.9020.082
0.559
RRF100.2770.4310.8270.8300.7200.077
0.647
L1250.DL1248.D
'RRF250.2440.4130.6620.6750.5670.057
0.532
-
RRF0.310 <0.4350.9400.9520.8180.077
^
-»0.612
%RSD31.5J3.522.121.723.715.7
16.9
GOCO
COcc
* Compounds with required minimum RRF and TnaTirmmi %RSD values.All other compounds must meet a minimum RRF of 0.010.
Page 2 of2FORM VI VOA Q r> £ Q;, 4 3/90
7A" VOLATILE CONTINUING CALIBRATION CHECK
Lab Name: CHEMTECH_____'• '*.-.•• x Contract: US EPA REGION.IJI
\ /Project No. A499-S____ Site:'____ Location: Group:
Instrument ID: VOAI_________ Calibration Pate; 5/6/95 Time; 1544
Lab Rle ID: L1253.D_________ Init. Calib. Date(s): 5/6/95 5/6/95
Heated Purge: (Y/N) ___ Init Calib. Times; 1116 1544
GC Column: DB624 ID: 0.53 (mm)
COMPOUNDDichlorodifluoromethaneChloromethaneVinyl ChlorideBromomethaneChloroethane . •1.1-DichloroetbeneMethylene ChlorideAcetoneCarbon Disulfidetrans-1.2-DJchloiDethene1 , 1-Dichloroethane. cis-1.2-DichloroetheneBiomocUoromethaneChloroform2-Butanorie1.1.1-TrichloroedianeCarbon TetrachlorideBenzene1.2-DichloroetfaaneTrichloroethene1 ,2-Dichloropropane1 ,2-DibromocthaneBromodicbloromethaneCis-l,3-DicbJoropropencToluenetrans-l,3-Dichloropropene1 . 1,2-TrichloroethaneTetxachloroetheneDibromochlorometnaneChlorobenzeneEthylbenzenem&p-xyleneso-xyleneStyieneBiomofotm4-MethyI-2-pentanone
RRF0.3390.4040.3940.2000.2740.6790.4160.1261.2480.6790.8860.7020.5200.8370.1450.9680.7681.6850.4250.6140.6730.3660.8060.7991.6010.6030.3080.6150.5401.0201.9891.3281.4550.9700.3020.356
RRF50.3640.4380.3970.2410.2850.7150.5650.1121.3150.7250.9120.7330.5240.8810.1411.0420.8361.7540.4480.6180.7050.3790.8350.8341.6890.6420.3040.5930.5411.0212.0291.3541.5511.0020.3040.405
MINt&F
0.1000.100
0.100
,
0.200
0.1000.200
0.1000.1000.5000.1000.300
0.1000.2000.2000.4000.1000.1000.2000.1000.5000.1000.3000.3000.3000.100
*D-7.4-8.44.8-20.5•4.0-5.3
C-35.8J11.1-5.4-6.8-2.9-4.4-0.8-5.32.8 --7.6-8.9-4.1-5.4-0.7-4.8-3.6-3.6-4.4-5.5-6.51.33.6-0.2-0.1-2.0 --1.9-6.6
• -3.4-0.7-13.8
MAX%D
30.030.0
,
30.0
30.0
30.030.0
.-,30.030.030.030.030.0
30.030.030.030.030.030.030.030.030.030.030.030.030.030.0
inCDGO
coor
All other compounds must meet a minimum RRF of 0.010.
'FORM VH VOA 3/90
7A* VOLATILE CONTINUING CALIBRATION CHECK
Lab Name: CHEMTECH _______ Contract: US EPA REGION IU
Project No. A499-S ____ Site: ____ Location: _____ Group:
VOA1 Calibration Date: 516/95 Tune; 1544
Lab File ID: L1253.D _________ Ink. Calib. Date(s): 5/6/95 5/6795
Heated Purge: (Y/N) ___ Init. Calib. Tunes; 1116 1544
GC Column: DB624 ID; 0.53 (mm)
COMPOUND2-Hexanone1. 1.2,2-Tetrachloroethane1.3-DichIorobenzene1.4-Dichlorobenzene1.2-DicbJorobenzene1 .2-Dibromo-3-diloropropaiie
•
4»Bromofluorobenzene
RRF0.3100.4350.9400.9520.3180.077
0.612
RRF50.2770.4580.9630.9310.8420.090
.
0.585
MINRRF
0.5000.6000.5000.400
*•
•
_•
%D"TwOST V
-5.3-2.4-3.0-2.9-16.9
-•.
.
>^
4.3
MAX%D
»fe •<30.030.030.030.0
-
»
COGO
oCOor
All other compounds must meet a minimi tr RRF of 0.010.
Page 2 of 2FOTW vn VOA 0 0 0 f 7 4
I
ii >£^I5
I•rfwoa
Ml
P
I
i
fc
<??
ct
«
&X
r>
tf
\
Cl
i
.6^ . . . . . . . . . . . . . .
cs<prb
I
X
4
V
C
e*§^
COiCJ
CO
1
Received by
: ISi
gn
|
•g
ved b
y:
i-u
Received by: (Si
v>
T
Recei
N^
S
Kv*
5
K
P
i"o
«a _i *^ o._ _> fA
.-
I
£?*
I
£ .GOr ooCOor
f » •
ChemTech Consulting Group, Inc.SAMPLE LOGIN PAGE
SAMPLES LOGGED IN BY *>^ pH Verified by ___CLIENT : US EPA REGION III SAMPLE BATCH NUMBER : 6935PROJECT NAME : A499-S CLIENT NO. : 650SAMPLES DELIVERED : 05/03/95 AT 1035 HOURS BY : FEDEXSAMPLES RECEIVED BY : BM 'LOG IN DATE AND TIME : 05/04/95 TIME 12:08
SAMPLE CLIENT CAMPLE SAMP FRACTIONS OR CONTAINBRS RECEIVEDBOMBER SAMPLE XD BATS TIM '
ANALYSES REQUESTED
41t»S litOS02A01 OS/02/*I 1310 SOCU S-fi*6 , $&•&*•V O A . . . . ' • 'MATRIX: MW SAMPLER: T. BOCXMALTER LOCATION: OOC K311STYPE SAMPLE: Grab COMMENT:RESULTS PROMISED MO LATER THAN I OC/07/9S '
41MC 11SOS02A01 MS OI/02/fC 13IS •GOT, t OCT. IOCUVOA ,MATRIX: NW SAMPLER: T. BUOOtALTER LOCATION: OGC R311S ;TYPE SAMPLE: Grab COMMENT:
, SSULTS PROMISED MO LATER TRW I OC/07/»S
41t)7 11COS02A01 MSB OS/02/tt 1ISS •GCD.IOCO.SGCn ' • " ' •VOA , '
MATRIX: MW SAMPLER: T. BUCKKALTER LOCATION: OGC RJ11ITYPE SAMPLE: Grab COMMENT:RESULTS PROMISED MO LATER THAN i OC/07/9S
41»S 11IOI02A07 OS/02/H 1430 SGCUVOA
MATRIX: HW SAMPLER: T. BUCKKALTER LOCATION: OOC R311CTYPE SAMPLE: Grab COMMENT:RESULTS PROMISED MO LATER THAN i OC/07/*S
*»0-OOIQ9
ChemTech Consulting Group, Inc.SAMPLE LOGIN PAGE ;
SAMPLES LOGGED IN BY * pH Verified byCLIENT : US EPA REGION III SAMPLE BATCH NUMBER : 6936PROJECT NAME : A499-S CLIENT NO. : 650SAMPLES DELIVERED : 05/04/95 AT 0900 HOURS BY : FEDEXSAMPLES RECEIVED BY : BMLOG IN DATE AND TIME : 05/04/95 TIME 12:13
SAKPLB CUBIT SAKPLB SAN* FRACTIONS OX COHXAXHERS RBCSXVSDBOMBER SAKPLB XO DAT! TZMB
ANALYSES REQUESTED
41i»» HIOSOJAOi OS/03 />S 102S »SCD, (SCO. ISCOVOA .MATRIX) MM SAMPLER: T. BUOCMALTER LOCATIOMi OOC U11STtn SANPLBi Grab OCMmHTi . *USULT3 PROMISED NO LATER THAN t OJ/OI/JI
41900 11SOS03A11 OS/03/IS 10SO tOCO. IOCO, tSCO
VOAHATRXZ: WN SAMPLKXi T. BOOCKAI.TBX LOCATIOMt OGC RJ11ITni SAKPLBl Crab OOWCKHTlR2SOIXS PROMISED MO LATZR THAS t 0(/Ot/»
41J01 11SOS01A14 OS/03/»S 1110 IGCO
VOAHAZXZXi MM SAMPLER! T. BOOOtALTSR LOCATIOM: OGC RllltTTP1 SAMPL1: Cr«b OOKMEHTtRESULTS PROMISED MO LATEX TRAM t OC/Ot/»S
41102 IISOSOIAIS OS/03/1S 1430 IGCU, iBCO, 1GCUVOAKATRXXt KN SAMPLERt T. BOOCKALTER LOCATIOMi OOC X311STXPX SAKPLBl Crmb COHNEMTiRB50LTS PROMISED MO LATER TKAM t 0*/0»/»i
United States Department of the InteriorU.S. GEOLOGICAL SURVEY
Vatar Raaouzcaa GivlaienCom 2204 Fadazal Building
1000 Liberty AvanuaFittabuzfh, Fannarlvania 15222
Hay 90. 1995Sanpla CuatodlanChaatacB Coniulting Croup110 Rout* 4EngUwood. RJ 07631 . - .Daaz Sanpla Custodian:TM« BMO to tht Cila correct! EFA «aapla nunbaza a ant to two ihipnanta of aanplai en 5-2-95 end 9-3-95. Triplicatevilla CZOB ona aaopla location lor low laval VOC tnalrala waxa arrontouily cfvan thraa aaqoaotlal EPA Satnla w arattxlpllcata viala from a aaomla location ara to hava onlr ena EPA Sanpla aun&ar. Xba Collowlst cumarlsaa Uxa problanand tha eorraapoadlat carialoaas • ......
COC data 5-2-95? COC 9 23551; FED. CCFBZSS Airbill 12642927C1; DAS S31151 Canlaz Tad Buekwaltar; EBO1. BO. BSGS)Caopla Tax ntnbaza: Bad EPA Bamla Hunbara: Eavlsad EPA Saopla Him. EIA. HO. BATE TIME PwrtiS-U7CS40 through I-107C54Z 1150502A02-03 1150502A01 CM-9 5-2-95 1350S-107<549 thzousb, 1-107*545 11SOS02A04-06 1150S02A01 IS/tSO W-8 5-2-95 1355 Duplicata•otat Station Location Coz 8TA. HO. CH-J ia Comoquanaiai&t Wall 3
OK data 5-3-95; OK I 23552; fED* EXPBESS Airbill 12S4292772; DAS R3115; Samplar'Iad Buekwaltar; tEOJ. HO. CSGS• Saonla Tag euabara: Bad EPA Baapla Huabtnr Raviaad EPA Baapla Hum. CXA. HO. DATE TIME3-107C4S1 through 3-107*453 1150S03A09-10 1150503A08 RKB-1 5-3-95 10253-107(547 through 3-107CS49 1150S03A12-13 1150503A11 HHB5 5-3-95 10503-107(454 through 3-107*456 11SOS03A1C-17 1130S03A13 FB-l 5-3-95 1430Hota: Station Location Coz STA. HO. FERB-1 ia Fiald Eqaipnant Rinaata Blank-1
Station Location tor SIA. HO. M4H5 ia Honitorlng Hall Eomawood 5Station Location Coz STA. HO. n-1 ia Fiald Blank-1 '
•altarci C. Slazza. USEPA RSOC ' ,~*
A. Laga, USIPA RSCC . ' .F. Vavra, OSCPA FM .0. ftiaaaz. DSCS
TTBtttt)
AR30789I
EaiKECH
Report Number: A499 Case Number: R3115*
Number of Samples and Date of Sample Receipt:
water samples were received intact on March 3. an J 4. 199ft
b. Parameters: »
These samples were analyzed for TCL Volatile + Dichlorodifluoromethane.t
c. Analytical Techniques:
Samples were purged and analyzed by EPA CLP Volatile Method according to the Exhibit D of LowConcentration CLP SOW.
N»_d, QA/QC's: ^
*
The surrogate recoveries of each sample is found on Form II- A. The Internal Standard Area counts for eachSample is found on Form vTfl-A, and Initial Calibration results are found on Form VI-A. Both ContinuingCalibrations and Instrument Tuning Information are located on Form V- A. Data for the Blank and associatedsamples are reported on Form 'TV- A". The LCS is reported on Form III A and all %R's are within the controllimits.
I certify that the data package is in compliance with the terms and conditions of the contract both technically and forcompleteness, for other than -the conditions detailed above. Release of the data contained in this hard copy datapackage has been authorized by the laboratory manager or his designed, as verified by the following signature.
Signature: ________;__________ Name: Diwaiit Mehta *
Tide: Lab Manager
11O Route 4 • Englewood New Jersey G7S31 Phone: (201) 567-6863 Fax: (201) 567-1333
flR30789|* Since 1967 000001
-' 3A -WATER VOLATILE MATRIX SPKE/MATRDC SPIKE DUPLICATE RECOVERY
Lab Name: CHEMTECH________• Contract: US EPA REGION ffl
Project No. A499-S . Site: ____ Location: _______ Group: ______a»_-^_» ^ ——i—— ^ ^—
Matrix Spike - Sample No.: LCS_____
1
COMPOUNDVinyl Chloride1 ,2-Dichloroetnane(Carbon tetrachloride[Benzene •rrichloroethene:ts-l ,3-Dichloropropene1.1,2-Trichloroethaneretrachloroetbane|l ,2-Dibromoethane(Broxnofonn|l,4*DicfaIorobenzene
SPIKEADDED(ug/L)5555S555555
SAMPLE .CONCENTRATION
(og/L)00.000000000
LCSCONCENTRATION
(ug/L)554
r 4445SS45
LCS%
REC I93 .93638484889690928891
QC.LIMITSREC.
60 14060-14050-14060-14060-14060-14050-14060-14060-14060-14060-140
it Column to be used to flag recovery and RPD values with an asterisk
* Values outside of QC limits
RPD: 0 out of 0 outside limitsSpike Recovery: 0 out of 0 outside limits
Comments:
FORMm VOA-1 3/90
AR307892 Q00005
1A SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET
LCSLab Name: CHEMTECH ______________ _ Contract: US EPA REGION II
Project No.: A499-S f Site: _____ Locadon: _________ Group:
Matrix: (soil/water) WATER * Lab Sample ID: LCS01
Sample wt/vol: 23.0 (g/mL) ML Lab File ID: L126I.D
Level: (low/med) _____ - Date Received: •
% Moisture: not dec. _____ Date Analyzed: 5/6/95
GC Column: DB624 _____ . ID; 0.53 (mm) Dilution Factor: 1.0
Soil Extract Volume: _____ (uL) Soil Aliquot Volume: ______ (uL)
Concentration Units:CASNo. Compound (ug/L or ug/Kg) ug/L Q
75-71-874-87-375-01-474-83-9754)0-375-35-475-09-267-64-175-15-0156-60-575-34-3 .156-59-474-97-567-66-378-93-371-55-656-23-571-43-2107-06-2794)1-678-87-5106-93-475-27-410061-01-5108-88-310061-02-679-00-5127-18-4124-48-1108-90-7100-41-4
DichlorodifhioromethaneChloromethaneVinyl ChlorideBromOfMfhane
Chloroethane1,1-DichloroetheneMetbylene ChlorideAcetoneCarbon Disulfidetrans-1 ,2-Dichlbroethene1,1-Dichloroethanecis-1 ,2-DichloroetbeneBromochloromethaneChloroform2-Butanone1 , 1 , 1-TrichloroethaneCarbon TetrachlorideBenzene1 ,2-DichloroethaneTrichloroethene1 ,2-Dichloropropane1,2-DibromoethaneBromodichloromefflanecis-l,3-DichloropropeneToluenetrans-l,3-Dichloropropene1,1.2-TrichIoroethaneTetrachloroetheneDibromochloromethaneChlorobenzeneEthylbenzenem&p-xyleneso-xylene
11 *
4.7111
1.95
.
1.61
4.24.24.64.21
4.91
4.411
4.84.5
•i
UuUuuJBUUUUUuuJBU
U
U
UU
-
Uuuuu
00cr*ODrx.CDCO0=
Page 1 of2
3/9°
1A SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATASHEET
LCSLab Name: CHEMTECH_________' Contract: US EPA REGION II
Project No.; A499-S Site: _____ Location: ________ Group:
Matrix: (soil/water) WATER * Lab Sample ID: LCS01
Sample wt/vol: 25.0 (g/mL) ML LabRleID;L1261.b
Level: (low/med) _____ Date Received: .
% Moisture: not dec. _____ Date Analyzed; S/6/95
GC Column: DB624_______^_ ID; 0.53 (mm) Dilution Factor 1.0
Soil Extract Volume: (uL) Soil Aliquot Volume: . (uL)
Concentration Units:CASNo. Compound . (ug/L or ug/Kg) ug/L Q
100-42-5 Styrene75-25-2 Bromoform108-10-1 4-Methyl-2-pentanone591-78-6 2-Hexanone79-34-5 1,1,2,2-Tetrachloroethane541-73-1 1,3-Dichlorobcnzene106-46-7 1,4-Dichlorobcnzene95-50-1 1,2-Dichlorobenzene96-12-8 l,2-Dibromo-3-chloropropane
i• .
.•
14.4 *SSI
4.6 .4.511
"-
.
,
a
uuuu
uu
''*"•«••.
t
»
Page 2 of2
roEMIVOA OOOC92
COt**.oCO01
Lab Name: CHEMTECH
1AVOLATILE ORGANICS ANALYSIS DATA SHEET
Contract: US EPA REGION II
SAMPLE NO.
STORAGE BLANK
Project No.: A499-S Site: _____ Location: _________ Group;
Matrix: (soil/water) WATER * Lab Sample ID: SBLK01
Sample wt/vol: 25.0 (g/mL) ML Lab File ID: L1262.D
Level: Oow/med) _____ Date Received: •
% Moisture: notdec. _____ Date Analyzed: 516195
GC Column: DB624 ____ - ID; 0.53 (mm) Dilution Factor: 1.0
Soil Extract Volume: _____ (uL) Soil Aliquot Volume: ___ ____ (uL)
Concentration Units:CASNo. Compound (ug/L or ug/Kg)
75-71-874-87-375-01-474-83-97540-375-35-475-09-257-64-175-15-0156-60-575-34-3156-59-474 97-5S7-66-378-93-371-55-656-23-571-43-210746-279-01-678-87-5106-93-475-27-410061-01-5108-88-310061-02-67940-5127-18-4124-48-1108-90-7100-41-4
DicblorodifiuoromethaneChloromethaneVinyl ChlorideBromomethaneChloroethane1,1-DichloroetheneMetbylene ChlorideAcetoneCarbon Disulfidetrans-1.2-Dichloroethene1,1-Dichloroethanecis-1 ,2-DichloroetheneBmmnriilniinmpfhanft
Chlorofbnn2-Butanone1 , 1 , 1 -TrichloroethaneCarbon TetrachlorideBenzene1 ,2-Dichloroethane
. Trichloroethene1 ,2-Dichloropropane1 ,2-DibromocthaneBromodichloromethanecis-l,3-DichloropropeneToluenetrans-1 ,3-DichIoropropcne1 , 1 ,2-TrichloroethaneTetrachloroetheneDibromochloromethaneChlorobenzeneEtbyibenzenem&p-xyleneso-xylene
*
25
1.
11 *111
UUUUUUUUUU
- uUUUJBUUUUUUUUUUUuUuuuuu
CDfx.o
Page 1 of2FORMIVOA 3/90
o n r\ r. n r
1A SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA'SliEET
Lab Name: CHEMTECH______________ Contract: US EPA REGION HISTORAGE BLANK
Project No.; A499-S Site: _____ Location: _________ Group:
Matrix: (soU/water) WATER * Lab Sample ID: SBLK01
Sample wt/vol: 25.0 (g/mL) ML Lab File P: L1262.D
Level: (tow/med) _____ Date Received: .
% Moisture: not dec. _____ Date Analyzed; 5/6/95
GC Column: DB624____' ID; 0.53 (mm) Dilution Factor 1.0
Soil Extract Volume: (uL) Soil Aliquot Volume: (uL)
Concentrarion Units:CASN6. Compound (ug/L or ug/Kg) ug/L Q
100-42-5 Styrcne75-25-2 Bromoform108-10-1 4-MethyI-2-pentanone591-78-6 2-Hexanone79-34-5 1,1,2.2-Tetrachloroethane541*73-1 1,3-Dicblorobenzene106-46-7 1,4-Dicblorobenzene95-50-1 1,2-Dichlorobenzene96-12-8 l,2-Dibromo-3-chloropropane
.• •
11 *55
.
,t
Vuuuuuuuu
••*•-. • •
»
o\oo
COor
Page 2 of 2FORMIVOA . 3/90
IE SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS STORAGE BLANK
Lab Name: CHEMTECH________________ Contract: US EPA REGION III
Project No. A499 Site: _____ Location: _________ Group:
Matrix: (soil/water) WATER * Lab Sample ID; SBLK01
Sample wt/vol: 25.0 (g/mL) ML Lab File ID: L1262.D
Level: (low/med) _______ Date Received: '
% Moisture: not dec. _________ Date Analyzed: 5/6/95
GC Column: DB624______ • ID; 0.53 (mm) .Dilution Factor 1.0
Soil Extract Volume: " _____ (uL) Soil Aliquot Volume: _____ (uL)
Concentration Units:Number TICs found: 0 (ug/L or ug/Kg) ug/L
: AS Number1.2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.
Compound Name
'
RT, EstConc.
•
.
^
0
_
*
enooCD00or
I FORMIVOA-TIC OOOC983/9°
1A SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA'SHEET
VBLK01Lab Name: CHEMTECH_____________________ Contract: US EPA REGION TO
Project No.: A499-S Site: _____ Location: _________ Group:
Matrix: (soil/water) WATER . * Lab Sample ID: PBLK01
Sample wt/vol: 25.0 (g/mL) ML Lab File ID: L1254.D
Level: (low/med) ._____ Date Received: .
* Moisture: not dec. •' Date Analyzed: S/6/95
GC Column: DB624__________ ID; "0.53 (mm) Dilution Factor: 1.0
Soil Extract Volume: (uL) Soil Aliquot Volume: __.____ (uL)
Concentration Units:CASNo. Compound (ug/L or ug/Kg) ug/L Q
75-71474-87-375-01-474-83-975-00-375-35-47549-2S7-64-175-15-0156-60-575-34-3156-59-474-97-557-66-378-93-371-55-656-23-571-43-2107-06-279-01-678-87-5106-93-475-27-410061-01-5108-88-310061-02-679-00-5127-18-4124-48-1108-90-7100-41-4
DichlorodifluoromemaneChloromethaneVinyl ChlorideBfomomethane vChloroediane1,1-Dichloroethene •Memylene ChlorideAcetoneCarbon Disulfidetrans-1 ,2-Dichloroediene1 . 1-Dichloroetbaneds-1 ,2-DichloroetheneBromochloromethanecnlorofonn2-Butanone1, 1,1-TrichloroethaneCarbon TetrachlorideBenzene1,2-DichIoroethaneTrichloroethene1 ,2-Dichloropropane1 ,2-DibromoethaneBromodichloromethanects-1 ,3-DichloropropeneToluenetrans-l,3-Dichloropropene1,1,2-TrichloroethancTetrachloroetheneDibromochloromedianeChlorobenzeneEthylbenzenem&p-xyleneso-xylene
*
1.35
0.9
t
." _L
uuuuuuJuuu
- uuuuJ.uuuuuuuuuuu
_ -uuuuuuu
ODcr»GOfoooor
Page 1 of 2FORM I VGA 3/90
1A SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET
VBLK01Lab Name: CHEMTECH______._______ Contract: US EPA REGION II _________
Project No.: A499-S Site: _____ Location: _________ Group:
Matrix: (soil/water) WATER * Lab Sample ID; PBLK01
Sample wt/vol: 23.0 (g/mL) ML Lab Hie ID:L1254JD
Level: (low/med) _____ Date Received: .
% Moisture: not dec. _____ Date Analyzed; 5/6795
GC Column: DB624_______ ID; 0.53 (mm) Dilution Factor 1.0
Soil Extract Volume: (uL) Soil Aliquot Volume; (uL)
Concentration Units:CASNo. Compound (ug/L or ug/Kg) j
100-42-575-25-2108-10-1591-78-679-34-5541-73-1106-46-7W-50-176-12-8
.
StyreneBromofbrm4-Methyl-2-pentanone2-Hexanone1,1,2,2-Tetrachloroethane1 ,3-Dichlorobenzene
• 1 .4-Dichlorobenzene1,2-Dichlorobenzene1 ,2-Dibromo-3-chloropropane
11*55
••%.
UUUU' UUUUU
- .
»
enenCO
Page 2 of2FORM I VOA r n T 3 e:OOoCoo
IE SAMPLE NO.VOLATILE ORGAN1CS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS VBLK01
Lab Name: CHEMTECH________________ Contract: US EPA REGION HI
Project No. A499 Site: _____ Location: _________ Group:
Matrix: (soil/water) WATER * Lab Staple ID: PBLK01
Sample wt/vol: 25.0 (g/mL) ML___ Lab FUe ID: L1254.D
Level: (low/med) ' Date Received: •
% Moisture: not dec. _______ Date Analyzed: 5/6/95
GC Column: DB624______ ID: 0.53 (mm) JDUurion Factor 1.0
Soil Extract Volume: _______(uL) Soil Aliquot Volume: ______ (uL)
Concentration Units:Number TICs found: 0 (ug/Lorug/Kg) vgfL
: AS Number1.2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.
Compound Name
^
RT*
EstConc.
~
*
0
CDCD
er>o:
FORMIVOA-TIC OOCC86 3/50