araldite 2018 isocyanate (xd 4445) · araldite® 2018 isocyanate (xd 4445) version 1.1 revision...

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

ARALDITE® 2018 ISOCYANATE (XD 4445)

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Revision Date:

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SDS Number: 400001010071

Date of last issue: 14.12.2016 Date of first issue: 14.12.2016

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SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Trade name

: ARALDITE® 2018 ISOCYANATE (XD 4445)

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the Substance/Mixture

: Adhesives and/or sealants

1.3 Details of the supplier of the safety data sheet

Company : Huntsman Advanced Materials (Europe)BVBA Address : Everslaan 45

3078 Everberg Belgium

Telephone : +41 61 299 20 41 Telefax : +41 61 299 20 40 E-mail address of person responsible for the SDS

: [email protected]

1.4 Emergency telephone number

Emergency telephone number : EUROPE: +32 35 75 1234 France ORFILA: +33(0)145425959 ASIA: +65 6336-6011 China: +86 20 39377888 +86 532 83889090 India: + 91 22 42 87 5333 Australia: 1800 786 152 New Zealand: 0800 767 437 USA: +1/800/424.9300

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Acute toxicity, Category 4

H332: Harmful if inhaled.

Skin sensitisation, Category 1

H317: May cause an allergic skin reaction.

Specific target organ toxicity - single exposure, Category 3, Respiratory system

H335: May cause respiratory irritation.

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)



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Hazard pictograms

:

Signal word

: Warning

Hazard statements

: H317 May cause an allergic skin reaction. H332 Harmful if inhaled. H335 May cause respiratory irritation.

Precautionary statements

: Prevention: P261 Avoid breathing mist or vapours. P280 Wear protective gloves. Response: P304 + P340 + P312 IF INHALED: Remove person to fresh

air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.

P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention.

P362 + P364 Take off contaminated clothing and wash it before reuse.

Storage: P403 + P233 Store in a well-ventilated place. Keep

container tightly closed.

Hazardous components which must be listed on the label:

Hexamethylene diisocyanate, oligomers Hexamethylene diisocyanate

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

SECTION 3: Composition/information on ingredients

3.2 Mixtures

Hazardous components

Chemical name CAS-No. EC-No. Index-No. Registration number

Classification Concentration

(% w/w)

Hexamethylene diisocyanate, oligomers

28182-81-2 500-060-2 01-2119485796-17

Acute Tox. 4; H332 Skin Sens. 1; H317 STOT SE 3; H335

>= 90 - <= 100

Hexamethylene diisocyanate 822-06-0 212-485-8 615-011-00-1

Acute Tox. 4; H302 Acute Tox. 1; H330 Skin Corr. 1C; H314

>= 0.1 - < 1



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01-2119457571-37 Resp. Sens. 1; H334 Skin Sens. 1; H317 STOT SE 3; H335

For explanation of abbreviations see section 16.

SECTION 4: First aid measures

4.1 Description of first aid measures

General advice

: Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended.

If inhaled

: Consult a physician after significant exposure. If unconscious, place in recovery position and seek medical advice.

In case of skin contact

: If on skin, rinse well with water.

In case of eye contact

: Flush eyes with water as a precaution. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist.

If swallowed

: Keep respiratory tract clear. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician.

4.2 Most important symptoms and effects, both acute and delayed

None known.

4.3 Indication of any immediate medical attention and special treatment needed

Treatment

: Treat symptomatically.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media

: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing media

: High volume water jet

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

Special protective equipment : Wear self-contained breathing apparatus for firefighting if



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for firefighters

necessary.

Specific extinguishing methods

: No data is available on the product itself.

Further information : Standard procedure for chemical fires.Use extinguishing

measures that are appropriate to local circumstances and the surrounding environment.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions

: Use personal protective equipment. Ensure adequate ventilation.

6.2 Environmental precautions

Environmental precautions

: Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up

: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal.

6.4 Reference to other sections

See Section 1 for emergency contact information. For personal protection see section 8. For disposal considerations see section 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on safe handling

: Avoid formation of aerosol. Do not breathe vapours or spray mist. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Provide sufficient air exchange and/or exhaust in work rooms. Dispose of rinse water in accordance with local and national regulations. Persons susceptible to skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used.



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Advice on protection against fire and explosion

: Normal measures for preventive fire protection.

Hygiene measures

: When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers

: Keep container tightly closed in a dry and well-ventilated place. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards.

Recommended storage temperature

: 2 - 40 °C

Further information on storage stability

: No decomposition if stored and applied as directed.

7.3 Specific end use(s)

Specific use(s)

: No data available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure Limits

Components CAS-No. Value type (Form of exposure)

Control parameters Basis

Hexamethylene diisocyanate, oligomers

28182-81-2 TWA 0.02 mg/m3 (as -NCO)

GB EH40

Further information Substances that can cause occupational asthma (also known as asthmagens and respiratory sensitisers) can induce a state of specific airway hyper-responsiveness via an immunological, irritant or other mechanism. Once the airways have become hyper-responsive, further exposure to the substance, sometimes even to tiny quantities, may cause respiratory symptoms. These symptoms can range in severity from a runny nose to asthma. Not all workers who are exposed to a sensitiser will become hyper-responsive and it is impossible to identify in advance those who are likely to become hyper-responsive. 54 Substances that can cause occupational asthma should be distinguished from substances which may trigger the symptoms of asthma in people with pre-existing airway hyper-responsiveness, but which do not include the disease themselves. The latter substances are not classified asthmagens or respiratory sensitisers., Wherever it is reasonably practicable, exposure to substances that can cause occupational asthma should be prevented. Where this is not possible, the primary aim is to apply adequate standards of control to prevent workers from becoming hyper-responsive. For substances that can cause occupational asthma, COSHH requires that exposure be reduced as low as is reasonably practicable. Activities giving rise



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to short-term peak concentrations should receive particular attention when risk management is being considered. Health surveillance is appropriate for all employees exposed or liable to be exposed to a substance which may cause occupational asthma and there should be appropriate consultation with an occupational health professional over the degree of risk and level of surveillance., Capable of causing occupational asthma. The identified substances are those which: - are assigned the risk phrase 'R42: May cause sensitisation by inhalation'; or 'R42/43: May cause sensitisation by inhalation and skin contact' or - are listed in section C of HSE publication 'Asthmagen? Critical assessments of the evidence for agents implicated in occupational asthma' as updated from time to time, or any other substance which the risk assessment has shown to be a potential cause of occupational asthma., The 'Sen' notation in the list of WELs has been assigned only to those substances which may cause occupational asthma.

STEL 0.07 mg/m3 (as -NCO)

GB EH40

Further information Substances that can cause occupational asthma (also known as asthmagens and respiratory sensitisers) can induce a state of specific airway hyper-responsiveness via an immunological, irritant or other mechanism. Once the airways have become hyper-responsive, further exposure to the substance, sometimes even to tiny quantities, may cause respiratory symptoms. These symptoms can range in severity from a runny nose to asthma. Not all workers who are exposed to a sensitiser will become hyper-responsive and it is impossible to identify in advance those who are likely to become hyper-responsive. 54 Substances that can cause occupational asthma should be distinguished from substances which may trigger the symptoms of asthma in people with pre-existing airway hyper-responsiveness, but which do not include the disease themselves. The latter substances are not classified asthmagens or respiratory sensitisers., Wherever it is reasonably practicable, exposure to substances that can cause occupational asthma should be prevented. Where this is not possible, the primary aim is to apply adequate standards of control to prevent workers from becoming hyper-responsive. For substances that can cause occupational asthma, COSHH requires that exposure be reduced as low as is reasonably practicable. Activities giving rise to short-term peak concentrations should receive particular attention when risk management is being considered. Health surveillance is appropriate for all employees exposed or liable to be exposed to a substance which may cause occupational asthma and there should be appropriate consultation with an occupational health professional over the degree of risk and level of surveillance., Capable of causing occupational asthma. The identified substances are those which: - are assigned the risk phrase 'R42: May cause sensitisation by inhalation'; or 'R42/43: May cause sensitisation by inhalation and skin contact' or - are listed in section C of HSE publication 'Asthmagen? Critical assessments of the evidence for agents implicated in occupational asthma' as updated from time to time, or any other substance which the risk assessment has shown to be a potential cause of occupational asthma., The 'Sen' notation in the list of WELs has been assigned only to those substances which may cause occupational asthma.

TWA 0.02 mg/m3 (NCO)

GB EH40

Further information Substances that can cause occupational asthma (also known as asthmagens and respiratory sensitisers) can induce a state of specific airway hyper-responsiveness via an immunological, irritant or other mechanism. Once the airways have become hyper-responsive, further exposure to the substance,



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sometimes even to tiny quantities, may cause respiratory symptoms. These symptoms can range in severity from a runny nose to asthma. Not all workers who are exposed to a sensitiser will become hyper-responsive and it is impossible to identify in advance those who are likely to become hyper-responsive. 54 Substances that can cause occupational asthma should be distinguished from substances which may trigger the symptoms of asthma in people with pre-existing airway hyper-responsiveness, but which do not include the disease themselves. The latter substances are not classified asthmagens or respiratory sensitisers., Wherever it is reasonably practicable, exposure to substances that can cause occupational asthma should be prevented. Where this is not possible, the primary aim is to apply adequate standards of control to prevent workers from becoming hyper-responsive. For substances that can cause occupational asthma, COSHH requires that exposure be reduced as low as is reasonably practicable. Activities giving rise to short-term peak concentrations should receive particular attention when risk management is being considered. Health surveillance is appropriate for all employees exposed or liable to be exposed to a substance which may cause occupational asthma and there should be appropriate consultation with an occupational health professional over the degree of risk and level of surveillance., Capable of causing occupational asthma. The identified substances are those which: - are assigned the risk phrase 'R42: May cause sensitisation by inhalation'; or 'R42/43: May cause sensitisation by inhalation and skin contact' or - are listed in section C of HSE publication 'Asthmagen? Critical assessments of the evidence for agents implicated in occupational asthma' as updated from time to time, or any other substance which the risk assessment has shown to be a potential cause of occupational asthma., The 'Sen' notation in the list of WELs has been assigned only to those substances which may cause occupational asthma.

STEL 0.07 mg/m3 (NCO)

GB EH40

Further information Substances that can cause occupational asthma (also known as asthmagens and respiratory sensitisers) can induce a state of specific airway hyper-responsiveness via an immunological, irritant or other mechanism. Once the airways have become hyper-responsive, further exposure to the substance, sometimes even to tiny quantities, may cause respiratory symptoms. These symptoms can range in severity from a runny nose to asthma. Not all workers who are exposed to a sensitiser will become hyper-responsive and it is impossible to identify in advance those who are likely to become hyper-responsive. 54 Substances that can cause occupational asthma should be distinguished from substances which may trigger the symptoms of asthma in people with pre-existing airway hyper-responsiveness, but which do not include the disease themselves. The latter substances are not classified asthmagens or respiratory sensitisers., Wherever it is reasonably practicable, exposure to substances that can cause occupational asthma should be prevented. Where this is not possible, the primary aim is to apply adequate standards of control to prevent workers from becoming hyper-responsive. For substances that can cause occupational asthma, COSHH requires that exposure be reduced as low as is reasonably practicable. Activities giving rise to short-term peak concentrations should receive particular attention when risk management is being considered. Health surveillance is appropriate for all employees exposed or liable to be exposed to a substance which may cause occupational asthma and there should be appropriate consultation with an occupational health professional over the degree of risk and level of surveillance., Capable of causing occupational asthma. The identified



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substances are those which: - are assigned the risk phrase 'R42: May cause sensitisation by inhalation'; or 'R42/43: May cause sensitisation by inhalation and skin contact' or - are listed in section C of HSE publication 'Asthmagen? Critical assessments of the evidence for agents implicated in occupational asthma' as updated from time to time, or any other substance which the risk assessment has shown to be a potential cause of occupational asthma., The 'Sen' notation in the list of WELs has been assigned only to those substances which may cause occupational asthma.

Hexamethylene diisocyanate

822-06-0 TWA 0.02 mg/m3 (as -NCO)

GB EH40


STEL 0.07 mg/m3 (as -NCO)

GB EH40

Further information Substances that can cause occupational asthma (also known as asthmagens and respiratory sensitisers) can induce a state of specific airway hyper-responsiveness via an immunological, irritant or other mechanism. Once the airways have become hyper-responsive, further exposure to the substance, sometimes even to tiny quantities, may cause respiratory symptoms. These symptoms can range in severity from a runny nose to asthma. Not all workers who are exposed to a sensitiser will become hyper-responsive and it is impossible to identify in advance those who are likely to become hyper-responsive. 54 Substances that can cause occupational asthma should be distinguished from substances which may trigger the symptoms of asthma in



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people with pre-existing airway hyper-responsiveness, but which do not include the disease themselves. The latter substances are not classified asthmagens or respiratory sensitisers., Wherever it is reasonably practicable, exposure to substances that can cause occupational asthma should be prevented. Where this is not possible, the primary aim is to apply adequate standards of control to prevent workers from becoming hyper-responsive. For substances that can cause occupational asthma, COSHH requires that exposure be reduced as low as is reasonably practicable. Activities giving rise to short-term peak concentrations should receive particular attention when risk management is being considered. Health surveillance is appropriate for all employees exposed or liable to be exposed to a substance which may cause occupational asthma and there should be appropriate consultation with an occupational health professional over the degree of risk and level of surveillance., Capable of causing occupational asthma. The identified substances are those which: - are assigned the risk phrase 'R42: May cause sensitisation by inhalation'; or 'R42/43: May cause sensitisation by inhalation and skin contact' or - are listed in section C of HSE publication 'Asthmagen? Critical assessments of the evidence for agents implicated in occupational asthma' as updated from time to time, or any other substance which the risk assessment has shown to be a potential cause of occupational asthma., The 'Sen' notation in the list of WELs has been assigned only to those substances which may cause occupational asthma.

TWA 0.02 mg/m3 (NCO)

GB EH40

Further information Substances that can cause occupational asthma (also known as asthmagens and respiratory sensitisers) can induce a state of specific airway hyper-responsiveness via an immunological, irritant or other mechanism. Once the airways have become hyper-responsive, further exposure to the substance, sometimes even to tiny quantities, may cause respiratory symptoms. These symptoms can range in severity from a runny nose to asthma. Not all workers who are exposed to a sensitiser will become hyper-responsive and it is impossible to identify in advance those who are likely to become hyper-responsive. 54 Substances that can cause occupational asthma should be distinguished from substances which may trigger the symptoms of asthma in people with pre-existing airway hyper-responsiveness, but which do not include the disease themselves. The latter substances are not classified asthmagens or respiratory sensitisers., Wherever it is reasonably practicable, exposure to substances that can cause occupational asthma should be prevented. Where this is not possible, the primary aim is to apply adequate standards of control to prevent workers from becoming hyper-responsive. For substances that can cause occupational asthma, COSHH requires that exposure be reduced as low as is reasonably practicable. Activities giving rise to short-term peak concentrations should receive particular attention when risk management is being considered. Health surveillance is appropriate for all employees exposed or liable to be exposed to a substance which may cause occupational asthma and there should be appropriate consultation with an occupational health professional over the degree of risk and level of surveillance., Capable of causing occupational asthma. The identified substances are those which: - are assigned the risk phrase 'R42: May cause sensitisation by inhalation'; or 'R42/43: May cause sensitisation by inhalation and skin contact' or - are listed in section C of HSE publication 'Asthmagen? Critical assessments of the evidence for agents implicated in occupational asthma' as updated from time to time, or any other substance which the risk assessment has shown to be a potential cause of occupational asthma., The



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'Sen' notation in the list of WELs has been assigned only to those substances which may cause occupational asthma.

STEL 0.07 mg/m3 (NCO)

GB EH40


Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:

Substance name Environmental Compartment Value

hexamethylene-diisocyanate, homopolymer

Fresh water 0.05 mg/l

Marine water 0.005 mg/l

Freshwater - intermittent 0.5 mg/l

Sewage treatment plant 55.6 mg/l

Fresh water sediment 1.33 mg/kg

Marine sediment 0.133 mg/kg

Soil 0.066 mg/kg

Siloxanes and Silicones, di-Me, reaction products with silica

Fresh water sediment > 100 mg/kg



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Remarks: Assessment Factors

Soil 23 mg/kg

Assessment Factors

8.2 Exposure controls

Personal protective equipment

Eye protection : Eye wash bottle with pure water Tightly fitting safety goggles

Hand protection Material : butyl-rubber Break through time : > 8 h Material : Nitrile rubber Break through time : 10 - 480 min Material : Ethyl Vinyl Alcohol Laminate (EVAL) Break through time : > 8 h Remarks

: The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact). The suitability for a specific workplace should be discussed with the producers of the protective gloves.

Skin and body protection : Impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place.

Respiratory protection : Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Recommended Filter type: Combined particulates and organic vapour type

Filter type : Filter type A-P

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance

: paste

Colour

: opaque

Odour : slight



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Odour Threshold


pH


Melting point

: ca. -24 °C

Boiling point

: > 200 °C

Flash point

: 158 °C Method: Pensky-Martens closed cup

Evaporation rate


Flammability (solid, gas)


Burning rate


Upper explosion limit / Upper flammability limit


Lower explosion limit / Lower flammability limit


Vapour pressure

: < 0.0001 hPa (20 °C)

Relative vapour density


Relative density


Density

: 1.16 g/cm3

Solubility(ies) Water solubility

: Decomposes in contact with water. (20 °C)

Solubility in other solvents


Partition coefficient: n-octanol/water


Auto-ignition temperature


Decomposition temperature

: > 200 °C

Viscosity Viscosity, dynamic

: 12,000 - 18,000 mPa.s (25 °C)

Explosive properties


Oxidizing properties




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9.2 Other information

No data available

SECTION 10: Stability and reactivity

10.1 Reactivity

No decomposition if stored and applied as directed.

10.2 Chemical stability


10.3 Possibility of hazardous reactions

Hazardous reactions

: Decomposes when moist. No decomposition if stored and applied as directed.

10.4 Conditions to avoid

Conditions to avoid

: Exposure to moisture

10.5 Incompatible materials

Materials to avoid

: Strong acids and strong bases Strong oxidizing agents

10.6 Hazardous decomposition products

Carbon oxides Nitrogen oxides (NOx) Burning produces noxious and toxic fumes.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity

Components:

Hexamethylene diisocyanate: Acute oral toxicity

: LD50 (Rat, male): 959 mg/kg Method: OECD Test Guideline 401

LD50 (Rat, male): 746 mg/kg Method: OECD Test Guideline 401

Acute inhalation toxicity - Product

: Acute toxicity estimate : 1.08 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: Calculation method

Components:

Hexamethylene diisocyanate, oligomers:



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Acute dermal toxicity

: LD50 (Rabbit): > 5,000 mg/kg

Hexamethylene diisocyanate: Acute dermal toxicity

: LD50 (Rat, male and female): > 7,000 mg/kg Method: OECD Test Guideline 402

Acute toxicity (other routes of administration)

: No data available

Skin corrosion/irritation

Components:

Hexamethylene diisocyanate, oligomers: Species: Rabbit Assessment: Mild skin irritant Result: slight irritation Hexamethylene diisocyanate: Species: Rabbit Exposure time: 4 h Method: OECD Test Guideline 404 Result: Corrosive after 1 to 4 hours of exposure

Serious eye damage/eye irritation

Components:

Hexamethylene diisocyanate, oligomers: Species: Rabbit Assessment: Mild eye irritant Result: slight irritation Hexamethylene diisocyanate: Species: Rabbit Method: OECD Test Guideline 405 Result: Irreversible effects on the eye

Respiratory or skin sensitisation

Components:

Hexamethylene diisocyanate, oligomers: Exposure routes: Skin Species: Guinea pig Method: OECD Test Guideline 406 Result: May cause sensitisation by skin contact. Hexamethylene diisocyanate: Test Type: Maximisation Test Exposure routes: Skin Species: Rabbit Method: OECD Test Guideline 406 Result: May cause sensitisation by skin contact.



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Exposure routes: Respiratory Tract Species: Guinea pig Result: May cause sensitisation by inhalation.

Components:

Hexamethylene diisocyanate: Assessment: Harmful if inhaled., Causes skin irritation., Causes serious eye

irritation. May cause an allergic skin reaction., May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Germ cell mutagenicity

Components:

Hexamethylene diisocyanate, oligomers: Genotoxicity in vitro

: Metabolic activation: with and without metabolic activation Result: negative

Hexamethylene diisocyanate: Genotoxicity in vitro

: Test Type: In vitro mammalian cell gene mutation test Test system: Chinese hamster ovary cells Concentration: 1,0 - 10 ml Metabolic activation: with and without metabolic activation Result: negative

: Test Type: Ames test Test system: Salmonella typhimurium Concentration: 6, 12, 20, 25, 50 and 150 µL p Metabolic activation: with and without metabolic activation Result: negative

Components:

Hexamethylene diisocyanate: Genotoxicity in vivo

: Test Type: Micronucleus test Test species: Mouse (male and female) Cell type: Bone marrow Application Route: Inhalation Exposure time: 6 h Dose: 1.47 ppm Method: OECD Test Guideline 474 Result: negative

Carcinogenicity

Components:

Hexamethylene diisocyanate: Species: Rat, male and female



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Application Route: Inhalation Exposure time: 24 month(s) Dose: 0,164 ppm Frequency of Treatment: 6 hour Method: OECD Test Guideline 453 Result: negative Carcinogenicity - Assessment

: No data available

Reproductive toxicity

Components:

Hexamethylene diisocyanate: Effects on fertility : Species: Rat, male and female

Application Route: Inhalation Target Organs: Nasal inner lining Method: OECD Test Guideline 422 Result: negative

Components:

Hexamethylene diisocyanate: Effects on foetal development

: Species: Rat, male and female Application Route: Inhalation General Toxicity Maternal: No observed adverse effect level: 0.005 ppm Method: OECD Test Guideline 414 Result: No teratogenic effects

Reproductive toxicity - Assessment

: No data available

STOT - single exposure

Components:

Hexamethylene diisocyanate, oligomers: Exposure routes: Inhalation Target Organs: Respiratory Tract Assessment: May cause respiratory irritation. Hexamethylene diisocyanate: Exposure routes: Inhalation Target Organs: Respiratory Tract Assessment: Causes damage to organs.

STOT - repeated exposure

Components:

Hexamethylene diisocyanate: Target Organs: Nasal inner lining



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Assessment: Causes damage to organs through prolonged or repeated exposure.

Repeated dose toxicity

Components:

Hexamethylene diisocyanate, oligomers: Species: Rat : 3.7 - 4.3 Exposure time: 3 Weeks Species: Rat : 3.3 - 3.4 Exposure time: 2,160 h Hexamethylene diisocyanate: Species: Rat, male and female : 0.005 Application Route: inhalation (vapour) Test atmosphere: vapour Exposure time: 2 yrNumber of exposures: 6 h Method: OECD Test Guideline 453

Components:

Hexamethylene diisocyanate: Repeated dose toxicity - Assessment

: Harmful if inhaled., Causes skin irritation., Causes serious eye irritation.

Aspiration toxicity

No data available

Experience with human exposure

General Information: No data available

Inhalation: No data available

Skin contact: No data available

Eye contact: No data available

Ingestion: No data available

Toxicology, Metabolism, Distribution

No data available



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Neurological effects

No data available

Further information


SECTION 12: Ecological information

12.1 Toxicity

Components:


Toxicity to fish

: IC0 (Brachydanio rerio (zebrafish)): > 100 mg/l Exposure time: 96 h

Toxicity to daphnia and other aquatic invertebrates

: IC0 (Daphnia magna (Water flea)): > 100 mg/l Exposure time: 48 h

Toxicity to algae

: EC50 (Desmodesmus subspicatus (green algae)): > 1,000 mg/l Exposure time: 72 h

Toxicity to microorganisms

: EC50 (activated sludge): > 1,000 mg/l Exposure time: 3 h

Hexamethylene diisocyanate:

Toxicity to fish

: LC50 (Brachydanio rerio (zebrafish)): > 82.8 mg/l Exposure time: 96 h Test Type: static test Test substance: Fresh water Method: Directive 67/548/EEC, Annex V, C.1.


: EC50 (Daphnia magna (Water flea)): > 89.1 mg/l Exposure time: 48 h Test Type: static test Test substance: Fresh water Method: Directive 67/548/EEC, Annex V, C.2.

Toxicity to algae

: EgC50 (Desmodesmus subspicatus (green algae)): > 77.4 mg/l Exposure time: 72 h Test Type: static test Test substance: Fresh water Method: Directive 67/548/EEC, Annex V, C.3.


: EC50 (activated sludge): 842 mg/l Exposure time: 3 h Test Type: static test Test substance: Fresh water



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Method: OECD Test Guideline 209

Ecotoxicology Assessment Acute aquatic toxicity

: This product has no known ecotoxicological effects.

Chronic aquatic toxicity

: This product has no known ecotoxicological effects.

12.2 Persistence and degradability

Components:


Biodegradability

: Result: Not readily biodegradable. Biodegradation: 0 % Exposure time: 28 d

Hexamethylene diisocyanate:

Biodegradability

: Inoculum: activated sludge Concentration: 100 mg/l Result: Not readily biodegradable. Biodegradation: 48 % Exposure time: 28 d Method: OECD Test Guideline 301F

12.3 Bioaccumulative potential

Components:

Hexamethylene diisocyanate: Bioaccumulation

: Bioconcentration factor (BCF): 3.2 Remarks: Bioaccumulation is unlikely.

12.4 Mobility in soil

Components:

Hexamethylene diisocyanate: Distribution among environmental compartments

: Koc: 1665 - 5861

12.5 Results of PBT and vPvB assessment

Product:

Assessment

: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher..

12.6 Other adverse effects

No data available

SECTION 13: Disposal considerations

13.1 Waste treatment methods



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Product : Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company.

Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers.

SECTION 14: Transport information

IATA Not regulated as dangerous goods

IMDG Not regulated as dangerous goods

ADR

Not regulated as dangerous goods

RID


Transport in bulk according to Annex II of Marpol and the IBC Code

Not applicable for product as supplied.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59).

: This product does not contain substances of very high concern (Regulation (EC) No 1907/2006 (REACH), Article 57).

REACH - List of substances subject to authorisation (Annex XIV)

: Not applicable

REACH - List of substances subject to authorisation - Future sunset date

: Not applicable

Other regulations:

Take note of Directive 94/33/EC on the protection of young people at work or stricter national regulations, where applicable.

The components of this product are reported in the following inventories:

DSL

: All components of this product are on the Canadian DSL



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AICS

: On the inventory, or in compliance with the inventory

NZIoC


ENCS


KECI


PICCS


IECSC


TCSI


TSCA


Inventories

AICS (Australia), DSL (Canada), IECSC (China), ENCS (Japan), KECI (Korea), NZIOC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (United States of America (USA))

15.2 Chemical safety assessment

SECTION 16: Other information

Full text of H-Statements

H302 : Harmful if swallowed. H314 : Causes severe skin burns and eye damage. H317 : May cause an allergic skin reaction. H330 : Fatal if inhaled. H332 : Harmful if inhaled. H334 : May cause allergy or asthma symptoms or breathing

difficulties if inhaled. H335 : May cause respiratory irritation.

Full text of other abbreviations

Acute Tox. : Acute toxicity Resp. Sens. : Respiratory sensitisation Skin Corr. : Skin corrosion Skin Sens. : Skin sensitisation STOT SE : Specific target organ toxicity - single exposure GB EH40 : UK. EH40 WEL - Workplace Exposure Limits GB EH40 / TWA : Long-term exposure limit (8-hour TWA reference period) GB EH40 / STEL : Short-term exposure limit (15-minute reference period)



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Further information

Classification of the mixture: Classification procedure:

Acute Tox. 4 H332 Calculation method

Skin Sens. 1 H317 Calculation method

STOT SE 3 H335 Calculation method

While the information and recommendations in this publication are to the best of our knowledge, information and belief accurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY, EXPRESS OR OTHERWISE.

IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY OF SUCH INFORMATION AND RECOMMENDATIONS AND THE SUITABILITY OF ANY PRODUCT FOR ITS OWN PARTICULAR PURPOSE.

THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE CERTAIN HAZARDS ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.

Hazards, toxicity and behaviour of the products may differ when used with other materials and are dependent upon the manufacturing circumstances or other processes. Such hazards, toxicity and behaviour should be determined by the user and made known to handlers, processors and end users.

The trademarks above are the property of Huntsman Corporation or an affiliate thereof.

NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO PROVIDE OR MAKE AVAILABLE DATA SHEETS FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM UNAUTHORIZED SOURCES MAY CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE.


ARALDITE® 2018 POLYOL (XD 4446)

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SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Trade name

: ARALDITE® 2018 POLYOL (XD 4446)

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the Substance/Mixture

: Adhesives and/or sealants

1.3 Details of the supplier of the safety data sheet

Company : Huntsman Advanced Materials (Europe)BVBA Address : Everslaan 45

3078 Everberg Belgium

Telephone : +41 61 299 20 41 Telefax : +41 61 299 20 40 E-mail address of person responsible for the SDS

: [email protected]

1.4 Emergency telephone number

Emergency telephone number : EUROPE: +32 35 75 1234 France ORFILA: +33(0)145425959 ASIA: +65 6336-6011 China: +86 20 39377888 +86 532 83889090 India: + 91 22 42 87 5333 Australia: 1800 786 152 New Zealand: 0800 767 437 USA: +1/800/424.9300

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Chronic aquatic toxicity, Category 3

H412: Harmful to aquatic life with long lasting effects.

Chronic aquatic toxicity, Category 3

H412: Harmful to aquatic life with long lasting effects.

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

Hazard statements

: H412 Harmful to aquatic life with long lasting effects.



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Precautionary statements

: Prevention: P273 Avoid release to the environment. Disposal: P501 Dispose of contents/container to an

approved facility in accordance with local, regional, national and international regulations.

Additional Labelling:

EUH208 Contains: 3-Aminopropyltriethoxysilane, bis(dodecylthio)dioctylstannane. May produce an allergic reaction.

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

SECTION 3: Composition/information on ingredients

3.2 Mixtures

Hazardous components

Chemical name CAS-No. EC-No. Index-No. Registration number

Classification Concentration

(% w/w)

1,1'-Isopropylidenebis(p-phenyleneoxy)dipropan-2-ol

116-37-0 204-137-9 01-2119888247-23

Aquatic Chronic 2; H411

>= 2.5 - < 10

3-Aminopropyltriethoxysilane 919-30-2 213-048-4 612-108-00-0 01-2119480479-24

Acute Tox. 4; H302 Skin Corr. 1B; H314 Skin Sens. 1; H317

>= 0.1 - < 1

bis(dodecylthio)dioctylstannane 22205-30-7 244-841-3

Acute Tox. 4; H302 Skin Sens. 1; H317 Repr. 2; H361 STOT RE 1; H372 Aquatic Chronic 4; H413

>= 0.1 - < 1

For explanation of abbreviations see section 16.

SECTION 4: First aid measures

4.1 Description of first aid measures

General advice

: Do not leave the victim unattended.

If inhaled

: If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician.



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In case of skin contact

: Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. If symptoms persist, call a physician.

In case of eye contact

: Remove contact lenses. Protect unharmed eye. If eye irritation persists, consult a specialist.

If swallowed

: Keep respiratory tract clear. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician.

4.2 Most important symptoms and effects, both acute and delayed

None known.

4.3 Indication of any immediate medical attention and special treatment needed

Treatment

: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored for at least 48 hours.

SECTION 5: Firefighting measures

5.1 Extinguishing media

5.2 Special hazards arising from the substance or mixture

Specific hazards during firefighting

: Do not allow run-off from fire fighting to enter drains or water courses.

Hazardous combustion products


5.3 Advice for firefighters

Special protective equipment for firefighters

: Wear self-contained breathing apparatus for firefighting if necessary.

Specific extinguishing methods


Further information : Collect contaminated fire extinguishing water separately. This

must not be discharged into drains.Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.



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SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions


6.2 Environmental precautions

Environmental precautions

: Prevent product from entering drains. If the product contaminates rivers and lakes or drains inform respective authorities.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up

: Wipe up with absorbent material (e.g. cloth, fleece). Keep in suitable, closed containers for disposal.

6.4 Reference to other sections

See Section 1 for emergency contact information. For personal protection see section 8. For disposal considerations see section 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on safe handling

: For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area.

Advice on protection against fire and explosion

: Normal measures for preventive fire protection.

Hygiene measures

: Handle in accordance with good industrial hygiene and safety practice. When using do not eat, drink or smoke. Wash hands before breaks and at the end of workday.

7.2 Conditions for safe storage, including any incompatibilities

Recommended storage temperature

: 2 - 40 °C

Further information on storage stability

: No decomposition if stored and applied as directed.

7.3 Specific end use(s)

Specific use(s)

: No data available



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SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure Limits

Components CAS-No. Value type (Form of exposure)

Control parameters Basis

bis(dodecylthio)dioctylstannane

22205-30-7 TWA 0.1 mg/m3 (Tin)

GB EH40

Further information Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity.

STEL 0.2 mg/m3 (Tin)

GB EH40

Further information Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity.

Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:

Substance name End Use Exposure routes Potential health effects

Value

.epsilon.-Caprolactone, oligomeric reaction products with propylidynetrimethanol

Workers Inhalation Long-term systemic effects

3.5 mg/m3

Workers Dermal Long-term systemic effects

1.1 mg/kg

Consumers Inhalation Long-term systemic effects

1 mg/m3

Consumers Dermal Long-term systemic effects

0.6 mg/kg

Consumers Oral Long-term systemic effects

0.6 mg/kg


Workers Dermal Long-term systemic effects

1.74 mg/kg


12.2 mg/m3

Workers Inhalation Systemic effects 12.2 mg/m3


1.04 mg/kg


3.6 mg/m3

Consumers Inhalation Systemic effects 3.6 mg/m3


1.04 mg/kg

Epsilon-Caprolactone, oligomeric reaction products with propylidynetrimethanol


3.5 mg/m3

Workers Dermal Long-term systemic 1.1 mg/kg



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effects


1 mg/m3


0.6 mg/kg


0.6 mg/kg

Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:

Substance name Environmental Compartment Value

.epsilon.-Caprolactone, oligomeric reaction products with propylidynetrimethanol




Sewage treatment plant 670 mg/l


Fresh water 2.3 µg/l

Marine water 0.23 µg/l

Freshwater - intermittent 23 µg/l


Fresh water sediment 0.64 mg/kg

Marine sediment 0.064 mg/kg

Soil 0.13 mg/kg

Epsilon-Caprolactone, oligomeric reaction products with propylidynetrimethanol





Siloxanes and Silicones, di-Me, reaction products with silica

Fresh water sediment > 100 mg/kg

Remarks: Assessment Factors

Soil 23 mg/kg

Assessment Factors

8.2 Exposure controls

Personal protective equipment

Eye protection : Safety glasses

Hand protection Material : butyl-rubber Break through time : > 8 h



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Material : Nitrile rubber Break through time : 10 - 480 min Material : Ethyl Vinyl Alcohol Laminate (EVAL) Break through time : > 8 h Remarks

: The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact). The suitability for a specific workplace should be discussed with the producers of the protective gloves.

Skin and body protection : Protective suit

Respiratory protection : Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Recommended Filter type: Combined particulates and organic vapour type

Filter type : Filter type A-P

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance

: paste

Colour

: opaque

Odour

: slight

Odour Threshold


pH


Freezing point


Melting point


Boiling point

: > 250 °C

Flash point

: > 250 °C Method: Pensky-Martens closed cup, closed cup

Evaporation rate




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Flammability (solid, gas)


Burning rate


Upper explosion limit / Upper flammability limit


Lower explosion limit / Lower flammability limit


Vapour pressure

: < 2 hPa (20 °C)

Relative vapour density


Relative density


Density

: 1.1 g/cm3 (20 °C)

Solubility(ies) Water solubility

: practically insoluble (20 °C)

Solubility in other solvents




Auto-ignition temperature


Decomposition temperature

: > 250 °C

Viscosity Viscosity, dynamic

: 3,000 - 6,000 mPa.s (25 °C)

Explosive properties


Oxidizing properties


9.2 Other information

No data available

SECTION 10: Stability and reactivity

10.1 Reactivity


10.2 Chemical stability


10.3 Possibility of hazardous reactions

Hazardous reactions

: Stable under recommended storage conditions. No hazards to be specially mentioned.



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10.4 Conditions to avoid

Conditions to avoid

: No data available

10.5 Incompatible materials

10.6 Hazardous decomposition products

Burning produces noxious and toxic fumes.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity

Components:

2-propanol, 1,1'-{(1-methylethyllidene)bis-(4,1-phenyleneoxy)}bis-: Acute oral toxicity

: LD50 (Rat, male and female): > 2.75 - < 3.3 g/kg Method: OECD Test Guideline 401 Assessment: The component/mixture is minimally toxic after single ingestion.

3-aminopropyltriethoxysilane: Acute oral toxicity

: LD50 (Rat, male and female): 1,491 - 2,688 mg/kg Method: EPA OTS 798.1175

Bis-(dodecylthio)-dioctylstannane: Acute oral toxicity

: LD50 (Rat): < 2,000 mg/kg Assessment: The component/mixture is moderately toxic after single ingestion.

Components:

3-aminopropyltriethoxysilane: Acute inhalation toxicity

: LC50 (Rat, male): > 5 ppm Exposure time: 6 h Test atmosphere: vapour Method: OECD Test Guideline 403

Components:

2-propanol, 1,1'-{(1-methylethyllidene)bis-(4,1-phenyleneoxy)}bis-: Acute dermal toxicity

: LD50 (Rat, male and female): > 2,000 mg/kg Method: OECD Test Guideline 402 Assessment: The substance or mixture has no acute dermal toxicity

3-aminopropyltriethoxysilane: Acute dermal toxicity

: LD50 (Rabbit, male and female): 4,075 mg/kg Method: Acute dermal toxicity



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Assessment: The substance or mixture has no acute dermal toxicity

Acute toxicity (other routes of administration)

: No data available

Skin corrosion/irritation

Components:

2-propanol, 1,1'-{(1-methylethyllidene)bis-(4,1-phenyleneoxy)}bis-: Species: Rabbit Assessment: No skin irritation Result: No skin irritation 3-aminopropyltriethoxysilane: Species: Rabbit Method: OECD Test Guideline 404 Result: Causes burns.

Serious eye damage/eye irritation

Components:

2-propanol, 1,1'-{(1-methylethyllidene)bis-(4,1-phenyleneoxy)}bis-: Species: Rabbit Assessment: No eye irritation Method: OECD Test Guideline 405 Result: No eye irritation 3-aminopropyltriethoxysilane: Species: Rabbit Method: OECD Test Guideline 405 Result: Risk of serious damage to eyes. Bis-(dodecylthio)-dioctylstannane: Species: Rabbit Result: No eye irritation

Respiratory or skin sensitisation

Components:

2-propanol, 1,1'-{(1-methylethyllidene)bis-(4,1-phenyleneoxy)}bis-: Exposure routes: Skin Species: Mouse Method: OECD Test Guideline 429 Result: Does not cause skin sensitisation. 3-aminopropyltriethoxysilane: Exposure routes: Skin Species: Guinea pig Method: OECD Test Guideline 406 Result: The product is a skin sensitiser, sub-category 1B.



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Bis-(dodecylthio)-dioctylstannane: Exposure routes: Skin Species: Guinea pig Result: May cause sensitisation by skin contact. Assessment: No data available

Germ cell mutagenicity

Components:

2-propanol, 1,1'-{(1-methylethyllidene)bis-(4,1-phenyleneoxy)}bis-: Genotoxicity in vitro

: Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476 Result: negative



3-aminopropyltriethoxysilane: Genotoxicity in vitro


Components:

2-propanol, 1,1'-{(1-methylethyllidene)bis-(4,1-phenyleneoxy)}bis-: Genotoxicity in vivo

: Test Type: Micronucleus test Test species: Mouse (male) Cell type: Bone marrow Dose: 500, 1000, 2000 mg/kg body Method: OECD Test Guideline 474

3-aminopropyltriethoxysilane: Genotoxicity in vivo

: Application Route: Intraperitoneal injection Method: OECD Test Guideline 474 Result: negative

Carcinogenicity

No data available Carcinogenicity - : No data available



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Assessment

Reproductive toxicity

Components:

2-propanol, 1,1'-{(1-methylethyllidene)bis-(4,1-phenyleneoxy)}bis-: Effects on fertility : Species: Rat, male and female

Application Route: Oral General Toxicity - Parent: No observed adverse effect level: 125 mg/kg body weight Fertility: No observed adverse effect level: 250 mg/kg body weight Early Embryonic Development: No observed adverse effect level: > 500 mg/kg body weight Method: OECD Test Guideline 422

Components:

2-propanol, 1,1'-{(1-methylethyllidene)bis-(4,1-phenyleneoxy)}bis-: Effects on foetal development

: Species: Rat, female Application Route: Oral Dose: 0, 40, 100, 250 milligram per kilogram General Toxicity Maternal: No observed adverse effect level: 100 mg/kg body weight Developmental Toxicity: No observed adverse effect level: > 250 mg/kg body weight Method: OECD Test Guideline 414 Result: No teratogenic effects

Components:

Bis-(dodecylthio)-dioctylstannane: Reproductive toxicity - Assessment

: Suspected human reproductive toxicant

STOT - single exposure

No data available

STOT - repeated exposure

Components:

Bis-(dodecylthio)-dioctylstannane: Exposure routes: Ingestion Target Organs: Immune system Assessment: Causes damage to organs through prolonged or repeated exposure.

Repeated dose toxicity

Components:

2-propanol, 1,1'-{(1-methylethyllidene)bis-(4,1-phenyleneoxy)}bis-: Species: Rat, male and female NOAEL: 125 mg/kg Application Route: Ingestion



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Exposure time: 696 hNumber of exposures: 7 d Method: Subacute toxicity 3-aminopropyltriethoxysilane: Species: Rat, male and female NOAEL: 200 mg/kg Application Route: Ingestion Exposure time: 2,160 hMethod: Subchronic toxicity Repeated dose toxicity - Assessment

: No data available

Aspiration toxicity

No data available

Experience with human exposure

General Information: No data available

Inhalation: No data available

Skin contact: No data available

Eye contact: No data available


Toxicology, Metabolism, Distribution

No data available

Neurological effects

No data available

Further information




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SECTION 12: Ecological information

12.1 Toxicity

Components:

2-propanol, 1,1'-{(1-methylethyllidene)bis-(4,1-phenyleneoxy)}bis-:

Toxicity to fish

: LC50 (Cyprinus carpio (Carp)): 8.8 mg/l Exposure time: 96 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 203


: EC50 (Daphnia magna (Water flea)): 2.3 mg/l Exposure time: 48 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 202

Toxicity to algae

: EC50 (Selenastrum capricornutum (green algae)): 28 mg/l Exposure time: 72 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 201

NOEC (Selenastrum capricornutum (green algae)): 2.5 mg/l Exposure time: 72 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 201


: EC50 (activated sludge): > 100 mg/l Exposure time: 3 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 209

Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity)

: 1 mg/l Exposure time: 21 d Species: Daphnia magna (Water flea) Test Type: semi-static test Method: OECD Test Guideline 211

3-aminopropyltriethoxysilane:

Toxicity to fish

: LC50 (Brachydanio rerio (zebrafish)): > 934 mg/l Exposure time: 96 h Test Type: semi-static test Test substance: Fresh water Method: OECD Test Guideline 203


: EC50 (Daphnia magna (Water flea)): 331 mg/l Exposure time: 48 h Test Type: static test Test substance: Fresh water



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Method: OECD Test Guideline 202

Toxicity to algae

: EC50 (Desmodesmus subspicatus (green algae)): > 1,000 mg/l Exposure time: 72 h Test Type: static test Test substance: Fresh water Method: Directive 67/548/EEC, Annex V, C.3.


: EC50 (Pseudomonas putida): 43 mg/l Exposure time: 5.75 h Test Type: static test Test substance: Fresh water

Bis-(dodecylthio)-dioctylstannane: Ecotoxicology Assessment Chronic aquatic toxicity

: May cause long lasting harmful effects to aquatic life.

12.2 Persistence and degradability

Components:

2-propanol, 1,1'-{(1-methylethyllidene)bis-(4,1-phenyleneoxy)}bis-:

Biodegradability

: Inoculum: activated sludge Concentration: 200 mg/l Result: Not biodegradable Biodegradation: 60 % Exposure time: 98 d Method: OECD Test Guideline 301D

Stability in water

: Degradation half life (DT50): > 1 yr (25 °C) pH: 7 Method: OECD Test Guideline 111 Remarks: Fresh water

Degradation half life (DT50): > 1 yr (25 °C) pH: 4 Method: OECD Test Guideline 111 Remarks: Fresh water

Degradation half life (DT50): > 1 yr (25 °C) pH: 9 Method: OECD Test Guideline 111 Remarks: Fresh water

3-aminopropyltriethoxysilane:

Biodegradability

: Inoculum: activated sludge Concentration: 8.95 mg/l Result: Not readily biodegradable. Biodegradation: 67 % Exposure time: 28 d Method: Directive 67/548/EEC Annex V, C.4.A.

Bis-(dodecylthio)-dioctylstannane:



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Biodegradability

: Result: Not readily biodegradable. Biodegradation: < 60 % Exposure time: 28 d

12.3 Bioaccumulative potential

Components:

2-propanol, 1,1'-{(1-methylethyllidene)bis-(4,1-phenyleneoxy)}bis-: Partition coefficient: n-octanol/water

: log Pow: 3.3 - 3.6 (25 °C) pH: 7 Method: OECD Test Guideline 117

3-aminopropyltriethoxysilane: Bioaccumulation

: Species: Cyprinus carpio (Carp) Bioconcentration factor (BCF): 3.4 Remarks: Does not bioaccumulate.


: log Pow: 1.7 (20 °C) pH: 7

12.4 Mobility in soil

Components:

2-propanol, 1,1'-{(1-methylethyllidene)bis-(4,1-phenyleneoxy)}bis-: Distribution among environmental compartments

: Koc: 1819 - 2754 Method: OECD Test Guideline 121

12.5 Results of PBT and vPvB assessment

Product:

Assessment

: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher..

12.6 Other adverse effects

Product:

Additional ecological information

: An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Harmful to aquatic life with long lasting effects.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

SECTION 14: Transport information

IATA Not regulated as dangerous goods



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IMDG Not regulated as dangerous goods

ADR


RID


Transport in bulk according to Annex II of Marpol and the IBC Code

Not applicable for product as supplied.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59).

: This product does not contain substances of very high concern (Regulation (EC) No 1907/2006 (REACH), Article 57).

REACH - List of substances subject to authorisation (Annex XIV)

: Not applicable

REACH - List of substances subject to authorisation - Future sunset date

: Not applicable

The components of this product are reported in the following inventories:

DSL

: All components of this product are on the Canadian DSL

AICS


NZIoC

: Not in compliance with the inventory

ENCS


KECI


PICCS


IECSC


TCSI




Version

1.1

Revision Date:

27.03.2018

SDS Number: 400001008394


SDS_GB-AM – – 400001008394 18 / 19

TSCA


Inventories

AICS (Australia), DSL (Canada), IECSC (China), ENCS (Japan), KECI (Korea), NZIOC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (United States of America (USA))

15.2 Chemical safety assessment

SECTION 16: Other information

Full text of H-Statements

H302 : Harmful if swallowed. H314 : Causes severe skin burns and eye damage. H317 : May cause an allergic skin reaction. H361 : Suspected of damaging fertility or the unborn child. H372 : Causes damage to organs through prolonged or repeated

exposure if swallowed. H411 : Toxic to aquatic life with long lasting effects. H413 : May cause long lasting harmful effects to aquatic life.

Full text of other abbreviations

Acute Tox. : Acute toxicity Aquatic Chronic : Chronic aquatic toxicity Repr. : Reproductive toxicity Skin Corr. : Skin corrosion Skin Sens. : Skin sensitisation STOT RE : Specific target organ toxicity - repeated exposure GB EH40 : UK. EH40 WEL - Workplace Exposure Limits GB EH40 / TWA : Long-term exposure limit (8-hour TWA reference period) GB EH40 / STEL : Short-term exposure limit (15-minute reference period)

Further information

Classification of the mixture: Classification procedure:

Aquatic Chronic 3 H412 Calculation method

Aquatic Chronic 3 H412 Calculation method

While the information and recommendations in this publication are to the best of our knowledge, information and belief accurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY, EXPRESS OR OTHERWISE.

IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY OF SUCH INFORMATION AND RECOMMENDATIONS AND THE SUITABILITY OF ANY PRODUCT FOR ITS OWN PARTICULAR PURPOSE.



Version

1.1

Revision Date:

27.03.2018

SDS Number: 400001008394


SDS_GB-AM – – 400001008394 19 / 19

THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE CERTAIN HAZARDS ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.

Hazards, toxicity and behaviour of the products may differ when used with other materials and are dependent upon the manufacturing circumstances or other processes. Such hazards, toxicity and behaviour should be determined by the user and made known to handlers, processors and end users.

The trademarks above are the property of Huntsman Corporation or an affiliate thereof.

NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO PROVIDE OR MAKE AVAILABLE DATA SHEETS FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM UNAUTHORIZED SOURCES MAY CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE.

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