AMINESAN EXTENSIVE CHOICE TO MEET YOUR INDUSTRIES

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AgrochemicalsCoating

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Resins

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Arkema’s amines are used in a wide variety of applications

and markets:

• Pharmaceuticals• Agrochemicals• Paints & Coatings• Foundry & Resins• Polymerization• Water treatment• Personal care

Arkema offers an extensive choice of amines including:

>Basic Alkylamines

• Monoethylamine 70%, Aqueous (MEA 70%)• Diethylamine (DEA)• Triethylamine (TEA)• Monoisopropylamine, Anhydrous (MIPA)• Monoisopropylamine 70%, Aqueous (MIPA 70%)• Diisopropylamine (DIPA)

>Specialty Amines

• Diethylaminopropylamine (DEAPA)• Dimethylaminopropylaminopropylamine (DMAPAPA)• Ethyl Diisopropylamine (EDIPA)• Tetramethyl Propylenediamine (TMPDA)• 3- Isopropoxypropylamine (IPOPA)• 3- Methoxypropylamine (MOPA)• Ethylmethylamine (EMA)• Sec-Butylamine (B2A)

>Foundry Amines

• Dimethyl Ethylamine (DMEA)• Dimethyl Isopropylamine (DMIPA)

>Alkylhydroxylamines

• PENNSTOP® 85%, Aqueous (DEHA 85%)• PENNSTOP®, Anhydrous (DEHA)• Term-N-ator P®

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Amines>

NH2

NH

NH2

NH2

NH

NH2 N

NH NH2 N

N

N N

NH2 O

NH2 O

NH

N

N

N OH

PRODUCT FORMULA PURITY CAS# GMW DENSITY pKa1 FLASH POINT BOILING POINT VAPOR PRESSURE(ABBREVIATION) (20°C) (TAG)2 (760mm Hg) (20°C)

BASIC ALKYLAMINES

MEA 70% 99.5% 75-04-7 45.1 0.809 10.80 -10,5°C 35°C 430 mm Hg(Monoethylamine 70%, Aqueous)

DEA 99% 109-89-7 73.1 0.705 11.07 -28°C 56°C 195 mm Hg(Diethylamine)

TEA 99.5% 121-44-8 101.2 0.728 10.80 -6°C 89°C 52 mm Hg(Triethylamine)

MIPA 99.5% 75-31-0 59.1 0.690 10.72 -34°C 33°C 470 mm Hg(Monoisopropylamine, Anhydrous)

MIPA 70% 99.5% 75-31-0 59.1 0.818 10.72 -21°C 53°C 276 mm Hg(Monoisopropylamine 70%, Aqueous)

DIPA 99% 108-18-9 101.2 0.714 11.16 -9°C 84°C 50 mm Hg(Diisopropylamine)

SPECIALTY AMINES

DEAPA 99% 104-78-9 130.2 0.824 10.60 52°C 169°C 5.3 mm Hg (Diethylaminopropylamine) 8.56 (30°C)

DMAPAPA 98.5% 10563-29-8 159.3 0.873 10.47 99°C 220°C < 1 mm Hg(Dimethylaminopropylaminopropylamine) 9.15

7.33

EDIPA 99% 7087-68-5 129.2 0.754 11.26 12°C 127°C 12 mm Hg(Ethyldiisopropylamine) (25°C)

TMPDA 99% 110-95-2 130.2 0.784 9.82 31°C 145°C 9 mm Hg(Tetramethylpropylenediamine) 7.77 (30°C)

IPOPA 98% 2906-12-9 117.2 0.840 10.12 42°C 147°C 30 mm Hg (3-Isopropoxypropylamine) (30°C)

MOPA 99% 5332-73-0 89.1 0.869 10.15 26°C 118°C 11 mm Hg(3-Methoxypropylamine)

EMA 99.5% 624-78-2 59.1 0.680 11.06 -38°C 33°C 472 mm Hg(Ethylmethylamine)

DMEA 99% 598-56-1 73.1 0.678 10.15 -36°C 37°C 395 mm Hg(Dimethylethylamine)

DMIPA 99% 996-35-0 87.2 0.713 10.49 -26°C 67°C 132 mm Hg(Dimethylisopropylamine)

B2A 99% 13952-84-6 73.1 0.721 10.66 -16°C 62°C 215 mm Hg(Sec-Butylamine)

ALKYLHYDROXYLAMINES

PENNSTOP® 85%, Aqueous 85% 3710-84-7 89.1 0.898 5.61 46°C 125°C 32 mm Hg(DEHA 85%)

PENNSTOP®, Anhydrous 98% 3710-84-7 89.1 0.870 5.61 50°C 133°C 5 mm Hg(DEHA)

Term-N-ator P® 85% 3710-84-7 89.1 0.898 5.61 46°C 125°C 32 mm Hg1 Measurements refer to the protonated amine at 25°C in aqueous solution2 Flash points were determined by the TAG closed cup method 3 The actual solubility of 85% PENNSTOP in water is 41% (0.35/0.85). The solubility quoted is that of neat PENNSTOP in water

NH2

N

Quality

Arkema has a long history of manufacturing amines at its facility located in the heart of the Alps, in La Chambre(France). To meet your most stringent requirements towardsexcellence, our plant is ISO 9001 and 14001, certified to thehighest standards of quality and efficiency.

Core competencies

Arkema has developed core competencies in manufacturingamines by a variety of processes including alcohol aminationand reductive amination of aldehydes & ketones. Our dedicatedspecialty amines multipurpose equipment provides the flexibility to carry out many other reactions: methylation, cyanoethylation, hydrogenation of nitriles and high-pressurehydrogenation.

Research & Development

Our research and development capabilities are committed tothe rapid definition of your process and sound developmentthrough our extensive and reactive pilot capability to commercialvolumes. This tool will provide the correct answer to your specific needs. Please, do not hesitate to contact us and let’s get started on finding the right amine for your specificapplication: we are open to partnerships.

We are committed to providing fast and confidential analysisof your manufacturing needs.

A flexible production tool to meetyour current needs

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Markets and Applications

Agrochemicals: MIPA – DIPA - B2A - MEA - DEA – TEA

� Alkylamines are important chemical intermediates forthe manufacture of many types of herbicides, pesticides andinsecticides.

MIPA is used for the neutralization of glyphosate in the formulation of herbicides.B2A is a building block for some herbicidal chemicals (suchas organophosphorus and toluidine herbicides)

� DEAPA, DMAPAPA and TMPDA are used as hardeners oraccelerators in some epoxy based adhesives or paints.

TEA is often utilized for the neutralization of various kinds ofresins.

� Many API require the use of amines in their synthesissuch as TEA, DIPA, EMA, and DMEA.

Tertiary amines are also utilized as acid scavenger in many reactions, from moderate selectivity such as TEA to highselectivity such as EDIPA.

� Pennstop®, based on DEHA technology, acts as oxygen scavenger in steam boilers and thus prevents corrosions ofthe metal parts.

MOPA and IPOPA acts as neutralizing agents of carbonic acidity.We also develop some new technologies as neutralizingagents or oxygen scavenger in order to replace hazardouschemistries.

Adhesives, Paints & Coatings: DEA - TEA - TMPDA - DEAPA – DMAPAPA – IPOPA

Pharmaceuticals: MEA - DEA – TEA - MIPA - DIPA - EMA – DMEA - EDIPA

Water treatment: DEHA - MOPA – IPOPA

� Amines can be used as building blocks for wide range ofmonomers and polymers.DEHA is widely used as shortstopper and emergency killer in theradical polymerization of SBR in emulsion.

It also acts as monomer stabilizer to avoid their polymerizationduring storage (butadiene, styrene, chloroprene...).Term-N-ator P exhibits outstanding properties as shortstopperfor the polymerization of PVC in suspension.

Polymerization: DEHA

� We propose a wide range of tertiary amines such as TEA,DMIPA and DMEA for the foundry industry.

They are used as catalyst in the manufacturing of sand corebound by a polyurethane resin.

Foundry & Resins: DMEA - DMIPA – TEA

� Textile, Cosmetics, Perfume, Oil and Petrochemicalsindustry, Personal Care, Inks, Rubber…

This is a non-exhaustive list of the possible applications for Arkema’s amines.

Other markets:

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The statements, technical information and recommendations contained herein are believed to be accurate as of the date hereof. Since the conditions and methods of use ofthe product and of the information referred to herein are beyond our control, Arkema expressly disclaims any and all liability as to any results obtained or arising from anyuse of the product or reliance on such information; NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY,EXPRESS OR IMPLIED, IS MADE CONCERNING THE GOODS DESCRIBED OR THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to thespecific product designated and may not be applicable when such product is used in combination with other materials or in any process. The user should thoroughly test anyapplication before commercialization. Nothing contained herein constitutes a license to practice under any patent and it should not be construed as an inducement toinfringe any patent and the user is advised to take appropriate steps to be sure that any proposed use of the product will not result in patent infringement.See MSDS for Health & Safety Considerations

The information contained in this document is based on trials carried out by our Research Centres and data selected from the literature, but shall in no event be held to constituteor imply any warranty, undertaking, express or implied commitment from our part. Our formal specifications define the limit of our commitment. No liability whatsoever canbe accepted by Arkema with regard to the handling, processing or use of the product or products concerned which must in all cases be employed in accordance with all relevantlaws and/or regulations in force in the country or countries concerned.

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420, rue d'Estienne d'Orves 92700 Colombes (France) Tel: +33 (0)1 49 00 80 80 Fax: +33 (0)1 49 00 83 96 www.arkema.com

SINGAPOREArkema PTE Ltd.10 Science Park Road #01-01AThe AlphaSingapore Science Park 2,Singapore 117684SingaporePhone: +65 64 19 91 99 Fax: +65 64 19 91 61

UNITED STATESArkema Inc.Thiochemicals Customer ServiceArkema Inc.2000 Market StreetPhiladelphia, PA 19103USATel: +1 800-628-4453Fax: +1 215-419-7210

EUROPE / REST OF THE WORLDLa Chambre plantBP 1073130 La Chambre FRANCEPhone : +33 (0)4 79 59 35 76Fax : +33 (0)4 79 59 35 79

SALES AND DISTRIBUTION

A global chemical player, Arkema consists of 3 coherent and related business segments:Vinyl Products, Industrial Chemicals and Performance Products.Present in over 40 countries with 17,000 employees, Arkema achieved sales of 5.7 billion euros in 2006.With its 6 research centres in France, the United Sates and Japan, and internationally recognized brand, Arkema holds leadership positions in its principal markets.

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