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[email protected] EC BOD TDS COD . DO Bhumbla & Keefer 1994 . As 5+ As 3+ As 3- As 0 Harvey et al. 2009 V cheng et al. 2009 Bodek et al. 1988 As As(V) As(III) (Kevin 2009) As As As(V) Smedley 2002, Wang & Mulligan 2006 As WHO 2011 µg/l

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ECBOD TDS COD.

DO

Bhumbla & Keefer 1994.

As5+As3+As3-As0

Harvey et al. 2009

V

cheng et al. 2009

Bodek et al. 1988

As

As(V) As(III)(Kevin 2009)

As

As

As(V)

Smedley 2002, Wang & Mulligan 2006

As

WHO 2011

µg/l

Smedley & Kinniburgh 2002

As

Harvey et al. 2002, Wang & Mulligan 2006

AsAs(V)

pH

Cullen and Reimer 1989 Macur et al. 2001, Macur et al. 2004)

As3+

As5+

cheng et al., 2009

EhpH

Redox

Day et al. 2004, Welch et al. 1988

As

cc

cc

(Nickson et al. 2000)ICP-OES

pH

DOTDS

EC

BODCODNo3

-Po4-3Cl-

So4-2 Co3

-2Hco3-

Ca+2Mg+2Na+K+

NH4+

cc500

9.3Arc GIS

.

19SPSS

C°)

mm

mm

Mha

Gm2.

mm970

4112

24

.

.

Zhang 2008Yidana et al. 2010

zscores

X

s

EC pH TDS Hco3- Cl- So4

-2 Co3-2 Ca+2 Mg+2 Na+ K+

(µS/cm) (mg/l)

Gibbs 1970

Mays 2005

Hounslow 1995

)(

PH EC T TDS DO BOD COD NH4

+ No3- Po4-

3 As

(mS/cm) (C°) (mg/l) (µg/l)

WShM-1

WAbS-2

WFA-3

WKB-4

Web-5

WS-6

WF-7

WVi-8

WKH-9

WLs-10

Wkl-11 Wkh-12 Wpa-13 Wfa-14

PH EC T TDS DO BOD COD NH4

+ No3- Po4- As Discharge

(mS/cm)

T(C°)

(mg/l) (µg/l) (m3 /s)

RM-1 RT-2 RS-3

RAS-4 RKI-5 RCH-6 RA-7

RTO-8 RRO-9 RH-10 RK-11 RD-12

RKH-13 RF-14 RB-15

RBA-16 RR-17 RG-18

RDO-19 RBI-20

*RM-1RT-2RS-3RAS-4RKI-5

RCH-6RA-7RTO-8RRO-9RH-10RK-11

RD-12RKH-13RF-14RB-14RBA-15RR-16

RG-17RDO-19RBI-20

WShM-1 WAbS-2 WFA-3(WKB-4)(Web-5)(WS-6)(WF-7)(WVi-8)(WKH-9)(WLs-10)Wkl-11Wkh-12Wpa-13Wfa-14

As

As

As

As

As

TDSBODCODTDS

CODBOD

pH TDS EC T DO BOD COD NH4+ No3

- Po4-3 As

pH TDS EC T

DO BOD COD NH4

+ No3

- Po4-

3 As

PH TDS EC T DO BOD COD NH4+ No3

- Po4-3 As

PH TDS EC T

DO BOD COD NH4

+ No3

- Po4-

3 As

As

As

As

DOECTDS BODCOD

DO

mg/l

DO

mg/l

As

AsDO

DO

As

pHAspH

pHAs

.

pH

pHAs

pH

pH

pH

pH

pH

pH

pH

pH

pHpH

.

pH Smedley & Kinniburgh 2002

BOD

mg/l

mg/l

BODAs

BODAs

COD

mg/l

mg/l

.BODCODAs

.

DO.

COD

AsCOD

As

TDS

mg/l

mg/l

As

TDS

EC

mS/cm

mS/cm

EC

EC

As

No3-

mg/l

mg/l

As No3-

As

mg/l

mg/l

As

Po4-3

mg/l

mg/l

Po4-3

As

As

AsPo4-3

mg/l

AsPo4-3

HAso4-2

HAso4-2

As

As

As

As

As

Na+

K+Mg2+HCO3-So4

-2

As

As

Liu et al. 2014 & Wang et al. 2007

EC

As

ppm

EC

As

EC

As

ECTDS

BODCOD

Po4-3 No3

-NH4+CODECTTDSpH

Po4-3 No3

-NH4+CODECTTDSpH

WHO

2011

AsTDSBOD

CODPo4-3TDS

CODBOD

ECTDS

As

5- Arsenic in Drinking WHO., (2011), "Guideline for drinking water quality", fourth ed. World Health Organization, Singapore (Geneva), pp 315-318. 6- Berg, M., Trang, P. T. K., Stengel, C., Buschmann, J., Viet, P. H., Dan, N. V., Giger, W. & Stuben, D., (2009), "Hydrological and sedimentary controls leading to arseniccontamination of groundwater in the Hanoi area", Vietnam: The impact of iron-arsenic ratios, peat, river bank deposits, and excessive groundwater abstraction. Chemical Geology, 249, pp 91-112. 7- Bhumbla, D. K. & Keefler, R. F., (1994), "Arsenic mobilization and bioavailability in soils, Niragu JO Arsenic in the Environment", Part I, Cycling and Characterization, John Wiley & Sons, New York Ed. Book, pp 51 82. 8- Bodek, I., Lyman, W. J., Reehl, W. F. & Rosenblatt, D. H., (1988), "Environmental Inorganic Geochemistry", NY: Pergaman, pp 43-47. 9- Cai, X., Yu,y., Huang, Y., Zhang, L., Jia, P.M., Zhao, Q., Chen, Z., Tong, J.H., Dai, W., & Chen, G.Q., (2003), "Arsenic trioxide-induced mitotic arrest and apoptosis in acute promyelocytic leukemia cells", pp 1333-1337.

10- Cheng, H.F., Hu, Y.N., Luo, J., Xu, B., Zhao, J.F., 2009 , "Geochemical processes controlling fate and transport of arsenic in acid mine drainage (AMD) and natural systems", Journal of Hazardous Materials 165, pp 13 26. 11- Cullen, W.R., & Reimer, K.J., (1989), "Arsenic speciation in the environment", Chem. Rev, 89, pp 64-713. 12-Day, P.A. O., Vlassopoulos, D., Root, R., Rivera, N., (2004), "The influence of sulfur and ironon dissolved arsenic concentrations in the shallow subsurface under changing redox conditions", Proc. Natl, Acad, Sci. U. S. A. 101, pp 13703 13708. 13- Edition of the Drinking Water Standards and Health Advisories., (2012), U.S. Environmental Protection Agency Washington, DC, P. 8. responsible for high arsenic concentrations in two groundwater catchments in Taiwan", Applied Geochemistry, 22, pp 460-476.

using multivariate and spatial analyses in the Keta basin, Ghana." Journal of African Earth Sciences 58(2): 220-234 31- Nickson, R.T., Mcarthur, J.M., Ravenscroft, P., Burgess, W.G., Ahmed, K.M (2000), "Mechanism of arsenic release to groundwater, Bangladesh and West Bengal", Applied Geochemistry 15, pp 403-413.

14- Gibbs, R., Sarkar, S. K., & Saha, M., (1970), " Mechanisms controlling world water chemistry. Science", 170, pp 1088-1090. 15- Halim, M. A., Majumder, R. K., Nessa, S. A., Hiroshiro, Y., Uddin, M. J., Shimada, J. & Jinno, k., (2009), "Hydrogeochemistry and arsenic contamination of groundwater in the Ganges Delta Plain, Bangladesh", Journal of Hazardous Materials, 164, pp 1335 1345. 16- Harvey, C. F., Swartz, C. H., Badruzzaman, A. B. M., Keon-Blute, N., Niedan, V., Brabander, D., Oates, P. M., Ashfaque, K. N., Islam, S., Hemond, H. F. & Ahmed, M. F., (2002), "Arsenic mobility and groundwater extraction in Bangladesh", Science, 298, pp 1602 1606. 17- Henke, K.R., (2009), "Arsenic: Environmental Chemistry", Health Threats and Waste Treatment. United Kingdom: John Wiley & Sons, pp 72- 160. 19- Hounslow, A., (1995), "Water quality data. Analysis and interpretation", CRC, pp 34-36. 20- Kevin, H., (2009), "Arsenic: Environmental Chemistry, Health Threats and Waste Treatment", United Kingdom: John Wiley & Sons, pp 81-88. 20- Li, S. & Zhang, Q., (2008), "Geochemistry of the Han river basin China", 1. Spatial distribution of the major ion compositions and their controlling factors, Applied geochemistry, 23, pp 3535-3544. 21- Liu, C. W., Lu, K. L., Kao, Y. H., Wang, C. J., Maji, S. K. & Lee, J. F., (2014), "Identifying sources and controlling factors of arsenic release in saline groundwater aquifers", Hydrology and Earth System Scinece, 18, pp 1089-1103. 22- Macur, R. E., Jackson, C. R., Botero, L. M., McDermott, T. R. & Inskeep, W. P., (2004)," Bacterial populations associated with the oxidation and reduction of arsenic in an unsaturated soil", Environ. Sci. Technol., 38, pp 104 11. 23- Macur, R. E., Wheeler, J. T., McDermott, T. R. & Inskeep, W. P., (2001), "Microbial populations associated with the reduction and enhanced mobilization of arsenic in mine tailings", Environ Sci Technol., 35, pp 3676 82. 24- Rahman, M., Naidu, R, and Bhattacharya, P., (2009), "Arsenic contaminationin groundwater in the Southeast Asia region. Environ", Geochem. Health, 31, pp 9 21. 25- Smedley, P. L. & Kinniburgh, D. G., (2002), "A review of the source, behaviour and distributionof arsenic in natural waters", Applied Geochemistry, 17, pp 517 568.

26- Todd, D. K., and Mays, L. W.,(2005), "Groundwater Hydrology", John Wiley & Sons, Inc., pp 636. 27- Wang, S. & Mulligan, C. N., (2006), "Effect of natural organic matter on arsenic release from soils and sediments in to groundwater", Environ, Geochem. Health, 28, pp 197 214. 28- Wang, S. W., Liu, C. W. & Jang, C. S., (2007), " Factors responsible for high arsenic concentrations 29- Welch, A.H., Lico, M.S. Hughes, J.L., (1988), "Arsenic in ground water of the western United States" GroundWater, 26, pp 333 347. 30-Yidana, S. M., B. Banoeng-Yakubo and T. M. Akabzaa (2010), "Analysis of groundwater quality