ars.els-cdn.com · web viewfig. s2: tg and dta curves of the as-spun precursor nfs. 3. sem image of...
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SUPPORTING INFORMATION
High-rate performance electrospun Na0.44MnO2
nanofibers as cathode material for sodium-ion batteriesBi Fua, b, Xuan Zhou,b,*and Yaping Wanga,*
a School of Science, and MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, State Key Laboratory for Manufacturing Systems Engineering, Xi’an Jiaotong University, Xi’an 710049, People’s Republic of Chinab Department of Electrical and Computer Engineering, Kettering University, Flint, MI-48504, USA
1. Fiber diameter distribution
Fig. S1: Fiber diameter distribution of the (a) as-spun precursor NFs, and the calcined
Na0.44MnO2 NFs at different temperatures: (b) 400 °C, (c) 500 °C, (d) 600 °C, and (e)
800 °C.
2. TG-DTA analysis of the electrospun precursor NFs
TG curve in Fig. S2 indicates that the precursor NFs undergo three primary weight
loss steps with the increase of temperature. The primary weight loss of 10 % in the
range of 0 °C to 280 °C is believed resulting from the volatilization of DI water and
CH3COOH. Correspondingly, an endothermic peak is observed in the DTA curve
around 80 °C. The biggest weight loss occurred at 280 °C to 580 °C, which is due to
the decomposition of the PVA. There is no obvious weight loss and heat flow at the
580 °C to 900 °C scope, which indicates the thorough decomposition of PVA as well
as the formation of NaxMnO2.
Fig. S2: TG and DTA curves of the as-spun precursor NFs.
3. SEM image of the Na0.44MnO2 NFs annealed at 900 °C for 1 h.
Fig. S3: SEM image of the Na0.44MnO2 NFs annealed at 900 °C for 1 h.
4. XRD pattern of the NaxMnO2 specimen with different x value at different
temperature.
The XRD pattern in Fig. S4 shows the as-spun NaxMnO2 (x = 0.45, 0.46, 0.47,
0.48, 0.49, 0.50) precursor NFs annealed at 600 °C for 1 h. It reveals that some
impurities Mn-based oxides such as Mn3O4, MnO2, and Mn2O3 appeared in the
specimens when x = 0.45 and 0.46. The Na0.7MnO2 phase dominates the x = 0.49 and
0.50 specimen. The x = 0.47 and 0.48 is the correct component of Na0.44MnO2 phase.
The XRD pattern of the 800 °C annealed NaxMnO2 (x = 0.45, 0.46, 0.47, 0.48, 0.49
and 0.50) precursor NFs in Fig. S5 confirmed that the x = 0.49 specimen corresponds
to the Na0.44MnO2 phase structure. The impurity of the Mn2O3 increased with
increasing of x. The Na0.77MnO2 phase appears in the annealed Na0.53MnO2 precursor
NFs specimen. Consequently, the Na0.44MnO2 NRs were generated by annealing the
Na0.49MnO2 precursor NFs at 800 °C for 1 h.
Fig. S4: XRD pattern of the Na0.44MnO2 precursor solution annealed at different
temperature for 1 h.
Fig. S5: XRD pattern of the NaxMnO2 (x = 0.45, 0.46, 0.47, 0.48, 0.49, and 0.50)
precursor solution annealed at 600 °C for 1 h.
Fig. S6: XRD pattern of the NaxMnO2 (x = 0.48, 0.49, 0.50, 0.51, 0.52, and 0.53)
precursor solution annealed at 800 °C for 1 h.
5. Galvanostatic charge/discharge profiles of Na0.44MnO2 NFs
Fig. S7: Galvanostatic charge/ discharge profiles of Na0.44MnO2 NFs (a) cycling at
different cycles, and (b) cycling at different rates.
Fig. S8: Relationship between Zreal and -1/2 at low frequency.
Fig. S9: Differentiate discharge curve and the corresponding incremental capacity
curve of Na0.44MnO2 (a) NF and (b) NR.