astm d6042 calibration mixture cat.# 31628 lot# a034173 ... · 9.100 11.933 16.108 spd-10avp...
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Analytical Reference Materials
ASTM D6042 Calibration MixtureCat.# 31628
Lot# A034173 & A034009
CERTIFICATE OF ANALYSIS
110 Benner Circle Bellefonte, PA 16823-8812
Tel: (800) 356-1688 Fax: (814) 353-1309
FOR LABORATORY USE ONLY - READ MSDS PRIOR TO USE
Catalog No.: 31628 Lot No.: A034009
Description: ASTM D6042 Calibration Mixture
Expiration Date¹: October 2007 Storage: Refrigerate
1 2,6-Di-tert-butyl-4-methylphenol (BHT) 128-37-0 99% 50 ug/mL +/- 0.12 Erucamide 112-84-5 90% 50 ug/mL +/- 0.13 Irganox 3114 27676-62-6 98% 50 ug/mL +/- 0.14 Irganox 1010 6683-19-8 98% 50 ug/mL +/- 0.15 Vitamin E 59-02-9 99% 50 ug/mL +/- 0.16 Irganox 1076 2082-79-3 99% 50 ug/mL +/- 0.17 Irgafos 168 31570-04-4 99% 50 ug/mL +/- 0.1
Solvent: Isopropanol 67-63-0 99%
Column:150 mm x 4.6 mmUltra C8 (cat.# 9103565)
Flow Rate:1.5 ml/min.
Mobile Phase A:H2O
Mobile Phase B:Acetonitrile
Mobile Phase Composition:0 min.-75%B; 5 min.-100%B; 25 min.-100%B
Det. Type:Wavelength: 200 nm
Manufactured By: MEW
1 Expiration date of the unopened ampul stored at recommended temperature.2 Purity was determined by one or more of the following techniques: GC/FID, HPLC, GC/ECD, GC/MS. Value rounded to the nearest LOWER whole percentage. In addtion to detectors listed above, chemical identity and purity are confirmed using 1 or more of the following: MS, DSC, solid probe MS, GC/FPD, GC/NPD, GC/TC, FTIR, melting point, reftactive index, and Karl Fisher. See data pack or contact Restek for further details.3 Based upon gravimetric preperation with balance calibration verified using NISTtraceable weights (7 mass levels).4 Percent Uncertainty based upon balance AND ASTM Class A volumetric glassware accuracy.
Manufactured Under Restek's ISO9001 Registered Quality System
Certificate #FM80397
Page 1 1
CERTIFICATE OF ANALYSIS
110 Benner Circle Bellefonte, PA 16823-8812
Tel: (800) 356-1688 Fax: (814) 353-1309
FOR LABORATORY USE ONLY - READ MSDS PRIOR TO USE
Catalog No.: 31628 Lot No.: A034173
Description: ASTM D6042 Calibration Mixture
Expiration Date¹: November 2007 Storage: Refrigerate
1 2,6-Di-tert-butyl-4-methylphenol (BHT) 128-37-0 99% 50 ug/mL +/- 0.12 Erucamide 112-84-5 90% 50 ug/mL +/- 0.13 Irganox 3114 27676-62-6 99% 50 ug/mL +/- 0.14 Irganox 1010 6683-19-8 99% 50 ug/mL +/- 0.15 Vitamin E 59-02-9 99% 50 ug/mL +/- 0.16 Irganox 1076 2082-79-3 99% 50 ug/mL +/- 0.17 Irgafos 168 31570-04-4 99% 50 ug/mL +/- 0.1
Solvent: Isopropanol 67-63-0 99%
Column:150 mm x 4.6 mmUltra C8 (cat.# 9103565)
Flow Rate:1.5 ml/min.
Mobile Phase A:H2O
Mobile Phase B:Acetonitrile
Mobile Phase Composition:0 min.-75%B; 5 min.-100%B; 25 min.-100%B
Det. Type:Wavelength: 200 nm
Manufactured By: FJT
1 Expiration date of the unopened ampul stored at recommended temperature.2 Purity was determined by one or more of the following techniques: GC/FID, HPLC, GC/ECD, GC/MS. Value rounded to the nearest LOWER whole percentage. In addtion to detectors listed above, chemical identity and purity are confirmed using 1 or more of the following: MS, DSC, solid probe MS, GC/FPD, GC/NPD, GC/TC, FTIR, melting point, reftactive index, and Karl Fisher. See data pack or contact Restek for further details.3 Based upon gravimetric preperation with balance calibration verified using NISTtraceable weights (7 mass levels).4 Percent Uncertainty based upon balance AND ASTM Class A volumetric glassware accuracy.
Manufactured Under Restek's ISO9001 Registered Quality System
Certificate #FM80397
Page 1 1
12/8/2004 10:36:42 AM 1/1 - 1
QA Report: ASTM D6042 Calibration Mixture (Cat.#31628)Lot # A034173 Lot # A034009
COMPONENT Run #1 Run #2 Run #3 AVG STD DEV % RSD Run #1 Run #2 Run #3 AVG STD DEV % RSD %D MEANBHT 2960116 2953568 2976682 296345 11913 0.40 2959890 3016830 3000913 2992544 29378 0.98 -0.98Erucamide 16697 18207 18246 17717 883 4.99 17440 18955 18728 18374 817 4.45 -3.71Irganox 3114 2483233 2472551 2465396 247372 8976 0.36 2477343 2517148 2515381 2503291 22489 0.90 -1.20Irganox 1010 2111029 2124457 2136325 212393 12656 0.60 2125718 2180120 2150944 2152261 27225 1.26 -1.33Vitamin E 1257097 1255979 1267150 126007 6152 0.49 1257618 1279741 1268921 1268760 11062 0.87 -0.69Irganox 1076 1440683 1442305 1460104 144769 10775 0.74 1432762 1457798 1449120 1446560 12713 0.88 0.08Irganox 168 2440470 2439253 2457947 244589 10459 0.43 2442874 2496510 2482507 2473964 27820 1.12 -1.15
Page 1 of 1Method Name: C:\EZStart\Projects\Default\Method\31628.metData: Z:\Data\Cat-Rep1.#31628 Lot#A034009 Acquired:11/16/2004 4:03:47 PM Printed:12/8/2004 10:35:58 AMInj. volume: 7.5 Vial 0 Cat.#31628 Lot#A034009ASTM D6042 Calibration Mixture
Column: Ultra C8 Cat.#9103565150 x 4.6mmFlow: 1.5 ml/min.UV @ 200 Pump A: H2OPump B: Acetonitrile
0 min. - 75% B5 min. - 100% B25min. - 100% B
Minutes0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0 22.5 25.0
Volts
0
500
1000
Volts
0
500
1000
4.00
0
6.30
06.
475
8.26
7
9.14
2
12.0
08
16.2
42
SPD-10Avp Ch1-200nm Results
Retention Time Area Area % Height4.000 2959890 23.28 6994736.300 17440 0.14 50616.475 2477343 19.49 5975738.267 2125718 16.72 3083549.142 1257618 9.89 162172
12.008 1432762 11.27 11512416.242 2442874 19.21 131443
Totals12713645 100.00 2019200
Page 1 of 1 (5)Method Name: C:\EZStart\Projects\Default\Method\31628.metData: Z:\Data\Cat-Rep2.#31628 Lot#A034009 Acquired:11/16/2004 4:38:07 PM Printed:12/8/2004 10:32:11 AMInj. volume: 7.5 Vial 0 Cat.#31628 Lot#A034009ASTM D6042 Calibration Mixture
Column: Ultra C8 Cat.#9103565150 x 4.6mmFlow: 1.5 ml/min.UV @ 200 Pump A: H2OPump B: Acetonitrile
0 min. - 75% B5 min. - 100% B25min. - 100% B
Minutes0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0 22.5 25.0
Volts
0
500
1000
Volts
0
500
1000
3.98
3
6.28
36.
458
8.24
2
9.10
0
11.9
33
16.1
08
SPD-10Avp Ch1-200nm Results
Retention Time Area Area % Height3.983 3016830 23.27 7100206.283 18955 0.15 56346.458 2517148 19.41 6133548.242 2180120 16.81 3150959.100 1279741 9.87 165610
11.933 1457798 11.24 11828016.108 2496510 19.25 132768
Totals12967102 100.00 2060761
Page 1 of 1 (6)Method Name: C:\EZStart\Projects\Default\Method\31628.metData: Z:\Data\Cat-Rep3.#31628 Lot#A034009 Acquired:11/16/2004 5:12:26 PM Printed:12/8/2004 10:32:24 AMInj. volume: 7.5 Vial 0 Cat.#31628 Lot#A034009ASTM D6042 Calibration Mixture
Column: Ultra C8 Cat.#9103565150 x 4.6mmFlow: 1.5 ml/min.UV @ 200 Pump A: H2OPump B: Acetonitrile
0 min. - 75% B5 min. - 100% B25min. - 100% B
Minutes0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0 22.5 25.0
Volts
0
500
1000
Volts
0
500
1000
4.00
0
6.30
86.
475
8.27
5
9.15
8
12.0
75
16.3
58
SPD-10Avp Ch1-200nm Results
Retention Time Area Area % Height4.000 3000913 23.29 7037176.308 18728 0.15 53226.475 2515381 19.52 6068158.275 2150944 16.69 3095309.158 1268921 9.85 161640
12.075 1449120 11.25 11251716.358 2482507 19.26 130557
Totals12886514 100.00 2030098
Page 1 of 1 (1)Method Name: C:\EZStart\Projects\Default\Method\31628.metData: Z:\Data\Cat-Rep1.#31628 Lot#A034173 Acquired:11/16/2004 2:20:55 PM Printed:12/8/2004 10:31:21 AMInj. volume: 7.5 Vial 0 Cat.#31628 Lot#A034173ASTM D6042 Calibration Mixture
Column: Ultra C8 Cat.#9103565150 x 4.6mmFlow: 1.5 ml/min.UV @ 200 Pump A: H2OPump B: Acetonitrile
0 min. - 75% B5 min. - 100% B25min. - 100% B
Minutes0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0 22.5 25.0
Volts
0
250
500
750
Volts
0
250
500
7503.98
3
6.30
86.
483
8.33
3
9.25
0
12.2
17
16.5
67
SPD-10Avp Ch1-200nm Results
Retention Time Area Area % Height3.983 2960116 23.29 6925586.308 16697 0.13 49656.483 2483233 19.54 5943018.333 2111029 16.61 2991549.250 1257097 9.89 157833
12.217 1440683 11.34 11330116.567 2440470 19.20 125981
Totals12709325 100.00 1988093
Page 1 of 1 (2)Method Name: C:\EZStart\Projects\Default\Method\31628.metData: Z:\Data\Cat-Rep2.#31628 Lot#A034173 Acquired:11/16/2004 2:55:13 PM Printed:12/8/2004 10:31:33 AMInj. volume: 7.5 Vial 0 Cat.#31628 Lot#A034173ASTM D6042 Calibration Mixture
Column: Ultra C8 Cat.#9103565150 x 4.6mmFlow: 1.5 ml/min.UV @ 200 Pump A: H2OPump B: Acetonitrile
0 min. - 75% B5 min. - 100% B25min. - 100% B
Minutes0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0 22.5 25.0
Volts
0
250
500
750
Volts
0
250
500
7504.00
8
6.30
86.
483
8.28
3
9.15
8
12.0
17
16.2
25
SPD-10Avp Ch1-200nm Results
Retention Time Area Area % Height4.008 2953568 23.24 6946336.308 18207 0.14 52846.483 2472551 19.46 6003438.283 2124457 16.72 3079449.158 1255979 9.88 162396
12.017 1442305 11.35 11537016.225 2439253 19.20 131699
Totals12706320 100.00 2017669
Page 1 of 1 (3)Method Name: C:\EZStart\Projects\Default\Method\31628.metData: Z:\Data\Cat-Rep3.#31628 Lot#A034173 Acquired:11/16/2004 3:29:31 PM Printed:12/8/2004 10:31:45 AMInj. volume: 7.5 Vial 0 Cat.#31628 Lot#A034173ASTM D6042 Calibration Mixture
Column: Ultra C8 Cat.#9103565150 x 4.6mmFlow: 1.5 ml/min.UV @ 200 Pump A: H2OPump B: Acetonitrile
0 min. - 75% B5 min. - 100% B25min. - 100% B
Minutes0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0 22.5 25.0
Volts
0
500
1000
Volts
0
500
1000
3.98
3
6.28
36.
458
8.23
3
9.09
2
11.9
17
16.0
83
SPD-10Avp Ch1-200nm Results
Retention Time Area Area % Height3.983 2976682 23.29 7043456.283 18246 0.14 54426.458 2465396 19.29 6025838.233 2136325 16.71 3123419.092 1267150 9.91 164403
11.917 1460104 11.42 11849916.083 2457947 19.23 131179
Totals12781850 100.00 2038792
