asymmetric synthesis of 2h-azirine 3-carboxylates
TRANSCRIPT
2007
Aziridine derivativesR 0040 Asymmetric Synthesis of 2H-Azirine 3-Carboxylates. — The synthesis of the title
compounds is accomplished by dehydrochlorination of 2-chloroaziridine 2-carboxy-lates. The products readily undergo aza Diels—Alder reaction with dienes to give enan-tiomerically pure bi- and tricyclic aziridine carboxylates. Photodesulfinylation of sul-finamides represents an important new procedure without the need of acids or bases. — (DAVIS*, F. A.; DENG, J.; Org. Lett. 9 (2007) 9, 1707-1710; Dep. Chem., Temple Univ., Philadelphia, PA 19122, USA; Eng.) — R. Steudel
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