at9900063 active metal brazing of different metals to

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AT9900063 Active metal brazing of different metals to aluminium nitride ceramics B. Loeser and D. Brunner ANCeram GmbH & Co.KG, Bindlach, Germany During recent years aluminium nitride ceramics for substrates, coolers and components have found more applications in micro- and power electronics. Aluminium nitride ceramic with high thermal conductivity, small CTE and good thermal shock resistance is used in aeronautical equipment as well as in drive systems of undergrounds and high speed trains. Different metals and alloys can be bonded to A1N by the so-called "AMB-process". The bonding mechanism is based on the use of so-called active metals like Ti, Zr, Hf. Copper conductor lines can be brazed onto AlN-jubstrates and components, resistor sheets can be applied on ceramic water coolers and a couple of other metals and alloys like Tantalium, Titanium, KOVAR and steel can be attached to AIN-ceramics by active brazing. Processing, analytical aspects and some special applications will be discussed. 167

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Page 1: AT9900063 Active metal brazing of different metals to

AT9900063

Active metal brazing of different metals to aluminiumnitride ceramics

B. Loeser and D. Brunner

ANCeram GmbH & Co.KG, Bindlach, Germany

During recent years aluminium nitride ceramics for substrates, coolers and components have

found more applications in micro- and power electronics.

Aluminium nitride ceramic with high thermal conductivity, small CTE and good thermal

shock resistance is used in aeronautical equipment as well as in drive systems of

undergrounds and high speed trains.

Different metals and alloys can be bonded to A1N by the so-called "AMB-process". The

bonding mechanism is based on the use of so-called active metals like Ti, Zr, Hf.

Copper conductor lines can be brazed onto AlN-jubstrates and components, resistor sheets

can be applied on ceramic water coolers and a couple of other metals and alloys like

Tantalium, Titanium, KOVAR and steel can be attached to AIN-ceramics by active brazing.

Processing, analytical aspects and some special applications will be discussed.

167

Page 2: AT9900063 Active metal brazing of different metals to

Active Metal Braang of Different Metals to AIN Vienna, 06/05/97

Historical Background of the AMB-Process

Aluminium Nitride

Active Metal Brazing of AIN

Analytical Aspects

Special Applications

Summary

Active Metal Brazing of

Different Metals

to Aluminium Nitride Ceramics

Dr. D. Brunner, B. Lflser, ANCeram GmbH & Co. KG, Bindlach,Germany

Aluminium Nitride Ceramics GmbH & Co KG, Esbachgraben 21, Bindlach, Germany

Page 3: AT9900063 Active metal brazing of different metals to

Active Metal Brazing of Different Metals to AIN Vienna. 06/05/97

Historical Background

W.D. Kingery and M. llumenik, 1954 :Surface tension and wettability of metal-ceramic systems

Y. Naidich, 1981 : Wetting induced by Titanium

Joints of Silicon Nitride and Carbide with Metals byActive Brazing ( 1982 ); Degussa, llanau

Joints of AIN with Kovar® by Active Brazing ( 1984 );lleraeus, llanau

Joints of AIN with Copper by Active Brazing ( 1984 );Toshiba

II. Krappitz, H. Thiemann, W. Weise, 1989 :Reactive brazed Ceraniic-Metal-Joints forAutomotive Applications

Joining AIN with Tantalum and Titanium ( 1993 );ANCeram

Historical Background of the AMB-Process

Aluminium Nitride

Active Metal Brazing of AIN

Analytical Aspects

Special Applications

Summary

Aluminium Nitride Ceramics GmbH & Co. KG, Esbachgraben 21, Bindlach, Germany

Page 4: AT9900063 Active metal brazing of different metals to

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Page 5: AT9900063 Active metal brazing of different metals to

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Active Metal Brazing of Diffefent Metals to AIN Vienna. 06/05/97

Historical Background of the AMB-Process

• Aluminium Nitride

Active Metal Brazing of AIN

Analytical Aspects

Special Applications

• Summary

Aluminium Nitride Ceramics GmbH & Co. KG, Esbachgraben 21, Bindlach, Germany

Page 6: AT9900063 Active metal brazing of different metals to

4. Mikroclinrnkterisiennifj

Rcaktionen:

Rcaktionszonen:

Schliflbild:

4Ti + 3A1N - 3TiN + TiAl3

Ag-Cu-Eutektikum bei 780°C

Kupfer

Ti-criche Schicht (ct. l-2fim)Eutektische L otschicfct (ca. 20ptn)

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Page 7: AT9900063 Active metal brazing of different metals to

Active Metal Brizing of Different Metals to A1N Vienna. 06/05/97

Historical Background of the AMB-Process

Aluminium Nitride

Active Metal Brazing of AIN

Analytical Aspects

Special Applications

Summary

Aluminium Nitride Ceramics GmbH & Co. KG, Esbachgraben 21, Bindlach, Germany

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Page 8: AT9900063 Active metal brazing of different metals to

A1N

Soldering Metal

Alloy Junction

OFHC-Cu

Alloy junction

Alumina

174

Page 9: AT9900063 Active metal brazing of different metals to

Active Metal Brazing of Difl'erenl Metals to AlN Vienna. 06/05/97

Historical Background of the AMB-Process

Aluminium Nitride

Active Metal Brazing of AlN

Analytical Aspects *-"'

Special Applications

• Summary

Aluminium Nitride Ceramics GmbH & Co. KG, Rsbachgraben 21, Bindlach, Germanyy

Page 10: AT9900063 Active metal brazing of different metals to

Active Brazing Process

AIN Substrate ] L Copper Foil

Rinsing Punching

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| Screen Printing of Metal Paste Cleaning

Adjusting of Copper Foils in Solder Fixture

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\cii\e Bra/ing Process

AIN Subsiraic ( tipper ( 'oil

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Page 11: AT9900063 Active metal brazing of different metals to

AIN/AMB Fa.ANCeramGefugeausbildung

Kante 5

Faust Kante 6

111"!Fraunhoftr

tnstitutZuvariflssigkeit undMkrointegration

DepartmentMECHANICAL RELIABILITYAND MICRO MATERIALSHead: Prof. Dr. Bemd Michel

Aluminium Nitride Substrates for Power Electronics

Active Brazed Copper (ABC)Substrates developed byANCeram

R . H a h l l , ANCERAM2DOC. 21.ll.1996. HahitTUB. Tel. 030 314 72833. Fax. 030 314 72 835

177

Page 12: AT9900063 Active metal brazing of different metals to

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178

Page 13: AT9900063 Active metal brazing of different metals to

Water-cooled inverter torunderground trains, equippedwith ANCeram modules

Page 14: AT9900063 Active metal brazing of different metals to

Active Metal Brazing of Different Metals to AIN Vienna. 06/05/97

Summary

AIN is wettable to different alloys activated by Ti, Zr, Hf,Ni, and Cr

AIN is attachable to KOVAR, Titanium, Tantalum, stainlessSteel and Copper

AIN-Metal-Joints show high peel strength and sufficientthermal and electrical behavior

AIN active brazed with Copper may become an alternativeto the DCB-Process on Alumina for high power application

Aluminium Nitride Ceramics GmbH & Co. KG. Esbachgraben 21. Bindlach. Germany

180