attachment-4-8-2-screening assessment for baseline report · baseline reports as required under...

Attachment-4-8-2-Screening Assessment for

Baseline Report

INDUSTRIAL EMISSIONS LICENCE APPLICATION

Dairygold Co-Operative Society Limited and TINE IRELAND LTD

Mogeely, Co. Cork

APPLICATION ID: LA003608

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Baseline Report – Screening Assessment

Dairygold Co-Operative Society Ltd & TINE Ireland Ltd.

Mogeely Co. Cork

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19110-6002-B Baseline Report January 2019

i

ISSUE FORM

Project number 19110

Document number 6002

Document revision B

Document title Baseline Report – Screening Assessment

Document status FINAL

Document prepared by C Fox

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19110-6002-B Baseline Report – Screening January 2019

ii

Table of contents

1 INTRODUCTION ......................................................................................................... 1

2 METHODOLOGY ......................................................................................................... 1

3 IDENTIFICATION OF HAZARDOUS SUBSTANCES (STAGE 1) .......................................... 2

4 IDENTIFICATION OF THE RELEVANT HAZARDOUS SUBSTANCES (STAGE 2) ................... 2

5 ASSESSMENT OF THE SITE-SPECIFIC POLLUTION POSSIBILITY (STAGE 3) ...................... 2

6 CONCLUSIONS ........................................................................................................... 5

Appendices

Appendix 1 Stage 1 Assessment



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19110-6002-A Baseline Report - Screening January 2019

1

1 INTRODUCTION

This report has been prepared on behalf of Dairygold Co-Operative Society Ltd and TINE Ireland Ltd.

as part of the Industrial Emissions licence application to the EPA for the installation at Mogeely, Co.

Cork

The purpose of the report is to determine whether or not a baseline report in accordance with the

requirements under Article 22(2) of Directive 2010/75/EU on Industrial Emissions is required for the

installation.

This report has been prepared in line with the European Guidance concerning baseline reports under

Article 22(2) of Directive 2010/75/EU on Industrial Emissions and forms part of the IE Licence

application.

The report provides information on ‘relevant hazardous substances’ used/to be used, produced or

released by the installation and the possibility of soil and groundwater contamination by ‘relevant

hazardous substances’ used/to be used, produced or released by the installation concerned.’

2 METHODOLOGY

The European Commission (EC) published guidance (6 May 2014) on the preparation and content of

Baseline Reports as required under Article 22(2) of the Industrial Emissions Directive (2010/75/EU).

The EC Guidance identifies key stages/tasks which are to be undertaken to determine whether a

baseline report needs to be produced and in order to produce the baseline report itself. The key

stages/tasks are as follows:

Stage 1: Identifying the hazardous substances that are currently used, produced or released

at the installation

Stage 2: Identifying the relevant hazardous substances

Stage 3: Assessment of the site-specific pollution possibility

Stage 4: Site history

Stage 5: Environmental setting

Stage 6: Site characterisation

Stage 7: Site investigation

Stage 8: Production of the baseline report

The assessment undertaken for preparation of this Baseline Screening Report has followed Stages 1-

3 of the EC Guidance.

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2

3 IDENTIFICATION OF HAZARDOUS SUBSTANCES (STAGE 1)

The range of materials, substances, intermediates, products, fuels, and chemicals which are/will be

produced or utilised by the installation can generally be categorised under the following groupings:

A comprehensive list of all of materials produced or utilised at the installation under each category is

provided in Attachment 4-6-2 of the IEL Application. Details of Danger category and Hazard

Statements are also provided.

A review of the substances listed in Attachment 4.6.2 of the IEL Application form has been

undertaken to identify any substances produced or utilised at the installation that are defined as

hazardous substances. Refer to Appendix 1.

4 IDENTIFICATION OF THE RELEVANT HAZARDOUS SUBSTANCES (STAGE 2)

Each substance identified in Stage 1 as being hazardous was further reviewed to identify any substances produced or utilised at the installation that are defined as ‘relevant hazardous substances’. Relevant Hazardous Substances have been determined by considering its chemical and physical

properties such as: composition, physical state (solid, liquid, and gas), solubility, toxicity, mobility,

persistence, etc. This information/Data has been determined from Material Safety Data Sheets

(MSDS). This information has been used to determine whether or not the substance has the

potential to cause pollution of soil and groundwater. The data, together with the rationale used to

interpret it, is provided in Appendix 2.

5 ASSESSMENT OF THE SITE-SPECIFIC POLLUTION POSSIBILITY (STAGE 3)

Each substance identified in Stage 2 as being a’ relevant hazardous substance’ has been considered

in the context of the site to determine whether circumstances exist which result /may result in the

release of the substance in sufficient quantities to represent a pollution risk to soils or groundwater,

REF CODE MATERIAL CATEGORY

ING Ingredients (Food Grade Raw Material Inputs)

PD Products

WTC Water Treatment Chemicals

CC Cleaning Chemicals

BTC Boiler Treatment Chemicals

ETP Effluent Treatment Plant Chemicals

F/L Fuels and Lubricants

PG Process Gases

RG Refrigeration Gases

LC Laboratory Chemicals

PM Packaging Materials

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3

either as a result of a single emission or as a result of accumulation from multiple emissions. Specific

appraisal criteria considered are as follows:

- The quantity of each hazardous substance handled, produced or emitted in relation to its

environmental effects. - The location of each hazardous substance on the site e.g. where it is or will be delivered, stored,

used, moved around the site, emitted etc., in particular in view of the characteristics of the soil and groundwater at that part of the site;

- The presence and integrity of containment mechanisms, nature and condition of site surfacing,

location of drains, services or other potential conduits for migration.

This data, together with the rationale used to interpret it, is provided in Appendix 3.

A hydrogeological assessment of the currently licensed (Reg No. P0817-01) portion of the site was

completed in April 2012 by Peter Conroy (Hydrogeologist). The assessment included a

hydrogeological conceptual model for the site and a source – pathway – receptor (SPR) groundwater

risk assessment for the site. Relevant information from the hydrogeological assessment provides

the following:

The site is underlain by approximately 12 m of subsoils predominantly comprised of

GRAVEL with some interbedded SILT and SILT/CLAY (Conroy, 2013).

The subsoil is underlain by weathered limestone bedrock. The bedrock is mapped as the

Waulsortian Limestone Formation, which is a massive, unbedded lime-mudstone.

The SPR site risk assessment identified that leakage of raw dairy ingredients, CIP chemicals,

wastewaters and hydrocarbons were potential contaminant sources; however, the

associated SPR linkages were all considered to be low risk (Conroy, 2012).

The low risk SPR linkages all envisaged leakage of the potential source contaminants to

ground followed by vertical infiltration through the unsaturated subsoil zone down to the

watertable. This would be followed by lateral migration of contaminants in the

groundwater in the saturated subsoils and hydraulically continuous shallow weathered

bedrock (Conroy, 2012).

Routine groundwater monitoring at upgradient and downgradient monitoring wells has been

undertaken at the currently licensed (Reg No. P0817-01) portion of the installation since 2012/2013.

The groundwater monitoring parameter suite was designed to monitor for parameters that would

indicate whether or not the potential contaminants were occurring in the groundwater at elevated

concentrations, and thereby potentially indicate the manifestation of a potential SPR link. The

parameter suite targets organic matter related potential contaminant sources (dairy ingredients,

wastewaters, greywater) and CIP chemicals used on-site.

Based on the groundwater monitoring undertaken at the installation, there is no evidence that any

of the potential SPR linkages have occurred at the site.

In addition under Schedule C.6 of the existing IE license, a once-off analysis of organic compounds in

groundwater beneath the site was carried out in 2012 as part of the hydrogeological investigation.

This monitoring found that no prescribed organic compounds (pesticides, PAHs or other organic

compounds specified by the legislation) were detectable in the groundwater beneath the site.

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4

The applicants intend to upgrade and expand the existing cheese manufacturing installation at

Mogeely, Co. Cork. The proposed extension to the installation will lie to the east of the existing

plant in a Greenfield site which is currently agricultural land.

In February 2017, exploratory investigations were undertaken at on the existing (live/operational)

cheese factory and the site of the proposed new cheese production building. These fieldwork

investigations included borehole drilling, trial pit excavations and soil sampling. Cable tool borehole

drilling (BH) (10 No.) was undertaken to a maximum depth of 14 mbgl. Rotary borehole (RC) drilling

(4 No.) was undertaken to a maximum depth of 15 mbgl. Trial pits (TP) (5 No.) were excavated to a

maximum depth of 3.2 mbgl. Soil samples were collected for chemical testing.

There will be no changes in the types of products produced or raw materials currently used on site.

There will be no change to the range of chemicals and detergents currently utilised on site for cleaning,

and wastewater treatment processes.

Gases currently used on site will continue to be utilised. In addition, Cl2 will be used in for water

treatment. There will be no changes to the types of fuel inputs or lubricants currently utilised on site.

The proposed development has been designed to eliminate risk of ground contamination from

hazardous substances. The proposed development will be constructed to current standards and

specifications when completed will not have a significant impact on soil or groundwater quality in the

area. All bunds and storage facilities have been designed to provide containment to a volume not less

than the greater of the following:

(i) 110% of the capacity of the largest tank or drum within the bunded area; or

(ii) 25% of the total volume of substance that could be stored within the bunded area.

Bunds will be impervious to the material/substance to be stored within

The upgrading of the underground drainage systems pipework and improvement in containment

measures, coupled with the presence of a concrete cover over most of the site and will ensure that

the possibility of soil and groundwater contamination at the site is very low.

Considering the containment measures and proposed upgraded underground drainage systems,

coupled with the presence of a concrete cover over most of the site and the volumes of relevant

hazardous substance held at any one time, the possibility of soil and groundwater contamination at

the site is very low.

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5

6 CONCLUSIONS

A review of all materials, substances, intermediates, products, fuels, and chemicals which are/will be

produced or utilised by the installation has identified that a number of ‘relevant hazardous

substances’ are/will be used/stored at the installation.

All identified ‘relevant hazardous substances’ identified are stored above ground either in secure containers indoors or externally in bunded areas. Bunds are surrounded by hard standing areas and all storage and handling is carried out in these areas. There are no direct discharges from the installation to ground. Potential migration pathways for hazardous substances to soil and groundwater are only considered to be likely through leaks in the containment structures or underground drainage systems. Based on the groundwater monitoring undertaken to date at the installation, there is no evidence

that any of the potential SPR linkages have occurred at the site. Considering the containment

measures and proposed upgraded underground drainage systems, coupled with the presence of a

concrete cover over most of the site and the volumes of relevant hazardous substance held at any

one time, the possibility of soil and groundwater contamination at the site is very low.

Routine groundwater monitoring at upgradient and downgradient monitoring wells has been

undertaken at the currently licensed (Reg No. P0817-01) portion of the installation since 2012/2013.

Analysis of organic compounds in groundwater beneath the site was carried out in 2012. In February

2017, exploratory investigations were undertaken at on the existing (live/operational) cheese factory

and the site of the proposed new cheese production building which included soil sampling.

Therefore it is considered the existing data available for the site is sufficient as a baseline and that a

further site investigation is not required.

The results of the groundwater samples from the upgradient well undertaken in 2012/2013 and the

soil samples taken in 2017 will form the basis for a comparison with the state of contamination upon

definitive cessation of activities.

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19110-6002-A Baseline Report - Screening January 2019

APPENDIX 1

STAGE 1 ASSESSMENT

Identification of Hazardous Substances used or generated at the installation

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STAGE 1 ASSESSMENT: Identification of Hazardous Substances used or generated on the site

Specific

pollutants

Priority

(hazardous)

substances

Hazardous Non-hazardous

ING Raw Milk n/a n/a <1500 530,000 Food Ingredient n/a n/a n/a n/a n/a n/a

ING PVD Salt (Food Grade) 7647-14-5 n/a 78 830 Food Ingredient n/a n/a n/a undetermined undetermined n/a

ING Edible Casein Grains n/a n/a 0.5 0.5 Food Ingredient n/a n/a n/a n/a n/a n/a

ING Calcium Chloride 35% 10043-52-4 Xi 1 4 Food additive H319 n/a n/a n/a n/a n/a

ING Anti foam extra 77-923-9 Xi 1 3 Food additive H319 n/a n/a n/a n/a n/a

ING Starter cultures n/a n/a 0.5 2 Food Ingredient n/a n/a n/a n/a n/a n/a

ING Skim Milk Powder n/a n/a 1.6 0 Food Ingredient n/a n/a n/a n/a n/a n/a

ING Lactic Acid 80% 50-21-5 Xi, C 0.18 0.18 Food Ingredient H315, H318 n/a n/a undetermined undetermined n/a

ING Delvo CID Instant n/a n/a 0.006 0.02 food preserative n/a n/a n/a n/a n/a n/a

PD Pasteurised milk n/a n/a 300 530000 intermediate n/a n/a n/a n/a n/a n/a

PD Cheese n/a n/a 3200 43000 product n/a n/a n/a n/a n/a n/a

PD Cream n/a n/a 88 4000 intermediate /product n/a n/a n/a n/a n/a n/a

PD Whey n/a n/a 1500 40000 intermediate / product n/a n/a n/a n/a n/a n/a

PG Ammonia 7664-41-7 0.9 0.1 refrigeration gas H280, H314, H332 No no no no no

PG Pureshield Argon 7440-37-1 N/A 1 0.08 refrigeration gas N/A no no no no no

PG Ozone

10028-15-6

F, N 0 0.4 food processingH270, H280, H330, H314, 318,

H335, H400, H410no no no no no

WTC Chlorine Gas 7782-50-5 F,C, N 0.26 0.26 water treatmentH270, H280, H330, H314, 318,

H335, H400, H410no no no no no

WTC Broxo Blocks 7647-14-5 n/a 1.8 1.8 water treatment n/a no no no no no

ETP

Cellfloc CE191

●1-propanaminium N,N,N-trimethl-3((1-oxo-2-

propenyl)amino) chloride

●ethoxylated alcohol

●Distillates (petroleum)

75150-29-7

Xi, N, Xn 1 2 flocculant H304, H318, H400, H411 no no no no no

ETP Aluminium Sulphate Liquor 10043-01-3 Xi 10 200 wastewater treatement H319 no no No yes no

ETP Caustic Soda 5% 1310-73-2 C 0.3 0.3 wastewater treatement H314, H290 No no undetermined undetermined no

ETP

Lime (hydrated)

●Calcium Hydroxide

●Crystalline Silica

●1305-62-0

●14808-60-7C <1 <1 wastewater treatement H315, H318, H335 No no undetermined undetermined no

F/L Natural Gas F+ 0 300000m3 boilers H220, H280 no no no no no

F/L Gas Oil (diesel) 68814-87-9 Xn, Xi, Carc. Cat. 3, N 5.9 0.5 Back-up GeneratorH226, H304, H315, H332, H351,

H373, H411 no no yes no no

Food Grade

Lubricants Cassida Fluid GL 460 n/a n/a 1 1 food manufacturing equipment n/a no no no no no

Food Grade

Lubricants Cassida Fluid HF32 n/a n/a 0.04 0.04 food manufacturing equipment n/a no no no no no

Food Grade

Lubricants

Klüber Degrippant NH1 Spray

●Alkanes, C9-12-iso-●90622-57-4 F+, N 0.04 0.04 food manufacturing equipment H226,H281, H304, H413 no no no no no

Food Grade

Lubricants

Foodlube Spray Chesterton 629

●Naphtha (petroleum)

●petroleum gases

●2,2,4-Trimethylpentane

●64741-66-8

●68476-86-8

●540-840-1

F, N 0.01 0.01 food manufacturing equipment H225, H304, H411 no no no no no

Non Food Grade

Lubricants Refrigeration Oil S2 FR-A 68 n/a n/a 0.6 0.6 Compressors n/a no no no no no

Non Food Grade

Lubricants Tellus 46 oil n/a n/a 0.2 0.2 valve/pump lubricant n/a no no no no no

Controlled

Substances

REACH SVHC

Hazard StatementNature of UseAnnual Usage

(tonnes)

Amount Stored

(tonnes)Danger

CategoryCAS NumberMaterial/ Substance

Ref. No.

or Code

EC EO (Surface Waters)

Regulations 2009

EC EO (Groundwater) Regulations

2010

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Specific

pollutants

Priority

(hazardous)

substances


Controlled

Substances

REACH SVHC


(tonnes)

Amount Stored

(tonnes)Danger


Ref. No.

or Code


Regulations 2009


2010

LC

Ammonia Cyanurate Reagent

● tri-Sodium citrate dihydrate

●di-Sodium tartrate dihydrate

●Lithium hydroxide

●Sodium dichloroisocyanurate

●6132-04-3

●6016-24-7

●1310-65-2

●2893-78-9

C, Xi 0.001 0.001 Testing chemical H302, H314, H335, H400, H413 no no no no no

LC

Ammonia Salicylate Reagent

●Sodium saliclate



●Sodium Nitroferricyanide

●54-21-7

●6132-04-3

●6106-24-7

●14402-89-2

Xn 0.001 0.001 Testing chemical H302 no no no no no

LC

Ammoxia Test N Tube Reagent

●Sodium saliclate

● caustic soda, sodium hydroxide

●54-21-7

●1310-73-2 Xn, C 0.001 0.001 Testing chemical H302 no no

undetermined

(1310-73-2)

undetermined

(1310-73-2)no

LC

COD-Cuvettes (0-1500mg/L COD)

●sulphuric acid

● mercury sulphate

●potassium dichromate

●7664-93-9

●7783-35-9

●7778-50-9

T+, C 0.001 0.001 Testing chemicalH301, H311, H331, H314, H350i,

H412no no undetermined undetermined

Yes (potassium

dichromate)

LC


●sulphuric acid



●7664-93-9

●7783-35-9

●7778-50-9

T+, C, N 0.001 0.001 Testing chemicalH301, H311, H331, H332, H314,

H350, H360F, H360D, H400no no no no no

LC COD Standard Solution

●potassium hydrogen phthalate ●877-24-7 n/a 0.005 0.005 Testing chemical n/a no no no no no

LC

Molybdate Reagent

●sulphuric acid

● ammonium heptamolydate tetrahydrate

●7664-93-9

●12054-85-2 C 0.001 0.002 Testing chemical H314 no no undetermined undetermined no

LC Nitrogen - Ammonia Standard Solution as NH3-

Nn/a n/a 0.003 0.003 Testing chemical n/a no no no no no

LC Phosphate Acid Reagent vials

●sulphuric acid ●7664-93-9 Xi 0.002 0.002 Testing chemical H319 no no undetermined undetermined no

LC Phosphate Standard Solutiona n/a n/a 0.001 0.001 Testing chemical n/a no no no no no

LC

PhosVer3 Phosphate Reagent

●Potassium disulfate

● ascorbic acid

●sodium molybdate

●7790-62-7

●50-81-7

●10102-40-6

Xi 0.002 0.002 Testing chemical H318 no no no no no

LC Potassium Persulfate Powder Pillows 7727-21-1 O, Xn, Xi 0.001 0.001 Testing chemical H270, H302 H319, H335 no no no no no

LC Sodium Hydroxide 1,54N

●caustic soda, sodium hydroxide ●1310-73-2 C 0.004 0.004 Testing chemical H314 no no undetermined undetermined no

LC TN Acid Reagent

●sulphuric acid ●7664-93-9 C 0.002 0.002 Testing chemical H314 no no undetermined undetermined no

LC TN Persulfate Reagent 7727-21-1 O, Xn, 0.0002 0.0002 Testing chemical H270, H302 H319, H335 no no no no no

LC Total Nitrogen Reagent A

●sodium metabisulphite ●7681-57-4 Xn, 0.002 0.002 Testing chemical H302, H318, no no undetermined undetermined no

LC Ammonia Solution (25%) 1336-21-6 C, N 0.003 0.003 Testing chemical H314, H400 no no no no no

LC Buffer Solution Ph4 n/a n/a 0.02 0.03 Testing chemical n/a no no no no no

LC Buffer Solution Ph7 n/a n/a 0.02 0.05 Testing chemical n/a no no no no no

LC Hydrochloric Acid >25% 7647-01-0 C, Xi 0.003 0.003 Testing chemical H314, H335 no no no no no

LC iso-Amyl Alcohol 123-51-3 Xn 0.003 0.004 Testing chemical H332, H335, EUH066 no no no no no

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Specific

pollutants

Priority

(hazardous)

substances


Controlled

Substances

REACH SVHC


(tonnes)

Amount Stored

(tonnes)Danger


Ref. No.

or Code


Regulations 2009


2010

LC Methylated spirits 64-17-5 F+, Xn 0.003 0.003 Testing chemical H225, H332, H312, H302 no no undetermined undetermined no

LC Nitric acid 65% 7697-37-2 O, C 0.003 0.003 Testing chemical H314 no no undetermined undetermined no

LC Phenolphthalein solution in Ethanol

●Ethanol ●64-17-5 F 0.003 0.001 Testing chemical H270 no no undetermined undetermined no

LC Silver Nitrate 7761-88-8 N 0.003 0.006 Testing chemical H411 no no no no no

LC Sodium Hydroxide <0.5%

●caustic soda, sodium hydroxide ●1310-73-2 C 0.03 0.03 Testing chemical H314, H319, H335 no no undetermined undetermined no

LC Sodium Hydroxide 40%

●caustic soda, sodium hydroxide●1310-73-2 C 0.01 0.005 Testing chemical H314, H290 no no undetermined undetermined no

LC Sulphuric acid 95-97% 7664-93-9 C 0.02 0.06 Testing chemical H314 no no no no no

LC Baird Parker Agar

●Lithium chloride ●7447-41-8 Xn, Xi 0.001 0.002 Biochemical analysis H302, H319, H315 no no no no no

LC Chromocult TBX Agar

●Sodium deoxycholate ●302-95-4 Xn 0.002 0.004 Biochemical analysis H302 no no no no no

CC Surfisan n/a C 2 2 surface sanitation H314 No no no √ no

CC

Doryl Mould Acid SS

●Sulphamic acid

●Hydrogen Peroxide

●5329-14-6

●7722-84-1C, N 2 18 disinfectant H314 No no undetermined undetermined no

CC

Bioster


●Peracetic acid

●7722-84-1

●79-21-0C 2 2 cleaning agent H314, H319 No no undetermined undetermined no

CC Maunster n/a F 0.03 0.04 Antiseptic handwash H314, H290 no no no no no

CCLactrin F

●sodium hydroxide

n/a

●1310-73-2C 25 364 CIP agent H314, H290 No no undetermined undetermined no

CCLoco DS11 NaOH

●sodium hydroxide

n/a

●1310-73-2C 0.4 0.4 CIP agent H314, H290 no no undetermined undetermined no

CCKingdon 90 Extra

●nitric acid

n/a

●7697-37-2C 2 26 CIP agent H314 No no undetermined undetermined no

CCKingdom Detergent

●Sodium Dichloroisocyanurate, Dihydrate

n/a

●751580-86-0C 0.3 0.3 cleaning agent H314, H290 No no no no no

CC Hydrogen peroxide 35% 7722-84-1 C 0.15 0.15 cleaning agent H318, H335 No no undetermined undetermined no

CC

Hydrox 10

●peroxyacetic acid

● acetic acid

●hydrogen peroxide

●79-21-0

●64-19-7

●7722-84-1

C, O 2 3.2 sterilent H314 No no undetermined undetermined no

CC Ntric acid 55/60% 7697-37-2 C 20 6.4 CIP agent H314, H290 No no undetermined undetermined no

CC Hydrochloric Acid 7647-01-0 C, Xi 25 2 Whey plant CIP agent H314, H335 no no no no no

CC Liquid Caustic 30% 1310-73-2 C 1 4 Testing chemical H314 no no undetermined undetermined no

CCAcid Foam Cleaner

●Citric Acid

n/a

●77-923-9Xi 2 4 detergent H319 no no n/a n/a no

CCAlkaline Foam Cleaner

●Sodium hydroxide

n/a

●1310-73-2C 2 4 detergent H314, H290 No no undetermined undetermined no

CC

Sodium Hypochlorite 5-15%

●sodium hydroxide

● sodium hypochlorite solution

●1310-73-2

●7681-52-9C, N 1.6 3.2 CIP agent H314, H400 No no

undetermined (1310-

73-2)

√

(7681-52-9) no

CC Rocklor 7681-52-9 C, N <1 <1 sanitation H314, H400 No No no √ no

CCRockquat Footbath Sanitiser

●C8-C18 alkyldimethyl chloride ammonium

n/a

●63449-41-2Xn 0.06 1.2 sanitiser H302, H319 No no no no no

CC

Divos 95 VM37

●Potassium hydroxide

● sodium carbonate

● tetrasodium ethylene diamine tetraacetate

●1310-58-3

●497-19-8

●64-02-8

C 2 10 Whey RO Plant CIP agent H318 No no undetermined undetermined no

CC

Divos ADD3 VM16

●sodium alkylbenzenesulphonate

● sodium hydroxide

●90194-45-9

●1310-73-2 C 2 4 Whey RO Plant CIP agent H315, H318 no no undetermined undetermined no

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Specific

pollutants

Priority

(hazardous)

substances


Controlled

Substances

REACH SVHC


(tonnes)

Amount Stored

(tonnes)Danger


Ref. No.

or Code


Regulations 2009


2010

CC

Divos 2 VM13

●nitric acid

● phosphoric acid

●7697-37-2

●7664-38-2 C 6 12 Whey RO Plant CIP agent H314, EUHO71, H290 no no undetermined undetermined no

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APPENDIX 2

STAGE 2 ASSESSMENT

Identification of Relevant Hazardous Substances used or generated at the installation

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STAGE 2 ASSESSMENT: Identification of Relevant Hazardous Substances used or generated at Dairygold Mogeely

Specific

pollutants

Priority

(hazardous)

substances


ING PVD Salt (Food Grade) 7647-14-5 n/a 78 480 Food Ingredient n/a n/a n/a undetermined undetermined n/a NoCrystalline substance. Product

is not classified as dangerous for

the environment MSDS.

ING Lactic Acid 80% 50-21-5 Xi, C 0.18 0.18 Food Ingredient H315, H318 n/a n/a undetermined undetermined n/a No

product is not classified as

dangerous for the environment

MSDS.

PG Ozone10028-15-6

F, N 0 0.4 food processing

H270, H280, H330,

H314, 318, H335,

H400, H410

no no no no no No Gas

WTC Chlorine Gas 7782-50-5 F,C, N 0.26 0.26 water treatment

H270, H280, H330,

H314, 318, H335,

H400, H410

no no no no no No Gas

ETP

Cellfloc CE191





75150-29-7

Xi, N, Xn 1 2 flocculantH304, H318, H400,

H411no no no no no yes

Product contains substantance

classified as Dangerous for the

environment. MSDS

ETP Caustic Soda 5% 1310-73-2 C 0.3 0.3 wastewater treatement H314, H290 No no undetermined undetermined no Yes

Precautionary determination.

Full environmental risks of

product unknown.

ETP

Lime (hydrated)

●Calcium Hydroxide

●Crystalline Silica

●1305-62-0

●14808-60-7C <1 <1 wastewater treatement H315, H318, H335 No no undetermined undetermined no no

Solid material. product is not

classified as dangerous for the

environment MSDS.

F/L Gas Oil (diesel) 68814-87-9 Xn, Xi, Carc. Cat. 3, N 5.9 0.5 Back-up Generator

H226, H304, H315,

H332, H351, H373,

H411

no no yes no no YesProduct classified as Dangerous

for the environment. MSDS

Food Grade

Lubricants

Klüber Degrippant NH1 Spray

●Alkanes, C9-12-iso-●90622-57-4 F+, N 0.04 0.04

food manufacturing

equipment

H226,H281, H304,

H413no no no no no no

aerosol, mixture no sub

considered to be PBT or vPvB

Food Grade

Lubricants

Foodlube Spray Chesterton 629

●Naphtha (petroleum)

●petroleum gases

●2,2,4-Trimethylpentane

●64741-66-8

●68476-86-8

●540-840-1

F, N 0.01 0,01food manufacturing

equipmentH225, H304, H411 no no no no no no

semi-solid, haz compound<35%,

not expected to bioaccumulate,

not soluble, has ingredients will

rapidly evaporate to the air if

released

LC

Ammonia Cyanurate Reagent



●Lithium hydroxide

●Sodium dichloroisocyanurate

●6132-04-3

●6016-24-7

●1310-65-2

●2893-78-9

C, Xi 0.001 0.001 Testing chemicalH302, H314, H335,

H400, H413no no no no no no solid sub, haz component <5%

LC

Ammoxia Test N Tube Reagent

●Sodium saliclate

● caustic soda, sodium hydroxide

●54-21-7

●1310-73-2 Xn, C 0.001 0.001 Testing chemical H302 no no

undetermined

(1310-73-2)

undetermined

(1310-73-2)no no Not classified for hazards to the

environment. MSDS

LC


●sulphuric acid



●7664-93-9

●7783-35-9

●7778-50-9

T+, C 0.001 0.001 Testing chemicalH301, H311, H331,

H314, H350i, H412no no undetermined undetermined

Yes

(potassium

dichromate)

Nohaz component <2.5%, small

quantities

LC


●sulphuric acid



●7664-93-9

●7783-35-9

●7778-50-9

T+, C, N 0.001 0.001 Testing chemical

H301, H311, H331,

H332, H314, H350,

H360F, H360D,

H400

no no no no no Nohaz component <2.5%, small

quantities

LC

Molybdate Reagent

●sulphuric acid

● ammonium heptamolydate tetrahydrate

●7664-93-9

●12054-85-2 C 0.001 0.002 Testing chemical H314 no no undetermined undetermined no no

Not classified for hazards to the

environment. MSDS

LC Phosphate Acid Reagent vials

●sulphuric acid ●7664-93-9 Xi 0.002 0.002 Testing chemical H319 no no undetermined undetermined no no


environment. MSDS

LC Sodium Hydroxide 1,54N

●caustic soda, sodium hydroxide ●1310-73-2 C 0.004 0.004 Testing chemical H314 no no undetermined undetermined no no


environment. Haz component

<15%. MSDS

Annual Usage

(tonnes)

Ref. No.

or CodeMaterial/ Substance CAS Number

Danger

Category

Amount Stored

(tonnes)Reason / Data usedNature of Use

Hazard

Statement


Regulations 2009


2010 Controlled

Substances

REACH SVHC

Relevant

hazardous

substance?

Yes/No

For

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Specific

pollutants

Priority

(hazardous)

substances


Annual Usage

(tonnes)

Ref. No.


Danger

Category

Amount Stored


Hazard

Statement


Regulations 2009


2010 Controlled

Substances

REACH SVHC

Relevant

hazardous

substance?

Yes/No

LC TN Acid Reagent

●sulphuric acid ●7664-93-9 C 0.002 0.002 Testing chemical H314 no no undetermined undetermined no Yes

Precautionary determination

Liquid substance. Full risks of

product to the environment

unknown. Haz component >80%

LC Total Nitrogen Reagent A

●sodium metabisulphite ●7681-57-4 Xn, 0.002 0.002 Testing chemical H302, H318, no no undetermined undetermined no no

powder substance. Not

classified for hazards to the

environment.

LC Ammonia Solution (25%) 1336-21-6 C, N 0.003 0.003 Testing chemical H314, H400 no no no no no yes

Hazard statement. Liquid

substance. Very toxic to

aquatic organisms.

LC Methylated spirits 64-17-5 F+, Xn 0.003 0.003 Testing chemicalH225, H332, H312,

H302no no undetermined undetermined no yes


Liquid mixture. Contains

undetermined substance under

groundwater regs. Full risks of


unknown.

LC Nitric acid 65% 7697-37-2 O, C 0.003 0.003 Testing chemical H314 no no undetermined undetermined no yesmsds do not allow to enter soil

or water

LC Phenolphthalein solution in Ethanol

●Ethanol ●64-17-5 F 0.003 0.001 Testing chemical H270 no no undetermined undetermined no no


environment.

LC Silver Nitrate 7761-88-8 N 0.003 0.006 Testing chemical H411 no no no no no yes Hazard statment

LC Sodium Hydroxide <0.5%

●caustic soda, sodium hydroxide ●1310-73-2 C 0.03 0.03 Testing chemical H314, H319, H335 no no undetermined undetermined no no



<0.5%. MSDS


●caustic soda, sodium hydroxide●1310-73-2 C 0.01 0.005 Testing chemical H314, H290 no no undetermined undetermined no yes


Liquid substance. Contains




unknown.

LC Sulphuric acid 95-97% 7664-93-9 C 0.02 0.06 Testing chemical H314 no no no no no Yes


Liquid substance. Full risks of


unknown.

CC

Doryl Mould Acid SS

●Sulphamic acid


●5329-14-6

●7722-84-1C, N 2 18 disinfectant H314 No no undetermined undetermined no Yes

Danger category. Product


environment. MSDS

CC

Bioster


●Peracetic acid

●7722-84-1

●79-21-0C 2 2 cleaning agent H314, H319 No no undetermined undetermined no No


environment. MSDS. Haz

component <10%

CCLactrin F

●sodium hydroxide

n/a

●1310-73-2C 25 364 CIP agent H314, H290 No no undetermined undetermined no no


environment. Substance does

not meet criteria for

classification as PBT or vPvB

(MSDS).

CCLoco DS11 NaOH

●sodium hydroxide

n/a

●1310-73-2C 0.4 0.4 CIP agent H314, H290 no no undetermined undetermined no No



<5%. Substance does not meet

criteria for classification as PBT

or vPvB (MSDS).

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EPA Export 16-02-2019:03:46:00

Specific

pollutants

Priority

(hazardous)

substances


Annual Usage

(tonnes)

Ref. No.


Danger

Category

Amount Stored


Hazard

Statement


Regulations 2009


2010 Controlled

Substances

REACH SVHC

Relevant

hazardous

substance?

Yes/No

CCKingdon 90 Extra

●nitric acid

n/a

●7697-37-2C 2 26 CIP agent H314 No no undetermined undetermined no no

The product is not classified as


MSDS. Biodegradabilty: not

applicable - inorganic substance.

No bioaccumulation potential.

CC Hydrogen peroxide 35% 7722-84-1 C 0.15 0.15 cleaning agent H318, H335 No no undetermined undetermined no no


environment. Product does not

contain any PBT or vPvB

substances. MSDS.

CC

Hydrox 10


● acetic acid


●79-21-0

●64-19-7

●7722-84-1

C, O 2 3.2 sterilent H314 No no undetermined undetermined no yes


Substance does not meet

criteria for classification as PBT

or vPvB. However Liquid

mixture. Contains undetermined

substance under groundwater

regs. Full risks of product to the

environment unknown. Haz

component <15%. Large

discharges may contribute to

acidification and may be fatal to

aquatic life

CC Ntric acid 55/60% 7697-37-2 C 20 6.4 CIP agent H314, H290 No no undetermined undetermined no Yes


Substance not classified as PBT

or vPvB. However Liquid

mixture. Contains undetermined

substance under groundwater

regs. Full risks of product to the

environment unknown. Large

discharges may contribute to

acidification of water and soil

and may injure aquatic life and

soil micro-organisms

CC Hydrochloric Acid 7647-01-0 C, Xi 25 2 Whey plant CIP agent H314, H335 no no no no no Yes


Substance not classified as

dangerous to the environment.

However Liquid mixture with ph

alteration potential. Contains




unknown. Large discharges may

contribute to acidification of

water and soil and may injure

aquatic life and soil micro-

organisms

CC Liquid Caustic 30% 1310-73-2 C 1 4 Testing chemical H314 no no undetermined undetermined no yes


Liquid mixture, water soluble

and can be toxic for aquatic

organisms because of alkalinity

CCAlkaline Foam Cleaner

●Sodium hydroxide

n/a

●1310-73-2C 1 2 detergent H314, H290 No no undetermined undetermined no no



MSDS.

CC

Sodium Hypochlorite 5-15%

●sodium hydroxide


●1310-73-2

●7681-52-9C, N 1.6 3.2 CIP agent H314, H400 NO no

undetermined

(1310-73-2)

√

(7681-52-9) no yes

Haz statement. Product


environment. MSDS

CC

Divos 95 VM37

●Potassium hydroxide

● sodium carbonate

● tetrasodium ethylene diamine tetraacetate

●1310-58-3

●497-19-8

●64-02-8

C 2 10 Whey RO Plant CIP agent H318 No no undetermined undetermined no No



MSDS. Low potential for

adsorption

to soil

CC

Divos ADD3 VM16

●sodium alkylbenzenesulphonate

● sodium hydroxide

●90194-45-9

●1310-73-2 C 2 4 Whey RO Plant CIP agent H315, H318 no no undetermined undetermined no no



MSDS.

CC

Divos 2 VM13

●nitric acid

● phosphoric acid

●7697-37-2

●7664-38-2 C 6 12 Whey RO Plant CIP agent H314, EUHO71, H290 no no undetermined undetermined no no



MSDS.

CC Rocklor 7681-52-9 C, N <1 <1 sanitation H314, H400 NO No no √ no yes

Haz statement. Product


environment. MSDS

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APPENDIX 3

STAGE 3 ASSESSMENT

Assessment of Identified Relevant Hazardous Substances used or generated at the

installation

For

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ectio

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s only

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Specific

pollutants

Priority

(hazardous)

substances


ETP

Cellfloc CE191





75150-29-7

Xi, N, Xn 1 2 flocculant H304, H318, H400, H411 no no no no no yes

Product contains substantance classified as Dangerous for the

environment. MSDS

Low. Suitable containment and storage

ETP Caustic Soda 5% 1310-73-2 C 0.3 0wastewater

treatementH314, H290 No no undetermined undetermined no Yes

Precautionary determination. Full environmental risks of

product unknown.


F/L Gas Oil (diesel) 68814-87-9

Xn, Xi,

Carc. Cat.

3, N

5.9 0.5Back-up

Generator

H226, H304, H315,

H332, H351, H373,

H411

no no yes no no YesProduct classified as Dangerous for the environment. MSDS Low. Suitable bunded containment and storage.Routine

visual inspections

LC TN Acid Reagent

●sulphuric acid ●7664-93-9 C 0.002 0.002 Testing chemical H314 no no undetermined undetermined no Yes

Precautionary determination Liquid substance. Full risks of

product to the environment unknown. Haz component >80%

Low. Considering the limited amount applied during use, the

size of the container, the amounts stored on site and storage

indoors, the risk of adverse effects is considered small.

LC Ammonia Solution (25%) 1336-21-6 C, N 0.003 0.003 Testing chemical H314, H400 no no no no no yes

Hazard statement. Liquid substance. Very toxic to aquatic

organisms.




LC Methylated spirits 64-17-5 F+, Xn 0.003 0.003 Testing chemicalH225, H332, H312,

H302no no undetermined undetermined no yes

Precautionary determination. Liquid mixture. Contains

undetermined substance under groundwater regs. Full risks

of product to the environment unknown.




LC Nitric acid 65% 7697-37-2 O, C 0.003 0.003 Testing chemical H314 no no undetermined undetermined no yes

msds do not allow to enter soil or water Low. Considering the limited amount applied during use, the



LC Silver Nitrate 7761-88-8 N 0.003 0.006 Testing chemical H411 no no no no no yes

Hazard statment Low. Considering the limited amount applied during use, the




●caustic soda, sodium hydroxide●1310-73-2 C 0.01 0.005 Testing chemical H314, H290 no no undetermined undetermined no yes

Precautionary determination. Liquid substance. Contains

undetermined substance under groundwater regs. Full risks

of product to the environment unknown.




LC Sulphuric acid 95-97% 7664-93-9 C 0.02 0.06 Testing chemical H314 no no no no no Yes

Precautionary determination. Liquid substance. Full risks of

product to the environment unknown.




CC

Doryl Mould Acid SS

●Sulphamic acid


●5329-14-6

●7722-84-1C, N 2 18 disinfectant H314 No no undetermined undetermined no Yes

Danger category. Product classified as Dangerous for the

environment. MSDS


CC

Hydrox 10


● acetic acid


●79-21-0

●64-19-7

●7722-84-1

C, O 2 3.2 sterilent H314 No no undetermined undetermined no yes

Precautionary determination. Substance does not meet

criteria for classification as PBT or vPvB. However Liquid

mixture. Contains undetermined substance under

groundwater regs. Full risks of product to the environment

unknown. Haz component <15%. Large discharges may

contribute to acidification and may be fatal to aquatic life


CC Ntric acid 55/60% 7697-37-2 C 20 6.4 CIP agent H314, H290 No no undetermined undetermined no Yes

Precautionary determination. Substance not classified as PBT

or vPvB. However Liquid mixture. Contains undetermined

substance under groundwater regs. Full risks of product to

the environment unknown. Large discharges may contribute

to acidification of water and soil and may injure aquatic life

and soil micro-organisms


CC Hydrochloric Acid 7647-01-0 C, Xi 25 2Whey plant CIP

agentH314, H335 no no no no no Yes

Precautionary determination. Substance not classified as

dangerous to the environment. However Liquid mixture with

ph alteration potential. Contains undetermined substance

under groundwater regs. Full risks of product to the

environment unknown. Large discharges may contribute to

acidification of water and soil and may injure aquatic life and

soil micro-organisms


CC Liquid Caustic 30% 1310-73-2 C 1 4 Testing chemical H314 no no undetermined undetermined no yes

Precautionary determination. Liquid mixture, water soluble

and can be toxic for aquatic organisms because of alkalinity


CCSodium Hypochlorite 5-15%

●sodium hydroxide


●1310-73-2

●7681-52-9C, N 1.6 3.2 CIP agent H314, H400 NO no

undetermined

(1310-73-2)

√

(7681-52-9) no yesHaz statement. Product classified as Dangerous for the

environment. MSDS


CC Rocklor 7681-52-9 C, N <1 <1 sanitation H314, H400 NO No no √ no yes Haz statement. Product classified as Dangerous for the

environment. MSDS


Danger

Category

Amount Stored

(tonnes)

Annual Usage

(tonnes)

Reason / Data used Likelihood of potential pollution risk to soil/groundwater

STAGE 3 ASSESSMENT: Assessment of Pollution Risk by identified ‘Relevant Hazardous Substances’ used or generated at Dairygold Mogeely

Nature of Use Hazard Statement


Regulations 2009


2010 Controlled

Substances

REACH SVHC

Relevant

hazardous

substance?

Yes/No

Ref. No.


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