attachment no. g resource use and energy · pdf file10 17 beta estradiol ep -50-28-2 toxic...

IPF’C Licence Application Attachment No. G

ATTACHMENT No. G

RESOURCE USE AND ENERGY EFFICIENCY

TABLE OF CONTENTS

G.1 Raw Materials and Products Tables

6.2 Energy Eficiency Audit

2

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IPPC Licence Application Attachment No. G

Table G.l(i): Details of ProceS s related Raw Materials, Intermediates, Products, etc., used or generated on the site

Ref. N2 or c-+,2..

Material/ Substance”’

- CAS flumber

Dangerc2’ Category

Amount Annual Stored Usage

(tonnmh (tnnnfs~

Nature of Use Rc3’ m s”’ - Phrase Phrase

LUUL: \-------I /

\-------/

1 ACETAMINOPHEN DC-90 N/a 3.840 20.838 GTs Active N/a N/a

- Paracetamol 103-90-2 9005-26-8

I

2 I ALULAMII itnnt I n5f3-l I 17 no HTs Active 40, 23/24/25 36 3 ACETYLSALIC~LIL; AC;IU -- .-- .-. . . -. , . . . . .I. . . .-. .-- .--.J8 GTs Active 22 26;37 4 ANHY CALCIUM HYDROGEN PHOS. EP -789-77-7 3.439 13.620 Active

J3N 00319) / 5 BISOPROLOL FUMARATE 66722-44-g Harmful 0.396 1.815 Efexor (Lederle) Active 20121 I22 720/21/22 6 CAFFEINE )58-08-2 Harmful 3.06 15.3 GTs Active R 20122 s 37139

- 7 ESTRADIOL VALERATE USP MICRO 979-32-8 Toxic 0.057 0.070 OCs Active R60/63/40/64 S 53145 (x8---‘

8 ESTRIOL, USP, MICRONISED a”-c,- I nalllll”l “.“4/ u.u4u ULS n IS AC~IVB 4/ ;ou;D.3;04 43;33 - 9 ETHINYLESTRADIOL EP MICRONISED 57-63-6 Toxic 0.037 0.110 OCs Active R 40/60/63/64 53145

(RN ~0140) 10 17 BETA ESTRADIOL EP -50-28-2 Toxic 0.099 0.150 HTs Active 20121122 22

(~0081) 4Ol42l43 60 63 36137138 4553

11 GESTODENE MICRONISED -0280-87-3 Harmful 0.010 1.703 OCs Active 20121122 -

RNzOl32/ ~0153 -0 MSDS 0.5 Active

IOLE EC GRANULES 7 Harmful, Irritant 22.005 130.247 Active 20121122 20/21;22;2 - __.^ -I^-

IZ ULYliizllYL

13 LANSOPRA? (RNzOl30lz0144) I I I I I 1 ti;BtS/B//BY

14 LEVONORGESTREL, BP, MICRONISED -787-63-7 Toxic 0.042 0.321 OCs Active 47 12/13;63 ,l-.LI ..,-.-,_I,-.\

,(r¶l\ x3, IL, I I

15 LORAZEPAM -846-75-9 Toxic 0.706 2.359 TRANQs Active R22l63 3/7/8/37/3 TN 09010, x9025) 8

,,

Notes: 1. 2. 3.

In cases where a material comprises a number of distinct and available dangerous substances, please give details for each compo c.f. Article 2(2) of SI N’! 77194 c.f. Schedules 2 and 3 of SI l@ 77’94

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* ‘C Licence Application 0 a Attachment Na

Table G.l(ii): Details of Process related Raw Materials, Intermediates, Products, etc., used or generated on the site

Ref. TA Luft Odour EU Lists I and II Ne or Material/ Class 1, (Tick and specify Group/Family Number) Code Substance’2’ 2or3 Odourous Threshold Dangerous Substances Directive Groundwater Directive

Yes/No Description 761464iEEC 80/68/EEC xh3 List I List II +12gc4) List I List II

1 ACETAMINOPHEN DC-90 N/A No 2 ACETAZOLAMIDE N/A No 3 ACETYLSALICYLIC ACID N/A No 4 ANHY CALCIUM HYDROGEN NA No

Notes (cont.): 4. The European Commission priority candidate list

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Table G.l(i): Details of Process related Raw Materials, Intermediates, Products, etc., used or generated on the site +

Ref. Material/ CAS Dangerc2’ Amount Annual Nature of Use R”’ m Sc3’ _ NC or Substance”’ Number Category Stored Usage Phrase Phrase Code (tonnes) (tonnes)

16 LORMETAZEPAM MICRONIZED (RN x8801) /

17 MEDROGESTONE, MlCRONlSED 977-7y Toxic 0.023 0.332 OCs Active 20/21/22 7lf73l74

18 MEDROXYPROGESTERONE 71-58-9 Flammable 0.225 0.275 HRTs Active 20/21/22; 36139 ACETATE EP (x9848) /

19 METHYLCELLULOSE EP ISCPS 9004-34-E

47 Irritant 0.054 0.080 Active/Excipient 1 O/22 28

(RN 20139) 20 MINOCYCLINE HCL EP Irritant, Harmful

36137139 20/22;36 7;22;26/20

/ 21 NORGESTREL, USP, MlCRONlSED 6533-00-2

I21 Toxic 0.015 0.071 OCs Active 21/22/23; 20/21/22l2

47 Toxic

3;12 2.674 8.551 TRANQs Active 23124125 37139

PARACETAMOL DC Toxic, Harmful 12.449 79.28 GTs Active 51 37139 24 PREMARIN 0.3MG BULK GRAN RP Harmful, Corrosive 47.289 173.9 HRTs Active/ 21122l23; 36139

45 0.023 0.025 ActivelExcip 8 2Ol2l22 26127128

26 TRIMEGESTONE Harmful 0.023 0.006 HRTs Active 48 7 37139 47 (~0082) 2Ol21122

/ 63

27 VENLAFAXINE HCL 99300-78-4 Irritant 39.067 87.971 TRANQs Active 22 22 (RN222865/x9541) -

28 ZALEPLON MICRONISED AWPl N/A +

0.01 TRANQs Active

lof2 Notes: 1. in cases where a material comJ?rises a number of distkt and available dangerous substances, please give details for each component substance.

2. c.f. Article 2(2) of SI N’ 77194 3. c.f. Schedules 2 and 3 of SI N9 77/94

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* C Licence Application Attachment Ne


9 20 21

22 23 24

25 26 27 28

ACETATE EP METHYLCELLULOSE EP 15CPS MINOCYCLINE HCL EP NORGESTREL, USP, MICRONISED OXAZEPAM PARACETAMOL DC PREMARIN 0.3MG BULK GRAN RP STEARIC ACID BP TRIMEGESTONE VENLAFAXINE HCL ZALEPLON MICRONISED AWPI

’ TALuft 1 Odour I EU Lists I and JI ‘,


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Table G.l(i): Details of Process related Raw Materials, Intermediates, Products, etc., used or generated on the site

Ref. Material/ CAS Dangerc2) Amount Annual Nature of Use Rc3’ _ s(3) - NC or Substance”’ Number Category Stored Usage Phrase Phrase Code (tonnes) (tonnes)

29 Aerosil200 (Silica colloidal) ,$45-52-5 0.17 0.17 Excipient - Silicon Dioxide (RN 9724) 7631-86-9

30 CARMINE POWDER ,&3-60-5 N/a 0.019 0.01 Excipient S22.536/37 (RNOl-1208-6) s43;s51/57

31 DILACTOSE JP N/a N/a

32 ETHYLCELLULOSE NF/EP (1OCPS) (50 CPS) 9s-57-3 5.669 5.600 Excipient 6.551 11.847 Excipient

(RN058320000, x9623) 33 FD&C BLUE #2 ALUM LAKE HT.5627 ,6al-38-3 0.07 0.11 Excipient/Colour

(RNOl-1208-8/010155000/x1953) 34 FERRIC OXIDE NF YELLOW -4-00-i N/A 0.02

l-6-72-4

Excipient

35 GLYCERYL MONO-OLEATE N/a

0.210 - 36 v-o-31 -1

0.155 HPMC PHTHALATE HP-50 (RNl7741) Irritant 0.16 Excipient 0.2 Excipient

37 LACTOSE MONOHYDRATE 75 MESH, 90 -9-26-6 5.436 13.560 Exciaient

38 39

40

Mesh, EP (DC), (Pharmatose) (RN TRLX9713, x9216, x9713) LACTOSE NF SPRAY DRIED (US) -1-93-1 / LACTOSE NF/EP HYDROUS (Jp, 100 mesh, 80 - mesh, 200mesh, 72 mesh) (RN x8881, x9670, x9687, x9706, x971 6,zOO93) / LACTOSE,NF,POWDER,ANHYDROUS

0.4 85.406

9.317

332.375

20.406

Excipient Excipient

Excipient (RN70010) -

41 LIGHT MINERAL OIL NF (RN62600) 0.239 0.177 Excipitent 42 MAIZE STARCH EP/Snowflake (RN 00369, &iii-25-8 14.836 77.600 Excipient

X9672, x91 65) / 43 NON-PAREIL SEEDS SIEVE 5.789 10.00

57-50-1, Excipient 36 7, 22,26,

- Sucrose - Starch (RNz0088) go@+25-8

S28,46

lof2

Notes: 1. h, cases where a material comprks a number of distinct and available dangerous substances, please give details for each component substance. 2. c.f. Article 2(2) of SI N’77/94 3. c.f. Schedules 2 and 3 of SI N’ 77/94

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e C Licence Application Attachment N 0


11 Ref. 1 1 TALuft 1 Odour I EU Lists I and II N2 or Material/ Class 1, (Tick and specify Group/Family Number) Code Substance”’ 2or3 Odourous Threshold Dangerous Substances Directive Groundwater Directive

Yes/No Description 761464ffiEC 80/68/EEC

dm3 List I List II +12gc4’ List I List II

29 Aerosil 200 N/A No 30 CARMINE POWDER N/A No 31 DILACTOSE JP N/A No 32 ETHYLCELLULOSE NF/EP (50 CPS) N/A No

33 34 35 36 37

38 39 40 41 42

43

(1OCPS) FD&C BLUE #2 ALUM LAKE HT.5627 FERRIC OXIDE NF YELLOW GLYCERYL MONO-OLEATE HPMC PHTHALATE HP-50 LACTOSE MONOHYDRATE 75 MESH, 90 Mesh, EP (DC), (Phatmatose) (RN TRLX9713, x9216, x9713) LACTOSE NF SPRAY DRIED (US) LACTOSE NF/EP HYDROUS LACTOSE,NF,POWDER,ANHYDROUS LIGHT MINERAL OIL NF MAIZE STARCH EP/Snowflake (RN 00369, X9672, x91 65) NON-PAREIL SEEDS SIEVE

N/A No N/A No N/A No N/A No N/A Yes

N/A Yes N/A No N/A No N/A Yes N/A Yes

N/A No

Faintly sweet

Faintly sweet

Mild Nearly odourless

2of2 Notes (cont.): 4. The European Commission priority candidate list

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Ref. Material/ CAS Dangert2’ Amount Annual Nature of Use Rc3’ m S”’ s

N2 or Substance(‘) Number Category Stored Usage Phrase Phrase Code (tonnes) (tonnes)

44 BREOX POLYETHELYNE GLYCOL 45 QUININE SULPHATE,EP Toxic, Harmful 0.061 0.126 Excipient 20/21/22 26 36

36137138 42l43

46 47

48

49

RICE STARCH EP N/A-b-- 5.815 15.650 Excipient - SODIUM LAURYL SULPHATE NF/BP No MS@ 0.091 0.091 Excipient

(RN 20151) - SODIUM STARCH GLYCOLLATE BP 9063-38-l Irritant, Harmful 560.57 1.65 Excipient 20 22 36 3 718 22 26

28 46 LUZEMAC PHARMA (TALC) 7.689 22.300 Excipient CHLORITE TALC 14807-96-6

1318-29-a (RN 20145)

lof2 Notes: 1. in cases where a material comprises a number of distinct and available dangerous substances, please give details for each component substance.

2. c.f. Article 2(2) of SI NQ 77/94 3. c.f. Schedules 2 and 3 of SI T’@ 771%

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e C Licence Application a Attachment N e


Ref. TA Luft Odour Ne or Material/ Class 1, Code Substance”’ 2or3 Odourous

Yes/No Description

44 BREOX POLYETHELYNE GLYCOL Yes Mild, sweet 45 QUININE SULPHATEEP N/A 46 RICE STARCH EP N/A No 47 SODIUM LAURYL SULPHATE

NFIBP 48 SODIUM STARCH GLYCOLLATE N/A No

BP 49 LUZEMAC PHARMA (TALC) No

TALC CHLORITE (RN 20145)

Notes (cont.): ~ 4. The European Commission priority candidate list

Threshold

Mm3

EU Lists I and II (Tick and specify Group/Family Number)

Dangerous Substances Directive Groundwater Directive 761464ffiEC 80/68/EEC

List I List II +1 29(4) List I List II

2of2

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Ref. Material/ CAS Danger”’ Amount Annual Nature of Use Rc3’ - s(3) - NC or Substance”’ Number Category Stored Usage Phrase Phrase Code (tonnes) (tonnes)

50 Premarin MPA HRT Bulk Product - Premarin N/A Variable Variable

- Conjugated Estrogens 12126-59-g - Lactose 63-42-3 - Methyl Cellulose

- MPA 9004-67-S

71-58-9, N/A

51 Zaleplon Caps 1 Omg (Sonata) None N/A 3,529,820 11,200,OO TRANQs Bulk Product - - Zaleplon tabs 0 tabs

52 Zaleplon Caps 5mg (Sonata) N/A 299,980 2,800,OOO TRANQs Bulk Product - - Zaleplon None, tabs tabs

53 Loettes 1.616 9.639 OCs Bulk Product - Gestodene 60282-87-S Toxic (Ethinylestradiol) Ol63/40/64 S 53145 - Ethinylestradiol 57-63-6,

54 Loettes Placebo 0.0075 1.035 OCs Bulk Product -

55 Efexor LP 37.5mg Zero 1 Efexor (Lederle) Bulk - Venlafaxine Irritant last Product R 38 S8

imported 2002

56 Efexor XR 75mg 2.526 9.275 Efexor (Lederle) Bulk - Venlafaxine Irritant / Product R 38 58

57 Efexor XR 150mg Zero 6.89 Efexor (Lederle) Bulk - Venlafaxine Product R 38 58

- Cyclohexanol Irritant - l-[2-(dimethylamino)-l-(4-

methoxyphenyl)ethyl] - Hydrochloride(+/-)

lof2 Notes: 1. In cases where a material coaP rises a number of distinct and available dangerous substances, please give details for each component substance.

2. c.f. Article 2(2) of SI NQ 77194 3. c.f. Schedules 2 and 3 of SI N’ 77’94

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e C Licence Application Attachment Ne

E

Ref. TA Luft Odour EU Lists I and II Ns or Material/ Class 1, (Tick and specify Group/Family Number) Code Substance’2’ 2or3 Odourous Threshold Dangerous Substances Directive Groundwatcr Directive

Yes/No Description 761464iEEC 80/68/EEC pg/m3 List I List II +129’4’ List I List II

50 Premarin MPA - Premarin N/A Yes Distinct ND

- Conjugated Estrogens - Lactose

- &PA Methyl Cellulose

No 51 Zaleplon Caps 1 Omg (Sonata) N/A

- Zaleplon N/A

52 Zaleplon Caps 5mg (Sonata) N/A - Zaleplon N/A

53 Loeites N/A - Gestodene No - Ethinylestradiol No

54 Loettes Placebo N/A No No

55 Efexor LP 37.5mg N/A - Venlafaxine ND

56 Efexor XR 75mg N/A - Venlafaxine ND

57 Efexor XR 15Omg N/A - Venlafaxine ND

- ^_ = 2of2

Table G.l(ii): DetaiIs of Process related Raw Materials, Intermediates, Products, etc., used or generated on the site


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Ref. N” or

Table G.l(i):


Details of Process related Raw Materials, Intermediates, Products, etc., used or generated on the site +

CAS Dangerc2’ Amount Annual Nature of Use Rc3’ - s”’ - Number Category Stored Usage Phrase Phrase

I (tonnes) (tonnes) 4 4.545 20.181 HRTs Bulk Product

N/A

Code 1 58 IPremarin 1.25mg

59

- Premarin - Conjugated Estrogens - Lactose - Methyl Cellulose

Premarin 0.625mg - Premarin

- Conjugated Estrogens - Lactose - Methyl Cellulose

12i26-59-Q 63-42-3

9004-67-a

lm?6-59-Q 63-42-3

9004-67-S I

60 IPremarin 0.3mg I 4

12126-59-Q 63-42-3

9004-67-L

60282-87-s 61

- Premarin - Conjugated Estrogens - Lactose - Methyl Cellulose

Gestodene 60/i 5 - Gestodene - (13 beta ethyl 17 alpha ethynyl 17

beta hydroxy 4,5,gonadien 3 one

4 62 Gestodene (Branded)

- Gestodene 60282-87-S

63 Rapamune Oral Solution - Rapamycin - Polyoxyethylene - Phosal50PG

-

53123-88-g 9005-65-e

None -

N/A 14.203 53.4 HRTs Bulk Product

N/A 3.040 4.752 HRTs Bulk Product

Dust Explosion if micronised May impair Fertility

zero 0.36 OCs Bulk Product

May cause harm to the unborn child Possible risks of irreversible effects

May cause harm to breastfed babies Dust Explosion if micronised

May impair Fertilitv 0.132 0.81 OCs Bulk Product

May cause hati to the unborn child Possible risks of irreversible effects

May cause harm to breastfed babies N/A Variable Variable Efexor (Lederle) Bulk -

Product

Notes: 1. 2. 3.

lof2 h cases where a material comprises a number of distinct and available dangerous substances, please give details for each component substance. c.f. Article 2(2) of SI N’ 77194 cf. Schedules 2 and 3 of SI PT’ 77194

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* C Licence Application 0 Attachment Ne


2of2

Ref. TA Luft Odour EU Lists I and II N2 or Material/ Class 1, (Tick and specify Group/Family Number) Code Substance(2) 2or3 Odourous Threshold Dangerous Substances Directive Groundwater Directive

Ye&Jo Description 761464lEEC 80/68/EEC llg/m3 List I List II +12gc4) List I List II

58 Premarin 1.25mg - Premarin Yes Distinct ND






61 Gestodene 60115 - Gestodene No

62 Gestodene (Branded) - Gestodene No

63 Rapamune Oral Solution ND - Rapamycin - Polyoxyethylene - Phosal50PG


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e Ref. 1 Material/ I CAS I Danger”’ 1 Amount 1 Annual 1 Nature of Use lRc3’ - 1 Sc3’ - - N2 or Substance(‘) NIlId= Category Stored Usage Phra Phrase

se Code (tonnes) (toMe?.)

/ 64 COLOR FD&C YELLOW #5 (ALUM LAKE / N/A 0.049 0.085 Colour N/A N/a

Cerl El02 ) ,9&1-O (RN X9386,26315,ZOl26,26515,26300) -

65 FD&C #6, YELLOW LAKE CERTIFIED 1579-07-5 N/a 0.262 0.063 Colour N/A (RN 26315/ x9386)

N/a

66 OPALUX dry (COLOR, AY-20980 BLUE N/A 0.244 0.295 N/A N/a and Color AY23005 Orange COLORCON) (20154/X9744,X9743) /

67 COLOUR BRILLIANT SCARLET 4R N/A 0.006 0.010 N/A N/a 68 COLOUR ERYTHROSINE ,642%8-O N/A 0.033 0.040 Colour

(RN26000) 69 COLOUR IRON OXIDE El72 1309*-l N/A 0.496 0.429

51274-o”-1 N/A N/A N/A

(Brown/Yellow/Red-BrownlChoc- Brown/Red) (RN091540,091545, x8827, x8828, x9098, 20150)) -

70 ERYTHROSINE LAKE El27 805005 16423-$8-o N/a 0.01 0.01 Colour Highly Flammable

N/A N/A 71 INK BLACK OPACODE S-8-27741 0.435 0.810

m-1 7-5 Colour

- Ethanol - Butan-l-01 71-36'3 - Ethyl Acetate 141-78-6 (20059)

72 INK WHITE OPACODE S-8-28905 Flammable 0.538 0.476 Colour - Ethanol 64-i7-5 - Butan-l -01 71-36-3 - Ethyl Acetate 141-78-6 - Ammonia Solution (zO188/x9923)

133~?-2'-~ -

73 MAROON CONC. Tl168 (RN 20149) No MS&?’ 0.127 0.574 Colour

lof2 In cases where a material comP rises c.f. Article 2(2) of SI N’ 77/94

a number of distinct and available dangerous substances, please give details for each component substance.

c.f. Schedules 2 and 3 of SI I@ 77’g4

Notes: 1. 2. 3.

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e C Licence Application Attachment N e


Ref. TA Luft Odour EU Lists I and II N2 or Material/ Class 1, (Tick and specify Group/Family Number) Code Substance(2) 2or3 Odourous Threshold Dangerous Substances Directive Groundwater Directive

Yes/No Description 761464iEEC 80/68iEEC w2h3 List I List II +12gc4’ List I List II

64 COLOR FD&C YELLOW #5 (ALUM N/A No LAKE I Cert El 02 ) (RN X9386,2631 5, ZO126,26515, 26300)

65 FD&C #6, YELLOW LAKE N/a No CERTIFIED (RN 263151 x9386)

66 COLOR, AY-20980 N/A No BLUE(COLORCON)

67 COLOUR BRILLIANT SCARLET 4R N/A No 68 COLOUR ERYTHROSINE N/A No 69 COLOUR IRON OXIDE El72 N/A No

(Brown/Yellow/Red-Brown/Choc- Brown/Red) (RN091 540,091545, x8827, x8828, x9096,zO150))

70 ERYTHROSINE LAKE El27 805005 N/a No 71 INK BLACK OPACODE S-8-27741 N/A Yes Alcoholic 72 INK WHITE OPACODE S-8-28905 N/A Yes Alcoholic 73 MAROON CONC. T1168 N/A

4 ..a*


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Ref. Material/ CAS Danger”’ Amount Annual Nature of Use R”’ m s”’ - N2 or Substance(l) Number Category Stored Usage Phrase Phrase Code (tonnes) (tonnes)

/ 74 CAP Shell ORANGE/BODY BROWN, 25.269 80.964 Excipient

LavendaVamethyst, transpar green, transpar blue, pink ibod white, yellow ‘lederle’ , peach , natural) orange,

(RN’s 00368,00594,00824,00596, 00664,8124220,8124820,00369, 0233132~0, trlz0223,0252142po, trlz0224, 028013Op0, trlz0225, glOcsOO127O,zO157) /

75 Licowax E Pharma 7338-452’ 0.016 0.007 Excipients 76 Methanol 67-56-I Toxic, Highly Flammable 68.97 176.01 Solvents 11 II2 7 16

(RN10024) 23124125 36137 45 39 /

77 Methylene Chloride NF 75-09-z Harmful 96.29 296.27 Solvents 40 23124125 (RN45955) 36f37 -

78 Industrial Methylated Spirit 740PBP Harmful 0.62 1.46 Solvents 11 X71636137 - Ethanol Highly Flammable 20/21/22 45

4012012 1 I22

Harmful 0.113 0.306 Solvents 65 66 23124 62 0.045 0.100 Excipient

81 White Wax NF (RN 9443) 0.012 0.025 - Excipient 82 Carnauba Wax EP Powdered 0.018 0.025 Excipient

(RN zO079) - 83 Wax E Pharma (RNzOl46) 73138-452 0.047 0.125 Excipient

lof2 Notes: 1. ~ cases where a material c,@prises a number of distinct and available dangerous substances, please give details for each component substance.

2. c.f. Article 2(2) of SI N”- 77/94 3. c.f. Schedules 2 and 3 of SI @ 77’94

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EPA Export 25-07-2013:15:14:22

e C Licence Application Attachment Na


Ref. N’! or Code

74

75 76 77

78 79 80 81 82 83

Material/ Substance”)

CAP Shell ORANGE / BODY BROWN, Lavendar/amethyst, transpar green, transpar blue, pink /hod white, yellow ‘lederle’ , orange, peach, natural)

(RN’s 00368,00594,00624,00596, 00664,8124220,8124620,00389, 0233132~0, trIz0223,0252142po, trlz0224, 028013Op0, trlz0225, ~lOcsOO1270, ~0157) . .

TA Luft Class 1, 2or3

N/A

Odour I EU List IandII II

Odourous Yes/No

No

Description Threshold

mdm3

(Tick and specify GI Dangerous Substances Directive

761464lEEC List I List II +12gc4’

Methylene Chloride NF I 3 I I

1 Yes Sharp per

mp/Family Number) Groundwater Directive

80/68/EEC List I List II


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Ref. Material/ CAS Dangerc2’ Amount Annual Nature of Use R”’ m s”’ - NC or Substance(‘) Number Category Stored Usage Phrase Phrase Code (tonnes) (tonnes)

a4 BIOMATE 5702 Corrosive <2 3 Utilities R31 R34 526 528 - sodium hypochlorite 7681-52-9 S36137139

545 - a5 BIOMATE 5725 Harmful e2 1 Utilities R20l22 S23

- 2,2-dibromo-3-nitrilopropionamide 10222-01-2 R36 R43 526127128 - diethylene glycol S36/37/39 - poly, aplohe-phenyl-omega-hydroxy 111-46-6

~~~~~~~ 86 CONTINUUM AEC3153 Irritant <2 6 Utilities R36l38 526 528

- chlorotolyltriazole sodium salt 202420-Ob-4 S36/37/39 - sodium hydroxide

310-730s a7 CORRSHIELD MD4100 Toxic <I 1.5 Utilities R25 526 S27

- sodium molybdate 763-95-o R36l38 s28 - sodium nitrite 7632-00-O S36ll37139 - sodium hydroxide 131 o-732 S45 S60

88 CORRSHIELD OR4410 Irritant co.5 1 Utilities R36l38 526 S28 - cyclohexylamine I 08-g-8 S36/37/39 - n,n diethylhydroxylamine 371 o-84-7 - Tolyltriezole 29385-43:

a9 CORTROL IS3000E Harmful cl 2 Utilities R22 R31 523 S26 - sodium bisulphite 7631-90-S s28

S36137139 90 CORTROL OS5300 Harmful <2 1 Utilities RIO R40 S16 526

- Hydroquinone 123-31-g R43 527 S28 - n,n diethylhydroxylamine 371 o-84-7 R20l2 536137139

R36l37l3 a

Notes: 1. 2. 3.

lof2 h cases where a material comprises a number of distinct and available dangerous substances, please give details for each component substance, c.f. Article 2(2) of SI N’ 77/94 c.f. Schedules 2 and 3 of SI I@ 77194

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EPA Export 25-07-2013:15:14:23

e- C Licence Application a Attachment Nb


Ref. N2 or Code

64

85

86

87

88

89

90

Material/ Substance(2)

BIOMATE 5702 - sodium hypochlorite BIOMATE 5725 - 2,2-dibromo-3-

nitrilopropionamide - diethylene glycol - poly, aplohe-phenyl-omega-

hydroxy

CONTINUUM AEC3153 - chlorotolyltriazole sodium salt - sodium hydroxide CORRSHIELD MD4100 - sodium molybdate - sodium nitrite - sodium hydroxide CORRSHIELD OR4410 - cyclohexylamine - n,n diethylhydroxylamine - Tolyltriazole CORTROL IS3000E - sodium bisulphite CORTROL OS5300 - hydroquinone - n,n diethylhydroxylamine

TA Luft Odour EU Lists I and II Class 1, (Tick and specify Group/Family Number) 2or3 Odourous Threshold Dangerous Substances Directive Groundwater Directive

Yes/No Description 76/464lEEC 80/68/EEC wdm3 List I List II +129’4’ List I List II

Chlorine J J Yes 1 1

Yes Mild 2

3 N/A

4 Yes Mild 4 1 1

4 Yes Mild 4 1:9 1:9

Yes Ammoniacal

Yes Slight

Yes Amine


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OPTIGUARD MCP1520 91 - sodium bisulphite

- sodium sulphite

95 SPECTRUS OX 1203 - 1-bromo, 3-chloro, 5.5-dimethyl hydantoln

Sulphuric Acid 35% (Battery Acid)

Sodium Hydroxide 30% (Caustic Acid)

100 Buffer Solution pH 4.0 101 Buffer Solution pH 10.0

Alcoseal3-3 - HexyleneGlycol

102 : Hydrolysed Protein Flourosuffactants

- Polymer - Bactericide

103 HydroVane Fluid Force Clear -blend of mineral oils

CAS Danger”’ Number Category

Amount Annual Nature of Use R”’ m Stored Usage Phras (tonnes) (tonnes)

7631-90-S 7757-83-Y

Corrosive

cl

c2

Utilities

Utilities

1310-58-s Cl 2 Utilities I I I I

7647-l 5-6

Oxidising, Harmful I 4 I 2 I - 31885-97-9

7664-93-g

7664-93-g 1

Corrosive

Corrosive

<l

4

4

4

Utiilities

Utilities R35 I I !

I I 3 <I2 Utilities 1 R35

Corrosive 3 <12 Utilities R35

Irritant

-

;e I

Sl 52 S26 s30 s45

52 S26 S30 S26 S37l39

s45 S24l25

524

lof2 In cases where a material comprises a number of distinct and available dangerous substances, please give details for each component substance. c.f. Article 2(2) of SI N’ 77194 c.f. Schedules 2 and 3 of SI N’ 77194

Notes: 1. 2. 3.

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EPA Export 25-07-2013:15:14:23

e C Licence Application 0 a Attachment N Q


- HexyleneGlycol

7

Ul L


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Table G.l(i): Details of Process related Raw Materials, Intermediates, Products, etc., used or generated on the site - 1 I 1

- Cellulose Nitrate

<I

Cl <I <2

cl

11 <I

3

Packaging

Packaging

R”’ - r&3' _

Phrase Phrase I 1 I I I

-” 24125

36137 1 16 33 719 24125

R S 16/33l7l9l~ 1 I36137 4125

t I

--I_ lof2

h cases where a material comprises a number of distinct and available dangerous substances, please give details for each component substance. c.f. Article 2(2) of SI NQ 77194 c.f. Schedules 2 and 3 of SI N’ 77’9

Notes: 1. 2. 3.

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EPA Export 25-07-2013:15:14:23

e C Licence Application 0 Attachment N 0


Ref. TA Luft Odour EU Lists I and II Ng or Material/ Class 1, (Tick and specify Group/Family Number) Code Substance(‘) 2or3 Odourous Threshold Dangerous Substances Directive Groundwater Directive

Yes/No Description 76/464/EEC 80/68/EEC

t&m3 List I List JI -l-129@’ List I List II

104 Chemical, Silica Gel No 105 Chemical, Methyl Orange Yes Alcoholic 106 Chemical, Methylene Blue 107 Domino 0121X Makeup Yes Slightly ketonic

- Butanone 3 - Ethanol - Isopropyl Acetate N:A - Propan-2-01 1

108 Domino 1000 Wash Yes Ketonic - Butanone 3

109 Domino Wl200 Wash Yes Ketonic -Butanone 3

110 Bearing Fit 111 Bostic, All purpose glue 112 Black Printing Ink Yes Ketonic

- Butanone 3 - Butanol N/A - Ethyl Acetate 2 - Ethanol - Propon-2-01

3

- Methanol N/A

- Cellulose Nitrate N:A 113 Fluid Silicon 1207 -

114 Glue Dorus PS578S Yes Slightly Intrinsic 115 Glue Dorus VS 705/2 No 116 Glue, Hot Melt, Dorus VS 700 No 117 Glue Sticks, Tecknomelt No -


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Ref. Material/ CAS Dangerc2’ Amount Annual Nature of Use Rc3’ - s”’ - Ne or Substance(l) Number Category Stored Usage Phrase Phrase Code (tonnes) (tonnes)

118 Lox-eal Instant Glue No MSDS <I <I 119 MC-270 BK No MSDS cl cl

120 Melt -O- Clean Irritant <l 4 Packaging 1036 24125 121 Silicone Blue, Veraschem, No MSDS - <I cl 122 Videojet Ink 16 8420 Highly Flammable <I 4 R S7l9f 16

- Butanone 78-93-3 Irritant Packaging

11 I36137 - Ethanol 64-l 7-5 - Nitrocellulose 9004-70-O - Propan-2-01 67-63-O - Ethyl Acetate - Chromium Complex Dye 6%

141-78-5

- Chromium

123 Videojet Makeup Fluid 16-8425 Highly Flammable 4 <l Packaging RI 113613 S7/9/16 - Butanone 78-93-3 Irritating 7 - Ethanol 64-l 7-5 - Ethyl Acetate 141-78-6 - Methanol 67-56-l

124 Domino WL200 Wash 78-93-3 Highly Flammable <I <I R36l37 S7/9/16 - Butanone Irritating

Packaging

Notes: 1. 2. 3.

lof2 ~ cases where a material comprises a number of distinct and available dangerous substances, please give details for each component substance. c.f. Article 2(2) of SI NQ 77194 c.f. Schedules 2 and 3 of SI @ 77/94

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e C Licence Application 0 l Attachment N a


Ref. NC or Code

118 119 120 121 122

123 124

- I -

1 TALuft 1 Odour I EU Lists I and II Material/ Class 1,

Substance” 2 or 3 Odourous Yes/No Description

Threshold

urlm3

(Tick and specify Group/Family Number) Dangerous Substances Directive Groundwater Directive

76l464/EEC 80/68iEEC List I I List II +12gC4) List I I List II

Lox-eal Instant Glue MC-270 BK Melt -O- Clean Silicone Blue, Veraschem, Videojet Ink 16 8420

I Yes Characteristic

I ”

Videojet Makeup Fluid 16-8425 Domino WE!00 Wash

I I I I I I I Yes Characteristic 4 4

-I .A 4.1 II

Yes Yes

Characteristic Characteristic

I .-r I I .-t

I


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Table G.l(i): Details of Process related Raw Materials, Intermediates, Products, etc., used or b,,,..,, cI mnnnra

Ref. Material/ NC or Substance”’

- CM

Number Dangerc2’ Category

Amount Annual Nature of Use R”’ - ,CJc3) _ Stored Usage Phras Phrase

e Code -

125 Bare Knuckles Corrosive - Potassium hydroxide 1310-56-3 - 2-butoxyethanol 1 l-76-2

R20/21/22 S37/39 S45

- P-aminoethanol 141-43-5 - sodium dodecvlbensene sulfonate 25155_30-0-

126 Bioscan - Hanful

127 Carefree Maintainer Polish Eternum Harmful 6a439-46-3

c2 <3 - ethoxylated alcohol

Cleaning R22

- ethoxylated alcohol 68439-45-2 R36/38

132 Mr. Shifter - hydrochloric acid R36/37/3 s2a 550

- a Cross 133 Nova

134 Nova Plus 135 Pine Disinfectant 136 Peldge Clean and Dust Origional 137 Prochem Multi Pro

64742-4$!T” Harmful

co.5 <0.5 CO.5 CO.1 eO.1

<1.5 4.5 cl .5 co.5 co.5

Cleaning

Cleaning Cleaning Cleaning

RlOR35 - N/a 52 S24125

138

139 140

141

Speedball Heavy Duty Spray Cleaner - 2-butoxyethanol - 2-aminoethanol Sprint Glass Cleaner - propan-2-01 Sprint Cream Cleaner - calcium carbonate - alkane sulphonate Sprint Hard surface Cleaner 2-(2-Butoxyethoxy)ethanol - altky aryl sulphonate - ethoxylated alcohol

- 111-76-2 141-42 67-632

1317-65-3 68508-z4

11 2-345 28155-30-O 68439-46’3

Harmful (Xi&r)

Harmful (XiXn)

Cleaning

Cleaning Cleaning

Cleaning

Rll R22

R36/38

R22 R36/37/3

8

S26

144 Solapol Hand Cleaner - 145 Stripkleen solution

- Sodium hydroxide 131 o-73-2 2 Butoxyethanol 111-76-2

- Surfactants - Sequestreants -

Irritant Cleaning R38l41 S2/24/25/26/3 9146

lted on the site

G-26of88

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Notes: 1. In cases where a material comprises a number of distinct and available dangerous substances, please give details for each component substance. 2. c.f. Article 2(2) of SI P 77/94 3. cf. Schedules 2 and 3 of SI P 77/94



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Table G.l(i): Details of Process related Raw Materials, Intermediates, Products, etc., used or generated on the site -4

Ref. Material/ CAS Dangerc2) Amount Annual Nature of Use R”’ _ s”’ rn

N2 or Substance(‘) Numbef Category Stored Usage Phrase Phrase

Code (tonnes) (tonnes)

- 146 Tetra-n-butylammonium hydroxide 2052-49-5 Corrosive 0.014 co.01 Lab Chemical

solution 147 1, 1, 1 -Trichloroethane Harmful 0.005 <O.Ol Lab Chemical R20/59/2 S59/61

4125

148 1, 10 phenanthroline ferrous indicator 66-71-7- co.01 40.01 Lab Chemical R25l50l S45lS6OlS6 BDH 53 1

149 1,2, Dichloroethane 107-06-Z Highly flam, Toxic 0.0225 <O.Ol Lab Chemical R45f7 II3 s45 6137138 -

150 2, 2, 4-Trimethylpentane 540-84-l Highly flam, Harmful 0.05 CO.1 Lab Chemical R 11 I3815 S9ll6l29l33l O/53/65/ 60/6-i/62

67

151 P-Butanol 78-92-2 Irritant <O.Ol <O.Ol Lab Chemical Rll36l37 S16l26136 I38141 -

152 2-Methoxyethanol romil 109-86-4 Toxic <O.Ol co.01 Lab Chemical R60lR61 s45 Flammable I10 -

153 4-Amino-2,3-Dimethyl-l -Phenyl-3- 83-07-8 Harmful co.01 <O.Ol Lab Chemical R22 - Pyrazolin

154 8 Anilino-1 -naphthalenesulfonic acid Harmful <O.Ol <O.Ol Lab Chemical R20l21l S 26136 sigma 22l36l37

I38

lof2 Notes: 1.

2. 3.

In cases where a material COUP rises a number of distinct and available dangerous substances, please give details for each component substance. c.f. Article 2(2) of SI N’ 77194 cf. Schedules 2 and 3 of SI N’ 77/94

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Ref. TA Luft Odour EU Lists I and II Ne or Material/ Class 1, (Tick and specify Group/Family Number) Code Substance’2’ 2or3 Odourous Threshold Dangerous Substances Directive Groundwater Directive

Yes/No Description 76f464iEEC 80/68/EEC l&m3 List I List II +12gc4) List I List II

146 Tetra-n-butylammonium hydroxide N/A ND solution

147 1, 1, 1 -Trichloroethane 1 ND 4 List 11,120/132 4 1 1

148 1, 10 phenanthroline ferrous N/A ND indicator BDH

149 1,2, Dichloroethane 3 ND 4 J 1 1

150 2, 2, 4-Trimethylpentane N/A ND 151 2-Butanol N/A 152 2-Methoxyethanol romil 2 ND 2.3ppm 153 4-Amino-2,3-Dimethyl-1-Phenyl-3- N/A ND

Pyrazolin 154 8 Anilino-1 -naphthalenesulfonic N/A ND

acid sigma


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Ref. Material/ CAS Dangerc2’ Amount Annual Nature of Use Rc3’ - $3’ - N” or Substance”’ Number Category Stored Usage Phrase Phrase Code (tonnes) (tonnes)

155 Acetaldehyde 75-07-O Extremely flam, Harmful 0.01 <O.Ol Lab Chemical R 12l36l S 16/33/36l3 37140 7

- 156 Acetic acid 64-19-5 Corrosive 0.015 co.01 Lab Chemical RI 0135. S23126145 157 - 643 Acetic acid romil Corrosive 0.003 <O.Ol Lab Chemical RiOl35. S23/26/45 158 Acetic anhydride 108-24-y Corrosive 0.027 co.01 Lab Chemical Ri O/R34 R26/45 159 Acetone 67-64-l Highly flam, Irritant 0.01 co.01 Lab Chemical RI II361 S9ll6l26

66167

160 Acetonitrile 75-05-8 Highly flam, Toxic 0.25 <O.Ol Lab Chemical Rl i/201 S36l37.

- 21122136 161 Acetylacetone 213-54-6 Harmful 0.003 co.01 Lab Chemical RlOl22 S2llS23lS2

4125 162 Activated carbon aldrich 7440-44-D Irritant 0.004 co.01 Lab Chemical R20l3613 5222126136

- 7138 163 Ammonium acetate merck 631-61-B Irritant 0.0035 <O.Ol Lab Chemical R36l371 S 26136

- 38

164 Ammonium carbonate extra pure EC No. Irritant 0.01 co.01 Lab Chemical R36l371 526136 merck 233-78-2 38

165 Ammonium carbonate HPLC 506-87-6 Irritant 0.0015 <O.Ol Lab Chemical R36l37l3 S26/36 8

166 Ammonium ceric sulphate O.lm BDH Irritant, Oxidizing agent 0.006 <O.Ol Lab Chemical

lof2 Notes: 1. in cases where a material cor@eses a number of distinct and available dangerous substances, please give details for each component substance.

2. 3.

c.f. Article 2(2) of SI NQ 77/94 c.f. Schedules 2 and 3 of SI fl77/94

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Ref. 1 Ne or

I

Material/ Code Substance(2’

1 TALuft 1 Odour I EU Lists I and II I

155 156 157

Acetaldehyde Acetic acid Acetic acid romil

ND ND

Threshold

wh3

I (Tick and snecifv &n~wdlbmilv Nllrnht-x-1 II , - - - - - __--__ _ .~ V Y I A ..a=- I.u’-v--,

Dangerous Substances Directive Groundwater Directive 761464iEEC 80/68/EEC

List I List II +12gc4) List I List II

158 Acetic anhydride N/A ND 159 Acetone 3 ND 100-140 160 Acetonitrile N/A ND 161 Acetylacetone N/A ND 162 Activated carbon aldrich N/A ND 163 Ammonium acetate merck N/A ND 164 Ammonium carbonate extra pure N/A ND

merck 165 Ammonium carbonate HPLC N/A ND 166 Ammonium ceric sulphate O.lm N/A ND

BDH

Notes (cont.): 4. The European Commission priority candidate list 2of2

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Ref. Material/ CAS Dangerc2) Amount Annual Nature of Use Rc3’ _ $3’ - Ng or Substance(‘) Number Category Stored Usage Phrase Phrase Code (tonnes) (tonnes)

167 Ammonium cerium [iv] nitrate Soln Highly flammable 0.004 <0.004 Lab Chemical RN36137 S17/26/36 merck I38

168 Ammonium chloride merck Harmful 0.003 co.004 Lab Chemical R22l36 s22

169 Ammonium fe [II] sulphate hexahydrate 7783-85-g Irritant <O.OOl <O.OOl Lab Chemical R36l38 S26l36 mk

170 Ammonium fe [Ill] sulphate 7783-83-T I - <O.OOl 1 co.001 1 Lab Chetiictii ~~~ lR36/38 1 S26l36 I dodecahydrate mk -

171 Ammonium hexanitratocerate [iv] BDH 16774-213 Irritant, Oxidizing agent <O.OOl co.oo1 Lab Chemical R8-41 S17-26-39

172 Ammonium molybdate 13106-76-B Irritant <O.OOl <O.OOl Lab Chemical R36l37l3 526136 aldrich 8

/ 173 Ammonium peroxodisulfate merck 7727-54-o Oxidising <O.OOl co.oo1 Lab Chemical R8122i36 522l2412613

Harmful /37/38l4 7 2!43 -

174 Ammonium sulphate 7783-20-z Irritant 0.0025 co.0025 Lab Chemical R36l37l3 S26l36 a

175 Barium chloride dihydrate merck Toxic 0.004 0.003 Lab Chemical R20l25 s45

- 176 Barium chloride dihydrate merck Toxic 0.004 0.003 Lab Chemical R20l25 s45 ~ ~ 177 Benzene 71-43-2 Highly flam, Toxic 0.0125 0.3 Lab Chemical RI II4514 545153

al23i24i 25

- 178 Boric acid merck Harmful co.01 eo.01 Lab Chemical -

lof2 Notes: 1.

2. 3.

~ cases where a material comprises a number of distinct and available dangerous substances, please give details for each component substance. c.f. Article 2(2) of SI NQ 77/94 c.f. Schedules 2 and 3 of SI fl’ 77194

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EPA Export 25-07-2013:15:14:24

e- C Licence Application 0 0 Attachment N

*


Ref. TA Luft Odour EU Lists I and II

N2 or Material/ Class 1, (Tick and specify Group/Family Number)

Code Substance(2) 2or3 Odourous Threshold Dangerous Substances Directive Groundwater Directive Yes/No Description 76/464/EEC 80/68/EEC

wdm3 List I List II +129@’ List I List II

167 Ammonium cerium [iv] nitrate soln WA ND merck

168 Ammonium chloride merck N/A ND 169 Ammonium fe [II] sulphate N/A ND

hexahydrate mk 170 Ammonium fe [Ill] sulphate N/A ND

dodecahydrate mk 171 Ammonium hexanitratocerate [iv] N/A ND

BDH ND 4 4

172 Ammonium molybdate aldrich N/A I:9 I:9

173 Ammonium peroxodisulfate merck N/A ND

174 Ammonium sulphate N/A ND ND J 4

175 Barium chloride dihydrate merck N/A I:12 I:12

4 176 Barium chloride dihydrate merck N/A ND J

1:12 I:12

177 Benzene 3 ND J 129,7/132

Boric acid merck N/A ND 4 J 178

I:14 I:14

2of2


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EPA Export 25-07-2013:15:14:24


Table G.l(i): Details of Process reiated Raw Materials, Intermediates, Products, etc., used or generated on the site

Ref. Material/ CAS Dangerc2) Amount Annual Nature of Use Rc3’ m s”’ - Ne or Substance(‘) Number Category Stored Usage Phrase Phrase Code (tonnes) (tonnes)

<O.OOl 0.001 Lab Chemical Irritant 0.003 0.003 Lab Chemical

n/a 0.008 0.008 Lab Chemical 182 Buffer solution ph 7 None I n/a Lab Chemical 183 Butan-l-01 71-36-3 Harmful, Flammable 0.008 0.008 Lab Chemical Rl O/22/ S7l9l13f

37/38/47/6 261371391 1 46

184 Butanone 78-93-3 Highly flam, Irritant 0.0025 0.0025 Lab Chemical RillR36lR S9lS16 66lR67

185 Cadmium sulphate 7790&l-3_ Toxic 0.0025 0.0025 Lab Chemical R49EiOl53 S45160161 186 CI~i8un5arbonate merck 474-34-l Irritant 5.842 35.640 Lab ChemicallExcipient R37l38141 526139

( ) 187 Chromium standard solution 7697-37-Z Toxic 0.004 0.004 Lab Chemical R23/24/25/ 5451261361

34 37139123 188 Chromotropic acid disodium salt 5808-22-O <O.OOl <O.OOl Lab Chemical R36l37138 S26lS36

dihydrate - _ 189 Citric acid Irritant 77-92-9 0.0025 <O.OOl Lab Chemical R37138141 S36137139

lof2 Notes: 1. in cases where a material comprises a number of distinct and available dangerous substances, please give details for each component substance.

2. c.f. Article 2(2) of SI N’ 77194 3. c.f. Schedules 2 and 3 of SI Ng 77’94

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1 Ref. 1 1 TALuft 1 Odour I EU Lists I and II N2 or Material/ Class 1, (Tick and specify Group/Family Number) Code Substance’2’ 2or3 Odourous Threshold Dangerous Substances Directive Groundwater Directive

Y&No Description 76M4lFEC 8OkWEEC List I List II +129“‘) List I List II

179 Bromophenol blue, sodium 11, 1

180 Buffer solution ph 181 Buffer solution ph 4 ND 182 Buffer solution ph 7 ND 183 Butan-l-01 N/A ND 830 184 Butanone 3 ND 540-l 000 185 Cadmium sulphate 1 ND 4 4

6 6 186 Calcium carbonate merck N/A ND 187 Chromium standard solution 3 ND 4 d

I:4 I:4 188 Chromotropic acid disodium salt 3 ND J J

dihydrate 1:4 1:4 189 Citric acid N/A ND


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Ref. Material/ CAS Dangerc2’ Amount Annual Nature of Use Rc3’ m S’S’ - N9 or Substance”’ Number Category Stored Usage Phrase Phrase Code (tonnes) (tonnes)

190 Cobalt [II] nitrate hexahydrate merck Flammable, Harmful <O.OOl 10.001 Lab Chemical R8/22/36 Sl7/26/36 l37/38/4 3

191 Conductivity standard lOOuS csklO0 n/a 0.003 0.003 Lab Chemical - 192 Copper II ethylendediamine solution 7447-39-4 Harmful, Corrosive 0.003 0.003 Lab Chemical Fi22- S23-

BDH 36/38- 26/36/37/39- 50153 45-61

193 Cyclohexane 110-82-7 Highly flam, Harmful 0.005 0.005 Lab Chemical Rlll30l5 S9l16l33l601 01531651 61162 67

194 Dibutylphthalat merck 84-74-2 Toxic 0.005 0.005 Lab Chemical R6ll50l6 S53l45l61 2

195 Dichloromethane 75-09-2 Lab Chemical R40 52312412513 6137

196 Diethanolamine BDH 11 l-42-2 Harmful 0.0025 0.0025 Lab Chemical R22l3814 S2613613713 1 i4af22. 9146

197 Diethyl ether 60-29-7 Highly flam, Harmful 0.0027 0.0027 Lab Chemical Rl2/19/2 S9/16/29/33 2l66l67

198 Diethylamin 11 l-42-2 Hi flam,Corrosive 0.01 0.01 Lab Chemical R22l38l4 S2613613713 l/40/22 9146

199 Digol 11 l-46-6, Harmful 0.0025 0.0025 Lab Chemical R22 546 200 Di-iso -propyl ether 108-20-3 Highly flammable 0.00125 0.00125 Lab Chemical Rl7/19/6 SQll6l29l33

lof2 h cases where a material comprises a number of distinct and available dangerous substances, please give details for each component substance. cf. Article 2(2) of SI N’ 77/94 c.f. Schedules 2 and 3 of SI Ng 77194

Notes: 1. 2. 3.

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Ref. N2 or Code

190

191

192

193 194 195

196 197 198 199 200

1 TALuft Odour EU Lists I and II


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Table G.l(i): Details of process related Raw Materials, Intermediates, Products, etc., used or generated on the site

Ref. Material/ CAS Dangerc2’ Amount Annual Nature of Use Rc3’ m s”’ rn N2 or Substance(l) Number Category Stored Usage Phrase Phrase Code (tonnes) (tonnes)

201 Dimethyl sulphoxide 67-68-5 Irritant 0.005 0.005 Toxic

Lab Chemical

202 Dimmethylformamide ar 68-12-2 0.025 0.025 Lab Chemical R6ll20l2ll s45 - 36 1314-56-3, Corrosive <O.OOl <O.OOi

Corrosive Lab Chemical R35 522-26-45

204 Drichloroacetic acid 79-43-6 0.003 - 0.003 Lab Chemical R35l50 52645161

205 Ethanediol GPR 107-21-l Harmful 0.0125 0.0125 Highly flammable

Lab Chemical R22 - 206 Ethanol 64-17-5 0.02

Irritant 0.02 Lab Chemical Rll S7l16

207 Ethyl acetate 141-78-6 Highly flam, Irritant 0.0125 0.0125 Lab Chemical 11361 RI 516126133 66167

mMSDS- - Harmful <O.OOl co.001 Lab Chemical 209 Formamide 75-12-7 - Toxic 0.005 0.005 ---

Corrosive Lab Chemical R61 S53l45

210 Formic acid 64-l 8-6 0.005 - 0.005 Lab Chemical R35. S23/26/45 211 Glycerol anhydrous extra pure 56-81-5 Caution; avoid contact 0.280 0.500 Lab Chemical

(RNx9695)

lof2 Notes: 1. In cases where a material comP rises a number of distinct and available dangerous substances, please give details for each component substance.

2. c.f. Article 2(2) of SI N’ 77/94 3. c.f. Schedules 2 and 3 of SI N’ 77@4

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* C Licence Application Attachment Na


Ref. TA Luft Odour NC or Material/ Class 1, Code Substance’2’ 2or3 Odourous

Yes/No Description

201 Dimethyl sulphoxide N/A ND 202 Dimmethylformamide ar 2 ND 203 Di-phosphorus pentaoxide N/A ND

204 Drichloroacetic acid NIA ND

205 Ethanediol GPR N/A ND 206 Ethanol 2 ND 207 Ethyl acetate 2 ND

208 Fe [II] sulphate hepta hydrate N/A merck

209 Formamide N/A ND 210 Formic acid 1 ND 211 Glycerol anhydrous extra pure N/A ND


Threshold

xh3

96- 176.9ppm

EU Lists I and II (Tick and specify Group/FamiIy Number)

Dangerous Substances Directive Groundwater Directive 761464lEEC 80/68/EEC

List I List II +12gc4) List I List II

If 4 5 5

4 4 I 1

2of2

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Ref. Material/ CAS Danger”’ Amount Annual Nature of Use Rc3’ . s(3) - Ng or Substance”’ Number Category Stored Usage Phrase Phrase Code (tonnes) (tonnes)

212 Glycine merck 56-40-6 N/A 0.003 0.003 Lab Chemical - - 213 Heptane 142-82-5 Highly flam, Harmful 0.03 0.03 Lab Chemical Rlll38l S9/16l29/33/

50153165 60161162 I67 /

214 Hydranal solvent Highly flam, Toxic 0.012 0.012 Lab Chemical R7l23l25 Sl6/45/36/3 - Methyl Alcohol 67-56-11 I34 7139 - Sulphur di-oxide 7446-09-5 - lmidazole 288-32-4

215 Hydranol titrant No MSDS- Highly flam, Toxic 0.007 0.007 Lab Chemical -

216 Hydrogen peroxide soln BDH 7722-84-i Oxidising 0.004 0.004 Lab Chemical R34 Corrosive

217 Hydrogen peroxide merck 7722-84-i Oxidising 0.003 0.003 Lab Chemical R34 Corrosive /

218 Iron (111) chlodide B-hydrate 10025-77-1 Corrosive 0.003 0.003 Lab Chemical R34l22 52612713613 7139

219 Iron [Ill] chloride solution fe merck 231-729-4 Corrosive, Harmful if swallowed 0.005 0.005 Lab Chemical R34l22. S2612736137 I39

220 Lactose monohydrate merck 5989-81-1, N/A 0.015 0.015 Lab Chemical

~ 221 Lead standard merck 10099-74-S Irritant <O.OOl co.001 Lab Chemical R34i33 S26/27/36/3 7139 /

222 Led [II] acetate 3 hydrate BDH 6080-56-4 Toxic 0.0015 0.0015 Lab Chemical R6ll33l5 S45/60/61 0153162

lof2 Notes: 1.

2. 3.

h cases where a material comprises a number of distinct and available dangerous substances, please give details for each component substance. c.f. Article 2(2) of SI NQ 77/94 c.f. Schedules 2 and 3 of SI I@ 77/94

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e C Licence Application a Attachment N a


Ref. Ng or Code

212 213 214 215 216 217 218 219

220 221

222

-

MaterhI/ Substance’2’

Lactose monohydrate merck Lead standard merck

Led [II] acetate 3 hydrate BDH

-

Class 1, (Tick and specify Group/Family Number) 2or3 Odourous Threshold Dangerous Substances Directive Groundwater Directive

Yes/No Description 761464iF~EC 80/68BEC rrolm3 T .i,t T T :ot 77 L,30(4) List I I List II

N/A ND 4 3 ND 4

I:5 1:5 J 3 ND J

-I .E 1.5


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1 Ref. Material/ CAS Dangerc2) Amount Annual Substance”’

Nature of Use Rc3’ m &q3’ - NC or Number Category Stored Usage Phrase Phrase

, Code (tonnes) (toMes)

~ 223 Magnesium chloride anahdrous BDH Lab Chemical R36/37/38 526136 224 Maleic acid 10-16-7 Harmful 0.008 0.008 Lab Chemical R22/36/37/ S26/28/37

I 225 - Manganese [iv] oxide precipitated Harmful 38

co.oo1 <O.OOl Lab Chemical R20122 226 Manganese chloride 4 hydrate BDH 13446-34-9 Harmful

525 <O.OOi co.001 Lab Chemical R22/36/37l 526136

38140 227 Methanol 67-56-l Highly flam, Toxic 0.332 0.332 Lab Chemical RI I/23/24/ S7/16/

25139 Irritant

36137145 228 Methylbenzothiazolinone hydrazone 4338-98-l <O.OOl <O.OOi

hydrochlorid Lab Chemical R25 537-45

229 Methyl-iso-butyl ketone 108-10-I Highly Flammable 0.0025 0.0025 Irritant

Lab Chemical Rl l/20/36/ S9/16/29 37166

230 Mist detergent gentigleme No MSDS n/a 0.01 0.01 Lab Chemical 231 N-Hexane 108-10-l Highly flam, Harmful 0.02 0.02 Lab Chemical RI t/20/36/ S9l7 6129

37166 232 Nickel chloride None Toxic 0.03 0.03 Lab Chemical R45/23/24/ S45/26/28/

25/42/43/3 2713613713 6137138. 9

233 Ninhydrin merck 485-47-2 Harmful <O.OOl <O.OOi Lab Chemical R22/36137/ S28/28/36 38.

Notes: 1. 2. 3.

lof2 In cases where a material comprises a number of d&inct and available dangerous substances, please give details for each component substance. c.f. Article 2(2) of SI NE 77/94 c.f. Schedules 2 and 3 of SI p 77194

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e C Licence Application Attachment N a



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Ref. Material/ CAS Dangerc2’ Amount Annual Nature of Use R”’ - s”’ - N2 or Substance”’ Number Category Stored Usage Phrase Phrase

I I I I IPerchloric 1 7601-90-3 Highly flam, Corrosive 1 1 I

I I 3 242 acid 0.01 0.01 Lab Chemical 1 i=LSh3/35. 1 S23/26/36/

I I I 243 IPetroleum ether aldrich 1 8032-32-d 1 Highly flam, Harmful 1

1 45 0.04 1 0.04 1 Lab Chemical ~R11/23/25/~816/26/361

244 Phenolphthalein 77-09-8- Harmful 0.012 0.012

36/37/3816 45162 5

Lab Chemical R40. 536

Notes: 1. 2. 3.

lof2 ~ cases where a material comprises a number of distinct a& available dangerous substances, please give details for each component substance. cf. Article 2(2) of SI NQ 77194 cf. Schedules 2 and 3 of SI T@ 77/M

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EPA Export 25-07-2013:15:14:24

e C Licence Application 0 a Attachment N4)


L 01 L Notes (cont.): 4. The European Commission priority candidate list

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Ng or Code

Substance”’ Number Category Amount Annual Nature of Use R”’ m s”’ - Stored Usage Phrase Phrase (tonnes) (tonnes)

245 246

247 248

249

250

251

252

253

254

255

Phthalic anhydride merck 85-44-9 Harmful 0.001 0.001 Lab Chemical R36/37/ 38 - Polyvinylalkohol protective colloid 9002-89-5 Harmful co.001 <O.OOl merck

Lab Chemical

Potassium chloride extra pure merck Potassium dihydrogen orthophosphate 7778-77-D Irritant 0.003 0.003 BDH

Lab Chemical

Potassium dihydrogen phosphate 7778-77-D Irritant 0.016 0.016 merck

Lab Chemical

Potassium ferrocyanide trihydrate 14459-59-I Irritant <O.OOl <O.OOl Aldrich

Lab Chemical R32 S22l24f25

Potassium hexacyanoferrate 13746-66-Z Toxic, Harmful co.001 <O.OOl Lab Chemical R32l36137l S26l36

Potassium hydroxide pellets merck 131 O-58-3 Corrosive 38

0.005 0.005 Lab Chemical R22l35 S26/36/37/

Potassium permanganate GPR 7722-64-7 Highly flammable 39145

co.oo1 <O.OOl Lab Chemical R8l22l50/5 S6Of61

Potassium sodium tartrate tetrahydrate 6381-59-5 N/A 3

<O.OOi <O.OOl AL

Lab Chemical S22/24/25

Potassium sulphate merck 7778-80-5 Harmful if Swallowed co.001 /-yLab R22 S36

Notes: 1. 2. 3. c.f. Schedules i and 3 of SI NQ 77194

lof2 ~ cases where a material comprises a number of distinct and available dangerous substances, please give details for each component substance. c.f. Article 2(2) of SI NQ 77194

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e C Licence Application

i

Attachment Nb


Ref. N2 or Code


3 Polyvinylalkohol protective colloid

248

249

250

251

252

merck Potassium dihydrogen orthophosphate BDH Potassium dihydrogen phosphate merck Potassium ferrocyanide trihydrate aldrich Potassium hexacyanoferrate

Potassium hydroxide pellets

Notes (cont.): 4. The Euro1 :an Commission priority candidate list

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Notes: 1. 2. 3.

* In cases where a material co@) lof2

c.f. Article 2(2) of SI N’ 77194 flses a number of distinct and available dangerous substances, please give details for each component substance.

cf. Schedules 2 and 3 of SI I@ 77’g4

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EPA Export 25-07-2013:15:14:24

e C Licence Application Attachment Ne


ium acetate 3

Sodium arsenite solution BDH


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Ref. Material/ CAS Dangerc2) Amount Annual Nature of Use Rc3’ m Sc3’ m N2 or Substance”’ Number Category Stored Usage Phrase Phrase Code (tonnes) (tonnes)

Irritant 0.0025 O.O( 267 Sodium chloride merck Irritant <O.OOl co.oo1 268 Sodium hydroxide Corrosive 0.006 0.006 269 Sodium hvdroxide oellets merck Corrosive 0.004 0.004

272 273

45 Corrosive co.001 <O.OOl Lab Chemical R34 -

Highly flam,Toxic 10.001 co.001 Lab Chemical RW25 545 Sodium nitrosopentacyanoferrate (Ill) 13755-3829 Toxic <O.OOi <O.OOl Lab Chemical R25 S22l37145 Sodium phosphate dodecahydrate 10101-89-O Irritant <0.001 <O.OOl Lab Chemical R36l37138 526136

274 275

merck Sodium sulphate anhydrous merck Harmful 0.0095 0.0095 Lab Chemical 522J24125 Sodium tetroxoiodate (vii) Oxidising / Harmful <O.OOl <O.OOl Lab Chemical R8/20/22l3 Sl7/26/36

Notes: 1. 2. 3.

I 1 6137130 1 I

lof2 ~ cases where a material co@prises a number of distinct and available dangerous substances, please give details for each component substance. c.f. Article 2(2) of SI NQ 77/94 c.f. Schedules 2 and 3 of SI I@ 77/M

0 G-50of88

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1 TALuft 1 Odour I EU Lists I and II N2 or Material/ Class 1, (Tick and sue@ Group/Famil~ Number Code Substance”’ 2or3 Odourous Threshold Dangerous Substanc :es Directive

YCSINO Description 761464ffiI 32 Mm3 List I r. ,m .rrr.,m

hr. 11 +lLy” ust 1 lxx ll

266 Sodium carbonate anhydrous N/A ND merck

367 Snrii~m chlnridn rn~~& hIId hln

9 Groundwater Directive

80/68/JzEC T .-. I I T.-ITT

- - - . - . . - . . - . . - - . . . - . - . .

Sodium hydroxide Sodium hydroxide pellets merck Sodium hydroxide solution Sodium nitrite surer free flowino

1.1,. I . Y

N/A ND N/A ND N/A ND N/A Nl-l

- - .

268 269 270 771

272 Sodium nitrosopentacyanoferrate 3 No (111)

273 Sodium phosphate dodecahydrate N/A ND merck

274 Sodium sulphate anhydrous merck N/A ND 275 Sodium tetroxoiodate (vii) N/A ND


4 J 7 8

2of2

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Ref. Material/ CAS Dangerc2’ Amount Annual Nature of Use Rc3’ m s”’ - N2 or Substance(l) Number Category Stored Usage Phrase Phrase Code (tonnes) (tonnes)

- 276 Tert-butyl methyl ether BDH Highly flammable 0.0075 0.0075 Lab Chemical R36137138 S26l36 277 Tetrabutylammonium hydroxid aldrich Corrosive 0.0064 0.0064 Lab Chemical R7l34 5717 6l45l36l

37139 278 Tetrabutylammonium hydroxide SigmS Corrosive 0.0045 0.0045 Lab Chemical R7l34 S7l7 6l45l36l

37139 279 Tetrahydrofuran 7 09-99-g Highly flam, Irritant 0.025 0.025 Lab Chemical R77/79/36/ S76l29l33

37 Corrosive 0.005 0.005 Lab Chemical

287 Thiourea 99% aldrich Harmful Lab Chemical 282 Titanium (iv) -oxide Caution; avoid contact 0.004 0.004 Lab Chemical 283 Toluene 7 08-88-3 Highly flam, Harmful 0.075 0.075 Lab Chemical R7 7120 S7 6/25/29/3

3 264 Trichloroethylene Harmful Lab Chemical - 285 Triethylamine 727-4-8 Highly flam, Corrosive 0.07 0.06 Lab Chemical R77l20l27l S3/76/26/29/

22 36137139145 286 Xylene Lab Chemical

lof2 Notes: 1. h cases where a material comprises a number of distinct and available dangerous substances, please give details for each component substance,

2 c.f. Article 2(2) of SI N’ 77194 3 c.f. Schedules 2 and 3 of SI @ 77/g4

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* C Licence Application Attachment N e ’



G-53of88

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Ref. Material/ Ng or Substance(‘) Code

287 Basta 20 SL Glufosinate ammonium Propyleneglycol Monomethylether

288 Casoran G - Dichlobenil

289 Decis Petroleum Distillates

290 Enforcer -Di Chlorophen

I

293 IGestatoa I- “-chlo&4, 6 bis(ethylamino)-s-

296 297

- 3,5,6-Trichloro-2-pyridyloxy- acetic acid-2-[2-butoxyethyl]

- 2,4,dichlorphenoxy acetic acid [as ethylhexyl ester]

- 3,6 - dichloro-2-methoxybnzoic acid

Ozone Rambo 360/Round Up Biactive/Round Up GC. Glyphosphate (isopropyl salt of)

CAS Number

Dangerc2’ Category

Harmful

Amount Annual Stored Usage (tonnes) (tonnes) co.002 <0.002

Nature of Use Rc3’ m s”’ - Phrase Phrase

Facilities Eng R21122l36 S2l13l2Ol21/ 44

lo1 194-65-6 X(n) co.002 co.002 Facilities Eng

N/A co.002 co.002 Facilities Eng.

R21

100097-23-4 May cause Burns to skin and eves(Xn)

co.002 <0.002 Facilities Eng R34 .%?l13/20/21 I 26136137139

Toxic ti Fish _ co.005 Cl

<0.002 co.002 N/A Facilities Eng N/A

)79241-46-6 Flammable Facilities Eng R38l41 S2l13l2Ol21

Toxic to acquatic organisms 26128136137 39

co.002 co.002 122-34-9 N/A

Facilities Eng

N/A-----_-7 co.002 co.002 Facilities Eng

Flammable co.002 -co.002 Toxic to Fish

Facilities Eng

I I

38641-94-o Irritant co.002 co.002 Facilities Eng Facilities Eng

N/A N/A

lof2 Notes: 1.

2 in cases where a material comprises a number of distinct and available dangerous substances, please give details for each component substance. c.f. Article 2(2) of SI Ng 77/94

3 c.f. Schedules 2 and 3 of SI N’ 77/94

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EPA Export 25-07-2013:15:14:24

-* l H.-w- Licence Application Attachment NC .A 2

Details of Process related Raw Materials, Intermediates, Products, etc., used or generated on the site

1 TALuft 1 EU Lists I and II N2 or Material/ Class 1, (Tick and specify Group/Family Number) Code . Substance(2) 2or3 Odourous Threshold Dangerous Substances Directive Groundwater Directive

Yes/No Description 76/464/EEC 80/68/EEC wh3 List I List II +12gq4) List I List II

287 Basta 20 SL Yes Aromatic Glufosinate ammonium N/A Propyleneglycol Monomethylether

288 Casoran G N/A Yes Aromatic - Dichlobenil

289 Decis N/A ND 4 4 Petroleum Distillates 6 6

290 Enforcer N/A Yes Phenolic 4 4 -Di Chlorophen 1 1

291 EWS Indicator THOOT - TH300T N/A 292 Fusilade N/A N/A 4 4

Fluazifop-p-Butyl 1 1 293 Gestatop N/A ND J 4

- ‘khloro-4, 6 bis(ethylamino)-s- 1 1 triazlne

294 Microwet 525 N/A No Ethoxilated Alkylphenole

295 Nettleban N/A Yes Solvent 4 .J - - 3,5,6-Trichloro-2-pyridyloxy- 1 1

acetic acid-2-[2-butoxyethyi] - 2,4,dichlorphenoxy acetic acid

[as ethylhexyl ester] - 36 - dichloro-2-methoxybnzoic

acid 296 Ozone Yes Acrid Odour 297 Rambo 360/Round Up N/A Yes Slight Amine

Biactiie/Round Up GC. Glyphosphate (isopropyl salt 09


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