b nano tech
TRANSCRIPT
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QinetiQ Nanomaterials
Presentation to Rolls Royce
QNL Business OverviewQNL Business Overview
1 March 2007
Dr Paul ReipFounder and CTO / QNL
- making a material difference
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QinetiQ Nanomaterials
QinetiQ PLC
Europe’s largest independent team of scientists and engineers
- 10,000 staff - $1.5bn revenue
QinetiQ Inc established with five
subsidiary companiesMain business streams:
- Technology-based solutions- Consultancy- Technology exploitation- Integrated managed services
IPO Feb 15th 2006
A commercial science and technology powerhouse formed from the UK Government’s military andaerospace research & development organization with an unrivalled track record in applied science andtechnology
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QinetiQ Nanomaterials
What is QNL?
UK based company and wholly ownedsubsidiary of QinetiQ plc.
Patented process for developing andmanufacturing novel nanomaterials
A leading nanotechnology company with a
broad set of international customers andpartners
Focussed on serving the unmet material needsfor renewable energy, clean technologysystems and performance materials
Working with a number of select industrial andleading academic partners to developsolutions to the markets needs
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QinetiQ Nanomaterials
Driving the need for nanomaterials
Renewable energy sources now demanded & operationalRenewable energy sources now demanded & operational
Clean technologies needed to meet regulatory and social pressureClean technologies needed to meet regulatory and social pressure ss
Process improvements demand performance materials to driveProcess improvements demand performance materials to drivedown costs and increase efficiencydown costs and increase efficiency
$1BN R&D in$1BN R&D inAutomotiveAutomotive
$250BN$250BNGlobalGlobal
$2BN$2BN15%15%
80% Global80% GlobalGDPGDP
$250BN$250BNGlobalGlobal
$1BN R&D$1BN R&DAutomotiveAutomotive
$2BN$2BN15% CAGR15% CAGR
80%80%Global GDPGlobal GDP
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QinetiQ Nanomaterials
Areas of FocusSustainable Economy
• Clean Technology• Anti viral• Anti bacterial• Anti fungal• Water purification• Functional Fibres
• Energy Management• Hydrogen storage materials• Photovoltaic silicon film production• Efficient coolants & refrigerants
• Performance Materials• Tooling• CMP• Catalysis• Super Capacitors
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QinetiQ Nanomaterials
Market Environment & Sector Needs
Need for multimodal solutions for antiviral &antimicrobial materials
- MRSA costs the NHS £1BN in the UK.- An Avian flu pandemic among humans could cost
the global economy about ca. US$1.25 trillion.
AVNP
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QinetiQ Nanomaterials
Market Environment & Sector Needs
Low pressure and temperature materialsneeded to carry H 2 gas
- Lack of material hampering wider and more rapid adoption.- >50 million new vehicle sales globally each year
Inefficient manufacturing processes for solar grade silicon keeps cost per Watt too high for mass adoption
- 26,000 tons of Si required in 2004, 90% supply achieved- $6BN market ca.12% growth
- Si pricing upward pressure
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QinetiQ Nanomaterials
Nanomaterial fabrication processes
high volumeproduction
but limited quality /yield of material
typically used for oxides for
sunscreens, etc
medium volumeproduction
but long processingcycles, quality issues
typically used for oxides - silica,
alumina
low volumeproduction
used for multilayer structured
applications
typically used for photovoltaics, highvalue applicationssuch as nano bar
codes
medium / highvolume production
with high quality of material
typically used for premium applications,
metals, oxides,carbides, nitrides
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QinetiQ Nanomaterials
Feedstock
Vaporised
Cooled &Modification
Nanoproduct
Feed
system
Advantages of using plasma
- material uniformity- chemical composition- no contamination- better control- scalability- flexibility
- controllability- safety
The QNL Tesima® plasma process
Twin torch plasma – side view
Twin torch plasma – bottom view
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QinetiQ Nanomaterials
QNL Tesima® Process
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QinetiQ Nanomaterials
Tesima ® materials
MetalsAluminium
Copper
Silver
Nickel
Cobalt
TitaniumTungsten
Tantalum *
Boron *
* planned
OxidesZinc Oxide
Copper Oxide
Cerium Oxide
Tin Oxide
Cuprous Oxide
Titanium DioxideNickel Oxide
Zirconium Oxide
Carbides and NitridesTungsten Carbide
Aluminium Nitride
Boron Nitride
Silicon Carbide*
Silicon Nitride*
Boron Carbide*
Tesimet ® Tesimox ® Tesimide ®
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QinetiQ Nanomaterials
Tesima ® materials
Types
Doped materials
Alloys
Structured Blends
Layered
Non Stoichiometric
Tesimorph ®
Materials
ZnO / CuO
ZnO / TiO 2
Non stoi ZnO
Mixed Oxides
Stainless Steel
+ others under NDA
Applications
Electronics
Fuel Cells
Opto - electronics
Pyrotechnics
Rocket MotorsExplosives
Cermets
O&G
Defence
LayeredStructuredAlloysDoped Stoichiometry
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QinetiQ Nanomaterials
QNL Tesima ® Plant
QNL Facility commissioned 2002
New Tesima system (Al capable) 200524/7 capable
Metals, oxides, nitrides, carbidesTesimorph mixed materials
COMINA Rapid Particle Prototyping SystemScheduled for spring 2007
COMINA RPPS
TESIMA®
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QinetiQ Nanomaterials
COMINA Materials
Rapid Particle PrototypingCapability
- Metals, Oxides, Carbides, Nitrides,Sulphides
- Alloys- Mixed Oxides- Doped materials- Magnetic Materials- Catalysts- Phosphors
Cost Effective
Scaling Potential to kg’s and beyond
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QinetiQ Nanomaterials
QNL Nanomaterial Characterisation Services
Standard Tests – all materials:
Laser Particle Size Analysis (Mastersizer) QSEM QXRD QBET X
Specialised Tests – on request:
Raman Spectroscopy QSurface Characterisation (XPS) QTEM QDifferential Scanning Calorimetry (DSC) QDynamic Mechanical Thermal Analysis (DMTA)QExplosivity ( minimum ignition energy, layer ignition
energy, minimum ignition temperature, explosionseverity and LOC analysis)XOxygen Measurement XChemical Analysis XTEM EELS X
Q = in-houseX = external
Particle Size Distribution
0.01 0.1 1 10 100 1000 3000Particle Size (µm)
0
5
10
15
20
M i x e d R e s u
l t T y p e
( % )
Nano W QNA 1485, 21 February 2006 09:09:58 Nano W QNA 1485, 21 February 2006 09:09:58
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QinetiQ Nanomaterials
Material
Production
Formulation
& Dispersion
Application
DevelopmentCharacterisation HS&E
Associate
Provider
(Non-funded)
Core
Technology
Provider
(Funded)
Technology
Provider
(Non-funded)
Flame PyrolysisJohnson Matthey
High Energy MixingUniversity of Liverpool
Nano characterisationICI MSG
EU Nanomanufacturing Group
Nanoscale EngineeringLeeds Nanofactory
Coatings & CeramicsLongbridge
Trade / ResearchOrganisations
Liq. Phase ProcessingCPI / Uniqema
NanoSafeIOM
Colloid ScienceBCC
ColloidCharacterisation
BCC
MNT MetrologyCEMMNT
Multilayer CoatingHarman
High Shear PrecipitationHarman Dispersants
Noveon
Mixing / DispersingReed Bordal
Plastic Film CoatingAutotype
Ink Jet PrintingPTL / Xennia?
Nano characterisationMalvern Instruments
DispersionsSunChemical
Other Dispersant &DispersionSuppliers?
DTF?Lucite?Invista?
Toll Manufacturers
Colloidal PrecipitationAMR
CNTT. Swan
Grinding/Mixing/Coating
Imerys
Plasma ProcessingQNL
NanoCentral
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QinetiQ Nanomaterials
Energetics – Aluminium – Special Products
Aluminium (passivated) 80nm
200nm
Aluminium (passivated) 200nm
Tesima enable arange of Particle sizes tobe produced
1 μm
Tesima enables some variation
in particle morphologyto be produced
Highly sensitivenano Al with 200nm+ “tails”
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QinetiQ Nanomaterials
Aluminium Boron Nanomaterials
Sponsored by UK MOD
Development of ultra high performance Al/Bmaterials for energetic applications- Pyrotechnics- Explosives- Igniters- Rocket motors
• Solid • Hybrid
QNL Tesima® Aluminium process chosen
System modified to enable high performancematerials to be manufactured
Successfully manufactured – a world first
10nm
200nm
1mm
QNL nano Aluminium
QNL nano Aluminium / Boron
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QinetiQ Nanomaterials
Aluminium Boron Nanomaterials for Energetics
Tesimorph® EAB-80
80nm aluminium boron particles
Passivated with oxide layer
Produced under UK MOD contract
World first
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QinetiQ Nanomaterials
Stainless Steel
Tests with standard 316 stainless steelfeedstock
Results show good quality result with 25nmaverage particle size, slightly Cr poor
0 2 4 6 8 10Energy (keV)
0
5
10
15
ps
COCr Fe
Ni
Ni
Al
Cr
Cr
Fe
FeNi
Ni
10
90
81
8686
%Oxide
12
1.2
31.954.9
Atomic%
3.3Si
23.4C
48.7O
0.4Ni
8.9Cr 15.3Fe
Atomic%Element(Surface)
XPS Quantification QNA1030
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QinetiQ Nanomaterials
Value Proposition
Openly InnovativePartnered development leads to shared IP
Exquisite control of process gives unique materials
Rapid prototype facility
Support of 10,000 QinetiQ scientists and engineers
QNL assists companies generate greater valueQNL assists companies generate greater valueby enhancing their competitive advantage throughby enhancing their competitive advantage through
the application of unique nanomaterials, whichthe application of unique nanomaterials, whichenhance performance and reduces costs.enhance performance and reduces costs.
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QinetiQ Nanomaterials
IP Assets
OpticalCompone
nts
Energetics
CMP
Hard &Tough
Performance Materials
EnhancedCooling
Renewable Energy
Water Treatment
FIBRES
AVNP
Sustainable Economy
Puresiliconfilms
H StorageMultifunctionalparticles
Polymer Composite
Fibres
NEMSExplosiveDevices
Fuel CellInk JetShapeMemoryAlloys
KnowHowMat’l
Design
IP
Area
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QinetiQ Nanomaterials
Summary
Leading Nanotechnology CompanyFocussed on solving importantproblems
Substantial IP portfolio
Locked in partners
Own production facility
Ability to supply volume
Rapid prototyping capabilityGrowing revenue
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QinetiQ Nanomaterials
Contact Details
- Founder and CTO
Dr Paul [email protected]+44 [0] 1252 39 7412
- Sales Director Dr Ian [email protected]
+44 [0] 1252 39 2348 QinetiQ Nanomaterials LtdY25 BuildingCody Technology ParkFarnboroughHampshireUKGU14 0LX
Web
www.nano.qinetiq.comwww.avnp.co.uk