behavior of polymerized liquid crystal phases studied by positron annihilation
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Symposium abstracts 283
Another example of the excellent parallelism
between Ps formation and fluorescence is
shown in Fig. 1 in which I3 and the
fluorescence intensity L (one component,
C6F6 , of the binary mixture Is fluorescent)
are seen to follow the same trend.
Ps formation in the mixture shows a peculiar
S-shaped dependence on the composition, and
we found that the fluorescence of C F also 66
shows a similar S-shape with the maxima and
minima very close to those of Ps formation.
It has been deduced from such parallelism
that some of the Ps formatfan takes place via
electron abstraction from excited molecular
state C6Ft: a new mechanism of Ps formation.
Further results of Ps formation studies
have been presented, and emphasis was made
on the importance of the study not only
from a scientific viewpoint but also for
potential applications as a tool of
studying ultra-fast (sub-picosecond)
processes in radiation spur.
Fig.1 Comparison of fluorescence yield, L,
and Ps intensity, I 3’
as a function of
volume fraction of C F in cyclohexane. 66
44. BEHAVIOR OF POLYMERIZED LIQUID CRYSTAL PHASES STUDIED BY POSITRON ANNIHILATIO#
RAFAEL LOPEZ, SONIA MILLAN. JUAN CARLOS ALVAREZ AND LUZ ALICIA FUCUGAUCHI
lnstituto National de lnvestigaciones Nucleares. Unidad de lnvestigacidn Aplicada
Ave. lnsurgentes Sur 1073, 03720, N6xico. D. F.
In earlier work the technique of positron
annhilation was applied to a study of the
polymerization of lyotropic liquid crystals.
In this study, the same technique has been
used to detect phase transitions in the
liquid crystal system sodium ID-undecenate-
water. The sharp changes of the positron
annihilation parameters as a function of
temperature indicate structural chanqes in
this system. Photomicrographs of these
samples show the presence of nematic,
hexagonal, laminar and isotropic phases.